CN108235996A - A kind of antibacterial smelly eliminating coagulator, preparation method and its application - Google Patents
A kind of antibacterial smelly eliminating coagulator, preparation method and its application Download PDFInfo
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- A—HUMAN NECESSITIES
- A01—AGRICULTURE; FORESTRY; ANIMAL HUSBANDRY; HUNTING; TRAPPING; FISHING
- A01N—PRESERVATION OF BODIES OF HUMANS OR ANIMALS OR PLANTS OR PARTS THEREOF; BIOCIDES, e.g. AS DISINFECTANTS, AS PESTICIDES OR AS HERBICIDES; PEST REPELLANTS OR ATTRACTANTS; PLANT GROWTH REGULATORS
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- A01—AGRICULTURE; FORESTRY; ANIMAL HUSBANDRY; HUNTING; TRAPPING; FISHING
- A01N—PRESERVATION OF BODIES OF HUMANS OR ANIMALS OR PLANTS OR PARTS THEREOF; BIOCIDES, e.g. AS DISINFECTANTS, AS PESTICIDES OR AS HERBICIDES; PEST REPELLANTS OR ATTRACTANTS; PLANT GROWTH REGULATORS
- A01N33/00—Biocides, pest repellants or attractants, or plant growth regulators containing organic nitrogen compounds
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- A01N33/12—Quaternary ammonium compounds
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- C08G81/00—Macromolecular compounds obtained by interreacting polymers in the absence of monomers, e.g. block polymers
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Abstract
The present invention relates to a kind of antibacterial smelly eliminating coagulators, by weight, prepare raw material and include：80 parts of macromolecule water uptake resin, 0.1 5 parts of chlorine dioxide releasing agent, 0.1 5 parts of quaternary ammonium salt, 1 30 parts of powdered rice hulls, 0.5 15 parts of straw powder and 0.5 10 parts of probiotics.The invention further relates to the methods for preparing the antibacterial smelly eliminating coagulator.The invention further relates to application of the antibacterial smelly eliminating coagulator in industry, agricultural, health care and daily life.The antibacterial smelly eliminating coagulator of the present invention, bacteriostasis property is good, absorption speed is fast, can quick smelly eliminating and stability is strong, with very extensive market prospects.
Description
Technical field
The present invention relates to macromolecule bacteriostatic agent technical fields, and in particular to a kind of antibacterial smelly eliminating coagulator, preparation method
And its application.
Background technology
Bacteriostatic agent is widely used in industry, agricultural, health care and daily life.For example, industrially it can be used for
The additive of plastic products.In it agriculturally, may be mixed in chemical fertilizer or pesticide, to improve crop yield.In health care,
It can be used in the cleaning solution of public place, the growth inhibited bacteria, prevent bacteria breed excessive.Application in daily life
More extensively, it can add in melon and fruit cleaning agent, in indoor coating or in lavatory, especially under emergency conditions (such as
The natural calamities such as earthquake, typhoon), for handling dirty things.However, existing antiseptic one side anti-microbial property is not comprehensive, absorbs
Speed is slow and antibacterial stability is poor, and another aspect deodorization is also bad, it is difficult to meet multiduty requirement.
Hence it is highly desirable to the antibacterial smelly eliminating coagulator of the new multi-purpose for developing good combination property.
Invention content
The purpose of the present invention is exactly to provide a kind of Novel antibacterial in order to overcome above-mentioned problems of the prior art and disappear
Smelly coagulator.
Specifically, the present invention provides a kind of antibacterial smelly eliminating coagulator, by weight, prepares raw material and includes：
80 parts of macromolecule water uptake resin, 0.1-5 parts of chlorine dioxide releasing agent, 0.1-5 parts of quaternary ammonium salt, 1-30 parts
Powdered rice hulls, the probiotics of 0.5-15 parts of straw powder and 0.5-10 part；
Preferably, raw material is prepared to include：
80 parts of macromolecule water uptake resin, 1-4 parts of chlorine dioxide releasing agent, 1-4 parts of quaternary ammonium salt, 5-15 parts of rice
Shell powder, the probiotics of 1-12 parts of straw powder and 1-9 part；
Include it is highly preferred that it prepares raw material：
80 parts of macromolecule water uptake resin, 1-2 parts of chlorine dioxide releasing agent, 1-2 parts of quaternary ammonium salt, 5-12 parts of rice
Shell powder, the probiotics of 1-8 parts of straw powder and 1-5 part；
Most preferably, raw material is prepared to include：
80 parts of macromolecule water uptake resin, 1 part of chlorine dioxide releasing agent, 1 part of quaternary ammonium salt, 10 parts of powdered rice hulls, 5
The straw powder of part and 3 parts of probiotics.
In one embodiment, the macromolecule water uptake resin is selected from polyacrylate water-absorbing resins, poly- second
Enol class water-absorbing resins, polyoxygenated alkanes water-absorbing resins, sulfonated polyimide class water-absorbing resins, sulfonated polyether sulfone class
Water-absorbing resins, sulfonated poly thioether sulfone class water-absorbing resins and sulfonated poly thioether sulfone/polyvinyl alcohol compound type water absorbent resin
At least one of；Preferably, the macromolecule water uptake resin is sulfonated poly thioether sulfone/polyvinyl alcohol compound type water absorbent tree
Fat.
In one embodiment, the preparation method of the sulfonated poly thioether sulfone/polyvinyl alcohol compound type water absorbent resin
For：
(1) in the reactor, sequentially add 0.03 mole of 4'4- dimercaptos diphenyl sulfide, 0.028 mole 3,3 '-disulfonic acid
Sodium -4,4 '-dichloro diphenyl sulfone, 0.1 mole of Anhydrous potassium carbonate, 75 milliliters of dimethyl sulfoxide (DMSO)s and 25 milliliters of toluene lead to argon gas protection,
Be then heated to 150 DEG C reaction 6 hours after, be again heated to 165 DEG C reaction 10 hours after, be down to room temperature, then ice bath reactor
And concentrated hydrochloric acid is slowly added dropwise, until reaction solution is after highly acid, is poured into deionized water and methanol by weight 1 by system：1
In mixed solution, after washing three times repeatedly, dry 10h at 60 DEG C, obtains sulfonated poly thioether sulfone in vacuum drying oven；
(2) in the reactor, 10 grams of poly thioether sulfone, 3 grams of polyvinyl alcohol, deionization obtained by above-mentioned steps (1) are sequentially added
100 grams of water, 0.5 gram of potassium hydroxide, 2 grams of silane coupling agent KH-560,100 grams of dimethyl sulfoxide (DMSO) lead to argon gas protection, then will
System temperature rises to 140 DEG C, after reacting 6 hours, is down to room temperature, discharges in deionized water and methanol by weight 1：1 mixing
In solution, solid product is obtained, with deionized water and methanol by weight 1：1 mixed solution washs the solid product 3 times, most
It is dried in vacuo 24 hours at 100 DEG C afterwards, obtains the sulfonated poly thioether sulfone/polyvinyl alcohol compound type water absorbent resin.
In one embodiment, the chlorine dioxide releasing agent is sodium chlorite and the mixture of malic acid.
In one embodiment, the quaternary ammonium salt is selected from dodecyl trimethyl ammonium chloride, dodecyl dimethyl benzyl
Ammonium chloride, dodecyl dimethyl benzyl ammonium bromide, cyano quaternary ammonium salt, poly- azacyclo- quaternary ammonium salt, bi-quaternary ammonium salt and poly- season
At least one of ammonium salt.
It is preferably carried out in scheme in one kind, the quaternary ammonium salt is polyquaternium, and the preparation method of the polyquaternium is：
In the reactor, sequentially add 0.1 mole of aminopromazine, 0.1 mole to cyclite and 300 milliliters of ethyl alcohol, rise to 50 DEG C,
After reaction 10 hours, room temperature is down to, vacuum distillation removal ethyl alcohol is to get the polyquaternium.
In one embodiment, the grain size of the powdered rice hulls is 10-200 mesh；Preferably, the grain size of the powdered rice hulls is
100-150 mesh.
In one embodiment, the straw powder is selected from corn stalk powder, wheat stalk powder, rice straw powder, potato
At least one of straw powder, rape straw, cotton stalk powder and sugarcane straw powder；Preferably, the straw powder is small
Wheat Straw powder.
In one embodiment, the grain size of the straw powder is 100-300 mesh；Preferably, the grain size of the straw powder
For 150-200 mesh.
This law also provides the method for preparing the antibacterial smelly eliminating coagulator, including：
After above-mentioned raw materials component is sufficiently mixed, spray drying obtains.
This law also provides the antibacterial smelly eliminating coagulator answering in industry, agricultural, health care and daily life
With.
Specific embodiment
It elaborates below to the embodiment of the present invention, the present embodiment is carried out lower based on the technical solution of the present invention
Implement, give detailed embodiment and specific operating process, but protection scope of the present invention is not limited to following implementation
Example.
The application raw material is following (unless stated otherwise, raw material is purchased from Aladdin reagent)：
A1：Macromolecule water uptake resin SAP-50, purchased from Lip river its.
A2：(it is laughable for Japan that it prepares material polyethylene alcohol to sulfonated poly thioether sulfone/polyvinyl alcohol compound type water absorbent resin
Beautiful PVA-217)
B1：Chlorine dioxide releasing agent, i.e. sodium chlorite and malic acid are by weight 1：2 mixture.
C1：Dodecyl benzyl dimethyl ammonium chloride
C2：Dodecyl trimethyl ammonium chloride
C3：Dodecyl dimethyl benzyl ammonium bromide
C4：Poly- azacyclo- quaternary ammonium salt FP-C, by document, " the flocculation bactericidal property of poly- azacyclo- quaternary ammonium salt is studied, oil field
Learn, the 2nd phase in 1997 " it prepares
C5：Bi-quaternary ammonium salt, the double ammonium chlorides of N- cetyls trimethylene diamine
C6：Polyquaternium, preparation method are：In the reactor, 0.1 mole of aminopromazine is sequentially added, 0.1 mole
To cyclite and 300 milliliters of ethyl alcohol, rise to 50 DEG C, after reaction 10 hours, be down to room temperature, vacuum distillation removal ethyl alcohol to get
The polyquaternium
D1：Powdered rice hulls (100 mesh)
E1：Corn stalk powder (200 mesh)
E2：Rice straw powder (200 mesh)
E3：Potato straw powder (200 mesh)
E4：Rape straw (200 mesh)
E5：Cotton stalk powder (200 mesh)
E6：Wheat stalk powder (200 mesh)
F1：Probiotic powder, purchased from Guangdong long-range medicine.
Embodiment 1
In mixing machine, by weight, 80 parts of A1,0.1 part of B1,0.1 part of C1 are sequentially added, 1 part of D1,
0.5 part of E1 and 0.5 part of F1, after being then sufficiently mixed with 1000 revs/min of stir speed (S.S.), mixture is spray-dried
Obtain antibacterial smelly eliminating coagulator.
Embodiment 2
In mixing machine, by weight, 80 parts of A1,5 parts of B1,5 parts of C1 are sequentially added, 30 parts of D1,15 parts
E1 and 10 part of F1, after being then sufficiently mixed with 1000 revs/min of stir speed (S.S.), mixture is spray-dried antibacterial
Smelly eliminating coagulator.
Embodiment 3
In mixing machine, by weight, 80 parts of A1,4 parts of B1,4 parts of C1 are sequentially added, 15 parts of D1,12 parts
E1 and 9 part of F1, after being then sufficiently mixed with 1000 revs/min of stir speed (S.S.), mixture is spray-dried antibacterial
Smelly eliminating coagulator.
Embodiment 4
In mixing machine, by weight, sequentially add 80 parts of A1,2 parts of B1,2 parts of C1,12 parts of D1,8 parts
E1 and 5 part of F1 after being then sufficiently mixed with 1000 revs/min of stir speed (S.S.), mixture is spray-dried antibacterial to disappear
Smelly coagulator.
Embodiment 5
In mixing machine, by weight, sequentially add 80 parts of A1,1 part of B1,1 part of C1,10 parts of D1,5 parts
E1 and 3 part of F1 after being then sufficiently mixed with 1000 revs/min of stir speed (S.S.), mixture is spray-dried antibacterial to disappear
Smelly coagulator.
Embodiment 6
In mixing machine, by weight, 80 parts of A2,0.1 part of B1,0.1 part of C1 are sequentially added, 1 part of D1,
0.5 part of E1 and 0.5 part of F1, after being then sufficiently mixed with 1000 revs/min of stir speed (S.S.), mixture is spray-dried
Obtain antibacterial smelly eliminating coagulator；
The preparation method of A2 is：
(1) in the reactor, sequentially add 0.03 mole of 4'4- dimercaptos diphenyl sulfide, 0.028 mole 3,3 '-disulfonic acid
Sodium -4,4 '-dichloro diphenyl sulfone, 0.1 mole of Anhydrous potassium carbonate, 75 milliliters of dimethyl sulfoxide (DMSO)s and 25 milliliters of toluene lead to argon gas protection,
Be then heated to 150 DEG C reaction 6 hours after, be again heated to 165 DEG C reaction 10 hours after, be down to room temperature, then ice bath reactor
And concentrated hydrochloric acid is slowly added dropwise, until reaction solution is after highly acid, is poured into deionized water and methanol by weight 1 by system：1
In mixed solution, after washing three times repeatedly, dry 10h at 60 DEG C, obtains sulfonated poly thioether sulfone in vacuum drying oven；
(2) in the reactor, 10 grams of poly thioether sulfone, 3 grams of polyvinyl alcohol, deionization obtained by above-mentioned steps (1) are sequentially added
100 grams of water, 0.5 gram of potassium hydroxide, 2 grams of silane coupling agent KH-560,100 grams of dimethyl sulfoxide (DMSO) lead to argon gas protection, then will
System temperature rises to 140 DEG C, after reacting 6 hours, is down to room temperature, discharges in deionized water and methanol by weight 1：1 mixing
In solution, solid product is obtained, with deionized water and methanol by weight 1：1 mixed solution washs the solid product 3 times, most
It is dried in vacuo 24 hours at 100 DEG C afterwards, obtains the sulfonated poly thioether sulfone/polyvinyl alcohol compound type water absorbent resin.
Embodiment 7
In mixing machine, by weight, 80 parts of A2,5 parts of B1,5 parts of C1 are sequentially added, 30 parts of D1,15 parts
E1 and 10 part of F1, after being then sufficiently mixed with 1000 revs/min of stir speed (S.S.), mixture is spray-dried antibacterial
Smelly eliminating coagulator；
The preparation method of A2 is：
(1) in the reactor, sequentially add 0.03 mole of 4'4- dimercaptos diphenyl sulfide, 0.028 mole 3,3 '-disulfonic acid
Sodium -4,4 '-dichloro diphenyl sulfone, 0.1 mole of Anhydrous potassium carbonate, 75 milliliters of dimethyl sulfoxide (DMSO)s and 25 milliliters of toluene lead to argon gas protection,
Be then heated to 150 DEG C reaction 6 hours after, be again heated to 165 DEG C reaction 10 hours after, be down to room temperature, then ice bath reactor
And concentrated hydrochloric acid is slowly added dropwise, until reaction solution is after highly acid, is poured into deionized water and methanol by weight 1 by system：1
In mixed solution, after washing three times repeatedly, dry 10h at 60 DEG C, obtains sulfonated poly thioether sulfone in vacuum drying oven；
(2) in the reactor, 10 grams of poly thioether sulfone, 3 grams of polyvinyl alcohol, deionization obtained by above-mentioned steps (1) are sequentially added
100 grams of water, 0.5 gram of potassium hydroxide, 2 grams of silane coupling agent KH-560,100 grams of dimethyl sulfoxide (DMSO) lead to argon gas protection, then will
System temperature rises to 140 DEG C, after reacting 6 hours, is down to room temperature, discharges in deionized water and methanol by weight 1：1 mixing
In solution, solid product is obtained, with deionized water and methanol by weight 1：1 mixed solution washs the solid product 3 times, most
It is dried in vacuo 24 hours at 100 DEG C afterwards, obtains the sulfonated poly thioether sulfone/polyvinyl alcohol compound type water absorbent resin.
Embodiment 8
In mixing machine, by weight, 80 parts of A2,4 parts of B1,4 parts of C1 are sequentially added, 15 parts of D1,12 parts
E1 and 9 part of F1, after being then sufficiently mixed with 1000 revs/min of stir speed (S.S.), mixture is spray-dried antibacterial
Smelly eliminating coagulator；
The preparation method of A2 is：
(1) in the reactor, sequentially add 0.03 mole of 4'4- dimercaptos diphenyl sulfide, 0.028 mole 3,3 '-disulfonic acid
Sodium -4,4 '-dichloro diphenyl sulfone, 0.1 mole of Anhydrous potassium carbonate, 75 milliliters of dimethyl sulfoxide (DMSO)s and 25 milliliters of toluene lead to argon gas protection,
Be then heated to 150 DEG C reaction 6 hours after, be again heated to 165 DEG C reaction 10 hours after, be down to room temperature, then ice bath reactor
And concentrated hydrochloric acid is slowly added dropwise, until reaction solution is after highly acid, is poured into deionized water and methanol by weight 1 by system：1
In mixed solution, after washing three times repeatedly, dry 10h at 60 DEG C, obtains sulfonated poly thioether sulfone in vacuum drying oven；
(2) in the reactor, 10 grams of poly thioether sulfone, 3 grams of polyvinyl alcohol, deionization obtained by above-mentioned steps (1) are sequentially added
100 grams of water, 0.5 gram of potassium hydroxide, 2 grams of silane coupling agent KH-560,100 grams of dimethyl sulfoxide (DMSO) lead to argon gas protection, then will
System temperature rises to 140 DEG C, after reacting 6 hours, is down to room temperature, discharges in deionized water and methanol by weight 1：1 mixing
In solution, solid product is obtained, with deionized water and methanol by weight 1：1 mixed solution washs the solid product 3 times, most
It is dried in vacuo 24 hours at 100 DEG C afterwards, obtains the sulfonated poly thioether sulfone/polyvinyl alcohol compound type water absorbent resin.
Embodiment 9
In mixing machine, by weight, sequentially add 80 parts of A2,2 parts of B1,2 parts of C1,12 parts of D1,8 parts
E1 and 5 part of F1 after being then sufficiently mixed with 1000 revs/min of stir speed (S.S.), mixture is spray-dried antibacterial to disappear
Smelly coagulator；
The preparation method of A2 is：
(1) in the reactor, sequentially add 0.03 mole of 4'4- dimercaptos diphenyl sulfide, 0.028 mole 3,3 '-disulfonic acid
Sodium -4,4 '-dichloro diphenyl sulfone, 0.1 mole of Anhydrous potassium carbonate, 75 milliliters of dimethyl sulfoxide (DMSO)s and 25 milliliters of toluene lead to argon gas protection,
Be then heated to 150 DEG C reaction 6 hours after, be again heated to 165 DEG C reaction 10 hours after, be down to room temperature, then ice bath reactor
And concentrated hydrochloric acid is slowly added dropwise, until reaction solution is after highly acid, is poured into deionized water and methanol by weight 1 by system：1
In mixed solution, after washing three times repeatedly, dry 10h at 60 DEG C, obtains sulfonated poly thioether sulfone in vacuum drying oven；
(2) in the reactor, 10 grams of poly thioether sulfone, 3 grams of polyvinyl alcohol, deionization obtained by above-mentioned steps (1) are sequentially added
100 grams of water, 0.5 gram of potassium hydroxide, 2 grams of silane coupling agent KH-560,100 grams of dimethyl sulfoxide (DMSO) lead to argon gas protection, then will
System temperature rises to 140 DEG C, after reacting 6 hours, is down to room temperature, discharges in deionized water and methanol by weight 1：1 mixing
In solution, solid product is obtained, with deionized water and methanol by weight 1：1 mixed solution washs the solid product 3 times, most
It is dried in vacuo 24 hours at 100 DEG C afterwards, obtains the sulfonated poly thioether sulfone/polyvinyl alcohol compound type water absorbent resin.
Embodiment 10
In mixing machine, by weight, sequentially add 80 parts of A2,1 part of B1,1 part of C1,10 parts of D1,5 parts
E1 and 3 part of F1 after being then sufficiently mixed with 1000 revs/min of stir speed (S.S.), mixture is spray-dried antibacterial to disappear
Smelly coagulator；
The preparation method of A2 is：
(1) in the reactor, sequentially add 0.03 mole of 4'4- dimercaptos diphenyl sulfide, 0.028 mole 3,3 '-disulfonic acid
Sodium -4,4 '-dichloro diphenyl sulfone, 0.1 mole of Anhydrous potassium carbonate, 75 milliliters of dimethyl sulfoxide (DMSO)s and 25 milliliters of toluene lead to argon gas protection,
Be then heated to 150 DEG C reaction 6 hours after, be again heated to 165 DEG C reaction 10 hours after, be down to room temperature, then ice bath reactor
And concentrated hydrochloric acid is slowly added dropwise, until reaction solution is after highly acid, is poured into deionized water and methanol by weight 1 by system：1
In mixed solution, after washing three times repeatedly, dry 10h at 60 DEG C, obtains sulfonated poly thioether sulfone in vacuum drying oven；
(2) in the reactor, 10 grams of poly thioether sulfone, 3 grams of polyvinyl alcohol, deionization obtained by above-mentioned steps (1) are sequentially added
100 grams of water, 0.5 gram of potassium hydroxide, 2 grams of silane coupling agent KH-560,100 grams of dimethyl sulfoxide (DMSO) lead to argon gas protection, then will
System temperature rises to 140 DEG C, after reacting 6 hours, is down to room temperature, discharges in deionized water and methanol by weight 1：1 mixing
In solution, solid product is obtained, with deionized water and methanol by weight 1：1 mixed solution washs the solid product 3 times, most
It is dried in vacuo 24 hours at 100 DEG C afterwards, obtains the sulfonated poly thioether sulfone/polyvinyl alcohol compound type water absorbent resin.
Embodiment 11
In mixing machine, by weight, sequentially add 80 parts of A2,1 part of B1,1 part of C2,10 parts of D1,5 parts
E1 and 3 part of F1 after being then sufficiently mixed with 1000 revs/min of stir speed (S.S.), mixture is spray-dried antibacterial to disappear
Smelly coagulator；
The preparation method of A2 is：
(1) in the reactor, sequentially add 0.03 mole of 4'4- dimercaptos diphenyl sulfide, 0.028 mole 3,3 '-disulfonic acid
Sodium -4,4 '-dichloro diphenyl sulfone, 0.1 mole of Anhydrous potassium carbonate, 75 milliliters of dimethyl sulfoxide (DMSO)s and 25 milliliters of toluene lead to argon gas protection,
Be then heated to 150 DEG C reaction 6 hours after, be again heated to 165 DEG C reaction 10 hours after, be down to room temperature, then ice bath reactor
And concentrated hydrochloric acid is slowly added dropwise, until reaction solution is after highly acid, is poured into deionized water and methanol by weight 1 by system：1
In mixed solution, after washing three times repeatedly, dry 10h at 60 DEG C, obtains sulfonated poly thioether sulfone in vacuum drying oven；
(2) in the reactor, 10 grams of poly thioether sulfone, 3 grams of polyvinyl alcohol, deionization obtained by above-mentioned steps (1) are sequentially added
100 grams of water, 0.5 gram of potassium hydroxide, 2 grams of silane coupling agent KH-560,100 grams of dimethyl sulfoxide (DMSO) lead to argon gas protection, then will
System temperature rises to 140 DEG C, after reacting 6 hours, is down to room temperature, discharges in deionized water and methanol by weight 1：1 mixing
In solution, solid product is obtained, with deionized water and methanol by weight 1：1 mixed solution washs the solid product 3 times, most
It is dried in vacuo 24 hours at 100 DEG C afterwards, obtains the sulfonated poly thioether sulfone/polyvinyl alcohol compound type water absorbent resin.
Embodiment 12
In mixing machine, by weight, sequentially add 80 parts of A2,1 part of B1,1 part of C3,10 parts of D1,5 parts
E1 and 3 part of F1 after being then sufficiently mixed with 1000 revs/min of stir speed (S.S.), mixture is spray-dried antibacterial to disappear
Smelly coagulator；
The preparation method of A2 is：
(1) in the reactor, sequentially add 0.03 mole of 4'4- dimercaptos diphenyl sulfide, 0.028 mole 3,3 '-disulfonic acid
Sodium -4,4 '-dichloro diphenyl sulfone, 0.1 mole of Anhydrous potassium carbonate, 75 milliliters of dimethyl sulfoxide (DMSO)s and 25 milliliters of toluene lead to argon gas protection,
Be then heated to 150 DEG C reaction 6 hours after, be again heated to 165 DEG C reaction 10 hours after, be down to room temperature, then ice bath reactor
And concentrated hydrochloric acid is slowly added dropwise, until reaction solution is after highly acid, is poured into deionized water and methanol by weight 1 by system：1
In mixed solution, after washing three times repeatedly, dry 10h at 60 DEG C, obtains sulfonated poly thioether sulfone in vacuum drying oven；
(2) in the reactor, 10 grams of poly thioether sulfone, 3 grams of polyvinyl alcohol, deionization obtained by above-mentioned steps (1) are sequentially added
100 grams of water, 0.5 gram of potassium hydroxide, 2 grams of silane coupling agent KH-560,100 grams of dimethyl sulfoxide (DMSO) lead to argon gas protection, then will
System temperature rises to 140 DEG C, after reacting 6 hours, is down to room temperature, discharges in deionized water and methanol by weight 1：1 mixing
In solution, solid product is obtained, with deionized water and methanol by weight 1：1 mixed solution washs the solid product 3 times, most
It is dried in vacuo 24 hours at 100 DEG C afterwards, obtains the sulfonated poly thioether sulfone/polyvinyl alcohol compound type water absorbent resin.
Embodiment 13
In mixing machine, by weight, sequentially add 80 parts of A2,1 part of B1,1 part of C4,10 parts of D1,5 parts
E1 and 3 part of F1 after being then sufficiently mixed with 1000 revs/min of stir speed (S.S.), mixture is spray-dried antibacterial to disappear
Smelly coagulator；
The preparation method of A2 is：
(1) in the reactor, sequentially add 0.03 mole of 4'4- dimercaptos diphenyl sulfide, 0.028 mole 3,3 '-disulfonic acid
Sodium -4,4 '-dichloro diphenyl sulfone, 0.1 mole of Anhydrous potassium carbonate, 75 milliliters of dimethyl sulfoxide (DMSO)s and 25 milliliters of toluene lead to argon gas protection,
Be then heated to 150 DEG C reaction 6 hours after, be again heated to 165 DEG C reaction 10 hours after, be down to room temperature, then ice bath reactor
And concentrated hydrochloric acid is slowly added dropwise, until reaction solution is after highly acid, is poured into deionized water and methanol by weight 1 by system：1
In mixed solution, after washing three times repeatedly, dry 10h at 60 DEG C, obtains sulfonated poly thioether sulfone in vacuum drying oven；
(2) in the reactor, 10 grams of poly thioether sulfone, 3 grams of polyvinyl alcohol, deionization obtained by above-mentioned steps (1) are sequentially added
100 grams of water, 0.5 gram of potassium hydroxide, 2 grams of silane coupling agent KH-560,100 grams of dimethyl sulfoxide (DMSO) lead to argon gas protection, then will
System temperature rises to 140 DEG C, after reacting 6 hours, is down to room temperature, discharges in deionized water and methanol by weight 1：1 mixing
In solution, solid product is obtained, with deionized water and methanol by weight 1：1 mixed solution washs the solid product 3 times, most
It is dried in vacuo 24 hours at 100 DEG C afterwards, obtains the sulfonated poly thioether sulfone/polyvinyl alcohol compound type water absorbent resin.
Embodiment 14
In mixing machine, by weight, sequentially add 80 parts of A2,1 part of B1,1 part of C5,10 parts of D1,5 parts
E1 and 3 part of F1 after being then sufficiently mixed with 1000 revs/min of stir speed (S.S.), mixture is spray-dried antibacterial to disappear
Smelly coagulator；
The preparation method of A2 is：
(1) in the reactor, sequentially add 0.03 mole of 4'4- dimercaptos diphenyl sulfide, 0.028 mole 3,3 '-disulfonic acid
Sodium -4,4 '-dichloro diphenyl sulfone, 0.1 mole of Anhydrous potassium carbonate, 75 milliliters of dimethyl sulfoxide (DMSO)s and 25 milliliters of toluene lead to argon gas protection,
Be then heated to 150 DEG C reaction 6 hours after, be again heated to 165 DEG C reaction 10 hours after, be down to room temperature, then ice bath reactor
And concentrated hydrochloric acid is slowly added dropwise, until reaction solution is after highly acid, is poured into deionized water and methanol by weight 1 by system：1
In mixed solution, after washing three times repeatedly, dry 10h at 60 DEG C, obtains sulfonated poly thioether sulfone in vacuum drying oven；
(2) in the reactor, 10 grams of poly thioether sulfone, 3 grams of polyvinyl alcohol, deionization obtained by above-mentioned steps (1) are sequentially added
100 grams of water, 0.5 gram of potassium hydroxide, 2 grams of silane coupling agent KH-560,100 grams of dimethyl sulfoxide (DMSO) lead to argon gas protection, then will
System temperature rises to 140 DEG C, after reacting 6 hours, is down to room temperature, discharges in deionized water and methanol by weight 1：1 mixing
In solution, solid product is obtained, with deionized water and methanol by weight 1：1 mixed solution washs the solid product 3 times, most
It is dried in vacuo 24 hours at 100 DEG C afterwards, obtains the sulfonated poly thioether sulfone/polyvinyl alcohol compound type water absorbent resin.
Embodiment 15
In mixing machine, by weight, sequentially add 80 parts of A2,1 part of B1,1 part of C6,10 parts of D1,5 parts
E1 and 3 part of F1 after being then sufficiently mixed with 1000 revs/min of stir speed (S.S.), mixture is spray-dried antibacterial to disappear
Smelly coagulator；
The preparation method of A2 is：
(1) in the reactor, sequentially add 0.03 mole of 4'4- dimercaptos diphenyl sulfide, 0.028 mole 3,3 '-disulfonic acid
Sodium -4,4 '-dichloro diphenyl sulfone, 0.1 mole of Anhydrous potassium carbonate, 75 milliliters of dimethyl sulfoxide (DMSO)s and 25 milliliters of toluene lead to argon gas protection,
Be then heated to 150 DEG C reaction 6 hours after, be again heated to 165 DEG C reaction 10 hours after, be down to room temperature, then ice bath reactor
And concentrated hydrochloric acid is slowly added dropwise, until reaction solution is after highly acid, is poured into deionized water and methanol by weight 1 by system：1
In mixed solution, after washing three times repeatedly, dry 10h at 60 DEG C, obtains sulfonated poly thioether sulfone in vacuum drying oven；
(2) in the reactor, 10 grams of poly thioether sulfone, 3 grams of polyvinyl alcohol, deionization obtained by above-mentioned steps (1) are sequentially added
100 grams of water, 0.5 gram of potassium hydroxide, 2 grams of silane coupling agent KH-560,100 grams of dimethyl sulfoxide (DMSO) lead to argon gas protection, then will
System temperature rises to 140 DEG C, after reacting 6 hours, is down to room temperature, discharges in deionized water and methanol by weight 1：1 mixing
In solution, solid product is obtained, with deionized water and methanol by weight 1：1 mixed solution washs the solid product 3 times, most
It is dried in vacuo 24 hours at 100 DEG C afterwards, obtains the sulfonated poly thioether sulfone/polyvinyl alcohol compound type water absorbent resin.
Embodiment 16
In mixing machine, by weight, sequentially add 80 parts of A2,1 part of B1,1 part of C6,10 parts of D1,5 parts
E2 and 3 part of F1 after being then sufficiently mixed with 1000 revs/min of stir speed (S.S.), mixture is spray-dried antibacterial to disappear
Smelly coagulator；
The preparation method of A2 is：
(1) in the reactor, sequentially add 0.03 mole of 4'4- dimercaptos diphenyl sulfide, 0.028 mole 3,3 '-disulfonic acid
Sodium -4,4 '-dichloro diphenyl sulfone, 0.1 mole of Anhydrous potassium carbonate, 75 milliliters of dimethyl sulfoxide (DMSO)s and 25 milliliters of toluene lead to argon gas protection,
Be then heated to 150 DEG C reaction 6 hours after, be again heated to 165 DEG C reaction 10 hours after, be down to room temperature, then ice bath reactor
And concentrated hydrochloric acid is slowly added dropwise, until reaction solution is after highly acid, is poured into deionized water and methanol by weight 1 by system：1
In mixed solution, after washing three times repeatedly, dry 10h at 60 DEG C, obtains sulfonated poly thioether sulfone in vacuum drying oven；
(2) in the reactor, 10 grams of poly thioether sulfone, 3 grams of polyvinyl alcohol, deionization obtained by above-mentioned steps (1) are sequentially added
100 grams of water, 0.5 gram of potassium hydroxide, 2 grams of silane coupling agent KH-560,100 grams of dimethyl sulfoxide (DMSO) lead to argon gas protection, then will
System temperature rises to 140 DEG C, after reacting 6 hours, is down to room temperature, discharges in deionized water and methanol by weight 1：1 mixing
In solution, solid product is obtained, with deionized water and methanol by weight 1：1 mixed solution washs the solid product 3 times, most
It is dried in vacuo 24 hours at 100 DEG C afterwards, obtains the sulfonated poly thioether sulfone/polyvinyl alcohol compound type water absorbent resin.
Embodiment 17
In mixing machine, by weight, sequentially add 80 parts of A2,1 part of B1,1 part of C6,10 parts of D1,5 parts
E3 and 3 part of F1 after being then sufficiently mixed with 1000 revs/min of stir speed (S.S.), mixture is spray-dried antibacterial to disappear
Smelly coagulator；
The preparation method of A2 is：
(1) in the reactor, sequentially add 0.03 mole of 4'4- dimercaptos diphenyl sulfide, 0.028 mole 3,3 '-disulfonic acid
Sodium -4,4 '-dichloro diphenyl sulfone, 0.1 mole of Anhydrous potassium carbonate, 75 milliliters of dimethyl sulfoxide (DMSO)s and 25 milliliters of toluene lead to argon gas protection,
Be then heated to 150 DEG C reaction 6 hours after, be again heated to 165 DEG C reaction 10 hours after, be down to room temperature, then ice bath reactor
And concentrated hydrochloric acid is slowly added dropwise, until reaction solution is after highly acid, is poured into deionized water and methanol by weight 1 by system：1
In mixed solution, after washing three times repeatedly, dry 10h at 60 DEG C, obtains sulfonated poly thioether sulfone in vacuum drying oven；
(2) in the reactor, 10 grams of poly thioether sulfone, 3 grams of polyvinyl alcohol, deionization obtained by above-mentioned steps (1) are sequentially added
100 grams of water, 0.5 gram of potassium hydroxide, 2 grams of silane coupling agent KH-560,100 grams of dimethyl sulfoxide (DMSO) lead to argon gas protection, then will
System temperature rises to 140 DEG C, after reacting 6 hours, is down to room temperature, discharges in deionized water and methanol by weight 1：1 mixing
In solution, solid product is obtained, with deionized water and methanol by weight 1：1 mixed solution washs the solid product 3 times, most
It is dried in vacuo 24 hours at 100 DEG C afterwards, obtains the sulfonated poly thioether sulfone/polyvinyl alcohol compound type water absorbent resin.
Embodiment 18
In mixing machine, by weight, sequentially add 80 parts of A2,1 part of B1,1 part of C6,10 parts of D1,5 parts
E4 and 3 part of F1 after being then sufficiently mixed with 1000 revs/min of stir speed (S.S.), mixture is spray-dried antibacterial to disappear
Smelly coagulator；
The preparation method of A2 is：
(1) in the reactor, sequentially add 0.03 mole of 4'4- dimercaptos diphenyl sulfide, 0.028 mole 3,3 '-disulfonic acid
Sodium -4,4 '-dichloro diphenyl sulfone, 0.1 mole of Anhydrous potassium carbonate, 75 milliliters of dimethyl sulfoxide (DMSO)s and 25 milliliters of toluene lead to argon gas protection,
Be then heated to 150 DEG C reaction 6 hours after, be again heated to 165 DEG C reaction 10 hours after, be down to room temperature, then ice bath reactor
And concentrated hydrochloric acid is slowly added dropwise, until reaction solution is after highly acid, is poured into deionized water and methanol by weight 1 by system：1
In mixed solution, after washing three times repeatedly, dry 10h at 60 DEG C, obtains sulfonated poly thioether sulfone in vacuum drying oven；
(2) in the reactor, 10 grams of poly thioether sulfone, 3 grams of polyvinyl alcohol, deionization obtained by above-mentioned steps (1) are sequentially added
100 grams of water, 0.5 gram of potassium hydroxide, 2 grams of silane coupling agent KH-560,100 grams of dimethyl sulfoxide (DMSO) lead to argon gas protection, then will
System temperature rises to 140 DEG C, after reacting 6 hours, is down to room temperature, discharges in deionized water and methanol by weight 1：1 mixing
In solution, solid product is obtained, with deionized water and methanol by weight 1：1 mixed solution washs the solid product 3 times, most
It is dried in vacuo 24 hours at 100 DEG C afterwards, obtains the sulfonated poly thioether sulfone/polyvinyl alcohol compound type water absorbent resin.
Embodiment 19
In mixing machine, by weight, sequentially add 80 parts of A2,1 part of B1,1 part of C6,10 parts of D1,5 parts
E5 and 3 part of F1 after being then sufficiently mixed with 1000 revs/min of stir speed (S.S.), mixture is spray-dried antibacterial to disappear
Smelly coagulator；
The preparation method of A2 is：
(1) in the reactor, sequentially add 0.03 mole of 4'4- dimercaptos diphenyl sulfide, 0.028 mole 3,3 '-disulfonic acid
Sodium -4,4 '-dichloro diphenyl sulfone, 0.1 mole of Anhydrous potassium carbonate, 75 milliliters of dimethyl sulfoxide (DMSO)s and 25 milliliters of toluene lead to argon gas protection,
Be then heated to 150 DEG C reaction 6 hours after, be again heated to 165 DEG C reaction 10 hours after, be down to room temperature, then ice bath reactor
And concentrated hydrochloric acid is slowly added dropwise, until reaction solution is after highly acid, is poured into deionized water and methanol by weight 1 by system：1
In mixed solution, after washing three times repeatedly, dry 10h at 60 DEG C, obtains sulfonated poly thioether sulfone in vacuum drying oven；
(2) in the reactor, 10 grams of poly thioether sulfone, 3 grams of polyvinyl alcohol, deionization obtained by above-mentioned steps (1) are sequentially added
100 grams of water, 0.5 gram of potassium hydroxide, 2 grams of silane coupling agent KH-560,100 grams of dimethyl sulfoxide (DMSO) lead to argon gas protection, then will
System temperature rises to 140 DEG C, after reacting 6 hours, is down to room temperature, discharges in deionized water and methanol by weight 1：1 mixing
In solution, solid product is obtained, with deionized water and methanol by weight 1：1 mixed solution washs the solid product 3 times, most
It is dried in vacuo 24 hours at 100 DEG C afterwards, obtains the sulfonated poly thioether sulfone/polyvinyl alcohol compound type water absorbent resin.
Embodiment 20
In mixing machine, by weight, sequentially add 80 parts of A2,1 part of B1,1 part of C6,10 parts of D1,5 parts
E6 and 3 part of F1 after being then sufficiently mixed with 1000 revs/min of stir speed (S.S.), mixture is spray-dried antibacterial to disappear
Smelly coagulator；
The preparation method of A2 is：
(1) in the reactor, sequentially add 0.03 mole of 4'4- dimercaptos diphenyl sulfide, 0.028 mole 3,3 '-disulfonic acid
Sodium -4,4 '-dichloro diphenyl sulfone, 0.1 mole of Anhydrous potassium carbonate, 75 milliliters of dimethyl sulfoxide (DMSO)s and 25 milliliters of toluene lead to argon gas protection,
Be then heated to 150 DEG C reaction 6 hours after, be again heated to 165 DEG C reaction 10 hours after, be down to room temperature, then ice bath reactor
And concentrated hydrochloric acid is slowly added dropwise, until reaction solution is after highly acid, is poured into deionized water and methanol by weight 1 by system：1
In mixed solution, after washing three times repeatedly, dry 10h at 60 DEG C, obtains sulfonated poly thioether sulfone in vacuum drying oven；
(2) in the reactor, 10 grams of poly thioether sulfone, 3 grams of polyvinyl alcohol, deionization obtained by above-mentioned steps (1) are sequentially added
100 grams of water, 0.5 gram of potassium hydroxide, 2 grams of silane coupling agent KH-560,100 grams of dimethyl sulfoxide (DMSO) lead to argon gas protection, then will
System temperature rises to 140 DEG C, after reacting 6 hours, is down to room temperature, discharges in deionized water and methanol by weight 1：1 mixing
In solution, solid product is obtained, with deionized water and methanol by weight 1：1 mixed solution washs the solid product 3 times, most
It is dried in vacuo 24 hours at 100 DEG C afterwards, obtains the sulfonated poly thioether sulfone/polyvinyl alcohol compound type water absorbent resin.
The antibacterial smelly eliminating coagulator of above-described embodiment 1-20 is tested, it is as a result as shown in table 1 below.
Smelly eliminating measure of merit：The antibacterial smelly eliminating coagulator of above-described embodiment 1-20 is applied in slop, is handled
After 30min, smelly eliminating effect is judged using human body method of testing, specially：100 smell test teachers are employed, are sentenced according to smell
Whether the processed above-mentioned slop that breaks is still odorous, according to the quantity for judging odorous test teacher, judges smelly eliminating etc.
Grade.It is specifically divided into 5 grades：
1 grade：Judge that the quantity of odorous test teacher is more than 70 people.2 grades：Judge that the odorous quantity for testing teacher is
40-70 people.3 grades：Judge the quantity of odorous test teacher for 10-39 people.4 grades：Judge that the odorous quantity for testing teacher is
5-9 people.5 grades：Judge that the quantity of odorous test teacher is less than 5 people.
Although specific embodiments of the present invention have been described above, it will be appreciated by those of skill in the art that these
It is merely illustrative of, protection scope of the present invention is defined by the appended claims.Those skilled in the art is not carrying on the back
Under the premise of from the principle and substance of the present invention, many changes and modifications may be made, but these are changed
Protection scope of the present invention is each fallen with modification.
Claims (10)
1. a kind of antibacterial smelly eliminating coagulator, which is characterized in that by weight, prepare raw material and include：
80 parts of macromolecule water uptake resin, 0.1-5 parts of chlorine dioxide releasing agent, 0.1-5 parts of quaternary ammonium salt, 1-30 parts of rice
Shell powder, 0.5-15 parts of straw powder and 0.5-10 parts of probiotics.
2. antibacterial smelly eliminating coagulator according to claim 1, which is characterized in that the macromolecule water uptake resin is selected from poly-
Acrylates water-absorbing resins, polyvinyl alcohol water-absorbing resins, polyoxygenated alkanes water-absorbing resins, sulfonated polyimide
Class water-absorbing resins, sulfonated polyether sulfone class water-absorbing resins, sulfonated poly thioether sulfone class water-absorbing resins and sulfonated poly thioether sulfone/
At least one of polyvinyl alcohol compound type water absorbent resin.
3. antibacterial smelly eliminating coagulator according to claim 2, which is characterized in that the sulfonated poly thioether sulfone/polyvinyl alcohol
The preparation method of compound type water absorbent resin is：
(1) in the reactor, sequentially add 0.03 mole of 4'4- dimercaptos diphenyl sulfide, 0.028 mole 3,3 '-sodium disulfonate-
4,4 '-dichloro diphenyl sulfone, 0.1 mole of Anhydrous potassium carbonate, 75 milliliters of dimethyl sulfoxide (DMSO)s and 25 milliliters of toluene lead to argon gas protection, so
After be heated to 150 DEG C of reactions 6 hours after, after being again heated to 165 DEG C of reactions 10 hours, be down to room temperature, then ice bath reactor is simultaneously
Concentrated hydrochloric acid is slowly added dropwise, until reaction solution is after highly acid, is poured into deionized water and methanol by weight 1 by system：1 it is mixed
It closes in solution, after washing three times repeatedly, dry 10h at 60 DEG C, obtains sulfonated poly thioether sulfone in vacuum drying oven；
(2) in the reactor, 10 grams of poly thioether sulfone, 3 grams of polyvinyl alcohol, deionized water 100 obtained by above-mentioned steps (1) are sequentially added
Gram, 0.5 gram of potassium hydroxide, 2 grams of silane coupling agent KH-560,100 grams of dimethyl sulfoxide (DMSO), lead to argon gas protection, then by system temperature
Degree rises to 140 DEG C, after reacting 6 hours, is down to room temperature, discharges in deionized water and methanol by weight 1：In 1 mixed solution,
Solid product is obtained, with deionized water and methanol by weight 1：1 mixed solution washs the solid product 3 times, finally 100
It is dried in vacuo 24 hours at DEG C, obtains the sulfonated poly thioether sulfone/polyvinyl alcohol compound type water absorbent resin.
4. antibacterial smelly eliminating coagulator according to claim 1 or 2, which is characterized in that the chlorine dioxide releasing agent is Asia
The mixture of sodium chlorate and malic acid.
5. antibacterial smelly eliminating coagulator according to claim 1 or 2, which is characterized in that the quaternary ammonium salt is selected from dodecyl
Trimethyl ammonium chloride, dodecyl dimethyl benzyl ammonium bromide, cyano quaternary ammonium salt, gathers dodecyl benzyl dimethyl ammonium chloride
At least one of azacyclo- quaternary ammonium salt, bi-quaternary ammonium salt and polyquaternium.
6. antibacterial smelly eliminating coagulator according to claim 1 or 2, which is characterized in that the grain size of the powdered rice hulls is 10-
200 mesh.
7. antibacterial smelly eliminating coagulator according to claim 1 or 2, which is characterized in that the straw powder is selected from maize straw
In powder, wheat stalk powder, rice straw powder, potato straw powder, rape straw, cotton stalk powder and sugarcane straw powder extremely
Few one kind.
8. antibacterial smelly eliminating coagulator according to claim 6, which is characterized in that the grain size of the straw powder is 100-300
Mesh.
9. the method for the antibacterial smelly eliminating coagulator according to any one of claim 1-8 is prepared, including：
After raw material components in any one of claim 1-8 are sufficiently mixed, spray drying obtains.
10. the antibacterial smelly eliminating coagulator described in any one of claim 1-8 is in industry, agricultural, health care and daily life
Application in work.
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| CN113458120A (en) * | 2021-07-06 | 2021-10-01 | 天津开通科技有限公司 | Solidified bactericide for liquid and solid-liquid mixed waste |
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