CN108137727B - 酰基锗光引发剂及其制备方法 - Google Patents
酰基锗光引发剂及其制备方法 Download PDFInfo
- Publication number
- CN108137727B CN108137727B CN201680054564.0A CN201680054564A CN108137727B CN 108137727 B CN108137727 B CN 108137727B CN 201680054564 A CN201680054564 A CN 201680054564A CN 108137727 B CN108137727 B CN 108137727B
- Authority
- CN
- China
- Prior art keywords
- group
- alkyl
- branched
- free
- alkoxy
- Prior art date
- Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
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Classifications
-
- C—CHEMISTRY; METALLURGY
- C07—ORGANIC CHEMISTRY
- C07F—ACYCLIC, CARBOCYCLIC OR HETEROCYCLIC COMPOUNDS CONTAINING ELEMENTS OTHER THAN CARBON, HYDROGEN, HALOGEN, OXYGEN, NITROGEN, SULFUR, SELENIUM OR TELLURIUM
- C07F7/00—Compounds containing elements of Groups 4 or 14 of the Periodic Table
- C07F7/30—Germanium compounds
-
- A—HUMAN NECESSITIES
- A61—MEDICAL OR VETERINARY SCIENCE; HYGIENE
- A61K—PREPARATIONS FOR MEDICAL, DENTAL OR TOILETRY PURPOSES
- A61K6/00—Preparations for dentistry
- A61K6/60—Preparations for dentistry comprising organic or organo-metallic additives
- A61K6/62—Photochemical radical initiators
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08F—MACROMOLECULAR COMPOUNDS OBTAINED BY REACTIONS ONLY INVOLVING CARBON-TO-CARBON UNSATURATED BONDS
- C08F2/00—Processes of polymerisation
- C08F2/46—Polymerisation initiated by wave energy or particle radiation
- C08F2/48—Polymerisation initiated by wave energy or particle radiation by ultraviolet or visible light
- C08F2/50—Polymerisation initiated by wave energy or particle radiation by ultraviolet or visible light with sensitising agents
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08F—MACROMOLECULAR COMPOUNDS OBTAINED BY REACTIONS ONLY INVOLVING CARBON-TO-CARBON UNSATURATED BONDS
- C08F222/00—Copolymers of compounds having one or more unsaturated aliphatic radicals, each having only one carbon-to-carbon double bond, and at least one being terminated by a carboxyl radical and containing at least one other carboxyl radical in the molecule; Salts, anhydrides, esters, amides, imides, or nitriles thereof
- C08F222/10—Esters
- C08F222/1006—Esters of polyhydric alcohols or polyhydric phenols
- C08F222/102—Esters of polyhydric alcohols or polyhydric phenols of dialcohols, e.g. ethylene glycol di(meth)acrylate or 1,4-butanediol dimethacrylate
- C08F222/1025—Esters of polyhydric alcohols or polyhydric phenols of dialcohols, e.g. ethylene glycol di(meth)acrylate or 1,4-butanediol dimethacrylate of aromatic dialcohols
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08F—MACROMOLECULAR COMPOUNDS OBTAINED BY REACTIONS ONLY INVOLVING CARBON-TO-CARBON UNSATURATED BONDS
- C08F4/00—Polymerisation catalysts
- C08F4/42—Metals; Metal hydrides; Metallo-organic compounds; Use thereof as catalyst precursors
- C08F4/72—Metals; Metal hydrides; Metallo-organic compounds; Use thereof as catalyst precursors selected from metals not provided for in group C08F4/44
Landscapes
- Chemical & Material Sciences (AREA)
- Health & Medical Sciences (AREA)
- Organic Chemistry (AREA)
- Polymers & Plastics (AREA)
- Medicinal Chemistry (AREA)
- Chemical Kinetics & Catalysis (AREA)
- Life Sciences & Earth Sciences (AREA)
- Materials Engineering (AREA)
- Engineering & Computer Science (AREA)
- Veterinary Medicine (AREA)
- Public Health (AREA)
- General Health & Medical Sciences (AREA)
- Animal Behavior & Ethology (AREA)
- Epidemiology (AREA)
- Oral & Maxillofacial Surgery (AREA)
- Biophysics (AREA)
- Organic Low-Molecular-Weight Compounds And Preparation Thereof (AREA)
- Polymerization Catalysts (AREA)
- Dental Preparations (AREA)
- Polymerisation Methods In General (AREA)
Applications Claiming Priority (3)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| EP15187284.3A EP3150641B1 (de) | 2015-09-29 | 2015-09-29 | Acylgermanium-photoinitiatoren und verfahren zu deren herstellung |
| EP15187284.3 | 2015-09-29 | ||
| PCT/EP2016/072835 WO2017055209A1 (de) | 2015-09-29 | 2016-09-26 | Acylgermanium-photoinitiatoren und verfahren zu deren herstellung |
Publications (2)
| Publication Number | Publication Date |
|---|---|
| CN108137727A CN108137727A (zh) | 2018-06-08 |
| CN108137727B true CN108137727B (zh) | 2020-07-24 |
Family
ID=54292569
Family Applications (1)
| Application Number | Title | Priority Date | Filing Date |
|---|---|---|---|
| CN201680054564.0A Active CN108137727B (zh) | 2015-09-29 | 2016-09-26 | 酰基锗光引发剂及其制备方法 |
Country Status (6)
| Country | Link |
|---|---|
| US (2) | US10533025B2 (enExample) |
| EP (1) | EP3150641B1 (enExample) |
| JP (1) | JP6872535B2 (enExample) |
| CN (1) | CN108137727B (enExample) |
| ES (1) | ES2695237T3 (enExample) |
| WO (1) | WO2017055209A1 (enExample) |
Families Citing this family (24)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| US10604659B2 (en) | 2015-06-08 | 2020-03-31 | Dsm Ip Assets B.V. | Liquid, hybrid UV/VIS radiation curable resin compositions for additive fabrication |
| KR102663364B1 (ko) | 2015-10-01 | 2024-05-08 | 스트래터시스,인코포레이티드 | 적층식 제조용 액체 하이브리드 uv/가시광 복사선-경화성 수지 조성물 |
| CN109096325B (zh) * | 2018-07-10 | 2020-09-01 | 杭州师范大学 | 一锅法制备二烷基二酰基锗化合物的方法与应用 |
| US11319456B2 (en) * | 2018-12-05 | 2022-05-03 | Corning Incorporated | Fiber coating compositions with acylgermane photoinitiators |
| EP3669856A1 (de) | 2018-12-21 | 2020-06-24 | Ivoclar Vivadent AG | Zusammensetzungen für die herstellung von transparenten dentalwerkstücken mittels stereolithographie |
| EP3669853B1 (de) | 2018-12-21 | 2022-03-30 | Ivoclar Vivadent AG | Zusammensetzungen für die herstellung von bruchzähen dentalwerkstücken mittels stereolithographie |
| CN113518805B (zh) | 2018-12-28 | 2023-08-08 | 意大利艾坚蒙树脂有限公司 | 光引发剂 |
| ES2879378T3 (es) * | 2019-02-07 | 2021-11-22 | Ivoclar Vivadent Ag | Materiales dentales a base de sistemas rédox con derivados de hidroperóxido de cumeno de olor reducido |
| EP3959246A1 (en) | 2019-04-25 | 2022-03-02 | Arkema France | Light-curable compositions useful for forming composite materials |
| WO2021070152A1 (en) | 2019-10-11 | 2021-04-15 | Igm Resins Italia S.R.L. | Coumarin glyoxylates for led photocuring |
| US11981693B2 (en) | 2019-10-24 | 2024-05-14 | Asai Germanium Research Institute Co., Ltd. | Organogermanium compound |
| EP3868767B1 (de) * | 2020-02-21 | 2022-01-05 | Ivoclar Vivadent AG | Langwellig absorbierende photoinitiatoren |
| CN112062879B (zh) * | 2020-08-18 | 2023-01-24 | 新丰博兴聚合材料有限公司 | 一种光引发剂及其制备方法和应用 |
| IT202000023815A1 (it) | 2020-10-09 | 2022-04-09 | Igm Resins Italia Srl | Ketoquinolones as photonitiators |
| DE102021113969A1 (de) | 2021-05-31 | 2022-12-01 | Mühlbauer Technology Gmbh | Monomermischung zur Herstellung eines Dentalmaterials |
| IT202100014885A1 (it) | 2021-06-08 | 2022-12-08 | Igm Resins Italia Srl | Fotoiniziatori a base di silicio bifunzionali |
| AT525740B1 (de) * | 2022-03-29 | 2023-07-15 | Univ Wien Tech | Verwendung von Tetrakisacylgermanen als Photoinitiatoren |
| EP4257592A1 (en) | 2022-04-08 | 2023-10-11 | Evonik Operations GmbH | Bisacyl digermanium compounds, their preparation and their use as photoinitiator for radical polymerization |
| DE102022116577A1 (de) | 2022-07-04 | 2024-01-04 | Mühlbauer Technology Gmbh | Monomermischung zur Herstellung eines Dentalmaterials |
| EP4331796A1 (en) | 2022-09-02 | 2024-03-06 | Arkema France | Actinic radiation curable cyanoacrylate compositions for ceramics and investment casting |
| EP4368167A1 (de) | 2022-11-08 | 2024-05-15 | Ivoclar Vivadent AG | Dentalwerkstoff zur herstellung dentaler voll- oder teilprothesen |
| DE102023111186A1 (de) | 2023-05-02 | 2024-11-07 | Mühlbauer Technology Gmbh | Radikalisch polymerisierbare Verbindung und Zusammensetzung |
| WO2025027517A1 (en) | 2023-08-03 | 2025-02-06 | Igm Resins Italia S.R.L. | 10,11 -dihydro-5h-dibenzo[b,f]azepine derivatives as photoinitiatiors in photopolymerisation for use in photocurable compositions |
| DE102023135732A1 (de) | 2023-12-19 | 2025-06-26 | Mühlbauer Technology Gmbh | Radikalisch polymerisierbare Verbindung und Zusammensetzung |
Family Cites Families (19)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| GB1408265A (en) | 1971-10-18 | 1975-10-01 | Ici Ltd | Photopolymerisable composition |
| DE2964564D1 (en) | 1978-12-18 | 1983-02-24 | Ici Plc | Dental compositions comprising a selected vinyl urethane prepolymer and processes for their manufacture |
| US4525256A (en) | 1983-07-01 | 1985-06-25 | Johnson & Johnson Dental Products Company | Photopolymerizable composition including catalyst comprising diketone plus 4-(N,N-dimethylamino)benzoic acid or ester thereof |
| AUPN023294A0 (en) | 1994-12-22 | 1995-01-27 | Commonwealth Scientific And Industrial Research Organisation | Polymerisable monomers and polymers |
| DE19616183C2 (de) | 1996-03-20 | 1999-05-12 | Ivoclar Ag | Funktionalisiertes und polymerisierbares Polymer |
| DE19903177C5 (de) | 1999-01-21 | 2010-09-16 | Ivoclar Vivadent Ag | Verwendung von Materialien auf der Basis von Polysiloxanen als Dentalmaterialien |
| EP1261655A1 (en) | 2000-01-13 | 2002-12-04 | UV Specialties, Inc. | Uv curable woodcoat compositions |
| US6470128B1 (en) | 2001-03-30 | 2002-10-22 | Alcatel | UV-curable coating composition for optical fiber for a fast cure and with improved adhesion to glass |
| DE10249324A1 (de) | 2002-10-22 | 2004-06-24 | Ivoclar Vivadent Ag | Polymerisationsfähige bicyclische Cyclopropanderivate und deren Verwendung zur Herstellung von Dentalmaterialien |
| EP1905413A1 (de) * | 2006-09-27 | 2008-04-02 | Ivoclar Vivadent AG | Polymerisierbare Zusammensetzungen mit Acylgermanen als Initiatoren |
| EP1905415B1 (de) * | 2006-09-27 | 2009-07-01 | Ivoclar Vivadent AG | Polymerisierbare Zusammensetzungen mit Acylgermanium-Verbindungen als Initiatoren |
| EP2103297B1 (de) * | 2008-03-20 | 2012-05-16 | Ivoclar Vivadent AG | Polymerisierbare Zusammensetzung mit mehrere Germanium-Atome enthaltenden Initiatoren |
| CN104246606B (zh) * | 2012-04-11 | 2019-05-10 | 义获嘉伟瓦登特公司 | 复合树脂组合物及其用途、用立体石印术制备牙组件的方法 |
| EP2649981B1 (de) * | 2012-04-11 | 2018-11-21 | Ivoclar Vivadent AG | Polymerisierbare Zusammensetzungen mit hoher Polymerisationstiefe |
| EP2870956A1 (en) | 2013-11-11 | 2015-05-13 | Dentsply DeTrey GmbH | Dental composition |
| EP2965741A1 (de) * | 2014-07-11 | 2016-01-13 | Ivoclar Vivadent AG | Komposite mit gesteuerter Netzwerkstruktur |
| EP3303415B1 (en) * | 2015-06-02 | 2022-12-28 | Alcon Inc. | Visible-light photoinitiators and uses thereof |
| DE102016214389B4 (de) * | 2016-08-03 | 2024-12-05 | Ivoclar Vivadent Ag | Dentalmaterialien auf der Basis von monofunktionellen Vinylcyclopropan-Derivaten |
| ES2718766T3 (es) * | 2016-08-03 | 2019-07-04 | Ivoclar Vivadent Ag | Materiales dentales a base de derivados de vinilciclopropano que contienen grupos uretano |
-
2015
- 2015-09-29 EP EP15187284.3A patent/EP3150641B1/de active Active
- 2015-09-29 ES ES15187284T patent/ES2695237T3/es active Active
-
2016
- 2016-09-26 WO PCT/EP2016/072835 patent/WO2017055209A1/de not_active Ceased
- 2016-09-26 CN CN201680054564.0A patent/CN108137727B/zh active Active
- 2016-09-26 JP JP2018514367A patent/JP6872535B2/ja active Active
- 2016-09-26 US US15/763,959 patent/US10533025B2/en active Active
-
2019
- 2019-11-19 US US16/687,896 patent/US10787468B2/en active Active
Also Published As
| Publication number | Publication date |
|---|---|
| US10533025B2 (en) | 2020-01-14 |
| US10787468B2 (en) | 2020-09-29 |
| EP3150641B1 (de) | 2018-08-29 |
| JP2018534249A (ja) | 2018-11-22 |
| US20200087329A1 (en) | 2020-03-19 |
| JP6872535B2 (ja) | 2021-05-19 |
| CN108137727A (zh) | 2018-06-08 |
| ES2695237T3 (es) | 2019-01-02 |
| WO2017055209A1 (de) | 2017-04-06 |
| EP3150641A1 (de) | 2017-04-05 |
| US20180265527A1 (en) | 2018-09-20 |
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|---|---|---|---|
| PB01 | Publication | ||
| PB01 | Publication | ||
| SE01 | Entry into force of request for substantive examination | ||
| SE01 | Entry into force of request for substantive examination | ||
| GR01 | Patent grant | ||
| GR01 | Patent grant |