CN107059442A - Utilize the method for gardenia blue pigment dyeing cotton fabric - Google Patents

Utilize the method for gardenia blue pigment dyeing cotton fabric Download PDF

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Publication number
CN107059442A
CN107059442A CN201710474491.7A CN201710474491A CN107059442A CN 107059442 A CN107059442 A CN 107059442A CN 201710474491 A CN201710474491 A CN 201710474491A CN 107059442 A CN107059442 A CN 107059442A
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Prior art keywords
dyeing
blue pigment
matchmaker
mordant
gardenia blue
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CN201710474491.7A
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宋慧君
王明
高玉梅
张宁
刘丽娇
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Henan Institute of Engineering
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Henan Institute of Engineering
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Priority to CN201710474491.7A priority Critical patent/CN107059442A/en
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    • DTEXTILES; PAPER
    • D06TREATMENT OF TEXTILES OR THE LIKE; LAUNDERING; FLEXIBLE MATERIALS NOT OTHERWISE PROVIDED FOR
    • D06PDYEING OR PRINTING TEXTILES; DYEING LEATHER, FURS OR SOLID MACROMOLECULAR SUBSTANCES IN ANY FORM
    • D06P3/00Special processes of dyeing or printing textiles, or dyeing leather, furs, or solid macromolecular substances in any form, classified according to the material treated
    • D06P3/58Material containing hydroxyl groups
    • D06P3/60Natural or regenerated cellulose
    • D06P3/64Natural or regenerated cellulose using mordant dyes or metallisable dyes
    • DTEXTILES; PAPER
    • D06TREATMENT OF TEXTILES OR THE LIKE; LAUNDERING; FLEXIBLE MATERIALS NOT OTHERWISE PROVIDED FOR
    • D06PDYEING OR PRINTING TEXTILES; DYEING LEATHER, FURS OR SOLID MACROMOLECULAR SUBSTANCES IN ANY FORM
    • D06P1/00General processes of dyeing or printing textiles, or general processes of dyeing leather, furs, or solid macromolecular substances in any form, classified according to the dyes, pigments, or auxiliary substances employed
    • D06P1/34General processes of dyeing or printing textiles, or general processes of dyeing leather, furs, or solid macromolecular substances in any form, classified according to the dyes, pigments, or auxiliary substances employed using natural dyestuffs
    • DTEXTILES; PAPER
    • D06TREATMENT OF TEXTILES OR THE LIKE; LAUNDERING; FLEXIBLE MATERIALS NOT OTHERWISE PROVIDED FOR
    • D06PDYEING OR PRINTING TEXTILES; DYEING LEATHER, FURS OR SOLID MACROMOLECULAR SUBSTANCES IN ANY FORM
    • D06P1/00General processes of dyeing or printing textiles, or general processes of dyeing leather, furs, or solid macromolecular substances in any form, classified according to the dyes, pigments, or auxiliary substances employed
    • D06P1/44General processes of dyeing or printing textiles, or general processes of dyeing leather, furs, or solid macromolecular substances in any form, classified according to the dyes, pigments, or auxiliary substances employed using insoluble pigments or auxiliary substances, e.g. binders
    • D06P1/445Use of auxiliary substances before, during or after dyeing or printing
    • DTEXTILES; PAPER
    • D06TREATMENT OF TEXTILES OR THE LIKE; LAUNDERING; FLEXIBLE MATERIALS NOT OTHERWISE PROVIDED FOR
    • D06PDYEING OR PRINTING TEXTILES; DYEING LEATHER, FURS OR SOLID MACROMOLECULAR SUBSTANCES IN ANY FORM
    • D06P1/00General processes of dyeing or printing textiles, or general processes of dyeing leather, furs, or solid macromolecular substances in any form, classified according to the dyes, pigments, or auxiliary substances employed
    • D06P1/44General processes of dyeing or printing textiles, or general processes of dyeing leather, furs, or solid macromolecular substances in any form, classified according to the dyes, pigments, or auxiliary substances employed using insoluble pigments or auxiliary substances, e.g. binders
    • D06P1/673Inorganic compounds
    • D06P1/67333Salts or hydroxides
    • D06P1/6735Salts or hydroxides of alkaline or alkaline-earth metals with anions different from those provided for in D06P1/67341
    • DTEXTILES; PAPER
    • D06TREATMENT OF TEXTILES OR THE LIKE; LAUNDERING; FLEXIBLE MATERIALS NOT OTHERWISE PROVIDED FOR
    • D06PDYEING OR PRINTING TEXTILES; DYEING LEATHER, FURS OR SOLID MACROMOLECULAR SUBSTANCES IN ANY FORM
    • D06P1/00General processes of dyeing or printing textiles, or general processes of dyeing leather, furs, or solid macromolecular substances in any form, classified according to the dyes, pigments, or auxiliary substances employed
    • D06P1/44General processes of dyeing or printing textiles, or general processes of dyeing leather, furs, or solid macromolecular substances in any form, classified according to the dyes, pigments, or auxiliary substances employed using insoluble pigments or auxiliary substances, e.g. binders
    • D06P1/673Inorganic compounds
    • D06P1/67333Salts or hydroxides
    • D06P1/6735Salts or hydroxides of alkaline or alkaline-earth metals with anions different from those provided for in D06P1/67341
    • D06P1/67358Halides or oxyhalides

Abstract

The invention discloses a kind of method of utilization gardenia blue pigment dyeing cotton fabric, using following colouring method:Matchmaker's processing post processing is dyed to bafta after pre- matchmaker's processing dyeing.In pre- matchmaker's treatment fluid, mordant consumption is 1% ~ 6% (owf), and gardenia blue pigment consumption is 2% ~ 5% (owf) in dye liquor, and during anhydrous sodium sulfate consumption is 20 ~ 40g/L, rear matchmaker's treatment fluid, mordant consumption is 1% ~ 6% (owf).Gardenia blue pigment dyeing cotton fabric meets people to environmental protection and healthy requirement using the mordant of environment-friendly type; mordant dyeing processing can reduce gardenia blue pigment before dyeing and the repulsion of cotton fiber is acted on; improve dye uptake; the color fastness of dyed fabric can be improved after dyeing through mordant dyeing processing again; mordant is made from zinc sulfate, lanthanum chloride, cerium chloride, aluminum sulfate; bright-coloured blue bafta is can obtain, wherein, zinc sulfate does mordant dyed fabric vividness highest.

Description

Utilize the method for gardenia blue pigment dyeing cotton fabric
Technical field
The invention belongs to the dyeing and finishing technique field of fabric, and in particular to a kind of side of utilization gardenia blue pigment dyeing cotton fabric Method.
Background technology
With gradually stepping up for people's life up-to-dateness, protect the common living environment of the mankind, realize sustainable development Exhibition is increasingly becoming the Main way of countries in the world economic development, and dress of the people to textile and TEXTILE CHEMICALS uses safety Increasingly pay attention to health, natural pigment has attracted the eyeball of correlative study person with its again the characteristics of richly endowed by nature.
In recent years, both at home and abroad many researchers to natural pigment be applied to textile dyeing carried out it is substantial amounts of exploitation with Research, wherein based on the warm-toned research such as red, yellow, brown, and the research to cool tone blueness is seldom, to cool tone blueness Research in, mainly research to indigo dyeing, but indigo dyeing through-dyeing is poor, complex process(Need indigo reduction first Into leuco compound, then make to contaminate fiber on leuco compound, be reoxidised into original indigo pigment and anchor on fiber).
Gardenia blue is a kind of extremely strong natural additive for foodstuff popular in the world of water solubility, and it is using cape jasmine fruit as original Material undergo microbial fermentation or the biotransformation of enzyme made from dark blue powder.Gardenia blue pigment can produce uniqueness because of it Blue cast, has the advantages that physico-chemical property is stable, tinting strength, tinting power is good, edible safety, China was just included in license in 1989 The food additives used, are widely used in the fields such as food and drink, medicine, daily-use chemical industry.There is work with gardenia blue pigment dyeing Skill is simple, advantage easy to operate, and gardenia blue pigment has affinity to cotton fiber, can directly upper dye cotton fiber.
The content of the invention
The technical problems to be solved by the invention are poor for indigo dyeing through-dyeing, and there is provided one for the defect of complex process The method using gardenia blue pigment dyeing cotton fabric is planted, gardenia blue pigment is to be undergone microbial fermentation using cape jasmine fruit as raw material or enzyme Biotransformation made from dark blue powder, dyeing course environmental protection, modifying porcelain easily, dyeing product using peace Entirely.
In order to solve the above technical problems, the present invention uses following technical scheme:
A kind of method of utilization gardenia blue pigment dyeing cotton fabric, is adopted with the following method:The pre- rear matchmaker's processing of matchmaker's processing-dyeing-- rear place Reason is dyed to bafta.
The step of rear matchmaker's processing-post processing of pre- matchmaker's processing-dyeing-is dyed to bafta is as follows:
(1)Pre- matchmaker's processing:By mordant preparation mordanting bath soluble in water, the bafta of warm water wetting, bath raio 1 are put into room temperature: 20~1:30,60 ~ 65 DEG C, 25 ~ 35min of isothermal holding are warming up to 2 DEG C/min heating rate;
(2)Dyeing:By gardenia blue pigment preparation dye liquor soluble in water, the bafta handled through pre- matchmaker, bath raio 1 are put into room temperature: 20~1:30, then addition anhydrous sodium sulfate rush dye after 60 ~ 65 DEG C, dyeing 10min is warming up to 2 DEG C/min heating rate, continue 30 ~ 40min of insulation dyeing;
(3)Matchmaker is handled afterwards:By mordant preparation mordanting bath soluble in water, the cotton put into room temperature after gardenia blue pigment dyeing is knitted Thing, bath raio 1:20~1:30,60 ~ 65 DEG C, 25 ~ 35min of isothermal holding are warming up to 2 DEG C/min heating rate;
(4)Post processing:Bafta after handling rear matchmaker is washed, is soaped, is washed, dried or dried naturally.
The step of decoration method(1)In mordant be zinc sulfate, cerium chloride, lanthanum chloride, aluminum sulfate in one kind, matchmaker Stain consumption is 1% (owf) ~ 6% (owf).
The step of decoration method(2)The consumption of gardenia blue pigment is 2% (owf) ~ 5% in middle gardenia blue pigment dye liquor (owf), anhydrous sodium sulfate consumption is the g/L of 20g/L ~ 40.
The step of decoration method(3)In mordant be zinc sulfate, cerium chloride, lanthanum chloride, aluminum sulfate in one kind, matchmaker Stain consumption is 1% (owf) ~ 6% (owf).
Beneficial effects of the present invention:Gardenia blue is a kind of extremely strong natural additive for foodstuff popular in the world of water solubility, It is undergone microbial fermentation by raw material of cape jasmine fruit or the biotransformation of enzyme made from dark blue powder.With materialization The advantages of property stabilization, good tinting strength, tinting power, edible safety, it is widely used in the fields such as food and drink, medicine, daily-use chemical industry.Use cape jasmine Cyanine dyeing has that technique is simple, advantage easy to operate.Compared with indigo dyeing, through-dyeing is good, and technique is simple, dyes Cheng Huanbao, modifying porcelain is easy.Gardenia blue pigment dyeing meets eco-dyeing and finishing developing direction.Mordant dyeing processing can be with before dyeing The repulsion for reducing gardenia blue pigment and cotton fiber is acted on, and improves dye uptake, and dye can be improved through mordant dyeing processing again after dyeing The color fastness of yarn dyed fabric, mordant is made from zinc sulfate, lanthanum chloride, cerium chloride, aluminum sulfate, be can obtain bright-coloured blue cotton and is knitted Thing, the maximum absorption wavelength of dyed cotton fabric between 600nm ~ 610nm, wherein, it is fresh that zinc sulfate does mordant dyed fabric Gorgeous degree highest, lanthanum chloride, cerium chloride do mordant dyed fabric vividness and taken second place.
Embodiment
Embodiment 1
The method of the utilization gardenia blue pigment dyeing cotton fabric of the present embodiment, step is as follows:
(1)Pre- matchmaker's processing:The bafta input room temperature that warm water is soaked contains in the mordanting bath of 1% (owf) zinc sulfate, bath raio 1:30,60 DEG C, insulation mordant dyeing processing 25min are warming up to 2 DEG C/min heating rate;
(2)Dyeing:Bafta input room temperature after being handled through pre- matchmaker contains in gardenia blue pigment 2% (owf) dye liquor, bath raio 1:30, anhydrous sodium sulfate is added after being warming up to 60 DEG C, insulation dyeing 10min with 2 DEG C/min heating rate, consumption is 20g/L, Continue to be incubated dyeing 30min;
(3)Matchmaker is handled afterwards:The mordant dyeing that the bafta input room temperature dyed by gardenia blue pigment is contained into 1% (owf) zinc sulfate In liquid, bath raio 1:30,60 DEG C, insulation mordant dyeing processing 25min are warming up to 2 DEG C/min heating rate;
(4)Post processing:Bafta after handling rear matchmaker is post-processed, post-process include washing, soap, wash, drying or Naturally dry, concrete operations are:Cold water is washed, 60 ~ 70 DEG C of warm water are washed, 3g/L detergent is in 80 ~ 85 DEG C of 3 ~ 5min that soap, 60 ~ 70 DEG C warm water is washed, 80 DEG C of drying or room temperature are dried.
Embodiment 2
The method of the utilization gardenia blue pigment dyeing cotton fabric of the present embodiment, step is as follows:
(1)Pre- matchmaker's processing:The bafta input room temperature that warm water is soaked contains in the mordanting bath of 6% (owf) aluminum sulfate, bath raio 1:20,65 DEG C, insulation mordant dyeing processing 35min are warming up to 2 DEG C/min heating rate;
(2)Dyeing:Bafta input room temperature after being handled through pre- matchmaker contains in gardenia blue pigment 5% (owf) dye liquor, bath raio 1:20, anhydrous sodium sulfate is added after being warming up to 65 DEG C, insulation dyeing 10min with 2 DEG C/min heating rate, consumption is 40g/L, Continue to be incubated dyeing 40min;
(3)Matchmaker is handled afterwards:The mordant dyeing that the bafta input room temperature dyed by gardenia blue pigment is contained into 6% (owf) aluminum sulfate In liquid, bath raio 1:20,65 DEG C, insulation mordant dyeing processing 35min are warming up to 2 DEG C/min heating rate;
(4)Post processing:Bafta after handling rear matchmaker is post-processed, post-process include washing, soap, wash, drying or Naturally dry.
Embodiment 3
The method of the utilization gardenia blue pigment dyeing cotton fabric of the present embodiment, step is as follows:
(1)Pre- matchmaker's processing:The bafta input room temperature that warm water is soaked contains in the mordanting bath of 2% (owf) lanthanum chloride, bath raio 1:30,60 DEG C are warming up to 2 DEG C/min heating rate, insulation mordant dyeing handles 27 min;
(2)Dyeing:Bafta input room temperature after being handled through pre- matchmaker contains in gardenia blue pigment 3% (owf) dye liquor, bath raio 1:30, anhydrous sodium sulfate is added after being warming up to 60 DEG C, insulation dyeing 10min with 2 DEG C/min heating rate, consumption is 30g/L, Continue to be incubated dyeing 33min;
(3)Matchmaker is handled afterwards:The mordant dyeing that the bafta input room temperature dyed by gardenia blue pigment is contained into 3% (owf) lanthanum chloride In liquid, bath raio 1:30,60 DEG C, insulation mordant dyeing processing 30min are warming up to 2 DEG C/min heating rate;
(4)Post processing:Bafta after handling rear matchmaker is post-processed, post-process include washing, soap, wash, drying or Naturally dry.
Embodiment 4
The method of the utilization gardenia blue pigment dyeing cotton fabric of the present embodiment, step is as follows:
(1)Pre- matchmaker's processing:The bafta input room temperature that warm water is soaked contains in the mordanting bath of 3% (owf) cerium chloride, bath raio 1:25,60 DEG C are warming up to 2 DEG C/min heating rate, insulation mordant dyeing handles 30 min;
(2)Dyeing:Bafta input room temperature after being handled through pre- matchmaker contains in gardenia blue pigment 3% (owf) dye liquor, bath raio 1:25, anhydrous sodium sulfate is added after being warming up to 60 DEG C, insulation dyeing 10min with 2 DEG C/min heating rate, consumption is 32g/L, Continue to be incubated dyeing 35min;
(3)Matchmaker is handled afterwards:The mordant dyeing that the bafta input room temperature dyed by gardenia blue pigment is contained into 3% (owf) cerium chloride In liquid, bath raio 1:25,60 DEG C, insulation mordant dyeing processing 33min are warming up to 2 DEG C/min heating rate;
(4)Post processing:Bafta after handling rear matchmaker is post-processed, post-process include washing, soap, wash, drying or Naturally dry.
Embodiment 5
The method of the utilization gardenia blue pigment dyeing cotton fabric of the present embodiment, step is as follows:
(1)Pre- matchmaker's processing:The bafta input room temperature that warm water is soaked contains in the mordanting bath of 4% (owf) zinc sulfate, bath raio 1:25,65 DEG C are warming up to 2 DEG C/min heating rate, insulation mordant dyeing handles 32 min;
(2)Dyeing:Bafta input room temperature after being handled through pre- matchmaker contains in gardenia blue pigment 4% (owf) dye liquor, bath raio 1:25, anhydrous sodium sulfate is added after being warming up to 60 DEG C, insulation dyeing 10min with 2 DEG C/min heating rate, consumption is 35g/L, Continue to be incubated dyeing 37min;
(3)Matchmaker is handled afterwards:The mordant dyeing that the bafta input room temperature dyed by gardenia blue pigment is contained into 4% (owf) zinc sulfate In liquid, bath raio 1:25,60 DEG C, insulation mordant dyeing processing 34min are warming up to 2 DEG C/min heating rate;
(4)Post processing:Bafta after handling rear matchmaker is post-processed, post-process include washing, soap, wash, drying or Naturally dry.
Embodiment 6
The method of the utilization gardenia blue pigment dyeing cotton fabric of the present embodiment, step is as follows:
(1)Pre- matchmaker's processing:The bafta input room temperature that warm water is soaked contains in the mordanting bath of 5% (owf) lanthanum chloride, bath raio 1:20,65 DEG C are warming up to 2 DEG C/min heating rate, insulation mordant dyeing handles 35 min;
(2)Dyeing:Bafta input room temperature after being handled through pre- matchmaker contains in gardenia blue pigment 4% (owf) dye liquor, bath raio 1:20, anhydrous sodium sulfate is added after being warming up to 65 DEG C, insulation dyeing 10min with 2 DEG C/min heating rate, consumption is 30g/L, Continue to be incubated dyeing 40min;
(3)Matchmaker is handled afterwards:The mordant dyeing that the bafta input room temperature dyed by gardenia blue pigment is contained into 5% (owf) zinc sulfate In liquid, bath raio 1:20,65 DEG C, insulation mordant dyeing processing 35min are warming up to 2 DEG C/min heating rate;
(4)Post processing:Bafta after handling rear matchmaker is post-processed, post-process include washing, soap, wash, drying or Naturally dry.
Embodiment 7
The method of the utilization gardenia blue pigment dyeing cotton fabric of the present embodiment, step is as follows:
(1)Pre- matchmaker's processing:The bafta input room temperature that warm water is soaked contains in the mordanting bath of 3% (owf) cerium chloride, bath raio 1:30,60 DEG C are warming up to 2 DEG C/min heating rate, insulation mordant dyeing handles 30 min;
(2)Dyeing:Bafta input room temperature after being handled through pre- matchmaker contains in gardenia blue pigment 2% (owf) dye liquor, bath raio 1:30, anhydrous sodium sulfate is added after being warming up to 60 DEG C, insulation dyeing 10min with 2 DEG C/min heating rate, consumption is 25g/L, Continue to be incubated dyeing 32min;
(3)Matchmaker is handled afterwards:The mordant dyeing that the bafta input room temperature dyed by gardenia blue pigment is contained into 2% (owf) cerium chloride In liquid, bath raio 1:30,65 DEG C, insulation mordant dyeing processing 28min are warming up to 2 DEG C/min heating rate;
(4)Post processing:Bafta after handling rear matchmaker is post-processed, post-process include washing, soap, wash, drying or Naturally dry.
Fabric apparent shade depthK/SThe measure of value:Determined with the high-precision colour photometers of CE-7000A SCT, using D65Light source and 10°Viewing angle, each sample is surveyed 4 times, is averaged.
Fastness to soaping:With reference to GB/T 3921-2008《Textile color stability tests fastness to soaping》Carry out Test.
Colour fastness to rubbing:With reference to GB/T 3920-2008《Textile color stability tests colour fastness to rubbing》Carry out Test.
Colour fastness to perspiration:With reference to GB/T 3922-2013《Textile color stability tests colour fastness to perspiration》Carry out Test.
Color fastness to hot pressing:With reference to GB/T 6152-1997《Textile color stability tests color fastness to hot pressing》Surveyed Examination.
The K/S values and color fastness of bafta after table 1 is dyed according to embodiment 4
The K/S values and color fastness of bafta after table 2 is dyed according to embodiment 5
The color fastness of the dyed cotton fabric measured reaches GB/T 411-2008《Cotton dyeing cloth》High-class product standard.
The general principle and principal character and advantages of the present invention of the present invention has been shown and described above.The skill of the industry Art personnel are it should be appreciated that the present invention is not limited to the above embodiments, and described in above-described embodiment and specification is explanation The principle of the present invention, without departing from the spirit and scope of the present invention, various changes and modifications of the present invention are possible, these Changes and improvements all fall within the protetion scope of the claimed invention.The claimed scope of the invention by appended claims and Its equivalent thereof.

Claims (5)

1. a kind of method of utilization gardenia blue pigment dyeing cotton fabric, it is characterised in that adopt with the following method:Pre- matchmaker's processing-dyeing- Matchmaker's processing-post processing is dyed to bafta afterwards.
2. the method for utilization gardenia blue pigment dyeing cotton fabric according to claim 1, it is characterised in that at described pre- matchmaker Reason-dyeing-rear matchmaker is handled-post-processes decoration method step as follows:
(1)Pre- matchmaker's processing:By mordant preparation mordanting bath soluble in water, the bafta of warm water wetting, bath raio 1 are put into room temperature: 20~1:30,60 ~ 65 DEG C, 25 ~ 35min of isothermal holding are warming up to 2 DEG C/min heating rate;
(2)Dyeing:By gardenia blue pigment preparation dye liquor soluble in water, the bafta handled through pre- matchmaker, bath raio 1 are put into room temperature: 20~1:30, then addition anhydrous sodium sulfate rush dye after 60 ~ 65 DEG C, dyeing 10min is warming up to 2 DEG C/min heating rate, continue 30 ~ 40min of insulation dyeing;
(3)Matchmaker is handled afterwards:By mordant preparation mordanting bath soluble in water, the cotton put into room temperature after gardenia blue pigment dyeing is knitted Thing, bath raio 1:20~1:30,60 ~ 65 DEG C, 25 ~ 35min of isothermal holding are warming up to 2 DEG C/min heating rate;
(4)Post processing:Bafta after handling rear matchmaker is washed, is soaped, is washed, dried or dried naturally.
3. the method for utilization gardenia blue pigment dyeing cotton fabric according to claim 2, it is characterised in that:The step(1) In mordant be zinc sulfate, cerium chloride, lanthanum chloride or aluminum sulfate in one kind, mordant consumption be 1% (owf) ~ 6% (owf)。
4. the method for utilization gardenia blue pigment dyeing cotton fabric according to claim 2, it is characterised in that:The step(2) In middle gardenia blue pigment dye liquor the consumption of gardenia blue pigment be 2% (owf) ~ 5% (owf), anhydrous sodium sulfate consumption be 20g/L ~ 40 g/L。
5. the method for utilization gardenia blue pigment dyeing cotton fabric according to claim 2, it is characterised in that:The step(3) In mordant be zinc sulfate, cerium chloride, lanthanum chloride or aluminum sulfate in one kind, mordant consumption be 1% (owf) ~ 6% (owf)。
CN201710474491.7A 2017-06-21 2017-06-21 Utilize the method for gardenia blue pigment dyeing cotton fabric Pending CN107059442A (en)

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CN108894017A (en) * 2018-06-04 2018-11-27 晋江市隆盛针织印染有限公司 The method of natural plant dye dyeing cotton fabric
CN109162119A (en) * 2018-09-05 2019-01-08 浙江稽山印染有限公司 A kind of natural plant dye and its application in dyeing and printing process
CN109162117A (en) * 2018-08-06 2019-01-08 河南工程学院 Using natural pigment to the method for cotton fabric green colouring
CN109235089A (en) * 2018-09-05 2019-01-18 浙江稽山印染有限公司 A kind of application of natural plant dye in dyeing and printing process
CN114855473A (en) * 2022-05-20 2022-08-05 青岛大学 Dyeing method of cellulose fiber material

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CN107829315A (en) * 2017-12-01 2018-03-23 河南工程学院 The method of silk fabric green colouring
CN108894017A (en) * 2018-06-04 2018-11-27 晋江市隆盛针织印染有限公司 The method of natural plant dye dyeing cotton fabric
CN109162117A (en) * 2018-08-06 2019-01-08 河南工程学院 Using natural pigment to the method for cotton fabric green colouring
CN109162117B (en) * 2018-08-06 2020-04-10 河南工程学院 Method for dyeing cotton fabric green by using natural pigment
CN109162119A (en) * 2018-09-05 2019-01-08 浙江稽山印染有限公司 A kind of natural plant dye and its application in dyeing and printing process
CN109235089A (en) * 2018-09-05 2019-01-18 浙江稽山印染有限公司 A kind of application of natural plant dye in dyeing and printing process
CN109235089B (en) * 2018-09-05 2021-07-30 浙江稽山印染有限公司 Application of natural plant dye in printing and dyeing process
CN114855473A (en) * 2022-05-20 2022-08-05 青岛大学 Dyeing method of cellulose fiber material
CN114855473B (en) * 2022-05-20 2023-12-15 青岛大学 Dyeing method of cellulose fiber material

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Application publication date: 20170818