CN108464953A - A kind of detergent composition and its application - Google Patents
A kind of detergent composition and its application Download PDFInfo
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- CN108464953A CN108464953A CN201810436702.2A CN201810436702A CN108464953A CN 108464953 A CN108464953 A CN 108464953A CN 201810436702 A CN201810436702 A CN 201810436702A CN 108464953 A CN108464953 A CN 108464953A
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- salt
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- A—HUMAN NECESSITIES
- A61—MEDICAL OR VETERINARY SCIENCE; HYGIENE
- A61K—PREPARATIONS FOR MEDICAL, DENTAL OR TOILETRY PURPOSES
- A61K8/00—Cosmetics or similar toiletry preparations
- A61K8/18—Cosmetics or similar toiletry preparations characterised by the composition
- A61K8/72—Cosmetics or similar toiletry preparations characterised by the composition containing organic macromolecular compounds
- A61K8/84—Cosmetics or similar toiletry preparations characterised by the composition containing organic macromolecular compounds obtained by reactions otherwise than those involving only carbon-carbon unsaturated bonds
- A61K8/86—Polyethers
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- A—HUMAN NECESSITIES
- A61—MEDICAL OR VETERINARY SCIENCE; HYGIENE
- A61K—PREPARATIONS FOR MEDICAL, DENTAL OR TOILETRY PURPOSES
- A61K8/00—Cosmetics or similar toiletry preparations
- A61K8/18—Cosmetics or similar toiletry preparations characterised by the composition
- A61K8/30—Cosmetics or similar toiletry preparations characterised by the composition containing organic compounds
- A61K8/40—Cosmetics or similar toiletry preparations characterised by the composition containing organic compounds containing nitrogen
- A61K8/44—Aminocarboxylic acids or derivatives thereof, e.g. aminocarboxylic acids containing sulfur; Salts; Esters or N-acylated derivatives thereof
-
- A—HUMAN NECESSITIES
- A61—MEDICAL OR VETERINARY SCIENCE; HYGIENE
- A61K—PREPARATIONS FOR MEDICAL, DENTAL OR TOILETRY PURPOSES
- A61K8/00—Cosmetics or similar toiletry preparations
- A61K8/18—Cosmetics or similar toiletry preparations characterised by the composition
- A61K8/30—Cosmetics or similar toiletry preparations characterised by the composition containing organic compounds
- A61K8/49—Cosmetics or similar toiletry preparations characterised by the composition containing organic compounds containing heterocyclic compounds
- A61K8/4906—Cosmetics or similar toiletry preparations characterised by the composition containing organic compounds containing heterocyclic compounds with one nitrogen as the only hetero atom
- A61K8/4926—Cosmetics or similar toiletry preparations characterised by the composition containing organic compounds containing heterocyclic compounds with one nitrogen as the only hetero atom having six membered rings
-
- A—HUMAN NECESSITIES
- A61—MEDICAL OR VETERINARY SCIENCE; HYGIENE
- A61Q—SPECIFIC USE OF COSMETICS OR SIMILAR TOILETRY PREPARATIONS
- A61Q1/00—Make-up preparations; Body powders; Preparations for removing make-up
- A61Q1/14—Preparations for removing make-up
-
- A—HUMAN NECESSITIES
- A61—MEDICAL OR VETERINARY SCIENCE; HYGIENE
- A61Q—SPECIFIC USE OF COSMETICS OR SIMILAR TOILETRY PREPARATIONS
- A61Q19/00—Preparations for care of the skin
-
- A—HUMAN NECESSITIES
- A61—MEDICAL OR VETERINARY SCIENCE; HYGIENE
- A61Q—SPECIFIC USE OF COSMETICS OR SIMILAR TOILETRY PREPARATIONS
- A61Q19/00—Preparations for care of the skin
- A61Q19/10—Washing or bathing preparations
-
- A—HUMAN NECESSITIES
- A61—MEDICAL OR VETERINARY SCIENCE; HYGIENE
- A61Q—SPECIFIC USE OF COSMETICS OR SIMILAR TOILETRY PREPARATIONS
- A61Q5/00—Preparations for care of the hair
- A61Q5/02—Preparations for cleaning the hair
-
- A—HUMAN NECESSITIES
- A61—MEDICAL OR VETERINARY SCIENCE; HYGIENE
- A61K—PREPARATIONS FOR MEDICAL, DENTAL OR TOILETRY PURPOSES
- A61K2800/00—Properties of cosmetic compositions or active ingredients thereof or formulation aids used therein and process related aspects
- A61K2800/10—General cosmetic use
-
- A—HUMAN NECESSITIES
- A61—MEDICAL OR VETERINARY SCIENCE; HYGIENE
- A61K—PREPARATIONS FOR MEDICAL, DENTAL OR TOILETRY PURPOSES
- A61K2800/00—Properties of cosmetic compositions or active ingredients thereof or formulation aids used therein and process related aspects
- A61K2800/40—Chemical, physico-chemical or functional or structural properties of particular ingredients
- A61K2800/54—Polymers characterized by specific structures/properties
- A61K2800/542—Polymers characterized by specific structures/properties characterized by the charge
- A61K2800/5426—Polymers characterized by specific structures/properties characterized by the charge cationic
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- Health & Medical Sciences (AREA)
- Life Sciences & Earth Sciences (AREA)
- Animal Behavior & Ethology (AREA)
- General Health & Medical Sciences (AREA)
- Public Health (AREA)
- Veterinary Medicine (AREA)
- Birds (AREA)
- Epidemiology (AREA)
- Dermatology (AREA)
- Cosmetics (AREA)
- Detergent Compositions (AREA)
Abstract
The invention discloses a kind of detergent composition and its applications, including following component：20‑90%（A）N long-chain fatty acyl group amino acid and/or its salt and/or N long-chain fatty acyl group modified amino acids and/or its salt；0.1‑1%（B）Cationic polymer；0‑1%（C）Long-chain PEG group hydrophobically modified compound；0‑1%（D）Piroctone olamine salt.The present invention is by the N acyl amino acid type surfactants of N long-chain fatty acyl group amino acid and/or its salt and/or N long-chain fatty acyl group modified amino acids and/or its salt, adding the component of certain content（B）And the component of specific compounding ratio（C）And component（D）It is compounded, the detergent composition being prepared has suitable viscosity and with good stability, viscosity reduction problem after thickening of the amino acid type surfactant in the cosmetics such as cleaning products or hair washing product can be well solved, can be widely used in the cosmetics such as cleaning products or hair washing product.
Description
Technical field
The present invention relates to biotechnology, more particularly to a kind of detergent composition and its application.
Background technology
N- acyl amino acid type surfactants since its structure is similar and simple in structure with natural surfactant,
The advantages that showing hypotoxicity and excellent biological degradability, to be widely used in cosmetic field.But amino acid pattern table
Face activating agent is when in applied to cleaning class product, in the case where adding cation high molecular, after often will appear thickening
Occurs the problem of viscosity reduction in high-temperature stability, so as to cause use feeling of the product in consumer is influenced, viscosity change can allow
Consumer feels that product quality changes during different time purchase or use, and viscosity reduction can make product be easy stream
It is dynamic, to which the palm of the hand can be leaked out, product is caused to waste and influence to use mood.
Invention content
In order to solve the above technical problems, the primary purpose of the present invention is that provide a kind of detergent composition, the detergent
Composition has suitable viscosity and with good stability, can well solve amino acid type surfactant and clean
Viscosity reduction problem after thickening in the cosmetics such as product or hair washing product.
The technical solution adopted by the present invention is as follows：
A kind of detergent composition, by weight percentage, including following component：
（A）N- long-chain fatty acyl group amino acid and/or its salt and/or N- long-chain fatty acyl group modified amino acids and/or its salt
20-90%；
（B）Cationic polymer 0.1-1%；
（C）Long-chain PEG group hydrophobically modified compound 0-1%；
（D）Piroctone olamine salt 0-1%.
Wherein, the component（C）：Component（D）Compounding weight ratio be（0.1-1）：（0.01-0.6）, preferably（0.3-
0.5）：（0.05-0.3）.
Wherein, component in the present invention（A）N- long-chain fatty acyl group amino acid and/or its salt and/or N- long-chain fatty acyl groups are modified
Amino acid and/or its salt can be obtained by known method.For example, between amino acid and fatty acid halide
Schotten-Baumann reactions are well-known method.
Instant component（A）Amino acid, can use acidic amino acid such as glutamic acid and aspartic acid, neutral amino
Sour such as alanine and threonine and basic amino acid such as arginine, lysine and ornithine, modified propylhomoserin such as flesh ammonia
Acid and methylalanine, N-methyltaurine.These amino acid and modified amino acid can be L- isomers, D- isomers, DL- different
The mixture of structure body or the above isomers of above two.They can be used alone or two kinds and two or more aforementioned substances
It is used in mixed way.
Component（A）Fatty acyl group group, can use 8-22 carbon saturation and unsaturated fatty acid derived from branched fatty acyl
Base group, aliphatic acid example include octanoic acid, capric acid, lauric acid, myristic acid, stearic acid, isostearic acid, palmitic acid, oleic acid,
The fatty acid of linoleic acid, behenic acid, coco-nut oil fatty acid, PALM FATTY ACID, hydrogenated animal, octanoic acid, undecanoic acid, tridecanoic acid, 15
Acid, heptadecanoic acid, nonadecanoic acid, heneicosoic acid etc..They can be used alone or two kinds and two or more aforementioned substances mixing make
With.In view of excellent foaming capacity and quality, froth, particularly preferred coco-nut oil fatty acid, palm kernel fatty acid, lauric acid
And myristic acid.
Component（A）Salt be not particularly limited, example includes inorganic salts, such as alkali metal such as sodium and potassium, alkaline earth gold
Belong to calcium and magnesium, aluminum and zinc, organic salt, such as ammonia, organic amine such as monoethanolamine, diethanol amine and triethanolamine, and alkalinity
The salt of amino acid such as arginine and lysine.They can be used alone or two kinds and two or more aforementioned substances mixing make
With.In view of easily acquirement property and operability, preferred as alkali salt, organic amine salt and basic amino acid salt, and it is especially excellent
Select the salt of sodium, potassium, triethanolamine, arginine and N-methyltaurine sodium.
Preferably, the component（A）Selected from cocoamido sodium propionate, sodium lauroyl sarcosine, myristoyl-N-methylaminoacetic acid
Sodium, cocoyl glutamic acid TEA salt, sodium cocoyl glutamate, cocounut oil acyl disodium glutamate, methyl cocoyl taurine
Sodium, cocounut oil acyl methyl taurine sodium taurocholate, lauroyl methylaminopropionic sodium, lauroyl methylaminopropionic acid TEA salt
With one or more of mixing of lauroyl NaAsp.
Wherein, the component（B）Selected from polyquaternium -7, Polyquaternium-10, polyquaternium -11, polyquaternium -39, melon
The mixing of one or more of youngster's glue hydroxypropyl-trimethyl ammonium chloride, hydroxypropyl guar hydroxypropyltrimonium chloride.
Component in the present invention（C）Long-chain PEG group, the degree of polymerization can between 50-250, particularly preferred 60,120
Or 150.
Component in the present invention（C）Hydrophobically modified group, can use 8-22 carbon saturation and unsaturated fatty acid derive
Branched fatty acyl base group or ether group.The example of aliphatic acid include octanoic acid, capric acid, lauric acid, myristic acid, stearic acid,
Isostearic acid, palmitic acid, oleic acid, linoleic acid, behenic acid, coco-nut oil fatty acid, PALM FATTY ACID, hydrogenated animal fat are sour, pungent
Sour acid, undecanoic acid, tridecanoic acid, pentadecanoic acid, heptadecanoic acid, nonadecanoic acid, heneicosoic acid etc..The example of fatty alcohol include octanol, decyl alcohol,
Laruyl alcohol, myristyl alcohol, stearyl alcohol, isooctadecanol, cetanol, oleyl alcohol, sub- oleyl alcohol, docosyl alcohol, octanol, undecyl alcohol, tridecanol,
Pentadecanol, heptadecanol, nonadecanol, two undecyl alcohols etc..They can be used alone or two kinds and two or more aforementioned substances are mixed
It closes and uses, particularly preferred stearic acid, palmitic acid, stearyl alcohol and cetanol.
Preferably, the component（C）Selected from PEG-150 distearates, PEG-120 methyls dioleate,
PEG-120 methyls trioleate, PEG-150 pentaerythritol tetrastearates, -60 nutmeg of ceteareth
The mixing of one or more of base glycol.
The detergent composition of the present invention, can under the premise of not reducing effect of the present invention in addition to above-mentioned main component
With a variety of suitable components suitably used containing ordinary cosmetics, special cosmetics etc..More specifically, it may include oil
Agent, surfactant（Such as amphoteric surfactant Cocoamidopropyl betaine, nonionic surfactant Plantacare 818
Deng）, thickener, preservative（Such as Kathon CG）, it is essence, ultra-violet absorber, wetting agent, physiologically active ingredient, antioxidant, anti-inflammatory
Agent, antiseptic, anhidrotic, chelating agent（Such as EDETATE SODIUM）, neutralizer, pH adjusting agent（Such as citric acid）Deng, and can basis
Specific purposes and form contain said components, and additive amount is the conventional additive amount in cosmetics.Pass through common method
The detergent composition of the present invention is produced, and the forms such as liquid, paste, gel, powder, solid may be used.It is suitble to
Cosmetics as skin, hair etc..
The application that the present invention also provides said detergent compositions in cosmetics.The detergent composition of the present invention
Purposes is not particularly limited, but can provide a variety of cosmetics.Its example includes：Cleaning supplies such as cleanser（Including face cleaning
Foam, liquid gel, wetting agent etc.）, shampoo, makeup removing agent and detergent, substrate product such as hair treating agent（Including spraying
The product of product, gel products, other forms）And shaving cream（Shave Gel miles, shaving cream etc.）, etc..In view of amino acid changes
The use scope that acidic amino acid table is lived, is preferred for cleaning products and hair washing product.
Compared with prior art, the present invention having the advantages that：
The present invention by N- long-chain fatty acyl group amino acid and/or its salt and/or N- long-chain fatty acyl group modified amino acids and/or its
In the N- acyl amino acid type surfactants of salt, the component of certain content is added（B）And the component of specific compounding ratio（C）
And component（D）It is compounded, the detergent composition being prepared has suitable viscosity and with good stability, can be with
Viscosity reduction problem after thickening of the amino acid type surfactant in the cosmetics such as cleaning products or hair washing product is well solved, it can
It is widely used in the cosmetics such as cleaning products or hair washing product.
Specific implementation mode
It is further illustrated the present invention below by specific implementation mode, but embodiments of the present invention are not by following realities
Apply the limitation of example.
Raw material used in the embodiment of the present invention and comparative example derives from purchased in market.
Test method：
The stability test method of detergent composition：Sample is individually positioned in room temperature and 50 DEG C of baking ovens, is placed 4 weeks, is surveyed
Test agent viscosity.
The test method of the viscosity of detergent composition：Brookfiled DV-C digital display viscosimeters, No. 62 rotors, rotating speed
6rpm expects temperature：25 DEG C, the reading duration：It is read at 1 minute after startup.
By 4 peripheral stability sample viscosities compared with sample initial viscosity, the percentage of viscosity change, viscosity change hundred are obtained
Point ratio=（Tested viscosity-sample initial viscosity）/ sample initial viscosity × 100%.
For assessment of bids standard according to tetra- grades of A, B, C, D, wherein viscosity change 0-10% is A, and viscosity change 10-20% is B, viscosity
Variation 20-30% is C, and viscosity change 30%-50% is D, and it is E that viscosity change, which is more than 50%,.
Foam height：According to《GB/T 29679-2013 shampoos, hair cream》Middle method is detected.
Embodiment 1-6 and comparative example 1-3：
By shown in table 1 be formulated, according to table 1 proportioning by water,（A）N- long-chain fatty acyl group amino acid and/or its salt and/or N- long-chains
Fatty acyl group modified amino acid and/or its salt,（B）Cationic polymer,（C）Long-chain PEG group hydrophobically modified compound and（D）Pyrrole
Rock ketone ethanolamine salt is heated to proper temperature dissolving, stirs evenly, surplus material, moisturizing to formula ratio are added after cooling
100%, it stirs evenly and adjusts after pH to prescribed limit to get detergent composition, the results are shown in Table 1 for test performance.
The each component weight percent of 1 embodiment and comparative example of table when each the performance test results
Remarks：
Component C）Adding too much can influence product smearing and lather quickness, and GB/T 29679-2013 shampoos, hair cream
In be more than or equal to 100mm, 50mm and 40mm to the foam height of shampoo transparent type, nontransparent type and juvenile product.Component
C）Adding too much can reduce the foam height of product, therefore not recommend to add the component C of high-content）, such as comparative example 2.
《Cosmetics safety technical specification（Version in 2015）》Middle regulation piroctone and piroctone olamine salt are eluting
The limitation of type product is 1%, other products are 0.5%；And the cost of piroctone olamine salt is higher.Therefore from safety and economy
Property consider, select component D）The upper limit be 1%, and reduce its dosage as possible.
The present invention is by N- long-chain fatty acyl group amino acid and/or its salt it can be seen from the embodiment and comparative example of table 1
And/or in the N- acyl amino acid type surfactants of N- long-chain fatty acyl group modified amino acids and/or its salt, certain content is added
Component（B）And the component of specific compounding ratio（C）And component（D）It is compounded, the detergent composition being prepared has
Suitable viscosity and with good stability, can well solve amino acid type surfactant in cleaning products or hair washing
Viscosity reduction problem after thickening in the cosmetics such as product, can be widely used in the cosmetics such as cleaning products or hair washing product.
Claims (7)
1. a kind of detergent composition, which is characterized in that by weight percentage, including following component：
（A）N- long-chain fatty acyl group amino acid and/or its salt and/or N- long-chain fatty acyl group modified amino acids and/or its salt
20-90%；
（B）Cationic polymer 0.1-1%；
（C）Long-chain PEG group hydrophobically modified compound 0-1%；
（D）Piroctone olamine salt 0-1%.
2. detergent composition according to claim 1, which is characterized in that the component（C）：Component（D）Compounding weight
Measuring ratio is（0.1-1）：（0.01-0.6）, preferably（0.3-0.5）：（0.05-0.3）.
3. detergent composition according to claim 1, which is characterized in that the component（A）Selected from cocoamido third
Sour sodium, sodium lauroyl sarcosine, myristoyl-N-methylaminoacetic acid sodium, cocoyl glutamic acid TEA salt, sodium cocoyl glutamate, coconut palm
Oleoyl disodium glutamate, sodium methyl cocoyl taurate, cocounut oil acyl methyl taurine sodium taurocholate, lauroyl methylamino
One or more of mixing of sodium propionate, lauroyl methylaminopropionic acid TEA salt and lauroyl NaAsp.
4. detergent composition according to claim 1, which is characterized in that the component（B）Selected from polyquaternium -7, gather
Quaternary ammonium salt -10, polyquaternium -11, polyquaternium -39, guar hydroxypropyltrimonium chloride, hydroxypropyl melon glue hydroxypropyl
The mixing of one or more of trimethyl ammonium chloride.
5. detergent composition according to claim 1 or 2, which is characterized in that the component（C）Selected from PEG-150 bis-
Stearate, PEG-120 methyls dioleate, PEG-120 methyls trioleate, PEG-150 pentaerythrites four
The mixing of one or more of stearate, -60 myristyl glycol of ceteareth.
6. application of the claim 1-5 any one of them detergent compositions in cosmetics.
7. application according to claim 6, which is characterized in that the cosmetics are cleaning products or hair washing product.
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| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| CN201810436702.2A CN108464953B (en) | 2018-05-09 | 2018-05-09 | A kind of detergent composition and its application |
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| Application Number | Priority Date | Filing Date | Title |
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| CN201810436702.2A CN108464953B (en) | 2018-05-09 | 2018-05-09 | A kind of detergent composition and its application |
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| CN108464953B CN108464953B (en) | 2019-07-09 |
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Cited By (2)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| WO2020144125A1 (en) * | 2019-01-07 | 2020-07-16 | Unilever N.V. | Hair care composition |
| CN113952289A (en) * | 2021-11-15 | 2022-01-21 | 广州华厦生物制药有限公司 | Plant amino acid shampoo and preparation method thereof |
Citations (3)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| DE102006037113A1 (en) * | 2006-08-07 | 2008-02-14 | Henkel Kgaa | Means for the control of scalp dandruff |
| CN106074252A (en) * | 2016-06-24 | 2016-11-09 | 杭州兰茜化妆品有限公司 | Shampoo |
| CN106109259A (en) * | 2016-07-08 | 2016-11-16 | 拉芳家化股份有限公司 | A kind of shampoo bath gel preventing stink with perspiration |
-
2018
- 2018-05-09 CN CN201810436702.2A patent/CN108464953B/en active Active
Patent Citations (3)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| DE102006037113A1 (en) * | 2006-08-07 | 2008-02-14 | Henkel Kgaa | Means for the control of scalp dandruff |
| CN106074252A (en) * | 2016-06-24 | 2016-11-09 | 杭州兰茜化妆品有限公司 | Shampoo |
| CN106109259A (en) * | 2016-07-08 | 2016-11-16 | 拉芳家化股份有限公司 | A kind of shampoo bath gel preventing stink with perspiration |
Cited By (4)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| WO2020144125A1 (en) * | 2019-01-07 | 2020-07-16 | Unilever N.V. | Hair care composition |
| CN113271919A (en) * | 2019-01-07 | 2021-08-17 | 联合利华知识产权控股有限公司 | Hair care composition |
| JP2022516931A (en) * | 2019-01-07 | 2022-03-03 | ユニリーバー・アイピー・ホールディングス・ベスローテン・ヴェンノーツハップ | Hair care composition |
| CN113952289A (en) * | 2021-11-15 | 2022-01-21 | 广州华厦生物制药有限公司 | Plant amino acid shampoo and preparation method thereof |
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