CN108127999A - 一种抗静电的窗帘面料 - Google Patents

一种抗静电的窗帘面料 Download PDF

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CN108127999A
CN108127999A CN201711237210.2A CN201711237210A CN108127999A CN 108127999 A CN108127999 A CN 108127999A CN 201711237210 A CN201711237210 A CN 201711237210A CN 108127999 A CN108127999 A CN 108127999A
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cloth
fiber
antistatic
parts
window curtain
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赵志云
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Huzhou China Mdt Infotech Ltd
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    • D02G3/04—Blended or other yarns or threads containing components made from different materials
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Abstract

本发明涉及窗帘面料技术领域，具体涉及一种抗静电的窗帘面料，包括两侧的布料层和设于布料层之间的防静电布层，其中两侧的布料层由抗静电改性氨纶纤维、涤纶纤维、亚麻纤维、剑麻纤维和槿麻纤维混纺而成；防静电布层由粘胶面料两侧涂覆抗静电料液制成，粘胶面料由粘胶纤维与亚麻纤维按质量比2:1混纺而成。本发明的窗帘面料由两侧的布料层和中间的防静电布层组成，布料层具有抗静电性质，防静电布层能够及时分散和转移静电荷，起到储存静电荷的作用，布料层和防静电布层协同作用使窗帘面料抗静电性能强。

Description

一种抗静电的窗帘面料
技术领域
本发明涉及窗帘面料技术领域，具体涉及一种抗静电的窗帘面料。
背景技术
静电是一种处于静止状态的电荷。在干燥和多风的秋天，在日常生活中，人们常常会碰到这种现象，例如北方冬天天气干燥，人体容易带上静电，当接触他人或金属导电体时就会出现放电现象。人会有触电的针刺感，夜间能看到火花，这是化纤衣物与人体摩擦人体带上正静电的原因。静电的危害很多，在飞机机体与空气、水气、灰尘等微粒摩擦时会使飞机带电，如果不采取措施将会严重干扰飞机无线电设备的正常工作；在印刷厂里，纸页之间的静电会使纸页粘合在一起难以分开。化纤衣物容易发生静电，尤其在冬季或干燥时节，但是一般对人体无害。但是当静电积累到一定程度可使血液中的碱性 升高，血清中钙含量减少，尿中钙排泄量增加，这对于正在生长发育的儿童， 血钙水平较低的老年人以及需钙量较多的孕妇和乳母无疑是有危害的，过多的静电在人体内堆积，还会引起脑神经细胞膜电流传导异常，影响中枢神经，从而导致血液酸碱度和机体氧特性的改变，影响机体的生理平衡。在易燃易爆地区，人体带有静电还会引起火灾。
窗帘是室内常用的装饰物，起到避光、隔音、挡风和保护隐私等功能。常用的窗帘布料一般有棉纱布、涤纶布、涤棉混纺、棉麻混纺、无纺布等。由于秋、春、冬等季节室内干燥，尤其是空调的使用，布窗帘表面容易产生静电，而且窗帘一般靠近沙发、插孔等，因此产生的静电容易带来安全风险。
发明内容
针对布料窗帘因室内干燥容易产生静电的问题，本发明的目的在于提供一种抗静电的窗帘面料，具有良好的抗静电性能，能够及时消除和分散表面产生的静电荷，使用更加安全。
本发明提供如下的技术方案：
一种抗静电的窗帘面料，窗帘面料包括两侧的布料层和设于布料层之间的防静电布层，其中两侧的布料层由以下重量份的组份纺织制成：抗静电改性氨纶纤维100份、涤纶纤维60～70份、亚麻纤维50～55份、剑麻纤维23～30份和槿麻纤维15～20份；防静电布层由粘胶面料两侧涂覆抗静电料液制成，粘胶面料由粘胶纤维与亚麻纤维按质量比2:1混纺而成。
作为本发明的一种改进，抗静电改性氨纶纤维由以下重量份的组份制成：聚氨酯母粒100份、纳米氧化镁10～16份、纳米氧化钛10～15份、纳米氧化锆7～11份、纳米氧化铝8～11份、纳米氧化钼3～7份、纳米碳纤维粉8～15份、KH550硅烷偶联剂1.3～1.8份和硬脂酸钙1～2份，将上述各原料组份经螺杆挤出机制成混合母粒，然后经湿法纺丝制得抗静电改性氨纶纤维。
作为本发明的一种改进，亚麻纤维、剑麻纤维和槿麻纤维经以下过程处理后使用：将亚麻纤维、剑麻纤维或槿麻纤维置纤维素酶水溶液中，调节pH值=4～5，在32～37℃下浸泡至亚麻纤维、剑麻纤维或槿麻纤维出现溶胀，立即取出并清水冲洗，然后置于浓度18wt%的双氧水溶液中在28～35℃浸泡2～4小时，然后取出清水冲洗并干燥，浸泡过程中双氧水没过亚麻纤维、剑麻纤维或槿麻纤维。
作为本发明的一种改进，抗静电料液经以下过程制成：将氧化石墨烯加入到2～3倍重量的水中超声分散均匀，然后加入氧化石墨烯1～1.5倍质量的18%v/v乙醇溶液和0.3～0.5倍质量的十二烷基二甲基苄基氯化铵，在80～85℃超声保持240min后加热蒸发得到固体物，超声功率10～15W，将固体物经水冲洗至无氯离子检出后干燥并研磨至1～3nm得到改性石墨烯，将改性石墨烯、纳米二氧化钛、纳米氧化钇和纳米氧化锆加入到水中超声分散均匀得到抗静电料液，改性石墨烯、纳米氧化钛、纳米氧化镁、纳米氧化锆与水的质量比为1:0.2～0.5:0.1～0.3:0.2～0.5:10～15。
作为本发明的一种改进，所述窗帘面料经以下过程制成：
（1）将抗静电改性氨纶纤维、涤纶纤维、亚麻纤维、剑麻纤维和槿麻纤维纺织制成布料层；
（2）在粘胶面料的两侧涂覆抗静电料液，喷涂密度为10～15mL/m3，然后在20～23℃通风干燥得到防静电布层；
（3）在防静电布层两侧分别经抗静电改性氨纶纤维缝接布料层制得窗帘面料。
本发明的窗帘面料由两层布料层和设置在布料层之间的防静电布层组成。布料层由抗静电改性氨纶纤维、涤纶纤维、亚麻纤维、剑麻纤维和槿麻纤维混纺而成。所用的抗静电改性氨纶纤维添加有纳米氧化钛、氧化镁、氧化锆、氧化铝、氧化钼和碳纤维粉，储存电荷的能力强，可以及时分散窗帘表面产生的静电荷，提升窗帘面料的抗静电性能强。亚麻纤维、剑麻纤维和槿麻纤维是植物纤维，含有大量的纤维素、半纤维素，不易产生静电，且具有一定的吸湿和透气性能，可以抑制静电的产生。而且亚麻纤维、剑麻纤维和槿麻纤维可以抵抗静电的产生。亚麻纤维、剑麻纤维和槿麻纤维经纤维酶水解一段时间后纤维素断开，然后经双氧水氧化使纤维素中的羟基向羧基转化，抗静电性能进一步增强。防静电布层由粘胶面料涂覆抗静电料液制成，粘胶面料中的粘胶纤维是是以天然木纤维、棉短绒为原料，经碱化、老化、磺化等工序制成可溶性纤维素黄原酸酯再溶于稀碱液制成粘胶，后经湿法纺丝而制成的纤维素纤维，具有良好的吸湿、透气性能，不易产生静电。抗静电料液中的氧化石墨烯、纳米二氧化钛、纳米氧化钇、纳米氧化锆具有良好的储存电荷的性能，再粘胶面料两侧涂覆后形成抗静电涂层，与粘胶面料一同形成储电荷层，使防静电层不产生静电，而且能及时分散和转移两侧的布料层上的静电荷，增强窗帘面料的抗静电能力。氧化石墨烯表面含有羧基、羰基等，经十二烷基二甲基苄基氯化铵改性后在上述基团上接枝极性的十二烷基二甲基苄基，吸引电荷的能力增强，进一步强化防静电布层的储电荷能力，分散窗帘面料表面的静电荷。布料层和防静电布层协同作用使窗帘面料抗静电性能强。
本发明的有益效果如下：
本发明的窗帘面料由两侧的布料层和中间的防静电布层组成，布料层具有抗静电性质，防静电布层能够及时分散和转移静电荷，起到储存静电荷的作用，布料层和防静电布层协同作用使窗帘面料抗静电性能强。
具体实施方式
下面就本发明的具体实施方式作进一步说明。
如无特别说明，本发明中所采用的原料均可从市场上购得或是本领域常用的，如无特别说明，下述实施例中的方法均为本领域的常规方法。
实施例1
一种抗静电的窗帘面料，窗帘面料包括两侧的布料层和设于布料层之间的防静电布层，两侧的布料层由以下组份纺织制成：抗静电改性氨纶纤维100g、涤纶纤维60g、亚麻纤维50g、剑麻纤维23g和槿麻纤维15g；防静电布层由粘胶面料两侧涂覆抗静电料液制成，粘胶面料由粘胶纤维与亚麻纤维按质量比2:1混纺而成。
其中抗静电改性氨纶纤维由以下组份制成：聚氨酯母粒100g、纳米氧化镁10g、纳米氧化钛10g、纳米氧化锆7g、纳米氧化铝8g、纳米氧化钼3g、纳米碳纤维粉8g、KH550硅烷偶联剂1.3g和硬脂酸钙1g，将上述各原料组份经螺杆挤出机制成混合母粒，然后经湿法纺丝制得抗静电改性氨纶纤维。
亚麻纤维、剑麻纤维和槿麻纤维经以下过程处理后使用：将亚麻纤维、剑麻纤维或槿麻纤维置纤维素酶水溶液中，调节pH值=4，在32℃下浸泡至亚麻纤维、剑麻纤维或槿麻纤维出现溶胀，立即取出并清水冲洗，然后置于浓度18wt%的双氧水溶液中在28℃浸泡2小时，然后取出清水冲洗并干燥，浸泡过程中双氧水没过亚麻纤维、剑麻纤维或槿麻纤维。
上述窗帘面料经以下过程制成：
（1）将抗静电改性氨纶纤维、涤纶纤维、亚麻纤维、剑麻纤维和槿麻纤维纺织制成布料层；
（2）在粘胶面料的两侧涂覆抗静电料液，喷涂密度为10mL/m3，然后在20℃通风干燥得到防静电布层；
（3）在防静电布层两侧分别经抗静电改性氨纶纤维缝接布料层制得窗帘面料。
其中抗静电料液经以下过程制成：将氧化石墨烯加入到2倍重量的水中超声分散均匀，然后加入氧化石墨烯1倍质量的18%v/v乙醇溶液和0.3倍质量的十二烷基二甲基苄基氯化铵，在80℃超声保持240min后加热蒸发得到固体物，超声功率10W，将固体物经水冲洗至无氯离子检出后干燥并研磨至1～3nm得到改性石墨烯，将改性石墨烯、纳米二氧化钛、纳米氧化钇和纳米氧化锆加入到水中超声分散均匀得到抗静电料液，改性石墨烯、纳米氧化钛、纳米氧化镁、纳米氧化锆与水的质量比为1:0.2:0.1:0.2:10。
实施例2
一种抗静电的窗帘面料，窗帘面料包括两侧的布料层和设于布料层之间的防静电布层，两侧的布料层由以下组份纺织制成：抗静电改性氨纶纤维100g、涤纶纤维65g、亚麻纤维55g、剑麻纤维26.5g和槿麻纤维17.5g；防静电布层由粘胶面料两侧涂覆抗静电料液制成，粘胶面料由粘胶纤维与亚麻纤维按质量比2:1混纺而成。
其中抗静电改性氨纶纤维由以下组份制成：聚氨酯母粒100g、纳米氧化镁13g、纳米氧化钛12.5g、纳米氧化锆9g、纳米氧化铝9.5g、纳米氧化钼5g、纳米碳纤维粉11.5g、KH550硅烷偶联剂1.55g和硬脂酸钙1.5g，将上述各原料组份经螺杆挤出机制成混合母粒，然后经湿法纺丝制得抗静电改性氨纶纤维。
亚麻纤维、剑麻纤维和槿麻纤维经以下过程处理后使用：将亚麻纤维、剑麻纤维或槿麻纤维置纤维素酶水溶液中，调节pH值=4.5，在35℃下浸泡至亚麻纤维、剑麻纤维或槿麻纤维出现溶胀，立即取出并清水冲洗，然后置于浓度18wt%的双氧水溶液中在32℃浸泡3小时，然后取出清水冲洗并干燥，浸泡过程中双氧水没过亚麻纤维、剑麻纤维或槿麻纤维。
上述窗帘面料经以下过程制成：
（1）将抗静电改性氨纶纤维、涤纶纤维、亚麻纤维、剑麻纤维和槿麻纤维纺织制成布料层；
（2）在粘胶面料的两侧涂覆抗静电料液，喷涂密度为13mL/m3，然后在22℃通风干燥得到防静电布层；
（3）在防静电布层两侧分别经抗静电改性氨纶纤维缝接布料层制得窗帘面料。
其中抗静电料液经以下过程制成：将氧化石墨烯加入到2.5倍重量的水中超声分散均匀，然后加入氧化石墨烯1.3倍质量的18%v/v乙醇溶液和0.4倍质量的十二烷基二甲基苄基氯化铵，在83℃超声保持240min后加热蒸发得到固体物，超声功率13W，将固体物经水冲洗至无氯离子检出后干燥并研磨至1～3nm得到改性石墨烯，将改性石墨烯、纳米二氧化钛、纳米氧化钇和纳米氧化锆加入到水中超声分散均匀得到抗静电料液，改性石墨烯、纳米氧化钛、纳米氧化镁、纳米氧化锆与水的质量比为1:35:0.2:0.35:12.5。
实施例3
一种抗静电的窗帘面料，窗帘面料包括两侧的布料层和设于布料层之间的防静电布层，两侧的布料层由以下组份纺织制成：抗静电改性氨纶纤维100g、涤纶纤维70g、亚麻纤维55g、剑麻纤维30g和槿麻纤维20g；防静电布层由粘胶面料两侧涂覆抗静电料液制成，粘胶面料由粘胶纤维与亚麻纤维按质量比2:1混纺而成。
其中抗静电改性氨纶纤维由以下组份制成：聚氨酯母粒100g、纳米氧化镁16g、纳米氧化钛15g、纳米氧化锆11g、纳米氧化铝11g、纳米氧化钼7g、纳米碳纤维粉15g、KH550硅烷偶联剂1.8g和硬脂酸钙2g，将上述各原料组份经螺杆挤出机制成混合母粒，然后经湿法纺丝制得抗静电改性氨纶纤维。
亚麻纤维、剑麻纤维和槿麻纤维经以下过程处理后使用：将亚麻纤维、剑麻纤维或槿麻纤维置纤维素酶水溶液中，调节pH值=5，在37℃下浸泡至亚麻纤维、剑麻纤维或槿麻纤维出现溶胀，立即取出并清水冲洗，然后置于浓度18wt%的双氧水溶液中在35℃浸泡4小时，然后取出清水冲洗并干燥，浸泡过程中双氧水没过亚麻纤维、剑麻纤维或槿麻纤维。
上述窗帘面料经以下过程制成：
（1）将抗静电改性氨纶纤维、涤纶纤维、亚麻纤维、剑麻纤维和槿麻纤维纺织制成布料层；
（2）在粘胶面料的两侧涂覆抗静电料液，喷涂密度为15mL/m3，然后在23℃通风干燥得到防静电布层；
（3）在防静电布层两侧分别经抗静电改性氨纶纤维缝接布料层制得窗帘面料。
其中抗静电料液经以下过程制成：将氧化石墨烯加入到3倍重量的水中超声分散均匀，然后加入氧化石墨烯1.5倍质量的18%v/v乙醇溶液和0.5倍质量的十二烷基二甲基苄基氯化铵，在85℃超声保持240min后加热蒸发得到固体物，超声功率15W，将固体物经水冲洗至无氯离子检出后干燥并研磨至1～3nm得到改性石墨烯，将改性石墨烯、纳米二氧化钛、纳米氧化钇和纳米氧化锆加入到水中超声分散均匀得到抗静电料液，改性石墨烯、纳米氧化钛、纳米氧化镁、纳米氧化锆与水的质量比为1:0.5:0.3:0.5:15。

Claims (5)

1.一种抗静电的窗帘面料，其特征在于，窗帘面料包括两侧的布料层和设于布料层之间的防静电布层，其中两侧的布料层由以下重量份的组份纺织制成：抗静电改性氨纶纤维100份、涤纶纤维60～70份、亚麻纤维50～55份、剑麻纤维23～30份和槿麻纤维15～20份；
防静电布层由粘胶面料两侧涂覆抗静电料液制成，粘胶面料由粘胶纤维与亚麻纤维按质量比2:1混纺而成。
2.根据权利要求1所述的窗帘面料，其特征在于，抗静电改性氨纶纤维由以下重量份的组份制成：聚氨酯母粒100份、纳米氧化镁10～16份、纳米氧化钛10～15份、纳米氧化锆7～11份、纳米氧化铝8～11份、纳米氧化钼3～7份、纳米碳纤维粉8～15份、KH550硅烷偶联剂1.3～1.8份和硬脂酸钙1～2份，将上述各原料组份经螺杆挤出机制成混合母粒，然后经湿法纺丝制得抗静电改性氨纶纤维。
3.根据权利要求1所述的窗帘面料，其特征在于，亚麻纤维、剑麻纤维和槿麻纤维经以下过程处理后使用：将亚麻纤维、剑麻纤维或槿麻纤维置纤维素酶水溶液中，调节pH值=4～5，在32～37℃下浸泡至亚麻纤维、剑麻纤维或槿麻纤维出现溶胀，立即取出并清水冲洗，然后置于浓度18wt%的双氧水溶液中在28～35℃浸泡2～4小时，然后取出清水冲洗并干燥，浸泡过程中双氧水没过亚麻纤维、剑麻纤维或槿麻纤维。
4.根据权利要求1所述的窗帘面料，其特征在于，抗静电料液经以下过程制成：将氧化石墨烯加入到2～3倍重量的水中超声分散均匀，然后加入氧化石墨烯1～1.5倍质量的18%v/v乙醇溶液和0.3～0.5倍质量的十二烷基二甲基苄基氯化铵，在80～85℃超声保持240min后加热蒸发得到固体物，超声功率10～15W，将固体物经水冲洗至无氯离子检出后干燥并研磨至1～3nm得到改性石墨烯，将改性石墨烯、纳米二氧化钛、纳米氧化钇和纳米氧化锆加入到水中超声分散均匀得到抗静电料液，改性石墨烯、纳米氧化钛、纳米氧化镁、纳米氧化锆与水的质量比为1:0.2～0.5:0.1～0.3:0.2～0.5:10～15。
5.根据权利要求1至4任一所述的窗帘面料，其特征在于，所述窗帘面料经以下过程制成：
（1）将抗静电改性氨纶纤维、涤纶纤维、亚麻纤维、剑麻纤维和槿麻纤维纺织制成布料层；
（2）在粘胶面料的两侧涂覆抗静电料液，喷涂密度为10～15mL/m3，然后在20～23℃通风干燥得到防静电布层；
（3）在防静电布层两侧分别经抗静电改性氨纶纤维缝接布料层制得窗帘面料。
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CN108926907A (zh) * 2018-07-26 2018-12-04 安徽省利特环保技术有限公司 一种抗静电除尘滤布及其制备方法
CN112848549A (zh) * 2021-01-09 2021-05-28 江苏丰裕纺织科技有限公司 一种防静电纺织布料
CN118216735A (zh) * 2024-02-05 2024-06-21 嘉兴钜锋制衣有限公司 一种防静电面料及应用该面料进行服饰加工的应用工艺

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Application publication date: 20180608