CN108411645A - A kind of polyimide fiber black-dyeing method - Google Patents
A kind of polyimide fiber black-dyeing method Download PDFInfo
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- CN108411645A CN108411645A CN201810218847.5A CN201810218847A CN108411645A CN 108411645 A CN108411645 A CN 108411645A CN 201810218847 A CN201810218847 A CN 201810218847A CN 108411645 A CN108411645 A CN 108411645A
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- fabric
- dyeing
- polyimide fiber
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- dye
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- D—TEXTILES; PAPER
- D06—TREATMENT OF TEXTILES OR THE LIKE; LAUNDERING; FLEXIBLE MATERIALS NOT OTHERWISE PROVIDED FOR
- D06P—DYEING OR PRINTING TEXTILES; DYEING LEATHER, FURS OR SOLID MACROMOLECULAR SUBSTANCES IN ANY FORM
- D06P1/00—General processes of dyeing or printing textiles, or general processes of dyeing leather, furs, or solid macromolecular substances in any form, classified according to the dyes, pigments, or auxiliary substances employed
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- D—TEXTILES; PAPER
- D06—TREATMENT OF TEXTILES OR THE LIKE; LAUNDERING; FLEXIBLE MATERIALS NOT OTHERWISE PROVIDED FOR
- D06P—DYEING OR PRINTING TEXTILES; DYEING LEATHER, FURS OR SOLID MACROMOLECULAR SUBSTANCES IN ANY FORM
- D06P1/00—General processes of dyeing or printing textiles, or general processes of dyeing leather, furs, or solid macromolecular substances in any form, classified according to the dyes, pigments, or auxiliary substances employed
- D06P1/0032—Determining dye recipes and dyeing parameters; Colour matching or monitoring
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Abstract
The invention discloses a kind of polyimide fiber black-dyeing methods, belong to textile dyeing and finishing manufacture field.The present invention uses following technique：(1) polyimide fiber fabric pretreatment with get rid of throwing, weaving and storage during fabric adhere to impurity；(2) dyeing assigns fabric certain tinctorial yield；(3) dyed fabric is washed, soap boiling, washing to be to remove dyeing loose colour.(4) high temperature bakes the miscellaneous taste of removable fabric after dyeing.In the present invention, polyimides fabric is dyed under the high temperature conditions using the dye of positive ion, under conditions of adding organic and inorganic assistant, fabric obtains black, and fabric has certain washing color fastness after dyeing.
Description
Technical field
The present invention relates to a kind of polyimide fiber black-dyeing methods, belong to textile dyeing and finishing manufacture field.
Background technology
Polyimides (Polyimide, PI) is a kind of high performance material containing imide ring, has excellent thermostabilization
Property, limit oxygen index has the characteristic that do not melt up to 38% or more, is put out from fire；The glass transition temperature of fiber 300 DEG C with
On, heat decomposition temperature is up to 600 DEG C.Except first, polyimide fiber also has preferable mechanical performance, the polyamides of equal benzene-type
The tensile strength of imine fiber is up to 170MPa, stretch modulus 3.0GPa；Polyimides does not dissolve in common organic solvents, to oxygen
Agent, the stability of reducing agent are high, but intolerant to basic hydrolysis, chemical stability is good.Therefore polyimides can be widely applied to navigate
Sky, space flight, automobile, microelectronics, the various special dimensions such as medical instrument.It is wide that various excellent performances assign polyimide fiber
Application prospect.
Polyimide fiber glass transition temperature is higher, and chemical-resistant reagent has good stability, and causes dyeing and the colorant match of fiber
It is very difficult.At present original liquid coloring method is mostly used in the polyimide of commercialization, but the original liquid coloring method product of fiber
Cost is higher, production is more difficult.In addition to this, the not alkali resistance that can utilize polyimides carries out fiber using alkaline agent
Processing, the content for increasing fiber polarity group achieve the purpose that dyeing to make the effect between dyestuff and fiber enhance.
For polyimide fiber itself in golden yellow, general coloring covers its golden yellow, the color after dyeing completely
It is in the Overlay of yellow and dye colour more, therefore also needs to the golden yellow by itself in terms of polyimides dyeing as three
Primary colors carries out colorant match using other dyestuffs.Additionally as textile, black is most common and most important color, as high property
Energy fiber is mainly used for commercial application just with greater need for black, and there has been no in terms of polyimides colorant match and dye black at present
Document report.
Invention content
The present invention provides a kind of polyimide fiber black-dyeing method, using the golden yellow of polyimides itself as three originals
Yellow in color recycles the red of various concentration and blue dyes to carry out colorant match.Dye of positive ion work is used in the present invention
Polyimides fabric is dyed under the high temperature conditions for formulation techniques, with the help of organic and inorganic assistant, fabric has
Deeper tinctorial yield.Compared to not adding organic additive and being added to other kinds of organic additive, using with acetophenone structure
Organic additive can preferably help on the dye of positive ion dye to obtain the fabric of black, and after dyeing fabric have it is certain preferably
Washing color fastness.
The cationic dyeing method of the polyimide fiber includes the following steps：
Step 1, the impurity of removal polyimide fiber surface attachment, dries；
Step 2, polyimides fabric after drying are added to containing the dye of positive ion, organic additive, inorganic assistant
In dye liquor, dyed；
Step 3, by polyimide fiber washing, soap boiling, washing to remove dyeing loose colour after the completion of dyeing；
Polyimides fabric after the completion of dyeing is baked removal carrier by step 4 at high temperature.
In one embodiment of the invention, the solution containing surfactant is added in step 1, polyimide fiber
In, bath raio 20-30:1,30-60min, naturally dry after taking-up are handled at 85-95 DEG C.A concentration of 2- of surfactant
3g/L.The surfactant can be nonionic surfactant, such as AEO-7.
In one embodiment of the invention, step 2, by the polyimide fiber after drying be added to containing sun from
In the dye liquor of sub- dyestuff, organic additive and inorganic assistant, heating rate is 1.5-3 DEG C/min, and dyeing temperature is 120-130 DEG C,
Keep the temperature 40-120min.The bath raio of dye liquor and fabric is 15:1-30:1；The dye of positive ion is to fabric weight (owf)
For 12.5-15%；The organic additive a concentration of 80-120g/L, inorganic assistant 40-60g/L.
In one embodiment of the invention, step 2, the dye of positive ion of addition be Cationic Red X-GRL, sun from
Sub- indigo plant X-GRRL；The organic additive of addition is the organic matter of acetophenone structure；The inorganic assistant of addition be sodium nitrate, sodium sulphate,
The inorganic salts such as sodium chloride.
In one embodiment of the invention, shown in the general structure of organic additive such as formula (1)：
In formula (1), R1For hydrogen, alkyl, aryl, alkoxy, R2、R3、R4、R5、R6For hydrogen, alkyl, aryl, alkoxy or hydroxyl
Base.
In one embodiment of the invention, step 3 is added to after washing polyimide fiber after the completion of dyeing
In solution containing 2-3g/L soaping agents, bath raio 10:1-30:1, it is fully washed after handling 30-60min at 85-95 DEG C.It is described
Soaping agent can be nonionic surfactant, such as AEO-7.
In one embodiment of the invention, step 4, baking temperature are 150-200 DEG C, and it is 1-5min to bake the time.
Using the colouring method of the present invention, the deeper black polyamide fabric of color can be obtained, and the dye after obtaining
Yarn dyed fabric color fastness to washing is preferable.
Specific implementation mode
Embodiment 1
2g polyimides fabrics are taken, are put into the solution containing nonionic surfactant AEO-7 (2g/L), bath raio is
30:1,60min, naturally dry are handled at 85 DEG C.
Cationic Red X-GRL (2%owf) and cationic blue x-grrl (13%owf) are added to containing acetophenone
In (100g/L) and sodium nitrate (60g/L) dye liquor, wherein the bath raio of dye liquor and fabric is 15:1, with the speed liter of 1.5 DEG C/min
Temperature keeps the temperature 120min to 120 DEG C.
After the completion of dyeing, fabric is put into the liquid of soaping containing AEO-7 (2g/L), bath raio 20:1, it is right at 85 DEG C
It is fully washed after fabric treating 60min, fabric naturally dry.
It is taken out after fabric after drying is baked 5min at 150 DEG C.The color parameter and washing fastness of sample after dyeing
As shown in table 1.
Embodiment 2
2g polyimides fabrics are taken, are put into the solution containing nonionic surfactant AEO-7 (3g/L), bath raio is
30:1,30min, naturally dry are handled at 95 DEG C.
Cationic Red X-GRL (2.5%owf) and cationic blue x-grrl (11%owf) are added to containing acetophenone
In (120g/L) and sodium nitrate (50g/L) dye liquor, wherein the bath raio of dye liquor and fabric is 20:1, it is heated up with the speed of 3 DEG C/min
To 130 DEG C of heat preservation 60min.
After the completion of dyeing, fabric is put into the liquid of soaping containing AEO-7 (2g/L), bath raio 30:1, it is right at 85 DEG C
It is fully washed after fabric treating 45min, fabric naturally dry.
It is taken out after fabric after drying is baked 1min at 200 DEG C.The color parameter of sample and washing fastness be such as after dyeing
Shown in table 1.
Embodiment 3
2g polyimides fabrics are taken, are put into the solution containing nonionic surfactant AEO-7 (3g/L), bath raio is
20:1,30min, naturally dry are handled at 95 DEG C.
Cationic Red X-GRL (2.5%owf) and cationic blue x-grrl (10%owf) are added to containing acetophenone
In (60g/L) and propiophenone (40g/L) and sodium sulphate (40g/L) dye liquor, wherein the bath raio of dye liquor and fabric is 30:1, with 3 DEG C/
The speed of min is warming up to 130 DEG C of heat preservation 90min.
After the completion of dyeing, fabric is put into the liquid of soaping containing AEO-7 (3g/L), bath raio 30:1, it is right at 95 DEG C
It is fully washed after fabric treating 30min, fabric naturally dry.
It is taken out after fabric after drying is baked 2min at 190 DEG C.The color parameter of sample and washing fastness be such as after dyeing
Shown in table 1.
Embodiment 4
2g polyimides fabrics are taken, are put into the solution containing nonionic surfactant AEO-7 (2g/L), bath raio is
10:1,40min, naturally dry are handled at 85 DEG C.
Cationic Red X-GRL (2%owf) and cationic blue x-grrl (11%owf) are added to containing to methylbenzene second
In ketone (80g/L) and sodium chloride (40g/L) dye liquor, wherein the bath raio of dye liquor and fabric is 10:1, it is heated up with the speed of 2 DEG C/min
To 130 DEG C of heat preservation 40min.
After the completion of dyeing, fabric is put into the liquid of soaping containing AEO-7 (2g/L), bath raio 10:1, it is right at 95 DEG C
It is fully washed after fabric treating 30min, fabric naturally dry.
It is taken out after fabric after drying is baked 3min at 180 DEG C.The color parameter of sample and washing fastness be such as after dyeing
Shown in table 1.
Comparative example 1 does not add organic additive, inorganic assistant
2g polyimides fabrics are taken, are put into the solution containing nonionic surfactant AEO-7 (3g/L), bath raio is
30:1,30min, naturally dry are handled at 95 DEG C.
Cationic Red X-GRL (2.5%owf) and cationic blue x-grrl (11%owf) are added in dye liquor, wherein contaminating
The bath raio of liquid and fabric is 20:1,130 DEG C of heat preservation 60min are warming up to the speed of 3 DEG C/min.
After the completion of dyeing, fabric is put into the liquid of soaping containing AEO-7 (2g/L), bath raio 30:1, it is right at 85 DEG C
It is fully washed after fabric treating 45min, fabric naturally dry.
It is taken out after fabric after drying is baked 1min at 200 DEG C.The color parameter of sample and washing fastness be such as after dyeing
Shown in table 1.
Comparative example 2 replaces acetophenone as organic additive using benzyl alcohol
2g polyimides fabrics are taken, are put into the solution containing nonionic surfactant AEO-7 (3g/L), bath raio is
30:1,30min, naturally dry are handled at 95 DEG C.
Cationic Red X-GRL (2.5%owf) and cationic blue x-grrl (11%owf) are added to containing benzyl alcohol
In (120g/L) and sodium nitrate (50g/L) dye liquor, wherein the bath raio of dye liquor and fabric is 20:1, it is heated up with the speed of 3 DEG C/min
To 130 DEG C of heat preservation 60min.
After the completion of dyeing, fabric is put into the liquid of soaping containing AEO-7 (2g/L), bath raio 30:1, it is right at 85 DEG C
It is fully washed after fabric treating 45min, fabric naturally dry.
Fabric after drying is baked at 200 DEG C take out after 1min, the color parameter of sample and washing fastness be such as after dyeing
Shown in table 1.
CIE Lab, K/S after 1 polyimides textile dyeing of tableSUMAnd washing fastness series
Note：K/SSUMIt is worth for fabric in 360-700nm, the K/S corresponding to 10nm wavelength is worth summation.Discoloration jail
Degree, staining fastness are measured according to textile color stability testing standard GB/T 3921-2008；Fracture strength is yarn strength.
From table 1 it follows that the CIE L values of fabric are remarkably decreased after dyeing, illustrate darkening for fabric.
After colouring method by black polyamide fabric, the CIE a values and CIE b values of fabric illustrate that fabric is in all close to 0
Existing black, the fabric of especially embodiment 2 has been black fabric.From fabric after the dyeing of comparative example 1, comparative example 2 and embodiment 2
Color parameter compare as can be seen that under conditions of not adding auxiliary agent, be unable to get depth using the red and blue of same concentrations
The brightness value of color, fabric is higher, illustrates that the color of fabric is shallower, and when addition benzyl alcohol is as carrier, the color of fabric slightly becomes
It is deep, but its CIE a value and CIE b values be close to 0, also and non-black.
Although the present invention has been described by way of example and in terms of the preferred embodiments, it is not limited to the present invention, any to be familiar with this skill
The people of art can do various change and modification, therefore the protection model of the present invention without departing from the spirit and scope of the present invention
Enclosing be subject to what claims were defined.
Claims (10)
1. a kind of polyimide fiber black-dyeing method, which is characterized in that using the golden yellow of polyimides itself as three originals
Yellow in color under the high temperature conditions dyes polyimides fabric using the dye of positive ion as formulation techniques, is having
With the help of machine aided agent and inorganic assistant, black polyamide fiber is obtained；The organic additive is with acetophenone structure
Organic matter.
2. a kind of polyimide fiber black-dyeing method according to claim 1, which is characterized in that including walking as follows
Suddenly：
Step 1, the impurity of removal polyimide fiber surface attachment, dries；
Step 2, the polyimides fabric after drying are added to the dye liquor containing the dye of positive ion, organic additive, inorganic assistant
In, it is dyed；
Step 3, by polyimide fiber washing, soap boiling, washing to remove dyeing loose colour after the completion of dyeing；
Polyimides fabric after the completion of dyeing is baked removal carrier by step 4 at high temperature.
3. a kind of polyimide fiber black-dyeing method according to claim 2, which is characterized in that step 1, polyamides
Imine fiber is added in the solution containing surfactant, bath raio 20-30:1,30-60min is handled at 85-95 DEG C, is taken out
Naturally dry afterwards.
4. a kind of polyimide fiber black-dyeing method according to claim 3, which is characterized in that surfactant
A concentration of 2-3g/L, the surfactant can be the nonionic surfactants including AEO-7.
5. a kind of polyimide fiber black-dyeing method according to claim 2 or 3, which is characterized in that step 2, it will
Polyimide fiber after drying is added in the dye liquor containing the dye of positive ion, organic additive and inorganic assistant, heating rate
For 1.5-3 DEG C/min, dyeing temperature is 120-130 DEG C, keeps the temperature 40-120min.
6. a kind of polyimide fiber black-dyeing method according to claim 5, which is characterized in that dye liquor is knitted with fiber
The bath raio of object is 15:1-30:1；The dye of positive ion is 12.5-15% to fabric weight (owf).
7. a kind of polyimide fiber black-dyeing method according to claim 5 or 6, which is characterized in that described has
Machine aided agent concentration is 80-120g/L, inorganic assistant 40-60g/L.
8. a kind of polyimide fiber black-dyeing method according to claim 5 or 6 or 7, which is characterized in that cation
Dyestuff is Cationic Red X-GRL, cationic blue x-grrl；Organic additive is the organic matter of acetophenone structure；Inorganic assistant is nitre
The inorganic salts such as sour sodium, sodium sulphate, sodium chloride.
9. the black polyamide fiber being prepared according to any the method for claim 1~8.
10. black polyamide described in claim 9 is in the application in the fields such as Aeronautics and Astronautics, automobile, microelectronics, medical instrument.
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| CN201810218847.5A CN108411645A (en) | 2018-03-16 | 2018-03-16 | A kind of polyimide fiber black-dyeing method |
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Cited By (3)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN109235073A (en) * | 2018-09-29 | 2019-01-18 | 青岛亿天环保科技有限公司 | A kind of cationic dyeing method of polyimide fiber |
| CN109898347A (en) * | 2019-02-28 | 2019-06-18 | 江苏工程职业技术学院 | A kind of colouring method of polyimides staple in bulk |
| CN109898346A (en) * | 2019-02-28 | 2019-06-18 | 江苏工程职业技术学院 | A kind of colouring method of polyimides yarn |
Citations (1)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN107447553A (en) * | 2017-08-15 | 2017-12-08 | 江南大学 | A kind of ketone ester class carrier dyeing method of polyimide fiber and fabric |
-
2018
- 2018-03-16 CN CN201810218847.5A patent/CN108411645A/en active Pending
Patent Citations (1)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN107447553A (en) * | 2017-08-15 | 2017-12-08 | 江南大学 | A kind of ketone ester class carrier dyeing method of polyimide fiber and fabric |
Non-Patent Citations (1)
| Title |
|---|
| 杨秀稳等: "《染色打样实训 （第2版）》", 30 June 2015, 中国纺织出版社 * |
Cited By (3)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN109235073A (en) * | 2018-09-29 | 2019-01-18 | 青岛亿天环保科技有限公司 | A kind of cationic dyeing method of polyimide fiber |
| CN109898347A (en) * | 2019-02-28 | 2019-06-18 | 江苏工程职业技术学院 | A kind of colouring method of polyimides staple in bulk |
| CN109898346A (en) * | 2019-02-28 | 2019-06-18 | 江苏工程职业技术学院 | A kind of colouring method of polyimides yarn |
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Application publication date: 20180817 |