CN108274589B - Method for making decorative concrete products - Google Patents
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- CN108274589B CN108274589B CN201711479021.6A CN201711479021A CN108274589B CN 108274589 B CN108274589 B CN 108274589B CN 201711479021 A CN201711479021 A CN 201711479021A CN 108274589 B CN108274589 B CN 108274589B
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- 239000004567 concrete Substances 0.000 title claims abstract description 92
- 238000000034 method Methods 0.000 title claims abstract description 21
- XLYOFNOQVPJJNP-UHFFFAOYSA-N water Substances O XLYOFNOQVPJJNP-UHFFFAOYSA-N 0.000 claims abstract description 21
- 238000004519 manufacturing process Methods 0.000 claims abstract description 9
- 238000013461 design Methods 0.000 claims abstract description 7
- 230000002745 absorbent Effects 0.000 claims abstract description 5
- 239000002250 absorbent Substances 0.000 claims abstract description 5
- 230000002209 hydrophobic effect Effects 0.000 claims abstract description 5
- 238000002360 preparation method Methods 0.000 claims description 4
- 239000011248 coating agent Substances 0.000 abstract description 4
- 238000000576 coating method Methods 0.000 abstract description 4
- 239000012528 membrane Substances 0.000 abstract description 3
- 238000005406 washing Methods 0.000 abstract description 2
- 238000002715 modification method Methods 0.000 abstract 1
- 239000004568 cement Substances 0.000 description 9
- 238000010521 absorption reaction Methods 0.000 description 6
- 239000007788 liquid Substances 0.000 description 5
- 229920006378 biaxially oriented polypropylene Polymers 0.000 description 4
- 239000011127 biaxially oriented polypropylene Substances 0.000 description 4
- 230000000052 comparative effect Effects 0.000 description 4
- 238000010276 construction Methods 0.000 description 4
- 238000005034 decoration Methods 0.000 description 4
- 230000000694 effects Effects 0.000 description 4
- 238000005516 engineering process Methods 0.000 description 4
- 239000011436 cob Substances 0.000 description 3
- 238000009792 diffusion process Methods 0.000 description 3
- 239000004698 Polyethylene Substances 0.000 description 2
- 239000005025 cast polypropylene Substances 0.000 description 2
- 239000003795 chemical substances by application Substances 0.000 description 2
- 238000011156 evaluation Methods 0.000 description 2
- 235000013312 flour Nutrition 0.000 description 2
- 238000013508 migration Methods 0.000 description 2
- 230000005012 migration Effects 0.000 description 2
- 238000007639 printing Methods 0.000 description 2
- 239000011398 Portland cement Substances 0.000 description 1
- 229910000831 Steel Inorganic materials 0.000 description 1
- 230000003796 beauty Effects 0.000 description 1
- 230000009286 beneficial effect Effects 0.000 description 1
- 238000005530 etching Methods 0.000 description 1
- 238000002474 experimental method Methods 0.000 description 1
- 238000012423 maintenance Methods 0.000 description 1
- 239000000463 material Substances 0.000 description 1
- 238000000465 moulding Methods 0.000 description 1
- 239000002245 particle Substances 0.000 description 1
- 239000011505 plaster Substances 0.000 description 1
- 239000004033 plastic Substances 0.000 description 1
- 229920003023 plastic Polymers 0.000 description 1
- -1 polyethylene Polymers 0.000 description 1
- 229920000573 polyethylene Polymers 0.000 description 1
- 230000000979 retarding effect Effects 0.000 description 1
- 239000004576 sand Substances 0.000 description 1
- 238000007650 screen-printing Methods 0.000 description 1
- 239000010959 steel Substances 0.000 description 1
- 239000004575 stone Substances 0.000 description 1
- 238000010998 test method Methods 0.000 description 1
- 238000012546 transfer Methods 0.000 description 1
- 238000010023 transfer printing Methods 0.000 description 1
- 230000000007 visual effect Effects 0.000 description 1
- 239000002699 waste material Substances 0.000 description 1
Classifications
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- B—PERFORMING OPERATIONS; TRANSPORTING
- B28—WORKING CEMENT, CLAY, OR STONE
- B28B—SHAPING CLAY OR OTHER CERAMIC COMPOSITIONS; SHAPING SLAG; SHAPING MIXTURES CONTAINING CEMENTITIOUS MATERIAL, e.g. PLASTER
- B28B7/00—Moulds; Cores; Mandrels
- B28B7/0064—Moulds characterised by special surfaces for producing a desired surface of a moulded article, e.g. profiled or polished moulding surfaces
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- B—PERFORMING OPERATIONS; TRANSPORTING
- B28—WORKING CEMENT, CLAY, OR STONE
- B28B—SHAPING CLAY OR OTHER CERAMIC COMPOSITIONS; SHAPING SLAG; SHAPING MIXTURES CONTAINING CEMENTITIOUS MATERIAL, e.g. PLASTER
- B28B11/00—Apparatus or processes for treating or working the shaped or preshaped articles
- B28B11/002—Apparatus for washing concrete for decorative purposes or similar surface treatments for exposing the texture
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- Engineering & Computer Science (AREA)
- Chemical & Material Sciences (AREA)
- Ceramic Engineering (AREA)
- Mechanical Engineering (AREA)
- Manufacturing & Machinery (AREA)
- Structural Engineering (AREA)
- Producing Shaped Articles From Materials (AREA)
- Devices For Post-Treatments, Processing, Supply, Discharge, And Other Processes (AREA)
- Moulds, Cores, Or Mandrels (AREA)
Abstract
Description
技术领域technical field
本发明涉及一种混凝土装饰技术领域,具体涉及一种装饰混凝土制品的制作方法。The invention relates to the technical field of concrete decoration, in particular to a manufacturing method of a decorative concrete product.
背景技术Background technique
混凝土问世的近两百年来,在大多数情况下都是以其高强度、廉价耐用等优势发展的。似乎混凝土本身没有装饰效果,要用瓷砖、石膏等材料将它掩盖起来,建筑物才完整。如果混凝土本身有装饰性,那么可以节省建筑物表面施工、装潢的费用,而且有一种原汁原味、顺其自然的美感。In the nearly two hundred years since the advent of concrete, in most cases, it has been developed with its advantages of high strength, low cost and durability. It seems that the concrete itself has no decorative effect. It needs to be covered up with materials such as tiles and plaster to make the building complete. If the concrete itself is decorative, it can save the cost of building surface construction and decoration, and it has an original and natural beauty.
基于此状况,有人开始使用清水混凝土。清水混凝土是一种将混凝土成型后直接裸露出来作为装饰面的混凝土。它不用做任何外饰,混凝土本身就是装饰。这可以说是一大飞跃。但清水混凝土对于施工要求特别是养护要求比较高,比如,同一工程中须保持水泥用同一炉烧制,以保持水泥的颜色一致。砂、石场须单独保护起来,保证其品质稳定。清水混凝土的养护过程同样严格,否则极易引起混凝土表面出现色差。所以,总的来说,我国现有的施工背景很难大范围推广清水混凝土。还有人开始使用其他的装饰混凝土。但目前的水泥装饰面板,其形状、样式的变化,主要依靠混凝土模具的形状变化来实现。模具有钢模、木模、塑料模等,花样繁多。该做法的特点是要想得到不同图案的混凝土,就要有不同图案的模具。显然这样的工艺成本高、难量产、周期长、浪费大。这也是它未能在国内推广的原因。Based on this situation, some people began to use fair-faced concrete. Fair-faced concrete is a kind of concrete in which concrete is directly exposed as a decorative surface after molding. It doesn't need any exterior decoration, the concrete itself is the decoration. This can be said to be a big leap. However, fair-faced concrete has relatively high requirements for construction, especially maintenance. For example, in the same project, the cement must be fired in the same furnace to keep the color of the cement consistent. Sand and stone fields must be protected separately to ensure stable quality. The curing process of fair-faced concrete is also strict, otherwise it is easy to cause color difference on the surface of the concrete. Therefore, in general, my country's existing construction background is difficult to promote fair-faced concrete on a large scale. Others are starting to use other decorative concretes. But the current cement decorative panel, the change of its shape and style, mainly depends on the shape change of the concrete mold. There are steel molds, wooden molds, plastic molds, etc., and there are many patterns. The characteristic of this method is that in order to obtain concrete of different patterns, it is necessary to have molds of different patterns. Obviously, such a process has high cost, difficult mass production, long cycle and large waste. This is also the reason why it has not been promoted in the country.
基于此状况,有报导利用转印技术来做混凝土饰面。其转印技术是通过将缓凝剂印在PVA基膜上实现的。而包括该文献列举出的示例在内,缓凝剂通常为水剂,而这样的液态缓凝剂通过丝网印刷印在基膜上以后,在混凝土浇筑和振捣过程中都会改变液态缓凝剂在混凝土上形成的图案,缓凝剂极其容易发生扩散、迁移、改变形状,导致局部缓凝剂的量不够,不能起到缓凝效果,无法得到图案,或者缓凝剂迁移或改变形状,而直接导致最后的图案变形,影响图案的精细程度。Based on this situation, it is reported that the use of transfer printing technology to do concrete veneer. Its transfer technology is realized by printing the retarder on the PVA base film. Including the examples listed in this document, the retarder is usually a water agent, and after such a liquid retarder is printed on the base film by screen printing, the liquid retarder will change during the concrete pouring and vibrating process. The pattern formed by the agent on the concrete, the retarder is extremely easy to diffuse, migrate and change shape, resulting in insufficient local retarder, unable to achieve the retarding effect, unable to obtain the pattern, or the retarder migrates or changes shape, It directly leads to the deformation of the final pattern, which affects the fineness of the pattern.
发明内容SUMMARY OF THE INVENTION
本发明的目的是为了解决上述技术问题,提供一种工艺极为简单、易于操作、图案成型精度高的装饰混凝土制品的制作方法。The purpose of the present invention is to solve the above-mentioned technical problems, and to provide a method for making decorative concrete products with extremely simple process, easy operation and high pattern forming precision.
技术方案包括以下步骤:The technical solution includes the following steps:
a、制备混凝土装饰纸:在纸的一面全覆膜,另一面按设计图案部分覆膜,得到混凝土装饰纸;所述纸为吸水纸,所述膜为疏水膜;a. Preparation of concrete decorative paper: one side of the paper is fully covered with film, and the other side is partially covered with a film according to the design pattern to obtain concrete decorative paper; the paper is absorbent paper, and the film is a hydrophobic film;
b、铺好混凝土装饰纸:将混凝土装饰纸平铺在模具底部,使具有图案的膜的一面朝上;b. Lay the concrete decorative paper: lay the concrete decorative paper on the bottom of the mold, so that the side of the film with the pattern is facing up;
c、浇筑混凝土:在模具中浇筑混凝土;c, pouring concrete: pouring concrete in the mold;
d、养护并拆模:养护、硬化后拆模得到混凝土制品;d. Curing and demoulding: After curing and hardening, demolding is done to obtain concrete products;
e、揭开混凝土装饰纸:从混凝土制品表面撕下混凝土装饰纸;e. Uncover the concrete decorative paper: tear off the concrete decorative paper from the surface of the concrete product;
f、水冲洗:用水冲洗撕下混凝土装饰纸的混凝土制品表面,使部分骨料露出,在混凝土制品表面得到图案。f. Rinse with water: Rinse the surface of the concrete product with the concrete decorative paper torn off with water, so that part of the aggregate is exposed, and a pattern is obtained on the surface of the concrete product.
所述纸的Cobb值为15~400g/m2。The Cobb value of the paper is 15 to 400 g/m 2 .
所述纸的Cobb值最优为30~300g/m2。The Cobb value of the paper is optimally 30-300 g/m 2 .
所述纸的厚度为0.02~0.5mm。The thickness of the paper is 0.02-0.5 mm.
所述膜的厚度为0.005mm~0.030mm。The thickness of the film is 0.005 mm to 0.030 mm.
针对背景技术中存在的问题,发明人创造性的改变思维方式,巧妙的利用纸和膜的结合来解决上述技术问题,其机理是在纸的一面全覆膜,另一面按设计图案覆膜,使具有图案的膜的一面朝上,浇筑混凝土后,使得混凝土处于部分与膜接触,部分与纸直接接触的状态,由于纸具有吸水性,会吸收与纸接触的水泥层中的水分,导致该区域内的水层泥水灰比降低而无法凝结;而与膜接触的其它区域的混凝土水泥层则能正常凝结,脱模后用水冲洗,未凝结部分的水泥层被冲下,露出骨料,其他区域未露出骨料,产生视觉对比形成图案。本发明方法中,彻底抛弃了使用缓凝剂及涂覆印刷技术的惯常思维,巧妙的利纸的吸水原理,不仅大大降低了操作难度和生产成本,也解决了涂覆液态缓凝剂存在的扩散、迁移、改变形状等问题。In view of the problems existing in the background technology, the inventor creatively changed the way of thinking, and skillfully used the combination of paper and film to solve the above-mentioned technical problems. The side of the film with the pattern is facing up. After the concrete is poured, the concrete is partially in contact with the film and partially in direct contact with the paper. Since the paper is absorbent, it will absorb the water in the cement layer in contact with the paper. The cement-water-cement ratio of the water layer in the area is reduced and cannot be coagulated; while the concrete cement layer in other areas in contact with the membrane can be coagulated normally. After demoulding, rinse with water, and the cement layer in the uncondensed part is washed down, exposing the aggregate, other Areas with no exposed aggregates create visual contrast to form patterns. In the method of the present invention, the conventional thinking of using retarder and coating and printing technology is completely abandoned, and the ingenious water absorption principle of paper not only greatly reduces the operation difficulty and production cost, but also solves the problem of coating liquid retarder. Diffusion, migration, changing shape, etc.
进一步的,优选纸的吸水性Cobb值为15~400g/m2,更为优选30~300g/m2,过高会导致纸吸水过多,混凝土图案部分过深影响美观和精细程度,过低会导致纸吸水过少,图案部分难以与非图案部分形成对比,影响图案精细程度,甚至无法形成图案。所述纸的厚度优选为0.02mm~0.5mm,过高会导致纸吸水性太强,最终影响混凝土图案的精细程度,过低会导致纸吸水性太弱,最终使得混凝土无法形成图案。所述膜为疏水膜,例如BOPP(双向拉伸聚丙烯薄膜)或BOPP/PE(聚乙烯)或BOPP/CPP(流延聚丙烯);Further, the water absorption Cobb value of the paper is preferably 15-400 g/m 2 , more preferably 30-300 g/m 2 , too high will cause the paper to absorb too much water, and the concrete pattern will be too deep to affect the appearance and fineness, and too low. It will cause the paper to absorb too little water, making it difficult for the pattern part to contrast with the non-pattern part, affecting the fineness of the pattern, and even failing to form a pattern. The thickness of the paper is preferably 0.02 mm to 0.5 mm. Too high a thickness will result in too strong water absorption of the paper, which will ultimately affect the fineness of the concrete pattern. Too low a thickness will result in too weak water absorption of the paper, which will ultimately make the concrete unable to form a pattern. The film is a hydrophobic film, such as BOPP (biaxially oriented polypropylene film) or BOPP/PE (polyethylene) or BOPP/CPP (cast polypropylene);
有益效果:Beneficial effects:
本发明方法工艺方法极为简单、构思巧妙,利用纸的吸水性能吸收浇注混凝土水泥层的水分使水泥层无法凝结,从而可以在混凝土制品脱膜后方便的用水冲洗形成图案,整个工艺操作难度低、生产周期短、生产成本低,能够在混凝土上形成线条清晰准确、蚀深度均匀的图案,具有广阔的市场前景。The method of the invention is extremely simple and ingenious in design. The water absorption property of the paper is used to absorb the water of the poured concrete cement layer, so that the cement layer cannot be coagulated, so that the pattern can be easily formed by washing with water after the concrete product is released from the film. The production cycle is short, the production cost is low, and the pattern with clear and accurate lines and uniform etching depth can be formed on the concrete, which has a broad market prospect.
具体实施方式Detailed ways
工艺实施例:Process example:
a、制备混凝土装饰纸:在纸的一面全覆膜,另一面按设计图案部分覆膜,得到混凝土装饰纸;所述纸为吸水纸,所述膜为疏水膜;a. Preparation of concrete decorative paper: one side of the paper is fully covered with film, and the other side is partially covered with a film according to the design pattern to obtain concrete decorative paper; the paper is absorbent paper, and the film is a hydrophobic film;
b、铺好混凝土装饰纸:将混凝土装饰纸平铺在模具底部,使具有图案的膜的一面朝上;b. Lay the concrete decorative paper: lay the concrete decorative paper on the bottom of the mold, so that the side of the film with the pattern is facing up;
c、浇筑混凝土:在模具中浇筑混凝土;c, pouring concrete: pouring concrete in the mold;
d、养护并拆模:养护、硬化后拆模得到混凝土制品;d. Curing and demoulding: After curing and hardening, demolding is done to obtain concrete products;
e、揭开混凝土装饰纸:从混凝土制品表面撕下混凝土装饰纸;e. Uncover the concrete decorative paper: tear off the concrete decorative paper from the surface of the concrete product;
f、水冲洗:用水冲洗撕下混凝土装饰纸的混凝土制品表面,使部分骨料露出,在混凝土制品表面得到图案。f. Rinse with water: Rinse the surface of the concrete product with the concrete decorative paper torn off with water, so that part of the aggregate is exposed, and a pattern is obtained on the surface of the concrete product.
上述工艺步骤中混凝土使用了强度等级不低于42.5级的普通硅酸盐水泥。In the above process steps, ordinary Portland cement with a strength grade of not less than 42.5 is used for the concrete.
为量化最终的图案效果,将测试最终混凝土表面图案与原始图案的变化率。具体做法是将干面粉颗粒填涂在图案区域,将非图案区域的面粉除去,使得图案区域呈白色,非图案区域呈现混凝土的灰色。此时对混凝土进行拍照,用计算机软件处理图形,与原始图像对比,得出图形变化率。To quantify the final pattern effect, the rate of change of the final concrete surface pattern from the original pattern is tested. The specific method is to fill the pattern area with dry flour particles, and remove the flour in the non-pattern area, so that the pattern area is white, and the non-pattern area is concrete gray. At this time, take pictures of the concrete, process the graphics with computer software, and compare with the original images to obtain the graphics change rate.
实施例1-9的工艺步骤同上,其中吸水率、纸厚和膜厚及制品成形图案效果评价见表1:The process steps of embodiment 1-9 are the same as above, wherein water absorption, paper thickness and film thickness and product forming pattern effect evaluation are shown in Table 1:
表1混凝土装饰纸的特征和装饰混凝土的图案效果Table 1 Characteristics of concrete decorative paper and pattern effect of decorative concrete
比较例:Comparative example:
将单面覆膜的铜版纸的覆膜面按图案印上液态缓凝剂,覆膜面朝上,其余同上述步骤制得装饰混凝土,经过多次实验,最后得到混凝土图案变形无法辨别,扩散情况严重,深度不一致,用相同测试方法测定的图案变化率平均值为89%,指标不满足设计要求。The coated surface of the single-sided coated coated paper is printed with liquid retarder according to the pattern, and the coated surface is facing up. The rest are the same as the above steps to prepare decorative concrete. After many experiments, it is finally obtained that the deformation of the concrete pattern cannot be distinguished and diffuse The situation is serious and the depth is inconsistent. The average pattern change rate measured by the same test method is 89%, and the index does not meet the design requirements.
结果评价:经过上述工序,本实施例中最后得到混凝土图案清晰精细,无扩散情况,深度较一致,指标满足设计要求。而比较例中的液体缓凝剂由于无法成膜,不仅使施工工艺难度增加,也难以避免出现扩散、迁移和图案面积改变、深度不均的问题发生。综合实施例1~9和比较例两者图案变化率比较,实施例的图案变化率较比较例降低80%,亦即精细程度大大提高。Evaluation of results: After the above procedures, the concrete pattern obtained in this example is clear and fine, without diffusion, the depth is relatively consistent, and the indicators meet the design requirements. However, the liquid retarder in the comparative example cannot form a film, which not only increases the difficulty of the construction process, but also makes it difficult to avoid the occurrence of problems such as diffusion, migration, change of pattern area, and uneven depth. Comprehensively comparing the pattern change rates of Examples 1 to 9 and the Comparative Example, the pattern change rate of the Example is 80% lower than that of the Comparative Example, that is, the degree of fineness is greatly improved.
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Citations (6)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
JPH1136580A (en) * | 1997-07-24 | 1999-02-09 | Tokai Rubber Ind Ltd | Sheet for exposing pattern by washing uncured concrete |
JP2003080513A (en) * | 2001-09-13 | 2003-03-19 | Tokai Rubber Ind Ltd | Method for manufacturing concrete product with patterned surface and exposed aggregate finish design panel to be used for this method |
CN106116690A (en) * | 2015-06-23 | 2016-11-16 | 德国莱利化工科技有限公司 | Erosion slow setting facing art transfer film washed by concrete |
CN106393395A (en) * | 2016-09-22 | 2017-02-15 | 黄贺明 | Manufacturing method for concrete decorative hanging plate |
CN206128529U (en) * | 2016-09-30 | 2017-04-26 | 上海鼎中新材料有限公司 | Cement base concrete decorative board is with convenient shaping membrane of three -dimensional morals and manners veneer |
CN107128117A (en) * | 2017-06-21 | 2017-09-05 | 中民筑友科技投资有限公司 | The preparation method that a kind of band undisguisedly expects the decorative panel of pattern |
-
2017
- 2017-12-29 CN CN201711479021.6A patent/CN108274589B/en active Active
Patent Citations (6)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
JPH1136580A (en) * | 1997-07-24 | 1999-02-09 | Tokai Rubber Ind Ltd | Sheet for exposing pattern by washing uncured concrete |
JP2003080513A (en) * | 2001-09-13 | 2003-03-19 | Tokai Rubber Ind Ltd | Method for manufacturing concrete product with patterned surface and exposed aggregate finish design panel to be used for this method |
CN106116690A (en) * | 2015-06-23 | 2016-11-16 | 德国莱利化工科技有限公司 | Erosion slow setting facing art transfer film washed by concrete |
CN106393395A (en) * | 2016-09-22 | 2017-02-15 | 黄贺明 | Manufacturing method for concrete decorative hanging plate |
CN206128529U (en) * | 2016-09-30 | 2017-04-26 | 上海鼎中新材料有限公司 | Cement base concrete decorative board is with convenient shaping membrane of three -dimensional morals and manners veneer |
CN107128117A (en) * | 2017-06-21 | 2017-09-05 | 中民筑友科技投资有限公司 | The preparation method that a kind of band undisguisedly expects the decorative panel of pattern |
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