CN108202519A - A kind of environment-friendlyradiation-proof radiation-proof wall paper - Google Patents

A kind of environment-friendlyradiation-proof radiation-proof wall paper Download PDF

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Publication number
CN108202519A
CN108202519A CN201611188211.8A CN201611188211A CN108202519A CN 108202519 A CN108202519 A CN 108202519A CN 201611188211 A CN201611188211 A CN 201611188211A CN 108202519 A CN108202519 A CN 108202519A
Authority
CN
China
Prior art keywords
parts
radiation
proof
heat discoloration
friendlyradiation
Prior art date
Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
Pending
Application number
CN201611188211.8A
Other languages
Chinese (zh)
Inventor
董发磊
Current Assignee (The listed assignees may be inaccurate. Google has not performed a legal analysis and makes no representation or warranty as to the accuracy of the list.)
Fujian Youya Environmental Protection Wallpaper Co Ltd
Original Assignee
Fujian Youya Environmental Protection Wallpaper Co Ltd
Priority date (The priority date is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the date listed.)
Filing date
Publication date
Application filed by Fujian Youya Environmental Protection Wallpaper Co Ltd filed Critical Fujian Youya Environmental Protection Wallpaper Co Ltd
Priority to CN201611188211.8A priority Critical patent/CN108202519A/en
Publication of CN108202519A publication Critical patent/CN108202519A/en
Pending legal-status Critical Current

Links

Classifications

    • BPERFORMING OPERATIONS; TRANSPORTING
    • B32LAYERED PRODUCTS
    • B32BLAYERED PRODUCTS, i.e. PRODUCTS BUILT-UP OF STRATA OF FLAT OR NON-FLAT, e.g. CELLULAR OR HONEYCOMB, FORM
    • B32B27/00Layered products comprising a layer of synthetic resin
    • B32B27/30Layered products comprising a layer of synthetic resin comprising vinyl (co)polymers; comprising acrylic (co)polymers
    • B32B27/306Layered products comprising a layer of synthetic resin comprising vinyl (co)polymers; comprising acrylic (co)polymers comprising vinyl acetate or vinyl alcohol (co)polymers
    • BPERFORMING OPERATIONS; TRANSPORTING
    • B32LAYERED PRODUCTS
    • B32BLAYERED PRODUCTS, i.e. PRODUCTS BUILT-UP OF STRATA OF FLAT OR NON-FLAT, e.g. CELLULAR OR HONEYCOMB, FORM
    • B32B27/00Layered products comprising a layer of synthetic resin
    • B32B27/06Layered products comprising a layer of synthetic resin as the main or only constituent of a layer, which is next to another layer of the same or of a different material
    • B32B27/10Layered products comprising a layer of synthetic resin as the main or only constituent of a layer, which is next to another layer of the same or of a different material of paper or cardboard
    • BPERFORMING OPERATIONS; TRANSPORTING
    • B32LAYERED PRODUCTS
    • B32BLAYERED PRODUCTS, i.e. PRODUCTS BUILT-UP OF STRATA OF FLAT OR NON-FLAT, e.g. CELLULAR OR HONEYCOMB, FORM
    • B32B27/00Layered products comprising a layer of synthetic resin
    • B32B27/12Layered products comprising a layer of synthetic resin next to a fibrous or filamentary layer
    • CCHEMISTRY; METALLURGY
    • C08ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08LCOMPOSITIONS OF MACROMOLECULAR COMPOUNDS
    • C08L29/00Compositions of homopolymers or copolymers of compounds having one or more unsaturated aliphatic radicals, each having only one carbon-to-carbon double bond, and at least one being terminated by an alcohol, ether, aldehydo, ketonic, acetal or ketal radical; Compositions of hydrolysed polymers of esters of unsaturated alcohols with saturated carboxylic acids; Compositions of derivatives of such polymers
    • C08L29/02Homopolymers or copolymers of unsaturated alcohols
    • C08L29/04Polyvinyl alcohol; Partially hydrolysed homopolymers or copolymers of esters of unsaturated alcohols with saturated carboxylic acids
    • EFIXED CONSTRUCTIONS
    • E04BUILDING
    • E04FFINISHING WORK ON BUILDINGS, e.g. STAIRS, FLOORS
    • E04F13/00Coverings or linings, e.g. for walls or ceilings
    • E04F13/002Coverings or linings, e.g. for walls or ceilings made of webs, e.g. of fabrics, or wallpaper, used as coverings or linings
    • BPERFORMING OPERATIONS; TRANSPORTING
    • B32LAYERED PRODUCTS
    • B32BLAYERED PRODUCTS, i.e. PRODUCTS BUILT-UP OF STRATA OF FLAT OR NON-FLAT, e.g. CELLULAR OR HONEYCOMB, FORM
    • B32B2307/00Properties of the layers or laminate
    • B32B2307/20Properties of the layers or laminate having particular electrical or magnetic properties, e.g. piezoelectric
    • B32B2307/212Electromagnetic interference shielding
    • BPERFORMING OPERATIONS; TRANSPORTING
    • B32LAYERED PRODUCTS
    • B32BLAYERED PRODUCTS, i.e. PRODUCTS BUILT-UP OF STRATA OF FLAT OR NON-FLAT, e.g. CELLULAR OR HONEYCOMB, FORM
    • B32B2307/00Properties of the layers or laminate
    • B32B2307/40Properties of the layers or laminate having particular optical properties
    • BPERFORMING OPERATIONS; TRANSPORTING
    • B32LAYERED PRODUCTS
    • B32BLAYERED PRODUCTS, i.e. PRODUCTS BUILT-UP OF STRATA OF FLAT OR NON-FLAT, e.g. CELLULAR OR HONEYCOMB, FORM
    • B32B2607/00Walls, panels
    • B32B2607/02Wall papers, wall coverings
    • CCHEMISTRY; METALLURGY
    • C08ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08KUse of inorganic or non-macromolecular organic substances as compounding ingredients
    • C08K2201/00Specific properties of additives
    • C08K2201/011Nanostructured additives
    • CCHEMISTRY; METALLURGY
    • C08ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08LCOMPOSITIONS OF MACROMOLECULAR COMPOUNDS
    • C08L2201/00Properties
    • C08L2201/08Stabilised against heat, light or radiation or oxydation

Abstract

The present invention relates to a kind of wallpapers, a kind of environment-friendlyradiation-proof radiation-proof wall paper is provided, the defects of solving the defects of wallpaper of the prior art not can effectively prevent radiation and more single function, including base material bottom, the base material bottom is equipped with radiation protective layer, the radiation protective layer is equipped with microcapsules heat discoloration layer, and the radiation protective layer includes each raw material of following parts by weight:10~15 parts of nano-graphite particle, 5~10 parts of titanium dioxide, 20~30 parts of epoxidized soybean oil, 10~15 parts of blanc fixe, 40~50 parts of polyvinyl alcohol;The microcapsules heat discoloration layer is made of microcapsule shell and the heat discoloration agent in microcapsule shell body;The microcapsule shell presses 1 for Arabic gum and gelatin:2 weight ratio mixes, and the heat discoloration agent is triphenylmenthane.

Description

A kind of environment-friendlyradiation-proof radiation-proof wall paper
Technical field
The present invention relates to a kind of wallpaper more particularly to a kind of environment-friendlyradiation-proof radiation-proof wall papers.
Background technology
Wallpaper is a kind of quite extensive house decorative material of application.Because wallpaper has, color is various, pattern enriches, person of outstanding talent The characteristics of a variety of other house decorative materials institutes such as magnificent style, safety and environmental protection, easy for construction, affordable are incomparable, therefore The developed countries and regions such as America and Europe, Southeast Asia, Japan obtain considerable degree of universal.With the raising of electrifing degree, people It can be touched in life from more and more electromagnetic radiation such as mobile phone, computer, television set, existed to the health of people Great hidden danger, and existing wallpaper not can effectively prevent various radiation, therefore develop a kind of wall for being capable of radiation proof function Paper protects people's health, and it is particularly important to promote domestic environment.
China Patent No. 201010521177.8 discloses a kind of radiation-resistant environment-friendly wallpaper, including superficial layer, the surface It is attached on one of side of layer and is made of expanded graphite for the electro-magnetic screen layer of radiation protection and for protecting successively The back of the body sheath of electro-magnetic screen layer is stated, the back of the body sheath is macromolecule membrane, and a side of the macromolecule membrane has metal Plated film should be in contact with side of metal coating with the electro-magnetic screen layer, the wallpaper with radiation-proof effect, structure also compared with To be simple, but function is more single, only has radiation proof function.
Invention content
Therefore, for more than content, the present invention provides a kind of environment-friendlyradiation-proof radiation-proof wall paper, solves wallpaper of the prior art not The defects of the defects of can effectively prevent radiation and more single function.
In order to achieve the above objectives, the present invention is achieved by the following technical solutions:A kind of environment-friendlyradiation-proof radiation-proof wall paper, including Base material bottom, the base material bottom are equipped with radiation protective layer, and the radiation protective layer is equipped with microcapsules heat discoloration layer, described anti- Radiating layer includes each raw material of following parts by weight:10~15 parts of nano-graphite particle, 5~10 parts of titanium dioxide, epoxidized soybean oil 20 ~30 parts, 10~15 parts of blanc fixe, 40~50 parts of polyvinyl alcohol;The microcapsules heat discoloration layer is by microcapsule shell and sets In the heat discoloration agent composition in microcapsule shell body;The microcapsule shell presses 1 for Arabic gum and gelatin:2 weight ratio is mixed It closes, the heat discoloration agent is triphenylmenthane.
A further improvement is that:The preparation method of the microcapsules heat discoloration layer is that Arabic gum, gelatin are pressed 1:2 Mixing dissolves by heating, is subsequently added into triphenylmenthane, is re-fed into dry spray tower and is dried, the temperature of the dry spray tower Control is at 150~160 DEG C.
A further improvement is that:The amount ratio of the heat discoloration agent and microcapsule shell is:=1 is calculated by weight: 10~16.
A further improvement is that:The amount ratio of the heat discoloration agent and microcapsule shell is:=1 is calculated by weight: 13。
A further improvement is that:The radiation protective layer includes each raw material of following parts by weight:Nano-graphite particle 13~15 Part, 6~10 parts of titanium dioxide, 25~30 parts of epoxidized soybean oil, 13~15 parts of blanc fixe, 45~50 parts of polyvinyl alcohol.
A further improvement is that:The base material bottom is non-woven fabrics or non-woven paper.
By using preceding solution, the beneficial effects of the invention are as follows:The environment-friendlyradiation-proof radiation-proof wall paper of the present invention, including Base material bottom, the base material bottom are equipped with radiation protective layer, and the radiation protective layer is equipped with microcapsules heat discoloration layer, described anti- Radiating layer includes each raw material of following parts by weight:10~15 parts of nano-graphite particle, 5~10 parts of titanium dioxide, epoxidized soybean oil 20 ~30 parts, 10~15 parts of blanc fixe, 40~50 parts of polyvinyl alcohol;Nano-graphite particle, blanc fixe in radiation protective layer is equal With preferable radiation proof function, blanc fixe can absorb a variety of rays in ambient enviroment, effectively prevent radiating, micro- glue Capsule heat discoloration layer is made of microcapsule shell and the heat discoloration agent in microcapsule shell body, and microcapsules heat discoloration layer exists Under light irradiation, as the variation of color occurs for the variation of ambient temperature, wallpaper of the invention that is, with radiation proof function, and has The effect for generating color change can be changed with ambient temperature by having, and increase visual effect.Furthermore the raw material components used in the present invention are equal It is nontoxic, it is more environmentally friendly.
Specific embodiment
Carry out the embodiment that the present invention will be described in detail below with reference to specific embodiment, how skill is applied to the present invention whereby Art means solve technical problem, and the realization process for reaching technique effect can fully understand and implement according to this.
Unless otherwise specified, the conventional hand that the technological means employed in embodiment is well known to those skilled in the art Section, used reagent and product are also available commercial.The source of agents useful for same, trade name and it is necessary to list it Constituent person indicates on the first appearance.
Embodiment one
A kind of environment-friendlyradiation-proof radiation-proof wall paper, including non-woven fabrics base material bottom, the non-woven fabrics base material bottom is equipped with radiation protection Layer, the radiation protective layer are equipped with microcapsules heat discoloration layer, and the radiation protective layer includes each raw material of following parts by weight:Nanometer 10 parts of graphite particle, 5 parts of titanium dioxide, 20 parts of epoxidized soybean oil, 10 parts of blanc fixe, 40 parts of polyvinyl alcohol;The microcapsules sense 1 part of heat discoloration agent of the warm photochromic layer by 10 parts of microcapsule shell and in microcapsule shell body forms;The microcapsule shell 1 is pressed for Arabic gum and gelatin:2 weight ratio mixes, and the heat discoloration agent is triphenylmenthane.
The preparation method of the microcapsules heat discoloration layer is that Arabic gum, gelatin are pressed 1:2 mixing, dissolve by heating, connect Addition triphenylmenthane, dry spray tower is re-fed into and is dried, the temperature of the dry spray tower is controlled at 150 DEG C.
Embodiment two
A kind of environment-friendlyradiation-proof radiation-proof wall paper, including nonwoven paper base material bottom, the nonwoven paper base material bottom is equipped with radiation protection Layer, the radiation protective layer are equipped with microcapsules heat discoloration layer, and the radiation protective layer includes each raw material of following parts by weight:Nanometer 13 parts of graphite particle, 6 parts of titanium dioxide, 25 parts of epoxidized soybean oil, 13 parts of blanc fixe, 45 parts of polyvinyl alcohol;The microcapsules sense 1 part of heat discoloration agent of the warm photochromic layer by 13 parts of microcapsule shell and in microcapsule shell body forms;The microcapsule shell 1 is pressed for Arabic gum and gelatin:2 weight ratio mixes, and the heat discoloration agent is triphenylmenthane.
The preparation method of the microcapsules heat discoloration layer is that Arabic gum, gelatin are pressed 1:2 mixing, dissolve by heating, connect Addition triphenylmenthane, dry spray tower is re-fed into and is dried, the temperature of the dry spray tower is controlled at 155 DEG C.
Embodiment three
A kind of environment-friendlyradiation-proof radiation-proof wall paper, including non-woven fabrics base material bottom, the non-woven fabrics base material bottom is equipped with radiation protection Layer, the radiation protective layer are equipped with microcapsules heat discoloration layer, and the radiation protective layer includes each raw material of following parts by weight:Nanometer 15 parts of graphite particle, 10 parts of titanium dioxide, 30 parts of epoxidized soybean oil, 15 parts of blanc fixe, 50 parts of polyvinyl alcohol;The microcapsules sense 1 part of heat discoloration agent of the warm photochromic layer by 16 parts of microcapsule shell and in microcapsule shell body forms;The microcapsule shell 1 is pressed for Arabic gum and gelatin:2 weight ratio mixes, and the heat discoloration agent is triphenylmenthane.
The preparation method of the microcapsules heat discoloration layer is that Arabic gum, gelatin are pressed 1:2 mixing, dissolve by heating, connect Addition triphenylmenthane, dry spray tower is re-fed into and is dried, the temperature of the dry spray tower is controlled at 160 DEG C.
Wherein, in the present invention, the present invention can be achieved in each raw material components of the radiation protective layer in following parameter area Purpose:10~15 parts of nano-graphite particle, 5~10 parts of titanium dioxide, 20~30 parts of epoxidized soybean oil, blanc fixe 10~15 Part, 40~50 parts of polyvinyl alcohol.The microcapsule shell and heat discoloration agent are 10~16:This hair can be achieved in the range of 1 Bright purpose.
The foregoing descriptions are merely the embodiment using this origination techniques content, any those skilled in the art use this wound Make done modifications and changes, all belong to the scope of the claims of this creation opinion, and be not limited to those disclosed embodiments.

Claims (6)

1. a kind of environment-friendlyradiation-proof radiation-proof wall paper, it is characterised in that:Including base material bottom, the base material bottom is equipped with radiation protective layer, The radiation protective layer is equipped with microcapsules heat discoloration layer, and the radiation protective layer includes each raw material of following parts by weight:Nanometer stone Black 10~15 parts of particle, 5~10 parts of titanium dioxide, 20~30 parts of epoxidized soybean oil, 10~15 parts of blanc fixe, polyvinyl alcohol 40~ 50 parts;The microcapsules heat discoloration layer is made of microcapsule shell and the heat discoloration agent in microcapsule shell body;It is described Microcapsule shell presses 1 for Arabic gum and gelatin:2 weight ratio mixes, and the heat discoloration agent is triphenylmenthane.
2. a kind of environment-friendlyradiation-proof radiation-proof wall paper according to claim 1 or 2, it is characterised in that:The microcapsules heat discoloration The preparation method of layer is that Arabic gum, gelatin are pressed 1:2 mixing, dissolve by heating, are subsequently added into triphenylmenthane, are re-fed into drying Spray tower is dried, and the temperature of the dry spray tower is controlled at 150~160 DEG C.
3. a kind of environment-friendlyradiation-proof radiation-proof wall paper according to claim 2, it is characterised in that:The heat discoloration agent and microcapsules The amount ratio of housing is:=1 is calculated by weight:10~16.
4. a kind of environment-friendlyradiation-proof radiation-proof wall paper according to claim 3, it is characterised in that:The heat discoloration agent and microcapsules The amount ratio of housing is:=1 is calculated by weight:13.
5. a kind of environment-friendlyradiation-proof radiation-proof wall paper according to claim 4, it is characterised in that:The radiation protective layer includes following heavy Measure each raw material of part:13~15 parts of nano-graphite particle, 6~10 parts of titanium dioxide, 25~30 parts of epoxidized soybean oil, blanc fixe 13 ~15 parts, 45~50 parts of polyvinyl alcohol.
6. a kind of environment-friendlyradiation-proof radiation-proof wall paper according to claim 5, it is characterised in that:The base material bottom for non-woven fabrics or Non-woven paper.
CN201611188211.8A 2016-12-20 2016-12-20 A kind of environment-friendlyradiation-proof radiation-proof wall paper Pending CN108202519A (en)

Priority Applications (1)

Application Number Priority Date Filing Date Title
CN201611188211.8A CN108202519A (en) 2016-12-20 2016-12-20 A kind of environment-friendlyradiation-proof radiation-proof wall paper

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Application Number Priority Date Filing Date Title
CN201611188211.8A CN108202519A (en) 2016-12-20 2016-12-20 A kind of environment-friendlyradiation-proof radiation-proof wall paper

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CN108202519A true CN108202519A (en) 2018-06-26

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Cited By (1)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
CN109880509A (en) * 2019-01-29 2019-06-14 张家港康得新光电材料有限公司 Aqueous allochroic paint and its painting membrane product

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* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
CN109880509A (en) * 2019-01-29 2019-06-14 张家港康得新光电材料有限公司 Aqueous allochroic paint and its painting membrane product

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