CN108157371B - Pesticide composition for seed coating agent - Google Patents

Pesticide composition for seed coating agent Download PDF

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Publication number
CN108157371B
CN108157371B CN201810182401.1A CN201810182401A CN108157371B CN 108157371 B CN108157371 B CN 108157371B CN 201810182401 A CN201810182401 A CN 201810182401A CN 108157371 B CN108157371 B CN 108157371B
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China
Prior art keywords
pesticide composition
hymexazol
spinetoram
pesticide
suspending agent
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Expired - Fee Related
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CN201810182401.1A
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Chinese (zh)
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CN108157371A (en
Inventor
冯夏
林庆胜
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    • AHUMAN NECESSITIES
    • A01AGRICULTURE; FORESTRY; ANIMAL HUSBANDRY; HUNTING; TRAPPING; FISHING
    • A01NPRESERVATION OF BODIES OF HUMANS OR ANIMALS OR PLANTS OR PARTS THEREOF; BIOCIDES, e.g. AS DISINFECTANTS, AS PESTICIDES OR AS HERBICIDES; PEST REPELLANTS OR ATTRACTANTS; PLANT GROWTH REGULATORS
    • A01N43/00Biocides, pest repellants or attractants, or plant growth regulators containing heterocyclic compounds
    • A01N43/02Biocides, pest repellants or attractants, or plant growth regulators containing heterocyclic compounds having rings with one or more oxygen or sulfur atoms as the only ring hetero atoms
    • A01N43/04Biocides, pest repellants or attractants, or plant growth regulators containing heterocyclic compounds having rings with one or more oxygen or sulfur atoms as the only ring hetero atoms with one hetero atom
    • A01N43/22Biocides, pest repellants or attractants, or plant growth regulators containing heterocyclic compounds having rings with one or more oxygen or sulfur atoms as the only ring hetero atoms with one hetero atom rings with more than six members
    • AHUMAN NECESSITIES
    • A01AGRICULTURE; FORESTRY; ANIMAL HUSBANDRY; HUNTING; TRAPPING; FISHING
    • A01CPLANTING; SOWING; FERTILISING
    • A01C1/00Apparatus, or methods of use thereof, for testing or treating seed, roots, or the like, prior to sowing or planting
    • A01C1/06Coating or dressing seed
    • AHUMAN NECESSITIES
    • A01AGRICULTURE; FORESTRY; ANIMAL HUSBANDRY; HUNTING; TRAPPING; FISHING
    • A01NPRESERVATION OF BODIES OF HUMANS OR ANIMALS OR PLANTS OR PARTS THEREOF; BIOCIDES, e.g. AS DISINFECTANTS, AS PESTICIDES OR AS HERBICIDES; PEST REPELLANTS OR ATTRACTANTS; PLANT GROWTH REGULATORS
    • A01N43/00Biocides, pest repellants or attractants, or plant growth regulators containing heterocyclic compounds
    • A01N43/72Biocides, pest repellants or attractants, or plant growth regulators containing heterocyclic compounds having rings with nitrogen atoms and oxygen or sulfur atoms as ring hetero atoms
    • A01N43/80Biocides, pest repellants or attractants, or plant growth regulators containing heterocyclic compounds having rings with nitrogen atoms and oxygen or sulfur atoms as ring hetero atoms five-membered rings with one nitrogen atom and either one oxygen atom or one sulfur atom in positions 1,2

Abstract

The invention discloses a pesticide composition for a seed coating agent, and relates to a pesticide composition containing spinetoram and hymexazol. The weight ratio of spinetoram to hymexazol in the pesticide composition is 1: 40-40: 1, preferably 1:20 to 20:1, more preferably 1:1 to 1: 10. the pesticide composition is particularly suitable for preventing and treating cruciferae pests and diseases, such as diamond back moth, beet armyworm, damping off and the like, is suitable for being processed into any one of missible oil, water dispersible granules, wettable powder, suspending agent, microemulsion, aqueous emulsion, dispersible oil suspending agent, microcapsule suspending agent and seed treating agent, and can also be directly added into coating materials to prepare pelleted seeds. The pesticide composition has good control effect, low dosage and environmental protection and safety.

Description

Pesticide composition for seed coating agent
Technical Field
The invention belongs to the technical field of pesticides, and particularly relates to a pesticide composition containing spinetoram and hymexazol and application of the pesticide composition in seed coating for preventing and treating cruciferae diseases and insect pests.
Background
Chemical control is an important means for preventing and controlling pests in agriculture. However, since the control of harmful diseases and pests is not effectively carried out due to the type, living characteristics, living environment, and the like of the disease and pest, the control effect is reduced, the chemical resistance is enhanced, and the control using conventional chemicals is becoming increasingly difficult, new means and methods are required for effectively controlling harmful diseases and pests that cannot be controlled or are difficult to control.
Spinetoram is a new spinosyn insecticide produced by the Dow Yinong company, is a new member of spinosyn insecticides, is obtained by chemically modifying natural products of spinosyns, and belongs to bionic pesticides. In spinosyn insecticides, spinetoram is a brand-new and unique active ingredient and is a high-efficiency broad-spectrum insecticide. The insecticidal composition is mainly used for preventing and controlling lepidoptera and thysanoptera pests, has good prevention and control effects on vegetable pests such as diamondback moth, beet armyworm and the like, and is widely applied to resistance control of the vegetable pests and alternate drug varieties.
Hymexazol is a heterocyclic compound, is a systemic bactericide and a soil disinfectant, and is also a plant growth regulator. The action mechanism is unique, high-efficiency, low-toxicity and pollution-free, and can inhibit the normal growth of pathogenic fungi mycelium or directly kill pathogenic bacteria and promote the growth of plants. The plant growth promoter has the functions of promoting the growth of plant roots, rooting and strengthening seedlings and improving the survival rate, has better safety to people, livestock, fish and birds, and has no cross resistance with the conventional medicament.
The mixing of different pesticide varieties is a common method for solving pesticide resistance and pest and disease damage. By reasonably compounding pesticides and screening out a reasonable formula, the actual control effect can be effectively improved, the dosage is reduced, the cost is reduced, the generation of drug resistance of diseases is delayed, and the method is an important means for comprehensively treating the diseases.
It has been found that after spinetoram and hymexazol are compounded, a synergistic effect is unexpectedly shown between spinetoram and hymexazol, the composition not only can prevent and control insect pests, but also has activity in preventing and controlling diseases larger than the activity of each component independently, and further research is carried out, thus the invention is completed.
Disclosure of Invention
Aiming at the defects in the prior art, particularly for effectively preventing and treating pests which are difficult to prevent and treat in the prior art, through a large number of biological assay screens, the invention finds that after the spinetoram and the hymexazol are compounded, the compounding has an obvious synergistic effect in a certain range, and the activity of controlling harmful pests and diseases after the spinetoram and the hymexazol are compounded is greatly higher than the synthesis of singly used compounds.
The invention also aims to provide application of the pesticide composition, and the pesticide composition is particularly suitable for controlling cruciferous pests and diseases, such as diamondback moth, phyllotreta striolata, asparagus caterpillar, damping off and the like.
In order to achieve the purpose, the invention adopts the following technical scheme:
a pesticide composition comprises at least spinetoram and hymexazol as active ingredients, wherein the ratio of the spinetoram to the hymexazol is 1: 40-40: 1, preferably 1:20 to 20:1, more preferably 1:1 to 1: 10.
Further, the content of the neutral component in the pesticide composition of the present invention depends on the selection of the optimal blending ratio of the active ingredients and also depends on the ease of processing the pesticide composition, and generally, the weight percentage content of the active ingredients in the pesticide composition is 1 to 90%, preferably 10 to 60%, and the balance is conventional adjuvants and/or carriers.
Furthermore, the active ingredient in the pesticide composition is processed into any one of dosage forms needed in actual production by being supplemented with conventional auxiliary ingredients in pesticide preparation processing, and the dosage forms are selected from any one of missible oil, water dispersible granules, wettable powder, suspending agents, microemulsions, aqueous emulsions, dispersible oil suspending agents, microcapsule suspending agents and seed treatment agents.
Further, the pesticide composition can be used for preparing seed pelleting agents.
Further, the seed pelleting agent means that the seeds are coated with the coating composition, and the pesticide composition of the invention can be additionally added into the coating composition to protect the seeds from insect pests, promote germination and field emergence and/or help provide nutrition to the seeds.
Furthermore, the pesticide composition has flexible application mode, can be sprayed on leaf surfaces, can be irrigated and drip-irrigated by soil, and can also be used for seed treatment.
Further, the pesticidal composition of the present invention may be used in admixture with other active ingredients, such as insecticides, attractants, nematicides, fungicides, plant growth regulators, herbicides, fertilizers, and the like.
Further, the pesticide composition of the invention can also comprise other pesticide active ingredients, including but not limited to one or more of pyrethroid pesticide, thiamethoxam, imidacloprid, acetamiprid, cartap, propiconazole and metalaxyl.
Further, the present invention provides a method for preventing or controlling vegetable pests, which comprises applying a pesticidal composition comprising spinetoram and hymexazol to a target useful plant, or its environment, or propagation material thereof.
Further, a method of protecting vegetables from pest infestation comprising contacting the vegetables with a pesticidal composition comprising spinetoram and hymexazol.
Further, a method for preventing or controlling pests and diseases comprises applying spinetoram and hymexazol separately, sequentially or simultaneously.
Further, the present invention provides a kit for preventing or controlling pests, which comprises spinetoram and hymexazol.
Compared with the prior art, the pesticide composition has the beneficial effects that: after the spinetoram and the hymexazol are compounded in the pesticide composition, the effect of preventing and treating plant diseases and insect pests after compounding is not the simple addition of single active ingredients, but the unexpected synergistic effect is shown after compounding; the active ingredients in the pesticide composition have no cross resistance, so that the use amount of the pesticide active ingredients can be reduced; the pesticide composition is safe for crops and is beneficial to the healthy growth of the crops.
Detailed Description
In order to make the objects, technical solutions and advantages of the present invention more apparent, the present invention is described with the following embodiments, but the present invention is by no means limited to these examples. The following description is only a preferred embodiment of the present invention and is only for the purpose of explanation, but not to be construed as limiting the scope of the invention. It should be understood that any modification, equivalent replacement or improvement made within the spirit and principle of the present invention shall be included in the protection scope of the present invention, and therefore, the protection scope of the present invention shall be subject to the appended claims.
First, preparation examples
1. EXAMPLE 1 36% Thiamphenicol wettable powder (1:5)
Figure BDA0001588859120000021
Figure BDA0001588859120000031
The preparation method of the wettable powder comprises the following steps: the wettable powder of the invention can be prepared by uniformly mixing the active ingredient, the dispersant, the wetting agent and the filler according to the formula, uniformly stirring in a stirring kettle, and uniformly mixing after airflow crushing.
2. Example 2 20% Ethoxyspinosyn-hymexazol granules (1:1)
Figure BDA0001588859120000032
The preparation method of the granules comprises the following steps: the active ingredients and the auxiliary ingredients are uniformly mixed according to the formula, are wetted by deionized water after being ground, are extruded and granulated, and are dried in air flow to obtain the granules.
3. Example 3 33% Spinetoram hymexazol suspension (1:10)
Figure BDA0001588859120000033
The preparation method of the suspending agent comprises the following steps: accurately weighing the original medicine, the dispersing agent and the deionized water according to the formula, premixing and crushing in a mixing kettle, grinding for 3 hours by a sand mill, adding the thickening agent, the antifreezing agent and the rest water, and shearing at a high speed to obtain the suspending agent.
Second, preparation of pelleted seeds
The preparation method comprises the following steps: pouring the selected cabbage seeds into a pill coating machine with the rotating speed of 80-100rpm, applying an adhesive polyvinyl alcohol aqueous solution to the seeds, and continuously adding a coating composition, wherein the coating composition contains a mother solution of diluted spinetoram and hymexazol.
Third, drug effect test
1. Field test for preventing cabbage diamondback moth
In order to verify the actual application effect of the pesticide composition, a field pesticide effect test for preventing and controlling cabbage diamondback moths is carried out by applying the pesticide composition, 15% of hymexazol water aqua and 25% of spinetoram water dispersible granules are used as contrast agents, the test site is arranged in an area in Guangzhou city, the diamondback moths are in the full-blown stage of larvae in the 1-2 instar, 6 treatments are carried out in the test, each treatment is repeated for 3 times, the cells are randomly arranged, and the planting habits of all the cells are the same as the local planting habits.
Sampling at 5 points before and 3 and 7 days after pesticide application, investigating 2 plants at each point, observing the number of live and young insects on the whole plant leaf, and calculating the control effect of each treatment area according to the reduction rate of insect population. The test results are shown in table 1:
TABLE 1 control test on cabbage diamondback moth by different agent treatments
Figure BDA0001588859120000041
Test results show that the spinetoram and the hymexazol show a synergistic effect on the control of the cabbage diamondback moth in the proportion, and after the spinetoram is compounded, the use amount of pesticide active ingredients can be reduced, and the control effect is improved.

Claims (7)

1. The pesticide composition is characterized in that active ingredients of the pesticide composition comprise spinetoram and hymexazol, wherein the weight ratio of the spinetoram to the hymexazol is 1:1-1: 10.
2. the pesticidal composition according to claim 1, characterized by further comprising other pesticidal active ingredients.
3. The pesticide composition as set forth in claim 1 further comprising a pyrethroid insecticide.
4. A kit for controlling crop diseases, characterized by comprising the pesticidal composition according to claim 1.
5. The pesticide composition as set forth in claim 1, wherein the pesticide composition is in the form of any one of emulsifiable concentrate, water dispersible granules, wettable powder, suspending agent, microemulsion, aqueous emulsion, dispersible oil suspending agent, microcapsule suspending agent and seed treatment agent.
6. The pesticidal composition according to claim 1, characterized in that it is a coating ingredient of a pelleted seed.
7. Use of the pesticidal composition according to claim 1 for controlling crop pests.
CN201810182401.1A 2018-03-06 2018-03-06 Pesticide composition for seed coating agent Expired - Fee Related CN108157371B (en)

Priority Applications (1)

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CN108157371B true CN108157371B (en) 2021-06-01

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Citations (2)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
CN104145965A (en) * 2014-07-28 2014-11-19 浙江省化工研究院有限公司 Insecticidal and fungicidal composition containing hymexazol
CN106256204A (en) * 2015-06-17 2016-12-28 沈阳中化农药化工研发有限公司 A kind of insecticidal and bactericidal composition

Patent Citations (2)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
CN104145965A (en) * 2014-07-28 2014-11-19 浙江省化工研究院有限公司 Insecticidal and fungicidal composition containing hymexazol
CN106256204A (en) * 2015-06-17 2016-12-28 沈阳中化农药化工研发有限公司 A kind of insecticidal and bactericidal composition

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