DE102006037113A1 - Means for the control of scalp dandruff - Google Patents

Abstract

A cosmetic composition is claimed which, for the effective and rapid control of dandruff on solid body surfaces, comprises a combination of A) at least one antidandruff active agent, B) at least one zinc salt and C) at least one compound selected from the group Laureth-7-citrate, Laureth -6-citrate, disodium PEG-5 lauryl citrate sulfosuccinate, disodium cocopolyglucose citrate, glyceryl stearate citrate and dicocoyl pentaerythryl distearyl citrate.

Description

The The invention relates to a cosmetic agent based on a special Drug combination, a method using the agents and the use of the means for prophylaxis, reduction, elimination and relieving dandruff on hairy body surfaces.

cleaning supplies for skin and hair, such as liquid soaps, shampoos, shower baths, bubble baths, shower and wash gels available commercially are, must not only have good cleaning power, but should continue for the skin and the hair well tolerated and even more often Application should not lead to excessive degreasing or dryness.

Usually are skin and hair cleaners based on anionic, nonionic and / or amphoteric surfactants, however most preferably based on anionic surfactants formulated. Although such compositions have good detergency, however, the cosmetic properties associated with them are inadequate, especially due to the removal of the skin and hair Lipids and proteins from the skin or hair surface.

a another important aspect of hair cleansing and care the fight of dandruff, because even the slight appearance of dandruff on the scalp or other hairy body regions is used as a sign lack of care. About that In addition, dandruff is usually accompanied by itching, the as disturbing is felt. An itching, however, causes scratching reactions, so that it can cause injury to the affected skin, which in turn is the basis for Can form infections and pathogenic agents.

The Requirements for a cosmetic remedy for dandruff therefore high, because on the one hand the scalp should be thorough and lasting from dandruff be freed, and secondly, the means for hair and Scalp well tolerated be. Another important requirement is one possible fast action, so that the above chain of disadvantages do not even occur.

Out The literature is known a variety of hair cosmetic products, which should prevent or reduce dandruff. To select usually stand Preparations in the nature of shampoos, lotions or hair lotions.

From the EP-A-348 015 the use of zinc salts as anti-dandruff agents is known.

The combination of three conventional and effective antidandruff agents is the subject of EP 1 238 645 B1 , Therein are 1- (4-chlorophenoxy) -1- (1H-imidazolyl) -3,3-dimethyl-2-butanone (INCI name: climbazole), bis (1-hydroxy-2- (1H) -pyridinethionato) zinc (INCI name: Zinc Pyrithione) and 1-hydroxy-4-methyl-6- (2,4,4-trimethylpentyl) -2- (1H) pyridinone, 2-aminoethanol salt (INCI name: Piroctone Olamine) already in low levels of use combined to produce an anti-dandruff agent that prevents or reduces the formation of dandruff.

adversely So far, the means of the prior art has been that they were effective against dandruff, but this effect only after frequent use occurred.

Therefore it was additional Object of the present invention, a fast against dandruff To find remedies that are gentle on the scalp and hair and the hair in terms of its combability, does not negatively affect its shine and suppleness.

These Task has been solved in that an anti-dandruff active with a zinc salt and another compound, selected from Group Laureth-7-citrate, Laureth-6-citrate, Disodium PEG-5 Lauryl citrate sulfosuccinate, disodium cocopolyglucose citrate, Glyceryl stearate citrate and dicocoyl pentaerythryl distearyl citrate, in a for suitable for use on hairy body surfaces Medium was combined with each other.

Surprisingly could be found that by the hair treatment with cosmetic means on the basis of this triple combination a much faster Effect occurred as with conventional means.

• A) mindestens einen Antischuppenwirkstoff,
• B) mindestens ein Zinksalz sowie
• C) mindestens eine Verbindung, ausgewählt aus der Gruppe Laureth-7-citrate, Laureth-6-citrate, Disodium PEG-5 Laurylcitrate Sulfosuccinate, Disodium Cocopolyglucose citrate, Glyceryl Stearate citrate und Dicocoyl pentaerythryl distearyl citrate

enthalten.The invention therefore cosmetic products, as the active ingredient combination

• A) at least one antidandruff active ingredient,
• B) at least one zinc salt as well
• C) at least one compound selected from the group consisting of laureth-7-citrate, laureth-6-citrate, disodium PEG-5 lauryl citrate sulfosuccinate, disodium cocopolyglucose citrate, glyceryl stearate citrate and dicocoyl pentaerythryl distearyl citrate

contain.

According to the invention preferred are cosmetic agents in which the ratio of the active ingredients used A), B) and C) is in the range of (0.1-1): (0.1-1) :( 1-10).

When Antidandruff active ingredient is in principle any known, effective Antidandruff active ingredient, for example Piroctone Olamine, climbazole, Zinc pyrithione, ketoconazole, salicylic acid, sulfur, tar preparations, Undecensäurederivate, Burdock root extracts, poplar extracts, stinging nettle extracts, walnut shell extracts, Birch extracts, willow bark extracts and arnica extracts.

Especially According to the invention, the antidandruff active ingredients are suitable Piroctone olamine, climbazole, zinc pyrithione and ketoconazole, in particular Piroctone Olamine (Octopirox).

According to the invention suitable Zinc salts are, for example, zinc sulfates, zinc sulfate hydrates (for example Zinc sulfate heptahydrate), zinc carbonate, zinc chlorides, zinc oxides and zinc (II) fluorides. Particularly suitable are zinc sulfate and Zinc sulfate hydrate.

Of the or the antidandruff active ingredient (s) are in the compositions of the invention - related on her weight - usually in an amount of 0.05 to 2%, preferably in an amount of 0.1 to 1.5% and especially in an amount of 0.3 to 1%.

Included in the invention the cosmetic products - related on her weight - 0.01 to 2%, preferably 0.1 to 1.5% and in particular 0.3 to 1% of a or more zinc salts.

Usually are the compounds C) in the inventive compositions - based on her weight - in in an amount of 0.1 to 10%, preferably in an amount of 0.5 to 7% and in particular in an amount of 1 to 5%.

The Cosmetic products also contain at least one representative from the group of anionic, amphoteric, zwitterionic, nonionic, cationic surfactants or mixtures thereof, the water-insoluble oil components, vitamins, provitamins, protein hydrolysates, plant extracts, the UV filter, the amino acids, the water-insoluble Silicones, the water-soluble Silicones and / or amodimethicones

• – lineare und verzweigte Fettsäuren mit 8 bis 30 C-Atomen (Seifen),
• – Ethercarbonsäuren der Formel R-O-(CH₂-CH₂O)_x-CH₂-COOH, in der R eine lineare Alkylgruppe mit 8 bis 30 C-Atomen und x = 0 oder 1 bis 16 ist,
• – Acylsarcoside mit 8 bis 24 C-Atomen in der Acylgruppe,
• – Acyltauride mit 8 bis 24 C-Atomen in der Acylgruppe,
• – Acylisethionate mit 8 bis 24 C-Atomen in der Acylgruppe,
• – Sulfobernsteinsäuremono- und -dialkylester mit 8 bis 24 C-Atomen in der Alkylgruppe und Sulfobernsteinsäuremono-alkylpolyoxyethylester mit 8 bis 24 C-Atomen in der Alkylgruppe und 1 bis 6 Oxyethylgruppen,
• – lineare Alkansulfonate mit 8 bis 24 C-Atomen,
• – lineare Alpha-Olefinsulfonate mit 8 bis 24 C-Atomen,
• – Alpha-Sulfofettsäuremethylester von Fettsäuren mit 8 bis 30 C-Atomen,
• – Alkylsulfate und Alkylpolyglykolethersulfate der Formel R-O(CH₂-CH₂O)_x-OSO₃H, in der R eine bevorzugt lineare Alkylgruppe mit 8 bis 30 C-Atomen und x = 0 oder 1 bis 12 ist,
• – Gemische oberflächenaktiver Hydroxysulfonate gemäß DE-A-37 25 030 ,
• – sulfatierte Hydroxyalkylpolyethylen- und/oder Hydroxyalkylenpropylenglykolether gemäß DE-A-37 23 354 ,
• – Sulfonate ungesättigter Fettsäuren mit 8 bis 24 C-Atomen und 1 bis 6 Doppelbindungen gemäß DE-A-39 26 344 ,
• – Ester der Weinsäure und Zitronensäure mit Alkoholen, die Anlagerungsprodukte von etwa 2–15 Molekülen Ethylenoxid und/oder Propylenoxid an Fettalkohole mit 8 bis 22 C-Atomen darstellen,
• – Alkyl- und/oder Alkenyletherphosphate der Formel (II),
  
  in der R⁶ bevorzugt für einen aliphatischen Kohlenwasserstoffrest mit 8 bis 30 Kohlenstoffatomen, R⁷ für Wasserstoff, einen Rest (CH₂CH₂O)_nR⁶ oder X, n für Zahlen von 1 bis 10 und X für Wasserstoff, ein Alkali- oder Erdalkalimetall oder NR⁶R⁹R¹⁰R¹¹, mit R⁸ bis R¹¹ unabhängig voneinander stehend für einen C₁ bis C₄-Kohlenwasserstoffrest, steht,
• – sulfatierte Fettsäurealkylenglykolester der Formel (III), R¹²CO(AlkO)_nSO₃M (III)in der R¹²CO- für einen linearen oder verzweigten, aliphatischen, gesättigten und/oder ungesättigten Acylrest mit 6 bis 22 C-Atomen, Alk für CH₂CH₂, CHCH₃CH₂ und/oder CH₂CHCH₃, n für Zahlen von 0,5 bis 5 und M für ein Kation steht, wie sie in der DE-OS 197 36 906.5 beschrieben sind,
• – Monoglyceridsulfate und Monoglyceridethersulfate der Formel (IV), wie sie beispielsweise in der EP-B1 0 561 825 , der EP-B1 0 561 999 , der DE-A1 42 04 700 oder von A.K.Biswas et al. in J.Am.Oil.Chem.Soc. 37, 171 (1960) und F.U.Ahmed in J.Am.Oil.Chem.Soc. 67, 8 (1990) beschrieben worden sind,
  
  in der R¹³CO für einen linearen oder verzweigten Acylrest mit 6 bis 22 Kohlenstoffatomen, x, y und z in Summe für 0 oder für Zahlen von 1 bis 30, vorzugsweise 2 bis 10, und X für ein Alkali- oder Erdalkalimetall steht. Typische Beispiele für im Sinne der Erfindung geeignete Monoglycerid(ether)sulfate sind die Umsetzungsprodukte von Laurinsäuremonoglycerid, Kokosfettsäuremonoglycerid, Palmitinsäuremonoglycerid, Stearinsäuremonoglycerid, Ölsäuremonoglycerid und Talgfettsäuremonoglycerid sowie deren Ethylenoxidaddukte mit Schwefeltrioxid oder Chlorsulfonsäure in Form ihrer Natriumsalze. Vor-zugsweise werden Monoglyceridsulfate der Formel (VIII) eingesetzt, in der R¹³CO für einen linearen Acylrest mit 8 bis 18 Kohlenstoffatomen steht.

Suitable anionic surfactants in preparations according to the invention are all anionic surfactants suitable for use on the human body. These are characterized by a water-solubilizing, anionic group such as. As a carboxylate, sulfate, sulfonate or phosphate group and a lipophilic alkyl group having about 8 to 30 carbon atoms. In addition, glycol or polyglycol ether groups, ester, ether and amide groups and hydroxyl groups may be present in the molecule. Examples of suitable anionic surfactants are, in each case in the form of the sodium, potassium and ammonium as well as the mono-, di- and trialkanolammonium salts having 2 to 4 C atoms in the alkanol group,

• - linear and branched fatty acids with 8 to 30 carbon atoms (soaps),
• Ether carboxylic acids of the formula RO- (CH ₂ -CH ₂ O) _x -CH ₂ -COOH, in which R is a linear alkyl group having 8 to 30 C atoms and x = 0 or 1 to 16,
• Acylsarcosides having 8 to 24 C atoms in the acyl group,
• Acyltaurides having 8 to 24 carbon atoms in the acyl group,
• Acyl isethionates having 8 to 24 C atoms in the acyl group,
• Sulfosuccinic acid mono- and dialkyl esters having 8 to 24 C atoms in the alkyl group and sulfosuccinic acid monoalkyl polyoxyethyl esters having 8 to 24 C atoms in the alkyl group and 1 to 6 oxyethyl groups,
• - linear alkanesulfonates having 8 to 24 carbon atoms,
• - linear alpha-olefin sulfonates having 8 to 24 carbon atoms,
• Alpha-sulfofatty acid methyl esters of fatty acids having 8 to 30 C atoms,
• Alkyl sulfates and alkyl polyglycol ether sulfates of the formula RO (CH ₂ -CH ₂ O) _x -OSO ₃ H, in which R is a preferably linear alkyl group having 8 to 30 C atoms and x = 0 or 1 to 12,
• Mixtures of surface active hydroxysulfonates according to DE-A-37 25 030 .
• - Sulfated Hydroxyalkylpolyethylen- and / or Hydroxyalkylenpropylenglykolether according to DE-A-37 23 354 .
• - Sulfonates of unsaturated fatty acids having 8 to 24 carbon atoms and 1 to 6 double bonds according to DE-A-39 26 344 .
• Esters of tartaric acid and citric acid with alcohols which are adducts of about 2-15 molecules of ethylene oxide and / or propylene oxide with fatty alcohols containing 8 to 22 carbon atoms,
• Alkyl and / or alkenyl ether phosphates of the formula (II),
  
  in the R ^{6 is} preferably an aliphatic hydrocarbon radical having 8 to 30 carbon atoms, R ^{7 is} hydrogen, a radical (CH ₂ CH ₂ O) _n R ⁶ or X, n is from 1 to 10 and X is hydrogen, an alkali metal radical or alkaline earth metal or NR ⁶ R ⁹ R ¹⁰ R ¹¹ , where R ⁸ to R ¹¹ independently of one another represent a C ₁ to C ₄ -hydrocarbon radical,
• Sulfated fatty acid alkylene glycol esters of the formula (III), R ¹² CO (AlkO) _n SO ₃ M (III) in the R ¹² CO- for a linear or branched, aliphatic, saturated and / or unsaturated acyl radical having 6 to 22 C atoms, Alk for CH ₂ CH ₂ , CHCH ₃ CH ₂ and / or CH ₂ CHCH ₃ , n for numbers from 0.5 to 5 and M stands for a cation, as in the DE-OS 197 36 906.5 are described
• Monoglyceride sulfates and monoglyceride ether sulfates of the formula (IV), as described, for example, in US Pat EP-B1 0 561 825 , of the EP-B1 0 561 999 , of the DE-A1 42 04 700 or from AKBiswas et al. in J.Am.Oil. Chem. Soc. 37, 171 (1960) and FUAhmed in J.Am.Oil.Chem.Soc. 67, 8 (1990) have been described
  
  in which R ¹³ CO is a linear or branched acyl radical having 6 to 22 carbon atoms, x, y and z are in total 0 or numbers of 1 to 30, preferably 2 to 10, and X is an alkali or alkaline earth metal. Typical examples of monoglyceride (ether) sulfates suitable for the purposes of the invention are the reaction products of lauric acid monoglyceride, coconut fatty acid monoglyceride, palmitic acid monoglyceride, stearic acid monoglyceride, oleic acid monoglyceride and tallow fatty acid monoglyceride and their ethylene oxide adducts with sulfur trioxide or chlorosulfonic acid in the form of their sodium salts. Preference is given to using monoglyceride sulfates of the formula (VIII) in which R ¹³ CO is a linear acyl radical having 8 to 18 carbon atoms.

preferred anionic surfactants are alkyl sulfates, alkyl polyglycol ether sulfates and ether carboxylic acid salts with 10 to 18 C atoms in the alkyl group and up to 12 glycol ether groups in the molecule and sulfosuccinic acid mono- and -dialkylester having 8 to 18 C-atoms in the alkyl group and sulfosuccinic monoalkylpolyoxyethylester with 8 to 18 C atoms in the alkyl group and 1 to 6 oxyethyl groups.

Especially preferred anionic surfactants are the alkali or ammonium salts of the lauryl ether sulfate having a degree of ethoxylation of 2 to 4 EO.

Zwitterionic surfactants are those surface-active compounds which carry in the molecule at least one quaternary ammonium group and at least one -COO ^(-) or -SO ₃ ^(-) group. Particularly suitable zwitterionic surfactants are the so-called betaines such as N-alkyl-N, N-dimethylammonium glycinates, for example cocoalkyldimethylammonium glycinate, N-acylaminopropyl-N, N-dimethylammonium glycinates, for example cocoacylaminopropyldimethylammonium glycinate, and 2-alkyl-3-carboxymethyl-3 Hydroxyethyl imidazolines each having 8 to 18 carbon atoms in the alkyl or acyl group and Kokosacylaminoethylhydroxyethylcarboxymethylglycinat. A preferred zwitterionic surfactant is the fatty acid amide derivative known by the INCI name Cocamidopropyl Betaine.

Amphoteric surfactants are understood to mean those surface-active compounds which, apart from a C ₈ -C ₂₄ -alkyl or -acyl group in the molecule, contain at least one free amino group and at least one -COOH or -SO ₃ H group and which are capable of forming internal salts , Examples of suitable ampholytic surfactants are N-alkylglycines, N-alkylpropionic acids, N-alkylaminobutyric acids, N-alkyliminodipropionic acids, N-hydroxyethyl-N-alkylamidopropylglycines, N-alkyltaurines, N-alkylsarcosines, 2-alkylaminopropionic acids and alkylaminoacetic acids each having about 8 to 24 C atoms in the alkyl group. Particularly preferred ampholytic surfactants are N-cocoalkylaminopropionate, cocoacylaminoethylaminopropionate and C ₁₂ -C ₁₈ acylsarcosine.

• – Anlagerungsprodukte von 2 bis 50 Mol Ethylenoxid und/oder 0 bis 5 Mol Propylenoxid an lineare und verzweigte Fettalkohole mit 8 bis 30 C-Atomen, an Fettsäuren mit 8 bis 30 C-Atomen und an Alkylphenole mit 8 bis 15 C-Atomen in der Alkylgruppe,
• – mit einem Methyl- oder C₂-C₆-Alkylrest endgruppenverschlossene Anlagerungsprodukte von 2 bis 50 Mol Ethylenoxid und/oder 0 bis 5 Mol Propylenoxid an lineare und verzweigte Fettalkohole mit 8 bis 30 C-Atomen, an Fettsäuren mit 8 bis 30 C-Atomen und an Alkylphenole mit 8 bis 15 C-Atomen in der Alkylgruppe, wie beispielsweise die unter den Verkaufsbezeichnungen Dehydol^® LS, Dehydol^® LT (Cognis) erhältlichen Typen,
• – C₁₂-C₃₀-Fettsäuremono- und -diester von Anlagerungsprodukten von 1 bis 30 Mol Ethylenoxid an Glycerin,
• – Anlagerungsprodukte von 5 bis 60 Mol Ethylenoxid an Rizinusöl und gehärtetes Rizinusöl, beispielsweise Rizinusöl-hydriert+40 EO, wie es beispielsweise unter dem Handelsnamen Cremophor CO 455 von der Firma SHC im Handel erhältlich ist,
• – Polyolfettsäureester, wie beispielsweise das Handelsprodukt Hydagen^® HSP (Cognis) oder Sovermol-Typen (Cognis),
• – alkoxilierte Triglyceride,
• – alkoxilierte Fettsäurealkylester der Formel (V) R¹⁴CO-(OCH₂CHR¹⁵)_wOR¹⁶ (V)in der R¹⁴CO für einen linearen oder verzweigten, gesättigten und/oder ungesättigten Acylrest mit 6 bis 22 Kohlenstoffatomen, R¹⁵ für Wasserstoff oder Methyl, R¹⁶ für lineare oder verzweigte Alkylreste mit 1 bis 4 Kohlenstoffatomen und w für Zahlen von 1 bis 20 steht,
• – Aminoxide,
• – Hydroxymischether, wie sie beipielsweise in der DE-OS 19738866 beschrieben sind,
• – Sorbitanfettsäureester und Anlagerungeprodukte von Ethylenoxid an Sorbitanfettsäureester wie beispielsweise die Polysorbate,
• – Zuckerfettsäureester und Anlagerungsprodukte von Ethylenoxid an Zuckerfettsäureester,
• – Anlagerungsprodukte von Ethylenoxid an Fettsäurealkanolamide und Fettamine,
• – Fettsäure-N-alkylglucamide,
• – Alkylpolygykoside entsprechend der allgemeinen Formel RO-(Z)_x wobei R für Alkyl, Z für Zucker sowie x für die Anzahl der Zuckereinheiten steht. Die erfindungsgemäß verwendbaren Alkylpolyglykoside können lediglich einen bestimmten Alkylrest R enthalten. Üblicherweise werden diese Verbindungen aber ausgehend von natürlichen Fetten und Ölen oder Mineralölen herge stellt. In diesem Fall liegen als Alkylreste R Mischungen entsprechend den Ausgangsverbindungen bzw. entsprechend der jeweiligen Aufarbeitung dieser Verbindungen vor.

Nonionic surfactants contain as hydrophilic group z. A polyol group, a polyalkylene glycol ether group or a combination of polyol and polyglycol ether groups. Such compounds are, for example

• - Addition products of 2 to 50 moles of ethylene oxide and / or 0 to 5 moles of propylene oxide to linear and branched fatty alcohols having 8 to 30 carbon atoms, to fatty acids having 8 to 30 carbon atoms and to alkylphenols having 8 to 15 carbon atoms in the alkyl group,
• - with a methyl or C ₂ -C ₆ alkyl radical end-capped addition products of 2 to 50 moles of ethylene oxide and / or 0 to 5 moles of propylene oxide to linear and branched fatty alcohols having 8 to 30 carbon atoms, to fatty acids having 8 to 30 C atoms and onto alkylphenols having 8 to 15 carbon atoms in the alkyl group, such as those available under the trade names Dehydol ^® LS, LT Dehydol ^® types (Cognis),
• C ₁₂ -C ₃₀ -fatty acid mono- and diesters of addition products of 1 to 30 mol of ethylene oxide with glycerol,
• Addition products of from 5 to 60 mol of ethylene oxide onto castor oil and hydrogenated castor oil, for example castor oil-hydrogenated + 40 EO, as it is commercially available, for example, under the trade name Cremophor CO 455 from SHC,
• - polyol, such as the commercially available product ^® Hydagen HSP (Cognis) or Sovermol types (Cognis),
• - alkoxylated triglycerides,
• Alkoxylated fatty acid alkyl esters of the formula (V) R ¹⁴ CO- (OCH ₂ CHR ¹⁵ ) _w OR ¹⁶ (V) in the R ¹⁴ CO is a linear or branched, saturated and / or unsaturated acyl radical having 6 to 22 carbon atoms, R ^{15 is} hydrogen or methyl, R ^{16 is} linear or branched alkyl radicals having 1 to 4 carbon atoms and w is a number from 1 to 20 stands,
• - amine oxides,
• Hydroxymix ethers, as described, for example, in US Pat DE-OS 19738866 are described
• Sorbitan fatty acid esters and adducts of ethylene oxide with sorbitan fatty acid esters such as the polysorbates,
• Sugar fatty acid esters and addition products of ethylene oxide with sugar fatty acid esters,
• Adducts of ethylene oxide with fatty acid alkanolamides and fatty amines,
• Fatty acid N-alkylglucamides,
• - Alkylpolygykoside according to the general formula RO- (Z) _x wherein R is alkyl, Z is sugar and x is the number of sugar units. The alkyl polyglycosides which can be used according to the invention can only contain one particular alkyl radical R. Usually, these compounds but starting from natural fats and oils or mineral oils Herge provides. In this case, the alkyl radicals R are mixtures corresponding to the starting compounds or corresponding to the particular work-up of these compounds.

• – im wesentlichen aus C₈- und C₁₀-Alkylgruppen,
• – im wesentlichen aus C₁₂- und C₁₄-Alkylgruppen,
• – im wesentlichen aus C₈- bis C₁₆-Alkylgruppen oder
• – im wesentlichen aus C₁₂- bis C₁₅-Alkylgruppen oder
• – im wesentlichen aus C₁₆ bis C₁₈-Alkylgruppen besteht.

Particularly preferred are those alkyl polyglycosides in which R

• Consisting essentially of C ₈ and C ₁₀ -alkyl groups,
• Essentially of C ₁₂ and C ₁₄ alkyl groups,
• - Essentially from C ₈ - to C ₁₆ alkyl groups or
• - Essentially from C ₁₂ - to C ₁₅ alkyl groups or
• - Consists essentially of C ₁₆ to C ₁₈ alkyl groups.

As sugar building block Z it is possible to use any desired mono- or oligosaccharides. Usually, sugars with 5 or 6 carbon atoms and the corresponding oligosaccharides are used. Such sugars are, for example, glucose, fructose, galactose, arabinose, ribose, xylose, lyxose, allose, altrose, Mannose, gulose, idose, talose and sucrose. Preferred sugar building blocks are glucose, fructose, galactose, arabinose and sucrose; Glucose is particularly preferred.

The alkyl polyglycosides according to the invention contain on average 1.1 to 5 sugar units. Alkylpolyglykoside with x values of 1.1 to 2.0 are preferred. Very particularly preferred are alkyl glycosides in which x is 1.1 to 1.8.

Also The alkoxylated homologs of said alkyl polyglycosides can be used according to the invention become. These homologs can an average of up to 10 ethylene oxide and / or propylene oxide units per alkyl glycoside unit.

When preferred nonionic surfactants are the alkylene oxide addition products to saturated linear Fatty alcohols and fatty acids with in each case 2 to 30 moles of ethylene oxide per mole of fatty alcohol or fatty acid. Preparations with excellent properties will also be obtained when they are fatty acid esters as nonionic surfactants of ethoxylated glycerol.

These Connections are identified by the following parameters. The alkyl radical R contains 6 to 22 carbon atoms and can be both linear and branched be. Preference is given to primary linear and methyl-branched in the 2-position aliphatic radicals. Such Examples of alkyl radicals are 1-octyl, 1-decyl, 1-lauryl, 1-myristyl, 1-cetyl and 1-stearyl. Particularly preferred are 1-octyl, 1-decyl, 1-Lauryl, 1-myristyl. When using so-called "oxo-alcohols" as starting materials predominate Compounds with an odd number of carbon atoms in the alkyl chain.

at it may be the compounds with alkyl groups used as surfactant each are uniform substances. It is, however, in usually preferred in the preparation of these substances by native vegetable or animal raw materials, so that you substance mixtures obtained with different, depending on the raw material alkyl chain lengths.

at the surfactants, the adducts of ethylene and / or propylene oxide represent fatty alcohols or derivatives of these addition products, can both products with a "normal" homolog distribution as well as those with a narrow homolog distribution become. Under "normal" homolog distribution are understood to mean mixtures of homologs which are used in the Reaction of fatty alcohol and alkylene oxide using alkali metals, Alkali metal hydroxides or alkali metal alcoholates as catalysts receives. Narrowed homolog distributions are obtained when, for example Hydrotalcites, alkaline earth metal salts of ether carboxylic acids, alkaline earth metal oxides, hydroxides or alcoholates are used as catalysts. The use of products with narrow homolog distribution may be preferred.

According to one another embodiment of the invention the cosmetic products continue to be cationic type surfactants quaternary Ammonium compounds containing esterquats and amidoamines.

preferred quaternary Ammonium compounds are ammonium halides, especially chlorides and Bromides such as alkyltrimethylammonium chlorides, dialkyldimethylammonium chlorides and trialkylmethylammonium chlorides, e.g. Cetyltrimethylammonium chloride, Stearyltrimethylammonium chloride, distearyldimethylammonium chloride, Lauryldimethylammonium chloride, Lauryldimethylbenzylammoniumchlorid and tricetylmethylammonium chloride, as well as those under the INCI names Quaternium-27 and quaternium-83 known imidazolium compounds. The long alkyl chains of the above surfactants are preferred 10 to 18 carbon atoms.

Esterquats are known substances which contain both at least one ester function and at least one quaternary ammonium group as a structural element. Preferred ester quats are quaternized ester salts of fatty acids with triethanolamine, quaternized ester salts of fatty acids with diethanolalkylamines and quaternized ester salts of fatty acids with 1,2-dihydroxypropyldialkylamines. Such products are marketed under the trade names Stepantex® ^{®, ®} and Dehyquart® Armocare® ^®. The products Armocare ^® VGH-70, a N, N-bis (2-palmitoyloxyethyl) dimethylammonium chloride, as well as Dehyquart ^® F-75, Dehyquart ^® C-4046, Dehyquart ^® L80 and Dehyquart ^® AU-35 are examples of such esterquats.

The alkylamidoamines are usually prepared by amidation of natural or synthetic fatty acids and fatty acid cuts with dialkylaminoamines. A particularly suitable according to the invention Compound from this group of substances under the name Tegoamid ^® S 18 commercial stearamidopropyl dimethylamine is.

The Cationic surfactants are preferred in amounts in the compositions according to the invention from 0.05 to 10 wt .-%, based on the total agent. Amounts of 0.1 to 5 wt .-% are particularly preferred.

Of the Total surfactant content in the cosmetic agent is 5 to 35%, preferably 7 to 25% and in particular 8 to 15% - related on the total weight of the agent.

In a particularly preferred embodiment of the invention, the cosmetic compositions continue to contain at least a cationic polymer.

Cationic polymers are polymers which have groups in the main and / or side chain which may be "temporary" or "permanent" cationic. According to the invention, "permanently cationic" refers to those polymers which have a cationic group independently of the pH of the agent These are generally polymers which contain a quaternary nitrogen atom, for example in the form of an ammonium group Preferred cationic groups are quaternary ammonium groups In particular, those polymers in which the quaternary ammonium group is bonded via a C _1-4 hydrocarbon group to a polymer main chain composed of acrylic acid, methacrylic acid or derivatives thereof have proven to be particularly suitable.

in der R¹⁷ = -H oder -CH₃ ist, R¹⁸, R¹⁹ und R²⁰ unabhängig voneinander ausgewählt sind aus C_1-4-Alkyl-, -Alkenyl- oder -Hydroxyalkylgruppen, m = 1, 2, 3 oder 4, n eine natürliche Zahl und X^– ein physiologisch verträgliches organisches oder anorganisches Anion ist, sowie Copolymere, bestehend im wesentlichen aus den in Formel (III) aufgeführten Monomereinheiten sowie nichtionogenen Monomereinheiten, sind besonders bevorzugte kationische Polymere. Im Rahmen dieser Polymere sind diejenigen erfindungsgemäß bevorzugt, für die mindestens eine der folgenden Bedingungen gilt:

• – R¹⁷ steht für eine Methylgruppe
• – R¹⁸, R¹⁹ und R²⁰ stehen für Methylgruppen
• – m hat den Wert 2.

Homopolymers of the general formula (IV),

where R ^{17 is} -H or -CH ₃ , R ¹⁸ , R ¹⁹ and R ^{20 are} independently selected from C _1-4 alkyl, alkenyl or hydroxyalkyl groups, m = 1, 2, 3 or 4 , n is a natural number and X ^{- is} a physiologically acceptable organic or inorganic anion, as well as copolymers consisting essentially of the monomer units listed in formula (III) and nonionic monomer units, are particularly preferred cationic polymers. In the context of these polymers, preference is given to those according to the invention for which at least one of the following conditions applies:

• - R ¹⁷ is a methyl group
• - R ¹⁸ , R ¹⁹ and R ²⁰ are methyl groups
• - m has the value 2.

Suitable physiologically tolerated counterions X ^- include, for example, halide ions, sulfate ions, phosphate ions, methosulfate ions and organic ions such as lactate, citrate, tartrate and acetate ions. Preference is given to halide ions, in particular chloride.

One suitable homopolymer is the, if desired crosslinked, poly (methacryloyloxyethyltrimethylammonium chloride) with the INCI name Polyquaternium-37.

The Networking can if desired with the help of multiple olefinically unsaturated compounds, for example Divinylbenzene, tetraallyloxyethane, methylenebisacrylamide, diallylether, Polyallylpolyglycerylether, or allyl ethers of sugars or sugar derivatives such as erythritol, pentaerythritol, arabitol, mannitol, sorbitol, sucrose or glucose. Methylenebisacrylamide is a preferred one Crosslinking agent.

The homopolymer is preferably used in the form of a nonaqueous polymer dispersion which should not have a polymer content of less than 30% by weight. Such polymer dispersions are (under the names Salcare ^® SC 95 about 50% polymer content, additional components: mineral oil (INCI name: Mineral Oil) and tridecyl-polyoxypropylene-polyoxyethylene-ether (INCI name: PPG-1 trideceth-6) ) and Salcare ^® SC 96 (about 50% polymer content, additional components: mixture of diesters of propylene glycol (with a mixture of caprylic and capric acid INCI name: propylene glycol Dicaprylate / Dicaprate) and Tridecylpolyoxypropylen polyoxyethylene ether (INCI name : PPG-1-trideceth-6)) are commercially available.

Copolymers with monomer units of the formula (VI) are contained as nonionic monomer units Preferred acrylamide, methacrylamide, acrylic acid-C _1-4 alkyl esters and methacrylic acid-C _1-4 alkyl esters. Among these nonionic monomers, the acrylamide is particularly preferred. These copolymers can also be crosslinked, as described above in the case of the homopolymers. A copolymer preferred according to the invention is the crosslinked acrylamide-methacryloyloxyethyltrimethylammonium chloride copolymer. Such copolymers in which the monomers are present in a weight ratio of about 20:80, are commercially available as approximately 50% non-aqueous polymer dispersion 92 under the name Salcare ^® SC.

• – quaternisierte Cellulose-Derivate, wie sie unter den Bezeichnungen Celquat^® und Polymer JR^® im Handel erhältlich sind. Die Verbindungen Celquat^® H 100, Celquat^® L 200 und Polymer JR^®400 sind bevorzugte quaternierte Cellulose-Derivate,
• – kationische Alkylpolyglycoside gemäß der DE-PS 44 13 686 ,
• – kationiserter Honig, beispielsweise das Handelsprodukt Honeyquat^® 50,
• – kationische Guar-Derivate, wie insbesondere die unter den Handelsnamen Cosmedia^®Guar und Jaguar^® vertriebenen Produkte,
• – Polysiloxane mit quaternären Gruppen, wie beispielsweise die im Handel erhältlichen erhältlichen Produkte Q2-7224 (Hersteller: Dow Corning; ein stabilisiertes Trimethylsilylamodimethicon), Dow Corning^® 929 Emulsion (enthaltend ein hydroxyl-aminomodifiziertes Silicon, das auch als Amodimethicone bezeichnet wird), SM-2059 (Hersteller: General Electric), SLM-55067 (Hersteller: Wacker) sowie Abil^®-Quat 3270 und 3272 (Hersteller: Th. Goldschmidt; diquaternäre Polydimethylsiloxane, Quaternium-80),
• – polymere Dimethyldiallylammoniumsalze und deren Copolymere mit Estern und Amiden von Acrylsäure und Methacrylsäure. Die unter den Bezeichnungen Merquat^®100 (Poly(dimethyldiallylammoniumchlorid)) und Merquat^®550 (Dimethyldiallylammoniumchlorid- Acrylamid-Copolymer) im Handel erhältlichen Produkte sind Beispiele für solche kationischen Polymere,
• – Copolymere des Vinylpyrrolidons mit quaternierten Derivaten des Dialkylaminoalkylacrylats und -methacrylats, wie beispielsweise mit Diethylsulfat quaternierte Vinylpyrrolidon-Dimethylaminoethylmethacrylat-Copolymere. Solche Verbindungen sind unter den Bezeichnungen Gafquat^®734 und Gafquat^®755 im Handel erhältlich,
• – Vinylpyrrolidon-Vinylimidazoliummethochlorid-Copolymere, wie sie unter den Bezeichnungen Luviquat^® FC 370, FC 550, FC 905 und HM 552 angeboten werden,
• – quaternierter Polyvinylalkohol, sowie die unter den Bezeichnungen
• – Polyquaternium 2,
• – Polyquaternium 17,
• – Polyquaternium 18 und
• – Polyquaternium 27 bekannten Polymeren mit quartären Stickstoffatomen in der Polymerhauptkette.

Further preferred cationic polymers are, for example

• - Quaternized cellulose derivatives, such as those under the names Celquat ^® and Polymer JR ^® commercially available. The compounds Celquat ^® H 100, Celquat L 200 and Polymer JR ^{® ®} 400 are preferred quaternized cellulose derivatives
• Cationic alkyl polyglycosides according to DE-PS 44 13 686 .
• - cationized honey, for example the commercial product Honeyquat ^® 50,
• - cationic guar derivatives, such as in particular the products sold under the trade names Cosmedia® ^® Guar and Jaguar ^®,
• - polysiloxanes with quaternary groups, such as the commercially available products Q2-7224 (manufacturer: Dow Corning; a stabilized trimethylsilylamodimethicone), Dow Corning ^® 929 Emulsion (containing a hydroxylamino-modified silicone which is also known as amodimethicone), SM -2059 (manufacturer: General Electric), SLM-55067 (manufacturer: Wacker) and Abil ^® quat 3270 and 3272 (manufacturer: Th Goldschmidt; diquaternary polydimethylsiloxanes, quaternium-80).,
• - Dimethyldiallylammoniumsalze polymeric and their copolymers with esters and amides of acrylic acid and methacrylic acid. Under the names Merquat ^® 100 (Poly (dimethyldiallylammonium chloride)) and Merquat ^® 550 (dimethyldiallylammonium chloride-acrylamide copolymer) are examples of such cationic polymers,
• - Copolymers of vinylpyrrolidone with quaternized derivatives of dialkylaminoalkyl acrylate and methacrylate, such as diethyl sulfate quaternized vinylpyrrolidone-dimethylaminoethyl methacrylate copolymers. Such compounds are sold under the names Gafquat ^® 734 and Gafquat ^® 755 commercially,
• - vinylpyrrolidone vinylimidazoliummethochloride copolymers, such as those offered under the names Luviquat.RTM ^® FC 370, FC 550, FC 905 and HM 552,
• - Quaternized polyvinyl alcohol, as well as those under the names
• - Polyquaternium 2,
• - Polyquaternium 17,
• - Polyquaternium 18 and
• Polyquaternium 27 known polymers with quaternary nitrogen atoms in the polymer main chain.

Can be used as cationic polymers are sold under the names Polyquaternium-24 (commercial product z. B. Quatrisoft ^® LM 200), known polymers. , Gaffix ^® VC 713 (manufactured by ISP): Also according to the invention can be used the copolymers of vinylpyrrolidone, such as the commercial products Copolymer 845 (ISP manufacturer) are Gafquat ^® ASCP 1011, Gafquat ^® HS 110, Luviquat ^® 8155 and Luviquat ^® MS 370 available are.

Other cationic polymers of the present invention, the "temporarily cationic" polymers. These polymers are usually contain an amino group present at certain pH values as a quaternary ammonium group and hence cationic. For example, chitosan and its derivatives are preferred, such as for example, under the trade designations Hydagen ^® CMF, Hydagen® ^® HCMF, Kytamer ^® PC and Chitolam ^® NB / 101 are freely available commercially. chitosans are deacetylated, in different degrees of deacetylation and varying degrees of degradation (molecular weights) are commercially available. Their preparation is for example in DE 44 40 625 A1 and in DE 1 95 03 465 A1 described.

Particularly suitable chitosans have a degree of deacetylation of at least 80% and a molecular weight of 5 × 10 ⁵ to 5 × 10 ⁶ (g / mol).

For the production of preparations according to the invention, the chitosan must be converted into the salt form. This can be done by dissolving in dilute aqueous acids. Suitable acids are both mineral acids such as hydrochloric acid, sulfuric acid and phosphoric acid and organic acids, for example low molecular weight carboxylic acids, polycarboxylic acids and hydroxycarboxylic acids. Furthermore, higher molecular weight alkyl sulfonic acids or alkyl sulfuric acids or organophosphoric acids can be used, provided that they have the required physiological compatibility. Suitable acids for converting the chitosan into the salt form are, for example, acetic acid, glycolic acid, tartaric acid, malic acid, citric acid, lactic acid, 2-pyrrolidinone-5-carboxylic acid, benzoic acid or salicylic acid. Preference is given to using low molecular weight hydroxycarboxylic acids, for example glycolic acid or lactic acid.

In a particularly preferred embodiment The invention is at least one polymer as cationic polymer from the group Polyquaternium-7 (Merquat 550), Polyquaternium-6, Polyquaternium-10 and / or a cationic guar derivative in the contain cosmetic products.

The cationic polymers are preferred in amounts in the compositions according to the invention from 0.01 to 5 wt .-%, based on the total agent. Amounts of 0.05 to 3, in particular from 0.1 to 2 wt .-%, are particularly prefers.

In a further preferred embodiment moreover, the agents according to the invention additionally contain at least a component from the group of water-insoluble oil components, vitamins, provitamins, protein hydrolysates, plant extracts, the UV filter, the amino acids, the water-insoluble Silicones, the water-soluble Silicones and / or amodimethicones.

When water-insoluble oil components According to the invention, plant-based, mineral or synthetic oils, as well as mixtures of these components.

When natural (vegetable) oils become common Triglycerides and mixtures of triglycerides used. preferred natural oils in the sense of the invention are coconut oil, (sweet) almond oil, walnut oil, peach kernel oil, avocado oil, tea tree oil (Tea Tree Oil), soybean oil, Sesame oil, Sunflower oil, tsubaki, Evening primrose oil, rice bran oil, Palm kernel oil, Mango oil, Meadowfoam seed oil, Safflower oil, macadamia nut oil, Grape seed oil, Apricot kernel oil, Babssuöl, Olive oil, Wheat germ oil, Pumpkin seed oil, mallow oil, hazelnut oil, safflower oil, canola oil, sasanqua oil, jojoba oil and shea butter.

As mineral oils are used in particular mineral oils, paraffin and Isoparaffinöle and synthetic hydrocarbons. An inventively employable hydrocarbon is for example that available as a commercial product 1,3-di- (2-ethylhexyl) -cyclohexane (Cetiol ^® S).

When synthetic oils come silicone compounds, especially dialkyl and alkylaryl silicones, such as dimethylpolysiloxane and methylphenylpolysiloxane, and their hydroxy-terminated, alkoxylated and quaternized analogs into consideration. examples for such silicones are those of Dow Corning under the designations DC 190, DC 200, DC 344 and DC 345 (cyclomethicone) Products.

As an oil component may continue to serve a dialkyl ether.

Usable according to the invention Dialkyl ethers are in particular di-n-alkyl ethers with a total of between 12 to 36 C-atoms, in particular 12 to 24 C-atoms, such as Di-n-octyl ether, di-n-decyl ether, di-n-nonyl ether, Di-n-undecyl ether, di-n-dodecyl ether, n-hexyl n-octyl ether, n-octyl n-decyl ether, n-decyl n-undecyl ether, n-undecyl-n-dodecyl ether and n-hexyl n-undecyl ether and di-tert-butyl ether, di-iso-pentyl ether, Di-3-ethyldecyl ether, tert-butyl-n-octyl ether, iso-pentyl-n-octyl ether and 2-methylpentyl-n-octyl ether.

According to the invention particularly preferred is the di-n-octyl ether, which is commercially available under the name Cetiol ^® OE.

The agents according to the invention contain the water-insoluble oil component preferably in an amount range of 0.1 to 5 wt .-%, in particular from 0.5 to 2% by weight, based on the total weight of the composition.

In a further preferred embodiment The invention can the effect of the active ingredient combination of the invention further fatty substances can be further optimized. Among others Fats are understood to be fatty acids, fatty alcohols as well as natural and synthetic waxes which are both solid and liquid aqueous dispersion may be present.

As fatty acids can be used linear and / or branched, saturated and / or unsaturated fatty acids with 6-30 carbon atoms. Preferred are fatty acids with 10-22 carbon atoms. Among these could be mentioned, for example, isostearic as the commercial products Emersol ^® 871 and Emersol ^® 875, and isopalmitic acids such as the commercial product Edenor ^® IP 95, and all other trade among the designations Edenor ^® (Cognis) distributed fatty acids. Further typical examples of such fatty acids are caproic, caprylic, 2-ethylhexanoic, capric, lauric, isotridecanoic, myristic, palmitic, palmitoleic, stearic, isostearic, oleic, elaidic, petroselic, linoleic, linolenic as well as their technical mixtures, which are obtained, for example, in the pressure splitting of natural fats and oils, in the oxidation of aldehydes from Roelen's oxosynthesis or the dimerization of unsaturated fatty acids. Particularly preferred are usually the fatty acid cuttings obtainable from coconut oil or palm oil; In particular, the use of stearic acid is usually preferred.

The Amount used is thereby 0,1-15 % By weight, based on the total mean. In a preferred embodiment is the amount 0.5-10 Wt.%, Of which very particularly advantageous amounts of 1-5 wt.% Are.

As fatty alcohols it is possible to use saturated, mono- or polyunsaturated, branched or unbranched fatty alcohols with C ₆ -C ₃₀ -, preferably C ₁₀ -C ₂₂ - and very particularly preferably C ₁₂ -C ₂₂ -carbon atoms. Decanols, octanols, dodecadienol, decadienol, oleyl alcohol, eruca alcohol, ricinoleic alcohol, stearyl alcohol, isostearyl alcohol, cetyl alcohol, lauryl alcohol, myristyl alcohol, arachidyl alcohol, caprylic alcohol, capric alcohol, linoleyl alcohol, linolenyl alcohol and behenyl alcohol are, for example, decanol, octanolol, dodecadienol, decadienol , as well as their Guerbet alcohols, this list should have exemplary and non-limiting character. However, the fatty alcohols are derived from preferably natural fatty acids, which can usually be based on recovery from the esters of fatty acids by reduction. Also usable according to the invention are those fatty alcohol cuts which are produced by reduction of naturally occurring triglycerides such as beef tallow, palm oil, peanut oil, rapeseed oil, cottonseed oil, soybean oil, sunflower oil and linseed oil or fatty acid esters formed from their transesterification products with corresponding alcohols, and thus represent a mixture of different fatty alcohols. Such substances are, for example, under the names Stenol ^® such as Stenol ^® 1618 or Lanette ^® such as Lanette ^® O or Lorol ^®, for example, Lorol ^® C8, Lorol C14 ^®, Lorol C18 ^{®, ®} Lorol C8-18, HD-Ocenol ^®, Crodacol ^® such as Crodacol ^® CS, Novol ^®, Eutanol ^® G, Guerbitol ^® 16, Guerbitol ^® 18, Guerbitol ^® 20, Isofol ^® 12, Isofol ^® 16, Isofol ^® 24, Isofol ^® 36, Isocarb ^® 12, Isocarb ^® 16 or acquire Isocarb® ^® 24 for sale. Of course, wool wax alcohols, as are commercially available, for example under the names of Corona ^®, White Swan ^®, Coronet ^® or Fluilan ^® can be used according to the invention.

The Fatty alcohols are used in amounts of 0.1-20 wt .-%, based on the entire preparation, preferably used in amounts of 0.1-10 wt .-%.

When natural or synthetic waxes can used according to the invention be solid paraffins or isoparaffins, carnauba waxes, bee waxes, Candelilla, ozokerite, ceresin, spermaceti, sunflower wax, Fruit waxes such as apple wax or citrus wax, Microwachse made of PE or PP. Such waxes are available for example via the Fa. Kahl & Co., Trittau.

• – Esteröle. Unter Esterölen sind zu verstehen die Ester von C₆–C₃₀-Fettsäuren mit C₂–C₃₀-Fettalkoholen. Bevorzugt sind die Monoester der Fettsäuren mit Alkoholen mit 2 bis 24 C-Atomen. Beispiele für eingesetzte Fettsäurenanteile in den Estern sind Capronsäure, Caprylsäure, 2-Ethylhexansäure, Caprinsäure, Laurinsäure, Isotridecansäure, Myristinsäure, Palmitinsäure, Palmitoleinsäure, Stearinsäure, Isostearinsäure, Ölsäure, Elaidinsäure, Petroselinsäure, Linolsäure, Linolensäure, Elaeostearinsäure, Arachinsäure, Gadoleinsäure, Behensäure und Erucasäure sowie deren technische Mischungen, die z.B. bei der Druckspaltung von natürlichen Fetten und Ölen, bei der Oxidation von Aldehyden aus der Roelen'schen Oxosynthese oder der Dimerisierung von ungesättigten Fettsäuren anfallen. Beispiele für die Fettalkoholanteile in den Esterölen sind Isopropylalkohol, Capronalkohol, Caprylalkohol, 2-Ethylhexylalkohol, Caprinalkohol, Laurylalkohol, Isotridecylalkohol, Myristylalkohol, Cetylalkohol, Palmoleylalkohol, Stearylalkohol, Isostearylalkohol, Oleylalkohol, Elaidylalkohol, Petroselinylalkohol, Linolylalkohol, Linolenylalkohol, Elaeostearylalkohol, Arachylalkohol, Gadoleylalkohol, Behenylalkohol, Erucylalkohol und Brassidylalkohol sowie deren technische Mischungen, die z.B. bei der Hochdruckhydrierung von technischen Methylestern auf Basis von Fetten und Ölen oder Aldehyden aus der Roelen'schen Oxosynthese sowie als Monomerfraktion bei der Dimerisierung von ungesättigten Fettalkoholen anfallen. Erfindungsgemäß besonders bevorzugt sind Isopropylmyristat (Rilanit^® IPM), Isononansäure-C16-18-alkylester (Cetiol^® SN), 2-Ethylhexylpalmitat (Cegesoft^® 24), Stearinsäure-2-ethylhexylester (Cetiol^® 868), Cetyloleat, Glycerintricaprylat, Kokosfettalkohol-caprinat/-caprylat (Cetiol^® LC), n-Butylstearat, Oleylerucat (Cetiol^® J 600), Isopropylpalmitat (Rilanit^® IPP), Oleyl Oleate (Cetiol^®), Laurinsäurehexylester (Cetiol^® A), Di-n-butyladipat (Cetiol^® B), Myristylmyristat (Cetiol^® MM), Cetearyl Isononanoate (Cetiol^® SN), Ölsäuredecylester (Cetiol^® V).
• – Dicarbonsäureester wie Di-n-butyladipat, Di-(2-ethylhexyl)-adipat, Di-(2-ethylhexyl)-succinat und Di-isotridecylacelaat sowie Diolester wie Ethylenglykol-dioleat, Ethylenglykol-di-isotridecanoat, Propylenglykol-di(2-ethylhexanoat), Propylenglykol-di-isostearat, Propylenglykol-di-pelargonat, Butandiol-di-isostearat, Neopentylglykoldicaprylat,
• – symmetrische, unsymmetrische oder cyclische Ester der Kohlensäure mit Fettalkoholen, beispielsweise beschrieben in der DE-OS 197 56 454 , Glycerincarbonat oder Dicaprylylcarbonat (Cetiol^® CC),
• – ethoxylierte oder nicht ethoxylierte Mono,- Di- und Trifettsäureester von gesättigten und/oder ungesättigten linearen und/oder verzweigten Fettsäuren mit Glycerin, wie beispielsweise Monomuls^® 90-O18, Monomuls^® 90-L12, Cetiol^® HE oder Cutina^® MD.

Other fatty substances are, for example

• - Ester oils. Ester oils are understood as meaning the esters of C ₆ -C ₃₀ -fatty acids with C ₂ -C ₃₀ -fatty alcohols. The monoesters of the fatty acids with alcohols having 2 to 24 carbon atoms are preferred. Examples of fatty acid components used in the esters are caproic acid, caprylic acid, 2-ethylhexanoic acid, capric acid, lauric acid, isotridecanoic acid, myristic acid, palmitic acid, palmitoleic acid, stearic acid, isostearic acid, oleic acid, elaidic acid, petroselinic acid, linoleic acid, linolenic acid, elaeostearic acid, arachidic acid, gadoleic acid, behenic acid and Erucic acid and its technical mixtures, for example, in the pressure splitting of natural fats and oils, in the oxidation of aldehydes from the Roelen oxo synthesis or the dimerization of unsaturated fatty acids incurred. Examples of the fatty alcohol components in the ester oils are isopropyl alcohol, caproic alcohol, capryl alcohol, 2-ethylhexyl alcohol, capric alcohol, lauryl alcohol, isotridecyl alcohol, myristyl alcohol, cetyl alcohol, palmoleyl alcohol, stearyl alcohol, isostearyl alcohol, oleyl alcohol, elaidyl alcohol, petroselinyl alcohol, linolyl alcohol, linolenyl alcohol, elaeostearyl alcohol, arachyl alcohol, gadoleyl alcohol, Behenyl alcohol, erucyl alcohol and brassidyl alcohol and their technical mixtures, for example, in the high-pressure hydrogenation of technical methyl esters based on fats and oils or aldehydes from the Roelen oxo synthesis and as a monomer fraction in the dimerization of unsaturated fatty alcohols incurred. According to the invention, particularly preferred are isopropyl myristate (IPM Rilanit ^®), isononanoic acid C16-18 alkyl ester (Cetiol ^® SN), 2-ethylhexyl palmitate (Cegesoft ^® 24), stearic acid-2-ethylhexyl ester (Cetiol ^® 868), cetyl oleate, glycerol tricaprylate, Kokosfettalkohol- caprate / caprylate (Cetiol ^® LC), n-butyl stearate, oleyl erucate (Cetiol ^® J 600), isopropyl palmitate (IPP Rilanit ^®), oleyl Oleate (Cetiol ^®), hexyl laurate (Cetiol ^® A), di-n-butyl adipate (Cetiol ^® B), myristyl myristate (Cetiol ^® MM), Ce tearyl Isononanoate (Cetiol ^® SN), decyl oleate (Cetiol ^® V).
• Dicarboxylic acid esters such as di-n-butyl adipate, di- (2-ethylhexyl) adipate, di- (2-ethylhexyl) succinate and di-isotridecyl acelate, and diol esters such as ethylene glycol dioleate, ethylene glycol diisotridecanoate, propylene glycol di (2 ethylhexanoate), propylene glycol diisostearate, propylene glycol di-pelargonate, butanediol diisostearate, neopentyl glycol dicaprylate,
• Symmetrical, unsymmetrical or cyclic esters of carbonic acid with fatty alcohols, for example described in US Pat DE-OS 197 56 454 , Glycerol carbonate or dicaprylyl carbonate (Cetiol ^® CC),
• - ethoxylated or non ethoxylated mono, - di- and trifatty acid esters of saturated and / or unsaturated linear and / or branched fatty acids with glycerol such as ^® Monomuls 90-O18, Monomuls 90-L12 ^®, Cetiol ^® HE or Cutina ^® MD.

The Amount used is 0.1-50 Wt.% Based on the total agent, preferably 0.1-20 wt.% And more preferably 0.1-15 % By weight relative to the total mean.

The Total amount of oil and fat components in the compositions of the invention is usually 6-45% by weight, based on the total mean. Amounts of 10-35% by weight are preferred according to the invention.

Under preferred according to the invention Vitamins, provitamins and vitamin precursors and their derivatives are to be understood as those representatives who usually belong to groups A, B, C, E, F and H are assigned.

The group of substances called vitamin A includes retinol (vitamin A ₁ ) and 3,4-didehydroretinol (vitamin A ₂ ). The β-carotene is the provitamin of retinol. As vitamin A component according to the invention, for example, vitamin A acid and its esters, vitamin A aldehyde and vitamin A alcohol and its esters such as the palmitate and the acetate into consideration. The agents according to the invention preferably contain the vitamin A component in amounts of 0.01-1% by weight, based on the total preparation.

The vitamin B group or the vitamin B complex include, among others
Vitamin B ₁ (thiamine)
Vitamin B ₂ (riboflavin)
Vitamin B ₃ . Under this name, the compounds nicotinic acid and nicotinamide (niacinamide) are often performed. Preferred according to the invention is the nicotinic acid amide, which is preferably present in the agents according to the invention in amounts of from 0.05 to 1% by weight, based on the total agent.

Vitamin B ₅ (pantothenic acid, panthenol and pantolactone). Panthenol and / or pantolactone are preferably used in the context of this group. Derivatives of panthenol which can be used according to the invention are, in particular, the esters and ethers of panthenol and also cationically derivatized panthenols. Individual representatives are for example the Panthenoltriacetat, the Panthenolmonoethylether and its monoacetate as well as in the WO 92/13829 disclosed cationic panthenol derivatives.

Vitamin B ₆ (pyridoxine and pyridoxamine and pyridoxal).

The mentioned compounds of the vitamin B group are in the inventive compositions preferably in amounts of 0.01-2 Wt .-%, based on the total agent included. Amounts of 0.03-1% by weight are particularly preferred.

vitamin C (ascorbic acid). Vitamin C is preferred in the compositions used in the invention in amounts of 0.01 to 3 wt .-%, based on the total agent used. The use in the form of palmitic acid ester, glucosides or Phosphates may be preferred. The use in combination with Tocopherols may also be preferred.

vitamin E (tocopherols, especially α-tocopherol). Tocopherol and its derivatives, including in particular the esters such as the acetate, the nicotinate, the phosphate and the succinate fall, are used in the invention Agents preferably in amounts of 0.01-1 wt .-%, based on the entire medium, included.

vitamin F. By the term "vitamin F "are usually essential fatty acids, especially linoleic acid, linolenic and arachidonic acid, Understood.

vitamin H. The vitamin H is the compound (3aS, 4S, 6aR) -2-oxohexahydrothienol [3,4-d] imidazole-4-valeric acid, for the But in the meantime, the trivial name Biotin has prevailed. biotin is used in the invention Agents preferably in amounts of 0.0001 to 1.0 wt .-%, in particular in Amounts of 0.001 to 0.01 wt .-% included.

Prefers contain the agents of the invention Vitamins, provitamins and vitamin precursors from groups A, E, F and H. Of course can also contain several vitamins and vitamin precursors at the same time be.

The Total use of vitamins, provitamins, vitamin precursors and their derivatives in the compositions according to the invention is - based on the total weight of the agent - 0.01 to 5 wt .-%, preferably 0.02 to 4 wt .-% and in particular 0.05 to 3 wt .-%.

When Protein hydrolyzates in the context of the invention become protein hydrolysates and / or amino acids and their derivatives (H) understood. Protein hydrolysates are product mixtures, by acid, base or enzymatically catalyzed degradation of Proteins (proteins) to be obtained. The term protein hydrolyzates according to the invention also Totalhydrolysate as well as individual amino acids and their derivatives as well as mixtures of different amino acids understood. Furthermore, according to the invention from amino acids and amino acid derivatives understood polymers understood by the term protein hydrolysates. The latter include, for example, polyalanine, polyasparagine, polyserine etc. to count. Further examples of usable according to the invention Compounds are L-alanyl-L-proline, Polyglycine, glycyl-L-glutamine or D / L-methionine-S-methylsulfonium chloride. Of course can According to the invention also β-amino acids and their derivatives, such as β-alanine, anthranilic or hippuric acid be used. The molecular weight of the inventively usable Protein hydrolysates is between 75, the molecular weight of glycine, and 200,000, preferably the molecular weight 75 to 50,000 and most preferably 75 to 20000 daltons.

According to the invention, protein hydrolysates both herbal and animal or marine or synthetic Origin are used.

Animal protein hydrolysates are, for example, elastin, collagen, keratin, silk and milk protein protein hydrolysates, which may also be present in the form of salts. Such products are, for example, under the trademarks Dehylan ^® (Cognis), Promois® ^® (Interorgana) Collapuron ^® (Cognis), Nutrilan® ^® (Cognis), Gelita-Sol ^® (German Gelatinefabriken Stoess & Co), Lexein ^® (Inolex) and kerasol tm ^® (Croda) sold.

Preferred according to the invention are the protein hydrolysates of plant origin, eg. Soybean, almond, pea, potato and wheat protein hydrolysates. Such products are, for example, under the trademarks Gluadin ^® (Cognis), diamine ^® (Diamalt) ^® (Inolex), Hydrosoy ^® (Croda), hydro Lupine ^® (Croda), hydro Sesame ^® (Croda), Hydro tritium ^® (Croda) and Crotein ^® (Croda) available.

Although the use of the protein hydrolysates is preferred as such, amino acid mixtures otherwise obtained may be used in their place, if appropriate. Also possible is the use of derivatives of protein hydrolysates, for example in the form of their fatty acid condensation products. Such products are sold, for example, under the names Lamepon® ^® (Cognis), Lexein ^® (Inolex), Crolastin ^® (Croda) or crotein ^® (Croda).

The Protein hydrolysates or their derivatives are in the agents according to the invention preferably in amounts of 0.1 to 10 wt .-%, based on the total Means, included. Amounts of 0.1 to 5 wt .-% are particularly preferred.

According to the invention preferred are plant extracts of green tea, oak bark, stinging nettle, Witch hazel, hops, henna, chamomile, burdock root, horsetail, Hawthorn, Linden flowers, Almond, aloe vera, spruce needle, horse chestnut, sandalwood, juniper, Coconut, Mango, Apricot, Lime, Wheat, Kiwi, Melon, Orange, Grapefruit, Sage, Rosemary, Birch, Mallow, Meadowfoam, Quendel, Yarrow, Thyme, Melissa, hominy, coltsfoot, vanilla, marshmallow, meristem, ginseng and ginger root included.

Especially According to the invention, the extracts are preferred from green Tea, almond, aloe vera, coconut, Mango, apricot, lime, wheat, vanilla, kiwi and melon and in particular prefers the extracts of aloe vera, vanilla and melon.

Usually These extracts are produced by extraction of the whole plant. However, it may also be preferred in individual cases, the extracts exclusively from flowers and / or scrolling to produce the plant.

When Extraction agent for the preparation of said plant extracts can Water, alcohols and mixtures thereof are used. Under the alcohols are lower alcohols such as ethanol and isopropanol, but especially polyhydric alcohols such as ethylene glycol and propylene glycol, both as sole extractant and in mixture with Water, preferably. Plant extracts based on water / propylene glycol in relation to 1:10 to 10: 1 have proven to be particularly suitable.

The Plant extracts can according to the invention both in pure as well as in diluted Form are used. If used in dilute form, they usually contain about 2-80 Wt .-% of active substance and as a solvent the extractant or extractant mixture used in their extraction.

The Plant extracts are in the inventive compositions - related on her weight - in in an amount of 0.01 to 5% by weight, preferably 0.02 to 4% by weight and in particular 0.05 to 3 wt .-% used.

Farther can in a preferred embodiment the invention increases the effect of the preparations by UV filters become. The invention to be used UV filters are subject to structural and physical considerations Features no general restrictions. Rather, they are suitable all UV filters that can be used in the cosmetics sector, their absorption maximum in the UVA (315-400 nm) -, in the UVB (280-315nm) - or in UVC (<280 nm) range. UV filter with an absorption maximum in the UVB range, especially in the range of about 280 to about 300 nm, are particularly prefers.

The used according to the invention UV filters can for example, selected are substituted benzophenones, p-aminobenzoic acid esters, diphenylacrylates, cinnamic, salicylates, Benzimidazoles and o-aminobenzoic acid esters.

Examples of UV filters which can be used according to the invention are 4-aminobenzoic acid, N, N, N-trimethyl-4- (2-oxoborn-3-ylidenemethyl) aniline-methylsulfate, 3,3,5-trimethyl-cyclohexylsalicylate (homosalates), 2-hydroxy-4-methoxy-benzophenone (benzophenone-3; Uvinul ^® M 40, Uvasorb MET ^{®, ®} Neo Heliopan BB, Eusolex ^® 4360), 2-phenylbenzimidazole-5-sulfonic acid and potassium, sodium and triethanolamine salts ( Phenylbenzimidazole Sulfonic Acid; Parsol ^® HS; Neo Heliopan Hydro ^®), 3,3 '- (1,4-phenylenedimethylene) -bis (7,7-dimethyl-2-oxo-bicyclo [2.2.1] hept-1- yl-methane sulfonic acid) and salts thereof, 1- (4-tert-butylphenyl) -3- (4-methoxyphenyl) Methoxydibenzoylmethane -propane-1,3-dione (butyl; Parsol ^® 1789 Eusolex ^® 9020), α - (2-oxoborn-3-ylidene) toluene-4-sulfonic acid and salts thereof, ethoxylated 4-aminobenzoic acid ethyl ester (PEG-25 PABA; Uvinul ^® P 25), 4-methylaminobenzoic acid di-2-ethylhexyl (octyl dimethyl PABA; Uvasorb ^® DMO, Escalol ^® 507, Eusolex ^® 6007), salicylic acid-2-ethylhex ylester (octyl salicylate; Escalol ^® 587, Neo Heliopan ^® OS, Uvinul ^® O18), 4-methoxycinnamic acid isopentyl (isoamyl p-methoxycinnamate; Neo Heliopan ^® E 1000), 4-methoxycinnamic acid 2-ethylhexyl ester (Octyl Methoxycinnamate; Parsol ^® MCX, Escalol ^® 557, Neo Heliopan AV ^®), 2-hydroxy-4-methoxybenzophenone-5-sulfonic acid and its sodium salt (Benzophenone-4; Uvinul ^® MS 40; Uvasorb S 5 ^®), 3- (4'-methylbenzylidene) -D, L-camphor (4-methylbenzylidene camphor; Parsol ^® 5000, Eusolex ^® 6300), 3-benzylidene camphor (3-benzylidene camphor), 4-isopropylbenzyl, 2,4,6-trianilino- (p-carbo-2'- ethylhexyl-1'-oxi) -1,3,5-triazine, 3-imidazol-4-yl-acrylic acid and its ethyl ester, polymers of N - {(2 and 4) - [2-oxoborn-3-ylidenemethyl] benzyl } -acrylamids, 2,4-dihydroxy (benzophenone-1; Uvasorb ^® 20 H, Uvinul ^® 400), 1,1'-Diphenylacrylonitrilsäure-2-ethylhexyl ester (Octocrylene; Eusolex ^® OCR, Neo Heliopan ^® Type 303, Uvinul ^® N 539 SG), o-aminobenzoic acid menthyl ester (Menthyl Anthranilate; Neo He liopan ^® MA), 2,2 ', 4,4'-tetrahydroxy benzophenone (benzophenone-2; Uvinul ^® D-50), 2,2'-dihydroxy-4,4'-dimethoxybenzophenone (Benzophenone-6), 2,2'-dihydroxy-4,4'-dimethoxybenzophenone-5-sodium sulfonate, and 2-cyano-3, 3-diphenylacrylate 2'-ethylhexyl acrylate. Preference is given to 4-aminobenzoic acid, N, N, N-trimethyl-4- (2-oxoborn-3-ylidenemethyl) aniline methylsulfate, 3,3,5-trimethylcyclohexyl salicylate, 2-hydroxy-4-methoxybenzophenone , 2-phenylbenzimidazole-5-sulfonic acid and its potassium, sodium and triethanolamine salts, 3,3 '- (1,4-phenylenedimethylene) -bis (7,7-dimethyl-2-oxo-bicyclo- [2.2.1] hept-1-yl-methanesulfonic acid) and its salts, 1- (4-tert-butylphenyl) -3- (4-methoxyphenyl) -propane-1,3-dione, α- (2-oxoborn-3-yl) yliden) -toluene-4-sulfonic acid and its salts, ethoxylated 4-aminobenzoic acid ethyl ester, 2-ethylhexyl 4-dimethylaminobenzoate, 2-ethylhexyl salicylate, isopentyl 4-methoxycinnamate, 2-ethylhexyl 4-methoxycinnamate, 2 -Hydroxy-4-methoxybenzophenone-5-sulfonic acid and its sodium salt, 3- (4'-methylbenzylidene) -D, L-camphor, 3-benzylidene-camphor, 4-isopropylbenzyl salicylate, 2,4,6-trianyl N- (p-carbo-2'-ethylhexyl-1'-oxi) -1,3,5-triazine, 3-imidazol-4-yl-acrylic acid and its ethyl ester, polymers of N - {(2 and 4) - [2-oxoborn-3-ylidenemethyl] benzyl} acrylamide. Very particularly preferred according to the invention are 2-hydroxy-4-methoxybenzophenone, 2-phenylbenzimidazole-5-sulfonic acid and its potassium, sodium and triethanolamine salts, 1- (4-tert-butylphenyl) -3- (4-methoxyphenyl) -propane-1,3-dione, 4-methoxycinnamic acid 2-ethylhexyl ester and 3- (4'-methylbenzylidene) -D, L-camphor.

Prefers are those UV filters whose molar extinction coefficient at the absorption maximum above 15,000, especially above 20,000.

Farther was found to be structurally similar to UV filters in many make the water-insoluble Compound in the context of the teaching of the invention, the higher effect across from such water-soluble Compounds that are distinguished from it by one or more additionally distinguish ionic groups. As water-insoluble are within the scope of the invention to understand those UV filters which at 20 ° C to not more than 1 wt .-%, in particular not more than 0.1% by weight, dissolve in water. Farther should these compounds in usual cosmetic oil components at room temperature to at least 0.1, in particular at least 1% by weight soluble be). The use of water-insoluble UV filter may therefore be preferred according to the invention.

According to one another embodiment the invention, those UV filters are preferred which are cationic Group, in particular a quaternary Ammonium group.

These UV filters have the general structure U-Q.

• – substituierte Benzophenone,
• – p-Aminobenzoesäureester,
• – Diphenylacrylsäureester,
• – Zimtsäureester,
• – Salicylsäureester,
• – Benzimidazole und
• – o-Aminobenzoesäureester.

The structural part U stands for a UV-absorbing group. This group can in principle be derived from the known UV filters which can be used in the cosmetics sector, in which a group, generally a hydrogen atom, of the UV filter is replaced by a cationic group Q, in particular having a quaternary amino function , Compounds from which the structural part U can derive are, for example

• Substituted benzophenones,
• P-aminobenzoic acid ester,
• - diphenylacrylic acid ester,
• - cinnamic acid ester,
• Salicylic acid ester,
• Benzimidazoles and
• O-aminobenzoic acid ester.

structural parts U, derived from cinnamamide or derive from N, N-dimethylamino-benzoic acid amide are preferred according to the invention.

The Structural parts U can chosen in principle be that Absorption maximum of UV filters in both UVA (315-400 nm) -, as well as in the UVB (280-315nm) - or in UVC (<280 nm) range can be. UV filter with an absorption maximum in the UVB range, especially in the range of about 280 to about 300 nm, are particularly preferred.

Farther is the structural part U, also in dependence on structural part Q, preferably chosen that the molar extinction coefficient of the UV filter at the absorption maximum above 15,000, especially above 20,000.

Of the Structure part Q contains as a cationic group, a quaternary ammonium group is preferred. This quaternary ammonium group can in principle be connected directly to the structural part U, so that the Structural part U one of the four substituents of the positively charged Represents nitrogen atom. However, one of the four is preferred Substituents on the positively charged nitrogen atom is a group, in particular an alkylene group having 2 to 6 carbon atoms, which as a compound between the structural part U and the positively charged nitrogen atom acts.

Advantageously, the group Q has the general structure - (CH ₂ ) _X -N ⁺ R ¹ R ² R ³ X ^- , in which x is an integer from 1 to 4, R ¹ and R ² independently of one another are C _{1 -4} alkyl groups, R ³ is a C _1-22 alkyl group or a benzyl group and X ^{- is} a physiologically acceptable anion. In the context of this general structure, x preferably represents the number 3, R ¹ and R ² each represent a methyl group and R ^{3 represents} either a methyl group or a saturated or unsaturated, linear or branched hydrocarbon Stoffkette with 8 to 22, in particular 10 to 18, carbon atoms.

physiological compatible Anions are, for example, inorganic anions such as halides, in particular chloride, bromide and fluoride, sulfate ions and phosphate ions and organic anions such as lactate, citrate, acetate, tartrate, methosulfate and tosylate.

Two preferred UV filters with cationic groups are the commercially available compounds cinnamic acid trimethyl ammonium chloride (Incroquat ^® UV-283) and Dodecyldimethylaminobenzamidopropyl-tosylate (Escalol ^® HP 610).

Of course it includes the teaching of the invention also the use of a combination of several UV filters. in the Frame of this embodiment is the combination of at least one water-insoluble UV filter with at least a UV filter with a cationic group is preferred.

The UV filters (I) are customary in the compositions according to the invention in quantities of 0.1-5 Wt .-%, based on the total agent included. Amounts of 0.4-2.5% by weight are preferred.

According to one another preferred embodiment In addition, the cosmetic compositions of the invention contain at least a water-insoluble Silicone, a water-soluble Silicone and / or amino-functionalized silicone. According to the invention suitable Silicones cause different effects. So influence For example, at the same time they can be dry and wet combed, the grip of dry and wet hair as well as the shine. Under The term silicones is understood by the person skilled in the art to mean several structures of organosilicon Links.

Dimethiconols (S1) form the first group of silicones which are particularly preferred according to the invention. The dimethiconols according to the invention can be both linear and branched as well as cyclic or cyclic and branched. Linear dimethiconols can be represented by the following structural formula (S1-I): (SiOHR ¹ 2) -O- (SiR ² 2 -O-) _x - (SiOHR ¹ 2) (Si-I) Branched dimethiconols can be represented by the structural formula (S1-II):

The radicals R ¹ and R ² are each independently hydrogen, a methyl radical, a C ² to C 30 linear, saturated or unsaturated hydrocarbon radical, a phenyl radical and / or an aryl radical. Non-limiting examples of the groups represented by R ¹ and R ² include alkyl groups such as methyl, ethyl, propyl, isopropyl, butyl, isobutyl, pentyl, isopentyl, neopentyl, amyl, isoamyl, hexyl, isohexyl and the like; Alkenyl radicals such as vinyl, halovinyl, alkylvinyl, allyl, haloallyl, alkylallyl; Cycloalkyl radicals such as cyclobutyl, cyclopentyl, cyclohexyl and the like; Phenyl radicals, benzyl radicals, halohydrocarbon radicals such as 3-chloropropyl, 4-bromobutyl, 3,3,3-trifluoropropyl, chlorocyclohexyl, bromophenyl, chlorophenyl and the like, and sulfur-containing radicals such as mercaptoethyl, mercaptopropyl, mercaptohexyl, mercaptophenyl and the like; Preferably, R ¹ and R ^{2 is} an alkyl radical containing from 1 to about 6 carbon atoms, and most preferably R ¹ and R ^{2 are} methyl. Examples of R ¹ include methylene, ethylene, propylene, hexamethylene, decamethylene, -CH ₂ CH (CH ₃ ) CH ₂ -, phenylene, naphthylene, -CH ₂ CH ₂ SCH ₂ CH ₂ -, -CH ₂ CH ₂ OCH ₂ - , -OCH ₂ CH ₂ -, -OCH ₂ CH ₂ CH ₂ -, -CH ₂ CH (CH ₃ ) C (O) OCH ₂ -, - (CH ₂ ) ₃ CC (O) OCH ₂ CH ₂ -, C ₆ H ₄ C ₆ H ₄ - _, -C ₆ H ₄ CH ₂ C ₆ H ₄ -; and - (CH ₂ ) ₃ C (O) SCH ₂ CH ₂ -. Preferred as R ¹ and R ² are methyl; Phenyl and C2 to C22 alkyl radicals. Of the C2 to C22 alkyl radicals, lauryl, stearyl and behenyl radicals are particularly preferred. The numbers x, y and z are integers and each run independently from 0 to 50,000. The molecular weights of the dimethicones are between 1000 D and 10,000,000 D. The viscosities are between 100 and 10,000,000 cPs measured at 25 ° C. with the aid of a glass capillary viscometer according to the Dow Corning Corporate Test Method CTM 0004 of 20 July 1970. Preferred viscosities are between 1,000 and 5,000,000 cps, particularly preferred viscosities are between 10,000 and 3,000,000 cps. The most preferred range is between 50,000 and 2,000,000 cps.

Of course, the teaching of the invention also includes that the dimethiconols may already be present as an emulsion. In this case, the corresponding emulsion of the dimethiconols can be prepared both after the preparation of the corresponding dimethiconols from these and the usual methods of emulsification known to the person skilled in the art. For this purpose, both cationic, anionic, nonionic or zwitterionic surfactants and emulsifiers can be used as auxiliaries for the preparation of the corresponding emulsions. Of course, the emulsions of the dimethiconols can also be prepared directly by an emulsion polymerization process. Such methods are also well known to the person skilled in the art. For example, refer to the " Encyclopedia of Polymer Science and Engineering, Volume 15, Second Edition, pages 204 to 308, John Wiley & Sons, Inc. 1989 , This reference is expressly incorporated by reference.

If the dimethiconols of the invention used as an emulsion, then the droplet size of the emulsified particles According to the invention 0.01 microns to 10,000 microns, preferably 0.01 to 100 μm, most preferably 0.01 to 20 microns, and most preferably 0.01 up to 10 μm. The particle size is determined by the method of light scattering.

Become used branched dimethiconols, this is to be understood as meaning that the branching is bigger, as a random one Branching caused by contamination of the respective monomers fortuitously arises. In the sense of the present connection is therefore under branched Dimethiconols understand that the degree of branching is greater than 0.01% is. Preferably, a degree of branching is greater than 0.1% and most preferably greater than 0.5%. The degree of Branching is calculated from the ratio of unbranched monomers, this means the amount of monofunctional siloxane, to the branching monomers, this means the amount of tri- and tetrafunctional siloxanes. According to the invention both Low branched as well as highly branched Dimethiconole very particularly be preferred.

When examples for Such products are called the following commercial products: Botanisil NU-150M (Botanigenics), Dow Coming 1-1254 Fluid, Dow Corning 2-9023 Fluid, Dow Coming 2-9026 Fluid, Ultrapure Dimethiconol (Ultra Chemical), Unisil SF-R (Universal Preserve), X-21-5619 (Shin-Etsu Chemical Co.), Abil OSW 5 (Degussa Care Specialties), ACC DL-9430 Emulsion (Taylor Chemical Company, AEC Dimethiconol & Sodium Dodecylbenzenesulfonate (A & E Connock (Perfumery & Cosmetics) Ltd.), B C Dimethiconol Emulsion 95 (Basildon Chemical Company, Ltd.), Cosmetic Fluid 1401, Cosmetic Fluid 1403, Cosmetic Fluid 1501, Cosmetic Fluid 1401DC (all aforementioned Chemsil Silicones, Inc.), Dow Corning 1401 Fluid, Dow Corning 1403 Fluid, Dow Corning 1501 Fluid, Dow Corning 1784 HVF Emulsion, Dow Corning 9546 Silicone Elastomer Blend (all aforementioned Dow Corning Corporation), Dub Gel SI 1400 (Dubois Fils Stearinerie), HVM 4852 Emulsion (Crompton Corporation), Jeesilc 6056 (Jeen International Corporation), Lubrasil, Lubrasil DS (both Guardian Laboratories), Nonychosine E, Nonychosine V (both Exsymol), SanSurf Petrolatum-25, Satin Finish (both Collaborative Laboratories, Inc.), Silatex-D30 (Cosmetic Ingredient Resources), Silsoft 148, Silsoft E-50, Silsoft E-623 (all previously mentioned Crompton Corporation), SM555, SM2725, SM2765, SM2785 (all previously mentioned GE Silicones), Taylor T-Sil CD-1, Taylor TME-4050E (all Taylor Chemical Company), TH V 148 (Crompton Corporation), Tixogel CYD-1429 (Sud-Chemie Performance Additives), Wacker-Belsil CM 1000, Wacker-Belsil CM 3092, Wacker-Belsil CM 5040, Wacker-Belsil DM 3096, Wacker-Belsil DM 3112 VP, Wacker-Belsil DM 8005 VP, Wacker-Belsil DM 60081 VP (all aforementioned Wacker-Chemie GmbH).

If the dimethiconols (S1) are contained in the base composition, so these compositions contain 0.01 to 10 wt.%, Preferably 0.1 to 8 wt.%, Particularly preferably 0.25 to 7.5 wt.% And in particular 0.5 to 5 wt.% Dimethiconol based on the composition.

Also particularly suitable according to the invention are the so-called dimethicones (S2). These may be both linear and branched as well as cyclic or cyclic and branched. Linear dimethicones can be represented by the following structural formula (S2-I): (SiR ¹ ₃ ) -O- (SiR ² ₂ -O-) _x - (SiR ¹ ₃ ) (S2-I) Branched dimethicones can be represented by the structural formula (S2-II):

The radicals R ¹ and R ² are each independently hydrogen, a methyl radical, a C ² to C 30 linear, saturated or unsaturated hydrocarbon radical, a phenyl radical and / or an aryl radical. Non-limiting examples of the groups represented by R ¹ and R ² include alkyl groups such as methyl, ethyl, propyl, isopropyl, butyl, isobutyl, pentyl, isopentyl, neopentyl, amyl, isoamyl, hexyl, isohexyl and the like; Alkenyl radicals such as vinyl, halovinyl, alkylvinyl, allyl, haloallyl, alkylallyl; Cycloalkyl radicals such as cyclobutyl, cyclopentyl, cyclohexyl and the like; Phenyl radicals, benzyl radicals, halohydrocarbon radicals such as 3-chloropropyl, 4-bromobutyl, 3,3,3-trifluoropropyl, chlorocyclohexyl, bromophenyl, chlorophenyl and the like, and sulfur-containing radicals such as mercaptoethyl, mercaptopropyl, mercaptohexyl, mercaptophenyl and the like; Preferably, R ¹ and R ^{2 is} an alkyl radical containing from 1 to about 6 carbon atoms, and most preferably R ¹ and R ^{2 are} methyl. Examples of R ¹ include methylene, ethylene, propylene, hexamethylene, decamethylene, -CH ₂ CH (CH ₃ ) CH ₂ -, phenylene, naphthylene, -CH ₂ CH ₂ SCH ₂ CH ₂ -, -CH ₂ CH ₂ OCH ₂ - , -OCH ₂ CH ₂ -, -OCH ₂ CH ₂ CH ₂ -, -CH ₂ CH (CH ₃ ) C (O) OCH ₂ -, - (CH ₂ ) ₃ CC (O) OCH ₂ CH ₂ -, C ₆ H ₄ C ₆ H ₄ -, -C ₆ H ₄ CH ₂ C ₆ H ₄ -; and - (CH ₂ ) ₃ C (O) SCH ₂ CH ₂ -. Preferred as R ¹ and R ² are methyl, phenyl and C ² to C 22 alkyl radicals. Of the C2 to C22 alkyl radicals, lauryl, stearyl and behenyl radicals are particularly preferred. The numbers x, y and z are integers and each run independently from 0 to 50,000.

Especially According to the invention, the linear ones are preferred Polydialkylsiloxanes, the polyalkylarylsiloxanes, the polydiarylsiloxanes and / or the dihydroxypolydimethylsiloxanes.

The Molweights of the invention suitable Dimethicones are between 1000 D and 10000000 D.

The viscosities the invention suitable Dimethicones are usually between 0.01 and 10,000,000 cPs measured at 25 ° C using a glass capillary viscometer according to the Dow Corning Corporate Test Method CTM 0004 of 20 July 1970. Preferred viscosities are between 0.1 and 5000000 cPs, very particularly preferred Vsikositäten are between 0.1 and 3,000,000 cps. The most preferred viscosity range the dimethicone is between 0.6 and 600,000 cps.

Of course, the teaching of the invention also includes that the dimethicones may already be present as an emulsion. In this case, the corresponding emulsion of the dimethicones can be prepared both after the preparation of the corresponding dimethicones from these and the usual methods of emulsification known to the person skilled in the art. For this purpose, both cationic, anionic, nonionic or zwitterionic surfactants and emulsifiers can be used as auxiliaries for the preparation of the corresponding emulsions. Of course, the emulsions of dimethicones can also be prepared directly by an emulsion polymerization process. Such methods are also well known to the person skilled in the art. For example, refer to the " Encyclopedia of Polymer Science and Engineering, Volume 15, Second Edition, pages 204 to 308, John Wiley & Sons, Inc. 1989 , This reference is expressly incorporated by reference.

If the dimethicones of the invention used as an emulsion, then the droplet size of the emulsified particles According to the invention 0.01 microns to 10,000 microns, preferably 0.01 to 100 μm, most preferably 0.01 to 20 microns, and most preferably 0.01 up to 10 μm. The particle size is determined by the method of light scattering.

Become used branched dimethicones, so to understand it that the branching is bigger, as a random one Branching caused by contamination of the respective monomers fortuitously arises. In the sense of the present connection is therefore under branched Dimethicones understand that the degree of branching is greater than 0.01% is. Preferably, a degree of branching is greater than 0.1% and most preferably greater than 0.5%. The degree of Branching is calculated from the ratio of unbranched monomers, this means the amount of monofunctional siloxane, to the branching monomers, this means the amount of tri- and tetrafunctional siloxanes. According to the invention both Low branched as well as highly branched dimethicones in particular be preferred.

If the dimethicones (S2) are contained in the base composition, so these compositions contain 0.01 to 10 wt.%, Preferably 0.1 to 8 wt.%, Particularly preferably 0.25 to 7.5 wt.% And in particular 0.5 to 5% by weight of dimethicone, based on the composition.

Dimethicone copolyols (S3) form another group of preferred silicones. Dimethiconols can be represented by the following structural formulas: (SiR ¹ ₃₎ -O- (SiR ² ₂ -O-) _x - (Sirpe-O-) _y - (SiR ¹ ₃₎ (S3-I) or by the following structural formula: PE- (SiR ¹ ₂ ) -O- (SiR ² ₂ -O-) _x - (SiR ¹ ₂ ) -PE (S3-II)

oder durch die Strukturformel(S3-IV):

Branched dimethicone copolyols can be represented by the structural formula (S3-III):

or by the structural formula (S3-IV):

The radicals R ¹ and R ² are each independently hydrogen, a methyl radical, a C ² to C 30 linear, saturated or unsaturated hydrocarbon radical, a phenyl radical and / or an aryl radical. Non-limiting examples of the groups represented by R ¹ and R ² include alkyl groups such as methyl, ethyl, propyl, isopropyl, butyl, isobutyl, pentyl, isopentyl, neopentyl, amyl, isoamyl, hexyl, isohexyl and the like; Alkenyl radicals such as vinyl, halovinyl, alkylvinyl, allyl, haloallyl, alkylallyl; Cycloalkyl radicals such as cyclobutyl, cyclopentyl, cyclohexyl and the like; Phenyl radicals, benzyl radicals, halohydrocarbon radicals such as 3-chloropropyl, 4-bromobutyl, 3,3,3-trifluoropropyl, chlorocyclohexyl, bromophenyl, chlorophenyl and the like, and sulfur-containing radicals such as mercaptoethyl, mercaptopropyl, mercaptohexyl, mercaptophenyl and the like; Preferably, R ¹ and R ^{2 is} an alkyl radical containing from 1 to about 6 carbon atoms, and most preferably R ¹ and R ^{2 are} methyl. Examples of R ¹ include methylene, ethylene, propylene, hexamethylene, decamethylene, -CH ₂ CH (CH ₃ ) CH ₂ -, phenylene, naphthylene, -CH ₂ CH ₂ SCH ₂ CH ₂ -, -CH ₂ CH ₂ OCH ₂ - , -OCH ₂ CH ₂ -, -OCH ₂ CH ₂ CH ₂ -, -CH ₂ CH (CH ₃ ) C (O) OCH ₂ -, - (CH ₂ ) ₃ CC (O) OCH ₂ CH ₂ -, C ₆ H ₄ C ₆ H ₄ -, -C ₆ H ₄ CH ₂ C ₆ H ₄ -; and - (CH ₂ ) ₃ C (O) SCH ₂ CH ₂ -. Preferred as R ¹ and R ² are methyl, phenyl and C ² to C 22 alkyl radicals. Of the C2 to C22 alkyl radicals, lauryl, stearyl and behenyl radicals are particularly preferred. PE stands for a polyoxyalkylene radical. Preferred polyoxyalkylene radicals are derived from ethylene oxide, propylene oxide and glycerol. The numbers x, y and z are integers and each run independently from 0 to 50,000. The molecular weights of the dimethicones are between 1000 D and 10,000,000 D. The viscosities are between 100 and 10,000,000 cPs measured at 25 ° C. with the aid of a glass capillary viscometer according to the Dow Corning Corporate Test Method CTM 0004 of 20 July 1970. Preferred viscosities are between 1,000 and 5,000,000 cps, particularly preferred viscosities are between 10,000 and 3,000,000 cps. The most preferred range is between 50,000 and 2,000,000 cps.

Of course, the teaching of the invention also includes that the Dimethiconcopolymere can already be present as an emulsion. In this case, the corresponding emulsion of the dimethicone copolyols can be prepared both after the preparation of the corresponding dimethicone copolyols from these and the usual methods of emulsification known to the person skilled in the art. For this purpose, both cationic, anionic, nonionic or zwitterionic surfactants and emulsifiers can be used as auxiliaries for the preparation of the corresponding emulsions. Of course, the emulsions of dimethicone copolyols can also be prepared directly by an emulsion polymerization process. Also such methods are well known to those skilled in the art. For example, refer to the " Encyclopedia of Polymer Science and Engineering, Volume 15, Second Edition, pages 204 to 308, John Wiley & Sons, Inc. 1989 , This reference is expressly incorporated by reference.

If the dimethicone copolyols according to the invention used as an emulsion, then the droplet size of the emulsified particles According to the invention 0.01 microns to 10,000 microns, preferably 0.01 to 100 μm, whole more preferably 0.01 to 20 microns and most preferably 0.01 to 10 μm. The particle size is determined by the method of light scattering.

Become used branched dimethicone copolyols, it is to be understood as that the branching is bigger, as a random one Branching caused by contamination of the respective monomers fortuitously arises. In the sense of the present connection is therefore under branched Dimethicone copolyols understand that the degree of branching is greater than 0.01% is. Preferably, a degree of branching is greater than 0.1 % and most preferably greater than 0.5%. The degree of Branching is calculated from the ratio of unbranched monomers, this means the amount of monofunctional siloxane, to the branching monomers, this means the amount of tri- and tetrafunctional siloxanes. According to the invention both low branched as well as highly branched dimethicone copolyols completely particularly preferred.

If containing dimethicone copolyols (S3) in the base composition are, then, these compositions contain 0.01 to 10 wt.%, Preferably 0.1 to 8 wt.%, Particularly preferably 0.25 to 7.5 wt.% And in particular 0.5 to 5 wt.% Of dimethicone copolyol based on the composition.

Amino-functional Silicones or amodimethicones (S4) are called silicones which have at least one (optionally substituted) amino group.

Such silicones may be represented, for example, by the formula (S4-I) M (R _a Q _b SiO _{(4-ab) / 2) x} (R _c SiO _{(4-c) / 2) y} M (S4-I)

Will be described, wherein in the above formula R is a hydrocarbon or a hydrocarbon radical having from 1 to about 6 carbon atoms, Q is a polar radical of the general formula -R ¹ HZ, wherein R ^{1 is} a divalent connecting group attached to hydrogen and the Z is an organic, amino-functional radical containing at least one amino-functional group, carbon and hydrogen atoms, carbon, hydrogen and oxygen atoms or carbon, hydrogen and nitrogen atoms; "a" assumes values in the range of about 0 to about 2, "b" assumes values in the range of about 1 to about 3, "a" + "b" is less than or equal to 3, and "c" is a number in the range from about 1 to about 3, and x is a number ranging from 1 to about 2,000, preferably from about 3 to about 50, and most preferably from about 3 to about 25, and y is a number ranging from about 20 to about 10,000 , preferably from about 125 to about 10,000, and most preferably from about 150 to about 1,000, and M is a suitable silicone end group as known in the art, preferably trimethylsiloxy. Non-limiting examples of the groups represented by R include alkyl groups such as methyl, ethyl, propyl, isopropyl, isopropyl, butyl, isobutyl, amyl, isoamyl, hexyl, isohexyl and the like; Alkenyl radicals such as vinyl, halovinyl, alkylvinyl, allyl, haloallyl, alkylallyl; Cycloalkyl radicals such as cyclobutyl, cyclopentyl, cyclohexyl and the like; Phenyl radicals, benzyl radicals, halohydrocarbon radicals such as 3-chloropropyl, 4-bromobutyl, 3,3,3-trifluoropropyl, chlorocyclohexyl, bromophenyl, chlorophenyl and the like, and sulfur-containing radicals such as mercaptoethyl, mercaptopropyl, mercaptohexyl, mercaptophenyl and the like; preferably R is an alkyl radical containing from 1 to about 6 carbon atoms, and most preferably R is methyl. Examples of R ¹ include methylene, ethylene, propylene, hexamethylene, decamethylene, -CH ₂ CH (CH ₃ ) CH ₂ -, phenylene, naphthylene, -CH ₂ CH ₂ SCH ₂ CH ₂ -, -CH ₂ CH ₂ OCH ₂ - , -OCH ₂ CH ₂ -, -OCH ₂ CH ₂ CH ₂ -, -CH ₂ CH (CH ₃ ) C (O) OCH ₂ -, - (CH ₂ ) ₃ CC (O) OCH ₂ CH ₂ -, C ₆ H ₄ C ₆ H ₄ - _, -C ₆ H ₄ CH ₂ C ₆ H ₄ -; and - (CH ₂ ) ₃ C (O) SCH ₂ CH ₂ -.

Z is an organic, amino-functional radical containing at least one functional amino group. A possible formula for Z is NH (CH ₂ ) _z NH ₂ , wherein z is 1 or more. Another possible formula for Z is -NH (CH ₂ ) _z (CH ₂ ) _zz NH, wherein both z and zz are independently 1 or more, which structure includes diamino ring structures, such as piperazinyl. Z is most preferably a -NHCH ₂ CH ₂ NH ₂ radical. Another possible formula for Z is -N (CH ₂ ) _z (CH ₂ ) _zz NX ₂ or -NX ₂ , wherein each X of X _{2 is} independently selected from the group consisting of hydrogen and alkyl groups of 1 to 12 carbon atoms, and z is 0.

Q is most preferably a polar, amine functional group of the formula -CH ₂ CH ₂ CH ₂ NHCH ₂ CH ₂ NH ₂ . In the formulas, "a" assumes values in the range of about 0 to about 2, "b" assumes values in the range of about 2 to about 3, "a" + "b" is less than or equal to 3, and "c "is a number in the range of about 1 to about 3. The molar ratio of R _a Q _b SiO _{(4-ab) / 2)} units to the R _c SiO _{(4-c) / 2)} units is in the range from about 1: 2 to 1:65, preferably from about 1: 5 to about 1:65, and most preferably from about 1:15 to about 1:20. When one or more silicones of the above formula are used, then the various variables can be used Substituents in the above formula may be different for the various silicone components present in the silicone blend.

• – G ist–H, eine Phenylgruppe, -OH, -O-CH₃, -CH₃, -CH₂CH₃, -CH₂CH₂CH₃, -CH(CH₃)₂, -CH₂CH₂CH₂H₃, -CH₂CH(CH₃)₂, -CH(CH₃)CH₂CH₃, -C(CH₃)₃;
• – a steht für eine Zahl zwischen 0 und 3, insbesondere 0;
• – b steht für eine Zahl zwischen 0 und 1, insbesondere 1,
• – m und n sind Zahlen, deren Summe (m + n) zwischen 1 und 2000, vorzugsweise zwischen 50 und 150 beträgt, wobei n vorzugsweise Werte von 0 bis 1999 und insbesondere von 49 bis 149 und m vorzugsweise Werte von 1 bis 2000, insbesondere von 1 bis 10 annimmt,
• – R' ist ein monovalenter Rest ausgewählt aus – -N(R'')-CH₂-CH₂-N(R'')₂ – -N(R'')₂ – -N⁺(R'')₃A^– – -N⁺H(R'')₂A^– – -N⁺H₂(R'')A^– – -N(R'')-CH₂-CH₂-N⁺R''H₂A^–, wobei jedes R'' für gleiche oder verschiedene Reste aus der Gruppe -H, -Phenyl, -Benzyl, der C_1-20-Alkylreste, vorzugsweise -CH₃, -CH₂CH₃, -CH₂CH₂CH₃, -CH(CH₃)₂, -CH₂CH₂CH₂H₃, -CH₂CH(CH₃)₂, -CH(CH₃)CH₂CH₃, -C(CH₃)₃, steht und A ein Anion repräsentiert, welches vorzugsweise ausgewählt ist aus Chlorid, Bromid, Iodid oder Methosulfat.

Preferred agents according to the invention are characterized in that they contain an amino-functional silicone of the formula (S4-II) R _'a G _3-a -Si (OSiG _{2) n} - (OSiG _b R' _{2-b) m} -O-SiG _3-a -R _'a (S4-II), contain in which means:

• G is -H, a phenyl group, -OH, -O-CH ₃ , -CH ₃ , -CH ₂ CH ₃ , -CH ₂ CH ₂ CH ₃ , -CH (CH ₃ ) ₂ , -CH ₂ CH ₂ CH ₂ H ₃ , -CH ₂ CH (CH ₃ ) ₂ , -CH (CH ₃ ) CH ₂ CH ₃ , -C (CH ₃ ) ₃ ;
• A is a number between 0 and 3, in particular 0;
• B is a number between 0 and 1, in particular 1,
• M and n are numbers whose sum (m + n) is between 1 and 2000, preferably between 50 and 150, where n is preferably values from 0 to 1999 and in particular from 49 to 149 and m preferably values from 1 to 2000, in particular from 1 to 10,
• R 'is a monovalent radical selected from --N (R'') - CH ₂ -CH ₂ -N (R'') ₂ - -N (R'') ₂ - -N ⁺ (R'') ₃ A ^{- -} - N ⁺ H (R '') ₂ A ^{- -} - N ⁺ H ₂ (R '') A ^- - - N (R '') - CH ₂ -CH ₂ -N ⁺ R''H ₂ A ^- , wherein each R "represents identical or different radicals from the group -H, -phenyl, -benzyl, the C _1-20 -alkyl radicals, preferably -CH ₃ , -CH ₂ CH ₃ , -CH ₂ CH ₂ CH ₃ , -CH (CH ₃ ) ₂ , -CH ₂ CH ₂ CH ₂ H ₃ , -CH ₂ CH (CH ₃ ) ₂ , -CH (CH ₃ ) CH ₂ CH ₃ , -C (CH ₃ ) ₃ and A represents an anion, which is preferably selected from chloride, bromide, iodide or methosulfate.

enthalten, worin m und n Zahlen sind, deren Summe (m + n) zwischen 1 und 2000, vorzugsweise zwischen 50 und 150 beträgt, wobei n vorzugsweise Werte von 0 bis 1999 und insbesondere von 49 bis 149 und m vorzugsweise Werte von 1 bis 2000, insbesondere von 1 bis 10 annimmt.Particularly preferred agents according to the invention are characterized in that they contain an amino-functional silicone of the formula (S4-III)

in which m and n are numbers whose sum (m + n) is between 1 and 2000, preferably between 50 and 150, where n preferably values of 0 to 1999 and in particular of 49 to 149 and m preferably values of 1 to 2000 , in particular from 1 to 10 assumes.

These Silicones are classified as trimethylsilylamodimethicones according to the INCI declaration designated.

enthalten, worin R für -OH, -O-CH₃ oder eine -CH₃-Gruppe steht und m, n1 und n2 Zahlen sind, deren Summe (m + n1 + n2) zwischen 1 und 2000, vorzugsweise zwischen 50 und 150 beträgt, wobei die Summe (n1 + n2) vorzugsweise Werte von 0 bis 1999 und insbesondere von 49 bis 149 und m vorzugsweise Werte von 1 bis 2000, insbesondere von 1 bis 10 annimmt.Agents according to the invention which are characterized in that they contain an amino-functional silicone of the formula (S4-IV) are also particularly preferred.

in which R is -OH, -O-CH ₃ or a -CH ₃ group and m, n1 and n2 are numbers whose sum (m + n1 + n2) is between 1 and 2,000, preferably between 50 and 150 , where the sum (n1 + n2) preferably assumes values from 0 to 1999 and in particular from 49 to 149 and m preferably values from 1 to 2000, in particular from 1 to 10.

These Silicones are called amodimethicones according to the INCI declaration.

Independently of, which amino-functional silicones are used are agents according to the invention preferred in which the amino-functional silicone is an amine number above 0.25 meq / g, preferably above 0.3 meq / g and especially above 0.4 meq / g. The amine number is for the milliequivalents of amine per gram of amino-functional silicone. It can be determined by titration and also in the unit mg KOH / g be specified.

If the amodimethicones (S4) are contained in the base composition, so these compositions contain 0.01 to 10 wt.%, Preferably 0.1 to 8 wt.%, Particularly preferably 0.25 to 7.5 wt.% And in particular 0.5 to 5% by weight of amodimethicone based on the composition.

Become different silicones used as a mixture, so the mixing ratio is largely variable. However, all the silicones used for mixing are preferred in a relationship from 5: 1 to 1: 5 in the case of a binary mixture. One relationship from 3: 1 to 1: 3 is particularly preferred. Very particularly preferred Mixtures contain all the silicones contained in the mixture as far as possible in a relationship of about 1: 1, in each case based on the amounts used in wt.%.

If the silicone blend are included in the base composition, so these compositions contain 0.01 to 10 wt.%, Preferably 0.1 to 8 wt.%, Particularly preferably 0.25 to 7.5 wt.% And in particular 0.5 to 5 wt.% Of silicone mixture based on the composition.

• – Anlagerungsprodukte von 4 bis 30 Mol Ethylenoxid und/oder 0 bis 5 Mol Propylenoxid an lineare Fettalkohole mit 8 bis 22 C-Atomen, an Fettsäuren mit 12 bis 22 C-Atomen und an Alkylphenole mit 8 bis 15 C-Atomen in der Alkylgruppe,
• – C₁₂-C₂₂-Fettsäuremono- und diester von Anlagerungsprodukten von 1 bis 30 Mol Ethylenoxid an Polyole mit 3 bis 6 Kohlenstoffatomen, insbesondere an Glycerin,
• – Ethylenoxid- und Polyglycerin-Anlagerungsprodukte an Methylglucosid-Fettsäureester, Fettsäurealkanolamide und Fettsäureglucamide,
• – C₈-C₂₂-Alkylmono- und oligoglycoside und deren ethoxylierte Analoga, wobei Oligomerisierungsgrade von 1,1 bis 5, insbesondere 1,2 bis 2,0, und Glucose als Zuckerkomponente bevorzugt sind,
• – Gemische aus Alkyl-(oligo)-glucosiden und Fettalkoholen zu Beispiel das im Handel erhältliche Produkt Montanov^®68,
• – Anlagerungsprodukte von 5 bis 60 Mol Ethylenoxid an Rizinusöl und gehärtetes Rizinusöl,
• – Partialester von Polyolen mit 3 bis 6 Kohlenstoffatomen mit gesättigten Fettsäuren mit 8 bis 22 C-Atomen,
• – Sterine. Als Sterine wird eine Gruppe von Steroiden verstanden, die am C-Atom 3 des Steroid-Gerüsts eine Hydroxylgruppe tragen und sowohl aus tierischem Gewebe (Zoosterine) wie auch aus pflanzlichen Fetten (Phytosterine) isoliert werden. Beispiele für Zoosterine sind das Cholersterin und das Lanosterin. Beispiele geeigneter Phytosterine sind Ergosterin, Stigmasterin und Sitosterin. Auch aus Pilzen und Hefen werden Sterine, die sogenannten Mykosterine, isoliert.
• – Phospholipide. Hierunter werden vor allem die Glucose-Phospholipide, die z.B. als Lecithine bzw. Phosphatidylcholine aus z.B. Eidotter oder Pflanzensamen (z.B. Sojabohnen) gewonnen werden, verstanden.
• – Fettsäureestervon Zuckern und Zuckeralkoholen, wie Sorbit,
• – Polyglycerine und Polyglycerinderivate wie beispielsweise Polyglycerinpoly-12-hydroxystearat (Handelsprodukt Dehymuls^®PGPH),
• – Lineare und verzweigte Fettsäuren mit 8 bis 30 C-Atomen und deren Na-, K-, Ammonium-, Ca-, Mg- und Zn-Salze.

In a further preferred embodiment, the effect of the active ingredient combination according to the invention can be increased by emulsifiers. Such emulsifiers are, for example

• Addition products of from 4 to 30 mol of ethylene oxide and / or from 0 to 5 mol of propylene oxide onto linear fatty alcohols having from 8 to 22 carbon atoms, to fatty acids containing from 12 to 22 carbon atoms and to alkylphenols having from 8 to 15 carbon atoms in the alkyl group,
• C ₁₂ -C ₂₂ -fatty acid mono- and diesters of addition products of from 1 to 30 mol of ethylene oxide onto polyols having from 3 to 6 carbon atoms, in particular to glycerol,
• Ethylene oxide and polyglycerol addition products to methyl glucoside fatty acid esters, fatty acid alkanolamides and fatty acid glucamides,
• C ₈ -C ₂₂ -alkyl mono- and oligoglycosides and their ethoxylated analogues, preference being given to degrees of oligomerization of from 1.1 to 5, in particular from 1.2 to 2.0, and glucose as the sugar component,
• Glucosides mixtures of alkyl (oligo) and fatty alcohols for example, the commercially available product ^® Montanov 68, -
• Adducts of 5 to 60 moles of ethylene oxide with castor oil and hydrogenated castor oil,
• Partial esters of polyols having 3 to 6 carbon atoms with saturated fatty acids having 8 to 22 C atoms,
• - sterols. Sterols are understood to mean a group of steroids which have a hydroxyl group on C-atom 3 of the steroid skeleton and are isolated both from animal tissue (zoosterols) and from vegetable fats (phytosterols). Examples of zoosterols are cholesterol and lanosterol. Examples of suitable phytosterols are ergosterol, stigmasterol and sitosterol. Mushrooms and yeasts are also used to isolate sterols, the so-called mycosterols.
• - Phospholipids. These include, in particular, the glucose phospholipids which are obtained, for example, as lecithins or phosphatidylcholines from, for example, egg yolks or plant seeds (for example soybeans).
• Fatty acid esters of sugars and sugar alcohols, such as sorbitol,
• - polyglycerols and polyglycerol derivatives such as polyglycerol poly-12-hydroxystearate (commercial product Dehymuls ^® PGPH),
• - Linear and branched fatty acids with 8 to 30 carbon atoms and their Na, K, ammonium, Ca, Mg and Zn salts.

The agents according to the invention contain the emulsifiers preferably in amounts of 0.1-25 wt .-%, in particular 0.5-15 Wt .-%, based on the total agent.

The compositions according to the invention may preferably comprise at least one nonionic emulsifier having an HLB value of 8 to 18, according to the methods described in US Pat Rompp Lexicon Chemistry (ed. J. Falbe, M. Regitz), 10th edition, Georg Thieme Verlag Stuttgart, New York, (1997), page 1764 , listed definitions. Nonionic emulsifiers with an HLB value of 10-15 may be particularly preferred according to the invention.

As further advantageous, it has been found that further polymers can further support the action of the preparations according to the invention. In a preferred embodiment, polymers are therefore added to the compositions according to the invention, both anionic, amphoteric and noni Onic polymers have proven to be effective.

at the anionic polymers, which the effect of the preparations according to the invention support can, are anionic polymers which carboxylate and / or Have sulfonate groups. Examples of anionic monomers, from such polymers may be acrylic acid, methacrylic acid, crotonic acid, maleic anhydride and 2-acrylamido-2-methylpropanesulfonic acid. there can the acidic groups in whole or in part as sodium, potassium, ammonium, Mono- or triethanolammonium salt present. Preferred monomers are 2-acrylamido-2-methylpropanesulfonic acid and acrylic acid.

When anionic polymers have proven to be particularly effective containing as sole or co-monomer 2-acrylamido-2-methylpropanesulfonic acid, wherein the sulfonic acid group wholly or partly as sodium, potassium, ammonium, mono- or Triethanolammonium salt may be present.

More preferably, the homopolymer of 2-acrylamido-2-methyl propane sulfonic acid, which is available for example under the name Rheothik ^® 11-80 is commercially.

Within this embodiment For example, it may be preferable to use copolymers of at least one anionic Use monomer and at least one nonionic monomer. In terms of The anionic monomers are based on the substances listed above directed. Preferred nonionic monomers are acrylamide, methacrylamide, acrylate, methacrylates, Vinyl pyrrolidone, vinyl ethers and vinyl esters.

preferred anionic copolymers are acrylic acid-acrylamide copolymers as well in particular polyacrylamide copolymers with sulfonic acid-containing monomers. A particularly preferred anionic copolymer consists of 70 to 55 mole percent acrylamide and 30 to 45 mole percent 2-acrylamido-2-methylpropanesulfonic acid, wherein the sulfonic acid group wholly or partly as sodium, potassium, ammonium, mono- or triethanolammonium salt is present. This copolymer may also be crosslinked, wherein as Crosslinking agents preferably polyolefinically unsaturated compounds such as tetraallyloxyethane, allylsucrose, allylpentaerythritol and methylene-bisacrylamide be used.

Such a polymer is contained in the commercial product urchins ^® 305 from SEPPIC. The use of this compound, which in addition to the polymer component contains a hydrocarbon mixture (C ₁₃ -C ₁₄ isoparaffin) and a nonionic emulsifier (laureth-7), has proved to be particularly advantageous within the scope of the teaching according to the invention.

Also sold under the name Simulgel ^® 600 as a compound with isohexadecane and polysorbate-80 Natriumacryloyldimethyltaurat copolymers have proved to be particularly effective according to the invention.

Likewise preferred anionic homopolymers are uncrosslinked and crosslinked polyacrylic acids. Allyl ethers of pentaerythritol, sucrose and propylene may be preferred crosslinking agents. Such compounds are for example available under the trademark Carbopol ^® commercially.

Copolymers of maleic anhydride and methyl vinyl ether, especially those with crosslinks, are also color-retaining polymers. A with 1,9-decadiene crosslinked maleic acid-methyl vinyl ether copolymer is commercially available under the name Stabileze® ^® QM.

Furthermore, amphoteric polymers can be used as polymers to increase the activity of the preparations according to the invention. The term amphoteric polymers includes both those polymers which contain in the molecule both free amino groups and free -COOH or SO ₃ H groups and are capable of forming internal salts, as well as zwitterionic polymers which in the molecule have quaternary ammonium groups and -COO ^- or -SO ₃ groups, and those polymers summarized containing -COOH or SO ₃ H groups and quaternary ammonium groups.

An example for an inventive amphopolymer is the acrylic resin commercially available as Amphomer ^®, which is a copolymer of tert-butylaminoethyl methacrylate, N- (1,1,3,3-tetramethylbutyl) -acrylamide and two or more monomers from the group acrylic acid, methacrylic and their simple esters.

• (a) Monomeren mit quartären Ammoniumgruppen der allgemeinen Formel (G3-I), R¹-CH=CR²-CO-Z-(C_nH_2n)-N⁽⁺⁾R³R⁴R⁵ A^(–) (G3-I)in der R¹ und R² unabhängig voneinander stehen für Wasserstoff oder eine Methylgruppe und R³, R⁴ und R⁵ unabhängig voneinander für Alkylgruppen mit 1 bis 4 Kohlenstoffatomen, Z eine NH-Gruppe oder ein Sauerstoffatom, n eine ganze Zahl von 2 bis 5 und A^(–) das Anion einer organischen oder anorganischen Säure ist, und
• (b) monomeren Carbonsäuren der allgemeinen Formel (G3-II), R⁶-CH=CR⁷-COOH (G3-II) in denen R⁶ und R⁷ unabhängig voneinander Wasserstoff oder Methylgruppen sind.

Preferred amphoteric polymers are those polymers which consist essentially of one another

• (a) monomers having quaternary ammonium groups of the general formula (G3-I), R ¹ -CH = CR ² -CO-Z- (C _n H _2n ) -N ⁽⁺⁾ R ³ R ⁴ R ⁵ A ^(-) (G ³ -I) in which R ¹ and R ² independently of one another are hydrogen or a methyl group and R ³ , R ⁴ and R ⁵ independently of one another are alkyl groups having 1 to 4 carbon atoms, Z is an NH group or an oxygen atom, n is an integer from 2 to 5 and A ^{(-) is} the anion of an organic or inorganic acid, and
• (b) monomeric carboxylic acids of the general formula (G3-II), R ⁶ -CH = CR ⁷ -COOH (G3-II) in which R ⁶ and R ^{7 are} independently hydrogen or methyl groups.

These compounds can be used both directly and in salt form, which is obtained by neutralization of the polymers, for example with an alkali metal hydroxide, according to the invention. With regard to the details of the preparation of these polymers is expressly on the content of the German patent application 39 29 973 Referenced. Very particular preference is given to those polymers in which monomers of the type (a) are used in which R ³ , R ⁴ and R ^{5 are} methyl groups, Z is an NH group and a halide, methoxysulfate or ethoxysulfate ion; Acrylamidopropyl trimethyl ammonium chloride is a particularly preferred monomer (a). Acrylic acid is preferably used as monomer (b) for the stated polymers.

The agents according to the invention can in a further embodiment contain non-ionic polymers.

• – Vinylpyrrolidon/Vinylester-Copolymere, wie sie beispielsweise unter dem Warenzeichen Luviskol^® (BASF) vertrieben werden. Luviskol^® VA 64 und Luviskol^® VA 73, jeweils Vinylpyrrolidon/Vinylacetat-Copolymere, sind ebenfalls bevorzugte nichtionische Polymere.
• – Celluloseether, wie Hydroxypropylcellulose, Hydroxyethylcellulose und Methylhydroxypropylcellulose, wie sie beispielsweise unter den Warenzeichen Culminal^® und Benecel^® (AQUALON) vertrieben werden.
• – Schellack
• – Polyvinylpyrrolidone, wie sie beispielsweise unter der Bezeichnung Luviskol^® (BASF) vertrieben werden.
• – Siloxane. Diese Siloxane können sowohl wasserlöslich als auch wasserunlöslich sein. Geeignet sind sowohl flüchtige als auch nichtflüchtige Siloxane, wobei als nichtflüchtige Siloxane solche Verbindungen verstanden werden, deren Siedepunkt bei Normaldruck oberhalb von 200 °C liegt. Bevorzugte Siloxane sind Polydialkylsiloxane, wie beispielsweise Polydimethylsiloxan, Polyalkylarylsiloxane, wie beispielsweise Polyphenylmethylsiloxan, ethoxylierte Polydialkylsiloxane sowie Polydialkylsiloxane, die Amin- und/oder Hydroxy-Gruppen enthalten.
• – Glycosidisch substituierte Silicone.

Suitable nonionic polymers are, for example:

• - Vinylpyrrolidone / vinyl ester copolymers, such as those sold under the trademark Luviskol ^® (BASF). Luviskol ^® VA 64 and Luviskol ^® VA 73, each vinylpyrrolidone / vinyl acetate copolymers, are also preferred nonionic polymers.
• - cellulose ethers such as hydroxypropyl cellulose, hydroxyethyl cellulose and methylhydroxypropyl cellulose, as for example under the trademark Culminal® ^® and Benecel ^® (AQUALON).
• - shellac
• - polyvinylpyrrolidones, as for example under the name Luviskol ^® (BASF).
• - siloxanes. These siloxanes can be both water-soluble and water-insoluble. Both volatile and nonvolatile siloxanes are suitable, nonvolatile siloxanes being understood as meaning those compounds whose boiling point is above 200 ° C. under normal pressure. Preferred siloxanes are polydialkylsiloxanes, such as, for example, polydimethylsiloxane, polyalkylarylsiloxanes, such as, for example, polyphenylmethylsiloxane, ethoxylated polydialkylsiloxanes and polydialkylsiloxanes which contain amine and / or hydroxyl groups.
• - Glycosidically substituted silicones.

It According to the invention it is also possible that the preparations according to the invention several, in particular two different polymers of the same charge and / or in each case an ionic and an amphoteric and / or not contain ionic polymer.

The further polymers are preferred in amounts in the agents according to the invention from 0.05 to 10 wt .-%, based on the total agent. Amounts of 0.1 to 5, in particular from 0.1 to 3 wt .-%, are particularly prefers.

• – Verdickungsmittel wie Agar-Agar, Guar-Gum, Alginate, Xanthan-Gum, Gummi arabicum, Karaya-Gummi, Johannisbrotkernmehl, Leinsamengummen, Dextrane, Cellulose-Derivate, z. B. Methylcellulose, Hydroxyalkylcellulose und Carboxymethylcellulose, Stärke-Fraktionen und Derivate wie Amylose, Amylopektin und Dextrine, Tone wie Z. B. Bentonit oder vollsynthetische Hydrokolloide wie z. B. Polyvinylalkohol,
• – haarkonditionierende Verbindungen wie Phospholipide, beispielsweise Sojalecithin, Ei-Lecitin und Kephaline, sowie Silikonöle,
• – Parfümöle, Dimethylisosorbid und Cyclodextrine,
• – Lösungsmittel und -vermittler wie Ethanol, Isopropanol, Ethylenglykol, Propylenglykol, Glycerin und Diethylenglykol,
• – faserstrukturverbessernde Wirkstoffe, insbesondere Mono-, Di- und Oligosaccharide, wie beispielsweise Glucose, Galactose, Fructose, Fruchtzucker und Lactose,
• – Entschäumer wie Silikone,
• – Farbstoffe zum Anfärben des Mittels,
• – Weitere Antischuppenwirkstoffe wie Piroctone Olamine, Zink Omadine und Climbazol,
• – Wirkstoffe wie Allantoin und Bisabolol, Cholesterin,
• – Konsistenzgeber wie Zuckerester, Polyolester oder Polyolalkylether,
• – Fette und Wachse wie Walrat, Bienenwachs, Montanwachs und Paraffine,
• – Fettsäurealkanolamide,
• – Komplexbildner wie EDTA, NTA, β-Alanindiessigsäure und Phosphonsäuren,
• – Quell- und Penetrationsstoffe wie primäre, sekundäre und tertiäre Phosphate,
• – Trübungsmittel wie Latex, Styrol/PVP- und Styrol/Acrylamid-Copolymere,
• – Perlglanzmittel wie Ethylenglykolmono- und -distearat sowie PEG-3-distearat,
• – Pigmente,
• – Treibmittel wie Propan-Butan-Gemische, N₂O, Dimethylether, CO₂ und Luft,
• – Antioxidantien.

Other active ingredients, auxiliaries and additives are, for example

• Thickeners such as agar-agar, guar gum, alginates, xanthan gum, gum arabic, karaya gum, locust bean gum, linseed gums, dextrans, cellulose derivatives, e.g. As methylcellulose, hydroxyalkylcellulose and carboxymethylcellulose, starch fractions and derivatives such as amylose, amylopectin and dextrins, clays such as bentonite or fully synthetic hydrocolloids such. For example, polyvinyl alcohol,
• Hair-conditioning compounds such as phospholipids, for example soya lecithin, egg lecithin and cephalins, and silicone oils,
• Perfume oils, dimethylisosorbide and cyclodextrins,
• Solvents and mediators such as ethanol, isopropanol, ethylene glycol, propylene glycol, glycerol and diethylene glycol,
• Fiber-structure-improving active substances, in particular mono-, di- and oligosaccharides, such as, for example, glucose, galactose, fructose, fructose and lactose,
• Defoamers like silicones,
• Dyes for staining the agent,
• - Other anti-dandruff agents such as Piroctone Olamine, Zinc Omadine and Climbazole,
• - active substances such as allantoin and bisabolol, cholesterol,
• Bodying agents such as sugar esters, polyol esters or polyol alkyl ethers,
• - fats and waxes such as spermaceti, beeswax, montan wax and paraffins,
• Fatty acid alkanolamides,
• Complexing agents such as EDTA, NTA, β-alaninediacetic acid and phosphonic acids,
• - swelling and penetrating substances such as primary, secondary and tertiary phosphates,
• Opacifiers such as latex, styrene / PVP and styrene / acrylamide copolymers,
• Pearlescing agents such as ethylene glycol mono- and distearate and PEG-3-distearate,
• - pigments,
• Propellants such as propane-butane mixtures, N ₂ O, dimethyl ether, CO ₂ and air,
• - antioxidants.

The agents according to the invention There are no restrictions with regard to their form of packaging and can as an emulsion, cream, solution, Gel or mousse be formulated.

Prefers If the compositions according to the invention are a shampoo, a shower, a shower gel, a conditioner, a hair conditioner, a hair tonic, a hair gel, a hair spray, a lather, a fortifier, a aftershave or a deodorant.

One second subject of the invention is the cosmetic use the agent according to the invention for the prophylaxis, reduction, elimination and / or alleviation of Dandruff on hairy body regions.

One third subject of the invention is the cosmetic use a combination of an anti-dandruff agent, a zinc salt and at least one compound selected from the group Laureth-7-citrate, Laureth-6-citrate, disodium PEG-5 lauryl citrate sulfosuccinate, Disodium cocopolyglucose citrate, glyceryl stearate citrate and Dicocoyl pentaerythryl distearyl citrate, for the preparation of a preparation for the treatment of dander.

One The fourth aspect of the invention is a cosmetic method for the prophylaxis, reduction, elimination and / or alleviation of Dandruff on hairy body regions, in which a cosmetic according to the invention Medium is applied to the hair or the hairy skin and optionally rinsed again after an exposure time.

One fifth The invention relates to a cosmetic method for treatment of dandruff, characterized in that an agent containing at least one antidandruff active, a zinc salt and at least a connection selected from the group Laureth-7-citrate, Laureth-6-citrate, Disodium PEG-5 Lauryl citrate sulfosuccinate, disodium cocopolyglucose citrate, Glyceryl stearate citrate and dicocoyl pentaerythryl distearyl citrate, is applied to the hair or the hairy skin and optionally is rinsed out again after a contact time.

The The following examples are intended to explain the invention in more detail, without limiting it thereto.

• ¹ Hydroxy-4-methyl-6(2,4,4-trimethylpentyl)-2-pyridone-monoethanolamine salt (INCI-Bezeichnung: Piroctone Olamine); Clariant
• ² Laureth-7 Citrate: Cognis

Unless stated otherwise, the quantities given in the examples relate to% by weight. Examples: shampoo Laureth sulfate 25% 40.00% Citric acid monohydrate 0.15% Disodium Cocoamphodiacetate 5.00% Polyquaternium-10 0.20% Zinc sulfate × 7H ₂ O pure 0.50% sodium benzoate 0.50% Perfume 0.15% sodium chloride 1.30% Octopirox® ¹ 0.50% Plantapon ² 2.00% water ad 100%

• ¹ hydroxy-4-methyl-6 (2,4,4-trimethylpentyl) -2-pyridone-monoethanolamine salt (INCI name: Piroctone Olamine); Clariant
• ² Laureth-7 Citrate: Cognis

Claims (13)

Cosmetic agent containing as active ingredient combination A) at least one antidandruff active ingredient, B) at least one zinc salt such as C) at least one compound selected from the group Laureth-7-citrate, Laureth-6 citrate, Disodium PEG-5 lauryl citrate sulfosuccinate, disodium cocopolyglucose citrate, glyceryl stearate citrate and dicocoyl pentaerythryl distearyl citrate. Cosmetic composition according to claim 1, characterized that the antidandruff active, the zinc salt and the compound (s) C) in a weight ratio from (0,1-1) : (0,1-1) : (1-10) available. Cosmetic composition according to one of claims 1 or 2, characterized in that it is at least as anti-dandruff active a member of the group Piroctone olamine, climbazole, zinc Pyrithione, ketoconazole, salicylic acid, sulfur, tar preparations, undecenoic acid derivatives, Burdock root extracts, poplar extracts, stinging nettle extracts, walnut shell extracts, Birch extracts, willow bark extracts and Arnikaextrakte contains. Cosmetic composition according to one of claims 1 to 3, characterized in that it is at least one zinc salt Representatives of the group zinc sulfate, zinc sulfate hydrate, zinc carbonates, Contains zinc chlorides, zinc oxides and zinc (II) fluorides. Cosmetic composition according to one of claims 1 to 4, characterized in that - based on its total weight - 0.05 bis 2%, preferably 0.1 to 1.5% and in particular 0.3 to 1% of one or contains several anti-dandruff active ingredients. Cosmetic composition according to one of claims 1 to 5, characterized in that it - based on its total weight - 0.01 to 2%, preferably 0.1 to 1.5% and in particular 0.3 to 1% of one or contains several zinc salts. Cosmetic composition according to one of claims 1 to 6, characterized in that - based on its total weight - 0.1 to 10%, preferably 0.5 to 7% and in particular 1 to 5% of one or more compound (s) C) contains. Cosmetic composition according to one of claims 1 to 7, characterized in that it further comprises at least one representative from the group of anionic, amphoteric, zwitterionic, nonionic, cationic surfactants or mixtures thereof, the cationic Polymers, water-insoluble oil components, vitamins, provitamins, protein hydrolysates, plant extracts, the UV filter, the amino acids, the water-insoluble Silicones, the water-soluble Contains silicones and / or amodimethicones. Cosmetic composition according to one of claims 1 to 8, characterized in that it can be used as shampoo, shower bath, shower gel, rinse, Hair conditioner, hair lotions, hair gel, hair spray, foam, firming, aftershave or Deodorant is present. Cosmetic use of an agent according to a the claims 1 to 9 for the prophylaxis, reduction, elimination and / or palliation of dandruff on hairy body regions. Cosmetic use of a combination of a Antidandruff active ingredient, a zinc salt and at least one compound, selected from the group Laureth-7-citrate, Laureth-6-citrate, Disodium PEG-5 Lauryl citrate sulfosuccinate, disodium cocopolyglucose citrate, Glyceryl stearate citrate and dicocoyl pentaerythryl distearyl citrate, for the preparation of a preparation for the treatment of dander. Cosmetic method for prophylaxis, reduction, Removal and / or alleviation of dandruff on hairy body regions, wherein a cosmetic agent according to any one of claims 1 to 9 is applied to the hair or the hairy skin and optionally is rinsed out again after a contact time. Cosmetic method for treating dandruff, characterized in that an agent containing at least one Anti-dandruff active, a zinc salt and at least one compound, selected from the group Laureth-7-citrate, Laureth-6-citrate, Disodium PEG-5 Lauryl citrate sulfosuccinate, disodium cocopolyglucose citrate, Glyceryl stearate citrate and dicocoyl pentaerythryl distearyl citrate, is applied to the hair or the hairy skin and optionally is rinsed out again after a contact time.