CN108300036A - A kind of farm implement aqueous dip-coating baking vanish and preparation method thereof - Google Patents

A kind of farm implement aqueous dip-coating baking vanish and preparation method thereof Download PDF

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Publication number
CN108300036A
CN108300036A CN201710757857.1A CN201710757857A CN108300036A CN 108300036 A CN108300036 A CN 108300036A CN 201710757857 A CN201710757857 A CN 201710757857A CN 108300036 A CN108300036 A CN 108300036A
Authority
CN
China
Prior art keywords
farm implement
baking vanish
coating baking
dip
aqueous dip
Prior art date
Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
Pending
Application number
CN201710757857.1A
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Chinese (zh)
Inventor
赵娟
祁艳东
邵光清
张海伟
Current Assignee (The listed assignees may be inaccurate. Google has not performed a legal analysis and makes no representation or warranty as to the accuracy of the list.)
Hebei Chenyang Industry and Trade Group Co Ltd
Original Assignee
Hebei Chenyang Industry and Trade Group Co Ltd
Priority date (The priority date is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the date listed.)
Filing date
Publication date
Application filed by Hebei Chenyang Industry and Trade Group Co Ltd filed Critical Hebei Chenyang Industry and Trade Group Co Ltd
Priority to CN201710757857.1A priority Critical patent/CN108300036A/en
Publication of CN108300036A publication Critical patent/CN108300036A/en
Pending legal-status Critical Current

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Classifications

    • CCHEMISTRY; METALLURGY
    • C09DYES; PAINTS; POLISHES; NATURAL RESINS; ADHESIVES; COMPOSITIONS NOT OTHERWISE PROVIDED FOR; APPLICATIONS OF MATERIALS NOT OTHERWISE PROVIDED FOR
    • C09DCOATING COMPOSITIONS, e.g. PAINTS, VARNISHES OR LACQUERS; FILLING PASTES; CHEMICAL PAINT OR INK REMOVERS; INKS; CORRECTING FLUIDS; WOODSTAINS; PASTES OR SOLIDS FOR COLOURING OR PRINTING; USE OF MATERIALS THEREFOR
    • C09D133/00Coating compositions based on homopolymers or copolymers of compounds having one or more unsaturated aliphatic radicals, each having only one carbon-to-carbon double bond, and at least one being terminated by only one carboxyl radical, or of salts, anhydrides, esters, amides, imides, or nitriles thereof; Coating compositions based on derivatives of such polymers
    • CCHEMISTRY; METALLURGY
    • C09DYES; PAINTS; POLISHES; NATURAL RESINS; ADHESIVES; COMPOSITIONS NOT OTHERWISE PROVIDED FOR; APPLICATIONS OF MATERIALS NOT OTHERWISE PROVIDED FOR
    • C09DCOATING COMPOSITIONS, e.g. PAINTS, VARNISHES OR LACQUERS; FILLING PASTES; CHEMICAL PAINT OR INK REMOVERS; INKS; CORRECTING FLUIDS; WOODSTAINS; PASTES OR SOLIDS FOR COLOURING OR PRINTING; USE OF MATERIALS THEREFOR
    • C09D133/00Coating compositions based on homopolymers or copolymers of compounds having one or more unsaturated aliphatic radicals, each having only one carbon-to-carbon double bond, and at least one being terminated by only one carboxyl radical, or of salts, anhydrides, esters, amides, imides, or nitriles thereof; Coating compositions based on derivatives of such polymers
    • C09D133/04Homopolymers or copolymers of esters
    • CCHEMISTRY; METALLURGY
    • C09DYES; PAINTS; POLISHES; NATURAL RESINS; ADHESIVES; COMPOSITIONS NOT OTHERWISE PROVIDED FOR; APPLICATIONS OF MATERIALS NOT OTHERWISE PROVIDED FOR
    • C09DCOATING COMPOSITIONS, e.g. PAINTS, VARNISHES OR LACQUERS; FILLING PASTES; CHEMICAL PAINT OR INK REMOVERS; INKS; CORRECTING FLUIDS; WOODSTAINS; PASTES OR SOLIDS FOR COLOURING OR PRINTING; USE OF MATERIALS THEREFOR
    • C09D5/00Coating compositions, e.g. paints, varnishes or lacquers, characterised by their physical nature or the effects produced; Filling pastes
    • C09D5/08Anti-corrosive paints
    • CCHEMISTRY; METALLURGY
    • C08ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08LCOMPOSITIONS OF MACROMOLECULAR COMPOUNDS
    • C08L2201/00Properties
    • C08L2201/08Stabilised against heat, light or radiation or oxydation
    • CCHEMISTRY; METALLURGY
    • C08ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08LCOMPOSITIONS OF MACROMOLECULAR COMPOUNDS
    • C08L2205/00Polymer mixtures characterised by other features
    • C08L2205/03Polymer mixtures characterised by other features containing three or more polymers in a blend
    • C08L2205/035Polymer mixtures characterised by other features containing three or more polymers in a blend containing four or more polymers in a blend
    • CCHEMISTRY; METALLURGY
    • C08ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08LCOMPOSITIONS OF MACROMOLECULAR COMPOUNDS
    • C08L2312/00Crosslinking

Abstract

The present invention relates to technical field of coatings, specifically disclose a kind of farm implement aqueous dip-coating baking vanish and preparation method thereof.The aqueous dip-coating baking vanish of the farm implement, including the following raw material component by mass percentage:Water-based acrylic resin 35% 45%;Amino resins 6% 8.5%;PH adjusting agent 1.5% 2.5%;Cosolvent 18% 27%;Antifoaming agent 0.2% 0.4%;Wetting agent 0.3% 0.6%;Levelling agent 0.2% 0.4%;Deionized water 15.6% 38.8%.The aqueous dip-coating baking vanish of farm implement provided by the invention, hardness of film is high, and film is uniform, and richness is good;Without dip-coating edge foaming phenomena;With excellent salt fog resistance, artificial ageing resistance, the performances such as wearability.

Description

A kind of farm implement aqueous dip-coating baking vanish and preparation method thereof
Technical field
The present invention relates to technical field of coatings more particularly to a kind of farm implement aqueous dip-coating baking vanish and its preparation sides Method.
Background technology
With the continuous improvement of level of farming mechanization, peasant reduces the demand of farm implement year by year, but much Square farm implement is still using, and especially can not achieve the region of mechanization, existing major part farm implement is all carbon steel material Matter, it is cheap, but easily get rusty, to solve farm implement problem of rustiness, its one coating of face cap is just given, protection is formed Layer, prevents from getting rusty.Farm implement is special-shaped mostly, is easy construction, is typically chosen dip application, and need will be by for dip application Phenomena such as object hanging removes overbrushing coating, be easy to cause film upper-thin-lower-thick, workpiece lower edge sagging to drip is applied, this phenomenon exists Lower edge is susceptible to the disadvantages such as bubble when baking.
Invention content
Uneven for film of the existing technology, easily there is the problems such as sagging and bubble in coated article part lower edge, this Invention provides a kind of farm implement aqueous dip-coating baking vanish and preparation method thereof.
To achieve the above object of the invention, the embodiment of the present invention uses the following technical solution:
A kind of aqueous dip-coating baking vanish of farm implement, including the following raw material component by mass percentage:
Compared with the existing technology, farm implement provided by the invention makes painting with aqueous dip-coating baking vanish, water-based acrylic resin Film hardness is high, and film is uniform, and richness is good;The addition of antifoaming agent and cosolvent controls the dry speed of microvesicle and paint film in coating Degree solves dip-coating edge bubble problem;Amino resins and acrylic resin crosslinked action, make coating have suitable viscosity, avoid Sagging phenomenon, meanwhile, improve the salt fog resistance of paint film, artificial ageing resistance, the performances such as wearability.
Further, the present invention also provides the farm implement preparation methods of aqueous dip-coating baking vanish.The preparation side Method at least includes the following steps:
(1) water-based acrylic resin and pH adjusting agent, cosolvent, antifoaming agent, wetting agent are subjected to mixing treatment, are mixed Close material;
(2) mixed material and amino resins, levelling agent, deionized water are subjected to mixing treatment, obtain farm implement With aqueous dip-coating baking vanish.
Compared with the existing technology, the preparation method of the aqueous dip-coating baking vanish of farm implement provided by the invention, it is simple for process, It is easy to operate, it is securely and reliably, environmentally protective.
Specific implementation mode
In order to make the purpose , technical scheme and advantage of the present invention be clearer, with reference to embodiments, to the present invention It is further elaborated.It should be appreciated that the specific embodiments described herein are merely illustrative of the present invention, it is not used to Limit the present invention.
A kind of offer aqueous dip-coating baking vanish of farm implement of the embodiment of the present invention, the aqueous dip-coating baking vanish of the farm implement, Including the following raw material component by mass percentage:
Preferably, water-based acrylic resin be using acrylate as main monomer, by polymerisation in solution formed with diformazan Benzene and the single-phase uniform newton-type acrylic resin that butyl acetate is main solvent, are used cooperatively with amino resins, make coating With suitable viscosity, i.e., 25 ± 1 DEG C, -4 glasss of viscosity are applied to 25-30s, avoid sagging phenomenon, and improve the hardness of paint film and rich Full scale.
It is further preferred that water-based acrylic resin is the BS-962 of Jiangsu Miki Group.
Preferably, amino resins is made of methanol, formaldehyde, melamine, and preferred amino resins is handed over acrylic resin Connection can improve the performances such as the hardness of paint film, saline-alkali tolerant, weather-proof, wear-resistant.
It is further preferred that amino resins is selected from the 5717W of Jiangsu Miki Group.
Preferably, cosolvent is the mixture of butyl glycol ether and butyl, utilizes butyl glycol ether and diethyl The boiling point of glycol butyl ether is different, and volatility is different, controls the rate of drying of paint film to solve dip-coating edge bubble problem, obtains The aqueous dip-coating baking vanish of the farm implement haveing excellent performance.
It is further preferred that the mass ratio of butyl glycol ether and butyl is 1:1.1-1.4.
Preferably, antifoaming agent is organic silicon defoamer, has excellent brokenly bubble effect, and extremely effective to microvesicle, is eliminated Microvesicle in coating.
It is further preferred that antifoaming agent is the BYK-024 antifoaming agent of Bi Ke, main component is the hydrophobic in polyethylene glycol Solid and brokenly bubble polysiloxane mixture.
Preferably, wetting agent is hyperbranched polyether wetting agent, not only has wetting effect, while having suds and levelling effect Fruit improves coating property.
It is further preferred that wetting agent is the WE3322 of BASF
Preferably, levelling agent is polyurethane levelling agent, is suitable for newton-type, improves the rheological property of coating, make film more Add uniformly.
It is further preferred that levelling agent is the Coapur2025 of Gao Tai.
The aqueous dip-coating baking vanish of farm implement provided in an embodiment of the present invention, water-based acrylic resin keep hardness of film high, Film is uniform, and richness is good;The addition of antifoaming agent and cosolvent controls the rate of drying of microvesicle and paint film in coating and solves dip-coating Edge bubble problem;Amino resins and acrylic resin crosslinked action, make coating have suitable viscosity, avoid sagging phenomenon, And the salt fog resistance of paint film is improved, artificial ageing resistance, the performances such as wearability, application property is good, can be applied to spade, hoe, nail Rake, reaping hook etc. are easy to the farm implement to get rusty.
The present invention still further provides the farm implement under the premise of providing the farm implement aqueous dip-coating baking vanish With the preparation method of aqueous dip-coating baking vanish.
In one embodiment, which at least includes the following steps:
(1) water-based acrylic resin and pH adjusting agent, cosolvent, antifoaming agent, wetting agent are subjected to mixing treatment, are mixed Close material;
(2) mixed material and amino resins, levelling agent, deionized water are subjected to mixing treatment, obtain farm implement With aqueous dip-coating baking vanish.
Explanation is further explained to above-mentioned preparation method below:
Preferably, in step (1), the mixing speed of mixing treatment is 700-800r/min, and time 3-5min makes material It is uniformly mixed, and prevents from stirring and too fast bring bubble into.
Preferably, in step (2), the mixing speed of mixing treatment is 900-1000r/min, and time 7-10min makes object Material stirs evenly, and obtains required viscosity, i.e., 25 ± 1 DEG C, applies -4 glasss of viscosity to 25-30s.
This method preparation process is simple, easy to operate, securely and reliably, environmentally protective.
In order to better illustrate farm implement provided in an embodiment of the present invention aqueous dip-coating baking vanish and preparation method thereof, under Face is illustrated by the way that embodiment is further.
Embodiment 1
A kind of aqueous dip-coating baking vanish of farm implement, including the following raw material component by mass percentage:
Farm implement is included the following steps with the preparation method of aqueous dip-coating baking vanish:
(1) water-based acrylic resin and pH adjusting agent, cosolvent, antifoaming agent, wetting agent are subjected to mixing treatment, with 800r/min stirs 3min, obtains mixed material;
(2) mixed material and amino resins, levelling agent, deionized water are subjected to mixing treatment, are stirred with 1000r/min 8min is mixed, obtains farm implement with aqueous dip-coating baking vanish.
Embodiment 2
A kind of aqueous dip-coating baking vanish of farm implement, including the following raw material component by mass percentage:
Farm implement is included the following steps with the preparation method of aqueous dip-coating baking vanish:
(1) water-based acrylic resin and pH adjusting agent, cosolvent, antifoaming agent, wetting agent are subjected to mixing treatment, with 700r/min stirs 5min, obtains mixed material;
(2) mixed material and amino resins, levelling agent, deionized water are subjected to mixing treatment, are stirred with 900r/min 10min is mixed, obtains farm implement with aqueous dip-coating baking vanish.
Embodiment 3
A kind of aqueous dip-coating baking vanish of farm implement, including the following raw material component by mass percentage:
Farm implement is included the following steps with the preparation method of aqueous dip-coating baking vanish:
(1) water-based acrylic resin and pH adjusting agent, cosolvent, antifoaming agent, wetting agent are subjected to mixing treatment, with 800r/min stirs 3min, obtains mixed material;
(2) mixed material and amino resins, levelling agent, deionized water are subjected to mixing treatment, are stirred with 1000r/min 7min is mixed, obtains farm implement with aqueous dip-coating baking vanish.
It, below will be real in order to better illustrate the farm implement provided in an embodiment of the present invention characteristic of aqueous dip-coating baking vanish The farm implement for applying the preparation of example 1,2,3 carries out corresponding performance detection with aqueous dip-coating baking vanish, and the results are shown in Table 1.
Table 1
It can be obtained, the aqueous dip-coating baking vanish of the farm implement that the embodiment of the present invention is provided, be had good by above-mentioned data The performances such as water resistance, salt fog resistance, artificial ageing resistance, impact resistance, rub resistance, while having hardness of paint film high, outside paint film The features such as sight richness is good, bubble-free.
The foregoing is merely illustrative of the preferred embodiments of the present invention, is not intended to limit the invention, all essences in the present invention Any modification, equivalent replacement or improvement etc., should all be included in the protection scope of the present invention made by within refreshing and principle.

Claims (7)

1. a kind of aqueous dip-coating baking vanish of farm implement, it is characterised in that:With the farm implement original of aqueous dip-coating baking vanish Expect that gross mass is 100% meter, includes the following raw materials according component of following mass percentage:
2. the aqueous dip-coating baking vanish of farm implement as described in claim 1, it is characterised in that:The cosolvent is ethylene glycol fourth The mixture of ether and butyl.
3. the aqueous dip-coating baking vanish of farm implement as claimed in claim 2, it is characterised in that:The butyl glycol ether and diethyl The mass ratio of glycol butyl ether is 1:1.1-1.4.
4. the aqueous dip-coating baking vanish of farm implement as described in claim 1, it is characterised in that:The antifoaming agent disappears for organosilicon Infusion.
5. the aqueous dip-coating baking vanish of farm implement as described in claim 1, it is characterised in that:The amino resins by methanol, Formaldehyde, melamine are made.
6. the farm implement as described in any one in claim 1-5 preparation method of aqueous dip-coating baking vanish, it is characterised in that:Extremely Include the following steps less:
(1) water-based acrylic resin and pH adjusting agent, cosolvent, antifoaming agent, wetting agent are subjected to mixing treatment, obtain mixture Material;
(2) mixed material and amino resins, levelling agent, deionized water are subjected to mixing treatment, obtain farm implement water Property dip-coating baking vanish.
7. the farm implement as claimed in claim 6 preparation method of aqueous dip-coating baking vanish, it is characterised in that:The step (1) in, the mixing speed of mixing treatment is 700-800r/min, time 3-5min;And/or
In the step (2), the mixing speed of mixing treatment is 900-1000r/min, time 7-10min.
CN201710757857.1A 2017-08-29 2017-08-29 A kind of farm implement aqueous dip-coating baking vanish and preparation method thereof Pending CN108300036A (en)

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CN201710757857.1A CN108300036A (en) 2017-08-29 2017-08-29 A kind of farm implement aqueous dip-coating baking vanish and preparation method thereof

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Application Number Priority Date Filing Date Title
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Cited By (1)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
CN110016264A (en) * 2019-04-28 2019-07-16 河北晨阳工贸集团有限公司 A kind of dip-coating water soluble acrylic acid amino-stoving varnish and preparation method thereof

Citations (4)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
CN104263145A (en) * 2014-08-29 2015-01-07 湖南新力华纳米科技有限公司 Water-based thermosetting glass winebottle stoving varnish and preparation method thereof
CN105085771A (en) * 2015-07-14 2015-11-25 阜阳师范学院 Waterborne acrylic resin and preparation method therefor
CN106243873A (en) * 2016-08-30 2016-12-21 河北晨阳工贸集团有限公司 A kind of aqueous tape measure dip-coating baking vanish and preparation method thereof
CN106366870A (en) * 2016-08-27 2017-02-01 四川颜鼎水性环保漆科技有限公司 Compound waterborne metallic baking paint and coating method thereof

Patent Citations (4)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
CN104263145A (en) * 2014-08-29 2015-01-07 湖南新力华纳米科技有限公司 Water-based thermosetting glass winebottle stoving varnish and preparation method thereof
CN105085771A (en) * 2015-07-14 2015-11-25 阜阳师范学院 Waterborne acrylic resin and preparation method therefor
CN106366870A (en) * 2016-08-27 2017-02-01 四川颜鼎水性环保漆科技有限公司 Compound waterborne metallic baking paint and coating method thereof
CN106243873A (en) * 2016-08-30 2016-12-21 河北晨阳工贸集团有限公司 A kind of aqueous tape measure dip-coating baking vanish and preparation method thereof

Cited By (1)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
CN110016264A (en) * 2019-04-28 2019-07-16 河北晨阳工贸集团有限公司 A kind of dip-coating water soluble acrylic acid amino-stoving varnish and preparation method thereof

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Application publication date: 20180720