MX2013008287A - Metodos para producir 2,3,3,3-tetrafluoro-2-propeno. - Google Patents
Metodos para producir 2,3,3,3-tetrafluoro-2-propeno.Info
- Publication number
- MX2013008287A MX2013008287A MX2013008287A MX2013008287A MX2013008287A MX 2013008287 A MX2013008287 A MX 2013008287A MX 2013008287 A MX2013008287 A MX 2013008287A MX 2013008287 A MX2013008287 A MX 2013008287A MX 2013008287 A MX2013008287 A MX 2013008287A
- Authority
- MX
- Mexico
- Prior art keywords
- hydrofluorination
- tcp
- reactor
- vapor phase
- liquid phase
- Prior art date
Links
- 238000000034 method Methods 0.000 title claims abstract description 52
- 239000007791 liquid phase Substances 0.000 claims abstract description 40
- 239000012808 vapor phase Substances 0.000 claims abstract description 31
- 238000007033 dehydrochlorination reaction Methods 0.000 claims abstract description 22
- XLYOFNOQVPJJNP-UHFFFAOYSA-N water Substances O XLYOFNOQVPJJNP-UHFFFAOYSA-N 0.000 claims abstract description 16
- UMGQVBVEWTXECF-UHFFFAOYSA-N 1,1,2,3-tetrachloroprop-1-ene Chemical compound ClCC(Cl)=C(Cl)Cl UMGQVBVEWTXECF-UHFFFAOYSA-N 0.000 claims abstract description 9
- 238000004519 manufacturing process Methods 0.000 claims abstract description 9
- 239000007788 liquid Substances 0.000 claims abstract description 8
- 238000012545 processing Methods 0.000 claims abstract description 7
- 239000003518 caustics Substances 0.000 claims abstract description 4
- 239000003054 catalyst Substances 0.000 claims description 38
- 238000006243 chemical reaction Methods 0.000 claims description 28
- QAOWNCQODCNURD-UHFFFAOYSA-N Sulfuric acid Chemical compound OS(O)(=O)=O QAOWNCQODCNURD-UHFFFAOYSA-N 0.000 claims description 18
- PNEYBMLMFCGWSK-UHFFFAOYSA-N aluminium oxide Inorganic materials [O-2].[O-2].[O-2].[Al+3].[Al+3] PNEYBMLMFCGWSK-UHFFFAOYSA-N 0.000 claims description 17
- 239000000203 mixture Substances 0.000 claims description 17
- 229910052593 corundum Inorganic materials 0.000 claims description 13
- 239000000243 solution Substances 0.000 claims description 13
- 229910001845 yogo sapphire Inorganic materials 0.000 claims description 13
- 238000001035 drying Methods 0.000 claims description 11
- OSGAYBCDTDRGGQ-UHFFFAOYSA-L calcium sulfate Chemical compound [Ca+2].[O-]S([O-])(=O)=O OSGAYBCDTDRGGQ-UHFFFAOYSA-L 0.000 claims description 9
- 238000001816 cooling Methods 0.000 claims description 7
- 238000000926 separation method Methods 0.000 claims description 7
- VYPSYNLAJGMNEJ-UHFFFAOYSA-N Silicium dioxide Chemical compound O=[Si]=O VYPSYNLAJGMNEJ-UHFFFAOYSA-N 0.000 claims description 6
- 239000000741 silica gel Substances 0.000 claims description 6
- 229910002027 silica gel Inorganic materials 0.000 claims description 6
- -1 Sb / C Inorganic materials 0.000 claims description 5
- 238000011049 filling Methods 0.000 claims description 5
- UXVMQQNJUSDDNG-UHFFFAOYSA-L Calcium chloride Chemical compound [Cl-].[Cl-].[Ca+2] UXVMQQNJUSDDNG-UHFFFAOYSA-L 0.000 claims description 4
- OKTJSMMVPCPJKN-UHFFFAOYSA-N Carbon Chemical compound [C] OKTJSMMVPCPJKN-UHFFFAOYSA-N 0.000 claims description 4
- 229910021578 Iron(III) chloride Inorganic materials 0.000 claims description 4
- 239000001110 calcium chloride Substances 0.000 claims description 4
- 229910001628 calcium chloride Inorganic materials 0.000 claims description 4
- 229910052799 carbon Inorganic materials 0.000 claims description 4
- RBTARNINKXHZNM-UHFFFAOYSA-K iron trichloride Chemical compound Cl[Fe](Cl)Cl RBTARNINKXHZNM-UHFFFAOYSA-K 0.000 claims description 4
- 239000002808 molecular sieve Substances 0.000 claims description 4
- URGAHOPLAPQHLN-UHFFFAOYSA-N sodium aluminosilicate Chemical compound [Na+].[Al+3].[O-][Si]([O-])=O.[O-][Si]([O-])=O URGAHOPLAPQHLN-UHFFFAOYSA-N 0.000 claims description 4
- 229910021586 Nickel(II) chloride Inorganic materials 0.000 claims description 3
- 229910021627 Tin(IV) chloride Inorganic materials 0.000 claims description 3
- FAPDDOBMIUGHIN-UHFFFAOYSA-K antimony trichloride Chemical compound Cl[Sb](Cl)Cl FAPDDOBMIUGHIN-UHFFFAOYSA-K 0.000 claims description 3
- QMMRZOWCJAIUJA-UHFFFAOYSA-L nickel dichloride Chemical compound Cl[Ni]Cl QMMRZOWCJAIUJA-UHFFFAOYSA-L 0.000 claims description 3
- HPGGPRDJHPYFRM-UHFFFAOYSA-J tin(iv) chloride Chemical compound Cl[Sn](Cl)(Cl)Cl HPGGPRDJHPYFRM-UHFFFAOYSA-J 0.000 claims description 3
- 229910003074 TiCl4 Inorganic materials 0.000 claims description 2
- 239000013067 intermediate product Substances 0.000 claims description 2
- 238000010791 quenching Methods 0.000 claims description 2
- XJDNKRIXUMDJCW-UHFFFAOYSA-J titanium tetrachloride Chemical compound Cl[Ti](Cl)(Cl)Cl XJDNKRIXUMDJCW-UHFFFAOYSA-J 0.000 claims description 2
- GVVUPGXFVJLPDE-OWOJBTEDSA-N (e)-1,3,3,3-tetrachloroprop-1-ene Chemical compound Cl\C=C\C(Cl)(Cl)Cl GVVUPGXFVJLPDE-OWOJBTEDSA-N 0.000 claims 11
- 239000003929 acidic solution Substances 0.000 claims 2
- 229910021581 Cobalt(III) chloride Inorganic materials 0.000 claims 1
- 239000002253 acid Substances 0.000 abstract description 2
- HEMHJVSKTPXQMS-UHFFFAOYSA-M Sodium hydroxide Chemical compound [OH-].[Na+] HEMHJVSKTPXQMS-UHFFFAOYSA-M 0.000 description 15
- 239000000047 product Substances 0.000 description 10
- 238000004821 distillation Methods 0.000 description 9
- 238000011084 recovery Methods 0.000 description 9
- 239000002274 desiccant Substances 0.000 description 7
- 238000003682 fluorination reaction Methods 0.000 description 7
- 239000000543 intermediate Substances 0.000 description 6
- 238000010926 purge Methods 0.000 description 6
- 238000010521 absorption reaction Methods 0.000 description 5
- 235000011121 sodium hydroxide Nutrition 0.000 description 5
- 229910021580 Cobalt(II) chloride Inorganic materials 0.000 description 4
- 239000000463 material Substances 0.000 description 4
- 238000005191 phase separation Methods 0.000 description 4
- KLZUFWVZNOTSEM-UHFFFAOYSA-K Aluminium flouride Chemical compound F[Al](F)F KLZUFWVZNOTSEM-UHFFFAOYSA-K 0.000 description 3
- 101100004392 Arabidopsis thaliana BHLH147 gene Proteins 0.000 description 3
- 235000011148 calcium chloride Nutrition 0.000 description 3
- NBVXSUQYWXRMNV-UHFFFAOYSA-N fluoromethane Chemical compound FC NBVXSUQYWXRMNV-UHFFFAOYSA-N 0.000 description 3
- 239000010410 layer Substances 0.000 description 3
- 239000012044 organic layer Substances 0.000 description 3
- 238000012856 packing Methods 0.000 description 3
- DMUPYMORYHFFCT-UPHRSURJSA-N (z)-1,2,3,3,3-pentafluoroprop-1-ene Chemical compound F\C=C(/F)C(F)(F)F DMUPYMORYHFFCT-UPHRSURJSA-N 0.000 description 2
- FYIRUPZTYPILDH-UHFFFAOYSA-N 1,1,1,2,3,3-hexafluoropropane Chemical compound FC(F)C(F)C(F)(F)F FYIRUPZTYPILDH-UHFFFAOYSA-N 0.000 description 2
- UFHFLCQGNIYNRP-UHFFFAOYSA-N Hydrogen Chemical compound [H][H] UFHFLCQGNIYNRP-UHFFFAOYSA-N 0.000 description 2
- VMPVEPPRYRXYNP-UHFFFAOYSA-I antimony(5+);pentachloride Chemical compound Cl[Sb](Cl)(Cl)(Cl)Cl VMPVEPPRYRXYNP-UHFFFAOYSA-I 0.000 description 2
- 230000015572 biosynthetic process Effects 0.000 description 2
- 239000006227 byproduct Substances 0.000 description 2
- 150000001875 compounds Chemical class 0.000 description 2
- 239000007789 gas Substances 0.000 description 2
- HCDGVLDPFQMKDK-UHFFFAOYSA-N hexafluoropropylene Chemical compound FC(F)=C(F)C(F)(F)F HCDGVLDPFQMKDK-UHFFFAOYSA-N 0.000 description 2
- 229910052739 hydrogen Inorganic materials 0.000 description 2
- 239000001257 hydrogen Substances 0.000 description 2
- 238000005984 hydrogenation reaction Methods 0.000 description 2
- 238000002955 isolation Methods 0.000 description 2
- 239000000178 monomer Substances 0.000 description 2
- 238000002360 preparation method Methods 0.000 description 2
- 238000000746 purification Methods 0.000 description 2
- 239000000376 reactant Substances 0.000 description 2
- 230000003134 recirculating effect Effects 0.000 description 2
- 238000004064 recycling Methods 0.000 description 2
- 239000003507 refrigerant Substances 0.000 description 2
- 239000000126 substance Substances 0.000 description 2
- 235000011149 sulphuric acid Nutrition 0.000 description 2
- 238000010792 warming Methods 0.000 description 2
- 238000005406 washing Methods 0.000 description 2
- ZDCWZRQSHBQRGN-UHFFFAOYSA-N 1,1,1,2,3-pentafluoropropane Chemical compound FCC(F)C(F)(F)F ZDCWZRQSHBQRGN-UHFFFAOYSA-N 0.000 description 1
- LVGUZGTVOIAKKC-UHFFFAOYSA-N 1,1,1,2-tetrafluoroethane Chemical compound FCC(F)(F)F LVGUZGTVOIAKKC-UHFFFAOYSA-N 0.000 description 1
- SMCNZLDHTZESTK-UHFFFAOYSA-N 2-chloro-1,1,1,2-tetrafluoropropane Chemical compound CC(F)(Cl)C(F)(F)F SMCNZLDHTZESTK-UHFFFAOYSA-N 0.000 description 1
- 229910016569 AlF 3 Inorganic materials 0.000 description 1
- CBENFWSGALASAD-UHFFFAOYSA-N Ozone Chemical compound [O-][O+]=O CBENFWSGALASAD-UHFFFAOYSA-N 0.000 description 1
- 150000001336 alkenes Chemical class 0.000 description 1
- 229910052925 anhydrite Inorganic materials 0.000 description 1
- 238000013459 approach Methods 0.000 description 1
- 239000007864 aqueous solution Substances 0.000 description 1
- 238000010533 azeotropic distillation Methods 0.000 description 1
- 238000007664 blowing Methods 0.000 description 1
- 239000007795 chemical reaction product Substances 0.000 description 1
- 239000003153 chemical reaction reagent Substances 0.000 description 1
- 239000003245 coal Substances 0.000 description 1
- 238000007906 compression Methods 0.000 description 1
- 230000006835 compression Effects 0.000 description 1
- 238000005260 corrosion Methods 0.000 description 1
- 230000007797 corrosion Effects 0.000 description 1
- 230000007423 decrease Effects 0.000 description 1
- 238000013461 design Methods 0.000 description 1
- 238000010586 diagram Methods 0.000 description 1
- 238000010981 drying operation Methods 0.000 description 1
- 239000006260 foam Substances 0.000 description 1
- 239000013461 intermediate chemical Substances 0.000 description 1
- 238000002156 mixing Methods 0.000 description 1
- 238000012986 modification Methods 0.000 description 1
- 230000004048 modification Effects 0.000 description 1
- 239000005416 organic matter Substances 0.000 description 1
- 230000000704 physical effect Effects 0.000 description 1
- 230000002265 prevention Effects 0.000 description 1
- 238000005057 refrigeration Methods 0.000 description 1
- 238000004088 simulation Methods 0.000 description 1
- 238000009834 vaporization Methods 0.000 description 1
- 230000008016 vaporization Effects 0.000 description 1
Classifications
-
- C—CHEMISTRY; METALLURGY
- C07—ORGANIC CHEMISTRY
- C07C—ACYCLIC OR CARBOCYCLIC COMPOUNDS
- C07C17/00—Preparation of halogenated hydrocarbons
- C07C17/093—Preparation of halogenated hydrocarbons by replacement by halogens
- C07C17/20—Preparation of halogenated hydrocarbons by replacement by halogens of halogen atoms by other halogen atoms
- C07C17/21—Preparation of halogenated hydrocarbons by replacement by halogens of halogen atoms by other halogen atoms with simultaneous increase of the number of halogen atoms
-
- C—CHEMISTRY; METALLURGY
- C07—ORGANIC CHEMISTRY
- C07C—ACYCLIC OR CARBOCYCLIC COMPOUNDS
- C07C17/00—Preparation of halogenated hydrocarbons
- C07C17/25—Preparation of halogenated hydrocarbons by splitting-off hydrogen halides from halogenated hydrocarbons
-
- B—PERFORMING OPERATIONS; TRANSPORTING
- B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
- B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
- B01J23/00—Catalysts comprising metals or metal oxides or hydroxides, not provided for in group B01J21/00
- B01J23/16—Catalysts comprising metals or metal oxides or hydroxides, not provided for in group B01J21/00 of arsenic, antimony, bismuth, vanadium, niobium, tantalum, polonium, chromium, molybdenum, tungsten, manganese, technetium or rhenium
- B01J23/18—Arsenic, antimony or bismuth
-
- C—CHEMISTRY; METALLURGY
- C07—ORGANIC CHEMISTRY
- C07C—ACYCLIC OR CARBOCYCLIC COMPOUNDS
- C07C17/00—Preparation of halogenated hydrocarbons
- C07C17/07—Preparation of halogenated hydrocarbons by addition of hydrogen halides
- C07C17/087—Preparation of halogenated hydrocarbons by addition of hydrogen halides to unsaturated halogenated hydrocarbons
-
- C—CHEMISTRY; METALLURGY
- C07—ORGANIC CHEMISTRY
- C07C—ACYCLIC OR CARBOCYCLIC COMPOUNDS
- C07C17/00—Preparation of halogenated hydrocarbons
- C07C17/093—Preparation of halogenated hydrocarbons by replacement by halogens
- C07C17/20—Preparation of halogenated hydrocarbons by replacement by halogens of halogen atoms by other halogen atoms
- C07C17/202—Preparation of halogenated hydrocarbons by replacement by halogens of halogen atoms by other halogen atoms two or more compounds being involved in the reaction
- C07C17/206—Preparation of halogenated hydrocarbons by replacement by halogens of halogen atoms by other halogen atoms two or more compounds being involved in the reaction the other compound being HX
-
- C—CHEMISTRY; METALLURGY
- C07—ORGANIC CHEMISTRY
- C07C—ACYCLIC OR CARBOCYCLIC COMPOUNDS
- C07C17/00—Preparation of halogenated hydrocarbons
- C07C17/38—Separation; Purification; Stabilisation; Use of additives
-
- C—CHEMISTRY; METALLURGY
- C07—ORGANIC CHEMISTRY
- C07C—ACYCLIC OR CARBOCYCLIC COMPOUNDS
- C07C17/00—Preparation of halogenated hydrocarbons
- C07C17/38—Separation; Purification; Stabilisation; Use of additives
- C07C17/383—Separation; Purification; Stabilisation; Use of additives by distillation
-
- C—CHEMISTRY; METALLURGY
- C07—ORGANIC CHEMISTRY
- C07C—ACYCLIC OR CARBOCYCLIC COMPOUNDS
- C07C21/00—Acyclic unsaturated compounds containing halogen atoms
- C07C21/02—Acyclic unsaturated compounds containing halogen atoms containing carbon-to-carbon double bonds
- C07C21/18—Acyclic unsaturated compounds containing halogen atoms containing carbon-to-carbon double bonds containing fluorine
Landscapes
- Chemical & Material Sciences (AREA)
- Organic Chemistry (AREA)
- Chemical Kinetics & Catalysis (AREA)
- Engineering & Computer Science (AREA)
- Materials Engineering (AREA)
- Organic Low-Molecular-Weight Compounds And Preparation Thereof (AREA)
Applications Claiming Priority (3)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| US201161434005P | 2011-01-19 | 2011-01-19 | |
| US13/313,649 US9890096B2 (en) | 2011-01-19 | 2011-12-07 | Methods of making 2,3,3,3-tetrafluoro-2-propene |
| PCT/US2012/021158 WO2012099776A1 (en) | 2011-01-19 | 2012-01-13 | Methods of making 2,3,3,3-tetrafluoro-2-propene |
Publications (1)
| Publication Number | Publication Date |
|---|---|
| MX2013008287A true MX2013008287A (es) | 2013-09-13 |
Family
ID=46491269
Family Applications (1)
| Application Number | Title | Priority Date | Filing Date |
|---|---|---|---|
| MX2013008287A MX2013008287A (es) | 2011-01-19 | 2012-01-13 | Metodos para producir 2,3,3,3-tetrafluoro-2-propeno. |
Country Status (8)
| Country | Link |
|---|---|
| US (1) | US9890096B2 (https=) |
| EP (1) | EP2665696B1 (https=) |
| JP (1) | JP5953317B2 (https=) |
| KR (1) | KR101925339B1 (https=) |
| CN (2) | CN108358745A (https=) |
| ES (1) | ES2666489T3 (https=) |
| MX (1) | MX2013008287A (https=) |
| WO (1) | WO2012099776A1 (https=) |
Families Citing this family (25)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| US8927791B2 (en) * | 2010-04-29 | 2015-01-06 | Honeywell International Inc. | Method for producing tetrafluoropropenes |
| MX2014002893A (es) * | 2011-09-15 | 2014-04-30 | Daikin Ind Ltd | Metodo para purificar hidrocarburos clorados. |
| EP2970057B1 (en) | 2013-03-12 | 2018-11-07 | Honeywell International Inc. | A method for mitigating hfc-245cb formation during hcfo-1233xf hydrofluorination to hcfc-244bb |
| EP2970060A4 (en) * | 2013-03-13 | 2016-10-26 | Honeywell Int Inc | STEP-BY-STEP FLUORING METHOD AND REACTOR SYSTEM |
| US9272968B2 (en) | 2013-03-14 | 2016-03-01 | Honeywell International Inc. | Process to suppress the formation of 3,3,3-trifluoropropyne in fluorocarbon manufacture |
| US9353029B2 (en) | 2013-03-14 | 2016-05-31 | Honeywell International, Inc. | Fluorination process and reactor |
| US20140275651A1 (en) * | 2013-03-15 | 2014-09-18 | Honeywell International Inc. | Process for producing 2,3,3,3-tetrafluoropropene |
| WO2014172592A1 (en) * | 2013-04-18 | 2014-10-23 | Honeywell International Inc. | Reaction system and process to produce fluorinated organics |
| US20150225315A1 (en) * | 2014-02-10 | 2015-08-13 | Honeywell International Inc. | Reactor design for liquid phase fluorination |
| MX370708B (es) * | 2014-02-10 | 2019-12-20 | Honeywell Int Inc | Reactor para reacciones de fluoración en fase líquida. |
| WO2016051900A1 (ja) | 2014-09-30 | 2016-04-07 | ダイキン工業株式会社 | ２，３，３，３－テトラフルオロプロペンの製造方法 |
| JP6210073B2 (ja) * | 2015-01-21 | 2017-10-11 | ダイキン工業株式会社 | フルオロプロペンの製造方法 |
| CN107743479A (zh) * | 2015-04-24 | 2018-02-27 | 霍尼韦尔国际公司 | 降低244bb中的1233xf浓度的方法 |
| KR102847526B1 (ko) * | 2015-05-21 | 2025-08-20 | 더 케무어스 컴퍼니 에프씨, 엘엘씨 | SbF5에 의한 1233xf의 244bb로의 히드로플루오린화 |
| GB2540427B (en) * | 2015-07-17 | 2017-07-19 | Mexichem Fluor Sa De Cv | Process for the preparation of 2,3,3,3-tetrafluoropropene (1234yf) |
| GB201512510D0 (en) * | 2015-07-17 | 2015-08-19 | Mexichem Fluor Sa De Cv | Process |
| US9938213B2 (en) * | 2015-08-19 | 2018-04-10 | Honeywell International Inc. | Methods for removing acidic impurities from halogenated propenes |
| GB201701099D0 (en) * | 2017-01-23 | 2017-03-08 | Mexichem Fluor Sa De Cv | Process |
| KR101992230B1 (ko) | 2017-08-08 | 2019-06-25 | (주)후성 | 기상 촉매를 이용한 1,1,1-트리플루오로-2-클로로프로펜과 1,1,1,2-테트라플루오로프로펜의 동시 제조 방법 |
| US10233137B1 (en) | 2017-10-13 | 2019-03-19 | Honeywell International Inc. | Method for removing unsaturated halogenated impurities from 2,3,3,3-tetrafluoropropene (HFO-1234yf) |
| US10246389B1 (en) | 2018-01-08 | 2019-04-02 | Honeywell International Inc. | Compositions containing 2-chloro-1,1,1,2-tetrafluoropropane (HCFC-244bb) |
| US10351494B1 (en) | 2018-01-08 | 2019-07-16 | Honeywell International Inc. | Systems and methods for reducing the formation of impurities during 244bb dehydrochlorination to 1234yf |
| CN112313199A (zh) | 2018-06-06 | 2021-02-02 | 霍尼韦尔国际公司 | 用于HCFC-244bb的脱氯化氢以制备HFO-1234yf的方法 |
| US10941091B2 (en) | 2018-12-03 | 2021-03-09 | Honeywell International Inc. | Processes for producing high-purity trifluoroiodomethane |
| US20220080243A1 (en) * | 2020-09-11 | 2022-03-17 | Honeywell International Inc. | Azeotrope or azeotrope-like compositions of trifluoroiodomethane (cf3i) and water |
Family Cites Families (25)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| US5271918A (en) * | 1991-03-11 | 1993-12-21 | Alliedsignal Inc. | Furnace gas - sulfuric acid contact process for HF manufacture |
| CN1110449C (zh) * | 1995-10-10 | 2003-06-04 | 英尼奥斯费罗控股有限公司 | 分离和回收氟化氢的方法以及制备含氟有机化合物的方法 |
| US7880040B2 (en) * | 2004-04-29 | 2011-02-01 | Honeywell International Inc. | Method for producing fluorinated organic compounds |
| US8084653B2 (en) * | 2004-04-29 | 2011-12-27 | Honeywell International, Inc. | Method for producing fluorinated organic compounds |
| US8067649B2 (en) * | 2004-04-29 | 2011-11-29 | Honeywell International Inc. | Method for producing fluorinated organic compounds |
| US8058486B2 (en) * | 2004-04-29 | 2011-11-15 | Honeywell International Inc. | Integrated process to produce 2,3,3,3-tetrafluoropropene |
| US9102579B2 (en) * | 2004-04-29 | 2015-08-11 | Honeywell International Inc. | Method for producing fluorinated organic compounds |
| SI3336074T1 (sl) * | 2006-01-03 | 2025-09-30 | Honeywell International Inc. | Postopek za proizvodnjo fluoriranih organskih spojin |
| US8071825B2 (en) * | 2006-01-03 | 2011-12-06 | Honeywell International Inc. | Method for producing fluorinated organic compounds |
| US8664455B2 (en) * | 2008-08-08 | 2014-03-04 | Honeywell International Inc. | Process to manufacture 2-chloro-1,1,1,2-tetrafluoropropane (HCFC-244bb) |
| GB0611742D0 (en) * | 2006-06-14 | 2006-07-26 | Ineos Fluor Holdings Ltd | Desiccants for fluids |
| US8133406B2 (en) | 2006-10-31 | 2012-03-13 | E.I. Du Pont De Nemours And Company | Processes for producing 2,3,3,3-tetrafluoropropene and/or 1,2,3,3-tetrafluoropropene |
| GB0625214D0 (en) * | 2006-12-19 | 2007-01-24 | Ineos Fluor Holdings Ltd | Process |
| CN101597209A (zh) * | 2008-03-20 | 2009-12-09 | 霍尼韦尔国际公司 | 用于制备2,3,3,3-四氟丙烯的一体式方法 |
| GB0806389D0 (en) | 2008-04-09 | 2008-05-14 | Ineos Fluor Holdings Ltd | Process |
| GB0808836D0 (en) | 2008-05-15 | 2008-06-18 | Ineos Fluor Ltd | Process |
| US8916733B2 (en) * | 2008-06-17 | 2014-12-23 | Honeywell International Inc. | Processes for hydrofluorination of 2-chloro-3,3,3-trifluoropropene to 2-chloro-1,1,1,2-tetrafluoropropane |
| KR101610009B1 (ko) | 2008-06-26 | 2016-04-07 | 알케마 인코포레이티드 | 1230ｘａ에서 1234ｙｆ로의 촉매식 기체상 불소화 |
| FR2933402B1 (fr) | 2008-07-03 | 2010-07-30 | Arkema France | Procede de purification de 2,3,3,3-tetrafluoro-1-propene (hfo1234yf) |
| ES2365303T3 (es) * | 2008-08-08 | 2011-09-28 | Honeywell International Inc. | Proceso mejorado para fabricar 2-cloro-1,1,1,2-tetrafluoropropano (hcfc-244bb). |
| CA2743842C (en) * | 2008-11-19 | 2016-02-09 | Arkema Inc. | Process for the manufacture of hydrofluoroolefins |
| US8618340B2 (en) | 2009-11-03 | 2013-12-31 | Honeywell International Inc. | Integrated process for fluoro-olefin production |
| CN105062427A (zh) | 2009-12-22 | 2015-11-18 | 纳幕尔杜邦公司 | 包含2,3,3,3-四氟丙烯、1,1,2,3-四氯丙烯、2-氯-3,3,3-三氟丙烯、或2-氯-1,1,1,2-四氟丙烷的组合物 |
| WO2011077191A1 (en) | 2009-12-23 | 2011-06-30 | Arkema France | Catalytic gas phase fluorination of 1230xa to 1234yf |
| PL2545021T3 (pl) | 2010-03-10 | 2017-03-31 | Arkema France | Sposób fluorowania w fazie ciekłej |
-
2011
- 2011-12-07 US US13/313,649 patent/US9890096B2/en not_active Expired - Fee Related
-
2012
- 2012-01-13 CN CN201810257855.0A patent/CN108358745A/zh active Pending
- 2012-01-13 KR KR1020137021634A patent/KR101925339B1/ko not_active Expired - Fee Related
- 2012-01-13 MX MX2013008287A patent/MX2013008287A/es active IP Right Grant
- 2012-01-13 EP EP12737145.8A patent/EP2665696B1/en not_active Not-in-force
- 2012-01-13 ES ES12737145.8T patent/ES2666489T3/es active Active
- 2012-01-13 CN CN201280005395.3A patent/CN103534228A/zh active Pending
- 2012-01-13 JP JP2013550503A patent/JP5953317B2/ja not_active Expired - Fee Related
- 2012-01-13 WO PCT/US2012/021158 patent/WO2012099776A1/en not_active Ceased
Also Published As
| Publication number | Publication date |
|---|---|
| US20120184785A1 (en) | 2012-07-19 |
| JP5953317B2 (ja) | 2016-07-20 |
| JP2014510716A (ja) | 2014-05-01 |
| CN108358745A (zh) | 2018-08-03 |
| KR101925339B1 (ko) | 2019-02-27 |
| CN103534228A (zh) | 2014-01-22 |
| EP2665696B1 (en) | 2018-03-14 |
| US9890096B2 (en) | 2018-02-13 |
| EP2665696A1 (en) | 2013-11-27 |
| WO2012099776A1 (en) | 2012-07-26 |
| KR20140004725A (ko) | 2014-01-13 |
| ES2666489T3 (es) | 2018-05-04 |
| EP2665696A4 (en) | 2015-12-23 |
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