CN108135297A - Clothes with antistatic property - Google Patents
Clothes with antistatic property Download PDFInfo
- Publication number
- CN108135297A CN108135297A CN201680060008.4A CN201680060008A CN108135297A CN 108135297 A CN108135297 A CN 108135297A CN 201680060008 A CN201680060008 A CN 201680060008A CN 108135297 A CN108135297 A CN 108135297A
- Authority
- CN
- China
- Prior art keywords
- clothes
- mass
- suture
- conducting fibre
- fibre
- Prior art date
- Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
- Pending
Links
- 239000000835 fiber Substances 0.000 claims abstract description 119
- 239000004744 fabric Substances 0.000 claims abstract description 21
- 229920002972 Acrylic fiber Polymers 0.000 claims description 24
- GWEVSGVZZGPLCZ-UHFFFAOYSA-N Titan oxide Chemical compound O=[Ti]=O GWEVSGVZZGPLCZ-UHFFFAOYSA-N 0.000 claims description 20
- 239000004408 titanium dioxide Substances 0.000 claims description 10
- 239000004020 conductor Substances 0.000 claims description 8
- 239000006229 carbon black Substances 0.000 claims description 5
- 238000005406 washing Methods 0.000 abstract description 5
- 238000009987 spinning Methods 0.000 description 40
- 238000000034 method Methods 0.000 description 15
- 239000004615 ingredient Substances 0.000 description 12
- 239000011859 microparticle Substances 0.000 description 11
- 238000009958 sewing Methods 0.000 description 11
- 239000008358 core component Substances 0.000 description 10
- NLHHRLWOUZZQLW-UHFFFAOYSA-N Acrylonitrile Chemical compound C=CC#N NLHHRLWOUZZQLW-UHFFFAOYSA-N 0.000 description 8
- 238000004519 manufacturing process Methods 0.000 description 8
- 239000003960 organic solvent Substances 0.000 description 8
- 229920000742 Cotton Polymers 0.000 description 7
- 238000004043 dyeing Methods 0.000 description 7
- 238000011156 evaluation Methods 0.000 description 7
- 239000000203 mixture Substances 0.000 description 7
- 230000008569 process Effects 0.000 description 7
- 239000000306 component Substances 0.000 description 6
- 229920000058 polyacrylate Polymers 0.000 description 6
- 230000009467 reduction Effects 0.000 description 6
- IAZDPXIOMUYVGZ-UHFFFAOYSA-N Dimethylsulphoxide Chemical compound CS(C)=O IAZDPXIOMUYVGZ-UHFFFAOYSA-N 0.000 description 5
- 230000008602 contraction Effects 0.000 description 5
- 230000000694 effects Effects 0.000 description 5
- 239000007787 solid Substances 0.000 description 5
- XLOMVQKBTHCTTD-UHFFFAOYSA-N Zinc monoxide Chemical compound [Zn]=O XLOMVQKBTHCTTD-UHFFFAOYSA-N 0.000 description 4
- NIXOWILDQLNWCW-UHFFFAOYSA-N acrylic acid group Chemical group C(C=C)(=O)O NIXOWILDQLNWCW-UHFFFAOYSA-N 0.000 description 4
- 239000000178 monomer Substances 0.000 description 4
- 230000003068 static effect Effects 0.000 description 4
- 239000000126 substance Substances 0.000 description 4
- XOLBLPGZBRYERU-UHFFFAOYSA-N tin dioxide Chemical compound O=[Sn]=O XOLBLPGZBRYERU-UHFFFAOYSA-N 0.000 description 4
- 229910001887 tin oxide Inorganic materials 0.000 description 4
- -1 Alkene nitrile Chemical class 0.000 description 3
- PNEYBMLMFCGWSK-UHFFFAOYSA-N Alumina Chemical compound [O-2].[O-2].[O-2].[Al+3].[Al+3] PNEYBMLMFCGWSK-UHFFFAOYSA-N 0.000 description 3
- ZMXDDKWLCZADIW-UHFFFAOYSA-N N,N-Dimethylformamide Chemical compound CN(C)C=O ZMXDDKWLCZADIW-UHFFFAOYSA-N 0.000 description 3
- 230000008859 change Effects 0.000 description 3
- 239000000463 material Substances 0.000 description 3
- 229910052751 metal Inorganic materials 0.000 description 3
- 239000002184 metal Substances 0.000 description 3
- 230000000704 physical effect Effects 0.000 description 3
- 229920000728 polyester Polymers 0.000 description 3
- 238000009877 rendering Methods 0.000 description 3
- XLYOFNOQVPJJNP-UHFFFAOYSA-N water Substances O XLYOFNOQVPJJNP-UHFFFAOYSA-N 0.000 description 3
- 238000002166 wet spinning Methods 0.000 description 3
- SMZOUWXMTYCWNB-UHFFFAOYSA-N 2-(2-methoxy-5-methylphenyl)ethanamine Chemical compound COC1=CC=C(C)C=C1CCN SMZOUWXMTYCWNB-UHFFFAOYSA-N 0.000 description 2
- 238000003556 assay Methods 0.000 description 2
- 239000011248 coating agent Substances 0.000 description 2
- 238000000576 coating method Methods 0.000 description 2
- 238000005520 cutting process Methods 0.000 description 2
- 235000013399 edible fruits Nutrition 0.000 description 2
- 229910003437 indium oxide Inorganic materials 0.000 description 2
- PJXISJQVUVHSOJ-UHFFFAOYSA-N indium(iii) oxide Chemical compound [O-2].[O-2].[O-2].[In+3].[In+3] PJXISJQVUVHSOJ-UHFFFAOYSA-N 0.000 description 2
- 238000002156 mixing Methods 0.000 description 2
- 229920002994 synthetic fiber Polymers 0.000 description 2
- 239000012209 synthetic fiber Substances 0.000 description 2
- 210000002268 wool Anatomy 0.000 description 2
- 239000011787 zinc oxide Substances 0.000 description 2
- OEPOKWHJYJXUGD-UHFFFAOYSA-N 2-(3-phenylmethoxyphenyl)-1,3-thiazole-4-carbaldehyde Chemical compound O=CC1=CSC(C=2C=C(OCC=3C=CC=CC=3)C=CC=2)=N1 OEPOKWHJYJXUGD-UHFFFAOYSA-N 0.000 description 1
- NIXOWILDQLNWCW-UHFFFAOYSA-M Acrylate Chemical compound [O-]C(=O)C=C NIXOWILDQLNWCW-UHFFFAOYSA-M 0.000 description 1
- OKTJSMMVPCPJKN-UHFFFAOYSA-N Carbon Chemical compound [C] OKTJSMMVPCPJKN-UHFFFAOYSA-N 0.000 description 1
- ZAMOUSCENKQFHK-UHFFFAOYSA-N Chlorine atom Chemical compound [Cl] ZAMOUSCENKQFHK-UHFFFAOYSA-N 0.000 description 1
- VGGSQFUCUMXWEO-UHFFFAOYSA-N Ethene Chemical compound C=C VGGSQFUCUMXWEO-UHFFFAOYSA-N 0.000 description 1
- 239000005977 Ethylene Substances 0.000 description 1
- 229920000914 Metallic fiber Polymers 0.000 description 1
- CERQOIWHTDAKMF-UHFFFAOYSA-N Methacrylic acid Chemical compound CC(=C)C(O)=O CERQOIWHTDAKMF-UHFFFAOYSA-N 0.000 description 1
- BQCADISMDOOEFD-UHFFFAOYSA-N Silver Chemical compound [Ag] BQCADISMDOOEFD-UHFFFAOYSA-N 0.000 description 1
- XTXRWKRVRITETP-UHFFFAOYSA-N Vinyl acetate Chemical compound CC(=O)OC=C XTXRWKRVRITETP-UHFFFAOYSA-N 0.000 description 1
- 230000009471 action Effects 0.000 description 1
- 238000004378 air conditioning Methods 0.000 description 1
- 229910000410 antimony oxide Inorganic materials 0.000 description 1
- 229910052799 carbon Inorganic materials 0.000 description 1
- 238000009960 carding Methods 0.000 description 1
- 239000003795 chemical substances by application Substances 0.000 description 1
- 239000000460 chlorine Substances 0.000 description 1
- 229910052801 chlorine Inorganic materials 0.000 description 1
- 239000003086 colorant Substances 0.000 description 1
- 230000000052 comparative effect Effects 0.000 description 1
- 239000002131 composite material Substances 0.000 description 1
- 238000007334 copolymerization reaction Methods 0.000 description 1
- 238000000280 densification Methods 0.000 description 1
- 238000001035 drying Methods 0.000 description 1
- 230000008030 elimination Effects 0.000 description 1
- 238000003379 elimination reaction Methods 0.000 description 1
- 238000005516 engineering process Methods 0.000 description 1
- 150000002148 esters Chemical class 0.000 description 1
- 238000011049 filling Methods 0.000 description 1
- 230000009187 flying Effects 0.000 description 1
- 230000006870 function Effects 0.000 description 1
- YBMRDBCBODYGJE-UHFFFAOYSA-N germanium oxide Inorganic materials O=[Ge]=O YBMRDBCBODYGJE-UHFFFAOYSA-N 0.000 description 1
- 150000002500 ions Chemical class 0.000 description 1
- WFKAJVHLWXSISD-UHFFFAOYSA-N isobutyramide Chemical compound CC(C)C(N)=O WFKAJVHLWXSISD-UHFFFAOYSA-N 0.000 description 1
- 239000007788 liquid Substances 0.000 description 1
- 229910044991 metal oxide Inorganic materials 0.000 description 1
- 150000004706 metal oxides Chemical class 0.000 description 1
- 230000000116 mitigating effect Effects 0.000 description 1
- 230000003287 optical effect Effects 0.000 description 1
- 230000003647 oxidation Effects 0.000 description 1
- 238000007254 oxidation reaction Methods 0.000 description 1
- VTRUBDSFZJNXHI-UHFFFAOYSA-N oxoantimony Chemical compound [Sb]=O VTRUBDSFZJNXHI-UHFFFAOYSA-N 0.000 description 1
- PVADDRMAFCOOPC-UHFFFAOYSA-N oxogermanium Chemical compound [Ge]=O PVADDRMAFCOOPC-UHFFFAOYSA-N 0.000 description 1
- 239000002245 particle Substances 0.000 description 1
- 229920000642 polymer Polymers 0.000 description 1
- CHWRSCGUEQEHOH-UHFFFAOYSA-N potassium oxide Chemical compound [O-2].[K+].[K+] CHWRSCGUEQEHOH-UHFFFAOYSA-N 0.000 description 1
- 229910001950 potassium oxide Inorganic materials 0.000 description 1
- 238000004321 preservation Methods 0.000 description 1
- 238000003672 processing method Methods 0.000 description 1
- 229910052709 silver Inorganic materials 0.000 description 1
- 239000004332 silver Substances 0.000 description 1
- 238000007711 solidification Methods 0.000 description 1
- 230000008023 solidification Effects 0.000 description 1
- 239000004753 textile Substances 0.000 description 1
- 229920001169 thermoplastic Polymers 0.000 description 1
- 239000004416 thermosoftening plastic Substances 0.000 description 1
- 238000009941 weaving Methods 0.000 description 1
- YVTHLONGBIQYBO-UHFFFAOYSA-N zinc indium(3+) oxygen(2-) Chemical compound [O--].[Zn++].[In+3] YVTHLONGBIQYBO-UHFFFAOYSA-N 0.000 description 1
Classifications
-
- A—HUMAN NECESSITIES
- A41—WEARING APPAREL
- A41D—OUTERWEAR; PROTECTIVE GARMENTS; ACCESSORIES
- A41D13/00—Professional, industrial or sporting protective garments, e.g. surgeons' gowns or garments protecting against blows or punches
- A41D13/008—Professional, industrial or sporting protective garments, e.g. surgeons' gowns or garments protecting against blows or punches protecting against electric shocks or static electricity
-
- D—TEXTILES; PAPER
- D01—NATURAL OR MAN-MADE THREADS OR FIBRES; SPINNING
- D01D—MECHANICAL METHODS OR APPARATUS IN THE MANUFACTURE OF ARTIFICIAL FILAMENTS, THREADS, FIBRES, BRISTLES OR RIBBONS
- D01D5/00—Formation of filaments, threads, or the like
- D01D5/0007—Electro-spinning
- D01D5/0015—Electro-spinning characterised by the initial state of the material
- D01D5/003—Electro-spinning characterised by the initial state of the material the material being a polymer solution or dispersion
- D01D5/0046—Electro-spinning characterised by the initial state of the material the material being a polymer solution or dispersion the fibre formed by coagulation, i.e. wet electro-spinning
-
- D—TEXTILES; PAPER
- D01—NATURAL OR MAN-MADE THREADS OR FIBRES; SPINNING
- D01F—CHEMICAL FEATURES IN THE MANUFACTURE OF ARTIFICIAL FILAMENTS, THREADS, FIBRES, BRISTLES OR RIBBONS; APPARATUS SPECIALLY ADAPTED FOR THE MANUFACTURE OF CARBON FILAMENTS
- D01F1/00—General methods for the manufacture of artificial filaments or the like
- D01F1/02—Addition of substances to the spinning solution or to the melt
- D01F1/09—Addition of substances to the spinning solution or to the melt for making electroconductive or anti-static filaments
-
- D—TEXTILES; PAPER
- D01—NATURAL OR MAN-MADE THREADS OR FIBRES; SPINNING
- D01F—CHEMICAL FEATURES IN THE MANUFACTURE OF ARTIFICIAL FILAMENTS, THREADS, FIBRES, BRISTLES OR RIBBONS; APPARATUS SPECIALLY ADAPTED FOR THE MANUFACTURE OF CARBON FILAMENTS
- D01F8/00—Conjugated, i.e. bi- or multicomponent, artificial filaments or the like; Manufacture thereof
- D01F8/04—Conjugated, i.e. bi- or multicomponent, artificial filaments or the like; Manufacture thereof from synthetic polymers
- D01F8/08—Conjugated, i.e. bi- or multicomponent, artificial filaments or the like; Manufacture thereof from synthetic polymers with at least one polyacrylonitrile as constituent
-
- D—TEXTILES; PAPER
- D01—NATURAL OR MAN-MADE THREADS OR FIBRES; SPINNING
- D01F—CHEMICAL FEATURES IN THE MANUFACTURE OF ARTIFICIAL FILAMENTS, THREADS, FIBRES, BRISTLES OR RIBBONS; APPARATUS SPECIALLY ADAPTED FOR THE MANUFACTURE OF CARBON FILAMENTS
- D01F9/00—Artificial filaments or the like of other substances; Manufacture thereof; Apparatus specially adapted for the manufacture of carbon filaments
- D01F9/08—Artificial filaments or the like of other substances; Manufacture thereof; Apparatus specially adapted for the manufacture of carbon filaments of inorganic material
-
- D—TEXTILES; PAPER
- D02—YARNS; MECHANICAL FINISHING OF YARNS OR ROPES; WARPING OR BEAMING
- D02G—CRIMPING OR CURLING FIBRES, FILAMENTS, THREADS, OR YARNS; YARNS OR THREADS
- D02G3/00—Yarns or threads, e.g. fancy yarns; Processes or apparatus for the production thereof, not otherwise provided for
- D02G3/02—Yarns or threads characterised by the material or by the materials from which they are made
- D02G3/04—Blended or other yarns or threads containing components made from different materials
-
- D—TEXTILES; PAPER
- D02—YARNS; MECHANICAL FINISHING OF YARNS OR ROPES; WARPING OR BEAMING
- D02G—CRIMPING OR CURLING FIBRES, FILAMENTS, THREADS, OR YARNS; YARNS OR THREADS
- D02G3/00—Yarns or threads, e.g. fancy yarns; Processes or apparatus for the production thereof, not otherwise provided for
- D02G3/22—Yarns or threads characterised by constructional features, e.g. blending, filament/fibre
- D02G3/36—Cored or coated yarns or threads
-
- D—TEXTILES; PAPER
- D02—YARNS; MECHANICAL FINISHING OF YARNS OR ROPES; WARPING OR BEAMING
- D02G—CRIMPING OR CURLING FIBRES, FILAMENTS, THREADS, OR YARNS; YARNS OR THREADS
- D02G3/00—Yarns or threads, e.g. fancy yarns; Processes or apparatus for the production thereof, not otherwise provided for
- D02G3/44—Yarns or threads characterised by the purpose for which they are designed
- D02G3/441—Yarns or threads with antistatic, conductive or radiation-shielding properties
-
- D—TEXTILES; PAPER
- D02—YARNS; MECHANICAL FINISHING OF YARNS OR ROPES; WARPING OR BEAMING
- D02G—CRIMPING OR CURLING FIBRES, FILAMENTS, THREADS, OR YARNS; YARNS OR THREADS
- D02G3/00—Yarns or threads, e.g. fancy yarns; Processes or apparatus for the production thereof, not otherwise provided for
- D02G3/44—Yarns or threads characterised by the purpose for which they are designed
- D02G3/46—Sewing-cottons or the like
-
- A—HUMAN NECESSITIES
- A41—WEARING APPAREL
- A41D—OUTERWEAR; PROTECTIVE GARMENTS; ACCESSORIES
- A41D31/00—Materials specially adapted for outerwear
- A41D31/04—Materials specially adapted for outerwear characterised by special function or use
- A41D31/26—Electrically protective, e.g. preventing static electricity or electric shock
-
- D—TEXTILES; PAPER
- D06—TREATMENT OF TEXTILES OR THE LIKE; LAUNDERING; FLEXIBLE MATERIALS NOT OTHERWISE PROVIDED FOR
- D06M—TREATMENT, NOT PROVIDED FOR ELSEWHERE IN CLASS D06, OF FIBRES, THREADS, YARNS, FABRICS, FEATHERS OR FIBROUS GOODS MADE FROM SUCH MATERIALS
- D06M2101/00—Chemical constitution of the fibres, threads, yarns, fabrics or fibrous goods made from such materials, to be treated
- D06M2101/16—Synthetic fibres, other than mineral fibres
- D06M2101/18—Synthetic fibres consisting of macromolecular compounds obtained by reactions only involving carbon-to-carbon unsaturated bonds
- D06M2101/26—Polymers or copolymers of unsaturated carboxylic acids or derivatives thereof
- D06M2101/28—Acrylonitrile; Methacrylonitrile
-
- D—TEXTILES; PAPER
- D10—INDEXING SCHEME ASSOCIATED WITH SUBLASSES OF SECTION D, RELATING TO TEXTILES
- D10B—INDEXING SCHEME ASSOCIATED WITH SUBLASSES OF SECTION D, RELATING TO TEXTILES
- D10B2321/00—Fibres made from polymers obtained by reactions only involving carbon-to-carbon unsaturated bonds
- D10B2321/10—Fibres made from polymers obtained by reactions only involving carbon-to-carbon unsaturated bonds polymers of unsaturated nitriles, e.g. polyacrylonitrile, polyvinylidene cyanide
-
- D—TEXTILES; PAPER
- D10—INDEXING SCHEME ASSOCIATED WITH SUBLASSES OF SECTION D, RELATING TO TEXTILES
- D10B—INDEXING SCHEME ASSOCIATED WITH SUBLASSES OF SECTION D, RELATING TO TEXTILES
- D10B2401/00—Physical properties
- D10B2401/16—Physical properties antistatic; conductive
Landscapes
- Engineering & Computer Science (AREA)
- Textile Engineering (AREA)
- Mechanical Engineering (AREA)
- Chemical & Material Sciences (AREA)
- Chemical Kinetics & Catalysis (AREA)
- General Chemical & Material Sciences (AREA)
- General Health & Medical Sciences (AREA)
- Physical Education & Sports Medicine (AREA)
- Health & Medical Sciences (AREA)
- Manufacturing & Machinery (AREA)
- Dispersion Chemistry (AREA)
- Yarns And Mechanical Finishing Of Yarns Or Ropes (AREA)
- Professional, Industrial, Or Sporting Protective Garments (AREA)
- Details Of Garments (AREA)
- Multicomponent Fibers (AREA)
Abstract
A kind of clothes is provided, when knitted fabric is made not at the position as the portion of wearing using conducting fibre, and antistatic processing is not carried out to knitted fabric, and contains conducting fibre by making suture, thus with antistatic property and with washing resistance.The clothes is the clothes of suture (suture, linking thread) comprising conducting fibre, is to be charged by friction the quantity of electric charge as the clothes below 0.8 μ C/ parts.Resistance value between the 1cm of the fiber axial direction of the preferably above-mentioned conducting fibre of the clothes is 1 × 104Ω~5 × 108Ω, also, above-mentioned suture includes the above-mentioned conducting fibre of the mass % of 30 mass %~100.
Description
Technical field
The suture (suture) used when clothing product sews in the present invention is with antistatic property and can
The line for having used synthetic fibers of dyeing, the present invention relates to the clothes with antistatic property for having used the line.
Background technology
In recent years, air-conditioning equipment is complete, maintains comfortable temperature in operating room, but humidity set it is relatively low.Also, the winter
Season is the state that indoor and outdoor is low humidity.
The heat preservation dress material of use in winter easily makes to accumulate electrostatic in clothes due to the activity of wearer, static discharge when undressing
It can make one not feeling well.All the time, it is known that inhibit electrostatic, but due to repeatedly by carrying out antistatic processing to clothing product
Washing can continuously decrease anti-static function.In addition, also having makes the method that braided fabric contains the fiber with antistatic property, but
Fiber with antistatic property is the colored fibre for including carbon, titanium dioxide, metallics, even if dyeing can not also be had
There is the knitted fabric of bright colors, it is therefore desirable to the needle developed the grade for not reducing clothing product and persistently there is antistatic property
Fabric.
A kind of sewing thread is recorded in patent document 1, which is that the composite filament of at least 1 or more is further and twists with the fingers
It forms, which has the cored structure formed in a manner that sheath portion is conducting fibre, core is thermoplastic fibre, but
Due to coating sheath portion, thus homochromatism shortcoming during dyeing using conducting fibre.
The description below has been recorded in patent document 2：By the fabric comprising conducting fibre each other with including conducting fibre
Linear slit altogether, antistatic dress material is thus obtained, from the antistatic property of the previous just known knitted fabric comprising conducting fibre
Energy.
Existing technical literature
Patent document
Patent document 1：Japanese Unexamined Patent Publication 2010-255157 bulletins
Patent document 2：Japanese Unexamined Patent Publication 2015-30934 bulletins
Invention content
Problems to be solved by the invention
The purpose of the present invention is to provide a kind of clothes, when knitted fabric is made not micro as the position in the portion of wearing
Contain or using conducting fibre, and antistatic processing do not carried out to knitted fabric, and contain conducting fibre by making suture,
Thus with antistatic property and with washing resistance.
Means for solving the problems
The main points of the present invention are as described below.
The clothes that the clothes of the present invention is formed for each braided fabric portion using the suture sewing comprising conducting fibre, above-mentioned seam
The content of conducting fibre in line is the mass % of 30 mass %~100, and the content of the conducting fibre in each braided fabric portion is 1 matter
Amount % is hereinafter, the clothes is charged by friction the quantity of electric charge as below 0.8 μ C/ parts.
Resistance value between the 1cm of the fiber axial direction of the preferably above-mentioned conducting fibre of clothes of the present invention is 1 × 104Ω~5
×108Ω。
The clothes of the present invention is the mass % of 2 mass %~8 preferably with respect to the content of the above-mentioned suture of the gross mass of clothes.
The clothes of the present invention is 2 mass %~8 preferably with respect to the content of the above-mentioned conducting fibre of the gross mass of clothes
Quality %.
The preferably above-mentioned suture of clothes of the present invention is shoulder, sleeve portion, neck portion, oxter portion, arm hole, the bottom using position
It is more than at least one of portion, cuff.
The preferably above-mentioned suture of clothes of the present invention is spun yarn.
The filament denier of the preferably above-mentioned conducting fibre of clothes of the present invention is 1dtex~15dtex.
The a length of 30mm of the fiber of the single fiber of conducting fibre included in the preferably above-mentioned spun yarn of clothes of the present invention~
200mm。
The thickness of the preferred single thread of above-mentioned spun yarn in the clothes of the present invention is calculated as 20~110 with metric count, list
The filoplume number of more than 1mm in yarn is 130/more than m, and above-mentioned spun yarn is doublet cord or compenzine.
The filoplume number of above-mentioned spun yarn more than 3mm preferably in single thread in the clothes of the present invention is 10/more than m, 5mm
Above filoplume number is 1/more than m.
The present invention the preferably above-mentioned conducting fibre of clothes for comprising 5 mass %~9 mass % carbon black or 10 mass %
The fiber of the electric conductivity titanium dioxide of~25 mass %.
The preferably above-mentioned conducting fibre of clothes of the present invention contains the core-sheath-type acrylic fibre of conductive materials for core.
The clothes of the present invention is preferably sweater or fleece clothing.
The suture of the present invention includes the above-mentioned conducting fibre of the mass % of 30 mass %~100.
The effect of invention
Even if the conducting fibre included in braided fabric portion is few, clothing is being worn off comprising conducting fibre by making in suture
Electrostatic will not be accumulated when taking, can using commercial system provide undress when be charged by friction the quantity of electric charge as below 0.8 μ C/ parts, subtract
Uncomfortable clothes caused by electrostatic is lacked.
Specific embodiment
The clothes that the clothes of the present invention is formed for each braided fabric portion using the suture sewing comprising conducting fibre, above-mentioned seam
The conducting fibre of the mass % of 30 mass %~100 is included in line, the content of the conducting fibre in each braided fabric portion is 1 mass %
Hereinafter, clothes is charged by friction the quantity of electric charge as below 0.8 μ C/ parts.
In general, clothes for mainly by predecessor, rear body, tuck inside the sleeve and receive the composition that suture is connected together.
In the application, braided fabric portion refers to form the part of clothes, for example, predecessor, rear body, sleeve, neck.
In addition, suture is also sometimes referred to as suture, sewing sometimes referred to as sutures, and includes these arts in the application respectively
Language.
About the position being sewn, the part that predecessor and rear body are sewn is known as " oxter portion " and " shoulder ", by before and after
Body is known as " arm hole " with the part that sleeve is sewn, and the part that front and rear body and neck are sewn is known as " neck portion ", and sleeve is sewn
It is known as " sleeve portion " into the part of tubular, the part that the front end of sleeve is folded back and is sewed on is known as " cuff ", will be under front and rear body
End is known as " lower hem ".
If above-mentioned conducting fibre relative to the content of suture for more than 30 mass %, can be fully carried out when wearing from leading
The corona discharge of conductive fiber, electrostatic are difficult to accumulate in clothes, can reduce discomfort caused by electric discharge when undressing.From this respect
Set out, above-mentioned conducting fibre is preferably more than 50 mass % relative to the content of suture, further preferably 80 mass % with
On, most preferably 100 mass %.Core sheath conducting fibre carries out static elimination by corona discharge, thus fibre section increases
Performance is improved effectively, thus its raising of blending ratio in spun yarn produces effect influence.
If in addition, conducting fibre relative to each braided fabric portion content be 1 mass % hereinafter, will not generate electric conductivity fibre
The influence to the color of clothes is tieed up, thus preferably.The content of the conducting fibre in more preferable each braided fabric portion is 0 mass %, more
It is preferred that not comprising conducting fibre.
If the quantity of electric charge that is charged by friction in clothes causes for 0.8 μ C/ parts hereinafter, can reduce electrostatic when sloughing in clothes
Discomfort.
From the above considerations, the above-mentioned quantity of electric charge that is charged by friction is more preferably 0.7 μ C/ parts hereinafter, further preferably 0.6
Below μ C/ parts.
It is charged by friction the quantity of electric charge to be the base for being antistatic work clothes specified in JIS T8118 (2001) below 0.6 μ C/ parts
It is accurate.
The conducting fibre used in suture is not particularly limited, as long as clothes is charged by friction the quantity of electric charge as 0.8 μ C/
Below part.
As the example of conducting fibre, can enumerate makes the chemical fibre containing conductive materials in fiber, surface coating
There is fiber, metallic fiber of conductive materials etc..
Wherein, preferably dyeability, durability are good makes the chemical fibre containing conductive materials in fiber, more preferably can
The conducting fibre that acrylic fibre is made to contain conductive materials dyed with the good dye of positive ion of colour rendering.
The resistance value of the preferred contained conducting fibre of above-mentioned suture in the clothes of the present invention is 1 × 104Ω~5 ×
108Ω, comprising 30 mass %~100 mass % conducting fibre.
If the resistance value of conducting fibre is 1 × 104More than Ω, electric conductivity is high, the mixing that can be reduced in spun yarn
Ratio is preferred from this point；If 5 × 108Ω hereinafter, from cost aspect be preferred.
From the above considerations, the resistance value of conducting fibre is more preferably 1 × 105Ω~5 × 107Ω。
Preferred content in clothes shared by suture according to the size of product, there is sleeve, sleeveless etc. to form and change, but excellent
It is selected as the mass % of 2 mass %~8.
If the content of the shared suture comprising conducting fibre is more than 2 mass % in clothes, static discharge effect is high,
It is preferred from the aspect of discomfort when undressing is reduced；If the content is 8 mass % hereinafter, whole for cutting down sewed product
Cost-effective fruit, be preferred.From the above considerations, the suture comprising conducting fibre shared in clothes preferably contains
Amount is more preferably the mass % of 3 mass %~6.
The clothes of the present invention is the matter of 2 mass %~8 preferably with respect to the content of the conducting fibre of the gross mass of clothes
Measure %.
If the content relative to the conducting fibre of the gross mass of clothes is more than 2 mass %, static discharge effect is high, from
It is preferred from the aspect of discomfort when reduction is undressed；If the content is 8 mass % hereinafter, whole for cutting down sewed product
Cost-effective fruit is preferred.From the above considerations, the content relative to the conducting fibre of the gross mass of clothes is more preferable
For the mass % of 3 mass %~6.
Above-mentioned suture using position be preferably in shoulder, oxter portion, arm hole, sleeve portion, neck portion, lower hem at least one
It is more than person.
Above-mentioned suture is not necessarily limited to for sewing and being contained in the suture in clothes, can also be with the suture of sewing
Differently it is sewn on clothes.
Wherein, preferably by above-mentioned suture at least for tuck inside the sleeve portion, oxter portion, shoulder, arm hole, and then be more preferably used for neck portion
Or cuff, further preferably for whole sewing parts.
The use of the position of above-mentioned suture is the positions such as oxter portion, shoulder, sleeve portion, neck portion, for oxter portion, shoulder, sleeve portion
The position for waiting zone of action big is effective.
The preferably used above-mentioned suture of the clothes of the present invention is spun yarn.
Suture is formed by using spun yarn, is not only the surface of line, additionally it is possible to conducting fibre is made to be distributed in entirety, it can
Using be charged by friction the quantity of electric charge change relative to suture conducting fibre content.In addition, due to the use of staple fiber, thus lead
The end of conductive fiber becomes more, can be carried out efficiently corona discharge.
The filament denier of conducting fibre is preferably 1dtex~15dtex.
If the filament denier of conducting fibre is more than 1dtex, spun yarn number can be made to attenuate.If 15dtex with
Under, it can be ensured that yarn breaking force during spun yarn is made, is preferred.From the above considerations, more preferably 3dtex~
11dtex。
The fiber length of the single fiber of conducting fibre is preferably 30mm~200mm.
If a length of more than the 30mm of the fiber of the single fiber of conducting fibre, easily carried out with cotton or other chemical synthetic fibers
Mixed cotton；If 200mm hereinafter, can with wool mixed cotton, so as to utilize the various Weaving method systems such as cotton spinning or worsted spinning
Into spun yarn.If considering the easiness of textile process, more preferable filament denier is 3dtex~11dtex, the fibre of single fiber
Tie up a length of 35mm~120mm.
The thickness of the above-mentioned preferred single thread of spun yarn is calculated as 20~110 with metric count (NM).The single thread of suture according to
Metric count is made for the range of 20~110.In the case of for sweater, it is preferable to use being made with metric count
The finished yarn that doublet cord is processed has been carried out after being calculated as the single thread of 20~40；In the case of for fleece clothing, preferably make
It is calculated as having carried out the processing yarn of compenzine (three strands are twisted thread) processing with metric count after the single thread of 90~105 used in being made
Line.Mixed cotton object during as fleece clothing, it is preferable to use polyester staple fibers from the aspect of the yarn strength of spun yarn
Dimension.
In addition, in the single thread of spun yarn, when the filoplume number of more than 1mm is 130/more than m, conduction can be fully carried out
Property fiber feature be from the corona discharge of fibre section, thus preferably.
From process passability aspect, the upper limit is preferably 300/below m.
The filoplume number of more than 3mm in the preferred single thread of clothes of the present invention is for the 10/filoplume number of more than m, more than 5mm
1/more than m.
If the range, the feature of conducting fibre can be fully carried out i.e. from the corona discharge of fibre section, thus excellent
Choosing.
From process passability aspect, it is 100/m hereinafter, more than 5mm that the upper limit, which is preferably the filoplume number of more than 3mm,
Filoplume number be 10/below m.
About the quantity of filoplume, if reducing the twisting count of single thread, the quantity of filoplume can be increased.But if reduce twisting count
The then strength reduction of line, therefore consider that its balance suitably sets twisting count.
The present invention the preferably above-mentioned conducting fibre of clothes for comprising 5 mass %~9 mass % carbon black or 10 mass %
The fiber of the electric conductivity titanium dioxide of~14 mass %.
Carbon black easily improves the electric conductivity of fiber, thus preferably.In addition, electric conductivity titanium dioxide is compared with carbon black, it is fine
The electric conductivity of dimension is low, but color is grey, thus when clothes is made be not easy it is eye-catching.
It is sufficient from electric conductivity when the core-sheath-type acrylic fibre that core contains conductive materials is made in conducting fibre
Even if aspect prevents conductive materials come off during processing aspect, washs repeatedly and can also keep electric conductivity, can improve electric conductivity etc.
Aspect is set out, and is preferred.
(spun yarn)
The spun yarn used in the present invention can utilize the method for general cotton spinning or worsted spinning to obtain.Form spun yarn
Fiber in, conducting fibre, the preferably core-sheath-type acrylic that the mass % of 30 mass %~100 is included relative to spun yarn are fine
Dimension, it is further blended to contain other fibers.As blended object at this time, in order to keep the yarn strength of spun yarn and it is preferred that third
Alkene nitrile series fiber, polyester fiber, be made the yarn of 90 or more is calculated as with metric count when, more preferable polyester fiber is blended right
As.
(core-sheath-type acrylic fibre)
In the following, the preferred embodiment in the manufacturing method of the electric conductivity acrylic fibre of the present invention is carried out specifically
It is bright.
In the manufacturing method of the electric conductivity acrylic fibre of present embodiment, first prepare sheath ingredient spinning solution and
The spinning solution of core component.As the spinning solution of above-mentioned sheath ingredient, prepare acrylic polymer being dissolved in organic solvent
In the organic solvent solution that forms, also, as the spinning solution of core component, prepare electrically conductive microparticle (A) and acrylic
Polymer (B) by weight ratio (A)/(B) for mix in a manner of less than more than 4 20 and be dissolved in formed in organic solvent it is organic molten
Agent solution.
It is not special to the acrylic polymer used in the spinning solution of sheath ingredient and core component in present embodiment
It limits, the general acrylic polymer used in manufacture of existing acrylic fibre can be used.In particular it is preferred that
Use the substance that can easily show to be heat-shrinked in the thermal contraction treatment process for example after spinning described below.About
The composition of acrylic polymer and the relationship for mitigating caused thermal contraction, although the monomer component being also copolymerized is influenced, lead to
It is higher often with the more few then heat-shrinkable of the acrylonitrile content having the tendency that in polymer.It is therefore preferable that suitably adjust spinning solution
In acrylonitrile content, so as to obtaining defined percent thermal shrinkage in thermal contraction treatment process later.
Particularly, the spinning solution about sheath ingredient, the acrylonitrile content of acrylic polymer is more than 50 weight %
Below 98 weight %, particularly below 95 weight % of more than 50 weight % are suitable.If the content of acrylonitrile is less than 50 weights
Measure %, there is effectively to show to dye distinctiveness, colour rendering etc. as the script of acrylic fibre and
The tendency that other physical property using thermal characteristics as representative also reduce.In addition, in order to improve the dissolubility of acrylonitrile or dyeability etc., it is excellent
Choosing makes the unsaturated monomers such as acrylonitrile compolymer acrylate.
It is therefore preferable that copolymerization unsaturated monomer, so as to make acrylonitrile content in sheath portion as described above for 50 weight % with
Upper 98 weight % is not hereinafter, thus, it is possible to lose the acrylic fibre characteristic that has originally, and it is distinct to have excellent dyeing
Property, colour rendering, thermal characteristics.It is pair not special with the unsaturated monomer of acrylonitrile compolymer it should be noted that in present embodiment
It limits, such as acrylic acid and esters of acrylic acid, methacrylic acid and methyl acrylic ester, vinyl acetate, chlorine can be used
Ethylene, vinylidene chloride etc..
In addition, in this case, for the acrylic fibre with core sheath structure, in order to which core is inhibited to be exposed to sheath
Portion does not simultaneously generate broken end in yarn processed and steadily manufactures, and the viscosity for adjusting the spinning solution of sheath ingredient is of crucial importance, in order to
The viscosity of the spinning solution of sheath ingredient is made to moor following, preferably 150 pools hereinafter, in the spinning solution of control sheath ingredient for 300
Solid component concentration, temperature are critically important.
On the other hand, about the spinning solution of core component, as described above so that electrically conductive microparticle (A) polymerize with acrylic
The mode that weight ratio (A)/(B) of object (B) is less than more than 4 20 is mixed, and is dissolved in organic solvent.It is above-mentioned heavy by making
The value measured than (A)/(B) is more than 4, when manufacturing electric conductivity acrylic fibre, stablizes landform in the acrylic fibre
Into the continuous phase of electrically conductive microparticle, can have sufficient electric conductivity.On the other hand, if above-mentioned weight ratio (A)/(B) is more than
20, in the reduction of the stringiness for the reduction or spinning solution for can occur during spinning the dispersibility of electrically conductive microparticle, solidifying
During silk traction or the cut-out of core easily occurs for the when of stretching.Therefore, while spinnability reduces, acrylic fibre can also be made
Electric conductivity reduce.
At this point, it is 10 that the electrically conductive microparticle contained in the spinning solution of core component, which is preferably powdered conductivity,-3S/cm
The high metal oxide of above whiteness.It, can be suitable for using titanium dioxide or zinc oxide, separately as such electrically conductive microparticle
Outside, the titanium dioxide that surface has for example been coated with tin oxide, indium oxide, tin oxide or zinc oxide can be used in addition to this.This
Outside, in order to further improve electric conductivity, antimony oxide can be shared to tin oxide, indium oxide, tin oxide, oxidation is shared to zinc oxide
Indium, aluminium oxide, potassium oxide, germanium oxide etc..In addition, in this case, the form of the electrically conductive microparticle to containing in spinning solution does not have
Be particularly limited to, in particle in the case of granular, from the filter progress of its stoste in the manufacture of acrylic fibre and
From the aspect of stability in spinning process, preferably average grain diameter is less than 3 μm.
In addition, about for adjusting the organic solvent of each spinning solution of above-mentioned sheath ingredient and core component, can preferably make
It with organic solvents such as dimethylacetylamide, dimethylformamide, dimethyl sulfoxide (DMSO)s, is not particularly limited, can also select third
Other usually used organic solvents in the spinning of alkene nitrile series fiber.
In present embodiment, to the solid component concentration and temperature of each spinning solution of above-mentioned sheath ingredient and core component
It is not particularly limited, if solid component concentration is too low, gap is easily generated in the fiber after spinning, as a result, it is possible that drawing
Play the reduction of fibrous physical property, the reduction of electric conductivity.Therefore, the solid component concentration in the spinning solution of sheath ingredient is preferably 5
More than quality %, and the solid component concentration in the spinning solution of core component is preferably more than 30 mass %.
Then, for the sheath ingredient and the spinning solution of core component that prepare as described above, according to being wrapped in acrylic fibre
The content of the electrically conductive microparticle contained is that the mode of below 15 mass % of more than 5 mass % sets sheath portion and the ratio of core, is used
Core-sheath-type spinning head carries out spinning by wet-spinning.When carrying out spinning, the content of electrically conductive microparticle that is included in fiber
During less than 5 mass %, electrically conductive microparticle is few, therefore the excellent electric conductivity as target can not be assigned to acrylic fibre
Energy.On the other hand, when the content of electrically conductive microparticle is more than 15 mass %, fibre whiteness when manufacturing electric conductivity acrylic fibre
Difference, therefore it is limited to lead to the problem of its product-use
It should be noted that about above-mentioned wet-spinning, can in the manufacture of existing acrylic fibre usually
Method used is carried out similarly, for example, can by sheath ingredient and the spinning solution of core component from core-sheath-type spinning head be discharged to by
In the solidification liquid that organic solvent and water are formed and make its curing, thus carry out spinning.
At this point, as core-sheath-type spinning head, it is preferable to use hole count be more than 3000, particularly be more than 5000 spinneret
Head is carried out spinning using the core-sheath-type spinning head that hole count is more than 3000 in this way, can be manufactured with very high productivity
Electric conductivity acrylic fibre.
Also, for the coagulated yarn obtained by above-mentioned wet spinning, implement stretching later, desolventizing, finish imparting, do
After each processing such as dry densification, handled with less than more than 30% 50% shrinking percentage into the thermal contraction for exercising coagulated yarn contraction.It is right
Processing method and treatment conditions in each processing such as above-mentioned stretching, desolventizing, finish imparting, compacting by drying do not limit especially
It is fixed, it can be as needed suitable for change.Such as about stretch processing, can in 80 DEG C or more of hot water with desolventizing and into
Row, if in addition, considering physical property of stability of spinning process, obtained fiber etc., stretching ratio is preferably set to 3 times~10 times,
More preferably it is set as 4 times~7 times.
Embodiment
In the following, the present invention is illustrated by embodiment.It should be noted that assessment item in embodiment is using following
Method is measured.
(assay method of the resistance value of single fiber)
Electric conductivity acrylic fibre is accurately separated 1cm, and using silver paste material, (Fujikura Kasei Co., Ltd manufactures
DOTITE) it is bonded to metal terminal.Under 20 DEG C of temperature, the atmosphere of relative humidity 40RH%, apply between the metal terminal
The DC voltage of 1000V measures the resistance value between metal terminal (East Asia electric wave Co., Ltd. manufactures SM-8210).
(being charged by friction charge quantity measuring method)
In addition, about the product used in measure, after being repeated 5 times the carrying out washing treatment of 106 methods of JIS L217,20 points are carried out
After clock water filling is rinsed, tumble dryer is carried out, uses obtained article.
For the product after washing, the quantity of electric charge is charged by friction according to JIS T8118 measure.
(filoplume number assay method)
According to JIS L1095 9.22.2B methods, the filoplume for carrying out spun yarn measures.
(embodiment 1)
By electric conductivity core sheath acrylic fibre, (Li Yang societies of Mitsubishi manufacture：ET10, fiber number 3.3dtex, the long 38mm of fiber)
100 mass % put into the loom of cotton spinning process, make spun yarn.Above-mentioned electric conductivity core sheath acrylic fibre is included in core and is led
Electrical titanium dioxide, the content relative to the electric conductivity titanium dioxide of fiber entirety are 12 mass %.At this point, since single fiber is strong
Power is low, thus stretching ratio in each process or spins speed, and single fiber generates flyings it is possible that the damage that fractures, therefore
The speed that spins of carding machine is set as 40m/ minutes hereinafter, the stretching ratio of drawing frame is set as 8 times.About the single thread in spinning frame
Number is spun with 630 metric count 32, twisting count/m.The item used when being batched about single thread does the biography uniformly measured
Sensor uses optical profile type rather than common electrostatic capacitive.After single thread making, through doubling process, by the use of twisting machine as again
It twists with the fingers and S sth. made by twisting is carried out with 400 times/m, doublet cord is made, produces suture A.
2/32 doublet cord is used in terms of metric count by wool 100%, yarn count, separately produces the rib-loop group of 12G
The knitted fabric knitted.
Using above-mentioned suture A and above-mentioned knitted fabric, the sweater of crew neck is made.The sewing unit of above-mentioned suture A has been used to be divided into
Sleeve portion, oxter portion, shoulder, arm hole and neck portion.
Product dyeing is carried out to above-mentioned sweater with black, obtains the black sweater.Implement the friction band of above-mentioned black sweater
The measure of the electric quantity of electric charge.The composition of clothes is shown in table 1, evaluation result is shown in table 2.
(embodiment 2)
V neck sweaters are made, product dyeing is carried out with the pink colour of light color, obtains pink colour similarly to Example 1 in addition to this
V neck sweater.
Implement the measure for being charged by friction the quantity of electric charge of above-mentioned pink colour sweater.The composition of clothes is shown in table 1, evaluation result is shown
In table 2.
(embodiment 3)
As shown in table 1, the sewing unit of above-mentioned suture A has been used to be divided into sleeve portion, oxter portion, shoulder, arm hole, the seam in neck portion
System has used the suture without conducting fibre, has obtained sweater similarly to Example 1 in addition to this without using above-mentioned suture A.
By it evaluation result is shown in table 2.
(embodiment 4)
As shown in table 1, the sewing unit of above-mentioned suture A has been used to be divided into sleeve portion, oxter portion, shoulder, arm hole and cuff,
Obtain sweater similarly to Example 1 in addition to this.By it evaluation result is shown in table 2.
(embodiment 5)
As shown in table 1, the sewing unit of above-mentioned suture A has been used to be divided into sleeve portion, oxter portion, shoulder, arm hole and cuff,
And then the famous brand of long 1cm, width 5cm are sewed on above-mentioned suture A on the top of rear body, carry out product dyeing with navy blue, except this with
Sweater is obtained similarly to Example 1 outside.By it evaluation result is shown in table 2.
(embodiment 6)
It is 20 mass % to make the content relative to the electric conductivity titanium dioxide of fiber entirety, same with embodiment 1 in addition to this
Produce to sample spun yarn B.
By spun yarn B for tuck inside the sleeve portion, oxter portion, shoulder, arm hole, circle is produced similarly to Example 1 in addition to this
Lead sweater.The composition of clothes is shown in table 1, evaluation result is shown in table 2.
(comparative example 1)
Acrylic fibre (Li Yang societies of the Mitsubishi system without electric conductivity is used instead of the conducting fibre of embodiment 1
It makes：V17, filament denier 3.3dtex, the long 38mm of fiber), obtain black sweater similarly to Example 1 in addition to this.
Implement the measure for being charged by friction the quantity of electric charge of above-mentioned black sweater.The composition of clothes is shown in table 1, evaluation result is shown
In table 2.
[table 1]
[table 2]
Claims (15)
1. a kind of clothes sews the clothes formed for each braided fabric portion using the suture comprising conducting fibre, wherein, it is described
The content of conducting fibre in suture is the mass % of 30 mass %~100, and the content of the conducting fibre in braided fabric portion is 1
Quality % is hereinafter, the clothes is charged by friction the quantity of electric charge as below 0.8 μ C/ parts.
2. clothes as described in claim 1, wherein, resistance value between the 1cm of the fiber axial direction of the conducting fibre for 1 ×
104Ω~5 × 108Ω。
3. clothes as claimed in claim 1 or 2, wherein, relative to the gross mass of clothes, the content of the suture is 2 matter
Measure the mass % of %~8.
4. clothes as claimed in claim 1 or 2, wherein, relative to the gross mass of clothes, the content of the conducting fibre is
The mass % of 2 mass %~8.
5. such as clothes according to any one of claims 1 to 4, wherein, the suture is shoulder, sleeve portion, neck using position
It is more than at least one of portion, oxter portion, arm hole, lower hem, cuff.
6. such as clothes according to any one of claims 1 to 5, wherein, the suture is spun yarn.
7. such as clothes according to any one of claims 1 to 6, wherein, the filament denier of the conducting fibre is 1dtex
~15dtex.
8. clothes as claimed in claims 6 or 7, wherein, the fibre of the single fiber of the conducting fibre included in the spun yarn
Tie up a length of 30mm~200mm.
9. the clothes as described in any one of claim 6~8, wherein, the thickness of the single thread of the spun yarn is with metric count
Be calculated as 20~110, the filoplume number of more than 1mm in single thread be 130/more than m.
10. clothes as claimed in claim 9, wherein, the filoplume number of more than the 3mm in the single thread of the spun yarn is 10/m
Above, the filoplume number of more than 5mm is 1/more than m.
11. the clothes as described in any one of claim 6~10, wherein, the spun yarn is doublet cord or compenzine.
12. the clothes as described in any one of claim 1~11, wherein, the conducting fibre is includes 5 mass %~9
The fiber of the electric conductivity titanium dioxide of the mass % of the carbon black of quality % or 10 mass %~25.
13. the clothes as described in any one of claim 1~12, wherein, the conducting fibre contains conductive material for core
The core-sheath-type acrylic fibre of matter.
14. the clothes as described in any one of claim 1~13, wherein, the clothes is sweater or fleece clothing.
15. a kind of suture, it includes the conducting fibres of the mass % of 30 mass %~100.
Applications Claiming Priority (3)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| JP2015206234 | 2015-10-20 | ||
| JP2015-206234 | 2015-10-20 | ||
| PCT/JP2016/080771 WO2017069100A1 (en) | 2015-10-20 | 2016-10-18 | Garment having antistatic capability |
Publications (1)
| Publication Number | Publication Date |
|---|---|
| CN108135297A true CN108135297A (en) | 2018-06-08 |
Family
ID=58557052
Family Applications (1)
| Application Number | Title | Priority Date | Filing Date |
|---|---|---|---|
| CN201680060008.4A Pending CN108135297A (en) | 2015-10-20 | 2016-10-18 | Clothes with antistatic property |
Country Status (5)
| Country | Link |
|---|---|
| US (1) | US20180228225A1 (en) |
| EP (1) | EP3366151A4 (en) |
| JP (1) | JP6332471B2 (en) |
| CN (1) | CN108135297A (en) |
| WO (1) | WO2017069100A1 (en) |
Cited By (1)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN112410959A (en) * | 2020-11-12 | 2021-02-26 | 湖州欣缘纺织有限公司 | Preparation method of anti-static polyester core-spun yarn |
Families Citing this family (3)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| JPWO2018084040A1 (en) * | 2016-11-01 | 2019-06-24 | 帝人株式会社 | Fabric, method for producing the same, and textile |
| WO2019150976A1 (en) * | 2018-01-30 | 2019-08-08 | 三菱ケミカル株式会社 | Antistatic clothes |
| JPWO2022024827A1 (en) * | 2020-07-28 | 2022-02-03 |
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| CN112410959A (en) * | 2020-11-12 | 2021-02-26 | 湖州欣缘纺织有限公司 | Preparation method of anti-static polyester core-spun yarn |
Also Published As
| Publication number | Publication date |
|---|---|
| WO2017069100A1 (en) | 2017-04-27 |
| JPWO2017069100A1 (en) | 2017-10-19 |
| EP3366151A4 (en) | 2019-05-01 |
| EP3366151A1 (en) | 2018-08-29 |
| JP6332471B2 (en) | 2018-05-30 |
| US20180228225A1 (en) | 2018-08-16 |
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Application publication date: 20180608 |
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