CN109162119A - A kind of natural plant dye and its application in dyeing and printing process - Google Patents
A kind of natural plant dye and its application in dyeing and printing process Download PDFInfo
- Publication number
- CN109162119A CN109162119A CN201811032289.XA CN201811032289A CN109162119A CN 109162119 A CN109162119 A CN 109162119A CN 201811032289 A CN201811032289 A CN 201811032289A CN 109162119 A CN109162119 A CN 109162119A
- Authority
- CN
- China
- Prior art keywords
- mordant
- dyeing
- dye
- silk fabric
- real silk
- Prior art date
- Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
- Pending
Links
Classifications
-
- D—TEXTILES; PAPER
- D06—TREATMENT OF TEXTILES OR THE LIKE; LAUNDERING; FLEXIBLE MATERIALS NOT OTHERWISE PROVIDED FOR
- D06P—DYEING OR PRINTING TEXTILES; DYEING LEATHER, FURS OR SOLID MACROMOLECULAR SUBSTANCES IN ANY FORM
- D06P1/00—General processes of dyeing or printing textiles, or general processes of dyeing leather, furs, or solid macromolecular substances in any form, classified according to the dyes, pigments, or auxiliary substances employed
- D06P1/34—General processes of dyeing or printing textiles, or general processes of dyeing leather, furs, or solid macromolecular substances in any form, classified according to the dyes, pigments, or auxiliary substances employed using natural dyestuffs
-
- D—TEXTILES; PAPER
- D06—TREATMENT OF TEXTILES OR THE LIKE; LAUNDERING; FLEXIBLE MATERIALS NOT OTHERWISE PROVIDED FOR
- D06P—DYEING OR PRINTING TEXTILES; DYEING LEATHER, FURS OR SOLID MACROMOLECULAR SUBSTANCES IN ANY FORM
- D06P1/00—General processes of dyeing or printing textiles, or general processes of dyeing leather, furs, or solid macromolecular substances in any form, classified according to the dyes, pigments, or auxiliary substances employed
- D06P1/44—General processes of dyeing or printing textiles, or general processes of dyeing leather, furs, or solid macromolecular substances in any form, classified according to the dyes, pigments, or auxiliary substances employed using insoluble pigments or auxiliary substances, e.g. binders
- D06P1/673—Inorganic compounds
-
- D—TEXTILES; PAPER
- D06—TREATMENT OF TEXTILES OR THE LIKE; LAUNDERING; FLEXIBLE MATERIALS NOT OTHERWISE PROVIDED FOR
- D06P—DYEING OR PRINTING TEXTILES; DYEING LEATHER, FURS OR SOLID MACROMOLECULAR SUBSTANCES IN ANY FORM
- D06P1/00—General processes of dyeing or printing textiles, or general processes of dyeing leather, furs, or solid macromolecular substances in any form, classified according to the dyes, pigments, or auxiliary substances employed
- D06P1/44—General processes of dyeing or printing textiles, or general processes of dyeing leather, furs, or solid macromolecular substances in any form, classified according to the dyes, pigments, or auxiliary substances employed using insoluble pigments or auxiliary substances, e.g. binders
- D06P1/673—Inorganic compounds
- D06P1/67333—Salts or hydroxides
- D06P1/67341—Salts or hydroxides of elements different from the alkaline or alkaline-earth metals or with anions containing those elements
-
- D—TEXTILES; PAPER
- D06—TREATMENT OF TEXTILES OR THE LIKE; LAUNDERING; FLEXIBLE MATERIALS NOT OTHERWISE PROVIDED FOR
- D06P—DYEING OR PRINTING TEXTILES; DYEING LEATHER, FURS OR SOLID MACROMOLECULAR SUBSTANCES IN ANY FORM
- D06P3/00—Special processes of dyeing or printing textiles, or dyeing leather, furs, or solid macromolecular substances in any form, classified according to the material treated
- D06P3/02—Material containing basic nitrogen
- D06P3/04—Material containing basic nitrogen containing amide groups
-
- D—TEXTILES; PAPER
- D06—TREATMENT OF TEXTILES OR THE LIKE; LAUNDERING; FLEXIBLE MATERIALS NOT OTHERWISE PROVIDED FOR
- D06P—DYEING OR PRINTING TEXTILES; DYEING LEATHER, FURS OR SOLID MACROMOLECULAR SUBSTANCES IN ANY FORM
- D06P5/00—Other features in dyeing or printing textiles, or dyeing leather, furs, or solid macromolecular substances in any form
- D06P5/02—After-treatment
Landscapes
- Engineering & Computer Science (AREA)
- Textile Engineering (AREA)
- Chemical & Material Sciences (AREA)
- Inorganic Chemistry (AREA)
- Coloring (AREA)
Abstract
The invention belongs to textile dyeing and finishing fields, and in particular to a method of real silk fabric is dyed using rhizome of cyrtomium natural plant dye, the method includes the step of be, the pretreatment of real silk fabric, pre- mordant dyeing processing, dyeing, rear mordant dyeing processing and post-processing.Processing step and process conditions when dyeing of the invention is by dyeing optimize adjustment, carry out pre- mordant dyeing especially by the mordant using specific composition and rear mordant dyeing is handled, to greatly improve the dye-uptake and color fastness to real silk fabric.
Description
Technical field
The invention belongs to textile dyeing and finishing fields, and in particular to a kind of to be carried out using rhizome of cyrtomium natural plant dye to real silk fabric
The method of dyeing.
Background technique
As the improvement of people's living standards, more and more people start to advocate nature and healthy lifestyles, people
It is more more and more intense to the concern consciousness of own health and health care etc., and partially synthetic dyestuff is to human health and ecological environment
Generated harm is more and more noticeable.Existing result of study is it has been shown that have 23 kinds of carcinogenic aromatic amines, more than 100
Kind of synthetic dyestuffs are possible to generate carcinogen, and more than 20 synthetic dyestuffs generate allergy to skin, therefore European Union land in recent years
Regulation of the supervention cloth including prohibitive dye and other chemicals, as European Union 67/648/EC instruction, European Union 2001/C96E/18 refer to
It enables, European Union 2002/61/EC instruction, European Union 2003/3/EC instruction, ECO--Label new standard, chemicals REACH regulation etc., this
Seriously constrain China's textile exports.Moreover, synthetic dyestuffs can also generate a large amount of pollution in the process of production to environment.
Compared with traditional synthetic dyestuffs, natural dye is many with its is unique nontoxic, harmless, pollution-free and is concerned
Can also have healthcare function to human body using Chinese herbal medicine as the natural dye of raw material.For the needs to environmental protection, exploitation is natural
Resource is more urgent.With the raising that people's ecological, environmental protective is realized, in the development trend for increasingly focusing on environmental protection, eco-dyeing and finishing processing
Under, the exploitation and application of natural dye necessarily obtain continuous development.
Natural pigment is from a wealth of sources, it is made to have become the emphasis of new dye exploitation and source.The research of natural dye
It mainly include extraction process, dyeability and upper dye mechanism etc..Asia is concentrated mainly on to the research of natural dye in the world
Continent, especially South Korea, Japan etc..Research about natural dye has become one as technical coopreation among developing countries plan
Part, i.e. United Nations Development Programme (UNDP).Although China is of long standing and well established using the history of natural plants dyeing, synthesizing
After dyestuff replaces natural dye, in addition to some ethnic groups still use vegetable colour to produce artifacts, to natural dye
The research for carrying out system development and utilizing is seldom.At the beginning of 21 century, with the rise of natural dye in the world, the country is to day
The research report of right dyeing is just increasing.
Rhizome of cyrtomium, also known as pass through canal, pass through section, it is fern herbaceos perennial, rhizomes is short, overgrown, pinnate compound leaf, leaflet
It is sickle-shaped.Its is cold in nature, slight bitter, slightly poisonous.Its main component is complicated phloroglucin derivative etc., there is antivirus action, right
Influenza virus has strong inhibition effect, has the effects that clearing heat and detoxicating, expelling parasite, cool blood, hemostasis.Clinically for treating wind-heat sense
It emits, damp and hot ecchymosis, haematemesis, the diseases such as hematochezia and metrorrhagia and metrostaxis.
The pigment composition content of rhizome of cyrtomium is very high, can be used as a kind of natural brown dyestuff and is dyed, printed to textile
Flower, also have the function of it is antibacterial, antiviral, mosquito larvae can be killed etc..Therefore, a kind of brown natural dye is extracted from rhizome of cyrtomium and is answered
For textile dyeing, the shelves of textile are improved for expanding natural dye chromatography and application range, development functionality textile
Secondary and added value, has a very important significance.
Rhizome of cyrtomium natural plant dye is due to this body structure of its dye molecule, fastness to weathering deviation；And
In dyeing course, a certain amount of sugared part and pectin can be entrained in rhizome of cyrtomium dyestuff obtained natural due to extracting, described sugar part and
Pectin will affect the diffusion of dyestuff in dyeing technique in turn, so as to cause dye-uptake of the dyestuff on silk and cotton fabric and resistance to
Washing is poor.
A kind of colouring method of rhizome of cyrtomium natural dye as disclosed in Chinese patent CN01177542A, wherein by not having to matchmaker
The direct staining method of stain can get silk, wool and the cotton products of brown；By using mischmetal, Metal aluminum salt or metal
Ferrous salt is that the rear mordant dyeing of mordant can obtain the silk and wool product of yellowish-brown, rufous or brown respectively.The document
Although giving a kind of colouring method of rhizome of cyrtomium natural dye, using the silk of colouring method acquisition, sheep wool and cotton
The colour fastness to rubbing and fastness to soaping of product are not ideal enough.
As Institutes Of Technology Of Zhejiang's master thesis " extraction and its application on cotton fabric of natural dye " discloses
It is first cation-modified to cotton fabric progress based on the dyeing of rhizome of cyrtomium natural dye, it is then dyed, wherein optimal dye
Color process conditions are as follows: dye strength 10%, pH value 3.0,100 DEG C of temperature, time 60min, NaCl dosage 10g/L, bath raio 1:
50.But the color fastness to washing of the cotton fabric of the colouring method of document acquisition is undesirable, it is also necessary to a nanometer solvent is introduced to it
Color fixing agent is crosslinked color fixing agent to improve its color fastness to washing, substantially increases the complexity and production cost of technique.
Summary of the invention
For this purpose, technical problems to be solved in this application are that how to improve rhizome of cyrtomium natural dye dying technique knits silk
Specifically how the dyeing effect of object improves dye-uptake and color fastness using real silk fabric after dyeing processing.
In order to solve the above technical problems, present inventor is by the research conscientiously with effort, it was found that one kind has
Synergistic dyeing, processing step and process conditions when by dyeing optimize adjustment, especially by adopting
Pre- mordant dyeing and rear mordant dyeing processing are carried out with the mordant of specific composition, can significantly improve and be handled using rhizome of cyrtomium natural dye dying
The dye-uptake and color fastness of real silk fabric afterwards, thus solves the above technical problem.
The technical solution of the application is as follows: being contaminated this application discloses a kind of using rhizome of cyrtomium Natural Dye on Silk Fabric
The technique of color, includes the following steps:
1) real silk fabric the pretreatment of real silk fabric: is impregnated into about 5-20min in about 45-65 DEG C of hot water；
2) pre- mordant dyeing processing: by mordant preparation mordanting bath soluble in water, the pH value of mordanting bath is about 5-10, puts into pre- place
Real silk fabric after reason is warming up to about 50~95 DEG C with the heating rate of about 1-5 DEG C/min, keeps the temperature about 15~60min；
3) dye: by rhizome of cyrtomium natural dye preparation dye liquor soluble in water, the pH value of dye liquor is about 5-10, is put into through pre- mordant dyeing
The real silk fabric of processing, bath raio are about 1:10~1:50, then are warming up to about 70~95 DEG C with the heating rate of about 1-5 DEG C/min,
Keep the temperature about 30~120min；After stopping heating, dye liquor temperature is down to about 50-60 DEG C；
4) mordant dyeing is handled afterwards: mordant being added into dye liquor and constant temperature keeps about 20-40min, is subsequently reduced to room temperature；
5) post-process: mordant dyeing treated real silk fabric after taking-up is first washed it, is dried, then soaped, water
It washes, dry.
The mordant is the mixture of rare earth compound and ferrous sulfate, by the yttrium oxide of about 40-55wt%
(Y2O3), the cerous carbonate (Ce of about 45-60wt%2(CO3)3), the ferrous sulfate (FeSO of about 0.5-1.0wt%4) composition, with mixing
On the basis of the total weight of object.
The temperature of hot water is preferably from about 50-60 DEG C, even more preferably about 55 DEG C in the step 1)；Soaking time is preferably from about
8-18min, even more preferably about 12min.
The bath raio of mordanting bath is about 1:10~1:60, even more preferably about 1:20~1:50 in the step 2), most preferably
About 1:25.The dosage of mordant is about 0.3-1.5g/L, even more preferably about 0.5-1.2g/L, most preferably about 0.8g/L, with matchmaker
On the basis of the volume of dye liquor.
The pH value of mordanting bath is preferably from about 6-9, even more preferably about 8 in the step 2)；Heating rate is preferably from about 2-4
DEG C/min, even more preferably about 2.5 DEG C/min；The holding temperature of pre- mordant dyeing processing is preferably 60-80 DEG C, and more preferably 75 DEG C；It protects
The warm time is preferably 20-50min, more preferably 30-40min, most preferably 35min.
The bath raio of dye liquor is preferably from about 1:15~1:40, most preferably about 1:20 in the step 3)；The dye liquor it is dense
Degree is about 10-30wt.%, even more preferably about 15-20wt.%, most preferably about 18wt.%.
The pH value of dye liquor is preferably from about 7-8, even more preferably about 7.5 in the step 3)；Heating rate is preferably from about 2-4
DEG C/min, even more preferably about 2.5 DEG C/min；The holding temperature of pre- mordant dyeing processing is preferably 75-90 DEG C, and more preferably 80 DEG C；It protects
The warm time is preferably 50-100min, more preferably 60min.
The dosage of mordant is about 0.5-2.0g/L, even more preferably about 0.8-1.5g/L in the step 4), most preferably
About 1.2g/L, on the basis of the volume of dye liquor.
Soaking time in the step 4) is preferably 30min.
The pH adjusting agent that can be used for adjusting mordanting bath and dye liquor in the application includes the hydroxide of alkali metal, carbonic acid
Salt, silicate and/or phosphate, common inorganic acid, such as hydrochloric acid, nitric acid, sulfuric acid and common organic acid, such as citric acid
Deng.
The application has the beneficial effect that
1, compared with the dyeing of existing rhizome of cyrtomium natural dye, the dyeing dyeing of the application has technique letter
Single, advantage easy to operate；And dyeing course is environmentally friendly, generated dyeing waste-water is easily handled, and not will cause environment
Pollution.
2, processing step and process conditions when the dyeing of the application is by dyeing optimize adjustment, especially
Pre- mordant dyeing and rear mordant dyeing processing are carried out by using the mordant of specific composition, to greatly improve to the upper of real silk fabric
Dye rate and color fastness.
3, it is directly contacted with human skin using dyeing of real silk fabric obtained by the application dyeing using safe
Carcinogenic, teratogenesis is not had or is caused allergic reaction；But also there is certain medicinal health-care effect, antibacterial anti-inflammatory can be played
Effect, and can mosquito-proof sting.
4, obtain that color is uniform, color is soft, naturally typical using dyeing of real silk fabric obtained by the application dyeing, it can
Meet the aesthetic needs of modern.
Other advantage will be partly show in the following description, and can be partly able to by specific embodiment
Understand.Especially by point out in the dependent claims Chemical composition that, method and combinations thereof, will realize and obtain down
State advantage.It should be appreciated that general description and detailed description below above is merely exemplary and illustrative, rather than
It is restrictive.
Complementary definition
Material, compound, composition and component described herein, can be used for method and composition described herein,
Or it can be in connection or the production that can be used for implementing the method and prepare the composition or obtained as the method
Product.It should be appreciated that when disclosing combination, subset, interaction, the group etc. of these materials, although may not clearly have
Body refers to each and collective combinations and arrangement of these compounds, but specifically considers and describe wherein in this application
Each.For example, extracting adjuvant component if disclosing and discussing, and a variety of alternative solid-state forms of the component are discussed,
Then unless there is specific opposite instruction, each possible for referring to adjuvant component and solid-state form is otherwise specifically considered
Combination and permutation.The concept is suitable for all aspects of the application, is including but not limited to making and using disclosed combination
Step in the method for object.Therefore, if there is the multiple other steps that can be executed, then it should be appreciated that these are other
Each of step can be executed by the combination of any specific embodiment or multiple embodiments of disclosed method,
And each such combination is specifically considered, they should be considered as disclosing.
In claims in this specification and its later, refer to many terms, they should be defined as with
Lower meaning:
It must be noted that unless context is in addition clearly stipulate that otherwise such as institute in this specification and appended claims
Not only may include a referring to thing with, singular " one ", "/kind " and " should/described ", but may include multiple referring to thing (i.e.
Two or more, including two).Thus, for example, referring to that " pH adjusting agent " may include single pH adjusting agent or two
Kind or more mixture of pH adjusting agent, etc..
Unless otherwise specified, therefore it and may include in the model about that the numberical range in the application, which is,
Enclose outer value.The numberical range can be expressed as in the application from " about " particular value and/or to " about " another particular value.
It on the other hand include from one particular value and/or to another particular value when stating such range.Similarly,
When value is expressed as approximation by using antecedent " about ", it should be understood that the particular value is formed on the other hand.Also answer
Work as understanding, the endpoint of each in numberical range is important and independently of another end in the relationship with another endpoint
Point.
The parts by weight of element-specific or component in composition or product are referred in specification and last claims
Refer to the weight relationships stated in composition or product between the element or component and any other element or component with parts by weight.
Therefore, in the composition comprising 2 parts by weight of component X and 5 parts by weight of component Y, X and Y exist with the weight ratio of 2:5, and nothing
It whether include that other component exists with the ratio by composition.
Unless specifically stated to the contrary meanings, ways customary is dark or in context or technical field based on context
Show, all scores and percentage otherwise referred in the application are by weight, and the weight percent of component be based on comprising
The composition of the component or the total weight of product.
"comprising", " comprising ", " having " and the similar terms referred in the application are not intended to exclude any optional group
Divide, the presence of step or program, regardless of whether specifically disclosing any optional component, step or program.It is doubted in order to avoid any
It asks, unless may include otherwise one or more volumes by using all methods that term "comprising" requires there are state otherwise
Outer step, equipment part or component part and/or substance.In contrast, term " by ... form " exclude be not specifically delineated
Or any component, step or the program enumerated.Unless otherwise stated, otherwise term "or" refers to individually and with any combination shape
The member that formula is enumerated.
In addition, the side that the content of any referenced patent document or non-patent literature is all quoted in its entirety in the application
Formula is incorporated herein, especially with respect to disclosed in fields definition (any definition not provided specifically with the application not
Under unanimous circumstances) and common sense.
Specific embodiment
Iing is proposed the following example is to provide how to be made and evaluate the application institute to those skilled in the art
Entire disclosure and the description of compound state and claimed, composition, product, device and/or method,
And it is intended only to be illustrative, is not intended to be limiting the range that inventor is considered as its invention.Effort has been made to ensure
About the accuracy of digital (such as amount, temperature etc.), but it is contemplated that some errors and deviation.Unless otherwise specified, no
Then number is parts by weight, and temperature is DEG C to indicate or under environment temperature, and pressure is atmospheric pressure or close to atmospheric pressure.
There are reaction condition (such as concentration of component, required solvent, solvent mixture, temperature, pressure and other reaction ranges) and
It can be used for optimizing a variety of variations and combination of the condition of the product purity and yield that obtain by the method.It will only need
Reasonable routine experiment optimizes such method condition.
Embodiment 1:
The dyeing of the present embodiment, includes the following steps:
1) real silk fabric the pretreatment of real silk fabric: is impregnated into 20min in 45 DEG C of hot water；
2) pre- mordant dyeing processing: by mordant preparation mordanting bath soluble in water, the pH value of mordanting bath is 5, after investment pretreatment
Real silk fabric, be warming up to 50 DEG C with the heating rate of 1 DEG C/min, keep the temperature 60min；Wherein, the bath raio of mordanting bath is 1:10, matchmaker
The dosage of stain is 0.3g/L.
3) dye: by rhizome of cyrtomium natural dye preparation dye liquor soluble in water, the pH value of dye liquor is 5, and investment is handled through pre- mordant dyeing
Real silk fabric, bath raio 1:10, then be warming up to 70 DEG C with the heating rate of 1 DEG C/min keeps the temperature 120min；After stopping heating,
Dye liquor temperature is down to 50 DEG C；Wherein, the concentration of dye liquor is 10wt.%.
4) mordant dyeing is handled afterwards: mordant being added into dye liquor and constant temperature keeps 40min, is subsequently reduced to room temperature；Wherein mordant dyeing
The dosage of agent is 0.5g/L.
5) post-process: mordant dyeing treated real silk fabric after taking-up is first washed it, is dried, then soaped, water
It washes, dry.
Wherein, mordant used is the yttrium oxide (Y by 40wt%2O3), the cerous carbonate (Ce of 59wt%2(CO3)3),
Ferrous sulfate (the FeSO of 1.0wt%4) composition, on the basis of the total weight of mordant.
Embodiment 2
The dyeing of the present embodiment, includes the following steps:
1) real silk fabric the pretreatment of real silk fabric: is impregnated into 5min in 65 DEG C of hot water；
2) pre- mordant dyeing processing: by mordant preparation mordanting bath soluble in water, the pH value of mordanting bath is 10, after investment pretreatment
Real silk fabric, be warming up to 95 DEG C with the heating rate of 5 DEG C/min, keep the temperature 15min；Wherein, the bath raio of mordanting bath is 1:60, matchmaker
The dosage of stain is 1.5g/L.
3) dye: by rhizome of cyrtomium natural dye preparation dye liquor soluble in water, the pH value of dye liquor is 10, and investment is handled through pre- mordant dyeing
Real silk fabric, bath raio 1:50, then be warming up to 95 DEG C with the heating rate of 5 DEG C/min keeps the temperature 30min；It, will after stopping heating
Dye liquor temperature is down to 60 DEG C；Wherein, the concentration of dye liquor is 30wt.%.
4) mordant dyeing is handled afterwards: mordant being added into dye liquor and constant temperature keeps 20min, is subsequently reduced to room temperature；Wherein mordant dyeing
The dosage of agent is 2.0g/L.
5) post-process: mordant dyeing treated real silk fabric after taking-up is first washed it, is dried, then soaped, water
It washes, dry.
Wherein, mordant used is the yttrium oxide (Y by 55wt%2O3), the cerous carbonate (Ce of 44.5wt%2(CO3)3),
Ferrous sulfate (the FeSO of 0.5wt%4) composition, on the basis of the total weight of mordant.
Embodiment 3
The dyeing of the present embodiment, includes the following steps:
1) real silk fabric the pretreatment of real silk fabric: is impregnated into 18min in 50 DEG C of hot water；
2) pre- mordant dyeing processing: by mordant preparation mordanting bath soluble in water, the pH value of mordanting bath is 6, after investment pretreatment
Real silk fabric, be warming up to 60 DEG C with the heating rate of 2 DEG C/min, keep the temperature 50min；Wherein, the bath raio of mordanting bath is 1:20, matchmaker
The dosage of stain is 0.5g/L.
3) dye: by rhizome of cyrtomium natural dye preparation dye liquor soluble in water, the pH value of dye liquor is 7, and investment is handled through pre- mordant dyeing
Real silk fabric, bath raio 1:15, then be warming up to 75 DEG C with the heating rate of 2 DEG C/min keeps the temperature 100min；After stopping heating,
Dye liquor temperature is down to 55 DEG C；Wherein, the concentration of dye liquor is 15wt.%.
4) mordant dyeing is handled afterwards: mordant being added into dye liquor and constant temperature keeps 30min, is subsequently reduced to room temperature；Wherein mordant dyeing
The dosage of agent is 0.8g/L.
5) post-process: mordant dyeing treated real silk fabric after taking-up is first washed it, is dried, then soaped, water
It washes, dry.
Wherein, mordant used is the yttrium oxide (Y by 50wt%2O3), the cerous carbonate (Ce of 49.2wt%2(CO3)3),
Ferrous sulfate (the FeSO of 0.8wt%4) composition, on the basis of the total weight of mordant.
Embodiment 4
The dyeing of the present embodiment, includes the following steps:
1) real silk fabric the pretreatment of real silk fabric: is impregnated into 8min in 60 DEG C of hot water；
2) pre- mordant dyeing processing: by mordant preparation mordanting bath soluble in water, the pH value of mordanting bath is 9, after investment pretreatment
Real silk fabric, be warming up to 80 DEG C with the heating rate of 4 DEG C/min, keep the temperature 20min；Wherein, the bath raio of mordanting bath is 1:50, matchmaker
The dosage of stain is 1.2g/L.
3) dye: by rhizome of cyrtomium natural dye preparation dye liquor soluble in water, the pH value of dye liquor is 8, and investment is handled through pre- mordant dyeing
Real silk fabric, bath raio 1:40, then be warming up to 90 DEG C with the heating rate of 4 DEG C/min keeps the temperature 50min；It, will after stopping heating
Dye liquor temperature is down to 55 DEG C；Wherein, the concentration of dye liquor is 20wt.%.
4) mordant dyeing is handled afterwards: mordant being added into dye liquor and constant temperature keeps 30min, is subsequently reduced to room temperature；Wherein mordant dyeing
The dosage of agent is 1.5g/L.
5) post-process: mordant dyeing treated real silk fabric after taking-up is first washed it, is dried, then soaped, water
It washes, dry.
Wherein, mordant used is the yttrium oxide (Y by 44.1wt%2O3), the cerous carbonate (Ce of 55wt%2(CO3)3),
Ferrous sulfate (the FeSO of 0.9wt%4) composition, on the basis of the total weight of mordant.
Embodiment 5
The dyeing of the present embodiment, includes the following steps:
1) real silk fabric the pretreatment of real silk fabric: is impregnated into 12min in 55 DEG C of hot water；
2) pre- mordant dyeing processing: by mordant preparation mordanting bath soluble in water, the pH value of mordanting bath is 8, after investment pretreatment
Real silk fabric, be warming up to 75 DEG C with the heating rate of 2.5 DEG C/min, keep the temperature 35min；Wherein, the bath raio of mordanting bath is 1:25,
The dosage of mordant is 0.8g/L.
3) dye: by rhizome of cyrtomium natural dye preparation dye liquor soluble in water, the pH value of dye liquor is 7.5, is put at through pre- mordant dyeing
The real silk fabric of reason, bath raio 1:20, then 80 DEG C are warming up to the heating rate of 2.5 DEG C/min, keep the temperature 60min；Stop heating
Afterwards, dye liquor temperature is down to 55 DEG C；Wherein, the concentration of dye liquor is 18wt.%.
4) mordant dyeing is handled afterwards: mordant being added into dye liquor and constant temperature keeps 30min, is subsequently reduced to room temperature；Wherein mordant dyeing
The dosage of agent is 1.2g/L.
5) post-process: mordant dyeing treated real silk fabric after taking-up is first washed it, is dried, then soaped, water
It washes, dry.
Wherein, mordant used is the yttrium oxide (Y by 48.5wt%2O3), the cerous carbonate (Ce of 51wt%2(CO3)3),
Ferrous sulfate (the FeSO of 0.5wt%4) composition, on the basis of the total weight of mordant.
Comparative example 1
Preparation process is substantially the same manner as Example 5, and difference is only that: mordant used is only by yttrium oxide (Y2O3) constitute.
Comparative example 2
Preparation process is substantially the same manner as Example 5, and difference is only that: mordant used is only by cerous carbonate (Ce2(CO3)3)
It constitutes.
Comparative example 3
Preparation process is substantially the same manner as Example 5, and difference is only that: mordant used is the yttrium oxide by 49wt%
(Y2O3), the cerous carbonate (Ce of 51wt%2(CO3)3) composition, on the basis of the total weight of mordant.
Comparative example 4
Preparation process is substantially the same manner as Example 5, and difference is only that: mordant used is the yttrium chloride by 48.5wt%
(YCl3), the cerium chloride (CeCl of 51wt%3), the ferrous sulfate (FeSO of 0.5wt%4) composition, using the total weight of mordant as base
It is quasi-.
Comparative example 5
Preparation process is substantially the same manner as Example 5, and difference is only that: mordant used is the yttrium nitrate by 48.5wt%
(Y(NO3)3), the cerous nitrate (Ce (NO of 51wt%3)3), the ferrous sulfate (FeSO of 0.5wt%4) composition, with the gross weight of mordant
On the basis of amount.
Comparative example 6
Preparation process is substantially the same manner as Example 5, and difference is only that: the cerous carbonate in mordant is substituted for cerium oxide.
Comparative example 7
Preparation process is substantially the same manner as Example 5, and difference is only that: the yttrium oxide in mordant is substituted for lanthana.
Comparative example 8
Preparation process is substantially the same manner as Example 5, and difference is only that: the yttrium oxide in mordant is substituted for lanthanum chloride, carbon
Sour cerium is substituted for cerium chloride.
Comparative example 9
Preparation process is substantially the same manner as Example 5, and difference is only that: the pH value of mordanting bath is 4 in step 2)；In step 3)
The concentration of dye liquor is 8wt.%；The dosage of mordant is 0.4g/L in step 4).
Comparative example 10
Preparation process is substantially the same manner as Example 5, and difference is only that: the pH value of mordanting bath is 11 in step 2)；Step 3)
The concentration of middle dye liquor is 32wt.%；The dosage of mordant is 2.2g/L in step 4).
Comparative example 11
According to the conventional dyeing process of CN01177542A embodiment 3, i.e., not comprising step 1) and 2), and use and this Shen
Please 5 equivalent of embodiment mixed chlorinated rare earth, (be not introduced into mordant by mordant of the mixture of lanthanum chloride and cerium chloride
Ferrous sulfate).
Performance test and test result
Respectively to the dye-uptake of dyeing of real silk fabric obtained by embodiment 1-5, comparative example 1-11 dyeing, resistance to soap
Color fastness, colour fastness to rubbing, colour fastness to perspiration, color fastness to hot pressing, weathering color fastness are tested, test result such as table
Shown in 1.
Fastness to soaping: it is surveyed referring to GB/T 3921-2008 " textile color stability test fastness to soaping "
Examination.
Colour fastness to rubbing: it is surveyed referring to GB/T 3920-2008 " textile color stability test colour fastness to rubbing "
Examination.
Colour fastness to perspiration: it is surveyed referring to GB/T 3922-2013 " textile color stability test colour fastness to perspiration "
Examination.
Color fastness to hot pressing: it is surveyed referring to GB/T 6152-1997 " textile color stability test color fastness to hot pressing "
Examination.
Weathering color fastness: it is tested referring to GB/T 8427-2008 " textile color stability test weathering color fastness ".
Table 1- performance test data
It can be seen that the application by the way that dyeing condition is groped and improved from the test result of table 1, especially adopt
With the mordant with specific composition, so that there is raising beyond expectation in dye-uptake and every color fastness；And it will be real
Example 5 is applied compared with comparative example 1-8 and 11, has also been well demonstrated that each component in mordant used herein-yttrium oxide (Y2O3)、
Cerous carbonate (Ce2(CO3)3) and ferrous sulfate (FeSO4) between produce synergistic function really.
In text of the statement, various publications are referred to.Disclosures of these publications full text is accordingly with reference side
During formula is incorporated herein, so that compound, composition and method described herein is described more fully with.
Various modifications and change can be made to compound described herein, composition and method.In view of specification and
The practice of compound, composition and method disclosed in the present application, compound described herein, composition and method it is other
Aspect will be evident.Specification and example are intended to be considered as illustrative.
Obviously, the above embodiments are merely examples for clarifying the description, and does not limit the embodiments.It is right
For those of ordinary skill in the art, can also make on the basis of the above description it is other it is various forms of variation or
It changes.There is no necessity and possibility to exhaust all the enbodiments.And it is extended from this it is obvious variation or
It changes still within the protection scope of the invention.
Claims (7)
1. a kind of method dyed using rhizome of cyrtomium Natural Dye on Silk Fabric, is included the following steps:
1) real silk fabric the pretreatment of real silk fabric: is impregnated into about 5-20min in about 45-65 DEG C of hot water；
2) pre- mordant dyeing processing: by mordant preparation mordanting bath soluble in water, the pH value of mordanting bath is about 5-10, after investment pretreatment
Real silk fabric, be warming up to about 50~95 DEG C with the heating rate of about 1-5 DEG C/min, keep the temperature about 15~60min；
3) dye: by rhizome of cyrtomium natural dye preparation dye liquor soluble in water, the pH value of dye liquor is about 5-10, and investment is handled through pre- mordant dyeing
Real silk fabric, bath raio is about 1:10~1:50, then is warming up to about 70~95 DEG C with the heating rate of about 1-5 DEG C/min, heat preservation
About 30~120min；After stopping heating, dye liquor temperature is down to about 50-60 DEG C；
4) mordant dyeing is handled afterwards: mordant being added into dye liquor and constant temperature keeps about 20-40min, is subsequently reduced to room temperature；
5) post-process: mordant dyeing treated real silk fabric after taking-up is first washed it, is dried, then soaped, washed,
It is dry.
2. colouring method according to claim 1, the mordant is the mixture of rare earth compound and ferrous sulfate,
Its by about 40-55wt% yttrium oxide (Y2O3), the cerous carbonate (Ce of about 45-60wt%2(CO3)3), the sulphur of about 0.5-1.0wt%
Sour ferrous iron (FeSO4) composition, on the basis of the total weight of mixture.
3. colouring method according to claim 1, the temperature of hot water is preferably from about 50-60 DEG C in the step 1)；It impregnates
Time is preferably from about 8-18min.
4. colouring method according to claim 1, the bath raio of mordanting bath is about 1:10~1:60 in the step 2)；Mordant dyeing
The dosage of agent is about 0.3-1.5g/L, on the basis of the volume of mordanting bath.
5. colouring method according to claim 1, the pH value of mordanting bath is preferably from about 6-9 in the step 2)；Heating speed
Rate is preferably from about 2-4 DEG C/min；The holding temperature of pre- mordant dyeing processing is preferably 60-80 DEG C；Soaking time is preferably 20-50min.
6. colouring method according to claim 1, the bath raio of dye liquor is preferably from about 1:15~1:40 in the step 3).
7. colouring method according to claim 1, the dosage of mordant is about 0.5-2.0g/L in the step 4), with dye
On the basis of the volume of liquid.
Priority Applications (1)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| CN201811032289.XA CN109162119A (en) | 2018-09-05 | 2018-09-05 | A kind of natural plant dye and its application in dyeing and printing process |
Applications Claiming Priority (1)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| CN201811032289.XA CN109162119A (en) | 2018-09-05 | 2018-09-05 | A kind of natural plant dye and its application in dyeing and printing process |
Publications (1)
| Publication Number | Publication Date |
|---|---|
| CN109162119A true CN109162119A (en) | 2019-01-08 |
Family
ID=64894095
Family Applications (1)
| Application Number | Title | Priority Date | Filing Date |
|---|---|---|---|
| CN201811032289.XA Pending CN109162119A (en) | 2018-09-05 | 2018-09-05 | A kind of natural plant dye and its application in dyeing and printing process |
Country Status (1)
| Country | Link |
|---|---|
| CN (1) | CN109162119A (en) |
Citations (3)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN101177542A (en) * | 2007-11-16 | 2008-05-14 | 浙江理工大学 | Method for preparing aspidium rhizoma natural dye and product thereof |
| KR100868335B1 (en) * | 2007-06-05 | 2008-11-12 | 이문순 | A process of dyeing using loess |
| CN107059442A (en) * | 2017-06-21 | 2017-08-18 | 河南工程学院 | Utilize the method for gardenia blue pigment dyeing cotton fabric |
-
2018
- 2018-09-05 CN CN201811032289.XA patent/CN109162119A/en active Pending
Patent Citations (3)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| KR100868335B1 (en) * | 2007-06-05 | 2008-11-12 | 이문순 | A process of dyeing using loess |
| CN101177542A (en) * | 2007-11-16 | 2008-05-14 | 浙江理工大学 | Method for preparing aspidium rhizoma natural dye and product thereof |
| CN107059442A (en) * | 2017-06-21 | 2017-08-18 | 河南工程学院 | Utilize the method for gardenia blue pigment dyeing cotton fabric |
Non-Patent Citations (3)
| Title |
|---|
| 丁彤: "《中国化工产品大全 上》", 31 October 1994, 化学工业出版社 * |
| 中华文化通志编委会: "《中华文化通志 纺织与矿冶志》", 31 October 1998, 上海人民出版社 * |
| 韩长日: "《精细无机化学品制造技术》", 31 August 2008, 科技文献出版社 * |
Similar Documents
| Publication | Publication Date | Title |
|---|---|---|
| Jose et al. | Chickpea husk–A potential agro waste for coloration and functional finishing of textiles | |
| JP3179522B2 (en) | Dyed textile products and their production | |
| CN102634994A (en) | Ecological preparation method for anti-ultraviolet wool and silk textile based on granatum | |
| CN102587153A (en) | Method for dyeing silk broadcloth by using plant dye solution extracted from lily | |
| CN105040472A (en) | Clothing dyed by medicinal plants with health efficacy and fabrication method | |
| CN102767098B (en) | Preparation method of isatis root tie-dyed fabrics | |
| CN105780533A (en) | Dyeing method for textile containing enzymatic tea pigments | |
| CN105062130A (en) | Preparation method of wild chrysanthemum natural dye and preparation of anti-bacterial textiles adopting wild chrysanthemum natural dye | |
| CN106320001A (en) | Method for dyeing wool by myrobalan pigment | |
| CN105484019A (en) | Antibacterial printing and dyeing technology for blended fabric | |
| CN100554571C (en) | The method of crowndaisy chrysanthemum vegetable colour dyeing wool and COTTON FABRIC | |
| CN113737544B (en) | Dyed fabric and method for producing the same | |
| CN104233860A (en) | Process for ferric salt after-mordanting of real silk fabric by using henna pigment | |
| CN102561057A (en) | Method of improving dyeing property of natural dye for cotton fabrics by using sericin | |
| CN105780534B (en) | The technique dyed using myrobalan's pigment to silk fabric | |
| WO2004072182A2 (en) | A novel method of dyeing the textile article from medicinally rich herbs | |
| CN109235089B (en) | Application of natural plant dye in printing and dyeing process | |
| CN109162119A (en) | A kind of natural plant dye and its application in dyeing and printing process | |
| CN110669351A (en) | Preparation method of mango tree leaf dye solution, mango tree leaf dye solution and application of mango tree leaf dye solution in cotton fabric dyeing | |
| CN110607703A (en) | Natural dye formula capable of dyeing green on textile and dyeing method | |
| CN109021611A (en) | A kind of extracting method and its application of natural plant dye | |
| CN104233862A (en) | Process for aluminum salt pre-mordanting and after-dyeing for real silk fabric by using henna pigment | |
| CN114182542A (en) | Method for dyeing green by vegetable dye one-bath process | |
| CN108086017B (en) | Method for dyeing acrylic fabric by barberry plant dye | |
| JP3144863B2 (en) | Dyed textile products and their production |
Legal Events
| Date | Code | Title | Description |
|---|---|---|---|
| PB01 | Publication | ||
| PB01 | Publication | ||
| SE01 | Entry into force of request for substantive examination | ||
| SE01 | Entry into force of request for substantive examination | ||
| RJ01 | Rejection of invention patent application after publication |
Application publication date: 20190108 |
|
| RJ01 | Rejection of invention patent application after publication |