CN108403472B - Detergent composition and application thereof - Google Patents
Detergent composition and application thereof Download PDFInfo
- Publication number
- CN108403472B CN108403472B CN201810347994.2A CN201810347994A CN108403472B CN 108403472 B CN108403472 B CN 108403472B CN 201810347994 A CN201810347994 A CN 201810347994A CN 108403472 B CN108403472 B CN 108403472B
- Authority
- CN
- China
- Prior art keywords
- component
- detergent composition
- acid
- amino acid
- sodium
- Prior art date
- Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
- Active
Links
Classifications
-
- A—HUMAN NECESSITIES
- A61—MEDICAL OR VETERINARY SCIENCE; HYGIENE
- A61K—PREPARATIONS FOR MEDICAL, DENTAL OR TOILETRY PURPOSES
- A61K8/00—Cosmetics or similar toiletry preparations
- A61K8/18—Cosmetics or similar toiletry preparations characterised by the composition
- A61K8/30—Cosmetics or similar toiletry preparations characterised by the composition containing organic compounds
- A61K8/40—Cosmetics or similar toiletry preparations characterised by the composition containing organic compounds containing nitrogen
- A61K8/44—Aminocarboxylic acids or derivatives thereof, e.g. aminocarboxylic acids containing sulfur; Salts; Esters or N-acylated derivatives thereof
- A61K8/442—Aminocarboxylic acids or derivatives thereof, e.g. aminocarboxylic acids containing sulfur; Salts; Esters or N-acylated derivatives thereof substituted by amido group(s)
-
- A—HUMAN NECESSITIES
- A61—MEDICAL OR VETERINARY SCIENCE; HYGIENE
- A61K—PREPARATIONS FOR MEDICAL, DENTAL OR TOILETRY PURPOSES
- A61K8/00—Cosmetics or similar toiletry preparations
- A61K8/18—Cosmetics or similar toiletry preparations characterised by the composition
- A61K8/30—Cosmetics or similar toiletry preparations characterised by the composition containing organic compounds
- A61K8/40—Cosmetics or similar toiletry preparations characterised by the composition containing organic compounds containing nitrogen
- A61K8/44—Aminocarboxylic acids or derivatives thereof, e.g. aminocarboxylic acids containing sulfur; Salts; Esters or N-acylated derivatives thereof
-
- A—HUMAN NECESSITIES
- A61—MEDICAL OR VETERINARY SCIENCE; HYGIENE
- A61K—PREPARATIONS FOR MEDICAL, DENTAL OR TOILETRY PURPOSES
- A61K8/00—Cosmetics or similar toiletry preparations
- A61K8/18—Cosmetics or similar toiletry preparations characterised by the composition
- A61K8/72—Cosmetics or similar toiletry preparations characterised by the composition containing organic macromolecular compounds
- A61K8/84—Cosmetics or similar toiletry preparations characterised by the composition containing organic macromolecular compounds obtained by reactions otherwise than those involving only carbon-carbon unsaturated bonds
- A61K8/86—Polyethers
-
- A—HUMAN NECESSITIES
- A61—MEDICAL OR VETERINARY SCIENCE; HYGIENE
- A61Q—SPECIFIC USE OF COSMETICS OR SIMILAR TOILETRY PREPARATIONS
- A61Q19/00—Preparations for care of the skin
- A61Q19/10—Washing or bathing preparations
-
- A—HUMAN NECESSITIES
- A61—MEDICAL OR VETERINARY SCIENCE; HYGIENE
- A61Q—SPECIFIC USE OF COSMETICS OR SIMILAR TOILETRY PREPARATIONS
- A61Q5/00—Preparations for care of the hair
- A61Q5/02—Preparations for cleaning the hair
-
- A—HUMAN NECESSITIES
- A61—MEDICAL OR VETERINARY SCIENCE; HYGIENE
- A61K—PREPARATIONS FOR MEDICAL, DENTAL OR TOILETRY PURPOSES
- A61K2800/00—Properties of cosmetic compositions or active ingredients thereof or formulation aids used therein and process related aspects
- A61K2800/40—Chemical, physico-chemical or functional or structural properties of particular ingredients
- A61K2800/59—Mixtures
- A61K2800/596—Mixtures of surface active compounds
Landscapes
- Health & Medical Sciences (AREA)
- Life Sciences & Earth Sciences (AREA)
- Animal Behavior & Ethology (AREA)
- General Health & Medical Sciences (AREA)
- Public Health (AREA)
- Veterinary Medicine (AREA)
- Birds (AREA)
- Epidemiology (AREA)
- Dermatology (AREA)
- Cosmetics (AREA)
- Detergent Compositions (AREA)
Abstract
The invention discloses a detergent composition and application thereof, wherein the detergent composition comprises the following components: 1-90% (A) N-long chain fatty acyl amino acid and/or its salt and/or N-long chain fatty acyl modified amino acid and/or its salt; 0-5% (B) of one or more selected from polyalcohol fatty acid monoester, fatty alcohol polyether, fatty acid lactate and sorbitan fatty acid ester; 0-5% (C) of a long-chain PEG group hydrophobically modified compound; 0-5% (D) of one or more selected from the group consisting of alkylamide methyl MEA, alkylamide DEA, alkylamide MEA, and alkylamide MIPA. The detergent composition prepared by adding the component (B), the component (C) and the component (D) in a specific compounding ratio into the N-acyl amino acid type surfactant of the N-long-chain fatty acyl amino acid and/or the salt thereof and/or the N-long-chain fatty acyl modified amino acid and/or the salt thereof has proper viscosity, is clear and transparent, can well solve the thickening problem of the amino acid type surfactant, and can be widely used in cosmetics such as cleaning products or shampoo products.
Description
Technical Field
The invention relates to the technical field of biology, and particularly relates to a detergent composition and application thereof.
Background
N-acyl amino acid type surfactants have a similar structure to natural surfactants and a simple structure, and thus exhibit advantages such as low toxicity and excellent biodegradability, and thus are widely used in the field of cosmetics. However, when the amino acid type surfactant is applied to cleaning products, the problem that the thickening is difficult or even impossible, so that the wide application in the cosmetic industry is difficult often occurs.
In order to solve the thickening problem of amino acid type surfactants used in cosmetics such as cleansing products or hair washing products, various manufacturers have attempted to solve the problem by adding various high molecular polymers such as SF-1-like thickeners. However, even when such a thickener is used in a larger amount in cosmetics such as cleansing products or hair washing products, it still cannot achieve a suitable viscosity, and there are also disadvantages in that it is difficult to completely clear the appearance, it is difficult to apply it in use, and the foaming rate is affected.
Disclosure of Invention
In order to solve the above-mentioned problems, a primary object of the present invention is to provide a detergent composition having an appropriate viscosity, which can satisfactorily solve the problem of thickening of an amino acid type surfactant in cosmetics such as a cleansing product or a hair washing product.
The technical scheme adopted by the invention is as follows:
1. a detergent composition is characterized by comprising the following components in percentage by weight:
(A) 1-90% of N-long-chain fatty acyl amino acid and/or salt thereof and/or N-long-chain fatty acyl modified amino acid and/or salt thereof;
(B) 0-5% of one or more selected from polyalcohol fatty acid monoester, fatty alcohol polyether, fatty acid lactate and sorbitan fatty acid ester;
(C) 0-5% of long-chain PEG group hydrophobic modified compound;
(D) 0.1-5% of one or more selected from alkyl amide methyl MEA, alkyl amide DEA, alkyl amide MEA or alkyl amide MIPA.
2. A detergent composition according to claim 1, characterized in that component (B): a component (C): the weight ratio of the component (D) is (0.5-4): 0: (0.5-4), preferably (1-2.5): 0: (1-3).
3. A detergent composition according to claim 1, characterized in that component (B): a component (C): the weight ratio of the component (D) is 0: (0.3-2.5): (0.5-4), preferably 0: (0.5-1.5): (1-3).
4. A detergent composition according to claim 1, characterized in that component (B): a component (C): the weight ratio of the component (D) is (0.5-4): (0.3-2.5): (0.5-4), preferably (1-2.5), (0.5-1.5) to (1-3).
The N-long chain fatty acyl amino acid and/or salt thereof and/or the N-long chain fatty acyl-modified amino acid and/or salt thereof as component (A) in the present invention can be obtained by a known method. For example, the Schotten-Baumann reaction between amino acids and fatty acid halides is a well known method.
As the amino acid of the component (A) of the present invention, acidic amino acids such as glutamic acid and aspartic acid, neutral amino acids such as alanine and threonine, and basic amino acids such as arginine, lysine and ornithine, modified amino acids such as sarcosine and methylalanine, methyltaurine can be used. These amino acids and modified amino acids may be L-isomer, D-isomer, DL-isomer or a mixture of two or more of the above isomers. They may be used alone or in admixture of two or more of the foregoing.
As the fatty acyl group of component (A), branched fatty acyl groups derived from saturated and unsaturated fatty acids having 8 to 22 carbon atoms can be used, and examples of the fatty acids include caprylic acid, capric acid, lauric acid, myristic acid, stearic acid, isostearic acid, palmitic acid, oleic acid, linoleic acid, behenic acid, coconut oil fatty acid, palmitic fatty acid, hydrogenated tallow fatty acid, caprylic acid, undecanoic acid, tridecanoic acid, pentadecanoic acid, heptadecanoic acid, nonadecanoic acid, heneicosanoic acid and the like. They may be used alone or in admixture of two or more of the foregoing. Coconut oil fatty acid, palm kernel oil fatty acid, lauric acid, and myristic acid are particularly preferable in view of excellent foaming ability and foam quality.
The salt of the component (a) is not particularly limited, and examples thereof include inorganic salts, for example, alkali metals such as sodium and potassium, alkaline earth metals such as calcium and magnesium, aluminum and zinc, organic salts, for example, ammonia, organic amines such as monoethanolamine, diethanolamine and triethanolamine, and salts of basic amino acids such as arginine and lysine. They may be used alone or in admixture of two or more of the foregoing. In view of easy availability and workability, salts of alkali metal salts, organic amine salts and basic amino acids are preferable, and salts of sodium, potassium, triethanolamine, arginine and sodium methyltaurate are particularly preferable.
Preferably, the component (a) is selected from one or a mixture of several of sodium cocoamidopropionate, sodium lauroyl sarcosinate, sodium myristoyl sarcosinate, TEA cocoyl glutamate, sodium cocoyl glutamate, disodium cocoyl glutamate, sodium methyl cocoyl taurate, sodium cocoyl methyl taurate, sodium lauroyl methyl aminopropionate, TEA lauroyl methylamino propionate and sodium lauroyl aspartate.
As the fatty acyl group of component (B) in the present invention, branched fatty acyl groups derived from saturated and unsaturated fatty acids having 8 to 22 carbon atoms can be used, and examples of the fatty acids include caprylic acid, capric acid, lauric acid, myristic acid, stearic acid, isostearic acid, palmitic acid, oleic acid, linoleic acid, behenic acid, coconut fatty acid, palmitic fatty acid, hydrogenated tallow fatty acid, caprylic acid, undecanoic acid, tridecanoic acid, pentadecanoic acid, heptadecanoic acid, nonadecanoic acid, heneicosanoic acid and the like. They may be used alone or in admixture of two or more of the foregoing. Lauric acid and oleic acid are particularly preferred.
As the polyol group of component (B) in the present invention, glycerin, propylene glycol, butylene glycol and pentylene glycol can be used, and glycerin, propylene glycol or butylene glycol is particularly preferred.
Preferably, the component (B) is one or more selected from glycerol laurate, glycerol oleate, propylene glycol laurate, propylene glycol oleate, butylene glycol laurate, butylene glycol oleate, laureth-1, laureth-2, laureth-3, laureth-4, laureth lactate and sorbitan laurate.
The degree of polymerization of the long-chain PEG group of component (C) in the present invention may be in the range of 50 to 250, and 60, 120 or 150 is particularly preferred.
As the hydrophobic modifying group of component (C) in the present invention, branched fatty acyl groups or ether groups derived from saturated and unsaturated fatty acids having 8 to 22 carbon atoms can be used. Examples of fatty acids include caprylic acid, capric acid, lauric acid, myristic acid, stearic acid, isostearic acid, palmitic acid, oleic acid, linoleic acid, behenic acid, coconut oil fatty acid, palmitic fatty acid, hydrogenated tallow fatty acid, caprylic acid, undecanoic acid, tridecanoic acid, pentadecanoic acid, heptadecanoic acid, nonadecanoic acid, heneicosanoic acid, and the like. Examples of fatty alcohols include octanol, decanol, lauryl alcohol, myristyl alcohol, stearyl alcohol, isostearyl alcohol, cetyl alcohol, oleyl alcohol, linoleyl alcohol, behenyl alcohol, octanol, undecanol, tridecanol, pentadecanol, heptadecanol, nonadecanol, heneicosanol, and the like. These may be used alone or in admixture of two or more of the foregoing, with stearic acid, palmitic acid, stearyl alcohol and cetyl alcohol being particularly preferred.
Preferably, the component (C) is one or more selected from PEG-150 distearate, PEG-120 methyl glucose dioleate, PEG-120 methyl glucose trioleate, PEG-150 pentaerythritol tetrastearate and ceteareth-60 myristyl glycol.
Preferably, the component (D) is selected from one or a mixture of several of cocamide methyl MEA, cocamide MIPA or cocamide DEA.
The detergent composition of the present invention may contain, in addition to the above-mentioned main components, various suitable components used in general cosmetics, special cosmetics, and the like as appropriate without deteriorating the effect of the present invention. More specifically, oils, surfactants (e.g., amphoteric surfactant cocamidopropyl betaine, nonionic surfactant decyl glucoside, etc.), thickeners, preservatives (e.g., cason), perfumes, ultraviolet absorbers, moisturizers, physiologically active ingredients, antioxidants, anti-inflammatory agents, antibacterial agents, antiperspirants, chelating agents (e.g., disodium EDTA), neutralizing agents, pH adjusting agents (e.g., citric acid), etc., may be included, and the above components may be included in an amount conventionally added to cosmetics, depending on the particular use and form. The detergent composition of the present invention is manufactured by a general method, and may be in the form of liquid, paste, gel, powder, solid, etc. It is suitable for use as a cosmetic for skin, hair, etc.
The invention also provides the application of the detergent composition in cosmetics. The use of the detergent composition of the present invention is not particularly limited, but various cosmetics can be provided. Examples thereof include: cleansing products such as face cleansers (including cleansing foams, liquid gels, moisturizers, etc.), shampoos, make-up removers, and cleansers, base products such as hair treatment agents (including spray products, gel products, other forms of products) and shaving creams (shaving gels, shaving creams, etc.), and the like. In view of the range of use of amino acid-modified amino acids, it is preferably used for cleansing products and hair washing products.
Compared with the prior art, the invention has the following beneficial effects:
the detergent composition prepared by adding the component (B), the component (C) and the component (D) in a specific compounding ratio into the N-acyl amino acid type surfactant of the N-long-chain fatty acyl amino acid and/or the salt thereof and/or the N-long-chain fatty acyl modified amino acid and/or the salt thereof has proper viscosity, is clear and transparent, can well solve the thickening problem of the amino acid type surfactant, and can be widely used in cosmetics such as cleaning products or shampoo products.
Detailed Description
The present invention is further illustrated by the following specific embodiments, but the embodiments of the present invention are not limited by the following examples.
The raw materials used in the examples of the present invention and the comparative examples were commercially available.
The test method comprises the following steps:
method for testing viscosity of detergent composition: brookfiltered DV-C digital viscometer, number 64 rotor, rotation speed 20rpm, body temperature: 25 ℃, reading time: readings were taken 1 minute after start-up.
Test method for transparency of detergent composition: the samples were placed in 100ml clear glass bottles and visually observed at room temperature and in direct sunlight.
Examples 1 to 14 and comparative examples 1 to 12:
according to the formula shown in table 1, according to the mixture ratio of table 1, water, A) N-long chain fatty acyl amino acid and/or salt thereof and/or N-long chain fatty acyl modified amino acid and/or salt thereof, B) one or more of polyalcohol mono fatty acid ester, fatty alcohol polyether, fatty acid lactate and sorbitan fatty acid ester, C) long chain PEG group hydrophobic modified compound and D) one or more selected from alkyl amide methyl MEA, alkyl amide DEA, alkyl amide MEA or alkyl amide MIPA are heated to a proper temperature for dissolution, the mixture is uniformly stirred, the rest materials are added after cooling, water is supplemented to 100% of the formula amount, the mixture is uniformly stirred, the pH is adjusted to a specified range, and then the detergent composition is obtained, wherein the test performance results are shown in table 1.
TABLE 1 compositions of examples and comparative examples and results of performance tests (in weight percent)
TABLE 1
TABLE 2
As can be seen from the examples and comparative examples in Table 1, the detergent composition prepared by adding the components (B), (C) and (D) in specific compound ratio to the N-acyl amino acid type surfactant of the N-long-chain fatty acyl amino acid and/or the salt thereof and/or the N-long-chain fatty acyl modified amino acid and/or the salt thereof for compounding has proper viscosity, is clear and transparent, can well solve the thickening problem of the amino acid type surfactant, and can be widely applied to cosmetics such as cleaning products or shampoo products.
Claims (6)
1. A detergent composition is characterized by comprising the following components in percentage by weight:
(A) 9% of N-long-chain fatty acyl amino acid and/or salt thereof and/or N-long-chain fatty acyl modified amino acid and/or salt thereof;
(B) 0-5% of one or more selected from polyalcohol fatty acid monoester, fatty alcohol polyether, fatty acid lactate and sorbitan fatty acid ester;
(D) 0.1-5% of one or more selected from alkyl amide methyl MEA, alkyl amide DEA, alkyl amide MEA or alkyl amide MIPA;
a component (B): the weight ratio of the component (D) is (0.5-4): (0.5-4);
the component (A) is selected from one or a mixture of more of sodium cocoamidopropionate, sodium lauroyl sarcosinate, sodium myristoyl sarcosinate, TEA (TEA) cocoyl glutamate, sodium cocoyl glutamate, disodium cocoyl glutamate, sodium methyl cocoyl taurate, sodium cocoyl methyl taurate, sodium lauroyl methyl aminopropionate, TEA (TEA) lauroyl methylamino propionate and sodium lauroyl aspartate.
2. A detergent composition according to claim 1, characterized in that component (B): the weight ratio of the component (D) is (1-2.5): (1-3).
3. A detergent composition as claimed in claim 1 or 2, wherein said component (B) is selected from one or more of glycerol laurate, glycerol oleate, propylene glycol laurate, propylene glycol oleate, butylene glycol laurate, butylene glycol oleate, laureth-1, laureth-2, laureth-3, laureth-4, laureth lactate and sorbitan laurate.
4. A detergent composition according to claim 1 or 2, characterized in that said component (D) is selected from one or a mixture of several of cocamide methyl MEA, cocamide DEA or cocamide MIPA.
5. Use of a detergent composition according to any of claims 1 to 4 in cosmetics.
6. Use according to claim 5, characterized in that the cosmetic product is a cleansing product or a shampoo product.
Priority Applications (1)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| CN201810347994.2A CN108403472B (en) | 2018-04-18 | 2018-04-18 | Detergent composition and application thereof |
Applications Claiming Priority (1)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| CN201810347994.2A CN108403472B (en) | 2018-04-18 | 2018-04-18 | Detergent composition and application thereof |
Publications (2)
| Publication Number | Publication Date |
|---|---|
| CN108403472A CN108403472A (en) | 2018-08-17 |
| CN108403472B true CN108403472B (en) | 2021-02-19 |
Family
ID=63136015
Family Applications (1)
| Application Number | Title | Priority Date | Filing Date |
|---|---|---|---|
| CN201810347994.2A Active CN108403472B (en) | 2018-04-18 | 2018-04-18 | Detergent composition and application thereof |
Country Status (1)
| Country | Link |
|---|---|
| CN (1) | CN108403472B (en) |
Families Citing this family (5)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN109276494A (en) * | 2018-09-30 | 2019-01-29 | 江门职业技术学院 | A kind of inflammation-resisting itch-stopping shower cream and preparation method thereof |
| CN109984953B (en) * | 2019-05-22 | 2022-08-19 | 宁波御坊堂生物科技有限公司 | Protein peptide gel for bath and skin cleaning and preparation method thereof |
| CN110368320B (en) * | 2019-08-29 | 2021-08-10 | 江南大学 | Composition with glutamic acid type surfactant as main body for washing and caring products and thickening agent composition used for system |
| CN112426370A (en) * | 2020-11-27 | 2021-03-02 | 天津郁美净集团有限公司 | Washing composition with synergistic thickening and fat-endowing effects as well as preparation method and application thereof |
| CN116064191A (en) * | 2021-10-31 | 2023-05-05 | 中国石油化工股份有限公司 | Environment-friendly total-synthesis cutting fluid and preparation method thereof |
Citations (1)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN103505382A (en) * | 2013-09-17 | 2014-01-15 | 广州环亚化妆品科技有限公司 | Cleanser composition with stable wire drawing effect and preparation method thereof |
Family Cites Families (3)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN106074252B (en) * | 2016-06-24 | 2019-04-02 | 杭州兰茜化妆品有限公司 | Shampoo |
| CN107375063A (en) * | 2017-07-14 | 2017-11-24 | 曾万祥 | A kind of shower cream and preparation method |
| CN107496195A (en) * | 2017-08-01 | 2017-12-22 | 杭州惠博士健康产业有限公司 | A kind of recombined human hyaluronic acid compositions and its application in cosmetics |
-
2018
- 2018-04-18 CN CN201810347994.2A patent/CN108403472B/en active Active
Patent Citations (1)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN103505382A (en) * | 2013-09-17 | 2014-01-15 | 广州环亚化妆品科技有限公司 | Cleanser composition with stable wire drawing effect and preparation method thereof |
Also Published As
| Publication number | Publication date |
|---|---|
| CN108403472A (en) | 2018-08-17 |
Similar Documents
| Publication | Publication Date | Title |
|---|---|---|
| CN108403472B (en) | Detergent composition and application thereof | |
| US7867961B2 (en) | Wash composition | |
| JP2002167313A (en) | Surface active agent | |
| CN106901998B (en) | Bath foam | |
| JPWO2016104692A1 (en) | Detergent composition containing acyl basic amino acid derivative | |
| JP6240084B2 (en) | Cleaning composition | |
| US5387372A (en) | Composition for cleansing body with high foaming action | |
| WO2016104698A1 (en) | Creamy cleaning agent composition containing acyl basic amino acid derivative | |
| JP2010235833A (en) | Cleaning composition | |
| JP3116294B2 (en) | Liquid detergent composition | |
| JP2014062226A (en) | Thickener composition | |
| US20210283034A1 (en) | Cleansing material composition | |
| JPH06293620A (en) | Shampoo composition | |
| JP2012092064A (en) | Liquid and gelled detergent composition | |
| JP6134118B2 (en) | Liquid detergent composition | |
| CN108464953A (en) | A kind of detergent composition and its application | |
| CN114921296A (en) | Soap-based self-thickening cleansing compositions | |
| JP4471558B2 (en) | High viscosity liquid detergent composition | |
| CN110368320B (en) | Composition with glutamic acid type surfactant as main body for washing and caring products and thickening agent composition used for system | |
| JP2005146014A (en) | Alkylglycol polyhydric alcohol ether-containing surfactant composition improved in low-temperature stability, and detergent composition comprising the same | |
| JPS6039316B2 (en) | liquid cleaning composition | |
| EP3320890B1 (en) | Hair shampoo composition | |
| CN105997546B (en) | Body wash composition | |
| JPH06264091A (en) | Detergent composition | |
| JP6268595B2 (en) | Creamy detergent composition |
Legal Events
| Date | Code | Title | Description |
|---|---|---|---|
| PB01 | Publication | ||
| PB01 | Publication | ||
| SE01 | Entry into force of request for substantive examination | ||
| SE01 | Entry into force of request for substantive examination | ||
| GR01 | Patent grant | ||
| GR01 | Patent grant |