CN108441867A - A kind of aluminium ground and cleaned agent - Google Patents

A kind of aluminium ground and cleaned agent Download PDF

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Publication number
CN108441867A
CN108441867A CN201810357771.4A CN201810357771A CN108441867A CN 108441867 A CN108441867 A CN 108441867A CN 201810357771 A CN201810357771 A CN 201810357771A CN 108441867 A CN108441867 A CN 108441867A
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CN
China
Prior art keywords
aluminium
agent
parts
ground
cleaned
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Granted
Application number
CN201810357771.4A
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Chinese (zh)
Other versions
CN108441867B (en
Inventor
陈腾飞
Current Assignee (The listed assignees may be inaccurate. Google has not performed a legal analysis and makes no representation or warranty as to the accuracy of the list.)
GUANGDONG REDSUNSTAR INDUSTRY Co Ltd
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GUANGDONG REDSUNSTAR INDUSTRY Co Ltd
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Application filed by GUANGDONG REDSUNSTAR INDUSTRY Co Ltd filed Critical GUANGDONG REDSUNSTAR INDUSTRY Co Ltd
Priority to CN201810357771.4A priority Critical patent/CN108441867B/en
Publication of CN108441867A publication Critical patent/CN108441867A/en
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Publication of CN108441867B publication Critical patent/CN108441867B/en
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    • CCHEMISTRY; METALLURGY
    • C23COATING METALLIC MATERIAL; COATING MATERIAL WITH METALLIC MATERIAL; CHEMICAL SURFACE TREATMENT; DIFFUSION TREATMENT OF METALLIC MATERIAL; COATING BY VACUUM EVAPORATION, BY SPUTTERING, BY ION IMPLANTATION OR BY CHEMICAL VAPOUR DEPOSITION, IN GENERAL; INHIBITING CORROSION OF METALLIC MATERIAL OR INCRUSTATION IN GENERAL
    • C23GCLEANING OR DE-GREASING OF METALLIC MATERIAL BY CHEMICAL METHODS OTHER THAN ELECTROLYSIS
    • C23G1/00Cleaning or pickling metallic material with solutions or molten salts
    • C23G1/02Cleaning or pickling metallic material with solutions or molten salts with acid solutions
    • C23G1/12Light metals
    • C23G1/125Light metals aluminium
    • CCHEMISTRY; METALLURGY
    • C23COATING METALLIC MATERIAL; COATING MATERIAL WITH METALLIC MATERIAL; CHEMICAL SURFACE TREATMENT; DIFFUSION TREATMENT OF METALLIC MATERIAL; COATING BY VACUUM EVAPORATION, BY SPUTTERING, BY ION IMPLANTATION OR BY CHEMICAL VAPOUR DEPOSITION, IN GENERAL; INHIBITING CORROSION OF METALLIC MATERIAL OR INCRUSTATION IN GENERAL
    • C23GCLEANING OR DE-GREASING OF METALLIC MATERIAL BY CHEMICAL METHODS OTHER THAN ELECTROLYSIS
    • C23G1/00Cleaning or pickling metallic material with solutions or molten salts
    • C23G1/02Cleaning or pickling metallic material with solutions or molten salts with acid solutions
    • C23G1/04Cleaning or pickling metallic material with solutions or molten salts with acid solutions using inhibitors
    • C23G1/06Cleaning or pickling metallic material with solutions or molten salts with acid solutions using inhibitors organic inhibitors
    • C23G1/063Cleaning or pickling metallic material with solutions or molten salts with acid solutions using inhibitors organic inhibitors heterocyclic compounds

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  • Chemical & Material Sciences (AREA)
  • Chemical Kinetics & Catalysis (AREA)
  • General Chemical & Material Sciences (AREA)
  • Engineering & Computer Science (AREA)
  • Materials Engineering (AREA)
  • Mechanical Engineering (AREA)
  • Metallurgy (AREA)
  • Organic Chemistry (AREA)
  • Detergent Compositions (AREA)
  • Cleaning And De-Greasing Of Metallic Materials By Chemical Methods (AREA)

Abstract

The invention belongs to aluminium cleaning technique fields, and in particular to a kind of aluminium ground and cleaned agent.The aluminium cleaning technique field of the present invention includes following components:68 parts of fatty alcohol polyoxyethylene ether, 13 parts of dicarboxylate base complex, 13 parts of sodium metasilicate, 13 parts of sodium tripolyphosphate, 0.5 1.5 parts of ethylene diamine tetra methylene phosphonic acid, 0.8 1.6 parts of corrosion inhibiter, 13 parts of complexing agent, 46 parts of grinding agent, 30 40 parts of deionized water.The aluminium of the present invention ensures the lasting anti-corrosion of aluminium with the rusty stain and oil stain that can effectively remove aluminium material surface in ground and cleaned agent;The compounding of nano silicon dioxide and graphene oxide can reduce grinding agent and directly be scraped to aluminium material surface and cause cut, ensure that the aluminium material surface after cleaning is bright beautiful;The aluminum material cleaning agent itself of the present invention is nontoxic, can improve the glossiness of the aluminium material surface after cleaning, meet the requirement of aluminium, will not cause the deformation of aluminium.

Description

A kind of aluminium ground and cleaned agent
Technical field
The invention belongs to aluminium cleaning technique fields, and in particular to a kind of aluminium ground and cleaned agent.
Background technology
Aluminium is due to having many advantages, such as that density is small, specific strength is high, good heat conductivity, easily processed into type, in material engineering Aspect is widely used, and is widely used in the every field such as building materials, furniture, automobile component, communications and transportation, machine-building. As most metals, aluminium in use, is inevitably influenced by use environment.Present in environment Air, aqueous vapor, acidic materials, alkaline matter, oil stain etc., seriously affect aluminium at the problems such as causing corrosion contamination to aluminium Service life and appearance.
The problems such as corrosion and pollution in order to solve aluminium, aluminium need to be cleaned, at surface treatment, anti-corrosion The means such as reason, extend the service life of aluminium and ensure appearance.Existing aluminium cleaning agent, although aluminium material surface can be removed The pollutants such as rusty stain and oil stain, but the problem of in terms of not eliminating aluminium appearance.In addition, existing in existing aluminum material cleaning agent The high pollutions such as strong acid, highly basic or high toxic material not only endanger the body of user, also can cause environmental pollution and endanger.
Invention content
In view of the deficiencies of the prior art, the object of the present invention is to provide a kind of ground and cleaned agent of aluminium.The aluminium of the present invention Material cleaning agent includes the ingredient for removing the substances such as rusty stain, oil stain, can effectively remove the rusty stain and oil stain of aluminium material surface, and ensure aluminium The lasting anti-corrosion of material.In addition, also including grinding agent in the aluminum material cleaning agent of the present invention, aluminium table can be solved while cleaning The problem of appearance in face.
The purpose of the present invention is what is be achieved through the following technical solutions:
A kind of aluminium ground and cleaned agent, including following component by weight:
A kind of aluminium ground and cleaned agent, including following component by weight:
Preferably, the corrosion inhibiter is at least one of dicyclohexyl amine nitrite, benzotriazole.
It is further preferred that the corrosion inhibiter is dicyclohexyl amine nitrite and benzotriazole mass ratio 2:1 mixture.
Preferably, the complexing agent be in sodium citrate, sodium tartrate, sodium ethylene diamine tetracetate any one or it is more Kind.
Preferably, the grinding agent is at least one of nano silicon dioxide, graphene oxide.
It is further preferred that the grinding agent is nano silicon dioxide and graphene oxide mass ratio 1:3 mixture.
The aluminium ground and cleaned agent of the present invention, can effectively remove the rusty stain and spot of aluminium material surface.Nitrous acid is added Dicyclohexyl amine and benzotriazole mass ratio 2:1 mixture is as corrosion inhibiter, than individual dicyclohexyl amine nitrite or benzo The corrosion mitigating effect of triazole is more preferable.The nano silicon dioxide being added in ground and cleaned agent and graphene oxide in mass ratio 1:3 Mixture can reduce as grinding agent and directly cause cut using directly being scraped to aluminium material surface when nano silicon dioxide, Ensure that the aluminium material surface after cleaning is bright beautiful.By the compounding of each component special ratios, while ensureing elimination effect, also It can guarantee the bright smooth appearance of aluminium.
Beneficial effects of the present invention:
(1) the aluminium of the invention ingredient for including the substances such as removing rusty stain, oil stain in ground and cleaned agent, can effectively remove The rusty stain and oil stain of aluminium material surface, and ensure the lasting anti-corrosion of aluminium;
(2) grinding agent is nano silicon dioxide and graphene oxide mass ratio 1 in aluminum material cleaning agent of the invention:3 answer Match, grinding can be reduced, aluminium material surface is directly scraped and causes cut, ensures that the aluminium material surface after cleaning is bright beautiful;
(3) aluminum material cleaning agent itself of the invention is nontoxic, can improve the glossiness of the aluminium material surface after cleaning, full The requirement of sufficient aluminium will not cause the deformation of aluminium.
Specific implementation mode
The present invention is further explained in the light of specific embodiments.
Embodiment 1
A kind of aluminium ground and cleaned agent, including following component by weight:
Embodiment 2
A kind of aluminium ground and cleaned agent, including following component by weight:
Embodiment 3
A kind of aluminium ground and cleaned agent, including following component by weight:
Comparative example 1
A kind of aluminium ground and cleaned agent, including following component by weight:
Comparative example 2
A kind of aluminium ground and cleaned agent, including following component by weight:
Comparative example 3
A kind of aluminium ground and cleaned agent, including following component by weight:
The aluminium of embodiment 1 is compared with ground and cleaned agent and the aluminium of comparative example 1-3 with ground and cleaned, table is as a result listed in In 1.
1 embodiment 1 of table is compared with the aluminium of comparative example 1-3 ground and cleaned agent effect
There is upper table to can be seen that the aluminium of the present invention in ground and cleaned agent, corrosion inhibiter dicyclohexyl amine nitrite and benzene And triazole mass ratio 2:When 1 compounding, rust staining is had not seen in 6 months, corrosion mitigating effect is significantly better than exclusive use nitrous acid two The effect of cyclohexylamine or benzotriazole.When being not added with graphene oxide, aluminium ground and cleaned agent of the invention can be to aluminium Surface cause cut, and nano silicon dioxide and graphene oxide mass ratio 1:3 compounding, can be to avoid ground and cleaned agent pair The damage of aluminium ensures the surface that the bright beautiful, no marking of aluminium scratches.

Claims (7)

1. a kind of ground and cleaned agent of aluminium, which is characterized in that including following component by weight:
2. aluminium according to claim 1 ground and cleaned agent, which is characterized in that including following group by weight Point:
3. aluminium according to claim 1 or 2 ground and cleaned agent, which is characterized in that the corrosion inhibiter is nitrous acid two At least one of cyclohexylamine, benzotriazole.
4. aluminium according to claim 3 ground and cleaned agent, which is characterized in that the corrosion inhibiter is two hexamethylene of nitrous acid Amine and benzotriazole mass ratio 2:1 mixture.
5. aluminium according to claim 1 or 2 ground and cleaned agent, which is characterized in that the complexing agent be sodium citrate, Any one or more in sodium tartrate, sodium ethylene diamine tetracetate.
6. aluminium according to claim 1 or 2 ground and cleaned agent, which is characterized in that the grinding agent is nano-silica At least one of SiClx, graphene oxide.
7. aluminium according to claim 6 ground and cleaned agent, which is characterized in that the grinding agent is nano silicon dioxide With graphene oxide mass ratio 1:3 mixture.
CN201810357771.4A 2018-04-20 2018-04-20 Grinding cleaning agent for aluminum material Active CN108441867B (en)

Priority Applications (1)

Application Number Priority Date Filing Date Title
CN201810357771.4A CN108441867B (en) 2018-04-20 2018-04-20 Grinding cleaning agent for aluminum material

Applications Claiming Priority (1)

Application Number Priority Date Filing Date Title
CN201810357771.4A CN108441867B (en) 2018-04-20 2018-04-20 Grinding cleaning agent for aluminum material

Publications (2)

Publication Number Publication Date
CN108441867A true CN108441867A (en) 2018-08-24
CN108441867B CN108441867B (en) 2020-05-19

Family

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Family Applications (1)

Application Number Title Priority Date Filing Date
CN201810357771.4A Active CN108441867B (en) 2018-04-20 2018-04-20 Grinding cleaning agent for aluminum material

Country Status (1)

Country Link
CN (1) CN108441867B (en)

Citations (4)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
US20060241006A1 (en) * 2002-05-21 2006-10-26 Fujitsu Limited Method of washing a polished object
CN101285194A (en) * 2007-04-11 2008-10-15 姜堰市德美化工有限公司 Spent meal for treating surface of non-ferrous metal and method for preparing same
CN101337782A (en) * 2008-08-12 2009-01-07 江苏博特新材料有限公司 Synthetic fibre for reinforced concrete with rust prevention function and method for preparing same
CN107880784A (en) * 2017-12-04 2018-04-06 苏州市宽道模具机械有限公司 A kind of high-performance polishing fluid and preparation method thereof

Patent Citations (4)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
US20060241006A1 (en) * 2002-05-21 2006-10-26 Fujitsu Limited Method of washing a polished object
CN101285194A (en) * 2007-04-11 2008-10-15 姜堰市德美化工有限公司 Spent meal for treating surface of non-ferrous metal and method for preparing same
CN101337782A (en) * 2008-08-12 2009-01-07 江苏博特新材料有限公司 Synthetic fibre for reinforced concrete with rust prevention function and method for preparing same
CN107880784A (en) * 2017-12-04 2018-04-06 苏州市宽道模具机械有限公司 A kind of high-performance polishing fluid and preparation method thereof

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