CN1315957C - High temp, resistant lead-free and cadmium-free printing ink for glass - Google Patents
High temp, resistant lead-free and cadmium-free printing ink for glass Download PDFInfo
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- CN1315957C CN1315957C CNB031267955A CN03126795A CN1315957C CN 1315957 C CN1315957 C CN 1315957C CN B031267955 A CNB031267955 A CN B031267955A CN 03126795 A CN03126795 A CN 03126795A CN 1315957 C CN1315957 C CN 1315957C
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- lead
- glass powder
- cadmium
- cadmium free
- free
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Abstract
The present invention provides high-temperature resistance printing ink without lead and cadmium, which is used for glass, and relates to the correlation technique of color high-temperature resistance printing ink without lead and cadmium, which is used for toughening and hot-bending processing by glass in the fields of buildings, decoration, vehicles, etc. The present invention is composed of 30 to 80 wt% of glass powder without lead and cadmium, 1 to 50 wt% of inorganic pigment of which the high-temperature resistance reaches above 400 DEGC, and 15 to 50 wt% og organic adhesive of which the viscosity is 50 to 1200 Pas, wherein the glass powder without lead and cadmium comprises the components: 15 to 55 wt% of SiO2, 20 to 60 wt% of H3BO3, 5 to 30 wt% of Na2LO3, 0 to 20 wt% of K2CO3, 0 to 30 wt% of Li2CO3, 0 to 5 wt% of Al2O3, 0 to 25 wt% of ZnO, 0 to 15 wt% of ZrO2, 0 to 30 wt% of NaF, and 0 to 25 wt% of TiO2. The manufacturing method of the present invention comprises: firstly, after the glass powder without lead and cadmium is manufactured, the inorganic pigment is added in the glass powder to be fully mixed with the organic adhesive. The glass powder does not have lead and cadmium, and can not cause environmental pollution.
Description
Technical field
The present invention relates to high temperature resistant printing ink field, particularly handle with high temperature resistant colored lead and cadmium free printing ink correlation technique with glass tempering, hot bending in fields such as building, decoration and automobile.
Background technology
Glass types is a lot, but the overwhelming majority all contains lead, cadmium composition; Particularly plumbous its ratio is very high as major ingredient, has seriously become the pollution to environment of plumbous, cadmium.Aspect the glass colouring, general lead and cadmium free glass fusing point is higher, relatively poor with the matching of various pigments, can not reach glass tempering, hot bending and handle with ink technique and color requirement, do not find by retrieval that at present glass tempering, hot bending handle with high temperature resistant lead and cadmium free ink technology.
Technology contents
The object of the invention provides a kind of lead and cadmium free composition, is fit to the high temperature resistant colored ink of glass tempering, the requirement of hot bending treatment process.
The object of the invention can be achieved through the following technical solutions.
A kind of glass is with the prescription of durable high temperature resistant lead and cadmium free printing ink, the weight percent of described each component is: lead and cadmium free glass powder 30～80%, lead and cadmium free inorganic pigment 1～50%, viscosity be 50～1200pas caking agent 15～50%. wherein the weight percent of lead and cadmium free glass powder each component be:
SiO
2 15～55％ H
3BO
3 20～60％ Na
2?CO
3 5～30％
K
2CO
3 0～20％ Li
2CO
3 0～30％ Al
2O
3 0～5％
ZnO 0～25％ ZrO
2 0～15％ NaF?0～30％
TiO
2 0～25％
Glass is stand linseed oil with caking agent in the prescription of high-temp leadless cadmium printing ink, and caking agent also can be in the prescription of high-temperature-resistant Cd-lead-free ink used for Glasses: the tackiness agent that any one or more dissolvings that mix form in Mierocrystalline cellulose or acrylic resin and Terpineol 350, turps, Diethylene Glycol butyl ether, dibutyl phthalate or the Viscotrol C. described lead and cadmium free inorganic pigment is titanium dioxide or ceramic stain.H in prescription
3O
3, Na
2CO
3, K
2CO
3, Li
2CO
3Can be respectively with its oxide compound B
2O
3, Na
2O, K
2O, Li
2O substitutes.
The described production technique of the production technique of high-temperature-resistant Cd-lead-free ink used for Glasses is:
(1) production of lead and cadmium free glass:
1. take by weighing above-mentioned each the raw material thorough mixing of lead and cadmium free glass powder in proportion;
2. mixture is melted in smelting furnace;
3. the liquation of the fusing that will be melted is at the room temperature quenching-in water;
4. the glass powder comminution after will quenching is carefully obtained glass powder to 400 orders;
5. glass powder is dried between 40-80 ℃, make its moisture content less than 2%;
6. the glass of drying is broken to and promptly gets lead and cadmium free glass powder more than 100 orders;
(2) production of printing ink;
7. take by weighing lead and cadmium free glass powder in proportion, be crushed to the above lead and cadmium free glass powder of 100 orders, inorganic pigment, binding agent, fully ground and mixed is finished product.
Technical progress of the present invention is the lead and cadmium free composition, and the high temperature resistant colored ink that requires of suitable glass tempering, hot bending treatment process.
Specific embodiment
Produce the high temperature resistant lead and cadmium free printing ink of a kind of white, the prescription with high temperature resistant lead and cadmium free printing ink is handled in this glass reinforced plastic heat-transmission gulf, and the weight of described each composition part is: lead and cadmium free glass powder 100kg, and titanium dioxide 20kg, viscosity is 50～1200pas stand linseed oil 30kg; Wherein the weight of lead and cadmium free glass powder each component is:
SiO
2 20kg H
3BO
3 40kg Na
2CO
3 10kg
K
2CO
3?5kg Li
2CO
3?5kg Al
2O
3 5kg
ZnO 5kg ZrO
3 2kg NaF 5kg
TiO
2 3kg
Caking agent is a stand linseed oil in the prescription of high-temperature-resistant Cd-lead-free ink used for Glasses.Lead and cadmium free inorganic pigment described in the prescription of high-temperature-resistant Cd-lead-free ink used for Glasses is a titanium dioxide.
The production technique that a kind of glass tempering hot bending is handled with high temperature resistant lead and cadmium free printing ink is:
The ratio of connecing takes by weighing above-mentioned each the raw material thorough mixing of lead and cadmium free glass powder;
1. take by weighing above-mentioned each the raw material thorough mixing of lead and cadmium free glass powder in proportion;
2. mixture is melted in smelting furnace;
3. the liquation after will quenching is at the room temperature quenching-in water;
4. the glass powder after will quenching is broken to and promptly gets glass powder more than 400 orders;
5. glass powder is dried between 50 ℃, make its moisture content less than 2%;
6. the glass powder of drying is broken to the lead and cadmium free glass powder more than 100 orders;
7. get lead and cadmium free glass powder in proportion, be crushed to the above lead and cadmium free glass powder of 100 orders, the inorganic pigment titanium dioxide, the binding agent stand linseed oil, fully grinding is closed and is finished product.
Claims (3)
1, a kind of glass is with the prescription of high temperature resistant no aluminium cadmium printing ink, it is characterized in that, the weight percent of described each component is: lead and cadmium free glass powder 30～80%, and high temperature resistant is lead and cadmium free inorganic pigment 1～50% more than 400 ℃, described lead and cadmium free inorganic pigment is titanium dioxide or ceramic stain; Viscosity is the organic adhesive 15～50% of 50～1200Pas, and described organic adhesive is Mierocrystalline cellulose or acrylic resin and is selected from the caking agent that any one or more blended dissolution with solvents forms in Terpineol 350, turps, Diethylene Glycol butyl ether, dibutyl phthalate or the Viscotrol C; Wherein the weight percent of lead and cadmium free glass powder each component is:
SiO
2 15～55％ H
3BO
3 20～60％ Na
2CO
3 5～30％
K
2CO
3 0～20％ Li
2CO
3 0～30％ Al
2O
3 0～5％
ZnO 0～25％ ZrO
2 0～15％ NaF 0～30％
TiO
2 0～25％。
2, according to the prescription of the described high-temperature-resistant Cd-lead-free ink used for Glasses of claim 1, it is characterized in that the H in the described lead and cadmium free glass powder component
3BO
3Use B
2O
3Substitute Na
2CO
3Use Na
2O substitutes, K
2CO
3Use K
2O substitutes, Li
2CO
3Use Li
2O substitutes.
3, the production technique of a kind of high-temperature-resistant Cd-lead-free ink used for Glasses as claimed in claim 1 is characterized in that, described production technique is:
1. take by weighing lead and cadmium free glass powder each component in proportion, with the each component thorough mixing;
2. mixture is melted in smelting furnace;
3. with the liquation that is melted at the room temperature quenching-in water;
4. the glass powder after will quenching is obtained glass powder more than being broken to 400 orders;
5. glass powder is dried between 40-80 ℃, make its moisture content less than 2%;
6. the glass powder of drying is broken to and promptly gets lead and cadmium free glass powder more than 100 orders;
7. take by weighing the above lead and cadmium free glass powder of 100 orders in proportion, lead and cadmium free inorganic pigment and caking agent, fully ground and mixed is finished product.
Priority Applications (1)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| CNB031267955A CN1315957C (en) | 2003-06-02 | 2003-06-02 | High temp, resistant lead-free and cadmium-free printing ink for glass |
Applications Claiming Priority (1)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| CNB031267955A CN1315957C (en) | 2003-06-02 | 2003-06-02 | High temp, resistant lead-free and cadmium-free printing ink for glass |
Publications (2)
| Publication Number | Publication Date |
|---|---|
| CN1477163A CN1477163A (en) | 2004-02-25 |
| CN1315957C true CN1315957C (en) | 2007-05-16 |
Family
ID=34153115
Family Applications (1)
| Application Number | Title | Priority Date | Filing Date |
|---|---|---|---|
| CNB031267955A Expired - Fee Related CN1315957C (en) | 2003-06-02 | 2003-06-02 | High temp, resistant lead-free and cadmium-free printing ink for glass |
Country Status (1)
| Country | Link |
|---|---|
| CN (1) | CN1315957C (en) |
Cited By (1)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN109574502A (en) * | 2018-12-04 | 2019-04-05 | 咸阳盈和电子材料有限公司 | A kind of automobile back windshield half matt crown glass body powder and preparation method thereof |
Families Citing this family (11)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN101088947B (en) * | 2006-06-13 | 2010-10-27 | 上海宝银电子材料有限公司 | Heat resistant antisticking no-lead black glaze for automobile glass and its prepn process |
| CN102382518B (en) * | 2011-11-23 | 2015-03-04 | 佛山市明朝科技开发有限公司 | Ceramic ink-jet ink with low viscosity and preparation method thereof |
| CN102876112B (en) * | 2012-09-27 | 2014-10-08 | 彩虹集团公司 | Mirror ink for automotive glass and preparation method of mirror ink |
| CN102964907A (en) * | 2012-10-31 | 2013-03-13 | 彩虹集团公司 | Environment-friendly ink paste for automobile glass and preparation method thereof |
| CN102964906A (en) * | 2012-10-31 | 2013-03-13 | 彩虹集团公司 | Printing ink without lead or cadmium for toughened glass and preparation method thereof |
| CN104403419A (en) * | 2014-12-04 | 2015-03-11 | 河北省沙河玻璃技术研究院 | Glass ink for ink-jet printing and preparation method of glass ink |
| CN104861766A (en) * | 2015-06-03 | 2015-08-26 | 张阳康 | High-temperature glass printing ink |
| CN108329745A (en) * | 2017-01-18 | 2018-07-27 | 东莞华清光学科技有限公司 | The processing method of high temperature resistant ink and bend glass |
| CN108587317A (en) * | 2018-05-18 | 2018-09-28 | 刘凡领 | A kind of preparation method of crown glass ink |
| CN110157236A (en) * | 2019-05-20 | 2019-08-23 | 深圳市博耀新材料有限公司 | A kind of tasteless environmentally friendly glass ink and preparation method thereof applied to 3D, 4D heat-bending glass |
| CN115353289B (en) * | 2022-09-06 | 2024-01-26 | 湖南衡义材料科技有限公司 | Glass powder and preparation method and application thereof |
Citations (5)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN86104951A (en) * | 1986-07-26 | 1988-02-10 | 东北工学院 | Silicon resin, heat-resistant paint |
| US4810420A (en) * | 1986-10-02 | 1989-03-07 | General Electric Company | Thick film copper via-fill inks |
| CN1050890A (en) * | 1989-10-12 | 1991-04-24 | 中国建材研究院高技术陶瓷研究所 | Fire-resistant oxidation resistant coating |
| CN1069990A (en) * | 1992-06-09 | 1993-03-17 | 钱宏毅 | The preparation method of glass oil painting pigment |
| JP2000085251A (en) * | 1998-09-14 | 2000-03-28 | Nitto Denko Corp | Thermal transfer ink sheet |
-
2003
- 2003-06-02 CN CNB031267955A patent/CN1315957C/en not_active Expired - Fee Related
Patent Citations (5)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN86104951A (en) * | 1986-07-26 | 1988-02-10 | 东北工学院 | Silicon resin, heat-resistant paint |
| US4810420A (en) * | 1986-10-02 | 1989-03-07 | General Electric Company | Thick film copper via-fill inks |
| CN1050890A (en) * | 1989-10-12 | 1991-04-24 | 中国建材研究院高技术陶瓷研究所 | Fire-resistant oxidation resistant coating |
| CN1069990A (en) * | 1992-06-09 | 1993-03-17 | 钱宏毅 | The preparation method of glass oil painting pigment |
| JP2000085251A (en) * | 1998-09-14 | 2000-03-28 | Nitto Denko Corp | Thermal transfer ink sheet |
Cited By (1)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN109574502A (en) * | 2018-12-04 | 2019-04-05 | 咸阳盈和电子材料有限公司 | A kind of automobile back windshield half matt crown glass body powder and preparation method thereof |
Also Published As
| Publication number | Publication date |
|---|---|
| CN1477163A (en) | 2004-02-25 |
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| C06 | Publication | ||
| PB01 | Publication | ||
| C10 | Entry into substantive examination | ||
| SE01 | Entry into force of request for substantive examination | ||
| C14 | Grant of patent or utility model | ||
| GR01 | Patent grant | ||
| EE01 | Entry into force of recordation of patent licensing contract |
Assignee: Shenzhen Senlont Electronic Co., Ltd. Assignor: Ye Zhilong Contract fulfillment period: 2009.4.1 to 2023.3.31 contract change Contract record no.: 2009440000391 Denomination of invention: High temp, resistant lead-free and cadmium-free printing ink for glass Granted publication date: 20070516 License type: Exclusive license Record date: 2009.5.18 |
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| LIC | Patent licence contract for exploitation submitted for record |
Free format text: EXCLUSIVE LICENSE; TIME LIMIT OF IMPLEMENTING CONTACT: 2009.4.1 TO 2023.3.31; CHANGE OF CONTRACT Name of requester: SHENZHEN SENLONT ELECTRIC CO., LTD. Effective date: 20090518 |
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| CF01 | Termination of patent right due to non-payment of annual fee | ||
| CF01 | Termination of patent right due to non-payment of annual fee |
Granted publication date: 20070516 Termination date: 20160602 |