CN102766880A - Water-based washing agent for black metal parts - Google Patents
Water-based washing agent for black metal parts Download PDFInfo
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- CN102766880A CN102766880A CN2012102435352A CN201210243535A CN102766880A CN 102766880 A CN102766880 A CN 102766880A CN 2012102435352 A CN2012102435352 A CN 2012102435352A CN 201210243535 A CN201210243535 A CN 201210243535A CN 102766880 A CN102766880 A CN 102766880A
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- C—CHEMISTRY; METALLURGY
- C23—COATING METALLIC MATERIAL; COATING MATERIAL WITH METALLIC MATERIAL; CHEMICAL SURFACE TREATMENT; DIFFUSION TREATMENT OF METALLIC MATERIAL; COATING BY VACUUM EVAPORATION, BY SPUTTERING, BY ION IMPLANTATION OR BY CHEMICAL VAPOUR DEPOSITION, IN GENERAL; INHIBITING CORROSION OF METALLIC MATERIAL OR INCRUSTATION IN GENERAL
- C23G—CLEANING OR DE-GREASING OF METALLIC MATERIAL BY CHEMICAL METHODS OTHER THAN ELECTROLYSIS
- C23G1/00—Cleaning or pickling metallic material with solutions or molten salts
- C23G1/02—Cleaning or pickling metallic material with solutions or molten salts with acid solutions
- C23G1/08—Iron or steel
- C23G1/088—Iron or steel solutions containing organic acids
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Abstract
The invention discloses a water-based washing agent for black metal parts. The water-based washing agent comprises the following components by weight percent: 2-10% of alcohol ether carboxylate, 2-10% of polycarboxylate, 5-20% of alcohol ether surfactant, 5-10% of oleamide, 1-2.5% of diethanol amine, 1-2.5% of triethanolamine, 0.1-2% of benzotrizaole, 0.5-2% of benzoate, 0.5-2% of edetate, 2-10% of alcohols, 0.001-0.01% of colorant, and the balance being de-ionized water. The water-based washing agent is capable of guaranteeing washing cleanliness of black metal without corroding the black metal parts, good in detergency, good in surface quality, green and environment-friendly, quick and safe, non-combustible and nonexplosive, simple and convenient to operate, low in cost, non-toxic and harmless to a human body, convenient and safe for use, and capable of saving energy source; besides, the water-based washing agent has short-term rust protection function to the black metal parts; and the rust protection period is over 10 days.
Description
Technical field
The present invention relates to a kind of clean-out system, particularly a kind of ferrous metal part is used aqueous cleaning agent.
Background technology
Ferrous material is that the general designation to iron, chromium and manganese is gone up in industry, also comprises alloy, especially the alloy ferrous metal steel and the iron and steel of these three kinds of metals.When the maintenance and repair of machining and mechanical means, automobile etc.; More traditional mode is to adopt diesel oil, kerosene or gasoline to come cleaning components as scavenging solution, and this not only wastes energy, and exists the potential unsafe factor; Careless slightly, then possibly lead to fire.In recent years, metal cleaner has obtained using widely gradually, and it can substitute diesel oil, kerosene and gasoline well and come cleaning components.Ferrous metal generally adopts solvent cleaning, strong acid and strong base cleaning etc. with clean-out system both at home and abroad at present.Solvent cleaning is mainly utilized leaning solvent to carry out steam flushing through suitable equipment or is embathed.Because leaning solvent is not only expensive and have inflammable and shortcoming injured skin; Also be environmental pollutant simultaneously; Need prevent the solvent that steam leakage and recovery and processing and utilizing are crossed with the method and the special device of high cost; Have potential safety hazard equally, not environmental protection very easily causes environmental pollution, increases Financial cost simultaneously.And the strong acid and strong base cleaning is to utilize the intensive chemical action of strong acid (the for example vitriol oil, concentrated hydrochloric acid, SPA) or highly basic (like Pottasium Hydroxide, sodium hydroxide etc.) to remove crude removal; The strong acid and strong base very corrosive; Corrode part easily; Equipment there is infringement, the stagnation that causes the seepage of numerous hardwares easily even scrap and produce.More than two kinds of methods all exist and have after the drying residually, the ferrous metal part is corroded easily, shortcomings such as surface quality difference and dangerous environmental protection, postorder liquid waste disposal difficulty.Along with the particularly fast development of assemblying industries such as automobile, motorcycle and aircraft of modern industry, the component surface clean-out system of its assembly industry has proposed environmental protection thereupon, does not fire not quick-friedly, fast and safely waits high request.
Therefore, need a kind of ferrous metal part to use aqueous cleaning agent, do not corrode ferrous metal part itself; Soil removability is strong and cleaning speed is fast, and cleaning performance is good, and the ferrous metal surface quality that is cleaned is good; Do not have inflammable and explosive characteristic, and can not cause bigger detrimentally affect, do not contain hazardous substance Working environment; To operator's toxicological harmless, have Safety and Environmental Protection preferably, and the ferrous metal component that cleaned are had the rust protection effect.
Summary of the invention
In view of this, the object of the present invention is to provide a kind of ferrous metal part to use aqueous cleaning agent, have the strong osmotic ability; Porous can dissolve rapidly and remove various dirts and the impurity that is attached to the metallic surface to cleaning the thing bottom, does not have depositional phenomenon again during cleaning; Cleaning process does not have the burn into not damaged to the metallic surface, and cleaning speed is fast, and it is clean, bright to clean the metallic surface, back; The metallic surface quality is good, can effectively ensure the working accuracy of ferrous metal, does not have inflammable and explosive characteristic; SF is high during use, also can not cause bigger detrimentally affect to Working environment, does not contain harm surrounding materials such as nitrite, phenol, formaldehyde; Heating during use when cleaning, scrub, spray, modes such as vibration or UW make greasy dirt break away from workpiece surface as early as possible, thereby be distributed in the scavenging solution, to operator's toxicological harmless; Have Safety and Environmental Protection preferably, liquid waste disposal is easy, and the cleaning cost is low and economic benefit is high; Simultaneously can effectively improve processing environment and workshop hygiene situation, be beneficial to and increase work efficiency; This clean-out system has the effect of short-term rust protection to the ferrous metal component that cleaned, and rust-proof life was above 10 days.
Ferrous metal part of the present invention is used aqueous cleaning agent; Clean-out system comprises following component by weight percentage: 2-10% alcohol ether carboxylate, 2-10% polycarboxylate, 5-20% alcohol ether surface active agent, 5-10% oleylamide, 1-2.5% diethylolamine, 1-2.5% trolamine, 0.1-2% benzotriazole, and 0.5-2% benzoate, 0.5-2% edetate, 2-10% alcohols, 0.001-0.01% tinting material, all the other add to 100% for deionized water;
Further; Clean-out system comprises following component by weight percentage: 6% alcohol ether carboxylate, 6% polycarboxylate, 12% pure ether surface active agent, 7.5% oleylamide, 1.75% diethylolamine, 1.75% trolamine, 1% benzotriazole, and 1.2% benzoate, 1.2% edetate, 6% alcohols, 0.005% tinting material, all the other add to 100% for deionized water;
Further, said polycarboxylate is one or more the mixture in hexanodioic acid, sebacic acid, undecandioic acid, IRGACOR L190, Trisodium Citrate, Sunmorl N 60S, hydroxy acid sodium, the dimeracid potassium;
Further, said pure ether surface active agent is one or more the mixture in AEO, TX10, sorbitol monooleate, polyoxyethylene sorbitan monoleate, NP ether phosphoric acid methyl esters ethanolamine salt, oleic acid glycol ester, dodecyl polyethenoxy ether sodium sulfate, the polyoxyethylene glycol;
Further, said oleylamide is one or more the mixture in triethanolamine oleate, oleoyl sarcosine stearylamine, coconut oil terepthaloyl moietie acid amides, boronation oleylamide, the oleic acid terepthaloyl moietie acid amides.
Further, said alcohols is one or more the mixture in ethanol, Virahol, propyl carbinol, lauryl alcohol, terepthaloyl moietie, the USP Kosher;
Further, said tinting material be phthalocyanine, one or more the mixture in indigo.
Beneficial effect of the present invention: ferrous metal part of the present invention is used aqueous cleaning agent, is main promoting agent with polycarboxylate, pure ether surface active agent, is the lubrication protection synergistic agent with oleylamide, benzotriazole, and benzoate, edetate etc. is a washing assistant; Alcohols and deionized water are solvent, and the water base cleaning of weakly alkaline has the strong osmotic ability; Porous can dissolve rapidly and remove various dirts and the impurity that is attached to the metallic surface to cleaning the thing bottom, does not have depositional phenomenon again during cleaning; Cleaning process does not have the burn into not damaged to the metallic surface, and cleaning speed is fast, and it is clean, bright to clean the metallic surface, back; The metallic surface quality is good, can effectively ensure the working accuracy of ferrous metal, does not have inflammable and explosive characteristic during use; SF is high, also can not cause bigger detrimentally affect to Working environment, does not contain harm surrounding materials such as nitrite, phenol, formaldehyde; Heating during use when cleaning, scrub, spray, modes such as vibration or UW make greasy dirt break away from workpiece surface as early as possible, thereby be distributed in the scavenging solution, to operator's toxicological harmless; Have Safety and Environmental Protection preferably, liquid waste disposal is easy, and the cleaning cost is low and economic benefit is high; Simultaneously can effectively improve processing environment and workshop hygiene situation, be beneficial to and increase work efficiency; This clean-out system has the effect of short-term rust protection to the ferrous metal component that cleaned, and rust-proof life was above 10 days.
Embodiment
Embodiment one
The ferrous metal part of present embodiment is used aqueous cleaning agent; Clean-out system comprises following component by weight percentage: 6% alcohol ether carboxylate, 6% polycarboxylate, 12% pure ether surface active agent, 7.5% oleylamide, 1.75% diethylolamine, 1.75% trolamine, 1% benzotriazole, and 1.2% benzoate, 1.2% edetate, 6% alcohols, 0.005% tinting material, all the other add to 100% for deionized water;
In the present embodiment; Said polycarboxylate is a hexanodioic acid; In the present embodiment, hexanodioic acid is replaced with a kind of in sebacic acid, undecandioic acid, IRGACOR L190, Trisodium Citrate, Sunmorl N 60S, hydroxy acid sodium, the dimeracid potassium according to equivalent weight per-cent; Perhaps replace with the mixture of hexanodioic acid and sebacic acid, undecandioic acid, IRGACOR L190, Trisodium Citrate, Sunmorl N 60S, hydroxy acid sodium and dimeracid potassium according to equivalent weight per-cent; All qualified ferrous metal part is used aqueous cleaning agent, the character of products obtained therefrom does not have significant difference;
In the present embodiment; Said pure ether surface active agent is an AEO; In the present embodiment, AEO is replaced with a kind of in TX10, sorbitol monooleate, polyoxyethylene sorbitan monoleate, NP ether phosphoric acid methyl esters ethanolamine salt, oleic acid glycol ester, dodecyl polyethenoxy ether sodium sulfate, the polyoxyethylene glycol according to equivalent weight per-cent; Perhaps replace with the mixture of AEO and TX10, sorbitol monooleate, polyoxyethylene sorbitan monoleate, NP ether phosphoric acid methyl esters ethanolamine salt, oleic acid glycol ester, dodecyl polyethenoxy ether sodium sulfate and polyoxyethylene glycol according to equivalent weight per-cent; All qualified ferrous metal part is used aqueous cleaning agent, the character of products obtained therefrom does not have significant difference;
In the present embodiment; Said oleylamide is a triethanolamine oleate; In the present embodiment; Triethanolamine oleate is replaced with a kind of of oleoyl sarcosine stearylamine, coconut oil terepthaloyl moietie acid amides, boronation oleylamide, oleic acid terepthaloyl moietie acid amides according to equivalent weight per-cent; Perhaps replace with the mixture of triethanolamine oleate and oleoyl sarcosine stearylamine, coconut oil terepthaloyl moietie acid amides, boronation oleylamide and oleic acid terepthaloyl moietie acid amides according to equivalent weight per-cent, all qualified ferrous metal part is used aqueous cleaning agent, the character of products obtained therefrom does not have significant difference;
In the present embodiment; Said alcohols is an ethanol; In the present embodiment, ethanol is replaced with a kind of in Virahol, propyl carbinol, lauryl alcohol, terepthaloyl moietie, the USP Kosher according to equivalent weight per-cent, perhaps replace with the mixture of ethanol and Virahol, propyl carbinol, lauryl alcohol, terepthaloyl moietie and USP Kosher according to equivalent weight per-cent; All qualified ferrous metal part is used aqueous cleaning agent, the character of products obtained therefrom does not have significant difference;
In the present embodiment, said tinting material is a phthalocyanine, in the present embodiment, replaces with indigo according to equivalent weight per-cent phthalocyanine; Perhaps replace with phthalocyanine and indigo mixture according to equivalent weight per-cent, all qualified ferrous metal part is used aqueous cleaning agent, the character of products obtained therefrom does not have significant difference;
The ferrous metal part of present embodiment is used aqueous cleaning agent, the heating during use when cleaning, scrub, spray, modes such as vibration or UW make greasy dirt break away from workpiece surface as early as possible, thereby are distributed in the scavenging solution; Nonflammable; To operator's toxicological harmless, have Safety and Environmental Protection preferably, the metallic surface there is not the burn into not damaged; The cleaning of ferrous metal piece surface, light and no color differnece, rust-proof life surpasses more than 15 days.
Embodiment two
The ferrous metal part of present embodiment is used aqueous cleaning agent; Clean-out system comprises following component by weight percentage: 2% alcohol ether carboxylate, 2% polycarboxylate, 5% pure ether surface active agent, 5% oleylamide, 1% diethylolamine, 1% trolamine, 0.1% benzotriazole, and 0.5% benzoate, 0.5% edetate, 2% alcohols, 0.001% tinting material, all the other add to 100% for deionized water;
In the present embodiment; Said polycarboxylate is a sebacic acid; In the present embodiment, sebacic acid is replaced with a kind of in hexanodioic acid, undecandioic acid, IRGACOR L190, Trisodium Citrate, Sunmorl N 60S, hydroxy acid sodium, the dimeracid potassium according to equivalent weight per-cent; Perhaps replace with the mixture of sebacic acid and hexanodioic acid, undecandioic acid, IRGACOR L190, Trisodium Citrate, Sunmorl N 60S, hydroxy acid sodium and dimeracid potassium according to equivalent weight per-cent; All qualified ferrous metal part is used aqueous cleaning agent, the character of products obtained therefrom does not have significant difference;
In the present embodiment; Said pure ether surface active agent is a TX10; In the present embodiment, TX10 is replaced with a kind of in AEO, sorbitol monooleate, polyoxyethylene sorbitan monoleate, NP ether phosphoric acid methyl esters ethanolamine salt, oleic acid glycol ester, dodecyl polyethenoxy ether sodium sulfate, the polyoxyethylene glycol according to equivalent weight per-cent; Perhaps replace with the mixture of TX10 and AEO, sorbitol monooleate, polyoxyethylene sorbitan monoleate, NP ether phosphoric acid methyl esters ethanolamine salt, oleic acid glycol ester, dodecyl polyethenoxy ether sodium sulfate and polyoxyethylene glycol according to equivalent weight per-cent; All qualified ferrous metal part is used aqueous cleaning agent, the character of products obtained therefrom does not have significant difference;
In the present embodiment; Said oleylamide is the oleoyl sarcosine stearylamine; In the present embodiment; The oleoyl sarcosine stearylamine is replaced with a kind of of triethanolamine oleate, coconut oil terepthaloyl moietie acid amides, boronation oleylamide, oleic acid terepthaloyl moietie acid amides according to equivalent weight per-cent; Perhaps replace with the mixture of oleoyl sarcosine stearylamine and triethanolamine oleate, coconut oil terepthaloyl moietie acid amides, boronation oleylamide and oleic acid terepthaloyl moietie acid amides according to equivalent weight per-cent, all qualified ferrous metal part is used aqueous cleaning agent, the character of products obtained therefrom does not have significant difference;
In the present embodiment; Said alcohols is a Virahol; In the present embodiment, ethanol is replaced with a kind of in ethanol, propyl carbinol, lauryl alcohol, terepthaloyl moietie, the USP Kosher according to equivalent weight per-cent, perhaps replace with the mixture of Virahol and ethanol, propyl carbinol, lauryl alcohol, terepthaloyl moietie and USP Kosher according to equivalent weight per-cent; All qualified ferrous metal part is used aqueous cleaning agent, the character of products obtained therefrom does not have significant difference;
In the present embodiment, said tinting material is indigo, in the present embodiment, phthalocyanine is replaced with phthalocyanine according to equivalent weight per-cent; Perhaps replace with indigo and mixture phthalocyanine according to equivalent weight per-cent, all qualified ferrous metal part is used aqueous cleaning agent, the character of products obtained therefrom does not have significant difference;
The ferrous metal part of present embodiment is used aqueous cleaning agent, the heating during use when cleaning, scrub, spray, modes such as vibration or UW make greasy dirt break away from workpiece surface as early as possible, thereby are distributed in the scavenging solution; Nonflammable; To operator's toxicological harmless, have Safety and Environmental Protection preferably, the metallic surface there is not the burn into not damaged; The cleaning of ferrous metal piece surface, light and no color differnece, rust-proof life was above 12 days.
Embodiment three
The ferrous metal part of present embodiment is used aqueous cleaning agent; Clean-out system comprises following component by weight percentage: 10% alcohol ether carboxylate, 10% polycarboxylate, 20% pure ether surface active agent, 10% oleylamide, 2.5% diethylolamine, 2.5% trolamine, 2% benzotriazole, and 2% benzoate, 2% edetate, 10% alcohols, 0.01% tinting material, all the other add to 100% for deionized water;
In the present embodiment; Said polycarboxylate is a undecandioic acid; In the present embodiment, undecandioic acid is replaced with a kind of in sebacic acid, hexanodioic acid, IRGACOR L190, Trisodium Citrate, Sunmorl N 60S, hydroxy acid sodium, the dimeracid potassium according to equivalent weight per-cent; Perhaps replace with the mixture of undecandioic acid and hexanodioic acid, sebacic acid, IRGACOR L190, Trisodium Citrate, Sunmorl N 60S, hydroxy acid sodium and dimeracid potassium according to equivalent weight per-cent; All qualified ferrous metal part is used aqueous cleaning agent, the character of products obtained therefrom does not have significant difference;
In the present embodiment; Said pure ether surface active agent is a sorbitol monooleate; In the present embodiment, AEO is replaced with a kind of in TX10, AEO, polyoxyethylene sorbitan monoleate, NP ether phosphoric acid methyl esters ethanolamine salt, oleic acid glycol ester, dodecyl polyethenoxy ether sodium sulfate, the polyoxyethylene glycol according to equivalent weight per-cent; Perhaps replace with the mixture of sorbitol monooleate and TX10, AEO, polyoxyethylene sorbitan monoleate, NP ether phosphoric acid methyl esters ethanolamine salt, oleic acid glycol ester, dodecyl polyethenoxy ether sodium sulfate and polyoxyethylene glycol according to equivalent weight per-cent; All qualified ferrous metal part is used aqueous cleaning agent, the character of products obtained therefrom does not have significant difference;
In the present embodiment; Said oleylamide is a coconut oil terepthaloyl moietie acid amides; In the present embodiment; Triethanolamine oleate is replaced with a kind of of oleoyl sarcosine stearylamine, triethanolamine oleate, boronation oleylamide, oleic acid terepthaloyl moietie acid amides according to equivalent weight per-cent; Perhaps replace with the mixture of coconut oil terepthaloyl moietie acid amides and oleoyl sarcosine stearylamine, triethanolamine oleate, boronation oleylamide and oleic acid terepthaloyl moietie acid amides according to equivalent weight per-cent, all qualified ferrous metal part is used aqueous cleaning agent, the character of products obtained therefrom does not have significant difference;
In the present embodiment; Said alcohols is a propyl carbinol; In the present embodiment, ethanol is replaced with a kind of in Virahol, ethanol, lauryl alcohol, terepthaloyl moietie, the USP Kosher according to equivalent weight per-cent, perhaps replace with the mixture of propyl carbinol and Virahol, ethanol, lauryl alcohol, terepthaloyl moietie and USP Kosher according to equivalent weight per-cent; All qualified ferrous metal part is used aqueous cleaning agent, the character of products obtained therefrom does not have significant difference;
In the present embodiment, said tinting material is a phthalocyanine, in the present embodiment, replaces with indigo according to equivalent weight per-cent phthalocyanine; Perhaps replace with phthalocyanine and indigo mixture according to equivalent weight per-cent, all qualified ferrous metal part is used aqueous cleaning agent, the character of products obtained therefrom does not have significant difference;
The ferrous metal part of present embodiment is used aqueous cleaning agent, the heating during use when cleaning, scrub, spray, modes such as vibration or UW make greasy dirt break away from workpiece surface as early as possible, thereby are distributed in the scavenging solution; Nonflammable; To operator's toxicological harmless, have Safety and Environmental Protection preferably, the metallic surface there is not the burn into not damaged; The cleaning of ferrous metal piece surface, light and no color differnece, rust-proof life was above 10 days.
Embodiment four
The ferrous metal part of present embodiment is used aqueous cleaning agent; Clean-out system comprises following component by weight percentage: 6% alcohol ether carboxylate, 6% polycarboxylate, 20% pure ether surface active agent, 10% oleylamide, 2.5% diethylolamine, 2.5% trolamine, 0.1% benzotriazole, and 0.5% benzoate, 0.5% edetate, 6% alcohols, 0.01% tinting material, all the other add to 100% for deionized water;
In the present embodiment; Said polycarboxylate is a Trisodium Citrate; In the present embodiment, hexanodioic acid is replaced with a kind of in sebacic acid, undecandioic acid, IRGACOR L190, hexanodioic acid, Sunmorl N 60S, hydroxy acid sodium, the dimeracid potassium according to equivalent weight per-cent; Perhaps replace with the mixture of Trisodium Citrate and sebacic acid, undecandioic acid, IRGACOR L190, hexanodioic acid, Sunmorl N 60S, hydroxy acid sodium and dimeracid potassium according to equivalent weight per-cent; All qualified ferrous metal part is used aqueous cleaning agent, the character of products obtained therefrom does not have significant difference;
In the present embodiment; Said pure ether surface active agent is the polyoxyethylene sorbitan monoleate; In the present embodiment, AEO is replaced with a kind of in TX10, sorbitol monooleate, AEO, NP ether phosphoric acid methyl esters ethanolamine salt, oleic acid glycol ester, dodecyl polyethenoxy ether sodium sulfate, the polyoxyethylene glycol according to equivalent weight per-cent; Perhaps replace with the mixture of sorbitol monooleate and TX10, AEO, polyoxyethylene sorbitan monoleate, NP ether phosphoric acid methyl esters ethanolamine salt, oleic acid glycol ester, dodecyl polyethenoxy ether sodium sulfate and polyoxyethylene glycol according to equivalent weight per-cent; All qualified ferrous metal part is used aqueous cleaning agent, the character of products obtained therefrom does not have significant difference;
In the present embodiment; Said oleylamide is the boronation oleylamide; In the present embodiment; Triethanolamine oleate is replaced with a kind of of oleoyl sarcosine stearylamine, coconut oil terepthaloyl moietie acid amides, triethanolamine oleate, oleic acid terepthaloyl moietie acid amides according to equivalent weight per-cent; Perhaps replace with the mixture of boronation oleylamide and oleoyl sarcosine stearylamine, coconut oil terepthaloyl moietie acid amides, triethanolamine oleate and oleic acid terepthaloyl moietie acid amides according to equivalent weight per-cent, all qualified ferrous metal part is used aqueous cleaning agent, the character of products obtained therefrom does not have significant difference;
In the present embodiment; Said alcohols is a lauryl alcohol; In the present embodiment, ethanol is replaced with a kind of in Virahol, propyl carbinol, ethanol, terepthaloyl moietie, the USP Kosher according to equivalent weight per-cent, perhaps replace with the mixture of lauryl alcohol and Virahol, propyl carbinol, ethanol, terepthaloyl moietie and USP Kosher according to equivalent weight per-cent; All qualified ferrous metal part is used aqueous cleaning agent, the character of products obtained therefrom does not have significant difference;
In the present embodiment, said tinting material is a phthalocyanine, in the present embodiment, replaces with indigo according to equivalent weight per-cent phthalocyanine; Perhaps replace with phthalocyanine and indigo mixture according to equivalent weight per-cent, all qualified ferrous metal part is used aqueous cleaning agent, the character of products obtained therefrom does not have significant difference;
The ferrous metal part of present embodiment is used aqueous cleaning agent, the heating during use when cleaning, scrub, spray, modes such as vibration or UW make greasy dirt break away from workpiece surface as early as possible, thereby are distributed in the scavenging solution; Nonflammable; To operator's toxicological harmless, have Safety and Environmental Protection preferably, the metallic surface there is not the burn into not damaged; The cleaning of ferrous metal piece surface, light and no color differnece, rust-proof life reaches 15 days.
Embodiment five
The clean-out system of present embodiment comprises following component by weight percentage: 10% alcohol ether carboxylate, 6% polycarboxylate, 20% pure ether surface active agent, 7.5% oleylamide, 2.5% diethylolamine, 2.5% trolamine, 0.1% benzotriazole, and 0.5% benzoate, 0.5% edetate, 10% alcohols, 0.01% tinting material, all the other add to 100% for deionized water;
In the present embodiment; Said polycarboxylate is a Sunmorl N 60S; In the present embodiment, hexanodioic acid is replaced with a kind of in sebacic acid, undecandioic acid, IRGACOR L190, Trisodium Citrate, hexanodioic acid, hydroxy acid sodium, the dimeracid potassium according to equivalent weight per-cent; Perhaps replace with the mixture of Sunmorl N 60S and sebacic acid, undecandioic acid, IRGACOR L190, Trisodium Citrate, hexanodioic acid, hydroxy acid sodium and dimeracid potassium according to equivalent weight per-cent; All qualified ferrous metal part is used aqueous cleaning agent, the character of products obtained therefrom does not have significant difference;
In the present embodiment; Said pure ether surface active agent is a NP ether phosphoric acid methyl esters ethanolamine salt; In the present embodiment, AEO is replaced with a kind of in TX10, sorbitol monooleate, polyoxyethylene sorbitan monoleate, AEO, oleic acid glycol ester, dodecyl polyethenoxy ether sodium sulfate, the polyoxyethylene glycol according to equivalent weight per-cent; Perhaps replace with the mixture of NP ether phosphoric acid methyl esters ethanolamine salt and TX10, sorbitol monooleate, polyoxyethylene sorbitan monoleate, AEO, oleic acid glycol ester, dodecyl polyethenoxy ether sodium sulfate and polyoxyethylene glycol according to equivalent weight per-cent; All qualified ferrous metal part is used aqueous cleaning agent, the character of products obtained therefrom does not have significant difference;
In the present embodiment; Said oleylamide is an oleic acid terepthaloyl moietie acid amides; In the present embodiment; Triethanolamine oleate is replaced with a kind of of oleoyl sarcosine stearylamine, coconut oil terepthaloyl moietie acid amides, boronation oleylamide, triethanolamine oleate according to equivalent weight per-cent; Perhaps replace with the mixture of oleic acid terepthaloyl moietie acid amides and oleoyl sarcosine stearylamine, coconut oil terepthaloyl moietie acid amides, boronation oleylamide and triethanolamine oleate according to equivalent weight per-cent, all qualified ferrous metal part is used aqueous cleaning agent, the character of products obtained therefrom does not have significant difference;
In the present embodiment; Said alcohols is a USP Kosher; In the present embodiment, ethanol is replaced with a kind of in Virahol, propyl carbinol, lauryl alcohol, terepthaloyl moietie and the ethanol according to equivalent weight per-cent, perhaps replace with USP Kosher and Virahol, propyl carbinol, lauryl alcohol, terepthaloyl moietie and alcoholic acid mixture according to equivalent weight per-cent; All qualified ferrous metal part is used aqueous cleaning agent, the character of products obtained therefrom does not have significant difference;
In the present embodiment, said tinting material is a phthalocyanine, in the present embodiment, replaces with indigo according to equivalent weight per-cent phthalocyanine; Perhaps replace with phthalocyanine and indigo mixture according to equivalent weight per-cent, all qualified ferrous metal part is used aqueous cleaning agent, the character of products obtained therefrom does not have significant difference;
The ferrous metal part of present embodiment is used aqueous cleaning agent, the heating during use when cleaning, scrub, spray, modes such as vibration or UW make greasy dirt break away from workpiece surface as early as possible, thereby are distributed in the scavenging solution; Nonflammable; To operator's toxicological harmless, have Safety and Environmental Protection preferably, the metallic surface there is not the burn into not damaged; The cleaning of ferrous metal piece surface, light and no color differnece, rust-proof life surpasses more than 10 days.
In the foregoing description, more than composition replacement back in the various components to clean-out system character did not influence, thereby can both realize goal of the invention.
This shows, the object of the present invention is to provide a kind of ferrous metal part to use aqueous cleaning agent, is main promoting agent with polycarboxylate, pure ether surface active agent; With oleylamide, benzotriazole is the lubrication protection synergistic agent, and benzoate, edetate etc. is a washing assistant, and alcohols and deionized water are solvent; The water base cleaning of weakly alkaline has the strong osmotic ability, and porous is to cleaning the thing bottom; Can dissolve rapidly and remove various dirts and the impurity that is attached to the metallic surface, not have depositional phenomenon again during cleaning, cleaning process does not have the burn into not damaged to the metallic surface; Cleaning speed is fast, and it is clean, bright to clean the metallic surface, back, and the metallic surface quality is good; Can effectively ensure the working accuracy of ferrous metal, not have inflammable and explosive characteristic during use, SF is high; Can not cause bigger detrimentally affect to Working environment yet, not contain harm such as nitrite, phenol, formaldehyde surrounding material, the heating during use when cleaning, scrub, spray, modes such as vibration or UW make greasy dirt break away from workpiece surface as early as possible; Thereby be distributed in the scavenging solution,, have Safety and Environmental Protection preferably operator's toxicological harmless; Liquid waste disposal is easy, and the cleaning cost is low and economic benefit is high; Simultaneously can effectively improve processing environment and workshop hygiene situation, be beneficial to and increase work efficiency; This clean-out system has the effect of short-term rust protection to the ferrous metal component that cleaned, and rust-proof life was above 10 days.
And for above technique effect, the proportioning of embodiment one and processing parameter, result of use is best, obviously is superior to other embodiment, is the best.
Explanation is at last; Above embodiment is only unrestricted in order to technical scheme of the present invention to be described; Although with reference to preferred embodiment the present invention is specified, those of ordinary skill in the art should be appreciated that and can make amendment or be equal to replacement technical scheme of the present invention; And not breaking away from the aim and the scope of technical scheme of the present invention, it all should be encompassed in the middle of the claim scope of the present invention.
Claims (7)
1. a ferrous metal part is used aqueous cleaning agent; It is characterized in that: clean-out system comprises following component by weight percentage: 2-10% alcohol ether carboxylate, 2-10% polycarboxylate, 5-20% alcohol ether surface active agent, 5-10% oleylamide, 1-2.5% diethylolamine, 1-2.5% trolamine, 0.1-2% benzotriazole, 0.5-2% benzoate, 0.5-2% edetate, 2-10% alcohols, 0.001-0.01% tinting material, all the other add to 100% for deionized water.
2. ferrous metal part according to claim 1 is used aqueous cleaning agent; It is characterized in that: clean-out system comprises following component by weight percentage: 6% alcohol ether carboxylate, 6% polycarboxylate, 12% pure ether surface active agent, 7.5% oleylamide, 1.75% diethylolamine, 1.75% trolamine, 1% benzotriazole, 1.2% benzoate, 1.2% edetate, 6% alcohols, 0.005% tinting material, all the other add to 100% for deionized water.
3. ferrous metal part according to claim 2 is used aqueous cleaning agent, it is characterized in that: said polycarboxylate is one or more the mixture in hexanodioic acid, sebacic acid, undecandioic acid, IRGACORL190, Trisodium Citrate, Sunmorl N 60S, hydroxy acid sodium, the dimeracid potassium.
4. ferrous metal part according to claim 3 is used aqueous cleaning agent, it is characterized in that: said pure ether surface active agent is one or more the mixture in AEO, TX10, sorbitol monooleate, polyoxyethylene sorbitan monoleate, NP ether phosphoric acid methyl esters ethanolamine salt, oleic acid glycol ester, dodecyl polyethenoxy ether sodium sulfate, the polyoxyethylene glycol.
5. ferrous metal part according to claim 4 is used aqueous cleaning agent, it is characterized in that: oleylamide is one or more the mixture in triethanolamine oleate, oleoyl sarcosine stearylamine, coconut oil terepthaloyl moietie acid amides, boronation oleylamide, the oleic acid terepthaloyl moietie acid amides.
6. ferrous metal part according to claim 5 is used aqueous cleaning agent, it is characterized in that: alcohols is one or more the mixture in ethanol, Virahol, propyl carbinol, lauryl alcohol, terepthaloyl moietie, the USP Kosher.
7. ferrous metal part according to claim 6 is used aqueous cleaning agent, it is characterized in that: said tinting material is phthalocyanine, one or more the mixture in indigo.
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| CN201210243535.2A CN102766880B (en) | 2012-07-13 | 2012-07-13 | Water-based washing agent for black metal parts |
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| CN107268004A (en) * | 2017-08-01 | 2017-10-20 | 屏南县康迈精选科技有限公司 | A kind of water base metal cleaning agent and preparation method thereof |
| CN112708511A (en) * | 2020-12-25 | 2021-04-27 | 无锡优洁科技有限公司 | Aircraft cleaning agent and production method thereof |
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Inventor after: Yang Jun Inventor after: Wang Xiaolong Inventor after: Yuan Qinghe Inventor after: Zhang Kuitao Inventor before: Yang Jun Inventor before: Wang Xiaolong Inventor before: Yuan Qinghe Inventor before: Zhang Kuitao |
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Address after: Guangdong Province, Dongguan City Industrial Road 523808 Songshan Lake Science and Technology Industrial Park No. 6 Patentee after: AMER LUBRICANT TECHNOLOGY CO., LTD. Address before: 523808 Guangdong province Dongguan City Songshan Lake Science and Technology Industrial Park Road No. 6 Patentee before: Dongguan Amer Lubricant Technology Co., Ltd. |