CN108358745A - 制备2,3,3,3-四氟-2-丙烯的方法 - Google Patents
制备2,3,3,3-四氟-2-丙烯的方法 Download PDFInfo
- Publication number
- CN108358745A CN108358745A CN201810257855.0A CN201810257855A CN108358745A CN 108358745 A CN108358745 A CN 108358745A CN 201810257855 A CN201810257855 A CN 201810257855A CN 108358745 A CN108358745 A CN 108358745A
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- China
- Prior art keywords
- tcp
- reactor
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- phase
- catalyst
- Prior art date
- Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
- Pending
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Classifications
-
- C—CHEMISTRY; METALLURGY
- C07—ORGANIC CHEMISTRY
- C07C—ACYCLIC OR CARBOCYCLIC COMPOUNDS
- C07C17/00—Preparation of halogenated hydrocarbons
- C07C17/093—Preparation of halogenated hydrocarbons by replacement by halogens
- C07C17/20—Preparation of halogenated hydrocarbons by replacement by halogens of halogen atoms by other halogen atoms
- C07C17/21—Preparation of halogenated hydrocarbons by replacement by halogens of halogen atoms by other halogen atoms with simultaneous increase of the number of halogen atoms
-
- C—CHEMISTRY; METALLURGY
- C07—ORGANIC CHEMISTRY
- C07C—ACYCLIC OR CARBOCYCLIC COMPOUNDS
- C07C17/00—Preparation of halogenated hydrocarbons
- C07C17/25—Preparation of halogenated hydrocarbons by splitting-off hydrogen halides from halogenated hydrocarbons
-
- B—PERFORMING OPERATIONS; TRANSPORTING
- B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
- B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
- B01J23/00—Catalysts comprising metals or metal oxides or hydroxides, not provided for in group B01J21/00
- B01J23/16—Catalysts comprising metals or metal oxides or hydroxides, not provided for in group B01J21/00 of arsenic, antimony, bismuth, vanadium, niobium, tantalum, polonium, chromium, molybdenum, tungsten, manganese, technetium or rhenium
- B01J23/18—Arsenic, antimony or bismuth
-
- C—CHEMISTRY; METALLURGY
- C07—ORGANIC CHEMISTRY
- C07C—ACYCLIC OR CARBOCYCLIC COMPOUNDS
- C07C17/00—Preparation of halogenated hydrocarbons
- C07C17/07—Preparation of halogenated hydrocarbons by addition of hydrogen halides
- C07C17/087—Preparation of halogenated hydrocarbons by addition of hydrogen halides to unsaturated halogenated hydrocarbons
-
- C—CHEMISTRY; METALLURGY
- C07—ORGANIC CHEMISTRY
- C07C—ACYCLIC OR CARBOCYCLIC COMPOUNDS
- C07C17/00—Preparation of halogenated hydrocarbons
- C07C17/093—Preparation of halogenated hydrocarbons by replacement by halogens
- C07C17/20—Preparation of halogenated hydrocarbons by replacement by halogens of halogen atoms by other halogen atoms
- C07C17/202—Preparation of halogenated hydrocarbons by replacement by halogens of halogen atoms by other halogen atoms two or more compounds being involved in the reaction
- C07C17/206—Preparation of halogenated hydrocarbons by replacement by halogens of halogen atoms by other halogen atoms two or more compounds being involved in the reaction the other compound being HX
-
- C—CHEMISTRY; METALLURGY
- C07—ORGANIC CHEMISTRY
- C07C—ACYCLIC OR CARBOCYCLIC COMPOUNDS
- C07C17/00—Preparation of halogenated hydrocarbons
- C07C17/38—Separation; Purification; Stabilisation; Use of additives
-
- C—CHEMISTRY; METALLURGY
- C07—ORGANIC CHEMISTRY
- C07C—ACYCLIC OR CARBOCYCLIC COMPOUNDS
- C07C17/00—Preparation of halogenated hydrocarbons
- C07C17/38—Separation; Purification; Stabilisation; Use of additives
- C07C17/383—Separation; Purification; Stabilisation; Use of additives by distillation
-
- C—CHEMISTRY; METALLURGY
- C07—ORGANIC CHEMISTRY
- C07C—ACYCLIC OR CARBOCYCLIC COMPOUNDS
- C07C21/00—Acyclic unsaturated compounds containing halogen atoms
- C07C21/02—Acyclic unsaturated compounds containing halogen atoms containing carbon-to-carbon double bonds
- C07C21/18—Acyclic unsaturated compounds containing halogen atoms containing carbon-to-carbon double bonds containing fluorine
Landscapes
- Chemical & Material Sciences (AREA)
- Organic Chemistry (AREA)
- Chemical Kinetics & Catalysis (AREA)
- Engineering & Computer Science (AREA)
- Materials Engineering (AREA)
- Organic Low-Molecular-Weight Compounds And Preparation Thereof (AREA)
Applications Claiming Priority (5)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| US201161434005P | 2011-01-19 | 2011-01-19 | |
| US61/434005 | 2011-01-19 | ||
| US13/313649 | 2011-12-07 | ||
| US13/313,649 US9890096B2 (en) | 2011-01-19 | 2011-12-07 | Methods of making 2,3,3,3-tetrafluoro-2-propene |
| CN201280005395.3A CN103534228A (zh) | 2011-01-19 | 2012-01-13 | 制备2,3,3,3-四氟-2-丙烯的方法 |
Related Parent Applications (1)
| Application Number | Title | Priority Date | Filing Date |
|---|---|---|---|
| CN201280005395.3A Division CN103534228A (zh) | 2011-01-19 | 2012-01-13 | 制备2,3,3,3-四氟-2-丙烯的方法 |
Publications (1)
| Publication Number | Publication Date |
|---|---|
| CN108358745A true CN108358745A (zh) | 2018-08-03 |
Family
ID=46491269
Family Applications (2)
| Application Number | Title | Priority Date | Filing Date |
|---|---|---|---|
| CN201810257855.0A Pending CN108358745A (zh) | 2011-01-19 | 2012-01-13 | 制备2,3,3,3-四氟-2-丙烯的方法 |
| CN201280005395.3A Pending CN103534228A (zh) | 2011-01-19 | 2012-01-13 | 制备2,3,3,3-四氟-2-丙烯的方法 |
Family Applications After (1)
| Application Number | Title | Priority Date | Filing Date |
|---|---|---|---|
| CN201280005395.3A Pending CN103534228A (zh) | 2011-01-19 | 2012-01-13 | 制备2,3,3,3-四氟-2-丙烯的方法 |
Country Status (8)
| Country | Link |
|---|---|
| US (1) | US9890096B2 (https=) |
| EP (1) | EP2665696B1 (https=) |
| JP (1) | JP5953317B2 (https=) |
| KR (1) | KR101925339B1 (https=) |
| CN (2) | CN108358745A (https=) |
| ES (1) | ES2666489T3 (https=) |
| MX (1) | MX2013008287A (https=) |
| WO (1) | WO2012099776A1 (https=) |
Families Citing this family (25)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| US8927791B2 (en) * | 2010-04-29 | 2015-01-06 | Honeywell International Inc. | Method for producing tetrafluoropropenes |
| MX2014002893A (es) * | 2011-09-15 | 2014-04-30 | Daikin Ind Ltd | Metodo para purificar hidrocarburos clorados. |
| EP2970057B1 (en) | 2013-03-12 | 2018-11-07 | Honeywell International Inc. | A method for mitigating hfc-245cb formation during hcfo-1233xf hydrofluorination to hcfc-244bb |
| EP2970060A4 (en) * | 2013-03-13 | 2016-10-26 | Honeywell Int Inc | STEP-BY-STEP FLUORING METHOD AND REACTOR SYSTEM |
| US9272968B2 (en) | 2013-03-14 | 2016-03-01 | Honeywell International Inc. | Process to suppress the formation of 3,3,3-trifluoropropyne in fluorocarbon manufacture |
| US9353029B2 (en) | 2013-03-14 | 2016-05-31 | Honeywell International, Inc. | Fluorination process and reactor |
| US20140275651A1 (en) * | 2013-03-15 | 2014-09-18 | Honeywell International Inc. | Process for producing 2,3,3,3-tetrafluoropropene |
| WO2014172592A1 (en) * | 2013-04-18 | 2014-10-23 | Honeywell International Inc. | Reaction system and process to produce fluorinated organics |
| US20150225315A1 (en) * | 2014-02-10 | 2015-08-13 | Honeywell International Inc. | Reactor design for liquid phase fluorination |
| MX370708B (es) * | 2014-02-10 | 2019-12-20 | Honeywell Int Inc | Reactor para reacciones de fluoración en fase líquida. |
| WO2016051900A1 (ja) | 2014-09-30 | 2016-04-07 | ダイキン工業株式会社 | 2,3,3,3-テトラフルオロプロペンの製造方法 |
| JP6210073B2 (ja) * | 2015-01-21 | 2017-10-11 | ダイキン工業株式会社 | フルオロプロペンの製造方法 |
| CN107743479A (zh) * | 2015-04-24 | 2018-02-27 | 霍尼韦尔国际公司 | 降低244bb中的1233xf浓度的方法 |
| KR102847526B1 (ko) * | 2015-05-21 | 2025-08-20 | 더 케무어스 컴퍼니 에프씨, 엘엘씨 | SbF5에 의한 1233xf의 244bb로의 히드로플루오린화 |
| GB2540427B (en) * | 2015-07-17 | 2017-07-19 | Mexichem Fluor Sa De Cv | Process for the preparation of 2,3,3,3-tetrafluoropropene (1234yf) |
| GB201512510D0 (en) * | 2015-07-17 | 2015-08-19 | Mexichem Fluor Sa De Cv | Process |
| US9938213B2 (en) * | 2015-08-19 | 2018-04-10 | Honeywell International Inc. | Methods for removing acidic impurities from halogenated propenes |
| GB201701099D0 (en) * | 2017-01-23 | 2017-03-08 | Mexichem Fluor Sa De Cv | Process |
| KR101992230B1 (ko) | 2017-08-08 | 2019-06-25 | (주)후성 | 기상 촉매를 이용한 1,1,1-트리플루오로-2-클로로프로펜과 1,1,1,2-테트라플루오로프로펜의 동시 제조 방법 |
| US10233137B1 (en) | 2017-10-13 | 2019-03-19 | Honeywell International Inc. | Method for removing unsaturated halogenated impurities from 2,3,3,3-tetrafluoropropene (HFO-1234yf) |
| US10246389B1 (en) | 2018-01-08 | 2019-04-02 | Honeywell International Inc. | Compositions containing 2-chloro-1,1,1,2-tetrafluoropropane (HCFC-244bb) |
| US10351494B1 (en) | 2018-01-08 | 2019-07-16 | Honeywell International Inc. | Systems and methods for reducing the formation of impurities during 244bb dehydrochlorination to 1234yf |
| CN112313199A (zh) | 2018-06-06 | 2021-02-02 | 霍尼韦尔国际公司 | 用于HCFC-244bb的脱氯化氢以制备HFO-1234yf的方法 |
| US10941091B2 (en) | 2018-12-03 | 2021-03-09 | Honeywell International Inc. | Processes for producing high-purity trifluoroiodomethane |
| US20220080243A1 (en) * | 2020-09-11 | 2022-03-17 | Honeywell International Inc. | Azeotrope or azeotrope-like compositions of trifluoroiodomethane (cf3i) and water |
Citations (4)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| US20070129580A1 (en) * | 2004-04-29 | 2007-06-07 | Honeywell International Inc. | Method for producing fluorinated organic compounds |
| US20070197841A1 (en) * | 2004-04-29 | 2007-08-23 | Honeywell International Inc. | Method for producing fluorinated organic compounds |
| CN101597209A (zh) * | 2008-03-20 | 2009-12-09 | 霍尼韦尔国际公司 | 用于制备2,3,3,3-四氟丙烯的一体式方法 |
| CN101665403A (zh) * | 2008-08-08 | 2010-03-10 | 霍尼韦尔国际公司 | 生产2-氯-1,1,1,2-四氟丙烷(HCFC-244bb)的改进方法 |
Family Cites Families (21)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| US5271918A (en) * | 1991-03-11 | 1993-12-21 | Alliedsignal Inc. | Furnace gas - sulfuric acid contact process for HF manufacture |
| CN1110449C (zh) * | 1995-10-10 | 2003-06-04 | 英尼奥斯费罗控股有限公司 | 分离和回收氟化氢的方法以及制备含氟有机化合物的方法 |
| US8084653B2 (en) * | 2004-04-29 | 2011-12-27 | Honeywell International, Inc. | Method for producing fluorinated organic compounds |
| US8067649B2 (en) * | 2004-04-29 | 2011-11-29 | Honeywell International Inc. | Method for producing fluorinated organic compounds |
| US8058486B2 (en) * | 2004-04-29 | 2011-11-15 | Honeywell International Inc. | Integrated process to produce 2,3,3,3-tetrafluoropropene |
| SI3336074T1 (sl) * | 2006-01-03 | 2025-09-30 | Honeywell International Inc. | Postopek za proizvodnjo fluoriranih organskih spojin |
| US8071825B2 (en) * | 2006-01-03 | 2011-12-06 | Honeywell International Inc. | Method for producing fluorinated organic compounds |
| US8664455B2 (en) * | 2008-08-08 | 2014-03-04 | Honeywell International Inc. | Process to manufacture 2-chloro-1,1,1,2-tetrafluoropropane (HCFC-244bb) |
| GB0611742D0 (en) * | 2006-06-14 | 2006-07-26 | Ineos Fluor Holdings Ltd | Desiccants for fluids |
| US8133406B2 (en) | 2006-10-31 | 2012-03-13 | E.I. Du Pont De Nemours And Company | Processes for producing 2,3,3,3-tetrafluoropropene and/or 1,2,3,3-tetrafluoropropene |
| GB0625214D0 (en) * | 2006-12-19 | 2007-01-24 | Ineos Fluor Holdings Ltd | Process |
| GB0806389D0 (en) | 2008-04-09 | 2008-05-14 | Ineos Fluor Holdings Ltd | Process |
| GB0808836D0 (en) | 2008-05-15 | 2008-06-18 | Ineos Fluor Ltd | Process |
| US8916733B2 (en) * | 2008-06-17 | 2014-12-23 | Honeywell International Inc. | Processes for hydrofluorination of 2-chloro-3,3,3-trifluoropropene to 2-chloro-1,1,1,2-tetrafluoropropane |
| KR101610009B1 (ko) | 2008-06-26 | 2016-04-07 | 알케마 인코포레이티드 | 1230xa에서 1234yf로의 촉매식 기체상 불소화 |
| FR2933402B1 (fr) | 2008-07-03 | 2010-07-30 | Arkema France | Procede de purification de 2,3,3,3-tetrafluoro-1-propene (hfo1234yf) |
| CA2743842C (en) * | 2008-11-19 | 2016-02-09 | Arkema Inc. | Process for the manufacture of hydrofluoroolefins |
| US8618340B2 (en) | 2009-11-03 | 2013-12-31 | Honeywell International Inc. | Integrated process for fluoro-olefin production |
| CN105062427A (zh) | 2009-12-22 | 2015-11-18 | 纳幕尔杜邦公司 | 包含2,3,3,3-四氟丙烯、1,1,2,3-四氯丙烯、2-氯-3,3,3-三氟丙烯、或2-氯-1,1,1,2-四氟丙烷的组合物 |
| WO2011077191A1 (en) | 2009-12-23 | 2011-06-30 | Arkema France | Catalytic gas phase fluorination of 1230xa to 1234yf |
| PL2545021T3 (pl) | 2010-03-10 | 2017-03-31 | Arkema France | Sposób fluorowania w fazie ciekłej |
-
2011
- 2011-12-07 US US13/313,649 patent/US9890096B2/en not_active Expired - Fee Related
-
2012
- 2012-01-13 CN CN201810257855.0A patent/CN108358745A/zh active Pending
- 2012-01-13 KR KR1020137021634A patent/KR101925339B1/ko not_active Expired - Fee Related
- 2012-01-13 MX MX2013008287A patent/MX2013008287A/es active IP Right Grant
- 2012-01-13 EP EP12737145.8A patent/EP2665696B1/en not_active Not-in-force
- 2012-01-13 ES ES12737145.8T patent/ES2666489T3/es active Active
- 2012-01-13 CN CN201280005395.3A patent/CN103534228A/zh active Pending
- 2012-01-13 JP JP2013550503A patent/JP5953317B2/ja not_active Expired - Fee Related
- 2012-01-13 WO PCT/US2012/021158 patent/WO2012099776A1/en not_active Ceased
Patent Citations (4)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| US20070129580A1 (en) * | 2004-04-29 | 2007-06-07 | Honeywell International Inc. | Method for producing fluorinated organic compounds |
| US20070197841A1 (en) * | 2004-04-29 | 2007-08-23 | Honeywell International Inc. | Method for producing fluorinated organic compounds |
| CN101597209A (zh) * | 2008-03-20 | 2009-12-09 | 霍尼韦尔国际公司 | 用于制备2,3,3,3-四氟丙烯的一体式方法 |
| CN101665403A (zh) * | 2008-08-08 | 2010-03-10 | 霍尼韦尔国际公司 | 生产2-氯-1,1,1,2-四氟丙烷(HCFC-244bb)的改进方法 |
Also Published As
| Publication number | Publication date |
|---|---|
| US20120184785A1 (en) | 2012-07-19 |
| JP5953317B2 (ja) | 2016-07-20 |
| JP2014510716A (ja) | 2014-05-01 |
| KR101925339B1 (ko) | 2019-02-27 |
| CN103534228A (zh) | 2014-01-22 |
| EP2665696B1 (en) | 2018-03-14 |
| MX2013008287A (es) | 2013-09-13 |
| US9890096B2 (en) | 2018-02-13 |
| EP2665696A1 (en) | 2013-11-27 |
| WO2012099776A1 (en) | 2012-07-26 |
| KR20140004725A (ko) | 2014-01-13 |
| ES2666489T3 (es) | 2018-05-04 |
| EP2665696A4 (en) | 2015-12-23 |
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Legal Events
| Date | Code | Title | Description |
|---|---|---|---|
| PB01 | Publication | ||
| PB01 | Publication | ||
| SE01 | Entry into force of request for substantive examination | ||
| SE01 | Entry into force of request for substantive examination | ||
| WD01 | Invention patent application deemed withdrawn after publication |
Application publication date: 20180803 |
|
| WD01 | Invention patent application deemed withdrawn after publication |