CN108231905A - A kind of preparation method of laser treatment amorphous oxide thin film transistor - Google Patents

A kind of preparation method of laser treatment amorphous oxide thin film transistor Download PDF

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Publication number
CN108231905A
CN108231905A CN201711323516.XA CN201711323516A CN108231905A CN 108231905 A CN108231905 A CN 108231905A CN 201711323516 A CN201711323516 A CN 201711323516A CN 108231905 A CN108231905 A CN 108231905A
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thin film
amorphous oxide
film transistor
amorphous
oxide thin
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宁洪龙
刘贤哲
姚日晖
邓宇熹
邓培淼
章红科
周尚雄
袁炜健
吴为敬
彭俊彪
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South China University of Technology SCUT
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South China University of Technology SCUT
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    • HELECTRICITY
    • H01ELECTRIC ELEMENTS
    • H01LSEMICONDUCTOR DEVICES NOT COVERED BY CLASS H10
    • H01L29/00Semiconductor devices specially adapted for rectifying, amplifying, oscillating or switching and having potential barriers; Capacitors or resistors having potential barriers, e.g. a PN-junction depletion layer or carrier concentration layer; Details of semiconductor bodies or of electrodes thereof ; Multistep manufacturing processes therefor
    • H01L29/66Types of semiconductor device ; Multistep manufacturing processes therefor
    • H01L29/66007Multistep manufacturing processes
    • H01L29/66969Multistep manufacturing processes of devices having semiconductor bodies not comprising group 14 or group 13/15 materials
    • HELECTRICITY
    • H01ELECTRIC ELEMENTS
    • H01LSEMICONDUCTOR DEVICES NOT COVERED BY CLASS H10
    • H01L21/00Processes or apparatus adapted for the manufacture or treatment of semiconductor or solid state devices or of parts thereof
    • H01L21/02Manufacture or treatment of semiconductor devices or of parts thereof
    • H01L21/04Manufacture or treatment of semiconductor devices or of parts thereof the devices having potential barriers, e.g. a PN junction, depletion layer or carrier concentration layer
    • H01L21/34Manufacture or treatment of semiconductor devices or of parts thereof the devices having potential barriers, e.g. a PN junction, depletion layer or carrier concentration layer the devices having semiconductor bodies not provided for in groups H01L21/0405, H01L21/0445, H01L21/06, H01L21/16 and H01L21/18 with or without impurities, e.g. doping materials
    • H01L21/42Bombardment with radiation
    • H01L21/423Bombardment with radiation with high-energy radiation
    • H01L21/428Bombardment with radiation with high-energy radiation using electromagnetic radiation, e.g. laser radiation
    • HELECTRICITY
    • H01ELECTRIC ELEMENTS
    • H01LSEMICONDUCTOR DEVICES NOT COVERED BY CLASS H10
    • H01L29/00Semiconductor devices specially adapted for rectifying, amplifying, oscillating or switching and having potential barriers; Capacitors or resistors having potential barriers, e.g. a PN-junction depletion layer or carrier concentration layer; Details of semiconductor bodies or of electrodes thereof ; Multistep manufacturing processes therefor
    • H01L29/66Types of semiconductor device ; Multistep manufacturing processes therefor
    • H01L29/68Types of semiconductor device ; Multistep manufacturing processes therefor controllable by only the electric current supplied, or only the electric potential applied, to an electrode which does not carry the current to be rectified, amplified or switched
    • H01L29/76Unipolar devices, e.g. field effect transistors
    • H01L29/772Field effect transistors
    • H01L29/78Field effect transistors with field effect produced by an insulated gate
    • H01L29/786Thin film transistors, i.e. transistors with a channel being at least partly a thin film
    • H01L29/7869Thin film transistors, i.e. transistors with a channel being at least partly a thin film having a semiconductor body comprising an oxide semiconductor material, e.g. zinc oxide, copper aluminium oxide, cadmium stannate
    • H01L29/78693Thin film transistors, i.e. transistors with a channel being at least partly a thin film having a semiconductor body comprising an oxide semiconductor material, e.g. zinc oxide, copper aluminium oxide, cadmium stannate the semiconducting oxide being amorphous

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  • Engineering & Computer Science (AREA)
  • Microelectronics & Electronic Packaging (AREA)
  • Power Engineering (AREA)
  • Physics & Mathematics (AREA)
  • Condensed Matter Physics & Semiconductors (AREA)
  • General Physics & Mathematics (AREA)
  • Computer Hardware Design (AREA)
  • Ceramic Engineering (AREA)
  • Manufacturing & Machinery (AREA)
  • Electromagnetism (AREA)
  • Optics & Photonics (AREA)
  • Health & Medical Sciences (AREA)
  • Toxicology (AREA)
  • Thin Film Transistor (AREA)
  • Recrystallisation Techniques (AREA)

Abstract

The invention belongs to display device technical fields, disclose a kind of preparation method of laser treatment amorphous oxide thin film transistor.Magnetically controlled DC sputtering Al on the glass substrate:Then Nd films grow AlOx as grid and graphical by anodic oxidation:Nd gate insulating layers, then deposited amorphous oxide semiconductor thin-film is as active layer on gate insulation layer using rf magnetron sputtering, by the device of gained in energy density ranging from 40~70mJ/cm2266nm all-solid state lasers under the conditions of be irradiated, finally using mask method on amorphous oxide semiconductor film magnetically controlled DC sputtering prepare source/drain electrode, obtain the amorphous oxide thin film transistor.The all solid state laser of the TFT devices use 266nm wavelength of the present invention is quickly handled, and is made annealing treatment without Long Time Thermal and is obtained device performance, effectively saves production cost.

Description

A kind of preparation method of laser treatment amorphous oxide thin film transistor
Technical field
The invention belongs to display device technical fields, and in particular to a kind of laser treatment amorphous oxide thin film transistor Preparation method.
Background technology
In recent years, flat panel display is quickly grown, and is mainly used in smart mobile phone, tablet computer, TV, display etc. Field.Wherein, amorphous oxide thin film transistor (TFT) is due to having higher mobility, low temperature process, high uniformity etc. excellent Point is being the flat of representative with driven with active matrix liquid crystal display (AMLCD) and active matrix organic light-emitting diode (AMOLED) Plate plays an important role in showing.
For amorphous oxides TFT, embryo deposit state sull there are a large amount of internal flaw states and active layer/ The defects of gate insulator layer interface, it usually needs by different thermal anneal process techniques come reduce sull internal flaw state and The defects of active layer/gate insulator layer interface state, improve the electric property of device.Traditional method for annealing has air thermal annealing, true Air atmosphere thermal annealing, quick atmosphere thermal annealing etc..But thermal anneal process usually has the following disadvantages:1. film interior atoms absorb The thermal energy that the external world is given rearranges reduction defect state, and annealing temperature needs very high (>=300 DEG C), and annealing time length (>= 1h), production cost is high;2. amorphous oxides TFT is stacked by multilayered film material, and the coefficient of thermal expansion of layers of material Difference, graphically also different, thermal annealing can cause device inside stress variation, be easy to cause device performance failure;3. in order to carry High and optimized device performance, can often anneal under a variety of mixed atmospheres, cause it is dangerous, to the requirement of annealing device safety coefficient It is high.
Laser is since with brightness height, the features such as good directionality, monochromaticjty is good, and coherence is good, and action time is short, mainly should Used in laser cutting, laser communication, laser marking.It is seldom to the application for handling amorphous oxide thin film transistor.
Invention content
In place of above shortcoming and defect of the existing technology, the purpose of the present invention is to provide a kind of laser treatments The preparation method of amorphous oxide thin film transistor.
The object of the invention is achieved through the following technical solutions:
A kind of preparation method of laser treatment amorphous oxide thin film transistor, specific preparation process are as follows:
(1) magnetically controlled DC sputtering Al on the glass substrate:Then Nd films are carved as grid by exposure imaging and wet method Erosion technology is graphical;
(2) in patterned Al:The anodic oxidation of Nd gate surfaces grows AlOx:Nd gate insulating layers;
(3) using rf magnetron sputtering on gate insulation layer deposited amorphous oxide semiconductor thin-film, it is non-as active layer The thickness of amorphous oxide semiconductor film is 5~20nm;
(4) by the device obtained by step (3) in energy density ranging from 40~70mJ/cm2266nm all-solid state laser items It is irradiated under part;
(5) using mask method, magnetically controlled DC sputtering prepares source/drain electrode on amorphous oxide semiconductor film, obtains institute State amorphous oxide thin film transistor.
Preferably, Al described in step (1):The doping concentration of Nd is 0.5~5wt.%, Al:The thickness of Nd films is 100 ~300nm.
Preferably, AlOx described in step (2):The thickness of Nd gate insulating layers is 50~200nm.
Preferably, amorphous oxide semiconductor described in step (3) refers to that amorphous mixes silicon tin oxide;The amorphous mixes silica The doping concentration for changing tin is 1~10wt.%.
The method of the present invention has the following advantages that and advantageous effect:
The all solid state laser of the TFT devices use 266nm wavelength of the present invention is quickly handled, at Long Time Thermal annealing Reason obtains device performance, effectively saves production cost.
Description of the drawings
Fig. 1 is the structure diagram of the amorphous oxide thin film transistor of the embodiment of the present invention.
Fig. 2 is in grid voltage V in embodiment 1 without laser irradiation processing gained amorphous oxide thin film transistorGSPoint Output characteristic curve figure that Wei be under the conditions of 0V, 10V, 20V and 30V;Wherein, curve 21,22,23 and 24 is respectively grid voltage VGSFor 0V, 10V, 20V and 30V.
Fig. 3 is to handle gained amorphous oxide thin film transistor in grid voltage V by laser irradiation in embodiment 1GSPoint Output characteristic curve figure that Wei be under the conditions of 0V, 10V, 20V and 30V;Wherein, curve 31,32,33 and 34 is respectively grid voltage VGSFor 0V, 10V, 20V and 30V.
Fig. 4 is in source/drain voltage V in embodiment 1 without laser irradiation processing gained amorphous oxide thin film transistorDSFor The transfer characteristic curve figure of (channel width-over-length ratio W/L=300/300) under the conditions of 30.1V.
Fig. 5 is to handle gained amorphous oxide thin film transistor in source/drain voltage V by laser irradiation in embodiment 1DSFor The transfer characteristic curve figure of (channel width-over-length ratio W/L=300/300) under the conditions of 30.1V.
Fig. 6 is absorptivity figure of the 266nm wavelength lasers in amorphous mixes silicon SnO 2 thin film in embodiment 1.
Fig. 7 is to handle gained amorphous oxide thin film transistor in grid voltage V by laser irradiation in embodiment 2GSPoint Output characteristic curve figure that Wei be under the conditions of 0V, 10V, 20V and 30V.
Fig. 8 is to handle gained amorphous oxide thin film transistor in source/drain voltage V by laser irradiation in embodiment 2DSFor The transfer characteristic curve figure of (channel width-over-length ratio W/L=300/300) under the conditions of 30.1V.
Fig. 9 is to handle gained amorphous oxide thin film transistor in grid voltage V by laser irradiation in embodiment 3GSPoint Output characteristic curve figure that Wei be under the conditions of 0V, 10V, 20V and 30V.
Figure 10 is to handle gained amorphous oxide thin film transistor in source/drain voltage V by laser irradiation in embodiment 3DS Transfer characteristic curve figure for (channel width-over-length ratio W/L=300/300) under the conditions of 30.1V.
Specific embodiment
With reference to embodiment and attached drawing, the present invention is described in further detail, but embodiments of the present invention are unlimited In this.
Embodiment 1
A kind of preparation method of laser treatment amorphous oxide thin film transistor of the present embodiment, the amorphous oxides are thin The structure diagram of film transistor is as shown in Figure 1, substrate 11, grid 12, gate insulating layer 13, active layer 14 by stacking gradually It is formed with source/drain electrode 15.The specific preparation process of the amorphous oxide thin film transistor is as follows:
(1) Al that magnetically controlled DC sputtering thickness is 100nm on the glass substrate:(doping of Nd is dense as grid for Nd films Spend for 3wt.%), it is then graphical by exposure imaging and wet etching technique;
(2) in patterned Al:Nd gate surface anodic oxidations growth thickness is the AlOx of 50nm:Nd gate insulating layers;
(3) using rf magnetron sputtering on gate insulation layer deposited amorphous mix silicon tin oxide semiconductive thin film (silicon doping it is dense Spend for 1wt.%), as active layer, the thickness that amorphous mixes silicon tin oxide semiconductive thin film is 5nm;
(4) by the device obtained by step (3) in energy density ranging from 60mJ/cm2266nm all-solid state lasers under the conditions of It is irradiated;
(5) magnetically controlled DC sputtering on silicon tin oxide semiconductive thin film is mixed in amorphous using mask method and prepare source/drain electrode, obtain To the amorphous oxide thin film transistor.
The present embodiment handles gained amorphous oxide thin film transistor in grid voltage V through laser irradiationGSRespectively 0V, Output characteristic curve figure under the conditions of 10V, 20V and 30V is as shown in Figure 3.And without laser irradiation processing gained amorphous oxides The output characteristic curve figure of thin film transistor (TFT) is as shown in Figure 2.
The present embodiment handles gained amorphous oxide thin film transistor in source/drain voltage V through laser irradiationDSFor 30.1V items The transfer characteristic curve figure of (channel width-over-length ratio W/L=300/300) is as shown in Figure 5 under part.And without laser irradiation processing gained The transfer characteristic curve figure of amorphous oxide thin film transistor is as shown in Figure 4.
Absorptivity of the 266nm wavelength lasers in amorphous mixes silicon SnO 2 thin film is as shown in Figure 6 in the present embodiment.
As can be seen from the above results, mixing silicon oxidation tinware part without the amorphous of laser treatment does not have device performance.With It device to handle by suitable laser energy density, transfer characteristic curve occurs in device.Illustrate that amorphous is mixed silicon tin oxide and partly led Body device can obtain device performance by laser treatment.
Embodiment 2
A kind of preparation method of laser treatment amorphous oxide thin film transistor of the present embodiment, the amorphous oxides are thin The structure diagram of film transistor is as shown in Figure 1, substrate 11, grid 12, gate insulating layer 13, active layer 14 by stacking gradually It is formed with source/drain electrode 15.The specific preparation process of the amorphous oxide thin film transistor is as follows:
(1) Al that magnetically controlled DC sputtering thickness is 200 on the glass substrate:Nd films are as the grid (doping concentration of Nd For 4wt.%), it is then graphical by exposure imaging and wet etching technique;
(2) in patterned Al:Nd gate surface anodic oxidations growth thickness is the AlOx of 100nm:Nd gate insulating layers;
(3) using rf magnetron sputtering on gate insulation layer deposited amorphous mix silicon tin oxide semiconductive thin film (silicon doping it is dense Spend for 3wt.%), as active layer, the thickness that amorphous mixes silicon tin oxide semiconductive thin film is 10nm;
(4) by the device obtained by step (3) in energy density ranging from 70mJ/cm2266nm all-solid state lasers under the conditions of It is irradiated;
(5) magnetically controlled DC sputtering on silicon tin oxide semiconductive thin film is mixed in amorphous using mask method and prepare source/drain electrode, obtain To the amorphous oxide thin film transistor.
The present embodiment handles gained amorphous oxide thin film transistor in grid voltage V through laser irradiationGSRespectively 0V, Output characteristic curve figure under the conditions of 10V, 20V and 30V is as shown in Figure 7;In source/drain voltage VDSFor (ditch road width under the conditions of 30.1V It is long than W/L=300/300) transfer characteristic curve figure it is as shown in Figure 8.
As can be seen from the above results, it is handled by suitable laser energy density, transfer characteristic curve occurs in device.It says Bright amorphous, which mixes silicon tin oxide semiconductor devices, to obtain device performance by laser treatment.
Embodiment 3
A kind of preparation method of laser treatment amorphous oxide thin film transistor of the present embodiment, the amorphous oxides are thin The structure diagram of film transistor is as shown in Figure 1, substrate 11, grid 12, gate insulating layer 13, active layer 14 by stacking gradually It is formed with source/drain electrode 15.The specific preparation process of the amorphous oxide thin film transistor is as follows:
(1) Al that magnetically controlled DC sputtering thickness is 300nm on the glass substrate:(doping of Nd is dense as grid for Nd films Spend for 5wt.%), it is then graphical by exposure imaging and wet etching technique;
(2) in patterned Al:Nd gate surface anodic oxidations growth thickness is the AlOx of 200nm:Nd gate insulating layers;
(3) using rf magnetron sputtering on gate insulation layer deposited amorphous mix silicon tin oxide semiconductive thin film (silicon doping it is dense Spend for 10wt.%), as active layer, the thickness that amorphous mixes silicon tin oxide semiconductive thin film is 15nm;
(4) by the device obtained by step (3) in energy density ranging from 50mJ/cm2266nm all-solid state lasers under the conditions of It is irradiated;
(5) magnetically controlled DC sputtering on silicon tin oxide semiconductive thin film is mixed in amorphous using mask method and prepare source/drain electrode, obtain To the amorphous oxide thin film transistor.
The present embodiment handles gained amorphous oxide thin film transistor in grid voltage V through laser irradiationGSRespectively 0V, Output characteristic curve figure under the conditions of 10V, 20V and 30V is as shown in Figure 9;In source/drain voltage VDSFor (ditch road width under the conditions of 30.1V It is long than W/L=300/300) transfer characteristic curve figure it is as shown in Figure 10.
As can be seen from the above results, it is handled by suitable laser energy density, transfer characteristic curve occurs in device.It says Bright amorphous, which mixes silicon tin oxide semiconductor devices, to obtain device performance by laser treatment.
Above-described embodiment is the preferable embodiment of the present invention, but embodiments of the present invention are not by above-described embodiment Limitation, other any Spirit Essences without departing from the present invention with made under principle change, modification, replacement, combine, simplification, Equivalent substitute mode is should be, is included within protection scope of the present invention.

Claims (4)

1. a kind of preparation method of laser treatment amorphous oxide thin film transistor, it is characterised in that specific preparation process is as follows:
(1) magnetically controlled DC sputtering Al on the glass substrate:Then Nd films pass through exposure imaging and wet etching skill as grid Art is graphical;
(2) in patterned Al:The anodic oxidation of Nd gate surfaces grows AlOx:Nd gate insulating layers;
(3) using rf magnetron sputtering on gate insulation layer deposited amorphous oxide semiconductor thin-film, as active layer, amorphous oxygen The thickness of compound semiconductive thin film is 5~20nm;
(4) by the device obtained by step (3) in energy density ranging from 40~70mJ/cm2266nm all-solid state lasers under the conditions of It is irradiated;
(5) using mask method, magnetically controlled DC sputtering prepares source/drain electrode on amorphous oxide semiconductor film, obtains described non- Oxide thin film transistor.
2. a kind of preparation method of laser treatment amorphous oxide thin film transistor according to claim 1, feature exist In:Al described in step (1):The doping concentration of Nd is 0.5~5wt.%, Al:The thickness of Nd films is 100~300nm.
3. a kind of preparation method of laser treatment amorphous oxide thin film transistor according to claim 1, feature exist In:AlOx described in step (2):The thickness of Nd gate insulating layers is 50~200nm.
4. a kind of preparation method of laser treatment amorphous oxide thin film transistor according to claim 1, feature exist In:Amorphous oxide semiconductor described in step (3) refers to that amorphous mixes silicon tin oxide;The doping that the amorphous mixes silicon tin oxide is dense It spends for 1~10wt.%.
CN201711323516.XA 2017-12-13 2017-12-13 A kind of preparation method of laser treatment amorphous oxide thin film transistor Pending CN108231905A (en)

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Cited By (2)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
CN109411542A (en) * 2018-09-10 2019-03-01 华南理工大学 A kind of back channel-etch type amorphous oxide thin film transistor and preparation method thereof
CN109767973A (en) * 2018-12-14 2019-05-17 华南理工大学 A method of it is annealed using deep ultraviolet laser to oxide semiconductor thin-film

Citations (2)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
US20090261449A1 (en) * 2008-03-26 2009-10-22 Semiconductor Energy Laboratory Co., Ltd. Method for manufacturing soi substrate and semiconductor device
CN107170833A (en) * 2017-06-14 2017-09-15 华南理工大学 A kind of amorphous oxide thin film transistor and preparation method thereof

Patent Citations (2)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
US20090261449A1 (en) * 2008-03-26 2009-10-22 Semiconductor Energy Laboratory Co., Ltd. Method for manufacturing soi substrate and semiconductor device
CN107170833A (en) * 2017-06-14 2017-09-15 华南理工大学 A kind of amorphous oxide thin film transistor and preparation method thereof

Cited By (2)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
CN109411542A (en) * 2018-09-10 2019-03-01 华南理工大学 A kind of back channel-etch type amorphous oxide thin film transistor and preparation method thereof
CN109767973A (en) * 2018-12-14 2019-05-17 华南理工大学 A method of it is annealed using deep ultraviolet laser to oxide semiconductor thin-film

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Application publication date: 20180629