CN108360289B - Series pigments for underglaze small film flower paper and preparation method thereof - Google Patents
Series pigments for underglaze small film flower paper and preparation method thereof Download PDFInfo
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- CN108360289B CN108360289B CN201810194029.6A CN201810194029A CN108360289B CN 108360289 B CN108360289 B CN 108360289B CN 201810194029 A CN201810194029 A CN 201810194029A CN 108360289 B CN108360289 B CN 108360289B
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- D—TEXTILES; PAPER
- D21—PAPER-MAKING; PRODUCTION OF CELLULOSE
- D21H—PULP COMPOSITIONS; PREPARATION THEREOF NOT COVERED BY SUBCLASSES D21C OR D21D; IMPREGNATING OR COATING OF PAPER; TREATMENT OF FINISHED PAPER NOT COVERED BY CLASS B31 OR SUBCLASS D21G; PAPER NOT OTHERWISE PROVIDED FOR
- D21H19/00—Coated paper; Coating material
- D21H19/36—Coatings with pigments
- D21H19/38—Coatings with pigments characterised by the pigments
- D21H19/385—Oxides, hydroxides or carbonates
-
- D—TEXTILES; PAPER
- D21—PAPER-MAKING; PRODUCTION OF CELLULOSE
- D21H—PULP COMPOSITIONS; PREPARATION THEREOF NOT COVERED BY SUBCLASSES D21C OR D21D; IMPREGNATING OR COATING OF PAPER; TREATMENT OF FINISHED PAPER NOT COVERED BY CLASS B31 OR SUBCLASS D21G; PAPER NOT OTHERWISE PROVIDED FOR
- D21H19/00—Coated paper; Coating material
- D21H19/36—Coatings with pigments
- D21H19/38—Coatings with pigments characterised by the pigments
-
- D—TEXTILES; PAPER
- D21—PAPER-MAKING; PRODUCTION OF CELLULOSE
- D21H—PULP COMPOSITIONS; PREPARATION THEREOF NOT COVERED BY SUBCLASSES D21C OR D21D; IMPREGNATING OR COATING OF PAPER; TREATMENT OF FINISHED PAPER NOT COVERED BY CLASS B31 OR SUBCLASS D21G; PAPER NOT OTHERWISE PROVIDED FOR
- D21H19/00—Coated paper; Coating material
- D21H19/36—Coatings with pigments
- D21H19/38—Coatings with pigments characterised by the pigments
- D21H19/40—Coatings with pigments characterised by the pigments siliceous, e.g. clays
Abstract
The invention discloses a series of pigments for underglaze small membrane stained paper and a preparation method thereof, wherein the series of pigments for the underglaze small membrane stained paper comprise at least one of orange pigment, manganese red pigment, black pigment, cymbidium pigment, turquoise green pigment and brown pigment; the orange pigment comprises the following components in percentage by mass: niobium oxide: 15%, cerium oxide: 15%, erbium oxide: 40% and quartz: 30%, glass powder: 20 percent; the manganese red pigment comprises the following components in percentage by mass: alumina: 70%, manganese carbonate: 15%, sodium fluoride: 3% and red lead: 4%, calcium oxide: 5 percent; the black pigment comprises the following components in percentage by mass: vanadium pentoxide: 25% and tin dioxide: 15%, zirconia: 25%, oxalic acid: 12.5%, quartz: 10%, cobalt oxide: 3 percent; brown pigment: 9.5 percent; the small film stained paper prepared by the method is pasted on the glaze, so that the glaze can show the effect of underglaze five-color porcelain, the effect is greatly improved, the production cost is reduced, and the method is suitable for mass production.
Description
Technical Field
The invention relates to a series of pigments for underglaze small membrane stained paper and a preparation method thereof.
Background
At present, the film decal paper produced in large scale is only suitable for the production at the overglaze low temperature of 700 ℃, the porcelain prepared by the film decal paper has the effect of no underglazed five-color porcelain, and the underglazed five-color porcelain prepared by the manual fencing process has low effect and high production cost, and cannot be produced in large scale.
Disclosure of Invention
The technical problem to be solved by the invention is to overcome the defects of the prior art and provide a series of pigments for underglaze small membrane stained paper, and the small membrane stained paper prepared by the pigments is pasted on glaze, so that the glaze can show the effect of underglaze five-color porcelain, the effect is greatly improved, the production cost is reduced, and the pigments are suitable for mass production.
In order to solve the technical problems, the technical scheme of the invention is as follows: a series of pigments for underglaze small membrane flower paper comprises at least one of orange pigment, manganese red pigment, black pigment, cymbidium pigment, pine green pigment and brown pigment, wherein the black pigment contains brown pigment; wherein the content of the first and second substances,
the orange pigment comprises the following components in percentage by mass: niobium oxide: 15%, cerium oxide: 15%, erbium oxide: 40% and quartz: 30%, glass powder: 20 percent;
the manganese red pigment comprises the following components in percentage by mass: alumina: 70%, manganese carbonate: 15%, sodium fluoride: 3% and red lead: 4%, calcium oxide: 5 percent;
the black pigment comprises the following components in percentage by mass: vanadium pentoxide: 25% and tin dioxide: 15%, zirconia: 25%, oxalic acid: 12.5%, quartz: 10%, cobalt oxide: 3 percent; brown pigment: 9.5 percent;
the cymbidium pigment comprises the following components in percentage by mass: cobalt oxide: 10% -12%, chromium oxide: 16% -18%, zinc oxide: 14% -16%, calomel: 36% -38%, alumina: 20-22%, quartz: 3% -5%, and the total amount of the components is 100%;
the pine green pigment comprises the following components in percentage by mass: chromium oxide: 1% -2%, quartz: 30% -32%, beryllium oxide: 48% -50%, zinc oxide: 8% -10%, calcium oxide: 8% -10%, quartz: 2% -4%, and the total amount of the components is 100%;
the brown pigment comprises the following components in percentage by mass: potassium bichromate: 12% -14%, blue vitriol: 8% -10%, manganese oxide: 15% -17%, chromium oxide: 10% -12%, sandstone: 5% -7%, Jiepai mud: 4% -6%, quartz: 46% -50%, and the total amount of the components is 100%.
A preparation method of series pigments for underglaze filmy stained paper comprises the following steps:
s1: preparing materials according to the components of the corresponding pigment and the mass percentage of each component;
s2: the components of the pigment are mixed and sieved, the sieved powder is filled into a sagger and is calcined in a kiln to form blocky or granular pigment, and then the blocky or granular pigment is crushed once, ball-milled, dried and crushed twice and is sieved to obtain a corresponding pigment finished product.
Further, in step S2, the temperature of calcination was 1360 ℃.
After the technical scheme is adopted, the underglaze pellicle stained paper produced by the series of pigments can be suitable for 1360 ℃ of underglaze high temperature, the porcelain fired by reducing flame has the effect of underglaze five-color porcelain, the effect can be improved by about 50 times compared with the manual fencing process, the production cost is greatly reduced, the underglaze pellicle stained paper can be suitable for mass production, and a very important role is played in the development of the underglaze five-color porcelain.
Detailed Description
In order that the present invention may be more clearly understood, the following detailed description of the present invention is given with reference to specific examples.
Example one
A series of pigments for underglaze small membrane flower paper comprises at least one of orange pigment, manganese red pigment, black pigment, cymbidium pigment, pine green pigment and brown pigment, wherein the black pigment contains brown pigment; wherein the content of the first and second substances,
the orange pigment comprises the following components in percentage by mass: niobium oxide: 15%, cerium oxide: 15%, erbium oxide: 40% and quartz: 30%, glass powder: 20 percent;
the manganese red pigment comprises the following components in percentage by mass: alumina: 70%, manganese carbonate: 15%, sodium fluoride: 3% and red lead: 4%, calcium oxide: 5 percent;
the black pigment comprises the following components in percentage by mass: vanadium pentoxide: 25% and tin dioxide: 15%, zirconia: 25%, oxalic acid: 12.5%, quartz: 10%, cobalt oxide: 3 percent; brown pigment: 9.5 percent;
the cymbidium pigment comprises the following components in percentage by mass: cobalt oxide: 10%, chromium oxide: 16%, zinc oxide: 14%, calomel: 36%, alumina: 20% and quartz: 4 percent;
the pine green pigment comprises the following components in percentage by mass: chromium oxide: 1% and quartz: 30%, beryllium oxide: 48%, zinc oxide: 8%, calcium oxide: 9% and quartz: 4 percent;
the brown pigment comprises the following components in percentage by mass: potassium bichromate: 12% and blue vitriol: 8%, manganese oxide: 15%, chromium oxide: 10% of sand and stone: 5% and Jiepai mud: 4% and quartz: 46 percent.
The preparation method of the series of pigments for the underglaze small membrane stained paper comprises the following steps:
s1: preparing materials according to the components of the corresponding pigment and the mass percentage of each component;
s2: the components of the pigment are mixed and sieved, the sieved powder is filled into a sagger and is calcined in a kiln to form blocky or granular pigment, and then the blocky or granular pigment is crushed once, ball-milled, dried and crushed twice and is sieved to obtain a corresponding pigment finished product.
In step S2, the calcination temperature was 1360 ℃.
In this example, in the process of preparing the black pigment, it is necessary to prepare the brown pigment first and then prepare the black pigment using the brown pigment.
Example two
A series of pigments for underglaze small membrane flower paper comprises at least one of orange pigment, manganese red pigment, black pigment, cymbidium pigment, blue-green pigment and brown pigment; wherein the content of the first and second substances,
the orange pigment comprises the following components in percentage by mass: niobium oxide: 15%, cerium oxide: 15%, erbium oxide: 40% and quartz: 30%, glass powder: 20 percent;
the manganese red pigment comprises the following components in percentage by mass: alumina: 70%, manganese carbonate: 15%, sodium fluoride: 3% and red lead: 4%, calcium oxide: 5 percent;
the black pigment comprises the following components in percentage by mass: vanadium pentoxide: 25% and tin dioxide: 15%, zirconia: 25%, oxalic acid: 12.5%, quartz: 10%, cobalt oxide: 3 percent; brown pigment: 9.5 percent;
the cymbidium pigment comprises the following components in percentage by mass: cobalt oxide: 10%, chromium oxide: 17%, zinc oxide: 14%, calomel: 36%, alumina: 20% and quartz: 3 percent;
the pine green pigment comprises the following components in percentage by mass: chromium oxide: 2% and quartz: 30%, beryllium oxide: 48%, zinc oxide: 8%, calcium oxide: 8% and quartz: 4 percent;
the brown pigment comprises the following components in percentage by mass: potassium bichromate: 14% and blue vitriol: 10%, manganese oxide: 17%, chromium oxide: 10% of sand and stone: 5% and Jiepai mud: 4% and quartz: 40 percent.
The preparation method of the series of pigments for the underglaze small membrane stained paper comprises the following steps:
s1: preparing materials according to the components of the corresponding pigment and the mass percentage of each component;
s2: the components of the pigment are mixed and sieved, the sieved powder is filled into a sagger and is calcined in a kiln to form blocky or granular pigment, and then the blocky or granular pigment is crushed once, ball-milled, dried and crushed twice and is sieved to obtain a corresponding pigment finished product.
In step S2, the calcination temperature was 1360 ℃.
In this example, in the process of preparing the black pigment, it is necessary to prepare the brown pigment first and then prepare the black pigment using the brown pigment.
The underglaze film stained paper prepared by the two examples is used for preparing the film stained paper by using the series of pigments, and then the porcelain is prepared, and the porcelain can show the effect of underglaze colorful porcelain.
The above embodiments are described in further detail to solve the technical problems, technical solutions and advantages of the present invention, and it should be understood that the above embodiments are only examples of the present invention and are not intended to limit the present invention, and any modifications, equivalent substitutions, improvements and the like made within the spirit and principle of the present invention should be included in the protection scope of the present invention.
Claims (2)
1. A preparation method of series pigments for underglaze small membrane flower paper is characterized in that,
the series of pigments for the underglaze small membrane flower paper comprise at least one of orange pigment, manganese red pigment, black pigment, cymbidium pigment, turquoise pigment and brown pigment, wherein the black pigment contains brown pigment; wherein the content of the first and second substances,
the orange pigment comprises the following components in percentage by mass: niobium oxide: 15%, cerium oxide: 15%, erbium oxide: 40% and quartz: 30%, glass powder: 20 percent;
the manganese red pigment comprises the following components in percentage by mass: alumina: 70%, manganese carbonate: 15%, sodium fluoride: 3% and red lead: 4%, calcium oxide: 5 percent;
the cymbidium pigment comprises the following components in percentage by mass: cobalt oxide: 10% -12%, chromium oxide: 16% -18%, zinc oxide: 14% -16%, calomel: 36% -38%, alumina: 20-22%, quartz: 3% -5%, and the total amount of the components is 100%;
the pine green pigment comprises the following components in percentage by mass: chromium oxide: 1% -2%, quartz: 30% -32%, beryllium oxide: 48% -50%, zinc oxide: 8% -10%, calcium oxide: 8% -10%, quartz: 2% -4%, and the total amount of the components is 100%;
the brown pigment comprises the following components in percentage by mass: potassium bichromate: 12% -14%, blue vitriol: 8% -10%, manganese oxide: 15% -17%, chromium oxide: 10% -12%, sandstone: 5% -7%, Jiepai mud: 4% -6%, quartz: 40% -46%, and the total amount of the components is 100%;
the black pigment comprises the following components in percentage by mass: vanadium pentoxide: 25% and tin dioxide: 15%, zirconia: 25%, oxalic acid: 12.5%, quartz: 10%, cobalt oxide: 3 percent; brown pigment: 9.5 percent;
the preparation steps of each pigment in the series of pigments for the underglaze small membrane flower paper are as follows:
s1: preparing materials according to the components of the corresponding pigment and the mass percentage of each component;
s2: the components of the pigment are mixed and sieved, the sieved powder is filled into a sagger and is calcined in a kiln to form blocky or granular pigment, and then the blocky or granular pigment is crushed once, ball-milled, dried and crushed twice and is sieved to obtain a corresponding pigment finished product.
2. The method of claim 1, wherein: in step S2, the calcination temperature was 1360 ℃.
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| Application Number | Priority Date | Filing Date | Title |
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| CN201810194029.6A CN108360289B (en) | 2018-03-09 | 2018-03-09 | Series pigments for underglaze small film flower paper and preparation method thereof |
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| CN201810194029.6A CN108360289B (en) | 2018-03-09 | 2018-03-09 | Series pigments for underglaze small film flower paper and preparation method thereof |
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| CN108360289A CN108360289A (en) | 2018-08-03 |
| CN108360289B true CN108360289B (en) | 2020-10-23 |
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| CN113845783A (en) * | 2021-09-30 | 2021-12-28 | 湖南省陶瓷研究所有限公司 | Underglaze orange high-temperature pigment and preparation method thereof |
Citations (4)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN1158876A (en) * | 1996-03-04 | 1997-09-10 | 司志宏 | Preparation of pigment for screen printing |
| CN1165122A (en) * | 1997-02-03 | 1997-11-19 | 景德镇市宇宙瓷业有限公司 | High-temp. |
| CN103508757A (en) * | 2012-06-16 | 2014-01-15 | 醴陵市瓷艺堂有限责任公司 | Method for preparing underglaze green pigment |
| CN106467414A (en) * | 2016-09-27 | 2017-03-01 | 阜阳科技工程学校 | Boundary's head ancient painted pottery underglaze colour processing technology |
-
2018
- 2018-03-09 CN CN201810194029.6A patent/CN108360289B/en active Active
Patent Citations (4)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN1158876A (en) * | 1996-03-04 | 1997-09-10 | 司志宏 | Preparation of pigment for screen printing |
| CN1165122A (en) * | 1997-02-03 | 1997-11-19 | 景德镇市宇宙瓷业有限公司 | High-temp. |
| CN103508757A (en) * | 2012-06-16 | 2014-01-15 | 醴陵市瓷艺堂有限责任公司 | Method for preparing underglaze green pigment |
| CN106467414A (en) * | 2016-09-27 | 2017-03-01 | 阜阳科技工程学校 | Boundary's head ancient painted pottery underglaze colour processing technology |
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Effective date of registration: 20190619 Address after: 412200 No. 198 Zuoquan Road, Liling City, Zhuzhou City, Hunan Province Applicant after: Hunan New Century Ceramics Co., Ltd. Applicant after: Tang Linsheng Address before: 412200 Room 102, 3 Building No. 1, Xiangqianyan, Liling City, Zhuzhou City, Hunan Province Applicant before: Tang Linsheng |
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