CN108182984A - 一种离子液体改性聚吡咯导电材料 - Google Patents
一种离子液体改性聚吡咯导电材料 Download PDFInfo
- Publication number
- CN108182984A CN108182984A CN201810057389.1A CN201810057389A CN108182984A CN 108182984 A CN108182984 A CN 108182984A CN 201810057389 A CN201810057389 A CN 201810057389A CN 108182984 A CN108182984 A CN 108182984A
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- Prior art keywords
- ion liquid
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- added
- modified polypyrrole
- liquid modified
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- 229920000128 polypyrrole Polymers 0.000 title claims abstract description 61
- 239000007788 liquid Substances 0.000 title claims abstract description 48
- 239000004020 conductor Substances 0.000 title claims abstract description 25
- 150000002500 ions Chemical class 0.000 claims abstract description 44
- 239000002994 raw material Substances 0.000 claims abstract description 15
- -1 dimethyl dimercapto 2-ethyl hexyl ethanoate tin Chemical compound 0.000 claims abstract description 13
- YRIZYWQGELRKNT-UHFFFAOYSA-N 1,3,5-trichloro-1,3,5-triazinane-2,4,6-trione Chemical compound ClN1C(=O)N(Cl)C(=O)N(Cl)C1=O YRIZYWQGELRKNT-UHFFFAOYSA-N 0.000 claims abstract description 9
- TXSUIVPRHHQNTM-UHFFFAOYSA-N n'-(3-methylanilino)-n-phenyliminobenzenecarboximidamide Chemical compound CC1=CC=CC(NN=C(N=NC=2C=CC=CC=2)C=2C=CC=CC=2)=C1 TXSUIVPRHHQNTM-UHFFFAOYSA-N 0.000 claims abstract description 9
- SRESKMPUIWAGML-UHFFFAOYSA-N n,n-dimethyldecan-1-amine;hydrobromide Chemical class Br.CCCCCCCCCCN(C)C SRESKMPUIWAGML-UHFFFAOYSA-N 0.000 claims abstract description 9
- 229950009390 symclosene Drugs 0.000 claims abstract description 9
- 150000008301 phosphite esters Chemical class 0.000 claims abstract description 5
- YHMYGUUIMTVXNW-UHFFFAOYSA-N 1,3-dihydrobenzimidazole-2-thione Chemical class C1=CC=C2NC(S)=NC2=C1 YHMYGUUIMTVXNW-UHFFFAOYSA-N 0.000 claims abstract description 3
- 239000000243 solution Substances 0.000 claims description 45
- 150000001408 amides Chemical class 0.000 claims description 25
- 238000003756 stirring Methods 0.000 claims description 24
- 238000006243 chemical reaction Methods 0.000 claims description 17
- XLYOFNOQVPJJNP-UHFFFAOYSA-N water Chemical compound O XLYOFNOQVPJJNP-UHFFFAOYSA-N 0.000 claims description 16
- 239000002253 acid Substances 0.000 claims description 15
- RBTARNINKXHZNM-UHFFFAOYSA-K iron trichloride Chemical compound Cl[Fe](Cl)Cl RBTARNINKXHZNM-UHFFFAOYSA-K 0.000 claims description 13
- ZMXDDKWLCZADIW-UHFFFAOYSA-N N,N-Dimethylformamide Chemical compound CN(C)C=O ZMXDDKWLCZADIW-UHFFFAOYSA-N 0.000 claims description 12
- 239000008367 deionised water Substances 0.000 claims description 12
- 229910021641 deionized water Inorganic materials 0.000 claims description 12
- IJGRMHOSHXDMSA-UHFFFAOYSA-N Atomic nitrogen Chemical compound N#N IJGRMHOSHXDMSA-UHFFFAOYSA-N 0.000 claims description 10
- 150000003233 pyrroles Chemical class 0.000 claims description 10
- OYPRJOBELJOOCE-UHFFFAOYSA-N Calcium Chemical compound [Ca] OYPRJOBELJOOCE-UHFFFAOYSA-N 0.000 claims description 9
- 241000158728 Meliaceae Species 0.000 claims description 9
- 229910052791 calcium Inorganic materials 0.000 claims description 9
- 239000011575 calcium Substances 0.000 claims description 9
- BDHFUVZGWQCTTF-UHFFFAOYSA-M sulfonate Chemical compound [O-]S(=O)=O BDHFUVZGWQCTTF-UHFFFAOYSA-M 0.000 claims description 9
- 230000001476 alcoholic effect Effects 0.000 claims description 8
- 238000007599 discharging Methods 0.000 claims description 8
- 239000000203 mixture Substances 0.000 claims description 8
- 238000002360 preparation method Methods 0.000 claims description 8
- 239000006185 dispersion Substances 0.000 claims description 7
- 229910052757 nitrogen Inorganic materials 0.000 claims description 5
- LFQSCWFLJHTTHZ-UHFFFAOYSA-N Ethanol Chemical compound CCO LFQSCWFLJHTTHZ-UHFFFAOYSA-N 0.000 claims description 4
- 229910021578 Iron(III) chloride Inorganic materials 0.000 claims description 4
- ATJFFYVFTNAWJD-UHFFFAOYSA-N Tin Chemical compound [Sn] ATJFFYVFTNAWJD-UHFFFAOYSA-N 0.000 claims description 4
- 238000007605 air drying Methods 0.000 claims description 4
- 239000007864 aqueous solution Substances 0.000 claims description 4
- 238000001816 cooling Methods 0.000 claims description 4
- 150000002148 esters Chemical class 0.000 claims description 4
- 238000001914 filtration Methods 0.000 claims description 4
- 238000002156 mixing Methods 0.000 claims description 4
- 239000002244 precipitate Substances 0.000 claims description 4
- 125000000118 dimethyl group Chemical group [H]C([H])([H])* 0.000 claims description 3
- ZXLOSLWIGFGPIU-UHFFFAOYSA-N 1-ethyl-3-methyl-1,2-dihydroimidazol-1-ium;acetate Chemical compound CC(O)=O.CCN1CN(C)C=C1 ZXLOSLWIGFGPIU-UHFFFAOYSA-N 0.000 claims description 2
- 239000000463 material Substances 0.000 abstract description 7
- OKTJSMMVPCPJKN-UHFFFAOYSA-N Carbon Chemical compound [C] OKTJSMMVPCPJKN-UHFFFAOYSA-N 0.000 description 3
- 150000001875 compounds Chemical class 0.000 description 3
- 238000000034 method Methods 0.000 description 3
- KAESVJOAVNADME-UHFFFAOYSA-N Pyrrole Chemical compound C=1C=CNC=1 KAESVJOAVNADME-UHFFFAOYSA-N 0.000 description 2
- 239000002041 carbon nanotube Substances 0.000 description 2
- 229910021393 carbon nanotube Inorganic materials 0.000 description 2
- 229920001940 conductive polymer Polymers 0.000 description 2
- BPMFZUMJYQTVII-UHFFFAOYSA-N guanidinoacetic acid Chemical compound NC(=N)NCC(O)=O BPMFZUMJYQTVII-UHFFFAOYSA-N 0.000 description 2
- 239000002608 ionic liquid Substances 0.000 description 2
- 239000000178 monomer Substances 0.000 description 2
- 238000002604 ultrasonography Methods 0.000 description 2
- HYZJCKYKOHLVJF-UHFFFAOYSA-N 1H-benzimidazole Chemical compound C1=CC=C2NC=NC2=C1 HYZJCKYKOHLVJF-UHFFFAOYSA-N 0.000 description 1
- 239000002216 antistatic agent Substances 0.000 description 1
- 239000003990 capacitor Substances 0.000 description 1
- 229910052799 carbon Inorganic materials 0.000 description 1
- 239000003575 carbonaceous material Substances 0.000 description 1
- 238000006555 catalytic reaction Methods 0.000 description 1
- 239000002131 composite material Substances 0.000 description 1
- 239000012141 concentrate Substances 0.000 description 1
- 239000002322 conducting polymer Substances 0.000 description 1
- 230000007547 defect Effects 0.000 description 1
- 230000007812 deficiency Effects 0.000 description 1
- 238000001514 detection method Methods 0.000 description 1
- 239000002019 doping agent Substances 0.000 description 1
- 230000000694 effects Effects 0.000 description 1
- 239000002305 electric material Substances 0.000 description 1
- 230000005611 electricity Effects 0.000 description 1
- 239000007772 electrode material Substances 0.000 description 1
- 238000005516 engineering process Methods 0.000 description 1
- 239000007789 gas Substances 0.000 description 1
- JMANVNJQNLATNU-UHFFFAOYSA-N glycolonitrile Natural products N#CC#N JMANVNJQNLATNU-UHFFFAOYSA-N 0.000 description 1
- 239000012528 membrane Substances 0.000 description 1
- LUPFEBYGUGEEQA-UHFFFAOYSA-N methyl 2,2-bis(sulfanyl)propanoate Chemical compound COC(=O)C(C)(S)S LUPFEBYGUGEEQA-UHFFFAOYSA-N 0.000 description 1
- 239000007800 oxidant agent Substances 0.000 description 1
- 230000003647 oxidation Effects 0.000 description 1
- 238000007254 oxidation reaction Methods 0.000 description 1
- 230000001590 oxidative effect Effects 0.000 description 1
- 238000011056 performance test Methods 0.000 description 1
- 229920000642 polymer Polymers 0.000 description 1
- 238000004321 preservation Methods 0.000 description 1
- 239000000047 product Substances 0.000 description 1
- QLNJFJADRCOGBJ-UHFFFAOYSA-N propionamide Chemical compound CCC(N)=O QLNJFJADRCOGBJ-UHFFFAOYSA-N 0.000 description 1
- 229940080818 propionamide Drugs 0.000 description 1
- 238000000926 separation method Methods 0.000 description 1
- PXQLVRUNWNTZOS-UHFFFAOYSA-N sulfanyl Chemical class [SH] PXQLVRUNWNTZOS-UHFFFAOYSA-N 0.000 description 1
Classifications
-
- H—ELECTRICITY
- H01—ELECTRIC ELEMENTS
- H01B—CABLES; CONDUCTORS; INSULATORS; SELECTION OF MATERIALS FOR THEIR CONDUCTIVE, INSULATING OR DIELECTRIC PROPERTIES
- H01B1/00—Conductors or conductive bodies characterised by the conductive materials; Selection of materials as conductors
- H01B1/06—Conductors or conductive bodies characterised by the conductive materials; Selection of materials as conductors mainly consisting of other non-metallic substances
-
- H—ELECTRICITY
- H01—ELECTRIC ELEMENTS
- H01B—CABLES; CONDUCTORS; INSULATORS; SELECTION OF MATERIALS FOR THEIR CONDUCTIVE, INSULATING OR DIELECTRIC PROPERTIES
- H01B1/00—Conductors or conductive bodies characterised by the conductive materials; Selection of materials as conductors
- H01B1/06—Conductors or conductive bodies characterised by the conductive materials; Selection of materials as conductors mainly consisting of other non-metallic substances
- H01B1/12—Conductors or conductive bodies characterised by the conductive materials; Selection of materials as conductors mainly consisting of other non-metallic substances organic substances
- H01B1/124—Intrinsically conductive polymers
- H01B1/127—Intrinsically conductive polymers comprising five-membered aromatic rings in the main chain, e.g. polypyrroles, polythiophenes
-
- H—ELECTRICITY
- H01—ELECTRIC ELEMENTS
- H01B—CABLES; CONDUCTORS; INSULATORS; SELECTION OF MATERIALS FOR THEIR CONDUCTIVE, INSULATING OR DIELECTRIC PROPERTIES
- H01B13/00—Apparatus or processes specially adapted for manufacturing conductors or cables
Landscapes
- Engineering & Computer Science (AREA)
- Manufacturing & Machinery (AREA)
- Physics & Mathematics (AREA)
- Spectroscopy & Molecular Physics (AREA)
- Polyoxymethylene Polymers And Polymers With Carbon-To-Carbon Bonds (AREA)
Abstract
Description
Claims (4)
Priority Applications (1)
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CN201810057389.1A CN108182984B (zh) | 2018-01-22 | 2018-01-22 | 一种离子液体改性聚吡咯导电材料 |
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CN201810057389.1A CN108182984B (zh) | 2018-01-22 | 2018-01-22 | 一种离子液体改性聚吡咯导电材料 |
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CN108182984A true CN108182984A (zh) | 2018-06-19 |
CN108182984B CN108182984B (zh) | 2019-08-23 |
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Cited By (1)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
CN110484746A (zh) * | 2019-08-27 | 2019-11-22 | 浙江工业大学 | 一种贵金属浸出剂及从废催化剂中回收贵金属的方法 |
Citations (6)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
CN101314639A (zh) * | 2008-06-26 | 2008-12-03 | 华东理工大学 | 一种以含Fe(Ⅲ)离子液体为氧化剂制备聚吡咯的方法 |
CN101492545A (zh) * | 2009-02-17 | 2009-07-29 | 武汉工程大学 | 超级电容器用聚吡咯/聚噻吩衍生物复合导电高分子材料的制备方法 |
CN101928459A (zh) * | 2010-09-03 | 2010-12-29 | 华东理工大学 | 一种制备磁性纳米聚吡咯材料的方法 |
CN102516538A (zh) * | 2011-12-15 | 2012-06-27 | 河海大学 | 界面聚合制备纤维网络结构导电聚吡咯膜的方法 |
CN104034432A (zh) * | 2014-06-18 | 2014-09-10 | 中国人民大学 | 一种近红外传感芯片及其制备方法与应用 |
CN107501932A (zh) * | 2017-09-04 | 2017-12-22 | 苏州宇希新材料科技有限公司 | 一种轻质聚吡咯材料的制备方法 |
-
2018
- 2018-01-22 CN CN201810057389.1A patent/CN108182984B/zh active Active
Patent Citations (6)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
CN101314639A (zh) * | 2008-06-26 | 2008-12-03 | 华东理工大学 | 一种以含Fe(Ⅲ)离子液体为氧化剂制备聚吡咯的方法 |
CN101492545A (zh) * | 2009-02-17 | 2009-07-29 | 武汉工程大学 | 超级电容器用聚吡咯/聚噻吩衍生物复合导电高分子材料的制备方法 |
CN101928459A (zh) * | 2010-09-03 | 2010-12-29 | 华东理工大学 | 一种制备磁性纳米聚吡咯材料的方法 |
CN102516538A (zh) * | 2011-12-15 | 2012-06-27 | 河海大学 | 界面聚合制备纤维网络结构导电聚吡咯膜的方法 |
CN104034432A (zh) * | 2014-06-18 | 2014-09-10 | 中国人民大学 | 一种近红外传感芯片及其制备方法与应用 |
CN107501932A (zh) * | 2017-09-04 | 2017-12-22 | 苏州宇希新材料科技有限公司 | 一种轻质聚吡咯材料的制备方法 |
Cited By (2)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
CN110484746A (zh) * | 2019-08-27 | 2019-11-22 | 浙江工业大学 | 一种贵金属浸出剂及从废催化剂中回收贵金属的方法 |
CN110484746B (zh) * | 2019-08-27 | 2021-12-07 | 浙江工业大学 | 一种贵金属浸出剂及从废催化剂中回收贵金属的方法 |
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CN108182984B (zh) | 2019-08-23 |
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Effective date of registration: 20190731 Address after: 311404 Songxi Village, Xindeng Town, Fuyang District, Hangzhou City, Zhejiang Province Applicant after: Hangzhou Fuyang Zhengcheng Machinery and Equipment Factory Address before: 310013 Zijingang Campus, Zhejiang University, 866 Yuhangtang Road, Xihu District, Hangzhou City, Zhejiang Province Applicant before: Wang Yixu |
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Effective date of registration: 20211220 Address after: 410000 rooms 516 and 518, building B2, Lugu science and technology innovation and entrepreneurship Park, No. 1698, Yuelu West Avenue, high tech Development Zone, Changsha City, Hunan Province Patentee after: Hunan size Photoelectric Technology Co.,Ltd. Address before: 311404 Songxi village, Xindeng Town, Fuyang District, Hangzhou City, Zhejiang Province Patentee before: Hangzhou Fuyang Zhengcheng Machinery and Equipment Factory |