CN108135798B

CN108135798B - Color cosmetic composition for improving transfer viscosity and preparation method thereof

Info

Publication number: CN108135798B
Application number: CN201680056650.5A
Authority: CN
Inventors: 韩高云; 沈珉敬; 金银晶
Original assignee: Amorepacific Corp
Current assignee: Amorepacific Corp
Priority date: 2015-09-30
Filing date: 2016-09-19
Publication date: 2021-10-26
Anticipated expiration: 2036-09-19
Also published as: KR20170038265A; CN108135798A; KR102453363B1; SG11201802191XA; WO2017057862A1; HK1254685A1

Abstract

The invention relates to a color cosmetic composition for improving transfer viscosity and a preparation method thereof. Specifically, the invention provides a wax-free color cosmetic composition containing a silicate film forming agent, a silsesquioxane film forming agent, platy powder and spherical powder. In addition, the present invention provides a method for preparing a wax-free color cosmetic composition, the method comprising: a) mixing a silicate film-forming agent, a silsesquioxane film-forming agent, plate-shaped powder and spherical powder; and b) a step of adding a hydrocarbon oil to the mixture to form a composition in the form of a paste. The color cosmetic composition disclosed by the invention not only improves the transfer viscosity and improves the durability, but also does not reduce the moisturizing feeling and the smearing property compared with the traditional composition, and the preparation method has the characteristics of convenience in process and improvement on the production efficiency.

Description

Color cosmetic composition for improving transfer viscosity and preparation method thereof

Technical Field

The present application claims benefits based on priority of korean patent application No. 10-2015-.

The present invention relates to a color cosmetic composition that can be prepared without using wax and high content of oil and improves transfer tack, and a method for preparing the same.

Background

Conventional make-up compositions, such as lipsticks and the like, are often manufactured using waxes as an essential ingredient. Waxes are added to make-up compositions for forming the appropriate hardness and shape of the make-up formulation, generally have high melting points, and are used in combination with high levels of oils and pigments. However, the above ingredients do not dry well on the surface of lips or skin due to their properties, thus maintaining a wet state when used, and easily transfer to a cup or clothes, causing great inconvenience to daily life. In addition, a portion remaining on the skin surface without transfer-sticking is also wiped off with the passage of time due to the skin condition and the influence of the external environment, and thus makeup cannot be continued for a long time.

Therefore, users of color cosmetic products are required to face the trouble of correcting and reapplying cosmetics several times a day, and thus users are largely restricted from freely using color cosmetic compositions. In order to solve these problems, it is necessary to develop an improved form of color cosmetic composition.

As a solution to the above problems, it has been considered that the main cause of the trans-adhesion of the formulation of the conventional color cosmetic composition is wax and a high content of oil, and thus it is considered most effective to limit the use of these materials. However, in the case of preparing a formulation without using wax, there are various technical limitations such as difficulty in forming a paste (paste) at an appropriate concentration, or difficulty in forming a formulation having appropriate hardness upon hardening, and the like. On the other hand, attempts have been made to use a film-forming agent in a mascara formulation to maintain a lasting effect and prevent trans-adhesion, however, unlike eyebrows, lips or skin are moved a lot and wrinkles are generated, thus hardening and cracking are generated when applied, or spreadability is reduced to generate an uncomfortable feeling in use, which has a problem that it is not suitable for commercialization.

Therefore, various studies have been made on color cosmetic compositions in order to overcome the technical limitations. In addition, in the manufacturing process of the color cosmetic composition, if wax is contained, high temperature processing conditions must be provided to melt the wax, and a process of melting the wax is required many times, which has a problem of lowering production efficiency, and thus, a need for improving the process to be faster and simpler has been suggested.

[ Prior art documents ]

[ patent document ]

(patent document 1) matte cosmetic compositions for color makeup or care of lips (korean patent No. 10-1060881).

Disclosure of Invention

In order to achieve the above object, the present invention provides a color cosmetic composition comprising a film-forming agent of silicate (silicate), a film-forming agent of silsesquioxane (silsesquioxane), a plate-like powder and a spherical powder.

At this time, the color cosmetic composition may further comprise a siliconized polysaccharide compound as a film forming agent.

In this case, the siliconized polysaccharide compound may be trimethylsiloxysilylcarbamoyl pullulan (trimethylsiloxysilylcarbamoyl pullulan).

At this time, the silicate type film forming agent may be at least one selected from the group consisting of trimethylsiloxy silicate (trimethlysilicate), phenylpropylpropyldimethylsiloxy silicate (phenopyldyimethicilliloxysilicate), trimethylsiloxy silicate/dimethicone crosspolymer (trimethlysilicate/dimethlysiloxane crosslinker), and dimethicone/vinyltrimethylsiloxy silicate crosspolymer (dimethlysiloxane/vinyltrimethylsiloxy silicate crosslinker).

In this case, the silsesquioxane-based film forming agent may be at least one selected from the group consisting of polyphenylsilsesquioxane (polyphenylsilsesquioxane), polypropylsilsesquioxane (polypropylsilsesquioxane), and dimethicone/silsesquioxane copolymer (dimethicone/silsesquioxane copolymer) combinations.

In this case, the silicate film former may be trimethylsiloxysilicate (trimethliloxysilicate), and the silsesquioxane film former may be polypropylsilsequioxane (polypropylsilsequioxane).

At this time, the spherical powder may be at least one selected from the group consisting of silica, Polymethylmethacrylate (PMMA), Polyurethane (PU), Polymethylsilsesquioxane (PMSQ), and nylon in combination.

In this case, the plate-like powder may be at least one selected from the group consisting of talc, boron nitride, mica, and sericite.

In this case, the weight ratio of the silicate film former to the silsesquioxane film former may be 3:1 to 3: 3.

At this time, the silicate film former and the silsesquioxane film former may be contained in a total amount of 10 to 40% by weight, based on the total weight of the composition.

The weight ratio of spherical powder to plate-like powder may be 2: 1-2: 2.

at this time, the total content of the spherical powder and the plate-shaped powder may be 30 to 95% by weight, based on the total weight of the composition.

At this time, the content of the oil contained in the makeup composition may not exceed 40% by weight, based on the total weight of the composition.

In addition, the present invention provides a method for preparing a color cosmetic composition, comprising:

a) mixing (misting) a silicate film former, a silsesquioxane film former, a plate-shaped powder and a spherical powder; and

b) a step of adding hydrocarbon oil (hydrocarbon) to the mixture to form a composition in the form of a paste (paste).

At this time, the step a) may include:

a-1) a step of mixing spherical powder and plate-like powder; and

a-2) a step of mixing a silicate film former and a silsesquioxane film former with the mixture of spherical powder and plate-shaped powder.

In this case, in step b), a humectant and a functional polymer may be further added.

In this case, the color cosmetic composition may be prepared at 15 to 30 ℃.

The invention has the following effects:

by using the technical solution, the color cosmetic composition of the present invention improves transfer tack and improves durability without lowering moisturizing feeling and spreadability as compared with conventional compositions.

In addition, according to the technical solution, as the process of melting wax is omitted in the process of preparing the color cosmetic composition, the process can be carried out at room temperature, and the process time is shortened to 10-20 minutes, so that the convenience and the production efficiency in preparation are improved, and the cost is reduced.

Drawings

FIG. 1 is an image for confirming the degree of transadhesion on a paper towel after (a) the compositions of example 1 and (b) comparative example 2, respectively, were applied to artificial leather;

FIG. 2 is an image for confirming the degree of transsticking on a paper cup when (a) the compositions of example 1 and (b) comparative example 2 were applied directly to the lips, respectively;

FIG. 3 is an image for confirming the durability of (a) the composition of example 1 and (b) comparative example 1.

Detailed Description

The invention provides a color cosmetic composition containing a silicate film forming agent, a silsesquioxane film forming agent, plate-shaped powder and spherical powder.

a) mixing a silicate film-forming agent, a silsesquioxane film-forming agent, plate-shaped powder and spherical powder; and

b) a step of adding hydrocarbon oil to the mixture to form a composition in a paste dosage form.

The color cosmetic composition of the present invention is a "Wax-free" preparation containing a small amount of oil, and can be preferably used as a color cosmetic composition, more preferably as a lip (lip) color cosmetic composition. As used herein, "Wax-free" refers to a formulation that does not contain Wax. In contrast to conventional makeup compositions, which typically contain a wax and a large amount of oil, such as lip makeup compositions, the makeup composition of the present invention can be prepared by mixing a film-forming agent and a powder, without using a wax and with a small amount of oil. Therefore, the color cosmetic composition of the present invention has the effects of effectively reducing transfer tack and improving durability after application.

In addition, the color cosmetic composition of the present invention may also have an effect of improving the durability by using a film-forming agent in the composition. The "durability" refers to a phenomenon in which the stability of the preparation itself changes with time and the spreading state becomes poor due to sebum or sweat secreted from the skin itself, or environmental stimuli such as temperature or humidity, unlike the concept of "transfer-tack", which is unrelated to the stability of the preparation itself, and refers to a phenomenon in which the cosmetic composition is transferred to an object or the spreading state becomes poor when external physical contact is applied thereto, for example, when the skin is in contact with another object.

In the present specification, the color cosmetic composition of the present invention is mainly described around lip color cosmetic products such as lipstick, lip gloss, lip protector, lip gloss, lip pencil, etc., but the present invention is not limited thereto, and can be freely and flexibly used as any form of cosmetic formulation to which the composition and effect of the composition of the present invention are applied.

The present invention will be described in detail below. In the following description, the most representative examples are provided to help understanding of the present invention, but the scope of the present invention is not limited thereto, and it should be understood that the present invention includes all the scope of the claims equivalent to the following description.

< color cosmetic composition >

Film forming agent

The color cosmetic composition of the present invention comprises a silicate film former and a silsesquioxane film former as one component of the composition to provide a wax-free color cosmetic composition for preventing transfer tack. The film forming agent is most effective in improving transfer and improving durability when used in combination with the powder described below.

The silicate film former may be at least one selected from the group consisting of trimethylsiloxysilicate, phenylpropyldimethylsiloxysiliconate, trimethylsiloxysilicate/polydimethylsiloxane crosspolymer, and polydimethylsiloxane/vinyltrimethylsiloxysilicate crosspolymer combination.

The silsesquioxane based film former may be at least one selected from the group of polyphenylsilsesquioxane, polypropylsilsesquioxane, and polydimethylsiloxane/silsesquioxane copolymer combinations.

The silicate and silsesquioxane film formers may be more generally categorized as silicon based film formers, include silicon based MQ resins and may have various M/Q ratios. The products of the silicone-based resin include MQ1600 (trimethylsiloxysilicate) from Dow Corning, TMS-803 (trimethylsiloxysilicate) from Wacker-Belsil, KF-7312K (trimethylsiloxysilicate and polydimethylsiloxane), Silschine 151 (phenylpropyldisiloxysiliconate) from GE, MQ1640, and the like.

As a more preferred embodiment of the present invention, trimethylsiloxysilicate may be used as the silicate film former, and polypropylsilsesquioxane may be used as the silsesquioxane film former.

The two film formers of the present invention are characterized by being used together. This is because if only any one type of film forming agent is used, it may cause the color cosmetic composition to feel uncomfortable to use. For example, when only a silicate film-forming agent such as trimethylsiloxysilicate is used, the surface of the dosage form becomes hard like a manicure, and there is a problem that flexibility is lowered. Thus, a dosage form having suitable rigidity and flexibility is formed by using a silicate film former and a silsesquioxane film former together.

Meanwhile, the color cosmetic composition may further include a silicified polysaccharide compound as the film forming agent of the present invention, in addition to the two film forming agents. As the siliconized polysaccharide compound, one formed by reacting trimethylsiloxysilyl isocyanate with a polysaccharide compound may be preferably used. Examples of the polysaccharide compound may include cellulose, gum arabic, alginic acid, carrageenan, xanthan gum, pullulan, and the like.

The siliconized polysaccharide compound may further comprise trimethylsiloxysilylcarbamoyl pullulan formed by reaction using pullulan (pullulan) as the polysaccharide compound. The product of trimethylsiloxysilylcarbamoyl amylopectin may include TSPL 30-D5 (trimethylsiloxysilylcarbamoyl amylopectin and cyclopentasiloxane) and TSPL 30-ID (trimethylsiloxysilylcarbamoyl amylopectin and isododecane) from Shin Etsu.

The total content of the film forming agent that may be included in the composition of the present invention is preferably 10 to 40% by weight, based on the weight of the entire composition. If the content is less than 10% by weight, the degree of film formation is not significant, and thus the effect of preventing trans-tackiness and improving durability to be provided by the present invention is reduced, and if it exceeds 40% by weight, the dosage form becomes too hard and the feeling in use is reduced.

In addition, the weight ratio of the silsesquioxane film forming agent to the silicate film forming agent in the film forming agent is preferably 3: 1-3: 3, more preferably 3: 2. the range is not necessarily limited to the range, but may vary depending on the type of the color cosmetic product, the purpose thereof, and the effect to be provided.

Powder of

In the color cosmetic composition of the present invention, spherical powder and plate-like powder are used simultaneously.

The spherical powder may be an organic powder, and at least one selected from the group consisting of silica, Polymethylmethacrylate (PMMA), Polyurethane (PU), Polymethylsilsesquioxane (PMSQ), and nylon in combination may be preferably used.

The plate-like powder may be an inorganic powder, and at least one selected from the group consisting of talc, boron nitride, mica, and a combination of sericite may be preferably used, and mica is more preferably used.

If only spherical powder among the materials is used, powder scattering may occur at the time of use, and if only plate-shaped powder is used, the bulk metathesis property of the composition is reduced, resulting in deterioration of the spreadability. Therefore, when the spherical powder and the plate-like powder are used together, the preparation layer can be smoothly detached and gently applied, and can be closely adhered to the skin without scattering.

The total content of the spherical powder and the plate-shaped powder of the present invention is preferably 30 to 80% by weight based on the total weight of the composition. If the content thereof is less than 30% by weight, it is difficult to form a paste (paste) phase, and if the content thereof is more than 80% by weight, an excessively hard formulation may be formed.

Further, the weight ratio of the spherical powder to the plate-like powder is preferably 2: 1-2: 2, more preferably 6: 5. the weight ratio is not limited to the range, but may vary depending on the type of the color cosmetic product, the use, and the degree of effect to be provided.

As described above, the color cosmetic composition of the present invention comprising the film-forming agent and the powder is characterized in that no wax is used and generally contains a smaller amount of oil than the prior art. In this case, the oil content affects the gloss, and therefore, the oil content must be adjusted so that the composition contains an appropriate amount of oil in balance with the anti-sliming effect. The oil content in the prior art must be 70-80%, on the contrary, the oil content in the color cosmetic composition of the present invention is not limited to a particularly high level and can be freely selected. The oil content for improving the trans-viscosity is preferably not more than 40% by weight, which corresponds to half of the prior art, more preferably not more than 20% by weight.

In addition, the color cosmetic composition of the present invention may further comprise functional materials such as a humectant and a polymer.

< preparation method >

In addition, the present invention provides a method for preparing a color cosmetic composition, the method comprising:

At this time, preferably, the step a) may include:

a-1) a step of mixing spherical powder and plate-like powder; and

The color cosmetic composition finally forms composition particles according to the preparation method, namely, the film-forming agent and the hydrocarbon oil sequentially form a coating on the powder. This structure is more effective in the sense of use and the prevention of the transfer of tackiness. For example, after the color cosmetic composition is applied to lips and the like, it does not feel tight, and the applied preparation does not turn sticky after drying.

Meanwhile, the mixture of the film forming agent and the powder prepared in step (a) of the present invention forms a diluted paste formulation, and in order to control the degree of dilution of the formulation and additionally add various functions, other oils, humectants and functional polymers may be further added when the hydrocarbon oil is added in said step (b).

The preparation method of the color cosmetic composition is characterized by being carried out at the room temperature of 15-30 ℃, and the total process time is about 10-20 minutes.

In order to produce a conventional color cosmetic composition containing wax, it is necessary to melt the wax having a melting point of 90 ℃ or more under high temperature conditions, the process of melting the wax requires 3 to 4 times of repeated processes, and the heating dissolution process generally requires a process time of about 1 hour or more. On the contrary, the present invention can reduce the troublesome processes in the process, improve convenience and workability, and reduce costs, thereby improving the overall production efficiency.

The following describes evaluation examples and experimental examples 1 to 4 relating to the effects of the present invention. In the experiment, a color cosmetic composition having the components of example 1, comparative example 1, and comparative example 2 below was used. However, the following experimental examples are only experimental examples relating to the configuration and effects of the present invention, and the scope and effects of the present invention are not limited thereto.

< example 1 and comparative example 1>

TABLE 1

The color cosmetic compositions of example 1 and comparative example 1 were prepared according to the contents and combinations of the ingredients shown in table 1 above. Example 1 is a makeup composition of the present invention, and comparative example 1 is a makeup composition containing no film-forming agent as compared with the makeup composition of the present invention.

< comparative example 2>

TABLE 2

The color cosmetic composition of comparative example 2 was prepared according to the contents and combinations of the ingredients shown in table 2 above. The color cosmetic composition of comparative example 2 is a conventional color cosmetic composition using wax.

< preparation example >

1) The powder raw materials and pigments were mixed and added to the mixer, and then mixed for 1 minute.

2) Adding the film forming agent and the silicon into the mixed raw materials in the step 1) and mixing for 1 minute.

3) The mixture of step 2) was transferred to a kneader and hydrocarbon oil, humectant and polymer were added, followed by mixing for 15 minutes in 2 stages.

< evaluation example >

In this evaluation example, the transfer tack, the durability and the spreadability of the example 1, the comparative example 1 and the comparative example 2 were evaluated. The evaluation was performed by sensory evaluation of 30 member groups, and was evaluated to be 1 to 5 points (1: very poor to 5 points: very good) in terms of the degree of excellence of each item. The total score for each item is shown as the average.

The results are shown in table 3 below.

TABLE 3

Item	Example 1	Comparative example 1	Comparative example 2
				Non-rotating adhesive	4.3	2.0	1.0
Durability	4.1	2.7	2.3
				Spreadability	3.9	3.6	4.0

Referring to table 3 above, it can be seen that example 1 has no transfer tack, improved durability, and maintained spreadability at an equivalent level, as compared to the conventional composition of comparative example 2. In addition, it was confirmed that the composition of example 1 did not trans-stick and the durability was improved when the composition of example 1 was compared with the composition of comparative example 1, which did not include a film-forming agent.

In the following experimental examples, several experimental examples relating to the sensory evaluation results are specifically shown.

< Experimental example 1> -transviscous experiment 1

The difference in the trans-adhesive properties was confirmed by comparing example 1 and comparative example 2.

As an experimental method, each of the compositions of example 1 and comparative example 2 was applied to artificial leather by rolling three times, then covered with a paper towel, pressed with a paperweight for 1 minute, and then compared in the degree of transfer-sticking to the paper towel. The results of experimental example 1 are shown in FIG. 1.

Referring to fig. 1, it can be confirmed that the applied composition was significantly sticky to the paper towel in the case of comparative example 2 (lower) of the conventional formulation containing wax, and not sticky in contrast to this in the case of example 1 (upper).

< Experimental example 2> -Trans-viscous experiment 2

The difference in the trans-adhesive properties between example 1 and comparative example 2 was confirmed by a method different from that of experimental example 1.

As an experimental method, the compositions of example 1 and comparative example 2 were applied to lips, respectively, and the degree of transfer of each composition to a paper cup was compared when water in the paper cup was drunk after 30 minutes. The results of experimental example 2 are shown in fig. 2.

Referring to fig. 2, it was confirmed that in the case of example 1 (left), transfer adhesion did not occur, and in the case of comparative example 2 (right), transfer adhesion of the composition applied to the lips was apparently occurred.

< Experimental example 3> -durability test

To investigate the extent to which the presence or absence of a film-forming agent affects the durability of the composition, a durability test was performed using the compositions of example 1 and comparative example 1.

As an experimental method, the compositions of example 1 and comparative example 1 were respectively applied to artificial leather, and then the whole artificial leather was immersed in a solution prepared with caprylic/capric triglyceride (caprylic/capric triglyceride) and water at a ratio of 1:4 (assuming similar skin conditions) and shaken (shaking) for 20 minutes. The results are shown in FIG. 3.

Referring to fig. 3, it was confirmed that in the case of example 1 (left), the composition remained in the initial applied state and was hardly erased, but in the case of comparative example 1 (right), there were many portions which fell off and become white.

In addition, in order to confirm whether or not the color cosmetic composition according to the present invention has a suitable degree of dryness for use as compared with the conventional color cosmetic composition containing wax, the following experiment was performed using the compositions of example 1 and comparative example 2. This experiment is shown in experimental example 4 below.

< Experimental example 4> -drying experiment

Measuring the degree of water evaporation from the surface of the skin

In order to measure the degree of water evaporation from the skin surface, the average value measured after skin contact by 10 subjects was confirmed. The results are shown in Table 4 below.

TABLE 4

	Example 1	Comparative example 2
			Immediately after application	40	43
After 2 hours of smearing	30	33
			After 5 hours of smearing	24	27

Referring to table 4, it can be confirmed that example 1 of the color cosmetic composition according to the present invention has no particular difference in practical use and has a similar degree of dryness as compared to comparative example 2, which is a conventional color cosmetic composition containing wax. Thus, it can be seen that the color cosmetic composition according to the present invention does not cause particular drawing or drying compared to the conventional formulation.

Sensory evaluation of dryness

The sensory evaluation was conducted by an evaluation group consisting of 10 members, and each item was evaluated to be 1 to 5 points (1: hardly felt-5: very serious) in terms of degree of excellence. As a result, the average value of example 1 was 2.4, and the average value of comparative example 2 was 2.1, and thus both were evaluated to have similar dryness without significant difference in actual use.

From the results of the evaluation examples and examples 1 to 4, it was confirmed that the color cosmetic composition according to the present invention was a wax-free preparation, and also was a color cosmetic composition that improved transfer tack, had excellent durability, and had no decrease in spreadability and moisturizing feel compared to conventional compositions.

Claims

1. A color cosmetic composition comprising a silicate film former, a silsesquioxane film former, a siliconized polysaccharide compound, a plate-like powder and a spherical powder,

the siliconized polysaccharide compound is trimethylsiloxysilylaminocarbonyl amylopectin,

the plate-like powder is at least one selected from the group consisting of talc, boron nitride, mica and sericite,

the total content of film formers including the silicate film formers, the silsesquioxane film formers, and the siliconized polysaccharide compounds is 10 to 40 weight percent based on the total weight of the composition,

the color cosmetic composition is a wax-free preparation.

2. The color cosmetic composition according to claim 1, wherein the silicate film former is at least one selected from the group consisting of trimethylsiloxysilicate, phenylpropyldimethylsiloxysilicate, trimethylsiloxysilicate/polydimethylsiloxane crosspolymer, and polydimethylsiloxane/vinyltrimethylsiloxysilicate crosspolymer.

3. The color cosmetic composition according to claim 1, wherein the silsesquioxane-based film former is at least one selected from the group consisting of polyphenylsilsesquioxane, polypropylsiilsesquioxane, and polydimethylsiloxane/silsesquioxane copolymer combination.

4. The color cosmetic composition according to claim 1, wherein the silicate film former is trimethylsiloxysilicate and the silsesquioxane film former is polypropylsilsesquioxane.

5. The color cosmetic composition according to claim 1, wherein the spherical powder is at least one selected from the group consisting of silica, polymethyl methacrylate, polyurethane, polymethylsilsesquioxane and nylon.

6. The color cosmetic composition according to claim 1, wherein the weight ratio of the silicate film former to the silsesquioxane film former is 3:1 to 3: 3.

7. The color cosmetic composition according to claim 1, wherein the weight ratio of the spherical powder to the plate-like powder is 2:1 to 2: 2.

8. The color cosmetic composition according to claim 1, wherein the total content of the spherical powder and the plate-like powder is 30 to 95% by weight based on the total weight of the composition.

9. The make-up composition according to claim 1, wherein the oil content of the make-up composition is not more than 40% by weight, based on the total weight of the composition.

10. A method of preparing the color cosmetic composition of claim 1, the method comprising:

a) mixing a silicate film former, a silsesquioxane film former, a silicified polysaccharide compound, plate-shaped powder and spherical powder; and

b) a step of adding hydrocarbon oil to the mixture to form a composition in the form of a paste,

characterized in that the plate-like powder is at least one selected from the group consisting of talc, boron nitride, mica and sericite,

the color cosmetic composition is a wax-free preparation.

11. The method for preparing the color cosmetic composition according to claim 10, wherein the step a) comprises,

a-1) a step of mixing spherical powder and plate-like powder; and

a-2) a step of mixing a silicate film former, a silsesquioxane film former and a siliconized polysaccharide compound with the mixture of spherical powder and plate-shaped powder.

12. The method for preparing the color cosmetic composition according to claim 10, wherein a humectant and a functional polymer are further added in the step b).

13. The method for preparing the makeup composition according to any one of claims 10 to 12, wherein the makeup composition is prepared at 15 to 30 ℃.