CN109594372A - Aqueous jet ink printing pigment ink for textile and its production method - Google Patents
Aqueous jet ink printing pigment ink for textile and its production method Download PDFInfo
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- CN109594372A CN109594372A CN201811324799.4A CN201811324799A CN109594372A CN 109594372 A CN109594372 A CN 109594372A CN 201811324799 A CN201811324799 A CN 201811324799A CN 109594372 A CN109594372 A CN 109594372A
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- D—TEXTILES; PAPER
- D06—TREATMENT OF TEXTILES OR THE LIKE; LAUNDERING; FLEXIBLE MATERIALS NOT OTHERWISE PROVIDED FOR
- D06P—DYEING OR PRINTING TEXTILES; DYEING LEATHER, FURS OR SOLID MACROMOLECULAR SUBSTANCES IN ANY FORM
- D06P5/00—Other features in dyeing or printing textiles, or dyeing leather, furs, or solid macromolecular substances in any form
- D06P5/30—Ink jet printing
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08F—MACROMOLECULAR COMPOUNDS OBTAINED BY REACTIONS ONLY INVOLVING CARBON-TO-CARBON UNSATURATED BONDS
- C08F212/00—Copolymers of compounds having one or more unsaturated aliphatic radicals, each having only one carbon-to-carbon double bond, and at least one being terminated by an aromatic carbocyclic ring
- C08F212/02—Monomers containing only one unsaturated aliphatic radical
- C08F212/04—Monomers containing only one unsaturated aliphatic radical containing one ring
- C08F212/06—Hydrocarbons
- C08F212/08—Styrene
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08F—MACROMOLECULAR COMPOUNDS OBTAINED BY REACTIONS ONLY INVOLVING CARBON-TO-CARBON UNSATURATED BONDS
- C08F220/00—Copolymers of compounds having one or more unsaturated aliphatic radicals, each having only one carbon-to-carbon double bond, and only one being terminated by only one carboxyl radical or a salt, anhydride ester, amide, imide or nitrile thereof
- C08F220/02—Monocarboxylic acids having less than ten carbon atoms; Derivatives thereof
- C08F220/10—Esters
- C08F220/12—Esters of monohydric alcohols or phenols
- C08F220/16—Esters of monohydric alcohols or phenols of phenols or of alcohols containing two or more carbon atoms
- C08F220/18—Esters of monohydric alcohols or phenols of phenols or of alcohols containing two or more carbon atoms with acrylic or methacrylic acids
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08F—MACROMOLECULAR COMPOUNDS OBTAINED BY REACTIONS ONLY INVOLVING CARBON-TO-CARBON UNSATURATED BONDS
- C08F222/00—Copolymers of compounds having one or more unsaturated aliphatic radicals, each having only one carbon-to-carbon double bond, and at least one being terminated by a carboxyl radical and containing at least one other carboxyl radical in the molecule; Salts, anhydrides, esters, amides, imides, or nitriles thereof
- C08F222/02—Acids; Metal salts or ammonium salts thereof, e.g. maleic acid or itaconic acid
-
- D—TEXTILES; PAPER
- D06—TREATMENT OF TEXTILES OR THE LIKE; LAUNDERING; FLEXIBLE MATERIALS NOT OTHERWISE PROVIDED FOR
- D06P—DYEING OR PRINTING TEXTILES; DYEING LEATHER, FURS OR SOLID MACROMOLECULAR SUBSTANCES IN ANY FORM
- D06P1/00—General processes of dyeing or printing textiles, or general processes of dyeing leather, furs, or solid macromolecular substances in any form, classified according to the dyes, pigments, or auxiliary substances employed
- D06P1/0004—General aspects of dyeing
- D06P1/0016—Dye baths containing a dyeing agent in a special form such as for instance in melted or solid form, as a floating film or gel, spray or aerosol, or atomised dyes
-
- D—TEXTILES; PAPER
- D06—TREATMENT OF TEXTILES OR THE LIKE; LAUNDERING; FLEXIBLE MATERIALS NOT OTHERWISE PROVIDED FOR
- D06P—DYEING OR PRINTING TEXTILES; DYEING LEATHER, FURS OR SOLID MACROMOLECULAR SUBSTANCES IN ANY FORM
- D06P1/00—General processes of dyeing or printing textiles, or general processes of dyeing leather, furs, or solid macromolecular substances in any form, classified according to the dyes, pigments, or auxiliary substances employed
- D06P1/44—General processes of dyeing or printing textiles, or general processes of dyeing leather, furs, or solid macromolecular substances in any form, classified according to the dyes, pigments, or auxiliary substances employed using insoluble pigments or auxiliary substances, e.g. binders
- D06P1/52—General processes of dyeing or printing textiles, or general processes of dyeing leather, furs, or solid macromolecular substances in any form, classified according to the dyes, pigments, or auxiliary substances employed using insoluble pigments or auxiliary substances, e.g. binders using compositions containing synthetic macromolecular substances
- D06P1/5207—Macromolecular compounds obtained by reactions involving only carbon-to-carbon unsaturated bonds
- D06P1/525—Polymers of unsaturated carboxylic acids or functional derivatives thereof
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08F—MACROMOLECULAR COMPOUNDS OBTAINED BY REACTIONS ONLY INVOLVING CARBON-TO-CARBON UNSATURATED BONDS
- C08F220/00—Copolymers of compounds having one or more unsaturated aliphatic radicals, each having only one carbon-to-carbon double bond, and only one being terminated by only one carboxyl radical or a salt, anhydride ester, amide, imide or nitrile thereof
- C08F220/02—Monocarboxylic acids having less than ten carbon atoms; Derivatives thereof
- C08F220/10—Esters
- C08F220/12—Esters of monohydric alcohols or phenols
- C08F220/16—Esters of monohydric alcohols or phenols of phenols or of alcohols containing two or more carbon atoms
- C08F220/18—Esters of monohydric alcohols or phenols of phenols or of alcohols containing two or more carbon atoms with acrylic or methacrylic acids
- C08F220/1804—C4-(meth)acrylate, e.g. butyl (meth)acrylate, isobutyl (meth)acrylate or tert-butyl (meth)acrylate
Abstract
The invention discloses a kind of aqueous jet ink printing pigment ink for textile and its production methods, are mainly made of aqueous microcapsules dispersible pigment color paste, wetting agent, preservative, deionized water.Simple production process of the present invention, low in cost, energy-saving and emission-reduction are pollution-free in process, meet environmental requirement；Ink carries out cladding self-control functional high-polymer dispersing agent to the pigment ground using microcapsules technology, pigment particles secondary agglomeration is effectively prevented, so that ink has preferable dispersion stabilization and storage stability.
Description
Technical field
The present invention relates to a kind of textile inks, and in particular to a kind of aqueous jet ink printing pigment ink for textile and its life
Production method.
Background technique
Digital ink jet printing technology is a kind of completely new textile printing technology, controls sprayed printed system by computer, will be black
Water is directly injected to the fabric surfaces such as cotton, fiber crops, silk, chemical fibre, to print off various patterns and decorative pattern.With Conventional decal technology phase
Have that high production efficiency, product quality are high, low energy consumption, pollution is small, can arbitrarily produce in batches than, digital dyestuff jet printing technique
Five big features.
Ink-jet printing ink is one of important content of Digital ink jet printing technology, as other stamp modes, ink-jet
Printing ink is the main consumable material of digital inking printing production.The exploitation of ink-jet printing ink has become spray at present
Ink-printed technology develops essential component part, becomes the research hotspot of weaving fine chemical fields.Ink-jet printed ink
Water is generally made of pigment, water, organic solvent and additive (such as moisturizer, dispersing agent, pH adjusting agent, fungicide), with
Paper is compared with ink-jet printing ink, fabric ink-jet printing ink in addition to pigment purity, insoluble solid grain diameter with
And viscosity, surface tension, conductivity, stability, pH value and foaming characteristic of ink etc. have except specific requirement, also require ink
Being ejected on fabric after forming pattern has the color fastness such as good water resistance, rub resistance, and cannot influence PRINTED FABRIC
Feel.
Digital ink-jet fabric printing ink can be divided into water-based ink and solvent type according to solvent used in ink is prepared
Ink, the former is referred to as ink, and the latter is frequently referred to ink.In terms of the trend of development, ink-jet printing ink is nearly all aqueous
, this not only conforms with environmental requirement, also complies with the basic demand of printing in textiles.It is ink-jet printed according to the pigment classification used
Ink can be divided into dye ink and paint ink.Dye ink is that dyestuff after purification is dissolved or dispersed in water, and adds
The auxiliary agents such as corresponding solvent, preservative are added to be formulated.Paint ink be first need by pigment grind at partial size 50~
Molecule within the scope of 200nm, and be dispersed stably in corresponding water-based system；Secondly, pigment is modified or
Pigment color fixing agent is added in the ink, enables to anchor on fiber after ink-jet printed, obtains decalcomania enough
Water resistance and the color fastness such as rub resistance.Pigment is to any fiber all without affinity, that is to say, that pigment itself cannot on
It contaminates, anchor on any general fibre.Application of the pigment in printing in textiles and dyeing mainly makes its fixation by adhesive
On fiber.It is different from dyestuff, pigment to fiber without selectivity, by adhesive pigment can more than contaminate any fiber.
Due to the These characteristics of pigment, compared with dye ink, paint ink has the advantage that 1, it is general to have to different fibers
Property.Different fibers is needed using different dye inks, and paint ink is suitable for various fabrics.2, technique for applying
Simply.Paint ink is applied to textile ink-jet stamp and does not need complicated pre-treatment and aftertreatment technology, directly carries out to fabric
It is ink-jet printed, it then only needs simply to bake.3, without sewage discharge is conducive to protect environment.After ink-jet printed by
Fixation, pigment will not generate loose colour on fiber, therefore, there is no need to be washed as dye ink to remove loose colour.4,
Fastness to light is good.It is not to be present on fiber with the state of fine particle, therefore not after paint ink is ejected on fabric
It is easy to be dispersed after illumination, even if the molecule of particle outer layer, by photodegradation, internal layer can equally keep color.And dye ink
It is then different, in ink injection to fiber after, they are with existing for molecular state or more open aggregation, so being easy
It is decomposed by illumination.Compared with dye ink, paint ink is by small pigment particles in fiber surface display color.Cause
This, the color representation power of paint ink is poor compared with dye ink, and after the fastness to rubbing of paint ink and stamp fabric hand
Feel also poor.This is one of the key technical problem that paint ink needs further to solve.
Summary of the invention
The purpose of the present invention is to provide a kind of aqueous jet ink printing pigment ink for textile of favorable working performance and its
Production method.
The technical solution of the invention is as follows:
A kind of aqueous jet ink printing pigment ink for textile, it is characterized in that: mainly by following weight percents at being grouped as:
Aqueous microcapsules dispersible pigment color paste 10~60%
Wetting agent 5~25%
Preservative 0.1~1%
Deionized water 30~80%；
The aqueous microcapsules dispersible pigment color paste is by following weight percents at being grouped as:
Pigment 1~50%
Macromolecule dispersing agent 1~20%
Aqueous organic solvent 5~30%
Surfactant 0.5~5%
Deionized water 20~80%；
The macromolecule dispersing agent is the terpolymer of styrene, butyl acrylate, maleic acid, and average molecular weight exists
Between 2000~20000.
Pigment is one or more of following kinds mixture:
Red pigment: C.I. paratonere 1, C.I. paratonere 2, C.I. pigment red 3, C.I. paratonere 5, C.I. paratonere 7,
C.I. paratonere 17, C.I. paratonere 22, C.I. paratonere 23, C.I. pigment red 31, C.I. pigment red 38, C.I. paratonere
48:2, C.I. pigment red 4 8:3, C.I. pigment red 4 8:4, C.I. paratonere 53:1, C.I. paratonere 60:1, C.I. paratonere
63:2, C.I. pigment red 81, C.I. pigment Red 83, C.I. pigment Red 88, C.I. Pigment Red 92, C.I. paratonere 105, C.I.
Pigment red 112, C.I. pigment red 122, C.I. paratonere 166, C.I. paratonere 168, C.I. paratonere 177, C.I. pigment
Red 178, C.I. paratonere 193, C.I. paratonere 209, C.I. pigment red 21 9；
Yellow uitramarine: C.I. pigment yellow 1, C.I. pigment yellow 3, C.I. pigment Yellow 12, C.I. pigment yellow 13, C.I. pigment yellow 17,
C.I. pigment yellow 23, C.I. pigment yellow 24, C.I. pigment yellow 34, C.I. pigment yellow 37, C.I. pigment yellow 42, C.I. pigment yellow
53, C.I. pigment yellow 55, C.I. pigment yellow 81, C.I. pigment yellow 83, C.I. pigment yellow 95, C.I. pigment yellow 97, C.I. pigment
Yellow 98, C.I. pigment yellow 100, C.I. pigment yellow 101, C.I. pigment yellow 104, C.I. pigment yellow 108, C.I. pigment yellow 110；
Blue pigment: C.I. pigment blue 1, C.I. pigment blue 2, C.I. pigment blue 15, C.I. pigment blue 15: 1, C.I. pigment blue
15:2, C.I. pigment blue 15: 3, C.I. pigment blue 15: 4, C.I. pigment blue 15: 5, C.I. pigment blue 15: 6, C.I. pigment blue
16, C.I. pigment blue 1 7:1, C.I. pigment blue 56, C.I. pigment blue 60, C.I. pigment blue 63, C.I. pigment blue 75；
Black pigment: C.I. pigment black 1, C.I. pigment black 6, C.I. pigment black 7, C.I. pigment black 11, C.I. pigment black 13,
C.I. pigment black 15, C.I. pigment black 32.
Aqueous organic solvent is acetone, butanone, 2-Pyrrolidone, n-methyl-2-pyrrolidone, methanol, ethyl alcohol, positive third
Alcohol, isopropanol, n-butanol, ethylene glycol monomethyl ether, ethylene glycol ethyl ether, butyl glycol ether, diethylene glycol dimethyl ether, diethylene glycol ether,
Butyl, triethylene glycol methyl ether, propylene glycol monomethyl ether, propylene-glycol ethyl ether, propandiol butyl ether, dipropylene glycol methyl ether, 3 third
One or more of glycol methyl ether mixture.
Surfactant is potassium oleate, sodium abietate, lauryl sodium sulfate, dodecyl sodium sulfate, detergent alkylate
Sodium sulfonate, Tween60, Tween65, Tween80, Tween85, Span40, Span60, Span80, is put down at Negel
Flat plus A-10, peregal O-25, peregal os-15, SG-10, LAE-9, OP-7, OP-10, OP-20, OE-15, SE-10,
One or more of DC-150 mixture.
Wetting agent be ethylene glycol, 1,3-PD, 1,4-butanediol, 1,6- hexylene glycol, diethylene glycol, dipropylene glycol,
Triethylene-glycol, tripropylene glycol, polyethylene glycol 200, polyethylene glycol 400, Macrogol 600, glycerine, in season four amylalcohol
One or more of mixtures.
Preservative is sodium benzoate, potassium sorbate, phenol, penta sodium pentachlorophenate, nisin, lysozyme, natamycin
One or more of mixture.
PH adjusting agent is one or more of trimethylamine, triethylamine, triethanolamine, aniline, ammonium hydroxide mixture.
2~10mPaS of ink viscosity, 25~35mN/m of surface tension, 50~150nm of partial size, pH value 7~10.
A kind of production method of aqueous jet ink printing pigment ink for textile, it is characterized in that: first by 1~50wt% face
Material, 1~20wt% macromolecule dispersing agent, 5~30wt% aqueous organic solvent, 0.5~5wt% surfactant, 20~
After the mixing of 80wt% deionized water, after stirring 15~45min on blender with the speed of 200~2000r/min, sand is utilized
Grinding machine grinds 60~300min, obtains the aqueous microcapsules dispersible pigment color paste of 50~200nm of partial size；Take that 10~60wt%'s is aqueous
Microcapsules dispersible pigment color paste is added 5~25wt% wetting agent, 0.1~1wt% preservative, 30~80wt% deionized water, uses pH
Regulator adjusts pH value 7~10；After 0.5~1 μm of micropore filtering film filtering, aqueous jet stamp used for textiles is obtained
Paint ink.
The terpolymer preparation method of the styrene, butyl acrylate, maleic acid:
First by 10~20 parts by weight of styrene, 5~20 parts by weight propylene acid butyl esters, 10-30 parts by weight maleic acid, 30~
70 parts by weight butanone wiring solution-formings, are added the above-mentioned solution of 1/3~2/3 weight in the reactor, and stirring is warming up to 40 DEG C~65
DEG C, 0.1~2 parts by weight dibenzoyl peroxide and remaining solution is added dropwise, after 1~2 hour is added dropwise, insulation reaction 1~
5 hours, lye is added and adjusts pH value to distilling off solvent at 7.0~9.0,80 DEG C, obtains milky white liquid.
Beneficial effects of the present invention: ink simple production process, low in cost, energy-saving and emission-reduction are without dirt in process
Dye, meets environmental requirement；Ink carries out cladding self-control functional high-polymer point to the pigment ground using microcapsules technology
Powder is effectively prevented pigment particles secondary agglomeration, so that ink has preferable dispersion stabilization and storage stability；Ink
Production makes pigment nanosizing with polishing, solves the problems, such as jetting stability, does not occur blocking spray head phenomenon in use process；Ink
Water can not only disperse pigment particles using homemade functional high-polymer dispersing agent, and have functionalization effect, can make to wrap
Pigment particles after covering have self-crosslinking effect, are used for textile printing, can get preferable color fastness and excellent feel.
Below with reference to embodiment, the invention will be further described.
Specific embodiment
Embodiment 1: the preparation method of red ink
By 20wt%C.I. pigment red 122,5wt% macromolecule dispersing agent-styrene, butyl acrylate, maleic acid three
Membered copolymer (average molecular weight 5400), 15wt% ethylene glycol monomethyl ether and 5wt% ethyl alcohol, 1wt%OP-7,55wt% deionization
After water mixing, after stirring 15min on blender with the speed of 2000r/min, 150min is ground using sand mill, is put down
The aqueous microcapsules dispersible pigment color paste of equal partial size 125nm.
The aqueous microcapsules dispersible pigment color paste of 25wt% is taken, 10wt% diethylene glycol, 5wt% glycerine, 0.2wt% is added
Penta sodium pentachlorophenate, 59.8wt% deionized water, adjusting pH value with triethanolamine is 9~10；It is filtered using 1 μm of micropore filtering film
Afterwards, aqueous jet ink printing pigment ink for textile is obtained.
Prepared red ink viscosity 3.37mPaS, surface tension 29.5mN/m, partial size 127nm.
The terpolymer preparation method of above-mentioned styrene, butyl acrylate, maleic acid:
First 20 parts by weight of styrene, 5 parts by weight propylene acid butyl esters, 30 parts by weight maleic acids, 45 parts by weight butanone are made into
1/3 (weight) in solution A is added in solution A in the reactor, and stirring is warming up to 50 DEG C, and 2 parts by weight diphenyl peroxide first are added dropwise
Acyl and remaining solution after 2 hours are added dropwise, insulation reaction 2 hours, are added lye and adjust pH value to distilling at 8.0,80 DEG C
Solvent out obtains the terpolymer of average molecular weight 5400.
The preparation method of 2 yellow ink of embodiment
By 10wt%C.I. pigment yellow 110,2.5wt% macromolecule dispersing agent-styrene, butyl acrylate, maleic acid
Terpolymer (average molecular weight 11400), 15wt%2- pyrrolidones, 0.5wt% peregal A-10,72wt% deionization
After water mixing, after stirring 15min on blender with the speed of 1000r/min, 60min is ground using sand mill, obtains partial size
The aqueous microcapsules dispersible pigment color paste of 89nm.
The aqueous microcapsules dispersible pigment color paste of 50wt% is taken, 5wt% polyethylene glycol 200,3wt% ethylene glycol, 0.6wt% is added
Potassium sorbate, 41.4wt% deionized water adjust pH value 7~8 with ammonium hydroxide；After 0.5 μm of micropore filtering film filtering, obtain
Aqueous jet ink printing pigment ink for textile.
Prepared yellow ink viscosity 4.86mPaS, surface tension 31.5mN/m, partial size 88nm.
The terpolymer preparation method of above-mentioned styrene, butyl acrylate, maleic acid:
First 15 parts by weight of styrene, 15 parts by weight propylene acid butyl esters, 30 parts by weight maleic acids, 40 parts by weight butanone are matched
At solution A, be added 2/3 weight of solution A in the reactor, stirring is warming up to 65 DEG C, 0.5 parts by weight dibenzoyl peroxide and
Remaining solution A after 1 hour is added dropwise, insulation reaction 5 hours, is added lye and adjusts pH value to distilling out at 9.0,80 DEG C
Solvent obtains the terpolymer of average molecular weight 11400.
The preparation method of 3 blue ink of embodiment
By 50wt%C.I. pigment blue 56,10wt% macromolecule dispersing agent-styrene, butyl acrylate, maleic acid three
Membered copolymer (average molecular weight 7200), 10wt% n-butanol and 5wt% tripropylene glycol methyl ether, 2wt%Tween 65,
After the mixing of 23wt% deionized water, after stirring 45min on blender with the speed of 4000r/min, ground using sand mill
300min obtains the aqueous microcapsules dispersible pigment color paste of partial size 97nm.
It takes the aqueous microcapsules dispersible pigment color paste of 10wt%, is added four amylalcohol of 12wt% season, 7wt%1,3-propanediol,
0.1wt% lysozyme, 70.9wt% deionized water adjust pH value 9~10 with triethylamine；Use 0.8 μm of micropore filtering film mistake
After filter, aqueous jet ink printing pigment ink for textile is obtained.
Prepared blue ink viscosity 2.69mPaS, surface tension 29.3mN/m, partial size 93nm.
The terpolymer preparation method of above-mentioned styrene, butyl acrylate, maleic acid:
First 20 parts by weight of styrene, 20 parts by weight propylene acid butyl esters, 30 parts by weight maleic acids, 30 parts by weight butanone are made into
2/3 weight of solution is added in solution A in the reactor, and stirring is warming up to 65 DEG C, 1.5 parts by weight dibenzoyl peroxides and surplus
Remaining solution, after 2 hours are added dropwise, insulation reaction 4 hours, lye is added, and to adjust pH value molten to distilling out at 7.0,80 DEG C
Agent obtains the terpolymer of average molecular weight 7200.
The preparation method of 4 black ink of embodiment
Make 20wt%C.I. pigment black 7,5wt% by oneself functional high-polymer dispersing agent-styrene, butyl acrylate, maleic
The terpolymer (average molecular weight 6600) of diacid, 8wt% methanol and 8wt% acetone, 4wt%DC-150,55wt% go from
After sub- water mixing, after stirring 30min on blender with the speed of 1000r/min, 300min is ground using sand mill, is obtained
The aqueous microcapsules dispersible pigment color paste of partial size 150nm.
The aqueous microcapsules dispersible pigment color paste of 25wt% is taken, 9wt%1,6- hexylene glycol, 7wt% glycerine, 0.3wt% is added
Nisin, 58.7wt% deionized water adjust pH value 7~8 with triethanolamine；It is filtered using 1 μm of micropore filtering film
Afterwards, aqueous jet ink printing pigment ink for textile is obtained.
Prepared black ink viscosity 3.24mPaS, surface tension 28.5mN/m, partial size 142nm.
The terpolymer preparation method of above-mentioned styrene, butyl acrylate, maleic acid:
First 10 parts by weight of styrene, 10 parts by weight propylene acid butyl esters, 10 parts by weight maleic acids, 70 parts by weight butanone are made into
1/3 weight in solution is added in solution in the reactor, and stirring is warming up to 45 DEG C, 0.1 parts by weight dibenzoyl peroxide and surplus
Remaining solution, after 1 hour is added dropwise, insulation reaction 1 hour, lye is added, and to adjust pH value molten to distilling out at 8.0,80 DEG C
Agent obtains the terpolymer of average molecular weight 6600.
Embodiment 5:
First 1~50wt% (example 1%, 25%, 50%) pigment, 1~20wt% (example 1%, 10%, 20%) macromolecule are dispersed
Agent, 5~30wt% (example 5%, 15%, 30%) aqueous organic solvent, 0.5~5wt% (example 1%, 2%, 5%) surface-active
After agent, the mixing of 20~80wt% (example 20%, 50%, 80%) deionized water, with the speed of 200~2000r/min on blender
After 15~45min of degree stirring, 60~300min is ground using sand mill, obtains the aqueous microcapsules face of 50~200nm of partial size
Expect mill base；The aqueous microcapsules dispersible pigment color paste of 10~60wt% (example 10%, 30%, 60%) is taken, 5~25wt% (example is added
5%, 15%, 25%) wetting agent, 0.1~1wt% (example 0.1%, 0.5%, 1%) preservative, 30~80wt% (example 30%,
50%, 80%) deionized water adjusts pH value 7~10 with pH adjusting agent；After 0.5~1 μm of micropore filtering film filtering,
Obtain aqueous jet ink printing pigment ink for textile.
Pigment is one or more of following kinds mixture:
Red pigment: C.I. paratonere 1, C.I. paratonere 2, C.I. pigment red 3, C.I. paratonere 5, C.I. paratonere 7,
C.I. paratonere 17, C.I. paratonere 22, C.I. paratonere 23, C.I. pigment red 31, C.I. pigment red 38, C.I. paratonere
48:2, C.I. pigment red 4 8:3, C.I. pigment red 4 8:4, C.I. paratonere 53:1, C.I. paratonere 60:1, C.I. paratonere
63:2, C.I. pigment red 81, C.I. pigment Red 83, C.I. pigment Red 88, C.I. Pigment Red 92, C.I. paratonere 105, C.I.
Pigment red 112, C.I. pigment red 122, C.I. paratonere 166, C.I. paratonere 168, C.I. paratonere 177, C.I. pigment
Red 178, C.I. paratonere 193, C.I. paratonere 209, C.I. pigment red 21 9；
Yellow uitramarine: C.I. pigment yellow 1, C.I. pigment yellow 3, C.I. pigment Yellow 12, C.I. pigment yellow 13, C.I. pigment yellow 17,
C.I. pigment yellow 23, C.I. pigment yellow 24, C.I. pigment yellow 34, C.I. pigment yellow 37, C.I. pigment yellow 42, C.I. pigment yellow
53, C.I. pigment yellow 55, C.I. pigment yellow 81, C.I. pigment yellow 83, C.I. pigment yellow 95, C.I. pigment yellow 97, C.I. pigment
Huang 98, C.I. pigment yellow 100, C.I. pigment yellow 101, C.I. pigment yellow 104, C.I. pigment yellow 108, C.I. pigment yellow 110,
C.I. pigment yellow 117, C.I. pigment Yellow 12 0, C.I. pigment yellow 13 8, C.I. pigment yellow 153；
Blue pigment: C.I. pigment blue 1, C.I. pigment blue 2, C.I. pigment blue 15, C.I. pigment blue 15: 1, C.I. pigment blue
15:2, C.I. pigment blue 15: 3, C.I. pigment blue 15: 4, C.I. pigment blue 15: 5, C.I. pigment blue 15: 6, C.I. pigment blue
16, C.I. pigment blue 1 7:1, C.I. pigment blue 56, C.I. pigment blue 60, C.I. pigment blue 63, C.I. pigment blue 75；
Black pigment: C.I. pigment black 1, C.I. pigment black 6, C.I. pigment black 7, C.I. pigment black 11, C.I. pigment black 13,
C.I. pigment black 15, C.I. pigment black 32.
Aqueous organic solvent is acetone, butanone, 2-Pyrrolidone, n-methyl-2-pyrrolidone, methanol, ethyl alcohol, positive third
Alcohol, isopropanol, n-butanol, ethylene glycol monomethyl ether, ethylene glycol ethyl ether, butyl glycol ether, diethylene glycol dimethyl ether, diethylene glycol ether,
Butyl, triethylene glycol methyl ether, propylene glycol monomethyl ether, propylene-glycol ethyl ether, propandiol butyl ether, dipropylene glycol methyl ether, 3 third
One or more of glycol methyl ether mixture.
Surfactant is potassium oleate, sodium abietate, lauryl sodium sulfate, dodecyl sodium sulfate, detergent alkylate
Sodium sulfonate, Tween60, Tween65, Tween80, Tween85, Span40, Span60, Span80, is put down at Negel
Flat plus A-10, peregal O-25, peregal os-15, SG-10, LAE-9, OP-7, OP-10, OP-20, OE-15, SE-10,
One or more of DC-150 mixture.
Wetting agent be ethylene glycol, 1,3-PD, 1,4-butanediol, 1,6- hexylene glycol, diethylene glycol, dipropylene glycol,
Triethylene-glycol, tripropylene glycol, polyethylene glycol 200, polyethylene glycol 400, Macrogol 600, glycerine, in season four amylalcohol
One or more of mixtures.
Preservative is sodium benzoate, potassium sorbate, phenol, penta sodium pentachlorophenate, nisin, lysozyme, natamycin
One or more of mixture.
PH adjusting agent is one or more of trimethylamine, triethylamine, triethanolamine, aniline, ammonium hydroxide mixture.
2~10mPaS of ink viscosity, 25~35mN/m of surface tension, 50~150nm of partial size, pH value 7~10.
The terpolymer preparation method of the styrene, butyl acrylate, maleic acid:
First by 10~20 parts by weight (10 parts by weight of example, 15 parts by weight, 20 parts by weight) styrene, 5~20 parts by weight (5 weight of example
Part, 13 parts by weight, 20 parts by weight) butyl acrylate, 10-30 parts by weight (10 parts by weight of example, 20 parts by weight, 30 parts by weight) are suitable
Butene dioic acid, 30~70 parts by weight (30 parts by weight of example, 50 parts by weight, 70 parts by weight) butanone wiring solution-forming, in the reactor
The above-mentioned solution of 1/3~2/3 weight is added, stirring is warming up to 40 DEG C~65 DEG C, and 0.1~2 parts by weight (0.1 weight of example is added dropwise
Part, 1 parts by weight, 2 parts by weight) dibenzoyl peroxide and remaining solution, after 1~2 hour is added dropwise, insulation reaction 1~5
Hour, lye is added and adjusts pH value to distilling off solvent at 7.0~9.0,80 DEG C, obtains milky white liquid (terpolymer),
Average molecular weight is between 2000~20000.
The above described is only a preferred embodiment of the present invention, be not intended to limit the present invention in any form, though
So the present invention has been disclosed as a preferred embodiment, and however, it is not intended to limit the invention, any technology people for being familiar with this profession
Member, without departing from the scope of the present invention, when the technology contents using the disclosure above make a little change or modification
It is right according to the technical essence of the invention for the equivalent embodiment of equivalent variations, but without departing from the technical solutions of the present invention
Any simple modification, equivalent change and modification made by above embodiments, all of which are still within the scope of the technical scheme of the invention.
Claims (9)
1. a kind of aqueous jet ink printing pigment ink for textile, it is characterized in that: mainly by following weight percents at grouping
At:
Aqueous microcapsules dispersible pigment color paste 10~60%
Wetting agent 5~25%
Preservative 0.1~1%
Deionized water 30~80%；
The aqueous microcapsules dispersible pigment color paste is by following weight percents at being grouped as:
Pigment 1~50%
Macromolecule dispersing agent 1~20%
Aqueous organic solvent 5~30%
Surfactant 0.5~5%
Deionized water 20~80%；
The macromolecule dispersing agent is the terpolymer of styrene, butyl acrylate, maleic acid, and average molecular weight exists
Between 2000~20000.
2. aqueous jet ink printing pigment ink for textile according to claim 1, it is characterized in that: pigment is following kinds
One or more of mixture: red pigment: C.I. paratonere 1, C.I. paratonere 2, C.I. pigment red 3, C.I. paratonere
5, C.I. paratonere 7, C.I. paratonere 17, C.I. paratonere 22, C.I. paratonere 23, C.I. pigment red 31, C.I. pigment
Red 38, C.I. pigment red 4 8:2, C.I. pigment red 4 8:3, C.I. pigment red 4 8:4, C.I. paratonere 53:1, C.I. paratonere
60:1, C.I. paratonere 63:2, C.I. pigment red 81, C.I. pigment 83, C.I. pigment 88, C.I. Pigment Red 92, C.I. pigment
Red 105, C.I. pigment red 112, C.I. pigment red 122, C.I. paratonere 166, C.I. paratonere 168, C.I. paratonere 177,
C.I. paratonere 178, C.I. paratonere 193, C.I. paratonere 209, C.I. pigment red 21 9；Yellow uitramarine: C.I. pigment yellow
1, C.I. pigment yellow 3, C.I. pigment Yellow 12, C.I. pigment yellow 13, C.I. pigment yellow 17, C.I. pigment yellow 23, C.I. pigment yellow
24, C.I. pigment yellow 34, C.I. pigment yellow 37, C.I. pigment yellow 42, C.I. pigment yellow 53, C.I. pigment yellow 55, C.I. pigment
Yellow 81, C.I. pigment yellow 83, C.I. pigment yellow 95, C.I. pigment yellow 97, C.I. pigment yellow 98, C.I. pigment yellow 100, C.I.
Pigment yellow 101, C.I. pigment yellow 104, C.I. pigment yellow 108, C.I. pigment yellow 110, C.I. pigment yellow 117, C.I. pigment yellow
120, C.I. pigment yellow 13 8, C.I. pigment yellow 153；Blue pigment: C.I. pigment blue 1, C.I. pigment blue 2, C.I. pigment blue
15, C.I. pigment blue 15: 1, C.I. pigment blue 15: 2, C.I. pigment blue 15: 3, C.I. pigment blue 15: 4, C.I. pigment blue 15:
5, C.I. pigment blue 15: 6, C.I. pigment blue 16, C.I. pigment blue 1 7:1, C.I. pigment blue 56, C.I. pigment blue 60, C.I.
Pigment blue 63, C.I. pigment blue 75；Black pigment: C.I. pigment black 1, C.I. pigment black 6, C.I. pigment black 7, C.I. pigment
Black 11, C.I. pigment black 13, C.I. pigment black 15, C.I. pigment black 32.
3. aqueous jet ink printing pigment ink for textile according to claim 1 or 2, it is characterized in that: aqueous organic molten
Agent is acetone, butanone, 2-Pyrrolidone, n-methyl-2-pyrrolidone, methanol, ethyl alcohol, normal propyl alcohol, isopropanol, n-butanol, second
Glycol methyl ether, ethylene glycol ethyl ether, butyl glycol ether, diethylene glycol dimethyl ether, diethylene glycol ether, butyl, three second two
One of alcohol methyl ether, propylene glycol monomethyl ether, propylene-glycol ethyl ether, propandiol butyl ether, dipropylene glycol methyl ether, tripropylene glycol methyl ether or
Several mixtures.
4. aqueous jet ink printing pigment ink for textile according to claim 1 or 2, it is characterized in that: surfactant
It is potassium oleate, sodium abietate, lauryl sodium sulfate, dodecyl sodium sulfate, neopelex, alkyl naphthalene sulfonic acid
It is sodium, Tween60, Tween 65, Tween 80, Tween 85, Span40, Span 60, Span 80, peregal A-10, average
Add one of O-25, peregal os-15, SG-10, LAE-9, OP-7, OP-10, OP-20, OE-15, SE-10, DC-150 or
Several mixtures.
5. aqueous jet ink printing pigment ink for textile according to claim 1 or 2, it is characterized in that: wetting agent is second
Glycol, 1,3-PD, 1,4-butanediol, 1,6- hexylene glycol, diethylene glycol, dipropylene glycol, triethylene-glycol, 3 third
The mixing of one or more of glycol, polyethylene glycol 200, polyethylene glycol 400, Macrogol 600, glycerine, four amylalcohol of season
Object.
6. aqueous jet ink printing pigment ink for textile according to claim 1 or 2, it is characterized in that: preservative is benzene
The mixing of one or more of sodium formate, potassium sorbate, phenol, penta sodium pentachlorophenate, nisin, lysozyme, natamycin
Object.
7. aqueous jet ink printing pigment ink for textile according to claim 1 or 2, it is characterized in that: pH adjusting agent is
One or more of trimethylamine, triethylamine, triethanolamine, aniline, ammonium hydroxide mixture.
8. aqueous jet ink printing pigment ink for textile according to claim 1 or 2, it is characterized in that: ink viscosity 2~
10mPaS, 25~35mN/m of surface tension, 50~150nm of partial size, pH value 7~10.
9. a kind of production method of aqueous jet ink printing pigment ink for textile, it is characterized in that: first by 1~50wt% pigment, 1
~20wt% macromolecule dispersing agent, 5~30wt% aqueous organic solvent, 0.5~5wt% surfactant, 20~80wt% are gone
After ionized water mixing, after stirring 15~45min on blender with the speed of 200~2000r/min, ground using sand mill
60~300min obtains the aqueous microcapsules dispersible pigment color paste of 50~200nm of partial size；Take the aqueous microcapsules face of 10~60wt%
Expect mill base, 5~25wt% wetting agent, 0.1~1wt% preservative, 30~80wt% deionized water is added, is adjusted with pH adjusting agent
PH value 7~10；After 0.5~1 μm of micropore filtering film filtering, aqueous jet ink printing pigment ink for textile is obtained.
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| CN111574659A (en) * | 2020-04-17 | 2020-08-25 | 传美讯电子科技（珠海）有限公司 | Dispersant containing multi-element structure, color paste containing dispersant and UV ink jet |
| WO2022004584A1 (en) * | 2020-06-29 | 2022-01-06 | ブラザー工業株式会社 | Water-based ink for ink-jet recording and ink cartridge |
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| CN101659808A (en) * | 2009-08-25 | 2010-03-03 | 江苏格美高科技发展有限公司 | Aqueous jet ink printing pigment ink for textile and production method thereof |
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| WO2022004584A1 (en) * | 2020-06-29 | 2022-01-06 | ブラザー工業株式会社 | Water-based ink for ink-jet recording and ink cartridge |
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