CN108202519A - A kind of environment-friendlyradiation-proof radiation-proof wall paper - Google Patents
A kind of environment-friendlyradiation-proof radiation-proof wall paper Download PDFInfo
- Publication number
- CN108202519A CN108202519A CN201611188211.8A CN201611188211A CN108202519A CN 108202519 A CN108202519 A CN 108202519A CN 201611188211 A CN201611188211 A CN 201611188211A CN 108202519 A CN108202519 A CN 108202519A
- Authority
- CN
- China
- Prior art keywords
- parts
- radiation
- proof
- heat discoloration
- friendlyradiation
- Prior art date
- Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
- Pending
Links
- 239000003094 microcapsule Substances 0.000 claims abstract description 44
- 238000002845 discoloration Methods 0.000 claims abstract description 35
- 230000005855 radiation Effects 0.000 claims abstract description 32
- 239000010410 layer Substances 0.000 claims abstract description 30
- GWEVSGVZZGPLCZ-UHFFFAOYSA-N Titan oxide Chemical compound O=[Ti]=O GWEVSGVZZGPLCZ-UHFFFAOYSA-N 0.000 claims abstract description 20
- 239000011241 protective layer Substances 0.000 claims abstract description 20
- 239000003795 chemical substances by application Substances 0.000 claims abstract description 19
- 239000000463 material Substances 0.000 claims abstract description 18
- TZCXTZWJZNENPQ-UHFFFAOYSA-L barium sulfate Chemical compound [Ba+2].[O-]S([O-])(=O)=O TZCXTZWJZNENPQ-UHFFFAOYSA-L 0.000 claims abstract description 12
- 108010010803 Gelatin Proteins 0.000 claims abstract description 11
- YSZKDKZFYUOELW-UHFFFAOYSA-N [diphenyl-(4-propan-2-ylcyclohexyl)methyl]benzene Chemical group C1(=CC=CC=C1)C(C1CCC(CC1)C(C)C)(C1=CC=CC=C1)C1=CC=CC=C1 YSZKDKZFYUOELW-UHFFFAOYSA-N 0.000 claims abstract description 11
- 235000010489 acacia gum Nutrition 0.000 claims abstract description 11
- 239000001785 acacia senegal l. willd gum Substances 0.000 claims abstract description 11
- 229920000159 gelatin Polymers 0.000 claims abstract description 11
- 239000008273 gelatin Substances 0.000 claims abstract description 11
- 235000019322 gelatine Nutrition 0.000 claims abstract description 11
- 235000011852 gelatine desserts Nutrition 0.000 claims abstract description 11
- 229910002804 graphite Inorganic materials 0.000 claims abstract description 11
- 239000010439 graphite Substances 0.000 claims abstract description 11
- 239000002245 particle Substances 0.000 claims abstract description 11
- 239000002994 raw material Substances 0.000 claims abstract description 11
- 239000004372 Polyvinyl alcohol Substances 0.000 claims abstract description 10
- 229920002451 polyvinyl alcohol Polymers 0.000 claims abstract description 10
- 235000012424 soybean oil Nutrition 0.000 claims abstract description 10
- 239000003549 soybean oil Substances 0.000 claims abstract description 10
- 239000004408 titanium dioxide Substances 0.000 claims abstract description 10
- 239000007921 spray Substances 0.000 claims description 10
- 239000004745 nonwoven fabric Substances 0.000 claims description 6
- 238000010438 heat treatment Methods 0.000 claims description 5
- 238000002360 preparation method Methods 0.000 claims description 5
- 238000001035 drying Methods 0.000 claims 1
- 239000004575 stone Substances 0.000 claims 1
- 230000007547 defect Effects 0.000 abstract description 4
- 230000006872 improvement Effects 0.000 description 5
- OKTJSMMVPCPJKN-UHFFFAOYSA-N Carbon Chemical compound [C] OKTJSMMVPCPJKN-UHFFFAOYSA-N 0.000 description 4
- 230000000694 effects Effects 0.000 description 3
- 238000000034 method Methods 0.000 description 3
- 230000036541 health Effects 0.000 description 2
- 229920002521 macromolecule Polymers 0.000 description 2
- 239000012528 membrane Substances 0.000 description 2
- 229910052751 metal Inorganic materials 0.000 description 2
- 239000002184 metal Substances 0.000 description 2
- 230000009286 beneficial effect Effects 0.000 description 1
- 239000002775 capsule Substances 0.000 description 1
- 230000008859 change Effects 0.000 description 1
- 239000003153 chemical reaction reagent Substances 0.000 description 1
- 239000011248 coating agent Substances 0.000 description 1
- 238000000576 coating method Methods 0.000 description 1
- 239000000470 constituent Substances 0.000 description 1
- 238000010276 construction Methods 0.000 description 1
- 230000005670 electromagnetic radiation Effects 0.000 description 1
- 238000005516 engineering process Methods 0.000 description 1
- 230000007613 environmental effect Effects 0.000 description 1
- 239000003292 glue Substances 0.000 description 1
- 239000000203 mixture Substances 0.000 description 1
- 230000004048 modification Effects 0.000 description 1
- 238000012986 modification Methods 0.000 description 1
- 231100000252 nontoxic Toxicity 0.000 description 1
- 230000003000 nontoxic effect Effects 0.000 description 1
- 230000008569 process Effects 0.000 description 1
- 230000000007 visual effect Effects 0.000 description 1
Classifications
-
- B—PERFORMING OPERATIONS; TRANSPORTING
- B32—LAYERED PRODUCTS
- B32B—LAYERED PRODUCTS, i.e. PRODUCTS BUILT-UP OF STRATA OF FLAT OR NON-FLAT, e.g. CELLULAR OR HONEYCOMB, FORM
- B32B27/00—Layered products comprising a layer of synthetic resin
- B32B27/30—Layered products comprising a layer of synthetic resin comprising vinyl (co)polymers; comprising acrylic (co)polymers
- B32B27/306—Layered products comprising a layer of synthetic resin comprising vinyl (co)polymers; comprising acrylic (co)polymers comprising vinyl acetate or vinyl alcohol (co)polymers
-
- B—PERFORMING OPERATIONS; TRANSPORTING
- B32—LAYERED PRODUCTS
- B32B—LAYERED PRODUCTS, i.e. PRODUCTS BUILT-UP OF STRATA OF FLAT OR NON-FLAT, e.g. CELLULAR OR HONEYCOMB, FORM
- B32B27/00—Layered products comprising a layer of synthetic resin
- B32B27/06—Layered products comprising a layer of synthetic resin as the main or only constituent of a layer, which is next to another layer of the same or of a different material
- B32B27/10—Layered products comprising a layer of synthetic resin as the main or only constituent of a layer, which is next to another layer of the same or of a different material of paper or cardboard
-
- B—PERFORMING OPERATIONS; TRANSPORTING
- B32—LAYERED PRODUCTS
- B32B—LAYERED PRODUCTS, i.e. PRODUCTS BUILT-UP OF STRATA OF FLAT OR NON-FLAT, e.g. CELLULAR OR HONEYCOMB, FORM
- B32B27/00—Layered products comprising a layer of synthetic resin
- B32B27/12—Layered products comprising a layer of synthetic resin next to a fibrous or filamentary layer
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08L—COMPOSITIONS OF MACROMOLECULAR COMPOUNDS
- C08L29/00—Compositions of homopolymers or copolymers of compounds having one or more unsaturated aliphatic radicals, each having only one carbon-to-carbon double bond, and at least one being terminated by an alcohol, ether, aldehydo, ketonic, acetal or ketal radical; Compositions of hydrolysed polymers of esters of unsaturated alcohols with saturated carboxylic acids; Compositions of derivatives of such polymers
- C08L29/02—Homopolymers or copolymers of unsaturated alcohols
- C08L29/04—Polyvinyl alcohol; Partially hydrolysed homopolymers or copolymers of esters of unsaturated alcohols with saturated carboxylic acids
-
- E—FIXED CONSTRUCTIONS
- E04—BUILDING
- E04F—FINISHING WORK ON BUILDINGS, e.g. STAIRS, FLOORS
- E04F13/00—Coverings or linings, e.g. for walls or ceilings
- E04F13/002—Coverings or linings, e.g. for walls or ceilings made of webs, e.g. of fabrics, or wallpaper, used as coverings or linings
-
- B—PERFORMING OPERATIONS; TRANSPORTING
- B32—LAYERED PRODUCTS
- B32B—LAYERED PRODUCTS, i.e. PRODUCTS BUILT-UP OF STRATA OF FLAT OR NON-FLAT, e.g. CELLULAR OR HONEYCOMB, FORM
- B32B2307/00—Properties of the layers or laminate
- B32B2307/20—Properties of the layers or laminate having particular electrical or magnetic properties, e.g. piezoelectric
- B32B2307/212—Electromagnetic interference shielding
-
- B—PERFORMING OPERATIONS; TRANSPORTING
- B32—LAYERED PRODUCTS
- B32B—LAYERED PRODUCTS, i.e. PRODUCTS BUILT-UP OF STRATA OF FLAT OR NON-FLAT, e.g. CELLULAR OR HONEYCOMB, FORM
- B32B2307/00—Properties of the layers or laminate
- B32B2307/40—Properties of the layers or laminate having particular optical properties
-
- B—PERFORMING OPERATIONS; TRANSPORTING
- B32—LAYERED PRODUCTS
- B32B—LAYERED PRODUCTS, i.e. PRODUCTS BUILT-UP OF STRATA OF FLAT OR NON-FLAT, e.g. CELLULAR OR HONEYCOMB, FORM
- B32B2607/00—Walls, panels
- B32B2607/02—Wall papers, wall coverings
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08K—Use of inorganic or non-macromolecular organic substances as compounding ingredients
- C08K2201/00—Specific properties of additives
- C08K2201/011—Nanostructured additives
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08L—COMPOSITIONS OF MACROMOLECULAR COMPOUNDS
- C08L2201/00—Properties
- C08L2201/08—Stabilised against heat, light or radiation or oxydation
Abstract
The present invention relates to a kind of wallpapers, a kind of environment-friendlyradiation-proof radiation-proof wall paper is provided, the defects of solving the defects of wallpaper of the prior art not can effectively prevent radiation and more single function, including base material bottom, the base material bottom is equipped with radiation protective layer, the radiation protective layer is equipped with microcapsules heat discoloration layer, and the radiation protective layer includes each raw material of following parts by weight:10~15 parts of nano-graphite particle, 5~10 parts of titanium dioxide, 20~30 parts of epoxidized soybean oil, 10~15 parts of blanc fixe, 40~50 parts of polyvinyl alcohol;The microcapsules heat discoloration layer is made of microcapsule shell and the heat discoloration agent in microcapsule shell body;The microcapsule shell presses 1 for Arabic gum and gelatin:2 weight ratio mixes, and the heat discoloration agent is triphenylmenthane.
Description
Technical field
The present invention relates to a kind of wallpaper more particularly to a kind of environment-friendlyradiation-proof radiation-proof wall papers.
Background technology
Wallpaper is a kind of quite extensive house decorative material of application.Because wallpaper has, color is various, pattern enriches, person of outstanding talent
The characteristics of a variety of other house decorative materials institutes such as magnificent style, safety and environmental protection, easy for construction, affordable are incomparable, therefore
The developed countries and regions such as America and Europe, Southeast Asia, Japan obtain considerable degree of universal.With the raising of electrifing degree, people
It can be touched in life from more and more electromagnetic radiation such as mobile phone, computer, television set, existed to the health of people
Great hidden danger, and existing wallpaper not can effectively prevent various radiation, therefore develop a kind of wall for being capable of radiation proof function
Paper protects people's health, and it is particularly important to promote domestic environment.
China Patent No. 201010521177.8 discloses a kind of radiation-resistant environment-friendly wallpaper, including superficial layer, the surface
It is attached on one of side of layer and is made of expanded graphite for the electro-magnetic screen layer of radiation protection and for protecting successively
The back of the body sheath of electro-magnetic screen layer is stated, the back of the body sheath is macromolecule membrane, and a side of the macromolecule membrane has metal
Plated film should be in contact with side of metal coating with the electro-magnetic screen layer, the wallpaper with radiation-proof effect, structure also compared with
To be simple, but function is more single, only has radiation proof function.
Invention content
Therefore, for more than content, the present invention provides a kind of environment-friendlyradiation-proof radiation-proof wall paper, solves wallpaper of the prior art not
The defects of the defects of can effectively prevent radiation and more single function.
In order to achieve the above objectives, the present invention is achieved by the following technical solutions:A kind of environment-friendlyradiation-proof radiation-proof wall paper, including
Base material bottom, the base material bottom are equipped with radiation protective layer, and the radiation protective layer is equipped with microcapsules heat discoloration layer, described anti-
Radiating layer includes each raw material of following parts by weight:10~15 parts of nano-graphite particle, 5~10 parts of titanium dioxide, epoxidized soybean oil 20
~30 parts, 10~15 parts of blanc fixe, 40~50 parts of polyvinyl alcohol;The microcapsules heat discoloration layer is by microcapsule shell and sets
In the heat discoloration agent composition in microcapsule shell body;The microcapsule shell presses 1 for Arabic gum and gelatin:2 weight ratio is mixed
It closes, the heat discoloration agent is triphenylmenthane.
A further improvement is that:The preparation method of the microcapsules heat discoloration layer is that Arabic gum, gelatin are pressed 1:2
Mixing dissolves by heating, is subsequently added into triphenylmenthane, is re-fed into dry spray tower and is dried, the temperature of the dry spray tower
Control is at 150~160 DEG C.
A further improvement is that:The amount ratio of the heat discoloration agent and microcapsule shell is:=1 is calculated by weight:
10~16.
A further improvement is that:The amount ratio of the heat discoloration agent and microcapsule shell is:=1 is calculated by weight:
13。
A further improvement is that:The radiation protective layer includes each raw material of following parts by weight:Nano-graphite particle 13~15
Part, 6~10 parts of titanium dioxide, 25~30 parts of epoxidized soybean oil, 13~15 parts of blanc fixe, 45~50 parts of polyvinyl alcohol.
A further improvement is that:The base material bottom is non-woven fabrics or non-woven paper.
By using preceding solution, the beneficial effects of the invention are as follows:The environment-friendlyradiation-proof radiation-proof wall paper of the present invention, including
Base material bottom, the base material bottom are equipped with radiation protective layer, and the radiation protective layer is equipped with microcapsules heat discoloration layer, described anti-
Radiating layer includes each raw material of following parts by weight:10~15 parts of nano-graphite particle, 5~10 parts of titanium dioxide, epoxidized soybean oil 20
~30 parts, 10~15 parts of blanc fixe, 40~50 parts of polyvinyl alcohol;Nano-graphite particle, blanc fixe in radiation protective layer is equal
With preferable radiation proof function, blanc fixe can absorb a variety of rays in ambient enviroment, effectively prevent radiating, micro- glue
Capsule heat discoloration layer is made of microcapsule shell and the heat discoloration agent in microcapsule shell body, and microcapsules heat discoloration layer exists
Under light irradiation, as the variation of color occurs for the variation of ambient temperature, wallpaper of the invention that is, with radiation proof function, and has
The effect for generating color change can be changed with ambient temperature by having, and increase visual effect.Furthermore the raw material components used in the present invention are equal
It is nontoxic, it is more environmentally friendly.
Specific embodiment
Carry out the embodiment that the present invention will be described in detail below with reference to specific embodiment, how skill is applied to the present invention whereby
Art means solve technical problem, and the realization process for reaching technique effect can fully understand and implement according to this.
Unless otherwise specified, the conventional hand that the technological means employed in embodiment is well known to those skilled in the art
Section, used reagent and product are also available commercial.The source of agents useful for same, trade name and it is necessary to list it
Constituent person indicates on the first appearance.
Embodiment one
A kind of environment-friendlyradiation-proof radiation-proof wall paper, including non-woven fabrics base material bottom, the non-woven fabrics base material bottom is equipped with radiation protection
Layer, the radiation protective layer are equipped with microcapsules heat discoloration layer, and the radiation protective layer includes each raw material of following parts by weight:Nanometer
10 parts of graphite particle, 5 parts of titanium dioxide, 20 parts of epoxidized soybean oil, 10 parts of blanc fixe, 40 parts of polyvinyl alcohol;The microcapsules sense
1 part of heat discoloration agent of the warm photochromic layer by 10 parts of microcapsule shell and in microcapsule shell body forms;The microcapsule shell
1 is pressed for Arabic gum and gelatin:2 weight ratio mixes, and the heat discoloration agent is triphenylmenthane.
The preparation method of the microcapsules heat discoloration layer is that Arabic gum, gelatin are pressed 1:2 mixing, dissolve by heating, connect
Addition triphenylmenthane, dry spray tower is re-fed into and is dried, the temperature of the dry spray tower is controlled at 150 DEG C.
Embodiment two
A kind of environment-friendlyradiation-proof radiation-proof wall paper, including nonwoven paper base material bottom, the nonwoven paper base material bottom is equipped with radiation protection
Layer, the radiation protective layer are equipped with microcapsules heat discoloration layer, and the radiation protective layer includes each raw material of following parts by weight:Nanometer
13 parts of graphite particle, 6 parts of titanium dioxide, 25 parts of epoxidized soybean oil, 13 parts of blanc fixe, 45 parts of polyvinyl alcohol;The microcapsules sense
1 part of heat discoloration agent of the warm photochromic layer by 13 parts of microcapsule shell and in microcapsule shell body forms;The microcapsule shell
1 is pressed for Arabic gum and gelatin:2 weight ratio mixes, and the heat discoloration agent is triphenylmenthane.
The preparation method of the microcapsules heat discoloration layer is that Arabic gum, gelatin are pressed 1:2 mixing, dissolve by heating, connect
Addition triphenylmenthane, dry spray tower is re-fed into and is dried, the temperature of the dry spray tower is controlled at 155 DEG C.
Embodiment three
A kind of environment-friendlyradiation-proof radiation-proof wall paper, including non-woven fabrics base material bottom, the non-woven fabrics base material bottom is equipped with radiation protection
Layer, the radiation protective layer are equipped with microcapsules heat discoloration layer, and the radiation protective layer includes each raw material of following parts by weight:Nanometer
15 parts of graphite particle, 10 parts of titanium dioxide, 30 parts of epoxidized soybean oil, 15 parts of blanc fixe, 50 parts of polyvinyl alcohol;The microcapsules sense
1 part of heat discoloration agent of the warm photochromic layer by 16 parts of microcapsule shell and in microcapsule shell body forms;The microcapsule shell
1 is pressed for Arabic gum and gelatin:2 weight ratio mixes, and the heat discoloration agent is triphenylmenthane.
The preparation method of the microcapsules heat discoloration layer is that Arabic gum, gelatin are pressed 1:2 mixing, dissolve by heating, connect
Addition triphenylmenthane, dry spray tower is re-fed into and is dried, the temperature of the dry spray tower is controlled at 160 DEG C.
Wherein, in the present invention, the present invention can be achieved in each raw material components of the radiation protective layer in following parameter area
Purpose:10~15 parts of nano-graphite particle, 5~10 parts of titanium dioxide, 20~30 parts of epoxidized soybean oil, blanc fixe 10~15
Part, 40~50 parts of polyvinyl alcohol.The microcapsule shell and heat discoloration agent are 10~16:This hair can be achieved in the range of 1
Bright purpose.
The foregoing descriptions are merely the embodiment using this origination techniques content, any those skilled in the art use this wound
Make done modifications and changes, all belong to the scope of the claims of this creation opinion, and be not limited to those disclosed embodiments.
Claims (6)
1. a kind of environment-friendlyradiation-proof radiation-proof wall paper, it is characterised in that:Including base material bottom, the base material bottom is equipped with radiation protective layer,
The radiation protective layer is equipped with microcapsules heat discoloration layer, and the radiation protective layer includes each raw material of following parts by weight:Nanometer stone
Black 10~15 parts of particle, 5~10 parts of titanium dioxide, 20~30 parts of epoxidized soybean oil, 10~15 parts of blanc fixe, polyvinyl alcohol 40~
50 parts;The microcapsules heat discoloration layer is made of microcapsule shell and the heat discoloration agent in microcapsule shell body;It is described
Microcapsule shell presses 1 for Arabic gum and gelatin:2 weight ratio mixes, and the heat discoloration agent is triphenylmenthane.
2. a kind of environment-friendlyradiation-proof radiation-proof wall paper according to claim 1 or 2, it is characterised in that:The microcapsules heat discoloration
The preparation method of layer is that Arabic gum, gelatin are pressed 1:2 mixing, dissolve by heating, are subsequently added into triphenylmenthane, are re-fed into drying
Spray tower is dried, and the temperature of the dry spray tower is controlled at 150~160 DEG C.
3. a kind of environment-friendlyradiation-proof radiation-proof wall paper according to claim 2, it is characterised in that:The heat discoloration agent and microcapsules
The amount ratio of housing is:=1 is calculated by weight:10~16.
4. a kind of environment-friendlyradiation-proof radiation-proof wall paper according to claim 3, it is characterised in that:The heat discoloration agent and microcapsules
The amount ratio of housing is:=1 is calculated by weight:13.
5. a kind of environment-friendlyradiation-proof radiation-proof wall paper according to claim 4, it is characterised in that:The radiation protective layer includes following heavy
Measure each raw material of part:13~15 parts of nano-graphite particle, 6~10 parts of titanium dioxide, 25~30 parts of epoxidized soybean oil, blanc fixe 13
~15 parts, 45~50 parts of polyvinyl alcohol.
6. a kind of environment-friendlyradiation-proof radiation-proof wall paper according to claim 5, it is characterised in that:The base material bottom for non-woven fabrics or
Non-woven paper.
Priority Applications (1)
Application Number | Priority Date | Filing Date | Title |
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CN201611188211.8A CN108202519A (en) | 2016-12-20 | 2016-12-20 | A kind of environment-friendlyradiation-proof radiation-proof wall paper |
Applications Claiming Priority (1)
Application Number | Priority Date | Filing Date | Title |
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CN201611188211.8A CN108202519A (en) | 2016-12-20 | 2016-12-20 | A kind of environment-friendlyradiation-proof radiation-proof wall paper |
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Publication Number | Publication Date |
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CN108202519A true CN108202519A (en) | 2018-06-26 |
Family
ID=62604360
Family Applications (1)
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CN201611188211.8A Pending CN108202519A (en) | 2016-12-20 | 2016-12-20 | A kind of environment-friendlyradiation-proof radiation-proof wall paper |
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CN (1) | CN108202519A (en) |
Cited By (1)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
CN109880509A (en) * | 2019-01-29 | 2019-06-14 | 张家港康得新光电材料有限公司 | Aqueous allochroic paint and its painting membrane product |
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Cited By (1)
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CN109880509A (en) * | 2019-01-29 | 2019-06-14 | 张家港康得新光电材料有限公司 | Aqueous allochroic paint and its painting membrane product |
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