CN108178276A - A kind of fishery substrate modifier and preparation method thereof - Google Patents
A kind of fishery substrate modifier and preparation method thereof Download PDFInfo
- Publication number
- CN108178276A CN108178276A CN201611121082.0A CN201611121082A CN108178276A CN 108178276 A CN108178276 A CN 108178276A CN 201611121082 A CN201611121082 A CN 201611121082A CN 108178276 A CN108178276 A CN 108178276A
- Authority
- CN
- China
- Prior art keywords
- zeolite powder
- fishery
- chloride
- frerrous chloride
- sodium percarbonate
- Prior art date
- Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
- Pending
Links
Classifications
-
- C—CHEMISTRY; METALLURGY
- C02—TREATMENT OF WATER, WASTE WATER, SEWAGE, OR SLUDGE
- C02F—TREATMENT OF WATER, WASTE WATER, SEWAGE, OR SLUDGE
- C02F1/00—Treatment of water, waste water, or sewage
- C02F1/72—Treatment of water, waste water, or sewage by oxidation
- C02F1/722—Oxidation by peroxides
-
- C—CHEMISTRY; METALLURGY
- C02—TREATMENT OF WATER, WASTE WATER, SEWAGE, OR SLUDGE
- C02F—TREATMENT OF WATER, WASTE WATER, SEWAGE, OR SLUDGE
- C02F1/00—Treatment of water, waste water, or sewage
- C02F1/50—Treatment of water, waste water, or sewage by addition or application of a germicide or by oligodynamic treatment
-
- C—CHEMISTRY; METALLURGY
- C02—TREATMENT OF WATER, WASTE WATER, SEWAGE, OR SLUDGE
- C02F—TREATMENT OF WATER, WASTE WATER, SEWAGE, OR SLUDGE
- C02F1/00—Treatment of water, waste water, or sewage
- C02F1/72—Treatment of water, waste water, or sewage by oxidation
-
- C—CHEMISTRY; METALLURGY
- C02—TREATMENT OF WATER, WASTE WATER, SEWAGE, OR SLUDGE
- C02F—TREATMENT OF WATER, WASTE WATER, SEWAGE, OR SLUDGE
- C02F2305/00—Use of specific compounds during water treatment
- C02F2305/02—Specific form of oxidant
- C02F2305/026—Fenton's reagent
Abstract
The present invention relates to a kind of fishery substrate modifiers, are made of SODIUM PERCARBONATE 50%, zeolite powder 40%, frerrous chloride 5%, carboxymethyl cellulose 5%, the preparation method of the modifying agent weighs 1000kg raw materials by weight percentage；It will be dissolved in frerrous chloride therein or the ferrous sulfate of equivalent weight input 150L water, obtain solution of ferrous chloride；Obtained solution of ferrous chloride with zeolite powder is mixed, and is sufficiently stirred, dries；The frerrous chloride and the mixture of zeolite powder that above-mentioned drying is finished are sufficiently mixed and stir evenly with SODIUM PERCARBONATE, sodium carboxymethylcellulose successively, carry out compressing tablet process.The present invention has the beneficial effect that：Have many advantages, such as that cost is relatively low, oxidability is strong, application effect is notable, action time is short, be not easy to cause acute injury to cultivation object.
Description
Technical field
The present invention relates to technical field of aquaculture more particularly to a kind of fishery substrate modifier and preparation method thereof.
Background technology
Nowadays, aquaculture practitioner more pursues high yield, thus, the breeding density of the water body of unit area or volume
Also it is increasing, it means that the feed dosage of unit area or volume water body is also increasing, further just causes foster
For the native pool, also there is substrate deterioration in the water quality deterioration during growing.Either water quality deterioration or substrate are disliked
Change, can all cause very negative impact to cultivation object or even jeopardize the life of cultivation object.
For water quality deterioration, can be improved by changing water or adding the measures such as improver of water quality；Deteriorate for substrate, also may be used
By dredging, add the measures such as substrate modifier and improve.But the way of dredging carries out all before and after cultivation, in the breeding process
Can not generally it implement, therefore in the breeding process mostly using the way for adding substrate modifier.
Existing substrate modifier has mainly and has adsorbent class, oxidants, probiotics class this three classes, oxygen therein
Agent class substrate modifier because its significant effect, it is cheap and with certain oxygenation effect due to by widely used.Common
Oxidants substrate modifier has calper calcium peroxide, SODIUM PERCARBONATE, potassium hydrogen persulfate etc..Wherein, calper calcium peroxide, SODIUM PERCARBONATE price
Cheaply, but oxidability is not good enough；Potassium hydrogen persulfate oxidability is stronger, but expensive.
Therefore, the fishery substrate modifier for needing a kind of oxidability strong and cheap at present.
Invention content
For disadvantages described above, a kind of cost of present invention offer is relatively low, oxidability is strong, application effect is notable, action time
It is short, be not easy to cause cultivation object fishery substrate modifier and preparation method thereof of acute injury.
To achieve the above object, the present invention uses following technical scheme：
A kind of fishery substrate modifier, comprises the following raw materials by weight percent：
SODIUM PERCARBONATE 50%；
Zeolite powder 40%；
Frerrous chloride 5%；
Carboxymethyl cellulose 5%；
A kind of preparation method of fishery substrate modifier, comprises the steps of：
(1) 1000kg raw materials are weighed by weight percentage, include SODIUM PERCARBONATE 50%, zeolite powder 40%, frerrous chloride
5%th, carboxymethyl cellulose 5%；
(2) it will be dissolved in frerrous chloride therein or the ferrous sulfate of equivalent weight input 150L water, obtain frerrous chloride
Solution；
(3) obtained solution of ferrous chloride with zeolite powder is mixed, and is sufficiently stirred, dries；
(4) frerrous chloride and the mixture of zeolite powder finished above-mentioned drying successively with SODIUM PERCARBONATE, carboxymethyl cellulose
Plain sodium is sufficiently mixed and stirs evenly, carry out compressing tablet process, formed pellet diameter be 6mm, tableting pressure 8kg/cm2。
This modifying agent is reacted using peroxy with iron ion generates hydroxyl radical free radical, as quick-acting oxygenation agents.
Fishery substrate modifier of the present invention and preparation method thereof has the beneficial effect that：
(1) with cost is relatively low, oxidability is strong, application effect is notable, action time is short, is not easy to cause cultivation object
The advantages that acute injury；
(2) in addition, also " Fenton's reaction " can occur by using peroxy and iron ion generates hydroxyl radical free radical, oxidation
Property is extremely strong, and the oxidability in nature is only second to fluorine simple substance, meanwhile, also there are quick-acting oxygenation agents in the application.
Specific embodiment
Fishery substrate modifier described in the embodiment of the present invention, is made of the raw material of following weight percent：
SODIUM PERCARBONATE 50%；
Zeolite powder 40%；
Frerrous chloride 5%；
Carboxymethyl cellulose 5%；
For preparing 1000kg substrate modifiers, preparation method is：
(1) 1000kg raw materials are weighed by above-mentioned weight percent；
(2) it will be dissolved in frerrous chloride therein or the ferrous sulfate of equivalent weight input 150L water, obtain frerrous chloride
Solution；
(3) obtained solution of ferrous chloride with zeolite powder is mixed, and is sufficiently stirred, dries；
(4) frerrous chloride and the mixture of zeolite powder finished above-mentioned drying successively with SODIUM PERCARBONATE, carboxymethyl cellulose
Plain sodium is sufficiently mixed and stirs evenly, carry out compressing tablet process, formed pellet diameter be 6mm, tableting pressure 8kg/cm2。
Fishery substrate modifier described in the more than embodiment of the present invention, implementation result are exemplified below：
The Qingdao of Shandong province Huangdao District leg Shrimp Litopenaeus vannamei Culture Raceway-type Ponds pool is changed using fishery substrate provided by the invention
Good dose, which may be because hot weather but when inventory is not reduced accordingly causes water quality deterioration, bed mud black smelly.It is cultivated
Ingest reduction, liver of Penaeus Vannmei obscures, and have " the trip pool " phenomenon to occur, and measures water nitrite content as 0.5mg/L,
Dissolved oxygen is 3.8mg/L.
The lower substrate modifier is uniformly spilt with 200g/ mus of dosage to the cultivating pool, the aquaculture pond is observed after 5 hours
The pool finds that " the trip pool " phenomenon disappears, measures content of nitrite as 0.3mg/L, dissolved oxygen 5.6mg/L, water transparency increases
Add；Next day, it has been observed that cultivated Penaeus Vannmei is ingested, recovery was normal again, and " the trip pool " individual significantly reduces.
Fishery substrate modifier described in the more than embodiment of the present invention, the present invention also have quick-acting oxygenation agents in the application
Effect, specifically：
When the present invention is put into aquaculture system and sinks to water bottom, SODIUM PERCARBONATE hydrolysis generates hydrogen peroxide,
Its reaction equation is as follows：
2Na2CO3·3H2O2→2Na2CO3+3H2O2；
Further, hydrogen peroxide reacts as follows with being adsorbed in the iron ion generation of zeolite powder or active powdered carbon：
Fe2++H2O2→Fe3++OH-+·OH；
Fe3++H2O2→Fe2++H++O2↑；
Above-mentioned reaction is " Fenton's reaction ", can generate the extremely strong hydroxyl radical free radical of oxidisability, so as to without selectively oxygen
Change water bottom pollutant, improve water bottom oxidation-reduction potential, while also be able to kill pathogenic microorganism, so as to systematically
Improve water bottom environment；As shown in reaction equation, the chemical valence of iron ion can the dynamic equilibrium between positive divalent and positive trivalent
It mutually converts, so as to recycle without being consumed totally, the solid phase that zeolite powder or active powdered carbon serve as iron ion carries
Body so as to which iron ion be made not allow readily soluble mistake, ensures that above-mentioned reaction can be carried out to relative durations in bottom.
Above example is one kind of the present invention more preferably specific embodiment, and those skilled in the art are in the technical program
In the range of the usual variations and alternatives that carry out should include it is within the scope of the present invention.
Claims (3)
1. a kind of fishery substrate modifier, which is characterized in that comprise the following raw materials by weight percent：
SODIUM PERCARBONATE 50%；
Zeolite powder 40%；
Frerrous chloride 5%；
Carboxymethyl cellulose 5%.
2. a kind of preparation method of fishery substrate modifier, which is characterized in that comprise the steps of：
(1) 1000kg raw materials are weighed by weight percentage, include SODIUM PERCARBONATE 50%, zeolite powder 40%, frerrous chloride 5%, carboxylic
Methylcellulose 5%；
(2) it will be dissolved in frerrous chloride therein or the ferrous sulfate of equivalent weight input 150L water, obtain solution of ferrous chloride；
(3) obtained solution of ferrous chloride with zeolite powder is mixed, and is sufficiently stirred, dries；
(4) frerrous chloride and the mixture of zeolite powder finished above-mentioned drying successively with SODIUM PERCARBONATE, sodium carboxymethylcellulose
Be sufficiently mixed and stir evenly, carry out compressing tablet process, formed pellet diameter be 6mm, tableting pressure 8kg/cm2。
3. the preparation method of fishery substrate modifier according to claim 2, it is characterised in that：This modifying agent used
Oxygroup is reacted with iron ion generates hydroxyl radical free radical, as quick-acting oxygenation agents.
Priority Applications (1)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| CN201611121082.0A CN108178276A (en) | 2016-12-08 | 2016-12-08 | A kind of fishery substrate modifier and preparation method thereof |
Applications Claiming Priority (1)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| CN201611121082.0A CN108178276A (en) | 2016-12-08 | 2016-12-08 | A kind of fishery substrate modifier and preparation method thereof |
Publications (1)
| Publication Number | Publication Date |
|---|---|
| CN108178276A true CN108178276A (en) | 2018-06-19 |
Family
ID=62544750
Family Applications (1)
| Application Number | Title | Priority Date | Filing Date |
|---|---|---|---|
| CN201611121082.0A Pending CN108178276A (en) | 2016-12-08 | 2016-12-08 | A kind of fishery substrate modifier and preparation method thereof |
Country Status (1)
| Country | Link |
|---|---|
| CN (1) | CN108178276A (en) |
Cited By (2)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN109626554A (en) * | 2019-01-16 | 2019-04-16 | 合肥工业大学 | A kind of preparation method of the solid oxygen particle with slow-release oxygen function |
| CN110078193A (en) * | 2019-04-29 | 2019-08-02 | 河北科技大学 | One type Fenton effervescent tablet and its preparation method and application |
Citations (6)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN101164911A (en) * | 2007-09-27 | 2008-04-23 | 袁长兵 | Method for producing concave-convex rod particle adsorption oxygen increasing agent |
| CN101168458A (en) * | 2007-09-27 | 2008-04-30 | 袁长兵 | Method for producing concave-convex rod adsorption oxygen increasing agent |
| US20080319246A1 (en) * | 2004-10-15 | 2008-12-25 | Giancarlo Cravotto | Process for the Degradation and/or Detoxification of Chemical and Biological Pollutants |
| CN101525164A (en) * | 2009-04-20 | 2009-09-09 | 河北科技大学 | Sodium percarbonate preparation used for water fast oxygenation and disinfection and preparation method thereof |
| CN102398936A (en) * | 2010-09-13 | 2012-04-04 | 清华大学 | Composite preparation for inhibiting water blackening and smell and its preparation method and use method |
| CN102869743A (en) * | 2010-04-30 | 2013-01-09 | 三菱瓦斯化学株式会社 | Peroxide activator and process for purifying soil and/or ground water |
-
2016
- 2016-12-08 CN CN201611121082.0A patent/CN108178276A/en active Pending
Patent Citations (6)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| US20080319246A1 (en) * | 2004-10-15 | 2008-12-25 | Giancarlo Cravotto | Process for the Degradation and/or Detoxification of Chemical and Biological Pollutants |
| CN101164911A (en) * | 2007-09-27 | 2008-04-23 | 袁长兵 | Method for producing concave-convex rod particle adsorption oxygen increasing agent |
| CN101168458A (en) * | 2007-09-27 | 2008-04-30 | 袁长兵 | Method for producing concave-convex rod adsorption oxygen increasing agent |
| CN101525164A (en) * | 2009-04-20 | 2009-09-09 | 河北科技大学 | Sodium percarbonate preparation used for water fast oxygenation and disinfection and preparation method thereof |
| CN102869743A (en) * | 2010-04-30 | 2013-01-09 | 三菱瓦斯化学株式会社 | Peroxide activator and process for purifying soil and/or ground water |
| CN102398936A (en) * | 2010-09-13 | 2012-04-04 | 清华大学 | Composite preparation for inhibiting water blackening and smell and its preparation method and use method |
Non-Patent Citations (5)
| Title |
|---|
| 刘应书等: "《缺氧环境制氧供氧技术》", 30 November 2010, 冶金工业出版社 * |
| 崔航等: "二价铁催化过碳酸钠处理水中乙苯", 《中国环境科学》 * |
| 梁吉艳等: "《环境工程学》", 31 October 2014, 中国建材工业出版社 * |
| 沈岳清: "《植物生长调节剂与保鲜剂》", 31 October 1990, 化学工业出版社 * |
| 赵克健: "《汉英化学药名词汇》", 30 June 2007, 中国医药科技出版社 * |
Cited By (4)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN109626554A (en) * | 2019-01-16 | 2019-04-16 | 合肥工业大学 | A kind of preparation method of the solid oxygen particle with slow-release oxygen function |
| CN109626554B (en) * | 2019-01-16 | 2021-06-08 | 合肥工业大学 | Preparation method of solid oxygen particles with oxygen slow-release function |
| CN110078193A (en) * | 2019-04-29 | 2019-08-02 | 河北科技大学 | One type Fenton effervescent tablet and its preparation method and application |
| CN110078193B (en) * | 2019-04-29 | 2021-11-19 | 河北科技大学 | Fenton-like effervescent tablet and preparation method and application thereof |
Similar Documents
| Publication | Publication Date | Title |
|---|---|---|
| CN104671433A (en) | Compound microbiological oxygenate for removing ammonia nitrogen in aquatic water and preparation method of compound microbiological oxygenate | |
| CN104671435B (en) | A kind of environmentally friendly breeding water body slow release oxygenation agent | |
| CN110801811A (en) | Mg/Fe oxide modified biochar nanocomposite and preparation method thereof | |
| JP5778669B2 (en) | Method for suppressing methane production | |
| CN107118983B (en) | Compound bacterium enzyme preparation for improving water quality and preparation method and application thereof | |
| CN106946430B (en) | Preparation method of substrate modifier for aquaculture | |
| JP4710036B2 (en) | Iron chelate generating material and method of using the same | |
| CN108178276A (en) | A kind of fishery substrate modifier and preparation method thereof | |
| JP6345951B2 (en) | Culture medium for promoting diatom growth and method for promoting diatom growth | |
| CN104045164A (en) | Microbial preparation for improvement of freshwater aquaculture water body | |
| CN107555607A (en) | A kind of compound oxygenation agent of biology and preparation method thereof | |
| CN107986517A (en) | The processing method of resistant gene in a kind of marine culture wastewater | |
| CN105170605B (en) | A kind of method of antibiotic in efficient process aquaculture feces of livestock and poultry | |
| CN110964536B (en) | Iron-based soil remediation agent and preparation method thereof | |
| CN102898116A (en) | Hydrophobic inorganic gel material and preparation method thereof | |
| CN103667139A (en) | Composite microbial preparation for culture water body improvement | |
| CN106430873A (en) | High-efficiency compound type substrate improver and preparation method | |
| CN107285450A (en) | A kind of high oxygen-enriching agent used in aquaculture and application thereof | |
| JP5099773B2 (en) | Sediment environment improving material and its use | |
| CN1875688A (en) | An agricultural irrigating and fertilizing method | |
| Li et al. | Encapsulation of denitrifying bacteria for potential recirculating aquaculture system denitrification | |
| CN100999351A (en) | Compound flocculating agent used for treating red tide organisms and its preparation method | |
| CN107055744A (en) | It is a kind of to activate the method for treating water that peroxy-monosulfate aoxidizes depollution using secondary iron mineral | |
| CN1908080A (en) | Metope mortar ash charcoal paste | |
| CN104478071B (en) | A kind of preparation method of rare earth-attapulgite living things catalysis mud |
Legal Events
| Date | Code | Title | Description |
|---|---|---|---|
| PB01 | Publication | ||
| PB01 | Publication | ||
| SE01 | Entry into force of request for substantive examination | ||
| SE01 | Entry into force of request for substantive examination | ||
| WD01 | Invention patent application deemed withdrawn after publication |
Application publication date: 20180619 |
|
| WD01 | Invention patent application deemed withdrawn after publication |