CN105170605B - A kind of method of antibiotic in efficient process aquaculture feces of livestock and poultry - Google Patents
A kind of method of antibiotic in efficient process aquaculture feces of livestock and poultry Download PDFInfo
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- CN105170605B CN105170605B CN201510539590.XA CN201510539590A CN105170605B CN 105170605 B CN105170605 B CN 105170605B CN 201510539590 A CN201510539590 A CN 201510539590A CN 105170605 B CN105170605 B CN 105170605B
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- 210000003608 fece Anatomy 0.000 title claims abstract description 63
- 244000144972 livestock Species 0.000 title claims abstract description 60
- 244000144977 poultry Species 0.000 title claims abstract description 60
- 230000003115 biocidal effect Effects 0.000 title claims abstract description 28
- 238000000034 method Methods 0.000 title claims abstract description 25
- 238000009360 aquaculture Methods 0.000 title claims abstract description 7
- 244000144974 aquaculture Species 0.000 title claims abstract description 7
- 238000000855 fermentation Methods 0.000 claims abstract description 53
- 230000004151 fermentation Effects 0.000 claims abstract description 53
- 229940072172 tetracycline antibiotic Drugs 0.000 claims abstract description 14
- 239000000843 powder Substances 0.000 claims description 24
- QVGXLLKOCUKJST-UHFFFAOYSA-N atomic oxygen Chemical compound [O] QVGXLLKOCUKJST-UHFFFAOYSA-N 0.000 claims description 20
- 229910052760 oxygen Inorganic materials 0.000 claims description 20
- 239000001301 oxygen Substances 0.000 claims description 20
- XLYOFNOQVPJJNP-UHFFFAOYSA-N water Substances O XLYOFNOQVPJJNP-UHFFFAOYSA-N 0.000 claims description 20
- 239000003245 coal Substances 0.000 claims description 18
- 239000002245 particle Substances 0.000 claims description 18
- 238000003756 stirring Methods 0.000 claims description 17
- VEXZGXHMUGYJMC-UHFFFAOYSA-N Hydrochloric acid Chemical compound Cl VEXZGXHMUGYJMC-UHFFFAOYSA-N 0.000 claims description 12
- XEEYBQQBJWHFJM-UHFFFAOYSA-N Iron Chemical compound [Fe] XEEYBQQBJWHFJM-UHFFFAOYSA-N 0.000 claims description 12
- QAOWNCQODCNURD-UHFFFAOYSA-N Sulfuric acid Chemical compound OS(O)(=O)=O QAOWNCQODCNURD-UHFFFAOYSA-N 0.000 claims description 12
- 238000001914 filtration Methods 0.000 claims description 12
- 239000007789 gas Substances 0.000 claims description 10
- 230000003647 oxidation Effects 0.000 claims description 10
- 238000007254 oxidation reaction Methods 0.000 claims description 10
- 239000010902 straw Substances 0.000 claims description 10
- QMQXDJATSGGYDR-UHFFFAOYSA-N methylidyneiron Chemical compound [C].[Fe] QMQXDJATSGGYDR-UHFFFAOYSA-N 0.000 claims description 9
- 239000000126 substance Substances 0.000 claims description 8
- WQZGKKKJIJFFOK-GASJEMHNSA-N Glucose Natural products OC[C@H]1OC(O)[C@H](O)[C@@H](O)[C@@H]1O WQZGKKKJIJFFOK-GASJEMHNSA-N 0.000 claims description 6
- OAICVXFJPJFONN-UHFFFAOYSA-N Phosphorus Chemical compound [P] OAICVXFJPJFONN-UHFFFAOYSA-N 0.000 claims description 6
- 235000014676 Phragmites communis Nutrition 0.000 claims description 6
- BLRPTPMANUNPDV-UHFFFAOYSA-N Silane Chemical group [SiH4] BLRPTPMANUNPDV-UHFFFAOYSA-N 0.000 claims description 6
- 239000000835 fiber Substances 0.000 claims description 6
- 239000008103 glucose Substances 0.000 claims description 6
- 239000000463 material Substances 0.000 claims description 6
- 229910000077 silane Inorganic materials 0.000 claims description 6
- 239000010802 sludge Substances 0.000 claims description 6
- UFHFLCQGNIYNRP-UHFFFAOYSA-N Hydrogen Chemical compound [H][H] UFHFLCQGNIYNRP-UHFFFAOYSA-N 0.000 claims description 3
- 229910052739 hydrogen Inorganic materials 0.000 claims description 3
- 239000001257 hydrogen Substances 0.000 claims description 3
- 238000002360 preparation method Methods 0.000 claims description 3
- 239000003795 chemical substances by application Substances 0.000 claims 1
- 230000015556 catabolic process Effects 0.000 abstract description 7
- 238000006731 degradation reaction Methods 0.000 abstract description 7
- 230000000694 effects Effects 0.000 abstract description 4
- 230000000813 microbial effect Effects 0.000 abstract description 3
- 230000007613 environmental effect Effects 0.000 abstract description 2
- 238000004904 shortening Methods 0.000 abstract 1
- 241001465754 Metazoa Species 0.000 description 6
- 239000004098 Tetracycline Substances 0.000 description 5
- 235000019364 tetracycline Nutrition 0.000 description 5
- 150000003522 tetracyclines Chemical class 0.000 description 5
- 238000009264 composting Methods 0.000 description 4
- 238000005516 engineering process Methods 0.000 description 4
- 239000002689 soil Substances 0.000 description 3
- 229960002180 tetracycline Drugs 0.000 description 3
- 229930101283 tetracycline Natural products 0.000 description 3
- 238000006424 Flood reaction Methods 0.000 description 2
- 240000004928 Paspalum scrobiculatum Species 0.000 description 2
- 235000003675 Paspalum scrobiculatum Nutrition 0.000 description 2
- 239000007822 coupling agent Substances 0.000 description 2
- 238000007789 sealing Methods 0.000 description 2
- 229940040944 tetracyclines Drugs 0.000 description 2
- 241000196324 Embryophyta Species 0.000 description 1
- 239000000654 additive Substances 0.000 description 1
- 230000000996 additive effect Effects 0.000 description 1
- 239000003674 animal food additive Substances 0.000 description 1
- 230000009286 beneficial effect Effects 0.000 description 1
- 238000009395 breeding Methods 0.000 description 1
- 230000001488 breeding effect Effects 0.000 description 1
- 238000000354 decomposition reaction Methods 0.000 description 1
- 239000003337 fertilizer Substances 0.000 description 1
- 235000013305 food Nutrition 0.000 description 1
- 229910052500 inorganic mineral Inorganic materials 0.000 description 1
- 239000010871 livestock manure Substances 0.000 description 1
- 238000004519 manufacturing process Methods 0.000 description 1
- 244000005700 microbiome Species 0.000 description 1
- 239000011707 mineral Substances 0.000 description 1
- 239000003895 organic fertilizer Substances 0.000 description 1
- 231100000572 poisoning Toxicity 0.000 description 1
- 230000000607 poisoning effect Effects 0.000 description 1
- 239000007787 solid Substances 0.000 description 1
- DPJRMOMPQZCRJU-UHFFFAOYSA-M thiamine hydrochloride Chemical compound Cl.[Cl-].CC1=C(CCO)SC=[N+]1CC1=CN=C(C)N=C1N DPJRMOMPQZCRJU-UHFFFAOYSA-M 0.000 description 1
Classifications
-
- B—PERFORMING OPERATIONS; TRANSPORTING
- B09—DISPOSAL OF SOLID WASTE; RECLAMATION OF CONTAMINATED SOIL
- B09B—DISPOSAL OF SOLID WASTE NOT OTHERWISE PROVIDED FOR
- B09B3/00—Destroying solid waste or transforming solid waste into something useful or harmless
-
- B—PERFORMING OPERATIONS; TRANSPORTING
- B09—DISPOSAL OF SOLID WASTE; RECLAMATION OF CONTAMINATED SOIL
- B09B—DISPOSAL OF SOLID WASTE NOT OTHERWISE PROVIDED FOR
- B09B5/00—Operations not covered by a single other subclass or by a single other group in this subclass
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- Engineering & Computer Science (AREA)
- Environmental & Geological Engineering (AREA)
- Fertilizers (AREA)
Abstract
The present invention relates to a kind of method of antibiotic in efficient process aquaculture feces of livestock and poultry, belong to technical field of biological environmental protection.The present invention is degraded using a kind of microbial fermentation and is chemically treated the method that is engaged, tetracycline antibiotics in fast degradation feces of livestock and poultry so that tetracycline antibiotics clearance is high in feces of livestock and poultry, processing time shortening, and simple to operate, easily controllable.This example proves, the inventive method is unique novel, influence factor is few in processing procedure, it is easily controllable, the tetracycline antibiotics that can not only be remained in fast degradation feces of livestock and poultry, so that processing time shortens 45%~50%, and the tetracycline antibiotics clearance for remain in feces of livestock and poultry reaches more than 95%, effect highly significant.
Description
Technical field
The present invention relates to a kind of method of antibiotic in efficient process aquaculture feces of livestock and poultry, belongs to biological environmental production technology neck
Domain.
Background technology
According to statistics, China's feces of livestock and poultry yield in 2002 is about 1,800,000,000 t, is 2.8 times of industrial solid castoff or so,
Wherein national pig manure output is 1,200,000,000 t, accounts for the 47% of feces of livestock and poultry total amount.Expect 2018, China there are about 8000t every year
Veterinary antibiotic is used for additive for farm animal feed, accounts for the 50% of national antibiotic feed additive usage amount, wherein Tetracyclines
Output of the antibiotic in China and whole world livestock and poultry breeding industry is maximum with actual use amount, is widely used in livestock and poultry and supports
Grow process.However, antibiotic is not fully absorbed mostly, about 45%~95% is discharged in the form of parent or metabolin
Outside animal body, into soil and water body environment, are produced by murder by poisoning, and is passed through for soil ecosystem, the health of water ecosystem
Food chain finally produces harm to health.Therefore, in feces of livestock and poultry pollution and the mankind of the residual antibiotic to environment danger
Evil has caused the great attention of people.
People are most of using Composting skill when remaining tetracycline antibiotics in handling feces of livestock and poultry at present
Art, composting technology are to utilize animals and plants remains and excreta containing fertilizer component, plus soil and mineral matter mixed-stacking,
High temperature, it is how wet under conditions of, the method for manufactured a kind of organic fertilizer by fermentation maturity, microorganism decomposition.Although its energy
Tetracycline antibiotics in feces of livestock and poultry are enough removed, but treatment effect is undesirable, and clearance is than relatively low, and in processing procedure
Influence factor is relatively more, is difficult to control so that processing time is long, not easy to operate.
The content of the invention
Present invention mainly solves technical problem：For currently used Composting technology processing time in processing procedure
It is longer, and influence factor is more in composting process, it is difficult to control, the problem of causing removal effect unstable, there is provided Yi Zhongli
Degraded with microbial fermentation and be engaged with chemical treatment, the method for fast degradation tetracycline antibiotics so that in feces of livestock and poultry
Residual antibiotic clearance is high, and processing time shortens, and simple to operate, easily controllable.
In order to solve the above-mentioned technical problem, the technical solution adopted in the present invention is：
（1）Feces of livestock and poultry is put into 15~20min in baking oven, temperature is set as 50~55 DEG C, dried animal dung
Just with river sludge according to mass ratio 4:1 is mixed, and is put into fermentation vat, in fermentation vat bottom 2~3cm of laying thickness rice
Grass, in straw top 1~2cm of laying thickness charing reed rod, it is 32~35 DEG C to control temperature during the fermentation；
（2）Oxygen is passed through into above-mentioned fermentation vat, ensures that oxygen volume content is 25~27% in fermentation pool gas, hair
Ferment 3~5 days, then adds water thereto, and the water content for making its fermentate is 40~50%, and stopping is passed through oxygen, is sealed
Fermentation 6~7 days, 2~5% white phosphorus of fermentate quality is added thereto, keeping temperature is constant, during the fermentation, every 1~
3h adds 1.2~1.5% glucose amount of fermentate quality into fermentation vat；
（3）Feces of livestock and poultry after above-mentioned fermentation is introduced into oxidation pond, adds water submerged feces of livestock and poultry thereto, thereto
Add carbon iron intermixture and H2O2, its addition is 2 with feces of livestock and poultry mass ratio:1:1000,30~50min is stirred, adds quality
Fraction is 50~55% hydrochloric acid solution, and regulation pH is 3.7~4.6, stirs 10~15min, stands 20~25min；
（4）After above-mentioned standing terminates, in the environment of pressure is 1.3~1.8MPa, using condensating fiber miillpore filter to oxygen
The material changed in pond is filtered, and then dries the feces of livestock and poultry after filtering, detects the content of its antibiotic；Wherein described step
Suddenly（3）Middle carbon iron intermixture preparation method is：
1. taking gangue to be put into pulverizer to carry out, 50~70 mesh powder are ground into, then powder is put into container, to
It is 1~5% silane that 30~40% sulfuric acid solutions flood powder and gangue powder mass fraction wherein to add mass fraction
Coupling agent, temperature are set as 65~75 DEG C, stir 30~40min, speed setting is 600~700r/min, is then filtered；
2. the coal gangue particle thing after above-mentioned filtering is put into container, it is 700~850MHz's that container, which is placed in frequency,
In electromagnetic wave, the iron powder that 150~200 mesh are loaded with high pressure-temperature air-flow is bombarded coal gangue particle thing, its iron powder
Addition is the 40~50% of coal gangue particle amount of substance, then stirs 10~25min, you can.
Described antibiotic is tetracycline antibiotics.
The high pressure-temperature air-flow is that temperature is 350~400 DEG C, and gas tank is 2.1~2.3MPa hydrogen.
The beneficial effects of the invention are as follows：
（1）The tetracycline antibiotics that can be remained in fast degradation feces of livestock and poultry so that processing time shortens 45%
~50%；
（2）Degraded by microbial fermentation and be engaged with chemical treatment so that the Tetracyclines remained in feces of livestock and poultry resists
Raw plain clearance reaches more than 95%；
（3）Influence factor is few in processing procedure, easily controllable, obvious processing effect.
Embodiment
（1）Feces of livestock and poultry is put into 15~20min in baking oven, temperature is set as 50~55 DEG C, dried animal dung
Just with river sludge according to mass ratio 4:1 is mixed, and is put into fermentation vat, in fermentation vat bottom 2~3cm of laying thickness rice
Grass, in straw top 1~2cm of laying thickness charing reed rod, it is 32~35 DEG C to control temperature during the fermentation；
（2）Oxygen is passed through into above-mentioned fermentation vat, ensures that oxygen volume content is 25~27% in fermentation pool gas, hair
Ferment 3~5 days, then adds water thereto, and the water content for making its fermentate is 40~50%, and stopping is passed through oxygen, is sealed
Fermentation 6~7 days, 2~5% white phosphorus of fermentate quality is added thereto, keeping temperature is constant, during the fermentation, every 1~
3h adds 1.2~1.5% glucose amount of fermentate quality into fermentation vat；
（3）Feces of livestock and poultry after above-mentioned fermentation is introduced into oxidation pond, adds water submerged feces of livestock and poultry thereto, thereto
Add carbon iron intermixture and H2O2, its addition is 2 with feces of livestock and poultry mass ratio:1:1000,30~50min is stirred, adds quality
Fraction is 50~55% hydrochloric acid solution, and regulation pH is 3.7~4.6, stirs 10~15min, stands 20~25min；
（4）After above-mentioned standing terminates, in the environment of pressure is 1.3~1.8MPa, using condensating fiber miillpore filter to oxygen
The material changed in pond is filtered, and then dries the feces of livestock and poultry after filtering, detects the content of its antibiotic；Wherein described step
Suddenly（3）Middle carbon iron intermixture preparation method is：
1. taking gangue to be put into pulverizer to carry out, 50~70 mesh powder are ground into, then powder is put into container, to
It is 1~5% silane that 30~40% sulfuric acid solutions flood powder and gangue powder mass fraction wherein to add mass fraction
Coupling agent, temperature are set as 65~75 DEG C, stir 30~40min, speed setting is 600~700r/min, is then filtered；
2. the coal gangue particle thing after above-mentioned filtering is put into container, it is 700~850MHz's that container, which is placed in frequency,
In electromagnetic wave, the iron powder that 150~200 mesh are loaded with high pressure-temperature air-flow is bombarded coal gangue particle thing, its iron powder
Addition is the 40~50% of coal gangue particle amount of substance, then stirs 10~25min, you can.
Described antibiotic is tetracycline antibiotics.
The high pressure-temperature air-flow is that temperature is 350~400 DEG C, and gas tank is 2.1~2.3MPa hydrogen.
Example 1
The feces of livestock and poultry that tetracycline antibiotics content is 1.23mg/kg is put into 15min in baking oven, temperature setting first
For 50 DEG C, according to oeverall quality 100g, take dried feces of livestock and poultry 80g to be mixed with river sludge 20g, be put into fermentation vat
In, thick 2cm straw is laid in fermentation vat bottom, thick 1cm charing reed rod is laid on straw top, controls during the fermentation
Temperature processed is 32 DEG C；State then up and oxygen be passed through in fermentation vat, ensure that oxygen volume content is 25% in fermentation pool gas,
Fermentation 3 days, then adds water thereto, and the water content for making its fermentate is 40%, and stopping is passed through oxygen, carries out sealing and fermenting 6
My god, 2% white phosphorus of fermentate quality is added thereto, and keeping temperature is constant, during the fermentation, adds per 1h into fermentation vat
Enter 1.2% glucose amount of fermentate quality；Next the feces of livestock and poultry after being fermented in above-mentioned steps is introduced into oxidation pond,
Water submerged feces of livestock and poultry is added thereto, adds carbon iron intermixture and H thereto2O2, its addition is with feces of livestock and poultry mass ratio
2:1:1000,30min is stirred, adds the hydrochloric acid solution that mass fraction is 50%, regulation pH is 3.7, stirs 10min, stands
20min；After last above-mentioned standing terminates, in the environment of pressure is 1.3MPa, using condensating fiber miillpore filter in oxidation pond
Material filtered, then by after filtering feces of livestock and poultry dry, detect the content of its antibiotic, then take gangue to be put into
Carried out in pulverizer, be ground into 50 mesh powder, then powder is put into container, it is 30% sulfuric acid to add mass fraction thereto
Solution floods 1% silane coupler of powder and gangue powder mass fraction, and temperature is set as 65 DEG C, stirs 30min, turns
Speed is set as 600r/min, then filters；Then the coal gangue particle thing after above-mentioned filtering is put into container, container is placed in
Frequency is in 700MHz electromagnetic wave, and the iron powder that 150 mesh are loaded with high pressure-temperature air-flow is bombarded coal gangue particle thing,
Its iron powder addition is the 40% of coal gangue particle amount of substance, then stirs 10min, you can.
This example operation influence factor is few, easily controllable, the tetracycline that can not only be remained in fast degradation feces of livestock and poultry
Class antibiotic so that processing time shortens 45%, and detects the Fourth Ring remained in the handled feces of livestock and poultry crossed of the present invention
Plain class antibiotic content is 60.2 μ g/kg, and clearance reaches 95%.
Example 2
The feces of livestock and poultry that tetracycline antibiotics content is 1.32mg/kg is put into 18min in baking oven, temperature setting first
For 53 DEG C, according to oeverall quality 200g, take dried feces of livestock and poultry 160g to be mixed with river sludge 40g, be put into fermentation
Chi Zhong, thick 2.5cm straw is laid in fermentation vat bottom, is laid thick 1.5cm charing reed rod on straw top, was being fermented
It is 33 DEG C that temperature is controlled in journey；State then up and oxygen is passed through in fermentation vat, ensure oxygen volume content in fermentation pool gas
For 26%, ferment 4 days, then add water thereto, the water content for making its fermentate is 45%, and stopping is passed through oxygen, is carried out close
Seal ferment 5 days, 4% white phosphorus of fermentate quality is added thereto, keeping temperature is constant, during the fermentation, per 2h to hair
1.3% glucose amount of fermentate quality is added in ferment pond；Next the feces of livestock and poultry after being fermented in above-mentioned steps is introduced
In oxidation pond, water submerged feces of livestock and poultry is added thereto, adds carbon iron intermixture and H thereto2O2, its addition and animal dung
Just mass ratio is 2:1:1000,40min is stirred, adds the hydrochloric acid solution that mass fraction is 52%, regulation pH is 4.2, stirring
13min, stand 23min；After last above-mentioned standing terminates, in the environment of pressure is 1.5MPa, condensating fiber miillpore filter is used
Material in oxidation pond is filtered, then the feces of livestock and poultry after filtering is dried, the content of its antibiotic is detected, then takes
Gangue is put into pulverizer and carried out, and is ground into 60 mesh powder, then powder is put into container, adds mass fraction thereto
3% silane coupler of powder and gangue powder mass fraction is flooded for 35% sulfuric acid solution, temperature is set as 70 DEG C, stirred
35min is mixed, speed setting 650r/min, is then filtered；Then the coal gangue particle thing after above-mentioned filtering is put into container,
Container is placed in the electromagnetic wave that frequency is 750MHz, the iron powder of 180 mesh is loaded to coal gangue particle with high pressure-temperature air-flow
Thing is bombarded, and its iron powder addition is the 45% of coal gangue particle amount of substance, then stirs 15min, you can.
This example operation influence factor is few, easily controllable, the tetracycline that can not only be remained in fast degradation feces of livestock and poultry
Class antibiotic so that processing time shortens 48%, and detects the Fourth Ring remained in the handled feces of livestock and poultry crossed of the present invention
Plain class antibiotic content is 52.4 μ g/kg, and clearance reaches 96%.
Example 3
It is that 1.02mg/kg feces of livestock and poultry is put into 20min in baking oven first by tetracycline antibiotics content, temperature is set as
55 DEG C, according to oeverall quality 300g, take dried feces of livestock and poultry 240g to be mixed with river sludge 60g, be put into fermentation vat
In, thick 3cm straw is laid in fermentation vat bottom, thick 2cm charing reed rod is laid on straw top, controls during the fermentation
Temperature processed is 35 DEG C；State then up and oxygen be passed through in fermentation vat, ensure that oxygen volume content is 27% in fermentation pool gas,
Fermentation 5 days, then adds water thereto, and the water content for making its fermentate is 50%, and stopping is passed through oxygen, carries out sealing and fermenting 7
My god, 5% white phosphorus of fermentate quality is added thereto, and keeping temperature is constant, during the fermentation, adds per 3h into fermentation vat
Enter 1.5% glucose amount of fermentate quality；Next the feces of livestock and poultry after being fermented in above-mentioned steps is introduced into oxidation pond,
Water submerged feces of livestock and poultry is added thereto, adds carbon iron intermixture and H thereto2O2, its addition is with feces of livestock and poultry mass ratio
2:1:1000,50min is stirred, adds the hydrochloric acid solution that mass fraction is 55%, regulation pH is 4.6, stirs 15min, stands
25min；After last above-mentioned standing terminates, in the environment of pressure is 1.8MPa, using condensating fiber miillpore filter in oxidation pond
Material filtered, then by after filtering feces of livestock and poultry dry, detect the content of its antibiotic, then take gangue to be put into
Carried out in pulverizer, be ground into 70 mesh powder, then powder is put into container, it is 40% sulfuric acid to add mass fraction thereto
Solution floods 5% silane coupler of powder and gangue powder mass fraction, and temperature is set as 75 DEG C, stirs 40min, turns
Speed is set as 700r/min, then filters；Then the coal gangue particle thing after above-mentioned filtering is put into container, container is placed in
Frequency is in 850MHz electromagnetic wave, and the iron powder that 200 mesh are loaded with high pressure-temperature air-flow is bombarded coal gangue particle thing,
Its iron powder addition is the 50% of coal gangue particle amount of substance, then stirs 25min, you can.
This example operation influence factor is few, easily controllable, the tetracycline that can not only be remained in fast degradation feces of livestock and poultry
Class antibiotic so that processing time shortens 50%, and detects the Fourth Ring remained in the handled feces of livestock and poultry crossed of the present invention
Plain class antibiotic content is 30.6 μ g/kg, and clearance reaches 97%.
Claims (3)
1. a kind of method of antibiotic in efficient process aquaculture feces of livestock and poultry, it is characterised in that specific method is：
（1）Feces of livestock and poultry is put into 15~20min in baking oven, temperature is set as 50~55 DEG C, dried feces of livestock and poultry with
River sludge is according to mass ratio 4:1 is mixed, and is put into fermentation vat, and 2~3cm of thickness straw is laid in fermentation vat bottom,
Straw top 1~2cm of laying thickness charing reed rod, it is 32~35 DEG C to control temperature during the fermentation；
（2）Oxygen is passed through into above-mentioned fermentation vat, ensures that oxygen volume content is 25~27% in fermentation pool gas, fermentation 3
~5 days, water is then added thereto, and the water content for making its fermentate is 40~50%, and stopping is passed through oxygen, is sealed by fermentation
6~7 days, thereto add fermentate quality 2~5% white phosphorus, keeping temperature is constant, during the fermentation, every 1~3h to
1.2~1.5% glucose amount of fermentate quality is added in fermentation vat；
（3）By step（2）Feces of livestock and poultry after middle fermentation is introduced into oxidation pond, adds water submerged feces of livestock and poultry, Xiang Qi thereto
Middle addition carbon iron intermixture and H2O2, its addition is 2 with feces of livestock and poultry mass ratio:1:1000,30~50min is stirred, adds matter
The hydrochloric acid solution that fraction is 50~55% is measured, regulation pH is 3.7~4.6, stirs 10~15min, stands 20~25min；
（4）After above-mentioned standing terminates, in the environment of pressure is 1.3~1.8MPa, using condensating fiber miillpore filter to oxidation pond
Interior material is filtered, and then dries the feces of livestock and poultry after filtering, detects the content of its antibiotic；Wherein described step
（3）Middle carbon iron intermixture preparation method is：
1. taking gangue to be put into pulverizer to carry out, 50~70 mesh powder are ground into, then powder are put into container, thereto
Add mass fraction be 30~40% sulfuric acid solutions flood powder and gangue powder mass fraction 1~5% it is silane coupled
Agent, temperature are set as 65~75 DEG C, stir 30~40min, speed setting is 600~700r/min, is then filtered；
2. the coal gangue particle thing after above-mentioned filtering is put into container, container is placed in the electromagnetism that frequency is 700~850MHz
In ripple, the iron powder that 150~200 mesh are loaded with high pressure-temperature air-flow is bombarded coal gangue particle thing, the addition of its iron powder
Measure as the 40~50% of coal gangue particle amount of substance, then stir 10~25min, you can.
2. the method for antibiotic in a kind of efficient process aquaculture feces of livestock and poultry according to claim 1, it is characterised in that：
Described antibiotic is tetracycline antibiotics.
3. the method for antibiotic in a kind of efficient process aquaculture feces of livestock and poultry according to claim 1, it is characterised in that：
Described step（4）Mesohigh high temperature gas flow is that temperature is 350~400 DEG C, and gas tank is 2.1~2.3MPa hydrogen.
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| CN105502864B (en) * | 2015-12-28 | 2018-03-06 | 浙江省农业科学院 | A kind of method that residual antibiotic in feces of livestock and poultry is efficiently removed using normal temperature fermentation |
| CN105503350A (en) * | 2015-12-29 | 2016-04-20 | 淄博永辰环境影响评价有限公司 | Composting method for efficient degradation of tetracycline antibiotics in livestock and poultry breeding excrement |
| CN106277166B (en) * | 2016-08-31 | 2019-12-03 | 昆明理工大学 | A method of utilizing antibiotic in modification biological charcoal removal breeding wastewater |
| CN109851453A (en) * | 2019-02-18 | 2019-06-07 | 黑龙江金合康肥业有限公司 | Organic and inorganic environmental protection and public nuisance free compound fertilizer |
| CN110683873A (en) * | 2019-10-22 | 2020-01-14 | 上海原本生物科技有限公司 | Method for efficiently degrading antibiotics in pig manure by using sludge charcoal |
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| WO2007114324A1 (en) * | 2006-03-31 | 2007-10-11 | Menicon Co., Ltd. | Method of treating biomass, compost, mulching material for livestock and agent for treating biomass |
| CN101307332B (en) * | 2008-06-23 | 2011-06-29 | 昆明东燃科技开发有限公司 | Innocent comprehensive approach method for human feces by biotechnology |
| CN102816332B (en) * | 2012-08-25 | 2017-10-20 | 福建超大集团有限公司 | A kind of feces of livestock and poultry prepares the innoxious extraction process of agricultural biochemical fulvic acid |
| GB201310798D0 (en) * | 2013-06-18 | 2013-07-31 | Aerobact Ltd | Animal waste treatment |
| CN103891674A (en) * | 2014-04-17 | 2014-07-02 | 北京华牧伟业科技有限公司 | Ecological cultivation method with health care fermented feed matched with probiotic fermentation bed |
| CN104293711B (en) * | 2014-09-29 | 2018-01-12 | 保罗蒂姆汉（潍坊）生物科技有限公司 | A kind of ox, sheep manure just fermenting compound fungus, preparation method and the method that organic fertilizer is prepared using the compound bacteria-fermented |
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