CN108086026A - A kind of water-borne UV-curing ink direct-injection printing technology - Google Patents
A kind of water-borne UV-curing ink direct-injection printing technology Download PDFInfo
- Publication number
- CN108086026A CN108086026A CN201711334963.5A CN201711334963A CN108086026A CN 108086026 A CN108086026 A CN 108086026A CN 201711334963 A CN201711334963 A CN 201711334963A CN 108086026 A CN108086026 A CN 108086026A
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- China
- Prior art keywords
- water
- borne
- ultraviolet
- direct
- curing ink
- Prior art date
- Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
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Classifications
-
- D—TEXTILES; PAPER
- D06—TREATMENT OF TEXTILES OR THE LIKE; LAUNDERING; FLEXIBLE MATERIALS NOT OTHERWISE PROVIDED FOR
- D06P—DYEING OR PRINTING TEXTILES; DYEING LEATHER, FURS OR SOLID MACROMOLECULAR SUBSTANCES IN ANY FORM
- D06P5/00—Other features in dyeing or printing textiles, or dyeing leather, furs, or solid macromolecular substances in any form
- D06P5/30—Ink jet printing
-
- C—CHEMISTRY; METALLURGY
- C09—DYES; PAINTS; POLISHES; NATURAL RESINS; ADHESIVES; COMPOSITIONS NOT OTHERWISE PROVIDED FOR; APPLICATIONS OF MATERIALS NOT OTHERWISE PROVIDED FOR
- C09D—COATING COMPOSITIONS, e.g. PAINTS, VARNISHES OR LACQUERS; FILLING PASTES; CHEMICAL PAINT OR INK REMOVERS; INKS; CORRECTING FLUIDS; WOODSTAINS; PASTES OR SOLIDS FOR COLOURING OR PRINTING; USE OF MATERIALS THEREFOR
- C09D11/00—Inks
- C09D11/02—Printing inks
- C09D11/10—Printing inks based on artificial resins
- C09D11/101—Inks specially adapted for printing processes involving curing by wave energy or particle radiation, e.g. with UV-curing following the printing
-
- D—TEXTILES; PAPER
- D06—TREATMENT OF TEXTILES OR THE LIKE; LAUNDERING; FLEXIBLE MATERIALS NOT OTHERWISE PROVIDED FOR
- D06P—DYEING OR PRINTING TEXTILES; DYEING LEATHER, FURS OR SOLID MACROMOLECULAR SUBSTANCES IN ANY FORM
- D06P3/00—Special processes of dyeing or printing textiles, or dyeing leather, furs, or solid macromolecular substances in any form, classified according to the material treated
- D06P3/02—Material containing basic nitrogen
- D06P3/04—Material containing basic nitrogen containing amide groups
- D06P3/24—Polyamides; Polyurethanes
-
- D—TEXTILES; PAPER
- D06—TREATMENT OF TEXTILES OR THE LIKE; LAUNDERING; FLEXIBLE MATERIALS NOT OTHERWISE PROVIDED FOR
- D06P—DYEING OR PRINTING TEXTILES; DYEING LEATHER, FURS OR SOLID MACROMOLECULAR SUBSTANCES IN ANY FORM
- D06P3/00—Special processes of dyeing or printing textiles, or dyeing leather, furs, or solid macromolecular substances in any form, classified according to the material treated
- D06P3/34—Material containing ester groups
- D06P3/52—Polyesters
-
- D—TEXTILES; PAPER
- D06—TREATMENT OF TEXTILES OR THE LIKE; LAUNDERING; FLEXIBLE MATERIALS NOT OTHERWISE PROVIDED FOR
- D06P—DYEING OR PRINTING TEXTILES; DYEING LEATHER, FURS OR SOLID MACROMOLECULAR SUBSTANCES IN ANY FORM
- D06P5/00—Other features in dyeing or printing textiles, or dyeing leather, furs, or solid macromolecular substances in any form
- D06P5/02—After-treatment
Abstract
The present invention relates to a kind of water-borne UV-curing ink direct-injection printing technologies, comprise the following steps:Water-borne UV-curing ink is sprayed on terylene mesh by nozzle, carries out stamp;Ultraviolet light irradiation carries out terylene mesh by ultraviolet radiator, ultraviolet wavelength is 310 410nm;In the environment of temperature is 55 65 °, terylene mesh is dried, drying time is 13 minutes;Curing is irradiated terylene mesh by ultraviolet light mercury lamp, ultraviolet wavelength is 350 370nm, and irradiation time is 12 minutes.The prior art is different from, water-borne UV-curing ink is sprayed on terylene mesh by the present invention by nozzle, carries out stamp;Good hand touch, common stamp may feel that stencil, and the technical program is exactly the feel of terylene mesh in itself.Without pre-treatment and post processing, situations such as hot setting not post-processed avoids elastic material contraction distortion, and 3D materials are driven plain.Convenient for the stamp on terylene mesh, printing quality is good.
Description
Technical field
The present invention relates to cloth printing technology, more particularly to a kind of water-borne UV-curing ink direct-injection printing technology.
Background technology
In the prior art, traditional direct-injection ink carries out direct-injection on cotton, but ink can not be attached on terylene.Or
Person carries out direct-injection using the disperse dyes of sublimation transfer, and cloth need to carry out starching pretreatment, and need to carry out 160-200 ° of temperature into
Row cures and the post processing of desizing.Hot setting makes elastic material contraction distortion, and high temperature cure process can pass through roller and squeeze,
The brushy fabrics such as fabric, the polar fleece of 3D bumps are flattened.
The content of the invention
For this reason, it may be necessary to provide a kind of water-borne UV-curing ink direct-injection printing technology, for solve in the prior art ink without
The technical issues of method attachment, elastic material contraction distortion, the fabric of 3D bumps are driven plain.
To achieve the above object, a kind of water-borne UV-curing ink direct-injection printing technology is inventor provided, including following step
Suddenly:
Direct-injection stamp
Water-borne UV-curing ink is sprayed on terylene mesh by nozzle, carries out stamp;
Ultraviolet light irradiates
Ultraviolet light irradiation, ultraviolet wavelength 310-410nm are carried out to terylene mesh by ultraviolet radiator;
Drying
In the environment of temperature is 55-65 °, terylene mesh is dried, drying time is 1-3 minutes;
Ultraviolet curing
Curing, ultraviolet wavelength 350-370nm are irradiated terylene mesh by ultraviolet light mercury lamp, irradiation time is
1-2 minutes.
As a kind of preferred structure of the present invention, in the direct-injection patterning step, water-borne UV-curing ink is by weight percentage
Meter includes:
UV cured printing inks 30%-50%/resin 25%-35%;
Ethylene glycol and/or propylene glycol 10%-30%;
Photoinitiator 1%-4%;
Pigment composition 3%-10%;
Water 10%-40%.
As a kind of preferred structure of the present invention, the pigment composition includes pigment and dispersant.
As a kind of preferred structure of the present invention, the ultraviolet radiator in the UV irradiation step is arranged on nozzle,
The direct-injection patterning step is synchronous with the UV irradiation step to carry out.
As a kind of preferred structure of the present invention, the ultraviolet curing step middle-ultraviolet lamp wavelength is 368nm.
The prior art is different from, water-borne UV-curing ink is sprayed on terylene mesh by above-mentioned technical proposal by nozzle, into
Row stamp;Terylene mesh can be attached to by water-borne UV-curing ink, the terylene mesh good hand touch after stamp, common stamp
It may feel that stencil, the technical program is exactly the feel of terylene mesh in itself.Without pre-treatment and post processing, without after
Situations such as hot setting of reason avoids elastic material contraction distortion, and 3D materials are driven plain.Convenient for the stamp on terylene mesh, print
Flower effect is good.
To achieve the above object, inventor additionally provides a kind of water-borne UV-curing ink direct-injection printing technology, including following
Step:
Direct-injection stamp
Water-borne UV-curing ink is sprayed on nylon cloth by nozzle, carries out stamp;
Ultraviolet light irradiates
Ultraviolet light irradiation, ultraviolet wavelength 310-410nm are carried out to nylon cloth by ultraviolet radiator;
Drying
In the environment of temperature is 55-65 °, nylon cloth is dried, drying time is 1-3 minutes;
Ultraviolet curing
Curing, ultraviolet wavelength 350-370nm are irradiated nylon cloth by ultraviolet light mercury lamp, irradiation time is
1-2 minutes.
As a kind of preferred structure of the present invention, in the direct-injection patterning step, water-borne UV-curing ink is by weight percentage
Meter includes:
UV cured printing inks 30%-50%/resin 25%-35%;
Ethylene glycol and/or propylene glycol 10%-30%;
Photoinitiator 1%-4%;
Pigment composition 3%-10%;
Water 10%-40%.
As a kind of preferred structure of the present invention, the pigment composition includes pigment and dispersant.
As a kind of preferred structure of the present invention, the ultraviolet radiator in the UV irradiation step is arranged on nozzle,
The direct-injection patterning step is synchronous with the UV irradiation step to carry out.
As a kind of preferred structure of the present invention, the ultraviolet curing step middle-ultraviolet lamp wavelength is 368nm.
The prior art is different from, water-borne UV-curing ink is sprayed on nylon cloth by above-mentioned technical proposal by nozzle, into
Row stamp;Nylon cloth can be attached to by water-borne UV-curing ink, the nylon cloth good hand touch after stamp, common stamp
It may feel that stencil, the technical program is exactly the feel of nylon cloth in itself.Without pre-treatment and post processing, without after
Situations such as hot setting of reason avoids elastic material contraction distortion, and 3D materials are driven plain.Convenient for the stamp on nylon cloth, print
Flower effect is good.
Specific embodiment
For the technology contents of technical solution, construction feature, the objects and the effects are described in detail, below in conjunction with specific reality
Example is applied to be explained in detail.
Embodiment one
A kind of water-borne UV-curing ink direct-injection printing technology, comprises the following steps:
Direct-injection stamp
Water-borne UV-curing ink is sprayed on terylene mesh by nozzle, carries out stamp;
Ultraviolet light irradiates
Ultraviolet light irradiation, ultraviolet wavelength 400nm are carried out to terylene mesh by ultraviolet radiator;
Drying
In the environment of temperature is 60 °, terylene mesh is dried, drying time is 2 minutes;
Ultraviolet curing
Curing, ultraviolet wavelength 368nm are irradiated terylene mesh by ultraviolet light mercury lamp, irradiation time is 1 point
30 seconds.
Further, in the present embodiment, water-borne UV-curing ink wraps by weight percentage in the direct-injection patterning step
It includes:
UV cured printing inks 40%;
Ethylene glycol 20%;
Photoinitiator 2%;
Pigment composition 7%;
Water 31%.
Following table is the data test form of water-borne UV-curing ink:
In numerous ink, the present embodiment selects water-borne UV-curing ink, has reached best performance.Laboratory is passed through
Test.Feel is fine, and common stamp may feel that stencil, present technology feel be exactly material in itself.
Further, in the present embodiment, the pigment composition includes pigment and dispersant, and pigment and dispersant press institute
Ratio is needed to mix, pigment composition is made.Pigment is powdered, and dyeing is used;Dispersant act as scattered pigment powder, reduces
Pigment powder precipitates.
Further, in the present embodiment, the ultraviolet radiator in the UV irradiation step is arranged on nozzle, described straight
Printing step is synchronous with the UV irradiation step to be carried out.In this way, ink levelling is controlled, so as to improve the picture of stamp
Element.
Further, in the present embodiment, the ultraviolet curing step middle-ultraviolet lamp wavelength is 368nm.In this way, further
Cure, to improve the adhesion strength of ink.
The prior art is distinguished, water-borne UV-curing ink is sprayed on terylene mesh by the present embodiment by nozzle, carries out stamp;
Good hand touch, common stamp may feel that stencil, and the technical program is exactly the feel of terylene mesh in itself.Without pre-treatment
And post processing, the hot setting not post-processed, elastic material contraction distortion is avoided, situations such as 3D materials are driven plain.Convenient for washing
Stamp on synthetic fibre screen cloth, printing quality are good.
Embodiment two
Difference lies in the purples with embodiment one for water-borne UV-curing ink direct-injection printing technology disclosed by the present embodiment
In outside line irradiating step, ultraviolet light irradiation, ultraviolet wavelength 310nm are carried out to terylene mesh by ultraviolet radiator.
Embodiment three
Difference lies in the purples with embodiment one for water-borne UV-curing ink direct-injection printing technology disclosed by the present embodiment
In outside line irradiating step, ultraviolet light irradiation, ultraviolet wavelength 410nm are carried out to terylene mesh by ultraviolet radiator.
Example IV
Difference lies in the bakings with embodiment one for water-borne UV-curing ink direct-injection printing technology disclosed by the present embodiment
In dry step, in the environment of temperature is 65 °, terylene mesh is dried, drying time is 1 minute.
Embodiment five
Difference lies in the bakings with embodiment one for water-borne UV-curing ink direct-injection printing technology disclosed by the present embodiment
In dry step, in the environment of temperature is 55 °, terylene mesh is dried, drying time is 3 minutes.
Embodiment six
Difference lies in the purples with embodiment one for water-borne UV-curing ink direct-injection printing technology disclosed by the present embodiment
In outside line curing schedule, curing is irradiated terylene mesh by ultraviolet light mercury lamp, ultraviolet wavelength 350nm, during irradiation
Between be 1 minute.
Embodiment seven
Difference lies in the purples with embodiment one for water-borne UV-curing ink direct-injection printing technology disclosed by the present embodiment
In outside line curing schedule, curing is irradiated terylene mesh by ultraviolet light mercury lamp, ultraviolet wavelength 370nm, during irradiation
Between be 3 minutes.
Embodiment eight
Difference lies in described straight with embodiment one for water-borne UV-curing ink direct-injection printing technology disclosed by the present embodiment
Water-borne UV-curing ink includes by weight percentage in printing step:
UV cured printing inks 30%;
Propylene glycol 30%;
Photoinitiator 4%;
Pigment composition 10%;
Water 26%.
Embodiment nine
Difference lies in described straight with embodiment one for water-borne UV-curing ink direct-injection printing technology disclosed by the present embodiment
Water-borne UV-curing ink includes by weight percentage in printing step:
UV cured printing inks 50%;
Ethylene glycol 5% and propylene glycol 5%;
Photoinitiator 1%;
Pigment composition 3%;
Water 36%.
Embodiment nine
Difference lies in Yi Zhongshui with embodiment one for water-borne UV-curing ink direct-injection printing technology disclosed by the present embodiment
Property UV cured printing ink direct-injection printing technologies, comprise the following steps:
Direct-injection stamp
Water-borne UV-curing ink is sprayed on nylon cloth by nozzle, carries out stamp;
Ultraviolet light irradiates
Ultraviolet light irradiation, ultraviolet wavelength 400nm are carried out to nylon cloth by ultraviolet radiator;
Drying
In the environment of temperature is 60 °, nylon cloth is dried, drying time is 2 minutes;
Ultraviolet curing
Curing, ultraviolet wavelength 368nm, irradiation time 1-2 are irradiated nylon cloth by ultraviolet light mercury lamp
Minute.
The prior art is distinguished, the present embodiment feel is fine, and common stamp may feel that stencil, present technology hand
It is sympathetic be material in itself.Pre-treatment and post processing is not required.The hot setting not post-processed avoids elastic material from shrinking and becomes
Situations such as shape, 3D materials are driven plain.This ink can be applicable on terylene and nylon material.
Embodiment ten
Difference lies in the purples with embodiment nine for water-borne UV-curing ink direct-injection printing technology disclosed by the present embodiment
In outside line irradiating step, ultraviolet light irradiation, ultraviolet wavelength 390nm are carried out to terylene mesh by ultraviolet radiator.
Embodiment 11
Difference lies in the purples with embodiment nine for water-borne UV-curing ink direct-injection printing technology disclosed by the present embodiment
In outside line irradiating step, ultraviolet light irradiation, ultraviolet wavelength 410nm are carried out to terylene mesh by ultraviolet radiator.
Embodiment 12
Difference lies in the bakings with embodiment nine for water-borne UV-curing ink direct-injection printing technology disclosed by the present embodiment
In dry step, in the environment of temperature is 65 °, terylene mesh is dried, drying time is 1 minute.
Embodiment 13
Difference lies in the bakings with embodiment nine for water-borne UV-curing ink direct-injection printing technology disclosed by the present embodiment
In dry step, in the environment of temperature is 55 °, terylene mesh is dried, drying time is 3 minutes.
Embodiment 14
Difference lies in the purples with embodiment nine for water-borne UV-curing ink direct-injection printing technology disclosed by the present embodiment
In outside line curing schedule, curing is irradiated terylene mesh by ultraviolet light mercury lamp, ultraviolet wavelength 350nm, during irradiation
Between be 1 minute.
Embodiment 15
Difference lies in the purples with embodiment nine for water-borne UV-curing ink direct-injection printing technology disclosed by the present embodiment
In outside line curing schedule, curing is irradiated terylene mesh by ultraviolet light mercury lamp, ultraviolet wavelength 370nm, during irradiation
Between be 3 minutes.
Embodiment 16
Difference lies in described straight with embodiment nine for water-borne UV-curing ink direct-injection printing technology disclosed by the present embodiment
Water-borne UV-curing ink includes by weight percentage in printing step:
UV cured printing inks 30%;
Propylene glycol 30%;
Photoinitiator 4%;
Pigment composition 10%;
Water 26%.
Embodiment 17
Difference lies in described straight with embodiment nine for water-borne UV-curing ink direct-injection printing technology disclosed by the present embodiment
Water-borne UV-curing ink includes by weight percentage in printing step:
UV cured printing inks 50%;
Ethylene glycol 5% and propylene glycol 5%;
Photoinitiator 1%;
Pigment composition 3%;
Water 36%.
It should be noted that herein, relational terms such as first and second and the like are used merely to a reality
Body or operation are distinguished with another entity or operation, are deposited without necessarily requiring or implying between these entities or operation
In any this actual relation or order.Moreover, term " comprising ", "comprising" or its any other variant are intended to
Non-exclusive inclusion, so that process, method, article or terminal device including a series of elements not only include those
Element, but also including other elements that are not explicitly listed or further include as this process, method, article or end
The intrinsic element of end equipment.In the absence of more restrictions, limited by sentence " including ... " or " including ... "
Element, it is not excluded that also there are other elements in the process including the element, method, article or terminal device.This
Outside, herein, " being more than ", " being less than ", " being more than " etc. are interpreted as not including this number;" more than ", " following ", " within " etc. understandings
It is to include this number.
Although the various embodiments described above are described, those skilled in the art once know basic wound
The property made concept can then make these embodiments other change and modification, so the foregoing is merely the embodiment of the present invention,
Not thereby the scope of patent protection of the present invention, every equivalent structure made using description of the invention or equivalent process are limited
Conversion, be directly or indirectly used in other related technical areas, be similarly included in the present invention scope of patent protection it
It is interior.
Claims (10)
1. a kind of water-borne UV-curing ink direct-injection printing technology, which is characterized in that comprise the following steps:
Direct-injection stamp
Water-borne UV-curing ink is sprayed on terylene mesh by nozzle, carries out stamp;
Ultraviolet light irradiates
Ultraviolet light irradiation, ultraviolet wavelength 310-410nm are carried out to terylene mesh by ultraviolet radiator;
Drying
In the environment of temperature is 55-65 °, terylene mesh is dried, drying time is 1-3 minutes;
Ultraviolet curing
Curing, ultraviolet wavelength 350-370nm, irradiation time 1-2 are irradiated terylene mesh by ultraviolet light mercury lamp
Minute.
2. water-borne UV-curing ink direct-injection printing technology according to claim 1, it is characterised in that:The direct-injection stamp step
Water-borne UV-curing ink includes by weight percentage in rapid:
UV cured printing inks 30%-50%/resin 25%-35%;
Ethylene glycol and/or propylene glycol 10%-30%;
Photoinitiator 1%-4%;
Pigment composition 3%-10%;
Water 10%-40%.
3. water-borne UV-curing ink direct-injection printing technology according to claim 2, it is characterised in that:The pigment composition
Including pigment and dispersant.
4. water-borne UV-curing ink direct-injection printing technology according to claim 1, it is characterised in that:The ultraviolet light irradiation
Ultraviolet radiator in step is arranged on nozzle, and the direct-injection patterning step is synchronous with the UV irradiation step to carry out.
5. water-borne UV-curing ink direct-injection printing technology according to claim 1, it is characterised in that:The ultraviolet curing
Step middle-ultraviolet lamp wavelength is 368nm.
6. a kind of water-borne UV-curing ink direct-injection printing technology, which is characterized in that comprise the following steps:
Direct-injection stamp
Water-borne UV-curing ink is sprayed on nylon cloth by nozzle, carries out stamp;
Ultraviolet light irradiates
Ultraviolet light irradiation, ultraviolet wavelength 310-410nm are carried out to nylon cloth by ultraviolet radiator;
Drying
In the environment of temperature is 55-65 °, nylon cloth is dried, drying time is 1-3 minutes;
Ultraviolet curing
Curing, ultraviolet wavelength 350-370nm, irradiation time 1-2 are irradiated nylon cloth by ultraviolet light mercury lamp
Minute.
7. water-borne UV-curing ink direct-injection printing technology according to claim 6, it is characterised in that:The direct-injection stamp step
Water-borne UV-curing ink includes by weight percentage in rapid:
UV cured printing inks 30%-50%/resin 25%-35%;
Ethylene glycol and/or propylene glycol 10%-30%;
Photoinitiator 1%-4%;
Pigment composition 3%-10%;
Water 10%-40%.
8. water-borne UV-curing ink direct-injection printing technology according to claim 7, it is characterised in that:The pigment composition
Including pigment and dispersant.
9. water-borne UV-curing ink direct-injection printing technology according to claim 6, it is characterised in that:The ultraviolet light irradiation
Ultraviolet radiator in step is arranged on nozzle, and the direct-injection patterning step is synchronous with the UV irradiation step to carry out.
10. water-borne UV-curing ink direct-injection printing technology according to claim 6, it is characterised in that:The ultraviolet light is consolidated
It is 368nm to change step middle-ultraviolet lamp wavelength.
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CN201711334963.5A CN108086026A (en) | 2017-12-14 | 2017-12-14 | A kind of water-borne UV-curing ink direct-injection printing technology |
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CN201711334963.5A CN108086026A (en) | 2017-12-14 | 2017-12-14 | A kind of water-borne UV-curing ink direct-injection printing technology |
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Cited By (5)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
CN110099790A (en) * | 2019-03-11 | 2019-08-06 | 福建华峰新材料有限公司 | A kind of composite material-feeding and its production method |
CN111909567A (en) * | 2020-08-12 | 2020-11-10 | 福建华峰运动用品科技有限公司 | Water-based UV (ultraviolet) curing ink, preparation method and 3D (three-dimensional) pattern fabric using ink |
CN113123146A (en) * | 2021-05-27 | 2021-07-16 | 东莞市粤雄纺织品有限公司 | Waterless dyeing preparation method of temperature/ultraviolet light color-changing yarn |
CN114703684A (en) * | 2022-04-12 | 2022-07-05 | 绍兴市柯桥区信和数码纺织技术有限公司 | Printing process of ultrathin fabric |
CN115260833A (en) * | 2022-07-19 | 2022-11-01 | 苏州大学 | Direct-injection printing ink and preparation method and application thereof |
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CN101665643A (en) * | 2009-09-18 | 2010-03-10 | 林国顺 | Ultraviolet curing pearl ink |
CN102286230A (en) * | 2011-09-15 | 2011-12-21 | 哈尔滨大东方卷烟材料科技开发有限责任公司 | Ultraviolet curable ink and preparation method thereof |
CN103160168A (en) * | 2011-12-12 | 2013-06-19 | 中国科学院化学研究所 | Waterborne UV-curable ink used in inkjet printing direct-to-plate, and preparation method and application thereof |
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CN101050325A (en) * | 2007-03-12 | 2007-10-10 | 佛山市儒林化工有限公司 | Environmental protection type tin printing ink solidified by ultraviolet light |
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Cited By (5)
Publication number | Priority date | Publication date | Assignee | Title |
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CN110099790A (en) * | 2019-03-11 | 2019-08-06 | 福建华峰新材料有限公司 | A kind of composite material-feeding and its production method |
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CN113123146A (en) * | 2021-05-27 | 2021-07-16 | 东莞市粤雄纺织品有限公司 | Waterless dyeing preparation method of temperature/ultraviolet light color-changing yarn |
CN114703684A (en) * | 2022-04-12 | 2022-07-05 | 绍兴市柯桥区信和数码纺织技术有限公司 | Printing process of ultrathin fabric |
CN115260833A (en) * | 2022-07-19 | 2022-11-01 | 苏州大学 | Direct-injection printing ink and preparation method and application thereof |
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