CN108291102A - The water-based spinning transfer ink and Fabric transfer paper of ink-jet printer - Google Patents
The water-based spinning transfer ink and Fabric transfer paper of ink-jet printer Download PDFInfo
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- CN108291102A CN108291102A CN201680061405.3A CN201680061405A CN108291102A CN 108291102 A CN108291102 A CN 108291102A CN 201680061405 A CN201680061405 A CN 201680061405A CN 108291102 A CN108291102 A CN 108291102A
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- Prior art keywords
- ink
- disperse dyes
- water
- jet printer
- agent
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Classifications
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- C—CHEMISTRY; METALLURGY
- C09—DYES; PAINTS; POLISHES; NATURAL RESINS; ADHESIVES; COMPOSITIONS NOT OTHERWISE PROVIDED FOR; APPLICATIONS OF MATERIALS NOT OTHERWISE PROVIDED FOR
- C09D—COATING COMPOSITIONS, e.g. PAINTS, VARNISHES OR LACQUERS; FILLING PASTES; CHEMICAL PAINT OR INK REMOVERS; INKS; CORRECTING FLUIDS; WOODSTAINS; PASTES OR SOLIDS FOR COLOURING OR PRINTING; USE OF MATERIALS THEREFOR
- C09D11/00—Inks
- C09D11/02—Printing inks
- C09D11/03—Printing inks characterised by features other than the chemical nature of the binder
-
- C—CHEMISTRY; METALLURGY
- C09—DYES; PAINTS; POLISHES; NATURAL RESINS; ADHESIVES; COMPOSITIONS NOT OTHERWISE PROVIDED FOR; APPLICATIONS OF MATERIALS NOT OTHERWISE PROVIDED FOR
- C09D—COATING COMPOSITIONS, e.g. PAINTS, VARNISHES OR LACQUERS; FILLING PASTES; CHEMICAL PAINT OR INK REMOVERS; INKS; CORRECTING FLUIDS; WOODSTAINS; PASTES OR SOLIDS FOR COLOURING OR PRINTING; USE OF MATERIALS THEREFOR
- C09D11/00—Inks
- C09D11/02—Printing inks
- C09D11/03—Printing inks characterised by features other than the chemical nature of the binder
- C09D11/033—Printing inks characterised by features other than the chemical nature of the binder characterised by the solvent
-
- C—CHEMISTRY; METALLURGY
- C09—DYES; PAINTS; POLISHES; NATURAL RESINS; ADHESIVES; COMPOSITIONS NOT OTHERWISE PROVIDED FOR; APPLICATIONS OF MATERIALS NOT OTHERWISE PROVIDED FOR
- C09D—COATING COMPOSITIONS, e.g. PAINTS, VARNISHES OR LACQUERS; FILLING PASTES; CHEMICAL PAINT OR INK REMOVERS; INKS; CORRECTING FLUIDS; WOODSTAINS; PASTES OR SOLIDS FOR COLOURING OR PRINTING; USE OF MATERIALS THEREFOR
- C09D11/00—Inks
- C09D11/02—Printing inks
- C09D11/03—Printing inks characterised by features other than the chemical nature of the binder
- C09D11/037—Printing inks characterised by features other than the chemical nature of the binder characterised by the pigment
Abstract
The present invention relates to a kind of water-based spinnings of ink-jet printer to transfer ink, wherein including：20 40% disperse dyes adhesive；10 30% moisturizer；0.01 0.1% surface tension regulator；0.01 0.5% antifoaming agent；0.01 0.5% preservative and 2 8% colorant；Surplus is deionized water.The production method of the water-based spinning transfer ink of this ink-jet printer is to put the composition material of proper proportion to be ground to grain size 60nm 200nm into grinder；With deionized water hybrid resin and colorant；Mixture is stirred completely to homogeneous mixture.In addition, the invention further relates to a kind of thermal transfer Fabric transfer paper of water-based spinning material (such as fabric of nylon, cotton, blend polyester, synthetic resin, acrylic, polypropylene), it is characterized in that base sheet structure is the ink-jet printer Fabric transfer paper of 30gsm 100gsm, first coating on body paper is 3gsm 5gsm, second coating on first coating is 2gsm 10gsm, and there is the back coating of starch and water mixing at the body paper back side.
Description
Technical field
The present invention relates to one kind for textile materials such as nylon, cotton, blend polyester, synthetic resin, acrylic, polypropylene
Carry out the water-based spinning transfer ink of the ink-jet printer of aqueous transfer printing printing and a kind of Fabric transfer paper.More particularly to a kind of
Ink and Fabric transfer paper are transferred for the aquosity fabric of ink-jet printer, what it is when Fabric transfer paper is nylon, cotton, terylene on one side
When the fabrics such as blended, synthetic resin, acrylic, polypropylene, such Fabric transfer paper can be by heating such spray and pressing
The water-based spinning transfer ink of black printer is transferred to the back side of Fabric transfer paper.
Background technology
In general transfer method, transfer paper first with ink-jet printer or printing machine stamp it is aqueous can sublimation dye or
Oiliness can sublimation dye, then by the transfer surface of transfer paper against being mixed with the fabric of at least 20% terylene ingredient, and
The back side of transfer paper is pressed under conditions of about 200 degrees Celsius.
Later, it can be vaporized against the ink of the transfer surface of fabric because of heating and pressure, the texture of dacron also can
Become loose because of heating and pressure, therefore the dyestuff after vaporization can also pass through these loose notches.It is big when releasing stress
After about 60 seconds, the texture of dacron can be restored to loose preceding script state, and the particle of dyestuff can be stayed in the line of fabric
Among reason.Generally at this time can use can sublimation dye.
The greatest problem of such thermal transfer printing is that only dacron can just change the object of its fabric in transfer process
Rationality matter, and only in the fabric contain at least 20% terylene ingredient when heat transfer be likely to complete.Traditional ink and
Transfer paper, with nylon, (a kind of plain being blended with terylene and cotton, is mainly used for traditional Korea Spro to blend polyester (TC blend)
Clothes and waistband, the white style that it is not only dyed, while having terylene liner.It is related to one kind and being used for different clothings, is compiling
The type of weave of mixing winding and weft when knitting composite fibre, and it can generally be related to the mixing of composite fibre and natural fiber
Braiding.), cotton, acrylic, polypropylene, synthetic resin etc. is is that impossible complete above-mentioned thermal transfer printing on the fabric of material
's.
However, the thermal transfer printing using oiliness dyestuff can be used for nylon, otherwise thermal transfer printing can only partial action
In in pretreated cotton, blend polyester, acrylic and composite fibre.One is cannot be used for using the thermal transfer printing of oiliness dyestuff
As ink-jet printer, and be only used among large-scale intaglio printing.
However, in this method using the thermal transfer printing of oiliness dyestuff, since ink is oiliness, cause work
Process is difficult, and is cleaned using methanol, causes to produce a large amount of additional waste material.The toning of dyestuff is also very difficult simultaneously, this
Naturally be one to both at home and abroad for be not very simple technology.In addition, expensive large-scale intaglio press is for this skill
Art is also indispensable.
The pre-treating technology of fabric needs to make resin force the method for attachment on the fabric to heat using a kind of so that this
The pretreated fabric texture of kind is very stiff after washing.And if such technique encounters that temperature is relatively low or fabric is one
Under a little internal influences, resin component can be caused to be peeled off from fabric, it means that the pattern after printing can be ruptured or is damaged.
Therefore, such fabric washing can be very inconvenient and be difficult to wash.
Thus, which traditional nylon product is not used on above method printing, this leads to nylon fabric unless using silk
Outside silk fabric printing or oiliness intaglio printing, dull dyestuff can only be used to carry out monochrome dyeing.But it is needed using when above-mentioned printing process
High temperature and cleaning are neutralized, this can cause to generate a large amount of industrial wastewaters.And cotton, blend polyester, synthetic resin and acrylic fabric
It needs to carry out the pretreatment before thermal transfer printing, this also will produce the deviation in the expense and design of great number.
Invention content
Technical problem to be addressed by invention：The object of the invention is that a kind of thermal transfer printing method of popularization is above-mentioned to solve
Workflow complexity in method in addition to polyester thread (polyester fiber yarn) and inconvenient technical problem：So that more than
It is terylene, nylon, synthetic resin, blend polyester, cotton and acrylic fabric do not need the pretreatment before thermal transfer printing yet；It is logical
It crosses and carries out thermal transfer printing using the ink-jet printer of water-based ink, by the waste water and trash discharge amount during thermal transfer printing
It is down to intimate 0%；So that the degree of fading after the product thermal transfer of commercialization appropriate can be received in range at one；It can prevent
The phenomenon that dyestuff after printing on fabric subsides.
Water-based ink in the present invention is compatible with additive, is suitable for ink-jet printer, suitable for printing and gathering around
There is high viscosity.Fabric transfer paper in the present invention possesses the structure that can fully adjust and is suitable for the invention ink.Therefore,
It can reach high-speed transfer using the transfer of the present invention and high quality is colour-fast.
One of present invention purpose is to provide ink-jet that is a kind of environmental protection, cheap, can meeting fabric property and beats
The water-based spinning transfer ink and Fabric transfer paper of print machine.
Improving textile printing by replacing the status of oiliness transfer ink it is a further object to provide a kind of
The aqueous transfer printing ink that industry keeps it more friendly to environment.
In addition, the present invention also for solve in conventional transfer method, nylon, synthetic resin, blend polyester, cotton, Ya Ke
The fabrics such as power need pretreated technical problem.In addition, being not required to pretreated terylene can also be used the present invention.
The technical problem to be solved in the invention does not terminate in the above problem, passes through following description, those skilled in the art
It can fully understand other the technical problem to be solved in the invention.
The water-based spinning of ink-jet printer involved by one aspect of the present invention transfers ink, is suitable for nylon, synthesis tree
The ink-jet printer caloric transfer printing technology of the fabrics such as fat, blend polyester, cotton or acrylic, including：
Disperse dyes adhesive：20-40wt%
Moisturizer:10-30wt%；
Surface tension modifier:0.01-0.1wt%；
Antifoaming agent:0.01--0.5wt%；
Preservative:0.01--0.5wt%；With
Deionized water:Surplus.
Further, the color developing agent of 2-8wt% is included in the water-based spinning transfer ink of ink-jet printer of the invention.
Include in disperse dyes adhesive in the present invention：Disperse dyes:15-35wt%；Dispersant:2-25wt%；It is secondary
Grade dispersant:15-35wt%；And deionized water:Surplus.
The preparation of disperse dyes adhesive in the present invention be mixing disperse dyes, dispersant, secondary dispersant and go from
Sub- water and milled mixtures, until the grain size of finished product disperse dyes is 60-200nm.
Disperse dyes in the present invention are selected from following dyestuff：Disperse dyes (magenta) 19, disperse dyes (magenta) 54, dispersion
Dyestuff (magenta) 60, disperse dyes (magenta) 86, disperse dyes (magenta) 118, disperse dyes (magenta) 179, disperse dyes are (yellow
Color) 54, disperse dyes (yellow) 64, disperse dyes (yellow) 79, disperse dyes (yellow) 104, disperse dyes (yellow) 163,
Disperse dyes (yellow) 232, disperse dyes (cyan) 7, disperse dyes (cyan) 14, disperse dyes (cyan) 26, disperse dyes
(cyan) 72, disperse dyes (cyan) 79, disperse dyes (cyan) 124, disperse dyes (cyan) 359, disperse dyes (orange)
11, disperse dyes (orange) 13, disperse dyes (orange) 29, disperse dyes (orange) 31, disperse dyes (orange) 73, dispersion
Dyestuff (orange) 149, disperse dyes (purple) 17, disperse dyes (purple) 26, disperse dyes (purple) 28 and disperse dyes are (purple
Color) 63 at least one.
Dispersant in the present invention is sodium lignosulfonate.
Secondary dispersant in the present invention is selected from polyester dispersion color additive, N-methyl-2-2-pyrrolidone N, ethyl -2- pyrroles
Alkanone, butyl carbitol, dimethyl ether, gamma butyrolactone, polyethylene glycol 200, polyethylene glycol 2000 and alpha-pyrrolidone
At least one of.
Color developing agent in the present invention is a kind of resin color-developing agent, selected from polyvinyl acetate, polyurethane, polyvinyl alcohol, is gathered
Acrylic resin:At least one of 5-15wt%, and surplus is deionized water.
The preparation of resin color-developing agent in the present invention is by polyvinyl acetate and polyurethane first according to mass ratio 2.3:
1.8 mixing.
The preparation of resin color-developing agent in the present invention, need to also be by polyurethane, polyvinyl alcohol, polyacrylic acid respectively according to quality
Than 2.2:1：1.5 mixing.
The preparation of resin color-developing agent in the present invention, need to also be by polyvinyl acetate, polyurethane, polyvinyl alcohol, polypropylene
Acid is respectively according to mass ratio 2:1.2:0.5:1.6 mixing.
Moisturizer in the present invention is selected from glycerine, butanediol, polyethylene glycol, propylene glycol, ethylene glycol, xylitol, propylene glycol
At least one of diglycidyl ether and sorbierite.
The preparation of moisturizer in the present invention is by propylene glycol, ethylene glycol, xylitol and sorbierite according to mass ratio 3:2:
1.5:1 mixes.
Surface tension activity agent in the present invention is selected from least one of Anonionic fluoride surface tension activity agent.
Antifoaming agent in the present invention is selected from least one of organic siliconresin antifoaming agent and inorganic polysiloxane antifoaming agent.
Preservative in the present invention is selected from potassium sorbate, sorbic acid, salicylic acid, methylhydroxybenzoate, methyl para hydroxy
At least one of methyl benzoate, propylbenzoic acid ester, butylbenzoic acid ester.
The preparation of preservative in the present invention is by potassium sorbate, and salicylic acid, methyl parabens are according to quality
Than 2.5:1.5:1 mixes.
The preparation of the water-based spinning transfer ink of ink-jet printer involved by one aspect of the present invention, contains dispersion dye
Expect adhesive, moisturizer, surface tension activity agent, antifoaming agent, preservative, the deionized water of color developing agent and surplus, wherein including
：
Disperse dyes adhesive is prepared, mixes disperse dyes adhesive, moisturizer, surface tension activity in certain proportion
Agent, antifoaming agent, preservative, color developing agent and deionized water are put into grinder, grind this mixture until grain size reaches 60-
200nm；
Color developing agent is prepared, with certain proportion hybrid resin color developing agent and deionized water, is heated to preset temperature until resin
Melt completely；And
With certain proportion mixing disperse dyes adhesive, color developing agent, moisturizer, surface tension activity agent, antifoaming agent, anti-corrosion
Agent and deionized water, and mixture is stirred with the rate uniform of 100-600rpm/min.
Confession in the present invention contains disperse dyes adhesive, moisturizer, surface tension activity agent, antifoaming agent, preservative,
The processing of the Fabric transfer paper of the water-based spinning transfer ink operation of the ink-jet printer of the deionized water of color developing agent and surplus
Step is：
Prepare the body paper of 30-100gsm；
The first coating solution that total amount is 3-5gsm is coated on body paper；
The second coating solution of 2-10gsm is coated in first coating；
Back coating solution is coated at the back side of body paper,
The preparation of above-mentioned first coating solution be selected from poly- phthalazines ether ketone ketone, poly- O-phthalic ether sulfone, poly- O-phthalic ether sulfone,
Polyether sulfone (PES), polysulfones, ethylene vinyl acetate (EVA), at least one of pigment and palm oil.Second coating solution
It prepares and is selected from polyvinyl acetate, polyurethane, polyvinyl alcohol, at least one of polyacrylic resin.Back coating solution
Prepare includes water and starch.
The preparation of second coating solution in the present invention, by comprising according to mass ratio 2.3:The 1.8 poly-vinegar acid mixed
Vinyl acetate and polyurethane composition.
The preparation of second coating solution in the present invention, by comprising respectively according to mass ratio 2.2:1:1.5 mix
Polyurethane, polyvinyl alcohol, polyacrylic acid composition.
The preparation of second coating solution in the present invention, by comprising according to mass ratio 2:1.2:0.5:1.6 mix
Polyvinyl acetate, polyurethane, polyvinyl alcohol, polyurethane resin composition.
Invention effect
The water-based spinning transfer ink and Fabric transfer paper of ink-jet printer in the present invention can solve above-mentioned technology
Problem.It is also possible to provide multiple color for nylon products easily and may not need pretreatment nylon, synthesis
The fabrics such as resin, blend polyester, cotton or acrylic.The present invention can allow product design more diversification, save production cost simultaneously
And keep the product high quality produced colour-fast.
Since the aquosity fabric transfer ink and Fabric transfer paper of the ink-jet printer in the present invention have used a kind of water
Property dye ink, the printing process of fabric is clean.Since the present invention uses anhydrous production method, generated because of waste water
Expense is possible to be down to close to 0%.In addition, the present invention can enhance printing effect, keep product high quality colour-fast, and
Multinomial performance requirement can be met, to prevent the dyestuff in fabric from subsiding.
Further, since the present invention ink-jet printer water-based spinning transfer ink be suitable for simple production procedure with
And its low cost, the present invention are suitable for mass production and large-scale production, while the water of the ink-jet printer of the present invention
Property weaving transfer ink be also applied for carrying out a large amount of steady productions with ink-jet printer.
In conventional approach, the digital dye printing in textile dyeing mainly uses acid dyes or oiliness dyestuff,
In dyeing course, these acid dyes or oiliness dyestuff can incorporate fabric in high-pressure process.Further, since limited color strength
Degree, disperse dyes will not generally be used, and using aqueous dispersion dye ink, colouring is to pass through on the fabric
High temperature makes dyestuff vaporize and reach.However, the present invention can be by using nature color developing agent in aqueous dispersion dye ink
Reach and exploitation appropriate is carried out to the color of dyestuff.
The simple declaration of attached drawing
Fig. 1 is the water-based spinning transfer ink for the ink-jet printer for showing production nylon fabric according to the present invention
Flow chart.
Fig. 2 is to show the water-based spinning transfer ink according to the present invention for producing the ink-jet printer of nylon fabric
The structure chart of the Fabric transfer paper of water operation.
The specific implementation mode of the present invention
The above-mentioned description of this invention is the example of a structure and function used to explain the present invention, and of the invention regards
Open country should not be limited by the content that above-mentioned text embodies.I other words implementation of the invention can there are many avatars, therefore,
The application range of the present invention is construed as being equal to the expanded range of technical concept.Due to purpose disclosed in this invention and effect
Fruit is not intended to be limited to specific example, therefore the application range of the present invention should not be limited by its above-mentioned explanation.
Term described in this specification should be understood that it is as follows,
Term " first " " second " etc. is used only to distinguish different elements, and the range of right should not be by these term institutes
Limitation.For example, first component may relate to second component, similar, second component is also possible to be related to first
A component.
It is to be appreciated that when an element is referred to as ' attach ' to another element, indicate that it can be directly connected to
To another element, although other element is possibly present therein.However, when an element is referred to as " being directly connected to " to another
When a element, it should be appreciated that there is no other element between the two.On the other hand, describe component between relationship other expression
Formula, as " ... between " relationship between " between directly existing ... " or " neighborhood " and " direct neighbor " also should be explained similarly.
Singulative should be understood to include plural form, unless clearly being stated in context."comprising" or " possessing " etc.
The purpose of term is feature, number, step, operation, element, part or the presence of combination of specified statement.It is to be appreciated that
Other one or more features, number, step, operation, element, part or the presence or addition of combination are excluded in advance.
In each of the steps, all cognizance code (for example, a, b, c etc.) is used to be explained to facilitate；Cognizance code is not retouched
State the sequence of step.Unless clearly stating within a context, otherwise each step all may be different from the sequence stated.Namely
It says, each step can occur according to the sequence of description, may be performed simultaneously, can also execute in a reverse order.
Unless otherwise defined, all terms used in the present invention are all to use general sense in the art.In dictionary
Defined in essential term should be interpreted it is consistent with the meaning in related field, unless explicitly defining in this application, otherwise
It cannot be construed to the purpose with ideal or too formal.
The present invention for ink-jet printer can processed through sublimation heat transfer printing ink must be aqueous solution.Ink composition should include resin at
Point, to carry out thermal transfer to fabric in the case that not pretreated, this is one of features of the present invention.Therefore, resin group
Part should can allow print head to pass through.In order to improve the colour-fast degree of dyestuff, Fabric transfer paper can be used to supplement insufficient resin
Part.
Water-based ink suitable for ink-jet printer needs to be developed.In addition, in order to when product is completed improve color and
A kind of dyestuff fastness, it would be desirable to special Fabric transfer paper being suitble to such ink.
Ink-jet printer aquosity fabric transfer ink of the present invention can be by the mass percent group of llowing group of materials
At.
Example 1：Disperse dyes adhesive:20-40wt%, moisturizer:10-30wt%, surface tension modifier:0.01-
0.1wt%, antifoaming agent:0.01-0.5wt%, preservative:0.01-0.5wt%, deionized water:Surplus.
In order to provide more remarkable color, the aquosity fabric transfer ink of the present invention for possessing above-mentioned composition can be by
The mass percent of llowing group of materials is constituted.
Example 2：Disperse dyes adhesive:25-35%, color developing agent:2-8%, moisturizer:10-25%, surface tension adjustment
Agent:0.01%-0.1%, antifoaming agent:0.01%-0.5%, preservative:0.01%-0.5%, deionized water:Surplus.
Disperse dyes adhesive can be made of the mass percent of llowing group of materials,
Disperse dyes:15-35wt%, dispersant:5-25wt%, secondary breakup agent:15-35wt%, deionized water:It is remaining
Amount.
Above-mentioned disperse dyes adhesive can be by grinding distribution dyestuff, dispersant, twice dispersing agent, the mixing of deionized water
Object is formulated.Equally, disperse dyes adhesive can also be by grinding distribution dyestuff, dispersant, twice dispersing agent, and decolorising agent is mixed
Object is closed to be formulated.Its grain size in 60-200nm to be preferred.
Disperse dyes can be selected from llowing group of materials：Disperse dyes (magenta) 19, disperse dyes (magenta) 54, disperse dyes
(magenta) 60, disperse dyes (magenta) 86, disperse dyes (magenta) 118, disperse dyes (magenta) 179, disperse dyes (yellow)
54, disperse dyes (yellow) 64, disperse dyes (yellow) 79, disperse dyes (yellow) 104, disperse dyes (yellow) 163, dispersion
Dyestuff (yellow) 232, disperse dyes (cyan) 7, disperse dyes (cyan) 14, disperse dyes (cyan) 26, disperse dyes are (green
Color) 72, disperse dyes (cyan) 79, disperse dyes (cyan) 124, disperse dyes (cyan) 359, disperse dyes (orange) 11,
Disperse dyes (orange) 13, disperse dyes (orange) 29, disperse dyes (orange) 31, disperse dyes (orange) 73, disperse dyes
(orange) 149, disperse dyes (purple) 17, disperse dyes (purple) 26, disperse dyes (purple) 28 and disperse dyes (purple)
63 at least one.
Dispersant can be made of sodium lignosulfonate.
Secondary dispersant is selected from polyester dispersion color additive, N-methyl-2-2-pyrrolidone N, ethyl-2-pyrrolidone, butyl card
Than alcohol, dimethyl ether, gamma butyrolactone, polyethylene glycol 200, at least one in polyethylene glycol 2000 and alpha-pyrrolidone
Kind.
Polyester dispersion color additive can be selected from least one of dispersant 5040, dispersant 1027 and dispersant 1029 work
For polyester copolymer solution.
Polyester dispersion color additive can be selected from Houtch D-127, in Houtch D-156 and Houtch D-160 at least
It is a kind of to be used as polyester copolymer solution.
In disperse dyes adhesive, using sodium lignosulfonate as dispersant, disperse dyes auxiliary agent is added, improves dispersion dye
The stability and tinting strength, tinting power of material reduce the damage to dyeing apparatus with this.
In example 2, color developing agent in aquosity fabric of the present invention transfer ink can by 5-15% resin color-developing agent and
The water of surplus forms.
Resin color-developing agent can be selected from following material, polyvinyl acetate, polyurethane, polyvinyl alcohol, polyacrylic resin
At least one of.
The preparation of resin color-developing agent, can be by polyvinyl acetate and polyurethane according to mass ratio 2.3:1.8 mixing.
The preparation of resin color-developing agent, preferably by polyvinyl acetate, polyurethane, polyvinyl alcohol, polyacrylic acid respectively according to
Mass ratio 2.2:1:1.5 mix to prepare.
The preparation of resin color-developing agent, preferably by polyurethane, polyvinyl alcohol, polyacrylic acid respectively according to mass ratio 2:1.2:
0.5:1.6 mix to prepare.
In example 1 and example 2, the present invention relates to moisturizer can be selected from following material, glycerine, butanediol, polyethylene glycol, third
Glycol, ethylene glycol, xylitol, at least one of propylene glycol glycidyl ether and D-sorbite.
The mass ratio of D-sorbite and butanediol in moisturizer is preferably 2:1.3
The mass ratio of glycerine and butanediol in moisturizer is preferably 1.6:1.1
The mass ratio of polyethylene glycol, propylene glycol and xylitol in moisturizer is preferably 2.3:1.3:1,
The mass ratio of glycerine in moisturizer, ethylene glycol and sorbierite is preferably 3:2:1.5:1,
Surface tension activity agent of the present invention is selected from least one of Anonionic fluoride surface tension activity agent.
Specifically, in the agent of Anonionic fluoride surface tension activity,W-77 tables in terms of reducing surface tension
Outstanding performance is revealed.It can enhance wettability, the surface propertys such as dispersed mobility.
W-77 does not include any VOC (volatile organic compounds), is free of APEO (alkyl ethoxylate),
And it is nonflammable, and it can coexist with any ion surface tension active agent.Surface tension according to the present invention
Activating agent includes a kind of commercially available Anonionic fluoride surface tension activity agent.
Antifoaming agent involved in the present invention in organic siliconresin antifoaming agent and inorganic polysiloxane antifoaming agent at least one
Kind.
Specifically, Defom W-052, Defom W-074 and Defom W-082 are contained in organic siliconresin antifoaming agent.
Specifically, contain in inorganic polysiloxane antifoaming agentAP7015,DF 1760,Defom
2700。
Certainly, the organic siliconresin antifoaming agent of dye for fabrics or inorganic polysiloxane antifoaming agent are all in the market in the present invention
It can buy.
Preservative in the present invention is selected from potassium sorbate, sorbic acid, salicylic acid, methylhydroxybenzoate, methyl para hydroxy
At least one of methyl benzoate, propylbenzoic acid ester, butylbenzoic acid ester.
Preservative is preferably made of potassium sorbate.
The mass ratio of sorbic acid and methyl para hydroxy methyl benzoate in preservative is preferably 3:1.
The preparation of preservative, preferably by potassium sorbate, salicylic acid, methyl parabens are according to mass ratio 2.5:
1.5:1 mixes.
Above-mentioned ink-jet printer transfers ink with aquosity fabric and can be allocated by following steps,
Step 1 (prepares disperse dyes adhesive)：Mixing disperse dyes adhesive, moisturizer, table in certain proportion
Face tension active agent, antifoaming agent, preservative, color developing agent and deionized water are put into grinder, grind this mixture until grain size
Reach 60-200nm；
Step 2 (prepares color developing agent)：With certain proportion hybrid resin color developing agent and deionized water, it is heated to preset temperature
Until resin melts completely；
Step 3 (stirring)：With certain proportion mixing disperse dyes adhesive, color developing agent, moisturizer, surface tension activity
Agent, antifoaming agent, preservative and deionized water, and mixture is stirred with the rate uniform of 100-600rpm/min.When this step,
Additional disinfectant and anti-coagulants can be added.
As shown in table 1, the pattern representation that ink-jet printer aquosity fabric transfer ink of the present invention is modulated is such as
Under：
Table 1 (experimental temperature is 20 DEG C)
《Sample 1》
Ink-jet printer in sample 1 aquosity fabric transfer ink by following material the structure in the form of mass percent
At：
118 adhesive of disperse dyes (magenta):30%, D-sorbite:10%, butanediol:10%, color developing agent:3%, disappear
Infusion:0.02%, surface tension activity agent:0.03%, deionized water:Surplus.
Wherein, 118 adhesive of disperse dyes (magenta) is constituted comprising following material in the form of mass percent：
Disperse dyes 86:21%, sodium lignosulfonate:17%, polyester dispersion color additive:15%, gamma butyrolactone:7%, it goes
Ionized water:Surplus, average grain diameter 65nm.
Wherein, color developing agent is constituted comprising following material in the form of mass percent：
Polyacrylic resin:8%, polyvinyl alcohol：4%, ion exchange water:Surplus.
Antifoaming agent is Defom W-052, and surface tension activity agent isW-77, polyester dispersion color additive are point
Powder 5040.
The production process of aquosity fabric thermal transfer ink is as follows,
Prepare disperse dyes adhesive：By disperse dyes (magenta) 118, sodium lignosulfonate, polyester dispersion color additive,
Gamma butyrolactone and deionized water mix in appropriate proportions, and mixture is ground in grinder.
And then at room temperature by color developing agent, antifoaming agent, surface tension activity agent and deionized water uniform stirring, and it is added
Disperse dyes adhesive.After mixture is stirred at room temperature 6 hours, filtered 2 hours under 0.4 μm with glass fibre, to
To thermal transfer ink.
This production process can carry out extensive, industrialization production since step is simple, investment is relatively low；It can be big
Amount produces the more stable aquosity fabric for ink-jet printer and transfers ink.
Aquosity fabric thermal transfer ink in above-mentioned sample is to use disperse dyes, using digital printing and thermal transfer technology,
And due to the pretreatment and post-processing that dye transfer is omitted, relevant industrial wastewater is not will produce.
In the disperse dyes adhesive of above-mentioned sample, using sodium lignosulfonate as dispersant, disperse dyes auxiliary agent is added,
The stability and tinting strength, tinting power for improving disperse dyes, the damage to dyeing apparatus is reduced with this.
Ink-jet printer in sample uses aquosity fabric thermal transfer ink, the pretreatment during the dye transfer of fabric
It is omitted with post-processing.Therefore, it realizes clean manufacturing of fabric during dye transfer and does not use water, and may make work
The discharge of industry waste water is reduced to nearly 0%.In addition, dye transfer effect promoting, it is colour-fast and effectively anti-that product possesses higher quality
Only the disperse dyes in fabric subside.
《Sample 2》
Ink-jet printer in sample 2 is a kind of sublimable ink with ink, it includes following material with mass percent
Form constitute,
104 adhesive of disperse dyes (yellow):32%, sorbierite:10%, butanediol:10%, color developing agent:3%, defoaming
Agent:0.02%, surface tension activity agent:0.3%, deionized water:Surplus.
Wherein, 104 adhesive of disperse dyes (yellow) is constituted comprising following material in the form of mass percent：
Disperse dyes (Huang) 64:24%, sodium lignosulfonate:21%, polyester dispersion color additive:18%, deionized water:
Surplus, average grain diameter 100nm.
Wherein, color developing agent is constituted comprising following material in the form of mass percent：
Polyacrylic resin:8%, polyvinyl alcohol:4%, polyurethane:1%, deionized water:Surplus.Antifoaming agent is Defom
W-074, surface tension activity agent are the Anonionic fluoride surface tension activator that can be bought in the market, polyester dispersion dyestuff
Auxiliary agent is dispersant 1027.
Remaining content of sample 2 is identical as sample 1, therefore omits.
《Sample 3》
Ink-jet printer in sample 3 is a kind of water-based ink carrying out cloth print by heating with ink, it includes
Following material is constituted in the form of mass percent,
79 adhesive of disperse dyes (cyan):35%, D-sorbite:10%, butanediol:10%, color developing agent:3.5%,
Antifoaming agent:0.02%, surface tension activity agent:0.2%, deionized water:Surplus.
Wherein, 79 adhesive of disperse dyes (cyan) is constituted comprising following material in the form of mass percent,
Disperse dyes (cyan) 124:23%, sodium lignosulfonate:21%, polyester dispersion color additive:In 16%, γ fourth
Ester:7%, deionized water:Surplus, average grain diameter 130nm.
Wherein, color developing agent is constituted comprising following material in the form of mass percent,
Polyacrylic resin:7%, polyvinyl alcohol:4%, polyurethane:2%, deionized water:Surplus.
Above-mentioned antifoaming agent is Defom W-082, and surface tension activity agent isW-77, polyester dispersion color additive
For Houtch D-127.
Remaining content of sample 3 is identical as sample 1, therefore omits.
《Sample 4》
Ink-jet printer in sample 4 is a kind of water-based ink carrying out cloth print by heating with ink, it includes
Following material is constituted in the form of mass percent,
31 adhesive of disperse dyes (orange):33.5%, glycerine:10%, butanediol:10%, color developing agent:3.5%, disappear
Infusion:0.02%, surface tension activity agent:0.2%, deionized water:Surplus.
Wherein, 31 adhesive of disperse dyes (orange) is constituted comprising following material in the form of mass percent,
Disperse dyes (black) 9:24%, sodium lignosulfonate:21%, polyester dispersion color additive:15%, gamma butyrolactone:
7%, deionized water:Residual volume, average grain diameter 135nm.
Wherein, color developing agent is constituted comprising following material in the form of mass percent,
Polyacrylic resin:8%, polyvinyl alcohol:4%, ion exchange water:Residual volume.
Above-mentioned antifoaming agent isAP 7015, surface tension activity agent areW-77, polyester dispersion dyestuff
Auxiliary agent is Houtch D-156.
Remaining content of sample 4 is identical as sample 1, therefore omits.
《Sample 5》
Ink-jet printer in sample 5 is a kind of water-based ink carrying out cloth print by heating with ink, it includes
Following material is constituted in the form of mass percent,
64 adhesive of disperse dyes (purple):25%, polyethylene glycol:10%, hexylene glycol:10%, sorbierite:5%, it shows
Toner:3.5%, antifoaming agent:0.02%, surface tension activity agent:0.1%, potassium sorbate:0.3%, deionized water:Surplus.
Wherein, 64 adhesive of disperse dyes (purple) is constituted comprising following material in the form of mass percent,
Disperse dyes 60:20%, sodium lignosulfonate:25%, polyester dispersion color additive:16%, methyl pyrrolidone:
7%, deionized water:Residual volume, average grain diameter 150nm.
Wherein, color developing agent is constituted comprising following material in the form of mass percent,
Polyurethane:8%, polyvinyl alcohol:4%, deionized water:Surplus.
Above-mentioned antifoaming agent isAP 1760, surface tension activity agent areW-77, polyester dispersion dyestuff help
Agent is Houtch D-160.
Remaining content of sample 5 is identical as sample 1, therefore omits.
《Sample 6》
Ink-jet printer in sample 6 is a kind of water-based ink carrying out cloth print by heating with ink, it includes
Following material is constituted in the form of mass percent,
179 adhesive 40% of disperse dyes (magenta), xylitol 10%, butanediol 10%, color developing agent 3.5%, antifoaming agent
0.02%, surface tension activity agent 0.4%, ascorbic acid 0.1%, methyl parabens:0.2%, deionized water:It is remaining
Amount.
Wherein, 179 adhesive of disperse dyes (magenta) is constituted comprising following material in the form of mass percent,
Disperse dyes (yellow) 163:20%, sodium lignosulfonate:15%, polyester dispersion color additive:16%, poly- second two
Alcohol 200:7%, deionized water:Surplus, average grain diameter 200nm.
Wherein, color developing agent is constituted comprising following material in the form of mass percent,
Polyacrylic acid:8%, polyvinyl alcohol:4%, deionized water:Surplus.
Above-mentioned antifoaming agent is Defom 2700, and surface tension activity agent isW-77, polyester dispersion color additive
For dispersant 1029.
It is described below a kind of for fabric that hereinbefore ink-jet printer of the present invention is used with aqueous transfer printing ink
Transfer paper.
Fig. 2 is the structure chart for showing ink-jet printer Fabric transfer paper according to the present invention.Fabric transfer paper is matched
It is made as：Prepare (gram every square metre of 30-100gsm；The weight of per unit area fabric) body paper 100；It is coated on body paper 100
Total amount is the first coating solution of 3-5gsm, forms first coating 300；Second that 2-10gsm is coated in first coating 300 applies
Layer solution, forms second coating 400；Back coating solution is coated at the back side of body paper, forms back coating 200.
First coating solution can be selected from the poly- phthalazines ether ketone ketone of following material, poly- O-phthalic ether sulfone, poly- O-phthalic ether sulfone,
Polyether sulfone (PES) and polysulfones, ethylene vinyl acetate (EVA), pigment, at least one of palm oil.
Second coating solution can be selected from following material polyvinyl acetate, polyurethane, polyvinyl alcohol, in polyacrylic resin
At least one.Wherein, the mass ratio of polyvinyl acetate and polyurethane can be 2.3:1.8, polyurethane, polyvinyl alcohol, poly- third
The mass ratio of olefin(e) acid can be 2.2:1：1.5, and polyvinyl acetate, polyurethane, polyvinyl alcohol, the mass ratio of polyacrylic resin
Can be 2:1.2:0.5:1.6.
Back coating solution can be made of water and starch.
In order to keep coating solution of the present invention to have certain viscosity, wherein a certain amount of elastomeric polymer can be added
Such as ethylene vinyl acetate (EVA) or polyurethane.In order to obtain excellent light resistance and excellent transfer acutance, can also be added anti-
Oxidant or ultra-violet absorber.
The first coating 300 formed by first coating solution, contains sublimable ink dye, moisture etc., turns in heat
During print, these sublimable ink dyes and moisture etc. can be transferred along from body paper 100 onto fabric.
The resin in second coating 400 in first coating 300 can be peeled off and be shifted during thermal transfer distils
Onto fabric, to reach the colour-fast and excellent transfer acutance of high quality.
Coating process can be blade method, point coating, lip coating, air knife method etc..
The sequence of coating process and coating above can according to the performance change of fabric, such as with nylon, blend polyester or
Cotton carries out inkjet printing, so as to being adjusted and be efficiently used thermal transfer printing technology.
The aquosity fabric thermal transfer ink that aforementioned present invention is related to can remove the pattern on fabric by heating ink,
And it can paint again.In addition, ink meets various performance requirements, recession of the dyestuff in textile can be effectively prevent.
It is clean during the dye transfer of fabric since the present invention uses aquosity fabric thermal transfer ink.And by
Clean manufacturing of fabric during dye transfer is realized in it and does not use water, and the discharge of industrial wastewater may be made to be reduced to nearly 0%.
In addition, dye transfer effect promoting, product possesses higher quality and does not allow fugitive color, and ink meets various performance requirements, can have
Effect prevents the disperse dyes in fabric from subsiding.
In addition, the step of due to ink production process is simple, it is relatively low to invest, extensive, industrialization production can be carried out；
It can transfer ink with the more stable aquosity fabric for ink-jet printer of mass production.
In conventional transfer method, the ink on the fabric of digital dye printing can generally use acid dyes or oil
Property dyestuff, these acid dyes or oiliness dyestuff can be by HIGH PRESSURE TREATMENT dye transfers to fabric during dye transfer.In addition, due to color
Intensity is weaker, and disperse dyes will not be frequently used in conventional method；And using aqueous dispersion dye ink,
Dyestuff is needed could be in dye transfer to fabric in the case where high temperature distils.However, the present invention can be by aqueous dispersion dyestuff
Solve the problems, such as that conventional transfer method can not suitably develop color using nature color developing agent in ink.
Described above relates to some preferable examples of the present invention.But it will be understood by those skilled in the art that not
Under the premise of the spirit and scope of the present invention, the present invention can make various change in form and details.
Claims (22)
1. a kind of water-based spinning of ink-jet printer transfers ink, which is characterized in that the transfer ink is ink-jet printer
With the ink on nylon, blend polyester, cotton, synthetic resin, acrylic or polypropylene fabric, the transfer in thermal transfer
Ink includes：
Disperse dyes adhesive：20wt%-40wt%
Moisturizer:10wt%-30wt%；
Surface tension modifier:0.01wt%-0.1wt%；
Antifoaming agent:0.01wt%-0.5wt%；
Preservative:0.01wt%-0.5wt%；With
Deionized water:Surplus.
2. the water-based spinning of ink-jet printer according to claim 1 transfers ink, which is characterized in that further include
The color developing agent of 2wt%-8wt%.
3. the water-based spinning of ink-jet printer according to claim 2 transfers ink, which is characterized in that the dispersion dye
Include in material adhesive：
Disperse dyes:15wt%-35wt%；
Dispersant:2wt%-25wt%；
Secondary dispersant:15wt%-35wt%；
And deionized water:Surplus.
4. the water-based spinning of ink-jet printer according to claim 3 transfers ink, which is characterized in that the dispersion dye
The preparation of material adhesive is mixing disperse dyes, dispersant, secondary dispersant and deionized water and milled mixtures, until finished product
The grain size of disperse dyes is 60nm-200nm.
5. the water-based spinning of ink-jet printer according to claim 4 transfers ink, which is characterized in that the dispersion dye
Material is selected from following dyestuff：Disperse dyes (magenta) 19, disperse dyes (magenta) 54, disperse dyes (magenta) 60, disperse dyes (product
It is red) 86, disperse dyes (magenta) 118, disperse dyes (magenta) 179, disperse dyes (yellow) 54, disperse dyes (yellow) 64,
Disperse dyes (yellow) 79, disperse dyes (yellow) 104, disperse dyes (yellow) 163, disperse dyes (yellow) 232, dispersion dye
Material (cyan) 7, disperse dyes (cyan) 14, disperse dyes (cyan) 26, disperse dyes (cyan) 72, disperse dyes (cyan)
79, disperse dyes (cyan) 124, disperse dyes (cyan) 359, disperse dyes (orange) 11, disperse dyes (orange) 13, dispersion
Dyestuff (orange) 29, disperse dyes (orange) 31, disperse dyes (orange) 73, disperse dyes (orange) 149, disperse dyes (purple
Color) 17, disperse dyes (purple) 26, at least one of disperse dyes (purple) 28 and disperse dyes (purple) 63.
6. the water-based spinning of ink-jet printer according to claim 3 transfers ink, which is characterized in that the dispersant
For sodium lignosulfonate.
7. the water-based spinning of ink-jet printer according to claim 3 transfers ink, which is characterized in that the secondary fraction
Powder is selected from polyester dispersion color additive, N-methyl-2-2-pyrrolidone N, ethyl-2-pyrrolidone, butyl carbitol, dipropylene glycol
Dimethyl ether, gamma butyrolactone, polyethylene glycol 200, at least one of polyethylene glycol 2000 and alpha-pyrrolidone.
8. the water-based spinning of ink-jet printer according to claim 2 transfers ink, which is characterized in that the color developing agent
Including a kind of resin color-developing agent, the resin color-developing agent is selected from polyvinyl acetate, polyurethane, polyvinyl alcohol, polyacrylic acid tree
Fat:At least one of 5wt%-15wt%；
Surplus is deionized water.
9. the water-based spinning of ink-jet printer according to claim 8 transfers ink, which is characterized in that the resin is aobvious
The preparation of toner, including polyvinyl acetate and polyurethane are according to mass ratio 2.3:1.8 mixing.
10. the water-based spinning of ink-jet printer according to claim 8 transfers ink, which is characterized in that the resin
The preparation of color developing agent, by polyurethane, polyvinyl alcohol, polyacrylic acid respectively according to mass ratio 2.2:1：1.5 mix to prepare.
11. the water-based spinning of ink-jet printer according to claim 8 transfers ink, which is characterized in that the resin
The preparation of color developing agent, by polyvinyl acetate, polyurethane, polyvinyl alcohol, polyacrylic acid respectively according to mass ratio 2:1.2:0.5:
1.6 mix to prepare.
12. the water-based spinning of ink-jet printer according to claim 1 transfers ink, which is characterized in that the moisturizing
Agent is selected from glycerine, butanediol, polyethylene glycol, propylene glycol, ethylene glycol, xylitol, in propylene glycol diglycidylether and sorbierite
At least one.
13. the water-based spinning of ink-jet printer according to claim 12 transfers ink, which is characterized in that the moisturizing
The preparation of agent is by propylene glycol, ethylene glycol, xylitol and sorbierite according to mass ratio 3:2:1.5:1 mixes.
14. the water-based spinning of ink-jet printer according to claim 1 transfers ink, which is characterized in that the surface
Tension active agent is selected from least one of Anonionic fluoride surface tension activity agent.
15. the water-based spinning of ink-jet printer according to claim 1 transfers ink, which is characterized in that the defoaming
Agent is selected from least one of organic siliconresin antifoaming agent and inorganic polysiloxane antifoaming agent.
16. the water-based spinning of ink-jet printer according to claim 1 transfers ink, which is characterized in that the anti-corrosion
Agent is selected from potassium sorbate, sorbic acid, salicylic acid, methylhydroxybenzoate, methyl para hydroxy methyl benzoate, propylbenzoic acid
At least one of ester, butylbenzoic acid ester.
17. the water-based spinning of ink-jet printer according to claim 16 transfers ink, which is characterized in that the anti-corrosion
The preparation of agent is by potassium sorbate, salicylic acid, and methyl parabens are according to mass ratio 2.5:1.5:1 mixes.
18. a kind of method for the water-based spinning transfer ink preparing any ink-jet printers of claim 2-17, matches
Include disperse dyes adhesive in the water-based spinning transfer ink of ink-jet printer processed, moisturizer, surface tension activity agent disappears
The deionized water of infusion, preservative, color developing agent and surplus, wherein preparation method include the following steps：
The step of preparing disperse dyes adhesive mixes disperse dyes adhesive, moisturizer, surface tension and lives in certain proportion
Property agent, antifoaming agent, preservative, color developing agent and deionized water, and be put into grinder, grind this mixture until grain size reaches
60nm-200nm；
The step of preparing color developing agent is heated to preset temperature until tree with certain proportion hybrid resin color developing agent and deionized water
Fat melts completely；And
The step of preparating mixture, with certain proportion mixing disperse dyes adhesive, color developing agent, moisturizer, surface tension activity
Agent, antifoaming agent, preservative and deionized water, and mixture is stirred with the rate uniform of 100rpm/min-600rpm/min.
19. a kind of Fabric transfer paper, which is characterized in that use the aqueous of any ink-jet printers of claim 2-17
Weaving transfer ink, the transfer ink include disperse dyes adhesive, moisturizer, surface tension activity agent, antifoaming agent, anti-corrosion
The deionized water of agent, color developing agent and surplus, the Fabric transfer paper conversion step include：
Prepare the body paper of 30gsm-100gsm (gram every square metre, the mass area ratio of fabric)；
Coated on body paper total amount be 3gsm-5gsm first coating solution to form first coating；
The second coating solution of 2gsm-10gsm is coated in first coating to form second coating；
Back coating solution is coated at the back side of body paper to form back coating,
The first coating solution is selected from poly- phthalazines ether ketone ketone, poly- O-phthalic ether sulfone, poly- O-phthalic ether sulfone, polyether sulfone
(PES), polysulfones, ethylene vinyl acetate (EVA), at least one of pigment and palm oil；Second coating solution is selected from poly-vinegar
Vinyl acetate, polyurethane, polyvinyl alcohol, at least one of polyacrylic resin；Back coating solution includes water and starch.
20. Fabric transfer paper according to claim 19, which is characterized in that the second coating solution includes poly-vinegar acid second
Enester and polyurethane are according to mass ratio 2.3:1.8 mixing.
21. Fabric transfer paper according to claim 19, which is characterized in that the second coating solution is comprising mass ratio
2.2:1:1.5 polyurethane, polyvinyl alcohol and polyacrylic acid.
22. Fabric transfer paper according to claim 19, which is characterized in that the second coating solution is comprising mass ratio
2:1.2:0.5:1.6 polyvinyl acetate, polyurethane, polyvinyl alcohol, polyurethane resin.
Applications Claiming Priority (3)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| KR1020150145666A KR101795639B1 (en) | 2015-10-19 | 2015-10-19 | Aqueous transferring ink for use of textile for inkjet printer and textile transferring paper for the same |
| KR10-2015-0145666 | 2015-10-19 | ||
| PCT/KR2016/003823 WO2017069355A1 (en) | 2015-10-19 | 2016-04-12 | Water-based transfer ink dedicated to inkjet printer textile, and textile transfer paper for applying same |
Publications (1)
| Publication Number | Publication Date |
|---|---|
| CN108291102A true CN108291102A (en) | 2018-07-17 |
Family
ID=58557624
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| Application Number | Title | Priority Date | Filing Date |
|---|---|---|---|
| CN201680061405.3A Pending CN108291102A (en) | 2015-10-19 | 2016-04-12 | The water-based spinning transfer ink and Fabric transfer paper of ink-jet printer |
Country Status (4)
| Country | Link |
|---|---|
| JP (1) | JP6665286B2 (en) |
| KR (1) | KR101795639B1 (en) |
| CN (1) | CN108291102A (en) |
| WO (1) | WO2017069355A1 (en) |
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| CN108265423A (en) * | 2018-03-28 | 2018-07-10 | 浙江工贸职业技术学院 | A kind of processing technology of Wenzhou embroidery embroidered cloth picture on surface |
| CN109593399A (en) * | 2018-12-18 | 2019-04-09 | 佛山市长盛兴隆装饰材料有限公司 | A kind of Environmental-protection water-based ink and transfer paper for thermal transfer |
| CN111472181A (en) * | 2019-01-24 | 2020-07-31 | 蓝宇涛 | Disperse dye digital printing ink and preparation method thereof |
| JP7293797B2 (en) * | 2019-03-28 | 2023-06-20 | セイコーエプソン株式会社 | AQUEOUS INKJET COMPOSITION AND METHOD FOR PRODUCING RECORDED MATERIAL |
| JP2022010590A (en) * | 2020-06-29 | 2022-01-17 | ブラザー工業株式会社 | Water-based ink for ink-jet recording and ink cartridge |
| KR20240030215A (en) | 2022-08-30 | 2024-03-07 | 정길환 | Pretreatment composition for sublimation transfer of cotton fabric |
Citations (7)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| KR20060014876A (en) * | 2004-08-12 | 2006-02-16 | 주식회사 킹잉텍 | Method of making ink for ink-jet |
| KR100726804B1 (en) * | 2006-09-25 | 2007-06-11 | 주식회사 씨드 | A water-based dye sublimation ink jet ink for textile printing with environmental property |
| CN101531848A (en) * | 2009-03-24 | 2009-09-16 | 深圳市墨库数码耗材有限公司 | An environment-friendly digital ink-jet direct printing textile ink and method for preparing same |
| CN102089155A (en) * | 2009-04-24 | 2011-06-08 | 韩国科林株式会社 | Holding paper for dye-sublimation thermal-transfer recording, and a production method therefor |
| KR20130054883A (en) * | 2011-11-17 | 2013-05-27 | 경북대학교 산학협력단 | Disperse dye, and piezo inkjet ink composition comprising the same |
| KR20130095918A (en) * | 2012-02-21 | 2013-08-29 | 강충원 | Transfer print and method of thereof |
| JP2013203960A (en) * | 2012-03-29 | 2013-10-07 | Seiko Epson Corp | Ink for sublimation transfer, method for manufacturing dyed product, and dyed product |
Family Cites Families (4)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| JP3515779B1 (en) * | 2002-08-27 | 2004-04-05 | 紀和化学工業株式会社 | Inkjet recording ink for sublimation transfer and dyeing method |
| JP5593650B2 (en) * | 2008-08-06 | 2014-09-24 | 大日本印刷株式会社 | Thermal transfer sheet |
| US20110316927A1 (en) * | 2009-03-05 | 2011-12-29 | Konica Minolta Ij Technologies, Inc | Ink-Jet Textile Printing/Recording Process |
| JP5778366B1 (en) * | 2015-02-27 | 2015-09-16 | 大王製紙株式会社 | Sublimation type inkjet printing transfer paper |
-
2015
- 2015-10-19 KR KR1020150145666A patent/KR101795639B1/en active IP Right Grant
-
2016
- 2016-04-12 CN CN201680061405.3A patent/CN108291102A/en active Pending
- 2016-04-12 JP JP2018521044A patent/JP6665286B2/en not_active Expired - Fee Related
- 2016-04-12 WO PCT/KR2016/003823 patent/WO2017069355A1/en active Application Filing
Patent Citations (7)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| KR20060014876A (en) * | 2004-08-12 | 2006-02-16 | 주식회사 킹잉텍 | Method of making ink for ink-jet |
| KR100726804B1 (en) * | 2006-09-25 | 2007-06-11 | 주식회사 씨드 | A water-based dye sublimation ink jet ink for textile printing with environmental property |
| CN101531848A (en) * | 2009-03-24 | 2009-09-16 | 深圳市墨库数码耗材有限公司 | An environment-friendly digital ink-jet direct printing textile ink and method for preparing same |
| CN102089155A (en) * | 2009-04-24 | 2011-06-08 | 韩国科林株式会社 | Holding paper for dye-sublimation thermal-transfer recording, and a production method therefor |
| KR20130054883A (en) * | 2011-11-17 | 2013-05-27 | 경북대학교 산학협력단 | Disperse dye, and piezo inkjet ink composition comprising the same |
| KR20130095918A (en) * | 2012-02-21 | 2013-08-29 | 강충원 | Transfer print and method of thereof |
| JP2013203960A (en) * | 2012-03-29 | 2013-10-07 | Seiko Epson Corp | Ink for sublimation transfer, method for manufacturing dyed product, and dyed product |
Also Published As
| Publication number | Publication date |
|---|---|
| JP6665286B2 (en) | 2020-03-13 |
| KR101795639B1 (en) | 2017-11-16 |
| JP2018538387A (en) | 2018-12-27 |
| KR20170045683A (en) | 2017-04-27 |
| WO2017069355A1 (en) | 2017-04-27 |
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Application publication date: 20180717 |