CN108136316B - 用于选择性移除硫化氢的吸收剂 - Google Patents

用于选择性移除硫化氢的吸收剂 Download PDF

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Publication number
CN108136316B
CN108136316B CN201680056215.2A CN201680056215A CN108136316B CN 108136316 B CN108136316 B CN 108136316B CN 201680056215 A CN201680056215 A CN 201680056215A CN 108136316 B CN108136316 B CN 108136316B
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acid
absorbent
fluid stream
alkyl
gas
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CN108136316A (zh
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G·福尔贝格
R·诺茨
T·因格拉姆
G·西德尔
T·卡茨
C·格鲁南格
P·德格尔曼
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BASF SE
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    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01D—SEPARATION
    • B01D53/00—Separation of gases or vapours; Recovering vapours of volatile solvents from gases; Chemical or biological purification of waste gases, e.g. engine exhaust gases, smoke, fumes, flue gases, aerosols
    • B01D53/14—Separation of gases or vapours; Recovering vapours of volatile solvents from gases; Chemical or biological purification of waste gases, e.g. engine exhaust gases, smoke, fumes, flue gases, aerosols by absorption
    • B01D53/1493—Selection of liquid materials for use as absorbents
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01D—SEPARATION
    • B01D53/00—Separation of gases or vapours; Recovering vapours of volatile solvents from gases; Chemical or biological purification of waste gases, e.g. engine exhaust gases, smoke, fumes, flue gases, aerosols
    • B01D53/14—Separation of gases or vapours; Recovering vapours of volatile solvents from gases; Chemical or biological purification of waste gases, e.g. engine exhaust gases, smoke, fumes, flue gases, aerosols by absorption
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01D—SEPARATION
    • B01D53/00—Separation of gases or vapours; Recovering vapours of volatile solvents from gases; Chemical or biological purification of waste gases, e.g. engine exhaust gases, smoke, fumes, flue gases, aerosols
    • B01D53/14—Separation of gases or vapours; Recovering vapours of volatile solvents from gases; Chemical or biological purification of waste gases, e.g. engine exhaust gases, smoke, fumes, flue gases, aerosols by absorption
    • B01D53/1425—Regeneration of liquid absorbents
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01D—SEPARATION
    • B01D53/00—Separation of gases or vapours; Recovering vapours of volatile solvents from gases; Chemical or biological purification of waste gases, e.g. engine exhaust gases, smoke, fumes, flue gases, aerosols
    • B01D53/14—Separation of gases or vapours; Recovering vapours of volatile solvents from gases; Chemical or biological purification of waste gases, e.g. engine exhaust gases, smoke, fumes, flue gases, aerosols by absorption
    • B01D53/1456—Removing acid components
    • B01D53/1468—Removing hydrogen sulfide
    • C—CHEMISTRY; METALLURGY
    • C10—PETROLEUM, GAS OR COKE INDUSTRIES; TECHNICAL GASES CONTAINING CARBON MONOXIDE; FUELS; LUBRICANTS; PEAT
    • C10L—FUELS NOT OTHERWISE PROVIDED FOR; NATURAL GAS; SYNTHETIC NATURAL GAS OBTAINED BY PROCESSES NOT COVERED BY SUBCLASSES C10G OR C10K; LIQUIFIED PETROLEUM GAS; USE OF ADDITIVES TO FUELS OR FIRES; FIRE-LIGHTERS
    • C10L3/00—Gaseous fuels; Natural gas; Synthetic natural gas obtained by processes not covered by subclass C10G, C10K; Liquefied petroleum gas
    • C10L3/06—Natural gas; Synthetic natural gas obtained by processes not covered by C10G, C10K3/02 or C10K3/04
    • C10L3/10—Working-up natural gas or synthetic natural gas
    • C10L3/101—Removal of contaminants
    • C10L3/102—Removal of contaminants of acid contaminants
    • C10L3/103—Sulfur containing contaminants
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01D—SEPARATION
    • B01D2252/00—Absorbents, i.e. solvents and liquid materials for gas absorption
    • B01D2252/20—Organic absorbents
    • B01D2252/204—Amines
    • B01D2252/20405—Monoamines
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01D—SEPARATION
    • B01D2252/00—Absorbents, i.e. solvents and liquid materials for gas absorption
    • B01D2252/20—Organic absorbents
    • B01D2252/204—Amines
    • B01D2252/2041—Diamines
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01D—SEPARATION
    • B01D2252/00—Absorbents, i.e. solvents and liquid materials for gas absorption
    • B01D2252/20—Organic absorbents
    • B01D2252/204—Amines
    • B01D2252/20415—Tri- or polyamines
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01D—SEPARATION
    • B01D2252/00—Absorbents, i.e. solvents and liquid materials for gas absorption
    • B01D2252/20—Organic absorbents
    • B01D2252/204—Amines
    • B01D2252/20426—Secondary amines
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01D—SEPARATION
    • B01D2252/00—Absorbents, i.e. solvents and liquid materials for gas absorption
    • B01D2252/20—Organic absorbents
    • B01D2252/204—Amines
    • B01D2252/20431—Tertiary amines
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01D—SEPARATION
    • B01D2252/00—Absorbents, i.e. solvents and liquid materials for gas absorption
    • B01D2252/20—Organic absorbents
    • B01D2252/204—Amines
    • B01D2252/20478—Alkanolamines
    • B01D2252/20484—Alkanolamines with one hydroxyl group
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01D—SEPARATION
    • B01D2252/00—Absorbents, i.e. solvents and liquid materials for gas absorption
    • B01D2252/20—Organic absorbents
    • B01D2252/204—Amines
    • B01D2252/20478—Alkanolamines
    • B01D2252/20489—Alkanolamines with two or more hydroxyl groups
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01D—SEPARATION
    • B01D2252/00—Absorbents, i.e. solvents and liquid materials for gas absorption
    • B01D2252/50—Combinations of absorbents
    • B01D2252/504—Mixtures of two or more absorbents
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01D—SEPARATION
    • B01D2252/00—Absorbents, i.e. solvents and liquid materials for gas absorption
    • B01D2252/60—Additives
    • B01D2252/602—Activators, promoting agents, catalytic agents or enzymes
    • C—CHEMISTRY; METALLURGY
    • C10—PETROLEUM, GAS OR COKE INDUSTRIES; TECHNICAL GASES CONTAINING CARBON MONOXIDE; FUELS; LUBRICANTS; PEAT
    • C10L—FUELS NOT OTHERWISE PROVIDED FOR; NATURAL GAS; SYNTHETIC NATURAL GAS OBTAINED BY PROCESSES NOT COVERED BY SUBCLASSES C10G OR C10K; LIQUIFIED PETROLEUM GAS; USE OF ADDITIVES TO FUELS OR FIRES; FIRE-LIGHTERS
    • C10L2290/00—Fuel preparation or upgrading, processes or apparatus therefore, comprising specific process steps or apparatus units
    • C10L2290/54—Specific separation steps for separating fractions, components or impurities during preparation or upgrading of a fuel
    • C10L2290/541—Absorption of impurities during preparation or upgrading of a fuel
    • Y—GENERAL TAGGING OF NEW TECHNOLOGICAL DEVELOPMENTS; GENERAL TAGGING OF CROSS-SECTIONAL TECHNOLOGIES SPANNING OVER SEVERAL SECTIONS OF THE IPC; TECHNICAL SUBJECTS COVERED BY FORMER USPC CROSS-REFERENCE ART COLLECTIONS [XRACs] AND DIGESTS
    • Y02—TECHNOLOGIES OR APPLICATIONS FOR MITIGATION OR ADAPTATION AGAINST CLIMATE CHANGE
    • Y02C—CAPTURE, STORAGE, SEQUESTRATION OR DISPOSAL OF GREENHOUSE GASES [GHG]
    • Y02C20/00—Capture or disposal of greenhouse gases
    • Y02C20/40—Capture or disposal of greenhouse gases of CO2

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  • Chemical & Material Sciences (AREA)
  • Oil, Petroleum & Natural Gas (AREA)
  • Engineering & Computer Science (AREA)
  • General Chemical & Material Sciences (AREA)
  • Chemical Kinetics & Catalysis (AREA)
  • Analytical Chemistry (AREA)
  • Organic Chemistry (AREA)
  • Gas Separation By Absorption (AREA)
  • Treating Waste Gases (AREA)
CN201680056215.2A 2015-09-29 2016-09-28 用于选择性移除硫化氢的吸收剂 Active CN108136316B (zh)

Applications Claiming Priority (3)

Application Number Priority Date Filing Date Title
EP15187389 2015-09-29
EP15187389.0 2015-09-29
PCT/EP2016/073025 WO2017055304A2 (de) 2015-09-29 2016-09-28 Absorptionsmittel zur selektiven entfernung von schwefelwasserstoff

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CN108136316A CN108136316A (zh) 2018-06-08
CN108136316B true CN108136316B (zh) 2021-07-23

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US (1) US10617993B2 (https=)
EP (1) EP3356013B1 (https=)
JP (1) JP2018531145A (https=)
KR (1) KR20180057628A (https=)
CN (1) CN108136316B (https=)
AU (1) AU2016330797A1 (https=)
BR (1) BR112018003733A2 (https=)
CA (1) CA3000037C (https=)
CO (1) CO2018003666A2 (https=)
IL (1) IL257668A (https=)
MX (1) MX2018004010A (https=)
RU (1) RU2746838C1 (https=)
SG (1) SG11201801360PA (https=)
WO (1) WO2017055304A2 (https=)
ZA (1) ZA201802683B (https=)

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Publication number Priority date Publication date Assignee Title
EA039814B1 (ru) * 2016-04-18 2022-03-16 Басф Се Предварительно приготовленная смесь для получения абсорбента для удаления кислотных газов из потока текучей среды
EP3448543B1 (en) 2016-04-25 2020-06-10 Basf Se Use of morpholine-based hindered amine compounds for selective removal of hydrogen sulfide
EP3493892B1 (de) 2016-08-01 2020-07-08 Basf Se Zweistufiges verfahren zum entfernen von co2 aus synthesegas
ES2877641T3 (es) 2017-02-10 2021-11-17 Basf Se Proceso para la remoción de gases ácidos de una corriente de fluido y los correspondientes usos
WO2018202765A1 (en) 2017-05-03 2018-11-08 Basf Se Process for the conversion of ethylene oxide to monoethanolamine and ethylenediamine employing a zeolite
EP3624922B1 (en) 2017-05-15 2021-07-07 Basf Se Absorbent, process for producing it and process for selectively removing hydrogen sulfide using it
US11471821B2 (en) 2020-04-18 2022-10-18 Indian Oil Corporation Limited Process for biogas upgradation
KR20250007660A (ko) * 2022-06-13 2025-01-14 아사히 가세이 가부시키가이샤 폴리카르보네이트의 제조 방법, 디히드록시 화합물의 회수 방법, 및 폴리카르보네이트의 제조 장치
WO2024180358A1 (en) 2023-02-27 2024-09-06 Totalenergies Onetech Method for selective separation of hydrogen sulfide from a gas mixture
CN116550100A (zh) * 2023-05-30 2023-08-08 江苏太湖新材料控股有限公司 脱硫剂及其制备方法
CN118577100B (zh) * 2024-06-26 2025-01-21 宜兴汉光高新石化有限公司 一种高效复配脱硫脱碳溶剂及其制备方法

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JPS53138403A (en) * 1977-05-10 1978-12-02 Ube Ind Ltd Desulfurization of industrial gases
JPS6048116A (ja) * 1983-06-30 1985-03-15 ユニオン、カ−バイド、コ−ポレ−シヨン ガス混合物から酸性ガスを増大除去するための吸収剤組成物及びそれを使用する方法
US4892674A (en) * 1987-10-13 1990-01-09 Exxon Research And Engineering Company Addition of severely-hindered amine salts and/or aminoacids to non-hindered amine solutions for the absorption of H2 S
CN102421507A (zh) * 2009-05-12 2012-04-18 巴斯夫欧洲公司 从流体流中选择性除去硫化氢的吸收剂
CN102470340A (zh) * 2009-06-30 2012-05-23 纳尔科公司 酸性气体洗涤组合物
CN102805989A (zh) * 2011-05-30 2012-12-05 株式会社东芝 酸性气体吸收剂、酸性气体去除方法及酸性气体去除装置
CN103505994A (zh) * 2012-06-25 2014-01-15 株式会社东芝 酸性气体吸收剂、酸性气体去除方法以及酸性气体去除装置
CN103635247A (zh) * 2011-06-10 2014-03-12 赢创德固赛有限公司 用于从气体混合物吸收酸性气体的吸收介质和方法
FR3001157A1 (fr) * 2013-01-24 2014-07-25 IFP Energies Nouvelles Solution absorbante a base d'une amine tertiaire ou encombree et d'un activeur particulier et procede d'elimination de composes acides d'un effluent gazeux
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CN104560252A (zh) * 2013-10-28 2015-04-29 中国石油化工股份有限公司 天然气脱硫脱碳剂

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* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
JPS53138403A (en) * 1977-05-10 1978-12-02 Ube Ind Ltd Desulfurization of industrial gases
JPS6048116A (ja) * 1983-06-30 1985-03-15 ユニオン、カ−バイド、コ−ポレ−シヨン ガス混合物から酸性ガスを増大除去するための吸収剤組成物及びそれを使用する方法
US4892674A (en) * 1987-10-13 1990-01-09 Exxon Research And Engineering Company Addition of severely-hindered amine salts and/or aminoacids to non-hindered amine solutions for the absorption of H2 S
CN102421507A (zh) * 2009-05-12 2012-04-18 巴斯夫欧洲公司 从流体流中选择性除去硫化氢的吸收剂
CN102470340A (zh) * 2009-06-30 2012-05-23 纳尔科公司 酸性气体洗涤组合物
CN102805989A (zh) * 2011-05-30 2012-12-05 株式会社东芝 酸性气体吸收剂、酸性气体去除方法及酸性气体去除装置
CN103635247A (zh) * 2011-06-10 2014-03-12 赢创德固赛有限公司 用于从气体混合物吸收酸性气体的吸收介质和方法
CN103505994A (zh) * 2012-06-25 2014-01-15 株式会社东芝 酸性气体吸收剂、酸性气体去除方法以及酸性气体去除装置
FR3001157A1 (fr) * 2013-01-24 2014-07-25 IFP Energies Nouvelles Solution absorbante a base d'une amine tertiaire ou encombree et d'un activeur particulier et procede d'elimination de composes acides d'un effluent gazeux
CN104338413A (zh) * 2013-08-07 2015-02-11 株式会社东芝 酸性气体吸收剂、酸性气体除去方法及酸性气体除去装置
CN104560252A (zh) * 2013-10-28 2015-04-29 中国石油化工股份有限公司 天然气脱硫脱碳剂

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JP2018531145A (ja) 2018-10-25
MX2018004010A (es) 2018-05-23
EP3356013B1 (de) 2021-08-04
US20180311611A1 (en) 2018-11-01
CA3000037A1 (en) 2017-04-06
IL257668A (en) 2018-04-30
CO2018003666A2 (es) 2018-08-21
KR20180057628A (ko) 2018-05-30
US10617993B2 (en) 2020-04-14
WO2017055304A3 (de) 2017-05-26
ZA201802683B (en) 2019-07-31
CA3000037C (en) 2023-08-01
SG11201801360PA (en) 2018-04-27
WO2017055304A2 (de) 2017-04-06
RU2746838C1 (ru) 2021-04-21
EP3356013A2 (de) 2018-08-08
AU2016330797A1 (en) 2018-03-29
CN108136316A (zh) 2018-06-08
BR112018003733A2 (pt) 2018-09-25

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