CN104371435A - Constructional solar reflective thermal insulating coating and preparation method thereof - Google Patents
Constructional solar reflective thermal insulating coating and preparation method thereof Download PDFInfo
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- C09D125/00—Coating compositions based on homopolymers or copolymers of compounds having one or more unsaturated aliphatic radicals, each having only one carbon-to-carbon double bond, and at least one being terminated by an aromatic carbocyclic ring; Coating compositions based on derivatives of such polymers
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Abstract
The invention provides a constructional solar reflective thermal insulating coating and a preparation method thereof. The coating is prepared from the following raw materials in parts by mass: 40-52 parts of styrene-acrylic emulsion, 14-25 parts of titanium dioxide, 3-8 parts of calcium carbonate, 2-5 parts of andalusite, 2-5 parts of bentonite, 3-6 parts of cyanite powder, 2-5 parts of mica powder, 0.3-0.7 part of lauryl sodium sulfate, 0.1-0.3 part of organo-siloxane, 0.2-0.5 part of dust-proofing agent, 0.07-0.18 part of dibutyl phthalate, 0.1-0.3 part of N,N-dimethylformamide, 0.8-1.6 parts of isopropanol, 1-4 parts of ammonium persulfate and 4-8 parts of water. The constructional solar reflective thermal insulating coating has an excellent reflection effect, and is good in flame retardance, crack resistance and watertightness.
Description
Technical field
The present invention relates to paint field, particularly relate to a kind of solar energy reflective insulation coating for construction and preparation method thereof.
Background technology
Building coating has decoration functions, defencive function and livability and improves function.Proportion shared by various function is not quite similar because application target is different.Decoration functions is the function of beautifying the appearance value improving it by buildings.Mainly comprise the design design of plane color, pattern and gloss aspect and the design design of three-dimensional pattern.But to match with the size and shape of the moulding of buildings itself and base material itself, just can fully play out.Defencive function refers to architecture protection thing not by the impact of environment and the function of destruction.The content that different types of protected body requires defencive function is also different.As just very large in the indoor index difference with reaching required by outdoor application.Some buildingss to mildew-resistant, fire prevention, heat insulating, corrosion-resistant etc. have particular requirement.Livability improves function mainly for indoor application, contributes to the function improving living environment exactly, as effect and classification, the antisweat etc. of sound-proofing, sound absorbing coating.Coating act as decoration and protection, protects by the surface being coated with jewelry, prevents the erosion of the light, oxygen, chemical substance, solvent etc. from the external world, improve the work-ing life of coated thing; Paint finishing material surface, changes its color, decorative pattern, gloss, texture etc., improves the aesthetic value of object.Wherein, a kind of well building coating during solar reflection coating.
Existing solar reflection coating kind for building is a lot of in the market, but its deficient function, generally its fire-retardant, cracking resistance, water-impervious poor-performing.Such as Chinese invention patent (the patent No. 200510028388.7, applying date 2005-08-02) disclose solar energy reflective insulation coating for construction, this coating has high reflectivity to most of wavelength in the radiation wave spectrum of the sun, but its easily cracking and infiltration; Chinese invention patent (patent No. 201180072968.X, applying date 2011-08-31) discloses solar reflection coating, and this coating has excellent reflecting effect, but otherwise function is poor.
Summary of the invention
the technical problem solved:for the defect that existing solar reflection coating for building exists, the invention provides a kind of solar energy reflective insulation coating for construction and preparation method thereof, this coating has excellent reflecting effect, and it is fire-retardant, cracking resistance, water-impervious performance are good.
technical scheme:a kind of solar energy reflective insulation coating for construction, comprise the following raw material according to mass fraction meter: benzene emulsion 40 ~ 52 parts, titanium dioxide 14 ~ 25 parts, 3 ~ 8 parts, calcium carbonate, 2 ~ 5 parts, Stanley stone, wilkinite 2 ~ 5 parts, aquamaine stone flour 3 ~ 6 parts, mica powder 2 ~ 5 parts, sodium lauryl sulphate 0.3 ~ 0.7 part, organo-siloxane 0.1 ~ 0.3 part, dust-proofing agent 0.2 ~ 0.5 part, dibutyl phthalate 0.07 ~ 0.18 part, DMF 0.1 ~ 0.3 part, Virahol 0.8 ~ 1.6 part, ammonium persulphate 1 ~ 4 part, 4 ~ 8 parts, water.
A kind of solar energy reflective insulation coating for construction described above, comprise the following raw material according to mass fraction meter: benzene emulsion 42 ~ 50 parts, titanium dioxide 15 ~ 23 parts, 4 ~ 7 parts, calcium carbonate, 3 ~ 4.5 parts, Stanley stone, wilkinite 3 ~ 4 parts, aquamaine stone flour 4 ~ 5.5 parts, mica powder 2.5 ~ 4 parts, sodium lauryl sulphate 0.4 ~ 0.6 part, organo-siloxane 0.15 ~ 0.25 part, dust-proofing agent 0.3 ~ 0.4 part, dibutyl phthalate 0.09 ~ 0.15 part, N, dinethylformamide 0.15 ~ 0.25 part, Virahol 1 ~ 1.5 part, ammonium persulphate 2 ~ 3.5 parts, 5 ~ 7 parts, water.
A kind of solar energy reflective insulation coating for construction described above, comprise the following raw material according to mass fraction meter: benzene emulsion 44 ~ 48 parts, titanium dioxide 18 ~ 22 parts, 5 ~ 6.5 parts, calcium carbonate, 3.5 ~ 4 parts, Stanley stone, wilkinite 3.3 ~ 3.8 parts, aquamaine stone flour 4.2 ~ 5 parts, mica powder 3 ~ 3.6 parts, sodium lauryl sulphate 0.45 ~ 0.55 part, organo-siloxane 0.17 ~ 0.23 part, dust-proofing agent 0.32 ~ 0.37 part, dibutyl phthalate 0.1 ~ 0.13 part, N, dinethylformamide 0.18 ~ 0.22 part, Virahol 1.1 ~ 1.4 parts, ammonium persulphate 2.5 ~ 3 parts, 5.5 ~ 6.5 parts, water.
A kind of solar energy reflective insulation coating for construction described above, comprises the following raw material according to mass fraction meter: benzene emulsion 45 parts, titanium dioxide 19 parts, 5.5 parts, calcium carbonate, 3.6 parts, Stanley stone, wilkinite 3.5 parts, aquamaine stone flour 4.4 parts, mica powder 3.2 parts, sodium lauryl sulphate 0.48 part, organo-siloxane 0.19 part, dust-proofing agent 0.33 part, dibutyl phthalate 0.11 part, DMF 0.19 part, Virahol 1.2 parts, ammonium persulphate 2.6 parts, 5.8 parts, water.
A kind of solar energy reflective insulation coating for construction described above, comprises the following raw material according to mass fraction meter: benzene emulsion 46 parts, titanium dioxide 20 parts, 5.7 parts, calcium carbonate, 3.8 parts, Stanley stone, wilkinite 3.55 parts, aquamaine stone flour 4.6 parts, mica powder 3.3 parts, sodium lauryl sulphate 0.5 part, organo-siloxane 0.2 part, dust-proofing agent 0.34 part, dibutyl phthalate 0.12 part, DMF 0.2 part, Virahol 1.25 parts, ammonium persulphate 2.8 parts, 6 parts, water.
The preparation method of a kind of solar energy reflective insulation coating for construction described above, comprises the steps:
(1) in agitator, add benzene emulsion and water, low whipping speed is be uniformly mixed 10 ~ 20min under 700 ~ 800r/min;
(2) sodium lauryl sulphate, organo-siloxane, dust-proofing agent, dibutyl phthalate, N is added again, dinethylformamide, Virahol and ammonium persulphate, 3 ~ 7min is uniformly mixed under rotating speed is 1300 ~ 1400 r/min, add titanium dioxide, calcium carbonate, Stanley stone, wilkinite, aquamaine stone flour, mica powder again, continue dispersed with stirring;
(3) be dispersed to fineness≤50 μm, discharging gets product.
In step (1) described above, low whipping speed is be uniformly mixed 15min under 750r/min
Under rotating speed is 1350 r/min, 5min is uniformly mixed in step (2) described above.
beneficial effect:compared with prior art, a kind of solar energy reflective insulation coating for construction provided by the invention and preparation method thereof, this coating has high reflectivity to wavelength most of in solar radiation spectrum, reduce the temperature difference of indoor and outdoor, play function of heat insulation, meanwhile, it is fire-retardant, cracking resistance, water-impervious performance are good, long service life.
Embodiment
embodiment 1
A kind of solar energy reflective insulation coating for construction, comprises the following raw material according to mass fraction meter: benzene emulsion 40 parts, titanium dioxide 14 parts, 3 parts, calcium carbonate, 2 parts, Stanley stone, wilkinite 2 parts, aquamaine stone flour 3 parts, mica powder 2 parts, sodium lauryl sulphate 0.3 part, organo-siloxane 0.1 part, dust-proofing agent 0.2 part, dibutyl phthalate 0.07 part, DMF 0.1 part, Virahol 0.8 part, ammonium persulphate 1 part, 4 parts, water.
A preparation method for solar energy reflective insulation coating for construction, comprises the steps:
(1) in agitator, add benzene emulsion and water, low whipping speed is be uniformly mixed 10min under 700r/min;
(2) sodium lauryl sulphate, organo-siloxane, dust-proofing agent, dibutyl phthalate, N is added again, dinethylformamide, Virahol and ammonium persulphate, 3min is uniformly mixed under rotating speed is 1300r/min, add titanium dioxide, calcium carbonate, Stanley stone, wilkinite, aquamaine stone flour, mica powder again, continue dispersed with stirring;
(3) be dispersed to fineness≤50 μm, discharging gets product.
embodiment 2
A kind of solar energy reflective insulation coating for construction, comprises the following raw material according to mass fraction meter: benzene emulsion 52 parts, titanium dioxide 25 parts, 8 parts, calcium carbonate, 5 parts, Stanley stone, wilkinite 5 parts, aquamaine stone flour 6 parts, mica powder 5 parts, sodium lauryl sulphate 0.7 part, organo-siloxane 0.3 part, dust-proofing agent 0.5 part, dibutyl phthalate 0.18 part, DMF 0.3 part, Virahol 1.6 parts, ammonium persulphate 4 parts, 8 parts, water.
A preparation method for solar energy reflective insulation coating for construction, comprises the steps:
(1) in agitator, add benzene emulsion and water, low whipping speed is be uniformly mixed 20min under 800r/min;
(2) sodium lauryl sulphate, organo-siloxane, dust-proofing agent, dibutyl phthalate, N is added again, dinethylformamide, Virahol and ammonium persulphate, 7min is uniformly mixed under rotating speed is 1400 r/min, add titanium dioxide, calcium carbonate, Stanley stone, wilkinite, aquamaine stone flour, mica powder again, continue dispersed with stirring;
(3) be dispersed to fineness≤50 μm, discharging gets product.
embodiment 3
A kind of solar energy reflective insulation coating for construction, comprises the following raw material according to mass fraction meter: benzene emulsion 42 parts, titanium dioxide 15 parts, 4 parts, calcium carbonate, 3 parts, Stanley stone, wilkinite 3 parts, aquamaine stone flour 4 parts, mica powder 2.5 parts, sodium lauryl sulphate 0.4 part, organo-siloxane 0.15 part, dust-proofing agent 0.3 part, dibutyl phthalate 0.09 part, DMF 0.15 part, Virahol 1 part, ammonium persulphate 2 parts, 5 parts, water.
A preparation method for solar energy reflective insulation coating for construction, comprises the steps:
(1) in agitator, add benzene emulsion and water, low whipping speed is be uniformly mixed 10min under 700r/min;
(2) sodium lauryl sulphate, organo-siloxane, dust-proofing agent, dibutyl phthalate, N is added again, dinethylformamide, Virahol and ammonium persulphate, 3min is uniformly mixed under rotating speed is 1300 r/min, add titanium dioxide, calcium carbonate, Stanley stone, wilkinite, aquamaine stone flour, mica powder again, continue dispersed with stirring;
(3) be dispersed to fineness≤50 μm, discharging gets product.
embodiment 4
A kind of solar energy reflective insulation coating for construction, comprises the following raw material according to mass fraction meter: benzene emulsion 50 parts, titanium dioxide 23 parts, 7 parts, calcium carbonate, 4.5 parts, Stanley stone, wilkinite 4 parts, aquamaine stone flour 5.5 parts, mica powder 4 parts, sodium lauryl sulphate 0.6 part, organo-siloxane 0.25 part, dust-proofing agent 0.4 part, dibutyl phthalate 0.15 part, DMF 0.25 part, Virahol 1.5 parts, ammonium persulphate 3.5 parts, 7 parts, water.
A preparation method for solar energy reflective insulation coating for construction, comprises the steps:
(1) in agitator, add benzene emulsion and water, low whipping speed is be uniformly mixed 20min under 800r/min;
(2) sodium lauryl sulphate, organo-siloxane, dust-proofing agent, dibutyl phthalate, N is added again, dinethylformamide, Virahol and ammonium persulphate, 7min is uniformly mixed under rotating speed is 1400 r/min, add titanium dioxide, calcium carbonate, Stanley stone, wilkinite, aquamaine stone flour, mica powder again, continue dispersed with stirring;
(3) be dispersed to fineness≤50 μm, discharging gets product.
embodiment 5
A kind of solar energy reflective insulation coating for construction, comprises the following raw material according to mass fraction meter: benzene emulsion 44 parts, titanium dioxide 18 parts, 5 parts, calcium carbonate, 3.5 parts, Stanley stone, wilkinite 3.3 parts, aquamaine stone flour 4.2 parts, mica powder 3 parts, sodium lauryl sulphate 0.45 part, organo-siloxane 0.17 part, dust-proofing agent 0.32 part, dibutyl phthalate 0.1 part, DMF 0.18 part, Virahol 1.1 parts, ammonium persulphate 2.5 parts, 5.5 parts, water.
A preparation method for solar energy reflective insulation coating for construction, comprises the steps:
(1) in agitator, add benzene emulsion and water, low whipping speed is be uniformly mixed 15min under 750r/min;
(2) sodium lauryl sulphate, organo-siloxane, dust-proofing agent, dibutyl phthalate, N is added again, dinethylformamide, Virahol and ammonium persulphate, 5min is uniformly mixed under rotating speed is 1350 r/min, add titanium dioxide, calcium carbonate, Stanley stone, wilkinite, aquamaine stone flour, mica powder again, continue dispersed with stirring;
(3) be dispersed to fineness≤50 μm, discharging gets product.
embodiment 6
A kind of solar energy reflective insulation coating for construction, comprises the following raw material according to mass fraction meter: benzene emulsion 48 parts, titanium dioxide 22 parts, 6.5 parts, calcium carbonate, 4 parts, Stanley stone, wilkinite 3.8 parts, aquamaine stone flour 5 parts, mica powder 3.6 parts, sodium lauryl sulphate 0.55 part, organo-siloxane 0.23 part, dust-proofing agent 0.37 part, dibutyl phthalate 0.13 part, DMF 0.22 part, Virahol 1.4 parts, ammonium persulphate 3 parts, 6.5 parts, water.
A preparation method for solar energy reflective insulation coating for construction, comprises the steps:
(1) in agitator, add benzene emulsion and water, low whipping speed is be uniformly mixed 15min under 750r/min;
(2) sodium lauryl sulphate, organo-siloxane, dust-proofing agent, dibutyl phthalate, N is added again, dinethylformamide, Virahol and ammonium persulphate, 5min is uniformly mixed under rotating speed is 1350 r/min, add titanium dioxide, calcium carbonate, Stanley stone, wilkinite, aquamaine stone flour, mica powder again, continue dispersed with stirring;
(3) be dispersed to fineness≤50 μm, discharging gets product.
embodiment 7
A kind of solar energy reflective insulation coating for construction, comprises the following raw material according to mass fraction meter: benzene emulsion 45 parts, titanium dioxide 19 parts, 5.5 parts, calcium carbonate, 3.6 parts, Stanley stone, wilkinite 3.5 parts, aquamaine stone flour 4.4 parts, mica powder 3.2 parts, sodium lauryl sulphate 0.48 part, organo-siloxane 0.19 part, dust-proofing agent 0.33 part, dibutyl phthalate 0.11 part, DMF 0.19 part, Virahol 1.2 parts, ammonium persulphate 2.6 parts, 5.8 parts, water.
A preparation method for solar energy reflective insulation coating for construction, comprises the steps:
(1) in agitator, add benzene emulsion and water, low whipping speed is be uniformly mixed 15min under 750r/min;
(2) sodium lauryl sulphate, organo-siloxane, dust-proofing agent, dibutyl phthalate, N is added again, dinethylformamide, Virahol and ammonium persulphate, 5min is uniformly mixed under rotating speed is 1350 r/min, add titanium dioxide, calcium carbonate, Stanley stone, wilkinite, aquamaine stone flour, mica powder again, continue dispersed with stirring;
(3) be dispersed to fineness≤50 μm, discharging gets product.
embodiment 8
A kind of solar energy reflective insulation coating for construction, comprises the following raw material according to mass fraction meter: benzene emulsion 46 parts, titanium dioxide 20 parts, 5.7 parts, calcium carbonate, 3.8 parts, Stanley stone, wilkinite 3.55 parts, aquamaine stone flour 4.6 parts, mica powder 3.3 parts, sodium lauryl sulphate 0.5 part, organo-siloxane 0.2 part, dust-proofing agent 0.34 part, dibutyl phthalate 0.12 part, DMF 0.2 part, Virahol 1.25 parts, ammonium persulphate 2.8 parts, 6 parts, water.
A preparation method for solar energy reflective insulation coating for construction, comprises the steps:
(1) in agitator, add benzene emulsion and water, low whipping speed is be uniformly mixed 15min under 750r/min;
(2) sodium lauryl sulphate, organo-siloxane, dust-proofing agent, dibutyl phthalate, N is added again, dinethylformamide, Virahol and ammonium persulphate, 5min is uniformly mixed under rotating speed is 1350 r/min, add titanium dioxide, calcium carbonate, Stanley stone, wilkinite, aquamaine stone flour, mica powder again, continue dispersed with stirring;
(3) be dispersed to fineness≤50 μm, discharging gets product.
performance test
Test the performance of the embodiment of the present invention 1 ~ 8 product, test result is in table 1.
Table 1 product performance test data
| Embodiment 1 | Embodiment 2 | Embodiment 3 | Embodiment 4 | Embodiment 5 | Embodiment 6 | Embodiment 7 | Embodiment 8 | |
| Sunlight transmitance (%) | 7.2 | 6.5 | 6.3 | 5.7 | 5.6 | 5.3 | 4.5 | 3.8 |
| Thermal insulation (DEG C, have be coated with charge level and without the painting charge level temperature difference) | 26 | 27 | 25 | 28 | 31 | 33 | 32 | 35 |
Above to invention has been detailed introduction, for one of ordinary skill in the art, according to the thought of the embodiment of the present invention, all will change in specific embodiments and applications, in sum, this description should not be construed as limitation of the present invention.
Claims (8)
1. a solar energy reflective insulation coating for construction, it is characterized in that comprising the following raw material according to mass fraction meter: benzene emulsion 40 ~ 52 parts, titanium dioxide 14 ~ 25 parts, 3 ~ 8 parts, calcium carbonate, 2 ~ 5 parts, Stanley stone, wilkinite 2 ~ 5 parts, aquamaine stone flour 3 ~ 6 parts, mica powder 2 ~ 5 parts, sodium lauryl sulphate 0.3 ~ 0.7 part, organo-siloxane 0.1 ~ 0.3 part, dust-proofing agent 0.2 ~ 0.5 part, dibutyl phthalate 0.07 ~ 0.18 part, DMF 0.1 ~ 0.3 part, Virahol 0.8 ~ 1.6 part, ammonium persulphate 1 ~ 4 part, 4 ~ 8 parts, water.
2. a kind of solar energy reflective insulation coating for construction according to claim 1, it is characterized in that comprising the following raw material according to mass fraction meter: benzene emulsion 42 ~ 50 parts, titanium dioxide 15 ~ 23 parts, 4 ~ 7 parts, calcium carbonate, 3 ~ 4.5 parts, Stanley stone, wilkinite 3 ~ 4 parts, aquamaine stone flour 4 ~ 5.5 parts, mica powder 2.5 ~ 4 parts, sodium lauryl sulphate 0.4 ~ 0.6 part, organo-siloxane 0.15 ~ 0.25 part, dust-proofing agent 0.3 ~ 0.4 part, dibutyl phthalate 0.09 ~ 0.15 part, N, dinethylformamide 0.15 ~ 0.25 part, Virahol 1 ~ 1.5 part, ammonium persulphate 2 ~ 3.5 parts, 5 ~ 7 parts, water.
3. a kind of solar energy reflective insulation coating for construction according to claim 1, it is characterized in that comprising the following raw material according to mass fraction meter: benzene emulsion 44 ~ 48 parts, titanium dioxide 18 ~ 22 parts, 5 ~ 6.5 parts, calcium carbonate, 3.5 ~ 4 parts, Stanley stone, wilkinite 3.3 ~ 3.8 parts, aquamaine stone flour 4.2 ~ 5 parts, mica powder 3 ~ 3.6 parts, sodium lauryl sulphate 0.45 ~ 0.55 part, organo-siloxane 0.17 ~ 0.23 part, dust-proofing agent 0.32 ~ 0.37 part, dibutyl phthalate 0.1 ~ 0.13 part, N, dinethylformamide 0.18 ~ 0.22 part, Virahol 1.1 ~ 1.4 parts, ammonium persulphate 2.5 ~ 3 parts, 5.5 ~ 6.5 parts, water.
4. a kind of solar energy reflective insulation coating for construction according to claim 1, it is characterized in that comprising the following raw material according to mass fraction meter: benzene emulsion 45 parts, titanium dioxide 19 parts, 5.5 parts, calcium carbonate, 3.6 parts, Stanley stone, wilkinite 3.5 parts, aquamaine stone flour 4.4 parts, mica powder 3.2 parts, sodium lauryl sulphate 0.48 part, organo-siloxane 0.19 part, dust-proofing agent 0.33 part, dibutyl phthalate 0.11 part, DMF 0.19 part, Virahol 1.2 parts, ammonium persulphate 2.6 parts, 5.8 parts, water.
5. a kind of solar energy reflective insulation coating for construction according to claim 1, it is characterized in that comprising the following raw material according to mass fraction meter: benzene emulsion 46 parts, titanium dioxide 20 parts, 5.7 parts, calcium carbonate, 3.8 parts, Stanley stone, wilkinite 3.55 parts, aquamaine stone flour 4.6 parts, mica powder 3.3 parts, sodium lauryl sulphate 0.5 part, organo-siloxane 0.2 part, dust-proofing agent 0.34 part, dibutyl phthalate 0.12 part, DMF 0.2 part, Virahol 1.25 parts, ammonium persulphate 2.8 parts, 6 parts, water.
6. the preparation method of a kind of solar energy reflective insulation coating for construction as claimed in claim 1, is characterized in that comprising the steps:
(1) in agitator, add benzene emulsion and water, low whipping speed is be uniformly mixed 10 ~ 20min under 700 ~ 800r/min;
(2) sodium lauryl sulphate, organo-siloxane, dust-proofing agent, dibutyl phthalate, N is added again, dinethylformamide, Virahol and ammonium persulphate, 3 ~ 7min is uniformly mixed under rotating speed is 1300 ~ 1400 r/min, add titanium dioxide, calcium carbonate, Stanley stone, wilkinite, aquamaine stone flour, mica powder again, continue dispersed with stirring;
(3) be dispersed to fineness≤50 μm, discharging gets product.
7. the preparation method of a kind of solar energy reflective insulation coating for construction according to claim 6, is characterized in that in described step (1), low whipping speed is be uniformly mixed 15min under 750r/min.
8. the preparation method of a kind of solar energy reflective insulation coating for construction according to claim 6, is characterized in that under rotating speed is 1350 r/min, being uniformly mixed 5min in described step (2).
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| Application Number | Priority Date | Filing Date | Title |
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| CN201410642173.3A CN104371435A (en) | 2014-11-13 | 2014-11-13 | Constructional solar reflective thermal insulating coating and preparation method thereof |
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Cited By (3)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN104761969A (en) * | 2015-03-18 | 2015-07-08 | 蚌埠市高华电子有限公司 | Anti-freezing radiation heat-insulating coating and preparation method thereof |
| CN104761976A (en) * | 2015-03-18 | 2015-07-08 | 蚌埠市高华电子有限公司 | Novel irradiation heat-insulation coating and preparation method thereof |
| CN113861728A (en) * | 2021-10-11 | 2021-12-31 | 无锡市南方耐材有限公司 | High-temperature air leakage prevention expansion coating for tundish sleeve and preparation method thereof |
-
2014
- 2014-11-13 CN CN201410642173.3A patent/CN104371435A/en not_active Withdrawn
Cited By (3)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN104761969A (en) * | 2015-03-18 | 2015-07-08 | 蚌埠市高华电子有限公司 | Anti-freezing radiation heat-insulating coating and preparation method thereof |
| CN104761976A (en) * | 2015-03-18 | 2015-07-08 | 蚌埠市高华电子有限公司 | Novel irradiation heat-insulation coating and preparation method thereof |
| CN113861728A (en) * | 2021-10-11 | 2021-12-31 | 无锡市南方耐材有限公司 | High-temperature air leakage prevention expansion coating for tundish sleeve and preparation method thereof |
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Application publication date: 20150225 |