CN108360289A - Membranelle marble paper serial pigment and preparation method thereof under glaze - Google Patents
Membranelle marble paper serial pigment and preparation method thereof under glaze Download PDFInfo
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- CN108360289A CN108360289A CN201810194029.6A CN201810194029A CN108360289A CN 108360289 A CN108360289 A CN 108360289A CN 201810194029 A CN201810194029 A CN 201810194029A CN 108360289 A CN108360289 A CN 108360289A
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- D—TEXTILES; PAPER
- D21—PAPER-MAKING; PRODUCTION OF CELLULOSE
- D21H—PULP COMPOSITIONS; PREPARATION THEREOF NOT COVERED BY SUBCLASSES D21C OR D21D; IMPREGNATING OR COATING OF PAPER; TREATMENT OF FINISHED PAPER NOT COVERED BY CLASS B31 OR SUBCLASS D21G; PAPER NOT OTHERWISE PROVIDED FOR
- D21H19/00—Coated paper; Coating material
- D21H19/36—Coatings with pigments
- D21H19/38—Coatings with pigments characterised by the pigments
- D21H19/385—Oxides, hydroxides or carbonates
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- D—TEXTILES; PAPER
- D21—PAPER-MAKING; PRODUCTION OF CELLULOSE
- D21H—PULP COMPOSITIONS; PREPARATION THEREOF NOT COVERED BY SUBCLASSES D21C OR D21D; IMPREGNATING OR COATING OF PAPER; TREATMENT OF FINISHED PAPER NOT COVERED BY CLASS B31 OR SUBCLASS D21G; PAPER NOT OTHERWISE PROVIDED FOR
- D21H19/00—Coated paper; Coating material
- D21H19/36—Coatings with pigments
- D21H19/38—Coatings with pigments characterised by the pigments
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- D—TEXTILES; PAPER
- D21—PAPER-MAKING; PRODUCTION OF CELLULOSE
- D21H—PULP COMPOSITIONS; PREPARATION THEREOF NOT COVERED BY SUBCLASSES D21C OR D21D; IMPREGNATING OR COATING OF PAPER; TREATMENT OF FINISHED PAPER NOT COVERED BY CLASS B31 OR SUBCLASS D21G; PAPER NOT OTHERWISE PROVIDED FOR
- D21H19/00—Coated paper; Coating material
- D21H19/36—Coatings with pigments
- D21H19/38—Coatings with pigments characterised by the pigments
- D21H19/40—Coatings with pigments characterised by the pigments siliceous, e.g. clays
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- Chemical & Material Sciences (AREA)
- Dispersion Chemistry (AREA)
- Glass Compositions (AREA)
Abstract
The invention discloses membranelle marble paper serial pigments and preparation method thereof under a kind of glaze, and membranelle marble paper serial pigment includes at least one of orange pigment, manganese red pigment, black pigment, the blue pigment in sea, pine green pigment, dark brown pigment under glaze；Wherein, the component of orange pigment and each component mass percent are as follows：Niobium oxide：15%, cerium oxide：15%, erbium oxide：40%, quartzy：30%, glass powder：20%；The component and each component mass percent of manganese red pigment are as follows：Aluminium oxide：70%, manganese carbonate：15%, sodium fluoride：3%, red lead：4%, calcium oxide：5%；The component and each component mass percent of black pigment are as follows：Vanadic anhydride：25%, stannic oxide：15%, zirconium oxide：25%, oxalic acid：12.5%, quartzy：10%, cobalt oxide：3%；Dark brown pigment：9.5%；It is affixed on glaze by the membranelle marble paper of its preparation, can not only make glaze that the effect of five color painting in the glaze porcelain be presented, and greatly improve effect, reduce production cost, can be suitable for producing in enormous quantities.
Description
Technical field
The present invention relates to membranelle marble paper serial pigments and preparation method thereof under a kind of glaze.
Background technology
Currently, the membranelle marble paper produced in enormous quantities, is only applicable to the production of 700 DEG C of low temperature on glaze, using membranelle marble paper system
The effect of five color painting in the glaze porcelain can be presented in standby porcelain, and five color painting in the glaze porcelain is prepared by using the technique of manual Fen Shui, and effect is low,
Production cost is high, cannot produce in enormous quantities.
Invention content
The technical problem to be solved by the present invention is to overcome the deficiencies of existing technologies, membranelle marble paper system under a kind of glaze is provided
Row pigment is affixed on by the membranelle marble paper of its preparation on glaze, can not only make glaze that the effect of five color painting in the glaze porcelain be presented, and significantly
Improvement effect reduces production cost, can be suitable for producing in enormous quantities.
In order to solve the above technical problems, the technical scheme is that：Membranelle marble paper serial pigment under a kind of glaze, it
Including at least one of orange pigment, manganese red pigment, black pigment, the blue pigment in sea, pine green pigment, dark brown pigment, black
Contain dark brown pigment in pigment；Wherein,
The component and each component mass percent of orange pigment are as follows：Niobium oxide：15%, cerium oxide：15%, erbium oxide：
40%, quartzy：30%, glass powder：20%；
The component and each component mass percent of manganese red pigment are as follows：Aluminium oxide：70%, manganese carbonate：15%, sodium fluoride：
3%, red lead：4%, calcium oxide：5%；
The component and each component mass percent of black pigment are as follows：Vanadic anhydride：25%, stannic oxide：15%, oxygen
Change zirconium：25%, oxalic acid：12.5%, quartzy：10%, cobalt oxide：3%；Dark brown pigment：9.5%；
The component and each component mass percent of extra large orchid pigment are as follows：Cobalt oxide：10%-12%, chromium oxide：16%-
18%, zinc oxide：14%-16%, calomel mercurous chloride：36%-38%, aluminium oxide：20-22%, quartz：3%-5%, the above component amount to
100%；
The component and each component mass percent of pine green pigment are as follows：Chromium oxide：1%-2%, quartz：30%-32%,
Beryllium oxide：48%-50%, zinc oxide：8%-10%, calcium oxide：8%-10%, quartz：2%-4%, the above component amount to
100%；
The component and each component mass percent of dark brown pigment are as follows：Arsenic potassium：12%-14%, green alum：8%-10%,
Manganese oxide：15%-17%, chromium oxide：10%-12%, sandstone：5%-7%, Jiepai clay：4%-6%, quartz：46%-50%,
The above component amounts to 100%.
The preparation method of membranelle marble paper serial pigment under a kind of glaze, each face under glaze in membranelle marble paper serial pigment
The preparation process of material is as follows：
S1：It stocks up according to the component and each component mass percent of corresponding pigment；
S2：The component of pigment is mixed, sieving, then the powder after sieving is packed into saggar, enters kiln calcining, formed it is blocky or
Granular pigment, then by once crushing, ball milling, drying, after separating twice, sieving obtains corresponding pigment finished product.
Further, in step S2, the temperature of calcining is 1360 DEG C.
After using above-mentioned technical proposal, the membranelle marble paper that membranelle marble paper serial pigment produces under glaze of the invention, energy
It is enough applicable in 1360 DEG C of high temperature under glaze, the porcelain of firing with reductive flame has the effect of five color painting in the glaze porcelain, compared with the hydraulic art of manual Fen,
50 times or so of effect can be improved, greatly reduce production cost, and can be suitable for producing in enormous quantities, be five color painting in the glaze porcelain
Development plays very great effect.
Specific implementation mode
In order that the present invention can be more clearly and readily understood, below according to specific embodiment, to the present invention make into
One step is described in detail.
Embodiment one
Membranelle marble paper serial pigment under a kind of glaze, it include orange pigment, manganese red pigment, black pigment, the blue pigment in sea,
At least one of pine green pigment, dark brown pigment contain dark brown pigment in black pigment；Wherein,
The component and each component mass percent of orange pigment are as follows：Niobium oxide：15%, cerium oxide：15%, erbium oxide：
40%, quartzy：30%, glass powder：20%；
The component and each component mass percent of manganese red pigment are as follows：Aluminium oxide：70%, manganese carbonate：15%, sodium fluoride：
3%, red lead：4%, calcium oxide：5%；
The component and each component mass percent of black pigment are as follows：Vanadic anhydride：25%, stannic oxide：15%, oxygen
Change zirconium：25%, oxalic acid：12.5%, quartzy：10%, cobalt oxide：3%；Dark brown pigment：9.5%；
The component and each component mass percent of extra large orchid pigment are as follows：Cobalt oxide：10%, chromium oxide：16%, zinc oxide：
14%, calomel mercurous chloride：36%, aluminium oxide：20%, quartzy：4%；
The component and each component mass percent of pine green pigment are as follows：Chromium oxide：1%, quartzy：30%, beryllium oxide：
48%, zinc oxide：8%, calcium oxide：9%, quartzy：4%；
The component and each component mass percent of dark brown pigment are as follows：Arsenic potassium：12%, green alum：8%, manganese oxide：
15%, chromium oxide：10%, sandstone：5%, Jiepai clay：4%, quartzy：46%.
The preparation method of membranelle marble paper serial pigment under glaze, each pigment under glaze in membranelle marble paper serial pigment
Preparation process is as follows：
S1：It stocks up according to the component and each component mass percent of corresponding pigment；
S2：The component of pigment is mixed, sieving, then the powder after sieving is packed into saggar, enters kiln calcining, formed it is blocky or
Granular pigment, then by once crushing, ball milling, drying, after separating twice, sieving obtains corresponding pigment finished product.
In step S2, the temperature of calcining is 1360 DEG C.
In the present embodiment, it during preparing black pigment, needs first to prepare dark brown pigment, recycles dark brown pigment system
Standby black pigment.
Embodiment two
Membranelle marble paper serial pigment under a kind of glaze, it include orange pigment, manganese red pigment, black pigment, the blue pigment in sea,
At least one of pine green pigment, dark brown pigment；Wherein,
The component and each component mass percent of orange pigment are as follows：Niobium oxide：15%, cerium oxide：15%, erbium oxide：
40%, quartzy：30%, glass powder：20%；
The component and each component mass percent of manganese red pigment are as follows：Aluminium oxide：70%, manganese carbonate：15%, sodium fluoride：
3%, red lead：4%, calcium oxide：5%；
The component and each component mass percent of black pigment are as follows：Vanadic anhydride：25%, stannic oxide：15%, oxygen
Change zirconium：25%, oxalic acid：12.5%, quartzy：10%, cobalt oxide：3%；Dark brown pigment：9.5%；
The component and each component mass percent of extra large orchid pigment are as follows：Cobalt oxide：10%, chromium oxide：17%, zinc oxide：
14%, calomel mercurous chloride：36%, aluminium oxide：20%, quartzy：3%；
The component and each component mass percent of pine green pigment are as follows：Chromium oxide：2%, quartzy：30%, beryllium oxide：
48%, zinc oxide：8%, calcium oxide：8%, quartzy：4%；
The component and each component mass percent of dark brown pigment are as follows：Arsenic potassium：14%, green alum：10%, manganese oxide：
17%, chromium oxide：10%, sandstone：5%, Jiepai clay：4%, quartzy：40%.
The preparation method of membranelle marble paper serial pigment under glaze, each pigment under glaze in membranelle marble paper serial pigment
Preparation process is as follows：
S1：It stocks up according to the component and each component mass percent of corresponding pigment；
S2：The component of pigment is mixed, sieving, then the powder after sieving is packed into saggar, enters kiln calcining, formed it is blocky or
Granular pigment, then by once crushing, ball milling, drying, after separating twice, sieving obtains corresponding pigment finished product.
In step S2, the temperature of calcining is 1360 DEG C.
In the present embodiment, it during preparing black pigment, needs first to prepare dark brown pigment, recycles dark brown pigment system
Standby black pigment.
Membranelle marble paper prepares membranelle marble paper with serial pigment under the glaze prepared using both examples above, then prepares porcelain
The effect of five color painting in the glaze porcelain can be presented in device, porcelain.
Particular embodiments described above, pair present invention solves the technical problem that, technical solution and advantageous effect carry out
It is further described, it should be understood that the above is only a specific embodiment of the present invention, is not limited to this
Invention, all within the spirits and principles of the present invention, any modification, equivalent substitution, improvement and etc. done should be included in this hair
Within bright protection domain.
Claims (3)
1. membranelle marble paper serial pigment under a kind of glaze, it is characterised in that：It include orange pigment, manganese red pigment, black pigment,
At least one of extra large orchid pigment, pine green pigment, dark brown pigment, contain dark brown pigment in black pigment；Wherein,
The component and each component mass percent of orange pigment are as follows：Niobium oxide：15%, cerium oxide：15%, erbium oxide：40%,
Quartz：30%, glass powder：20%；
The component and each component mass percent of manganese red pigment are as follows：Aluminium oxide：70%, manganese carbonate：15%, sodium fluoride：3%,
Red lead：4%, calcium oxide：5%；
The component and each component mass percent of extra large orchid pigment are as follows：Cobalt oxide：10%-12%, chromium oxide：16%-18%, oxygen
Change zinc：14%-16%, calomel mercurous chloride：36%-38%, aluminium oxide：20-22%, quartz：3%-5%, the above component amount to 100%；
The component and each component mass percent of pine green pigment are as follows：Chromium oxide：1%-2%, quartz：30%-32%, oxidation
Beryllium：48%-50%, zinc oxide：8%-10%, calcium oxide：8%-10%, quartz：2%-4%, the above component amount to 100%；
The component and each component mass percent of dark brown pigment are as follows：Arsenic potassium：12%-14%, green alum：8%-10%, oxidation
Manganese：15%-17%, chromium oxide：10%-12%, sandstone：5%-7%, Jiepai clay：4%-6%, quartz：40%-46%, it is above
Component amounts to 100%；
The component and each component mass percent of black pigment are as follows：Vanadic anhydride：25%, stannic oxide：15%, it aoxidizes
Zirconium：25%, oxalic acid：12.5%, quartzy：10%, cobalt oxide：3%；Dark brown pigment：9.5%.
2. the preparation method of membranelle marble paper serial pigment under a kind of glaze as described in claim 1, it is characterised in that small under glaze
The preparation process of each pigment in film marble paper serial pigment is as follows：
S1：It stocks up according to the component and each component mass percent of corresponding pigment；
S2：The component of pigment is mixed, sieving, then the powder after sieving is packed into saggar, enters kiln calcining, form blocky or particle
The pigment of shape, then by once crushing, ball milling, drying, after separating twice, sieving obtains corresponding pigment finished product.
3. preparation method according to claim 2, it is characterised in that：In step S2, the temperature of calcining is 1360 DEG C.
Priority Applications (1)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| CN201810194029.6A CN108360289B (en) | 2018-03-09 | 2018-03-09 | Series pigments for underglaze small film flower paper and preparation method thereof |
Applications Claiming Priority (1)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| CN201810194029.6A CN108360289B (en) | 2018-03-09 | 2018-03-09 | Series pigments for underglaze small film flower paper and preparation method thereof |
Publications (2)
| Publication Number | Publication Date |
|---|---|
| CN108360289A true CN108360289A (en) | 2018-08-03 |
| CN108360289B CN108360289B (en) | 2020-10-23 |
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| Application Number | Title | Priority Date | Filing Date |
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| CN201810194029.6A Active CN108360289B (en) | 2018-03-09 | 2018-03-09 | Series pigments for underglaze small film flower paper and preparation method thereof |
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Cited By (1)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN113845783A (en) * | 2021-09-30 | 2021-12-28 | 湖南省陶瓷研究所有限公司 | Underglaze orange high-temperature pigment and preparation method thereof |
Citations (4)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN1158876A (en) * | 1996-03-04 | 1997-09-10 | 司志宏 | Preparation of pigment for screen printing |
| CN1165122A (en) * | 1997-02-03 | 1997-11-19 | 景德镇市宇宙瓷业有限公司 | High-temp. |
| CN103508757A (en) * | 2012-06-16 | 2014-01-15 | 醴陵市瓷艺堂有限责任公司 | Method for preparing underglaze green pigment |
| CN106467414A (en) * | 2016-09-27 | 2017-03-01 | 阜阳科技工程学校 | Boundary's head ancient painted pottery underglaze colour processing technology |
-
2018
- 2018-03-09 CN CN201810194029.6A patent/CN108360289B/en active Active
Patent Citations (4)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN1158876A (en) * | 1996-03-04 | 1997-09-10 | 司志宏 | Preparation of pigment for screen printing |
| CN1165122A (en) * | 1997-02-03 | 1997-11-19 | 景德镇市宇宙瓷业有限公司 | High-temp. |
| CN103508757A (en) * | 2012-06-16 | 2014-01-15 | 醴陵市瓷艺堂有限责任公司 | Method for preparing underglaze green pigment |
| CN106467414A (en) * | 2016-09-27 | 2017-03-01 | 阜阳科技工程学校 | Boundary's head ancient painted pottery underglaze colour processing technology |
Cited By (1)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN113845783A (en) * | 2021-09-30 | 2021-12-28 | 湖南省陶瓷研究所有限公司 | Underglaze orange high-temperature pigment and preparation method thereof |
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| CN108360289B (en) | 2020-10-23 |
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| TA01 | Transfer of patent application right | ||
| TA01 | Transfer of patent application right |
Effective date of registration: 20190619 Address after: 412200 No. 198 Zuoquan Road, Liling City, Zhuzhou City, Hunan Province Applicant after: Hunan New Century Ceramics Co., Ltd. Applicant after: Tang Linsheng Address before: 412200 Room 102, 3 Building No. 1, Xiangqianyan, Liling City, Zhuzhou City, Hunan Province Applicant before: Tang Linsheng |
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