KR100868335B1 - A process of dyeing using loess - Google Patents

A process of dyeing using loess Download PDF

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KR100868335B1
KR100868335B1 KR1020070054927A KR20070054927A KR100868335B1 KR 100868335 B1 KR100868335 B1 KR 100868335B1 KR 1020070054927 A KR1020070054927 A KR 1020070054927A KR 20070054927 A KR20070054927 A KR 20070054927A KR 100868335 B1 KR100868335 B1 KR 100868335B1
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ocher
cloth
dyeing
water
mordant
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KR1020070054927A
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Korean (ko)
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이문순
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이문순
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    • DTEXTILES; PAPER
    • D06TREATMENT OF TEXTILES OR THE LIKE; LAUNDERING; FLEXIBLE MATERIALS NOT OTHERWISE PROVIDED FOR
    • D06PDYEING OR PRINTING TEXTILES; DYEING LEATHER, FURS OR SOLID MACROMOLECULAR SUBSTANCES IN ANY FORM
    • D06P1/00General processes of dyeing or printing textiles, or general processes of dyeing leather, furs, or solid macromolecular substances in any form, classified according to the dyes, pigments, or auxiliary substances employed
    • D06P1/34General processes of dyeing or printing textiles, or general processes of dyeing leather, furs, or solid macromolecular substances in any form, classified according to the dyes, pigments, or auxiliary substances employed using natural dyestuffs
    • DTEXTILES; PAPER
    • D06TREATMENT OF TEXTILES OR THE LIKE; LAUNDERING; FLEXIBLE MATERIALS NOT OTHERWISE PROVIDED FOR
    • D06PDYEING OR PRINTING TEXTILES; DYEING LEATHER, FURS OR SOLID MACROMOLECULAR SUBSTANCES IN ANY FORM
    • D06P1/00General processes of dyeing or printing textiles, or general processes of dyeing leather, furs, or solid macromolecular substances in any form, classified according to the dyes, pigments, or auxiliary substances employed
    • D06P1/36General processes of dyeing or printing textiles, or general processes of dyeing leather, furs, or solid macromolecular substances in any form, classified according to the dyes, pigments, or auxiliary substances employed using mordant dyes ; using metallisable dyes

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  • Engineering & Computer Science (AREA)
  • Textile Engineering (AREA)
  • Coloring (AREA)

Abstract

Loess dyeing method is provided to increase an adhesive force of particles of the loess and to enhance a washing durability of the loess dyeing cloth by using a soy juice and milk as a mordant at a pre-treatment process and a dye process and using charcoal and salt, and alum as the mordant at post-treatment process and to maintain inherent colors of loess after washing. Cloth is refined and dried. A pre-mordant is manufactured by mixing milk, soy juice and water. A mixing weight rate of the milk, the soy juice and the water is 2:1:40. The cloth is put into pre-mordant and dried by sunshine. The dried cloth is dried in the sunshine after putting the dried cloth into the loess water in which salt of 70~100°C is dissolved and fingering the dried cloth. The cloth is dried by the sunshine again after putting the cloth again into a middle-mordant mixing the milk, the soy juice and the loess water and fingering the cloth a few times. The cloth is dipped in the mordant and boiled for 5~7 hours after mixing the cloth into charcoal powder, salt, and alum into the 40L of loess water. The cloth is dried in the sunshine by rinsing the cloth for 7~8 times.

Description

황토 염색방법{A process of dyeing using loess}A process of dyeing using loess

본 발명은 황토 염색방법에 관한 것으로, 더욱 상세하게는 황토를 염색하기 위해서 선매염제와 중매염제, 후매염제를 별도로 제조하고 이를 황토염색의 각 단계별로 사용함으로써 원단의 구석구석에 황토입자의 흡착성을 좋게 하여 견뢰도를 높일 수 있도록 한 황토 염색방법에 관한 것이다.The present invention relates to a method for dyeing ocher, and more particularly, in order to dye ocher, the pre- or mid-morning agent and the post-moring agent are separately prepared and used for each step of the ocher dyeing so that the adsorbability of the ocher particles in every corner of the fabric. It relates to a method for dyeing ocher to improve the fastness by improving.

황토염색은 오래전부터 전해져온 전통 염색방법으로, 황토 자체가 우리 조상이 주변에서 매우 쉽게 구할 수 있는 염색재료였을 뿐만 아니라 염색방법이 매우 손쉬워 널리 활용되었다. 그러나 종래의 황토염색방법은 단순히 황토를 갠 물에 단순히 천연섬유를 담그다 꺼내는 정도에 불과한 것으로, 결국 붉은 색만 물들여진 것일 뿐, 황토입자가 섬유의 올 사이에 고루 염착됨으로써 황토가 가지는 인체에 미치는 긍정적인 효과를 기대하기란 곤란한 것이다.Ocher dyeing is a traditional dyeing method that has been handed down for a long time. Ocher itself was not only a dyeing material that our ancestors can obtain very easily, but also the dyeing method was very easy and widely used. However, the conventional ocher dyeing method is merely to immerse the natural fiber in the ocher water and take it out. Finally, only the red color is dyed. It is difficult to expect phosphorus effect.

황토는 석영 40~80%, 장석과 운모 10~20%, 탄산염광물 5~35%, 실트 2~4%등의 조성으로 이루어진 광물로, 붉은 색을 띄고 있고, 화학성분은 실리카가 50~60%, 알 루미나는 8~12%, 3가 산화철은 2~4%, 2가 산화철은 0.8~1.1%, 산화칼슘은 4~16%, 산화마그네슘은 2~6%, 약 0.5%의 산화티탄과 산화망간으로 구성되어 있으며, 수분함량이 10~15%정도로 이루어진 것이다.Ocher is a mineral composed of 40 to 80% of quartz, 10 to 20% of feldspar and mica, 5 to 35% of carbonate mineral, and 2 to 4% of silt. %, Alumina 8-12%, trivalent iron oxide 2-4%, divalent iron oxide 0.8-1.1%, calcium oxide 4-16%, magnesium oxide 2-6%, about 0.5% titanium oxide It is composed of manganese oxide, and water content is about 10 ~ 15%.

상기한 황토는 스스로 습도조절능력이 우수하고 원적외선을 방사함으로써 인체에 매우 유익한 재료이며, 다양한 무기물과 효소의 작용에 의해 수질 및 토양개선 및 치료, 미용효과 등의 효능이 알려져 있고, 천연 염색재료이므로 알레르기 및 기타 피부질환의 우려가 없고 피부와 친화력이 우수하므로 피부의 유연성 증대 및 모공의 노폐물제거, 해독작용 등의 효능이 알려지면서 최근에는 건강상품으로 더욱 각광을 받고 있다. The above-mentioned ocher is a material that is very beneficial to the human body by having excellent humidity control ability and radiating far infrared rays, and it is known to improve water quality, soil improvement, treatment and cosmetic effects by the action of various inorganic substances and enzymes, and is a natural dyeing material. There is no fear of allergies and other skin diseases, and it has excellent affinity with the skin, thus increasing the flexibility of the skin, removing the wastes of the pores, and detoxifying effects such as the effects of health products.

그러나 종래의 황토염색방법은 황토가 가지는 색상이 천에 물든 것에 불과한 것이어서 엄밀한 의미에서의 황토염색이라고 하기에는 곤란하며, 황토입자가 고르게 섬유의 올 사이사이에 분포되어 황토의 순기능을 그대로 살릴 수 있는 황토염색에 대한 연구는 많지않다.However, the conventional ocher dyeing method is difficult to be called ocher dyeing in the strict sense because the color of the ocher is only colored with cloth, and the ocher particles are evenly distributed between all the fibers of the ocher to preserve the pure function of the ocher. There is not much research on staining.

물론 종래에도 공개특허 제 99-38571호 및 공개특허 제 99-65741호와 같이 황토분말을 이용한 섬유의 염색방법이 안출된 바 있으나, 전자는 수비법 또는 바람에 의해 분리방법에 의하여 황토분을 분리하여 0.005mm 이하의 입경을 갖는 미세 황토분 만을 채취하여 이를 물에 현탁시켜 황토염욕을 제조하고, 상기 황토염욕을 가열하여 염욕의 온도를 90℃이상으로 유지하면서 섬유를 침지시켜 5-10분간 교반하여 황토분을 섬유상에 염착시킨다음 염욕으로 부터 염착된 섬유를 건져내어 건조한 후, 이를 물: 수분산성 유기점착재에 넣어 침적시킨다음 다시 건조시켜서 섬유 에 황토 염색하는 것을 특징으로 하는 것이나, 이는 앞에서 언급한 바와 같이 종래 구전되어 내려오는 전통적인 황토염색방법에 약간의 염색기술만을 가미한 수준에 불과한 것이다. 그나마 상기한 방법은 섬유에 황토분말을 화학성분의 섬유고착제로 고착하는 방법으로, 이는 황토를 섬유에 피복하는 방법이지 엄밀하게는 황토염색이라 할 수 없는 것이다. Of course, in the prior art, the dyeing method of the fiber using the ocher powder has been devised, as disclosed in Korean Patent Nos. 99-38571 and 99-65741, but the former separates the ocher powder by a separation method by a defensive method or wind. Only the fine ocher powder having a particle diameter of 0.005 mm or less is taken and suspended in water to prepare an ocher salt bath.Then the ocher salt bath is heated to immerse the fiber while maintaining the temperature of the salt bath at 90 ° C. or above, and stirring for 5-10 minutes. Dyeing the ocher powder onto the fiber, drying the dyeed fiber from the dye bath, and depositing it in a water: water-dispersible organic adhesive, and then drying it again to dye the fiber ocher. As mentioned, the traditional ocher dyeing method, which is traditionally oral, is only a level of dyeing technique. However, the method described above is a method in which the ocher powder is fixed to the fiber with a chemical fiber fixing agent, which is a method of coating the ocher on the fiber, which is not strictly referred to as ocher dyeing.

후자는 상기한 종래의 황토염색방법을 보다 구체화하긴 하였으나, 이 역시 전자의 황토염색방법에 생지원단을 양이온화 되도록 전처리하는 단계를 추가하는 것 외에는 새로운 방법이라 할 수 없는 것이다. 이처럼 종래의 황토분을 이용한 섬유의 염색방법들은 황토염색단계에서는 황토가 섬유에 완전히 염착되지 못하였다가 후처리단계에서 섬유고착제에 의해 황토가 섬유에 고착되도록 하는 방법을 구사하는 것으로, 단순히 물과 미세한 황토분말을 섞었다고 해서 황토자체가 황토염료화 하는 것이 아니고, 또한 황토염료가 아닌 황토물에 천연섬유를 넣고 끓였다고 해서 황토염색이 되는 것은 아니기 때문이다. 결국 종래의 황토염색방법들은 실제 황토염색에서 가장 중요한 황토를 염착시키는 방법을 전혀 알지 못하는 상태에서 섬유에 황토를 염색하려고 하다 보니 결국 섬유고착제를 사용하여 황토분말을 섬유에 고착시키는 염색 아닌 염색방법을 구사하게 된 것이다. The latter is more specific to the conventional loess dyeing method described above, but it is also a new method other than adding the pretreatment step to the cationization of the bio-support stage to the former loess dyeing method. Thus, conventional dyeing methods of the fiber using ocher powder are a method in which ocher is not completely dyed to the fiber in the ocher dyeing step, and the ocher is fixed to the fiber by the fiber fixing agent in the post-treatment step. Mixing the fine ocher powder does not cause the ocher itself to become ocher dye, and it does not mean ocher dyeing by putting natural fiber in the ocher to be boiled instead of the ocher dye. As a result, conventional ocher dyeing methods do not know how to dye ocher which is the most important in ocher dyeing, and try to dye ocher to fibers. Therefore, dyeing method of dyeing ocher powder to fiber using fiber fixing agent is used. I'm good at it.

이처럼 종래의 황토염색방법들은 천연황토염색이라 할 수 없는 것이며, 화학성분인 섬유고착제를 사용하므로 자연에 가장 가까워야 할 황토염색이 결국 인공재료를 이용한 황토 피복이 되어 황토 천연 염색으로 인해 기대되는 황토가 인체에 미치는 유익한 효과를 기대할 수 없어 천연황토로 염색된 천 및 섬유를 요구하는 소비자들의 욕구에 부응할 수 없는 폐단을 갖는 것이며, 또한 종래의 황토염색방법들은 섬유고착제에 의해 황토분말을 섬유의 표면에 피복만 한 상태이므로 시간이 흐르거나 세탁시에는 염색이 쉬 빠지게 되는 단점을 갖는 것이다. As such, conventional ocher dyeing methods cannot be called natural ocher dyeing, and the ocher dyeing, which should be closest to nature, becomes the ocher coating using artificial materials, and thus the ocher dyeing is expected due to natural dyeing. Does not expect a beneficial effect on the human body, and has a closed end that cannot meet the needs of consumers who require cloth and fibers dyed with natural loess. Since only the surface is coated, it has a disadvantage in that dyeing becomes easy when time passes or when washing.

따라서 본 발명은 상기와 같은 문제점을 해결하기 위하여 안출된 것으로, 본 발명 황토 염색방법은 전처리 및 염색공정에는 매염제로써 콩즙과 우유를 사용하고 후처리 공정에는 매염제로 숯과 소금, 백반을 사용함으로써 염색하고자 하는 천의 올과 올 사이에 황토입자의 부착력을 높일 수 있도록 함으로써 황토염색 천의 세탁 견뢰도를 높이고 황토의 고유한 색상이 세탁 이후에도 유지될 수 있도록 하기 위한 황토염색방법을 제공하는 데 그 목적이 있다.Therefore, the present invention has been devised to solve the above problems, the present invention, the dyeing method of the ocher dyeing by using soy juice and milk as a mordant in the pre-treatment and dyeing process and using charcoal, salt, alum as a mordant in the post-treatment process. The purpose of the present invention is to provide an ocher dyeing method for increasing the fastness of washing of ocher dyeing cloth by allowing the adhesion of ocher particles between all and all of the cloth to be maintained, and to maintain the unique color of ocher even after washing. have.

상기의 목적을 달성하기 위한 본 발명은 먼저 원단을 정련하고 이를 건조하는 단계와; 우유와 콩즙, 물을 중량비로 2:1:40로 혼합하여 선매염제를 제조하는 단계와; 상기 선매염제에 원단을 넣고 주물러서 햇볕에 건조하는 단계와; 상기 건조된 원단을 70~100℃의 소금이 용해된 황토물에 넣고 수회 주무른 뒤 햇볕에 건조하는 것을 반복하는 단계와; 상기 원단을 다시 우유와 콩즙, 황토물을 중량비로 1:1:40으로 혼합한 중매염제에 넣고 수회 주무른 후 다시 햇볕에 건조하는 것을 반복하는 단계와; 상기 원단을 황토물에 숯분말, 소금, 백반을 중량비로 30~70:2~10:2~10으로 넣고 혼합한 후매염제에 담궈 5~7시간 삶는 단계와; 상기 원단을 7~8번 정도 헹구어 이를 햇볕에 건조하는 단계;로 이루어진다.The present invention for achieving the above object comprises the steps of first refining the fabric and drying it; Preparing a pre- mordant by mixing milk, soybean juice and water in a weight ratio of 2: 1: 40; Putting the fabric in the pre-morning agent and rubbing to dry in the sun; Putting the dried fabric into 70 to 100 ° C. in which the salt is dissolved ocher, and rubbing several times and then drying in the sun; Putting the fabric back into a medium mordant mixed with milk, soybean juice, and ocher in a weight ratio of 1: 1: 40, and then rubbing several times and drying again in the sun; Charcoal powder, salt, and alum in ocher water in a weight ratio of 30 to 70: 2 to 10: 2 to 10, mixed and then soaked in mordant for 5 to 7 hours; Rinsing the fabric 7 to 8 times and drying it in the sun; consists of.

상기 단계 중 정련은 면, 모시, 마, 명주와 같은 염색하고자 하는 원단에 함유되어 있는 각종 유기물, 불순물, 먼지 등을 제거하기 위한 공정으로, 염착을 빠르게 하고 시간을 보충하기 위하여 필요한 공정이다. 이때 정련시 화학적인 정련제를 사용하면 섬유에 손상이 오고 환경오염이 심각하기 때문에 정련공정은 별도 준비된 잿물을 물에 섞되 사용되는 물은 연수를 사용함이 바람직하다.Refining of the step is a process for removing various organic matter, impurities, dust, etc. contained in the fabric to be dyed, such as cotton, ramie, hemp, silk, etc., is a process necessary to speed up the dyeing and replenish time. At this time, if chemical refining agent is used during the refining, the fiber is damaged and environmental pollution is serious, so the refining process is preferably mixed with lye prepared in water, and soft water is used for the water used.

상기 정련에 사용되는 잿물은 알카리 성분으로 표백제 역할을 하는 것으로, 이의 제조는 볏짚, 메밀대 등을 태워서 재를 모은 후 용기에 볏짚을 깔고 40~50℃의 따뜻한 물을 붓게 되면 얻어지는 PH 10-12의 액체이다.The lye used in the refining acts as a bleach as an alkali ingredient, the preparation of which is obtained by burning rice straw, buckwheat straw, etc. after collecting ashes in a container and pouring warm water at 40-50 ° C. Of liquid.

상기 황토물은 질 좋은 황토를 용기에 넣고 연수를 가득 부어 처음에는 손으로 잘 비벼 입자를 가늘게 하고 물에 뜨는 불순물질들은 건져낸 후 3~4시간 유지하는 수비과정을 거쳐 얻는다.The ocher is obtained through a defensive process of putting high quality ocher in a container, filling it with soft water, first rubbing the particles well by hand, and removing impurities from the water and keeping them for 3 to 4 hours.

본 발명에 있어 상기 선매염제는 우유와 콩즙, 물을 중량비로 2:1:40로 혼합하여 제조되어 지는데, 상기 선매염제는 다량의 단백질성분을 갖는 콩즙과 우유를 적당량 혼합하여 사용함으로써 공기중의 탄산가스와 화학작용에 의해 물에 대하여 불용성 성질을 갖도록 하였고, 상기 단백질성분으로 인해 염료(황토입자)와 천의 섬유 사이의 흡착력을 강하게 함으로써 견뢰도를 향상시킬 수 있도록 하였다. In the present invention, the pre-sale agent is prepared by mixing milk and soy juice and water in a weight ratio of 2: 1: 40. The pre-sale agent is used by mixing an appropriate amount of soy juice and milk having a large amount of protein in the air. It was made to have an insoluble property in water by the carbon dioxide and the chemical reaction, and to improve the fastness by increasing the adsorption force between the dye (ocher particles) and the fiber of the cloth due to the protein component.

특히 우유에 다량 함유되어있는 "카세인"은 인을 함유하는 단백질로서 칼슘 과 결합 된다. 상기 카세인 칼슘은 수분 중에 미세한 입자로 콜로이드 상태로 분산되는 성질을 갖는 것이어서 염료(황토입자)를 원단의 올과 올 사이에 균일하게 분산흡착함으로써 더욱 우수한 견뢰도를 갖게 하는 것이다.In particular, "casein", which is high in milk, is a phosphorus-containing protein that binds to calcium. The casein calcium has a property of dispersing in a colloidal state as fine particles in water to have a more excellent fastness by uniformly dispersed and adsorbed dye (ocher particles) between all of the fabric.

상기 콩즙은 메주용 콩을 불려 갈아서 건더기는 걸러내고 그 물을 사용할 수도 있으며, 생콩을 갈아 직접 물에 혼합한 다음 건더기만 걸러내고 사용할 수도 있다. The soybean juice may be used to filter the soybeans, filter out the dust, and use the water, or grind the raw soybeans directly into the water, and then filter and use only the dust.

중매염제는 상기 선매염제와는 달리 물이 아닌 황토물에 혼합되어 지는데, 본래는 우유와 황토물만을 2:40의 중량비로 혼합하는 것이 바람직하다.The mordant is mixed with the ocher, not water, unlike the pre-mold, but it is preferable to mix only milk and ocher in a weight ratio of 2:40.

그러나 우유와 황토물이 혼합될 경우는 우유와 물이 혼합되는 경우와는 달리 심한 악취가 발생하기 때문에 작업자들이 작업을 하기 힘들 정도가 되며, 따라서 우유를 절반으로 줄이고 대신 콩즙을 사용한 것이다. However, when milk and ocher are mixed, unlike the case where milk and water are mixed, a bad odor occurs, which makes it difficult for workers to work. Therefore, the milk is cut in half and soybean juice is used instead.

이때 우유와 황토물의 혼합으로 생기는 악취는 우유의 카세인과 황토의 칼슘성분이 반응하는 과정에서 발생되는 것으로 판단된다.At this time, the malodor caused by the mixing of milk and ocher is considered to be generated during the reaction of casein of milk and calcium component of ocher.

후매염제는 황토물에 숯분말, 소금, 백반을 중량비로 30~70:2~10:2~10으로 넣고 혼합함으로써 제조되어 지는데, 상기 숯분말은 산화방지 및 환원작용이 매우 우수한 재료로써, 원단에 황토의 흡착력을 더욱 높여주는 기능을 갖는다.Post-moring agent is prepared by mixing charcoal powder, salt and alum in a weight ratio of 30 ~ 70: 2 ~ 10: 2 ~ 10 in ocher water. The charcoal powder is an excellent material for preventing oxidation and reducing. It has a function to further increase the adsorption power of ocher.

또한 숯은 흡착성, 통기성, 보습성, 배습성, 축열성이 좋을 뿐만 아니라, 음이온과 원적외선을 발생량이 많아 인체에도 유익하다.In addition, charcoal is not only good adsorption, breathability, moisture retention, moisture repellency, heat storage properties, but also generates a lot of negative ions and far infrared rays, which is beneficial to the human body.

소금은 황토물에 첨가하는 것은 황토가 물에 용해되어 콜로이드(colloid) 형태로 되었을 때, 황토 콜로이드가 응집되는 것을 방지하게 되며, 염색의 균일성을 유지하도록 하고, 염색 후에는 황토성분이 피염색물인 원단(섬유)에 강하게 흡착되도록 하기 위해 첨가되어 진다.The addition of salt to the ocher water prevents the ocher colloid from agglomerating when the ocher is dissolved in water to form a colloid, and maintains uniformity of dyeing. It is added to be strongly adsorbed on the fabric (fiber) which is water.

백반은 일반적으로 널리 사용되는 매염제로써 황토의 흡착성 및 견뢰성을 높이기 위해 필요한 성분이다.Alum is a widely used mordant and is a necessary ingredient to increase the adsorption and fastness of loess.

이하 상기 본 발명 황토 염색방법에 대해 바람직한 실시예를 통해서 더욱 상세하게 설명하면 다음과 같다.Hereinafter, the present invention will be described in more detail with reference to preferred examples of the ocher dyeing method.

먼저 황토염색하고자 하는 원단을 정련하고 건조하여야 하는데, 이는 모든 원단이 직조과정에서 기름과 같은 불순물이 묻거나 풀이 먹여진 상태이기 때문에 상기 불순물들을 제거하여 염색이 잘되도록 한다.First, the fabric to be dyed ocher should be refined and dried. This is because all fabrics are impregnated with impurities such as oil or glued in the weaving process, so that the impurities are removed and the dyeing is performed well.

이때 황토염료는 광물성 원료이고, 0.005㎜ 이하의 고운 입자가 천의 올, 즉 씨줄과 날줄 사이에 흡착되어 염색되는 구조여서 원단의 섬유 굵기가 가는 원단을 사용하는 것이 바람직하다.At this time, the ocher dye is a mineral raw material, it is preferable that fine fibers of 0.005 mm or less are adsorbed and dyed between all of the fabric, that is, between the seed and the string, so that the fabric having a thin fiber thickness is preferably used.

다음 우유 2ℓ, 콩즙 1ℓ, 물 40ℓ를 혼합하여 선매염제를 제조하게 되는데, 상기 선매염제에 정련된 원단을 넣고 주물러서 선매염제가 원단에 잘 흡수되도록 한 다음 이를 햇볕에 말린다.Next, milk pretreatment is prepared by mixing 2L of milk, 1L of soybean juice, and 40L of water. The pre-refining agent is added to the pre-rinding agent, and then rubbed so that the pre-rinding agent is absorbed well by the fabric and dried in the sun.

다음 약간의 소금이 용해된 황토물 40ℓ에 전단계에서 건조된 원단을 넣고 3번 주무르고 1번 건조하는 작업을 반복한다. 이때 반복은 균일한 염색을 위해 8~12회가 바람직하다.Then, put the fabric dried in the previous step in 40 liters of the slightly dissolved ocher soil, rub three times and repeat the drying once. The repetition is preferably 8 to 12 times for uniform dyeing.

상기 황토물은 물과 황토의 중량비로 3:1~5:1로 이루어지며, 황토물 40ℓ에 첨가되는 소금의 양은 20~100g가 바람직하다.The loess is composed of 3: 1 to 5: 1 by weight ratio of water and loess, and the amount of salt added to 40 l of loess is preferably 20 to 100 g.

이때 상기 황토물의 온도는 70~100℃를 유지함이 바람직한데, 이는 황토물의 온도가 높을수록 원단의 섬유조직이 부드러워져 염색이 용이하게 이루어지기 때문이다. 또 상기 원단을 황토물에 넣고 수회 주무른 후 이를 햇볕에 건조하는 작업을 반복하는 이유는 매염제가 원단에 균일하게 분포되도록 하고, 이로 인해 황토염색 또한 원단에 고르게 이루어지도록 함으로써 균질한 색상의 원단을 얻기 위한 것이다.At this time, it is preferable to maintain the temperature of the ocher 70 ~ 100 ℃, because the higher the temperature of the ocher is softer the fabric of the fabric is dyed easily. The reason why the fabric is put in ocher water and kneaded several times and then dried in the sun is that the mordant is uniformly distributed on the fabric, and thus the ocher dye is evenly made on the fabric to obtain a homogeneous fabric. It is for.

상기와 같이 선매염작업이 완료되면, 상기 원단을 다시 우유 1ℓ, 콩즙 1ℓ, 황토물 40ℓ을 혼합하여 제조된 중매염제에 넣고 3번 주무르고 1번 건조하는 작업을 반복한다. 이때 반복은 균일한 염색을 위해 4~5회가 바람직하다.When the pre-soldering work is completed as described above, the fabric is put again into the medium mordant prepared by mixing 1 l of milk, 1 l of soybean juice, 40 l of loess, and kneading three times and repeating the drying once. The repetition is preferably 4 to 5 times for uniform dyeing.

상기와 같이 중매염작업이 완료되면, 상기 원단을 40ℓ의 황토물에 숯분말, 소금, 백반을 중량비로 30~70:2~10:2~10으로 넣고 혼합한 후매염제에 담궈 5~7시간 삶는다. 이때 40ℓ의 황토물의 첨가되는 숯분말, 소금, 백반의 양은 각각 300~700g, 소금 20~100g, 백반 20~100g 씩을 넣어 혼합하였다.When the medium salting operation is completed as described above, put the fabric in a weight ratio of 30 ~ 70: 2 ~ 10: 2 ~ 10 charcoal powder, salt and alum in 40 l of ocher water, and then mixed in a mordant for 5 to 7 hours. Boil At this time, the amount of charcoal powder, salt, and alum added to 40 l of ocher was mixed in each of 300 to 700 g, 20 to 100 g of salt, and 20 to 100 g of alum.

마지막으로 후매염작업이 완료된 원단을 맑은 물에 7~8번 정도 헹구고 이를 햇볕에 말림으로써 염색작업은 완료되어 진다.Lastly, the dyeing process is completed by rinsing the fabric after the post-dyeing operation is done 7-8 times in clear water and drying it in the sun.

이처럼 본 발명은 황토를 염색하기 위해서 선매염제와 중매염제, 후매염제를 별도로 제조하고 이를 황토염색의 각 단계별로 사용함으로써 원단의 구석구석에 황 토입자의 흡착성을 좋게 하였으며, 이로 인해 종래 세탁 견뢰성이 떨어지는 황토염색의 세탁 견뢰성을 현저히 높일 수 있는 것이다.As described above, the present invention prepares pre-seeding agent, heavy-medium dyeing agent, and post-moring agent separately to dye the yellow soil, and uses it for each step of the yellow soil dyeing to improve the adsorption of the yellow earth particles at every corner of the fabric, thereby improving the conventional laundry fastness. It is possible to significantly increase the washing fastness of the falling ocher dyeing.

또한 우유를 매염제로 사용함으로써 황토염색이 원단 전체에 균일하게 이루어지도록 함으로써 짙은 황토색상의 황토염색 원단을 얻을 수 있어 황토염색 원단의 상품성을 높일 수 있는 매우 유용한 발명인 것이다.In addition, by using milk as a mordant to make the ocher dyeing uniformly throughout the fabric to obtain a yellow ocher dyeing fabric of a dark ocher color is a very useful invention that can increase the commerciality of the ocher dyeing fabric.

Claims (1)

원단을 정련하고 이를 건조하는 단계와; Refining the fabric and drying it; 우유와 콩즙, 물을 중량비로 2:1:40로 혼합하여 선매염제를 제조하는 단계와; Preparing a pre- mordant by mixing milk, soybean juice and water in a weight ratio of 2: 1: 40; 상기 선매염제에 원단을 넣고 주물러서 햇볕에 건조하는 단계와; Putting the fabric in the pre-morning agent and rubbing to dry in the sun; 상기 건조된 원단을 70~100℃의 소금이 용해된 황토물에 넣고 수회 주무른 뒤 햇볕에 건조하는 것을 반복하는 단계와;Putting the dried fabric into 70 to 100 ° C. in which the salt is dissolved ocher, and rubbing several times and then drying in the sun; 상기 원단을 다시 우유와 콩즙, 황토물을 중량비로 1:1:40으로 혼합한 중매염제에 넣고 수회 주무른 후 다시 햇볕에 건조하는 것을 반복하는 단계와; Putting the fabric back into a medium mordant mixed with milk, soybean juice, and ocher in a weight ratio of 1: 1: 40, and then rubbing several times and drying again in the sun; 상기 원단을 황토물 40ℓ에 숯분말, 소금, 백반을 중량비로 30~70:2~10:2~10으로 넣고 혼합한 후매염제에 담궈 5~7시간 삶는 단계와; Charcoal powder, salt, and alum in 40 l of ocher water in a weight ratio of 30 to 70: 2 to 10: 2 to 10, mixed and soaked in mordant for 5 to 7 hours; 상기 원단을 7~8번 헹구어 이를 햇볕에 건조하는 단계;로 이루어짐을 특징으로 하는 황토 염색방법.Rinsing the fabric 7 to 8 times and drying it in the sun; Ocher dyeing method characterized in that consisting of.
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KR100925103B1 (en) 2008-06-27 2009-11-05 배미희 Filling Material of Bedclothes Having the loess dyeing cocoon
KR20150092833A (en) * 2014-02-06 2015-08-17 주식회사 바이본 Functional natural dyes using titanium dioxide and preparing method of the same
KR20160128495A (en) 2015-04-28 2016-11-08 재단법인나주시천연염색문화재단 Method of improving fastness in mineral dye
CN109162119A (en) * 2018-09-05 2019-01-08 浙江稽山印染有限公司 A kind of natural plant dye and its application in dyeing and printing process

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KR20030078283A (en) * 2002-03-29 2003-10-08 김영만 Process of Natural Dyeing for Fabric
KR200428232Y1 (en) 2006-05-03 2006-10-11 김문현 The yellowish clay cloth Mat to dye in the nature source as the furrows with some ceramic balls to hold

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KR20030078283A (en) * 2002-03-29 2003-10-08 김영만 Process of Natural Dyeing for Fabric
KR200428232Y1 (en) 2006-05-03 2006-10-11 김문현 The yellowish clay cloth Mat to dye in the nature source as the furrows with some ceramic balls to hold

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* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
KR100925103B1 (en) 2008-06-27 2009-11-05 배미희 Filling Material of Bedclothes Having the loess dyeing cocoon
KR20150092833A (en) * 2014-02-06 2015-08-17 주식회사 바이본 Functional natural dyes using titanium dioxide and preparing method of the same
KR101586560B1 (en) * 2014-02-06 2016-01-18 주식회사 바이본 Functional natural dyes using titanium dioxide and preparing method of the same
KR20160128495A (en) 2015-04-28 2016-11-08 재단법인나주시천연염색문화재단 Method of improving fastness in mineral dye
KR101685526B1 (en) * 2015-04-28 2016-12-13 재단법인나주시천연염색문화재단 Method of improving fastness in mineral or charcoal dye
CN109162119A (en) * 2018-09-05 2019-01-08 浙江稽山印染有限公司 A kind of natural plant dye and its application in dyeing and printing process

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