CN113062129A - Natural dye ink-jet transfer printing ink and application method thereof - Google Patents
Natural dye ink-jet transfer printing ink and application method thereof Download PDFInfo
- Publication number
- CN113062129A CN113062129A CN202110427724.4A CN202110427724A CN113062129A CN 113062129 A CN113062129 A CN 113062129A CN 202110427724 A CN202110427724 A CN 202110427724A CN 113062129 A CN113062129 A CN 113062129A
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- transfer printing
- ink
- fabric
- natural dye
- film
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Links
- 238000010023 transfer printing Methods 0.000 title claims abstract description 144
- 229930182559 Natural dye Natural products 0.000 title claims abstract description 46
- 239000000978 natural dye Substances 0.000 title claims abstract description 46
- 238000000034 method Methods 0.000 title claims abstract description 31
- 239000004744 fabric Substances 0.000 claims abstract description 138
- XLYOFNOQVPJJNP-UHFFFAOYSA-N water Chemical compound O XLYOFNOQVPJJNP-UHFFFAOYSA-N 0.000 claims abstract description 77
- 238000007639 printing Methods 0.000 claims abstract description 45
- 239000011248 coating agent Substances 0.000 claims abstract description 43
- 238000012546 transfer Methods 0.000 claims abstract description 31
- 239000008367 deionised water Substances 0.000 claims abstract description 27
- 229910021641 deionized water Inorganic materials 0.000 claims abstract description 27
- 108010039918 Polylysine Proteins 0.000 claims abstract description 26
- 229920000656 polylysine Polymers 0.000 claims abstract description 26
- 239000003381 stabilizer Substances 0.000 claims abstract description 19
- 239000002738 chelating agent Substances 0.000 claims abstract description 18
- 239000003906 humectant Substances 0.000 claims abstract description 18
- 239000004094 surface-active agent Substances 0.000 claims abstract description 18
- 238000000576 coating method Methods 0.000 claims abstract description 15
- 239000007864 aqueous solution Substances 0.000 claims abstract description 13
- 229920002799 BoPET Polymers 0.000 claims abstract description 9
- 239000011127 biaxially oriented polypropylene Substances 0.000 claims abstract description 8
- 229920006378 biaxially oriented polypropylene Polymers 0.000 claims abstract description 8
- LFQSCWFLJHTTHZ-UHFFFAOYSA-N Ethanol Chemical group CCO LFQSCWFLJHTTHZ-UHFFFAOYSA-N 0.000 claims description 26
- 238000001914 filtration Methods 0.000 claims description 24
- 239000011148 porous material Substances 0.000 claims description 24
- 238000009736 wetting Methods 0.000 claims description 24
- LYCAIKOWRPUZTN-UHFFFAOYSA-N Ethylene glycol Chemical compound OCCO LYCAIKOWRPUZTN-UHFFFAOYSA-N 0.000 claims description 21
- PEDCQBHIVMGVHV-UHFFFAOYSA-N Glycerine Chemical compound OCC(O)CO PEDCQBHIVMGVHV-UHFFFAOYSA-N 0.000 claims description 21
- 238000005507 spraying Methods 0.000 claims description 16
- 238000010025 steaming Methods 0.000 claims description 16
- 239000007788 liquid Substances 0.000 claims description 15
- 239000002904 solvent Substances 0.000 claims description 13
- 238000003756 stirring Methods 0.000 claims description 13
- GSEJCLTVZPLZKY-UHFFFAOYSA-N Triethanolamine Chemical compound OCCN(CCO)CCO GSEJCLTVZPLZKY-UHFFFAOYSA-N 0.000 claims description 12
- 238000009835 boiling Methods 0.000 claims description 12
- 238000011049 filling Methods 0.000 claims description 12
- LNTHITQWFMADLM-UHFFFAOYSA-N gallic acid Chemical compound OC(=O)C1=CC(O)=C(O)C(O)=C1 LNTHITQWFMADLM-UHFFFAOYSA-N 0.000 claims description 12
- 238000007789 sealing Methods 0.000 claims description 12
- 239000007921 spray Substances 0.000 claims description 12
- GVJHHUAWPYXKBD-IEOSBIPESA-N α-tocopherol Chemical compound OC1=C(C)C(C)=C2O[C@@](CCC[C@H](C)CCC[C@H](C)CCCC(C)C)(C)CCC2=C1C GVJHHUAWPYXKBD-IEOSBIPESA-N 0.000 claims description 12
- 229920000742 Cotton Polymers 0.000 claims description 9
- MTHSVFCYNBDYFN-UHFFFAOYSA-N diethylene glycol Chemical compound OCCOCCO MTHSVFCYNBDYFN-UHFFFAOYSA-N 0.000 claims description 9
- ZGTMUACCHSMWAC-UHFFFAOYSA-L EDTA disodium salt (anhydrous) Chemical group [Na+].[Na+].OC(=O)CN(CC([O-])=O)CCN(CC(O)=O)CC([O-])=O ZGTMUACCHSMWAC-UHFFFAOYSA-L 0.000 claims description 8
- 238000005096 rolling process Methods 0.000 claims description 8
- 244000163122 Curcuma domestica Species 0.000 claims description 7
- 235000003392 Curcuma domestica Nutrition 0.000 claims description 7
- -1 alkyl glycoside Chemical class 0.000 claims description 7
- 235000003373 curcuma longa Nutrition 0.000 claims description 7
- 229930182470 glycoside Natural products 0.000 claims description 7
- 235000013976 turmeric Nutrition 0.000 claims description 7
- 229940087168 alpha tocopherol Drugs 0.000 claims description 6
- 229940074391 gallic acid Drugs 0.000 claims description 6
- 235000004515 gallic acid Nutrition 0.000 claims description 6
- ZQBAKBUEJOMQEX-UHFFFAOYSA-N phenyl salicylate Chemical compound OC1=CC=CC=C1C(=O)OC1=CC=CC=C1 ZQBAKBUEJOMQEX-UHFFFAOYSA-N 0.000 claims description 6
- 229940051841 polyoxyethylene ether Drugs 0.000 claims description 6
- 229920000056 polyoxyethylene ether Polymers 0.000 claims description 6
- 229960000984 tocofersolan Drugs 0.000 claims description 6
- QAIPRVGONGVQAS-DUXPYHPUSA-N trans-caffeic acid Chemical compound OC(=O)\C=C\C1=CC=C(O)C(O)=C1 QAIPRVGONGVQAS-DUXPYHPUSA-N 0.000 claims description 6
- 238000005406 washing Methods 0.000 claims description 6
- 239000002076 α-tocopherol Substances 0.000 claims description 6
- 235000004835 α-tocopherol Nutrition 0.000 claims description 6
- DBMJMQXJHONAFJ-UHFFFAOYSA-M Sodium laurylsulphate Chemical compound [Na+].CCCCCCCCCCCCOS([O-])(=O)=O DBMJMQXJHONAFJ-UHFFFAOYSA-M 0.000 claims description 5
- 238000001035 drying Methods 0.000 claims description 5
- 230000008569 process Effects 0.000 claims description 5
- 241000228347 Monascus <ascomycete fungus> Species 0.000 claims description 4
- ACEAELOMUCBPJP-UHFFFAOYSA-N (E)-3,4,5-trihydroxycinnamic acid Natural products OC(=O)C=CC1=CC(O)=C(O)C(O)=C1 ACEAELOMUCBPJP-UHFFFAOYSA-N 0.000 claims description 3
- 235000007688 Lycopersicon esculentum Nutrition 0.000 claims description 3
- 229920000297 Rayon Polymers 0.000 claims description 3
- 240000003768 Solanum lycopersicum Species 0.000 claims description 3
- 229940074360 caffeic acid Drugs 0.000 claims description 3
- 235000004883 caffeic acid Nutrition 0.000 claims description 3
- QAIPRVGONGVQAS-UHFFFAOYSA-N cis-caffeic acid Natural products OC(=O)C=CC1=CC=C(O)C(O)=C1 QAIPRVGONGVQAS-UHFFFAOYSA-N 0.000 claims description 3
- HWDGVJUIHRPKFR-UHFFFAOYSA-I copper;trisodium;18-(2-carboxylatoethyl)-20-(carboxylatomethyl)-12-ethenyl-7-ethyl-3,8,13,17-tetramethyl-17,18-dihydroporphyrin-21,23-diide-2-carboxylate Chemical compound [Na+].[Na+].[Na+].[Cu+2].N1=C(C(CC([O-])=O)=C2C(C(C)C(C=C3C(=C(C=C)C(=C4)[N-]3)C)=N2)CCC([O-])=O)C(=C([O-])[O-])C(C)=C1C=C1C(CC)=C(C)C4=N1 HWDGVJUIHRPKFR-UHFFFAOYSA-I 0.000 claims description 3
- 229960000969 phenyl salicylate Drugs 0.000 claims description 3
- 235000013758 sodium copper chlorophyllin Nutrition 0.000 claims description 3
- 229940079841 sodium copper chlorophyllin Drugs 0.000 claims description 3
- FWVCSXWHVOOTFJ-UHFFFAOYSA-N 1-(2-chloroethylsulfanyl)-2-[2-(2-chloroethylsulfanyl)ethoxy]ethane Chemical compound ClCCSCCOCCSCCCl FWVCSXWHVOOTFJ-UHFFFAOYSA-N 0.000 claims description 2
- SEBIKDIMAPSUBY-ARYZWOCPSA-N Crocin Chemical compound C([C@H]1O[C@H]([C@@H]([C@@H](O)[C@@H]1O)O)OC(=O)C(C)=CC=CC(C)=C\C=C\C=C(/C)\C=C\C=C(C)C(=O)O[C@H]1[C@@H]([C@@H](O)[C@H](O)[C@@H](CO[C@H]2[C@@H]([C@@H](O)[C@H](O)[C@@H](CO)O2)O)O1)O)O[C@@H]1O[C@H](CO)[C@@H](O)[C@H](O)[C@H]1O SEBIKDIMAPSUBY-ARYZWOCPSA-N 0.000 claims description 2
- 240000001972 Gardenia jasminoides Species 0.000 claims description 2
- 235000012730 carminic acid Nutrition 0.000 claims description 2
- 239000004106 carminic acid Substances 0.000 claims description 2
- 229940080423 cochineal Drugs 0.000 claims description 2
- 235000019864 coconut oil Nutrition 0.000 claims description 2
- 239000003240 coconut oil Substances 0.000 claims description 2
- 235000014113 dietary fatty acids Nutrition 0.000 claims description 2
- 239000000194 fatty acid Substances 0.000 claims description 2
- 229930195729 fatty acid Natural products 0.000 claims description 2
- 150000004665 fatty acids Chemical class 0.000 claims description 2
- 239000009627 gardenia yellow Substances 0.000 claims description 2
- 239000012982 microporous membrane Substances 0.000 claims 2
- KFDNQUWMBLVQNB-UHFFFAOYSA-N 2-[2-[bis(carboxymethyl)amino]ethyl-(carboxymethyl)amino]acetic acid;sodium Chemical compound [Na].[Na].[Na].[Na].OC(=O)CN(CC(O)=O)CCN(CC(O)=O)CC(O)=O KFDNQUWMBLVQNB-UHFFFAOYSA-N 0.000 claims 1
- 229920001800 Shellac Polymers 0.000 claims 1
- 150000002191 fatty alcohols Chemical class 0.000 claims 1
- 239000000203 mixture Substances 0.000 claims 1
- 230000035515 penetration Effects 0.000 claims 1
- 239000004208 shellac Substances 0.000 claims 1
- ZLGIYFNHBLSMPS-ATJNOEHPSA-N shellac Chemical compound OCCCCCC(O)C(O)CCCCCCCC(O)=O.C1C23[C@H](C(O)=O)CCC2[C@](C)(CO)[C@@H]1C(C(O)=O)=C[C@@H]3O ZLGIYFNHBLSMPS-ATJNOEHPSA-N 0.000 claims 1
- 229940113147 shellac Drugs 0.000 claims 1
- 235000013874 shellac Nutrition 0.000 claims 1
- 239000004753 textile Substances 0.000 abstract description 8
- 238000005516 engineering process Methods 0.000 abstract description 4
- 230000008859 change Effects 0.000 abstract description 3
- 229910021645 metal ion Inorganic materials 0.000 abstract description 3
- 239000012528 membrane Substances 0.000 description 22
- 238000001471 micro-filtration Methods 0.000 description 22
- 230000000052 comparative effect Effects 0.000 description 14
- 238000011068 loading method Methods 0.000 description 12
- 238000003825 pressing Methods 0.000 description 11
- 230000005856 abnormality Effects 0.000 description 8
- 238000012360 testing method Methods 0.000 description 8
- 238000004043 dyeing Methods 0.000 description 6
- UEUXEKPTXMALOB-UHFFFAOYSA-J tetrasodium;2-[2-[bis(carboxylatomethyl)amino]ethyl-(carboxylatomethyl)amino]acetate Chemical compound [Na+].[Na+].[Na+].[Na+].[O-]C(=O)CN(CC([O-])=O)CCN(CC([O-])=O)CC([O-])=O UEUXEKPTXMALOB-UHFFFAOYSA-J 0.000 description 6
- 229920001661 Chitosan Polymers 0.000 description 5
- 239000000243 solution Substances 0.000 description 5
- 238000002791 soaking Methods 0.000 description 4
- HEMHJVSKTPXQMS-UHFFFAOYSA-M Sodium hydroxide Chemical compound [OH-].[Na+] HEMHJVSKTPXQMS-UHFFFAOYSA-M 0.000 description 3
- KRKNYBCHXYNGOX-UHFFFAOYSA-N citric acid group Chemical group C(CC(O)(C(=O)O)CC(=O)O)(=O)O KRKNYBCHXYNGOX-UHFFFAOYSA-N 0.000 description 3
- 239000000975 dye Substances 0.000 description 3
- 239000000835 fiber Substances 0.000 description 3
- 238000007641 inkjet printing Methods 0.000 description 3
- 150000002500 ions Chemical group 0.000 description 3
- VZSRBBMJRBPUNF-UHFFFAOYSA-N 2-(2,3-dihydro-1H-inden-2-ylamino)-N-[3-oxo-3-(2,4,6,7-tetrahydrotriazolo[4,5-c]pyridin-5-yl)propyl]pyrimidine-5-carboxamide Chemical compound C1C(CC2=CC=CC=C12)NC1=NC=C(C=N1)C(=O)NCCC(N1CC2=C(CC1)NN=N2)=O VZSRBBMJRBPUNF-UHFFFAOYSA-N 0.000 description 2
- 239000003109 Disodium ethylene diamine tetraacetate Substances 0.000 description 2
- 241000196324 Embryophyta Species 0.000 description 2
- 230000002159 abnormal effect Effects 0.000 description 2
- 230000009286 beneficial effect Effects 0.000 description 2
- 239000003086 colorant Substances 0.000 description 2
- 235000019301 disodium ethylene diamine tetraacetate Nutrition 0.000 description 2
- 230000006872 improvement Effects 0.000 description 2
- XEEYBQQBJWHFJM-UHFFFAOYSA-N iron Substances [Fe] XEEYBQQBJWHFJM-UHFFFAOYSA-N 0.000 description 2
- 238000004519 manufacturing process Methods 0.000 description 2
- 238000000643 oven drying Methods 0.000 description 2
- 239000012466 permeate Substances 0.000 description 2
- LRWZZZWJMFNZIK-UHFFFAOYSA-N 2-chloro-3-methyloxirane Chemical compound CC1OC1Cl LRWZZZWJMFNZIK-UHFFFAOYSA-N 0.000 description 1
- YLZOPXRUQYQQID-UHFFFAOYSA-N 3-(2,4,6,7-tetrahydrotriazolo[4,5-c]pyridin-5-yl)-1-[4-[2-[[3-(trifluoromethoxy)phenyl]methylamino]pyrimidin-5-yl]piperazin-1-yl]propan-1-one Chemical compound N1N=NC=2CN(CCC=21)CCC(=O)N1CCN(CC1)C=1C=NC(=NC=1)NCC1=CC(=CC=C1)OC(F)(F)F YLZOPXRUQYQQID-UHFFFAOYSA-N 0.000 description 1
- 229920003043 Cellulose fiber Polymers 0.000 description 1
- XSQUKJJJFZCRTK-UHFFFAOYSA-N Urea Chemical compound NC(N)=O XSQUKJJJFZCRTK-UHFFFAOYSA-N 0.000 description 1
- 238000010521 absorption reaction Methods 0.000 description 1
- 239000000980 acid dye Substances 0.000 description 1
- 150000001450 anions Chemical class 0.000 description 1
- 229960000892 attapulgite Drugs 0.000 description 1
- 239000004202 carbamide Substances 0.000 description 1
- 150000001768 cations Chemical class 0.000 description 1
- 239000006103 coloring component Substances 0.000 description 1
- 230000006196 deacetylation Effects 0.000 description 1
- 238000003381 deacetylation reaction Methods 0.000 description 1
- 239000000986 disperse dye Substances 0.000 description 1
- 239000012153 distilled water Substances 0.000 description 1
- 238000007646 gravure printing Methods 0.000 description 1
- 238000002347 injection Methods 0.000 description 1
- 239000007924 injection Substances 0.000 description 1
- 229910052500 inorganic mineral Inorganic materials 0.000 description 1
- 229910052742 iron Inorganic materials 0.000 description 1
- 238000005259 measurement Methods 0.000 description 1
- 239000011707 mineral Substances 0.000 description 1
- 229910052625 palygorskite Inorganic materials 0.000 description 1
- 230000000149 penetrating effect Effects 0.000 description 1
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- 238000001556 precipitation Methods 0.000 description 1
- 238000002360 preparation method Methods 0.000 description 1
- 238000012545 processing Methods 0.000 description 1
- 230000036632 reaction speed Effects 0.000 description 1
- 239000000985 reactive dye Substances 0.000 description 1
- 239000000126 substance Substances 0.000 description 1
- 239000002562 thickening agent Substances 0.000 description 1
- 235000013311 vegetables Nutrition 0.000 description 1
- 238000004804 winding Methods 0.000 description 1
- 229910052724 xenon Inorganic materials 0.000 description 1
- FHNFHKCVQCLJFQ-UHFFFAOYSA-N xenon atom Chemical compound [Xe] FHNFHKCVQCLJFQ-UHFFFAOYSA-N 0.000 description 1
Images
Classifications
-
- D—TEXTILES; PAPER
- D06—TREATMENT OF TEXTILES OR THE LIKE; LAUNDERING; FLEXIBLE MATERIALS NOT OTHERWISE PROVIDED FOR
- D06P—DYEING OR PRINTING TEXTILES; DYEING LEATHER, FURS OR SOLID MACROMOLECULAR SUBSTANCES IN ANY FORM
- D06P1/00—General processes of dyeing or printing textiles, or general processes of dyeing leather, furs, or solid macromolecular substances in any form, classified according to the dyes, pigments, or auxiliary substances employed
- D06P1/34—General processes of dyeing or printing textiles, or general processes of dyeing leather, furs, or solid macromolecular substances in any form, classified according to the dyes, pigments, or auxiliary substances employed using natural dyestuffs
-
- C—CHEMISTRY; METALLURGY
- C09—DYES; PAINTS; POLISHES; NATURAL RESINS; ADHESIVES; COMPOSITIONS NOT OTHERWISE PROVIDED FOR; APPLICATIONS OF MATERIALS NOT OTHERWISE PROVIDED FOR
- C09D—COATING COMPOSITIONS, e.g. PAINTS, VARNISHES OR LACQUERS; FILLING PASTES; CHEMICAL PAINT OR INK REMOVERS; INKS; CORRECTING FLUIDS; WOODSTAINS; PASTES OR SOLIDS FOR COLOURING OR PRINTING; USE OF MATERIALS THEREFOR
- C09D105/00—Coating compositions based on polysaccharides or on their derivatives, not provided for in groups C09D101/00 or C09D103/00
-
- C—CHEMISTRY; METALLURGY
- C09—DYES; PAINTS; POLISHES; NATURAL RESINS; ADHESIVES; COMPOSITIONS NOT OTHERWISE PROVIDED FOR; APPLICATIONS OF MATERIALS NOT OTHERWISE PROVIDED FOR
- C09D—COATING COMPOSITIONS, e.g. PAINTS, VARNISHES OR LACQUERS; FILLING PASTES; CHEMICAL PAINT OR INK REMOVERS; INKS; CORRECTING FLUIDS; WOODSTAINS; PASTES OR SOLIDS FOR COLOURING OR PRINTING; USE OF MATERIALS THEREFOR
- C09D7/00—Features of coating compositions, not provided for in group C09D5/00; Processes for incorporating ingredients in coating compositions
- C09D7/40—Additives
- C09D7/60—Additives non-macromolecular
- C09D7/61—Additives non-macromolecular inorganic
-
- C—CHEMISTRY; METALLURGY
- C09—DYES; PAINTS; POLISHES; NATURAL RESINS; ADHESIVES; COMPOSITIONS NOT OTHERWISE PROVIDED FOR; APPLICATIONS OF MATERIALS NOT OTHERWISE PROVIDED FOR
- C09D—COATING COMPOSITIONS, e.g. PAINTS, VARNISHES OR LACQUERS; FILLING PASTES; CHEMICAL PAINT OR INK REMOVERS; INKS; CORRECTING FLUIDS; WOODSTAINS; PASTES OR SOLIDS FOR COLOURING OR PRINTING; USE OF MATERIALS THEREFOR
- C09D7/00—Features of coating compositions, not provided for in group C09D5/00; Processes for incorporating ingredients in coating compositions
- C09D7/40—Additives
- C09D7/60—Additives non-macromolecular
- C09D7/63—Additives non-macromolecular organic
-
- D—TEXTILES; PAPER
- D06—TREATMENT OF TEXTILES OR THE LIKE; LAUNDERING; FLEXIBLE MATERIALS NOT OTHERWISE PROVIDED FOR
- D06P—DYEING OR PRINTING TEXTILES; DYEING LEATHER, FURS OR SOLID MACROMOLECULAR SUBSTANCES IN ANY FORM
- D06P1/00—General processes of dyeing or printing textiles, or general processes of dyeing leather, furs, or solid macromolecular substances in any form, classified according to the dyes, pigments, or auxiliary substances employed
- D06P1/0004—General aspects of dyeing
- D06P1/0016—Dye baths containing a dyeing agent in a special form such as for instance in melted or solid form, as a floating film or gel, spray or aerosol, or atomised dyes
-
- D—TEXTILES; PAPER
- D06—TREATMENT OF TEXTILES OR THE LIKE; LAUNDERING; FLEXIBLE MATERIALS NOT OTHERWISE PROVIDED FOR
- D06P—DYEING OR PRINTING TEXTILES; DYEING LEATHER, FURS OR SOLID MACROMOLECULAR SUBSTANCES IN ANY FORM
- D06P1/00—General processes of dyeing or printing textiles, or general processes of dyeing leather, furs, or solid macromolecular substances in any form, classified according to the dyes, pigments, or auxiliary substances employed
- D06P1/44—General processes of dyeing or printing textiles, or general processes of dyeing leather, furs, or solid macromolecular substances in any form, classified according to the dyes, pigments, or auxiliary substances employed using insoluble pigments or auxiliary substances, e.g. binders
- D06P1/64—General processes of dyeing or printing textiles, or general processes of dyeing leather, furs, or solid macromolecular substances in any form, classified according to the dyes, pigments, or auxiliary substances employed using insoluble pigments or auxiliary substances, e.g. binders using compositions containing low-molecular-weight organic compounds without sulfate or sulfonate groups
- D06P1/642—Compounds containing nitrogen
- D06P1/647—Nitrogen-containing carboxylic acids or their salts
-
- D—TEXTILES; PAPER
- D06—TREATMENT OF TEXTILES OR THE LIKE; LAUNDERING; FLEXIBLE MATERIALS NOT OTHERWISE PROVIDED FOR
- D06P—DYEING OR PRINTING TEXTILES; DYEING LEATHER, FURS OR SOLID MACROMOLECULAR SUBSTANCES IN ANY FORM
- D06P1/00—General processes of dyeing or printing textiles, or general processes of dyeing leather, furs, or solid macromolecular substances in any form, classified according to the dyes, pigments, or auxiliary substances employed
- D06P1/44—General processes of dyeing or printing textiles, or general processes of dyeing leather, furs, or solid macromolecular substances in any form, classified according to the dyes, pigments, or auxiliary substances employed using insoluble pigments or auxiliary substances, e.g. binders
- D06P1/64—General processes of dyeing or printing textiles, or general processes of dyeing leather, furs, or solid macromolecular substances in any form, classified according to the dyes, pigments, or auxiliary substances employed using insoluble pigments or auxiliary substances, e.g. binders using compositions containing low-molecular-weight organic compounds without sulfate or sulfonate groups
- D06P1/651—Compounds without nitrogen
- D06P1/65106—Oxygen-containing compounds
- D06P1/65118—Compounds containing hydroxyl groups
-
- D—TEXTILES; PAPER
- D06—TREATMENT OF TEXTILES OR THE LIKE; LAUNDERING; FLEXIBLE MATERIALS NOT OTHERWISE PROVIDED FOR
- D06P—DYEING OR PRINTING TEXTILES; DYEING LEATHER, FURS OR SOLID MACROMOLECULAR SUBSTANCES IN ANY FORM
- D06P5/00—Other features in dyeing or printing textiles, or dyeing leather, furs, or solid macromolecular substances in any form
- D06P5/003—Transfer printing
-
- D—TEXTILES; PAPER
- D06—TREATMENT OF TEXTILES OR THE LIKE; LAUNDERING; FLEXIBLE MATERIALS NOT OTHERWISE PROVIDED FOR
- D06P—DYEING OR PRINTING TEXTILES; DYEING LEATHER, FURS OR SOLID MACROMOLECULAR SUBSTANCES IN ANY FORM
- D06P5/00—Other features in dyeing or printing textiles, or dyeing leather, furs, or solid macromolecular substances in any form
- D06P5/02—After-treatment
- D06P5/04—After-treatment with organic compounds
- D06P5/08—After-treatment with organic compounds macromolecular
-
- D—TEXTILES; PAPER
- D06—TREATMENT OF TEXTILES OR THE LIKE; LAUNDERING; FLEXIBLE MATERIALS NOT OTHERWISE PROVIDED FOR
- D06P—DYEING OR PRINTING TEXTILES; DYEING LEATHER, FURS OR SOLID MACROMOLECULAR SUBSTANCES IN ANY FORM
- D06P5/00—Other features in dyeing or printing textiles, or dyeing leather, furs, or solid macromolecular substances in any form
- D06P5/30—Ink jet printing
Landscapes
- Engineering & Computer Science (AREA)
- Chemical & Material Sciences (AREA)
- Textile Engineering (AREA)
- Life Sciences & Earth Sciences (AREA)
- Materials Engineering (AREA)
- Wood Science & Technology (AREA)
- Organic Chemistry (AREA)
- Dispersion Chemistry (AREA)
- Inorganic Chemistry (AREA)
- Coloring (AREA)
Abstract
The invention provides natural dye ink-jet transfer printing ink and an application method thereof, wherein the transfer printing ink comprises the following components in parts by mass: 5-15% of natural dye, 15-30% of humectant, 0.5-1.0% of stabilizer, 0.1-0.5% of surfactant, 0.1-0.5% of chelating agent and the balance of deionized water. Printing ink on a PET film or a BOPP film coated with an ink-absorbing coating, and then transferring the pattern to a textile by a wet transfer printing technology; the polylysine aqueous solution is adopted to carry out color fixation treatment on the printed fabric, so that the natural dye transfer printed fabric with excellent color fastness is obtained, and the problems of serious color change and dark color caused by metal ion mordant treatment are avoided.
Description
Technical Field
The invention belongs to the technical field of textiles, and particularly relates to natural dye ink-jet transfer printing ink and an application method thereof.
Background
The transfer printing is a printing technology that patterns are printed on transfer printing paper firstly, then the patterns are transferred from the transfer printing paper to the textile under certain conditions, and the patterns are fixed and formed. Compared with the traditional printing mode, the printing pattern of the technology is clear and vivid, the printing and dyeing period is short, the processing mode is flexible, and the reaction speed to the market is high. Whether the transfer printing is the hot transfer printing or the cold transfer printing, the production of the transfer printing paper mostly adopts a gravure printing mode, and the production of the transfer printing paper rarely adopts an ink-jet printing mode. The colorant mainly comprises disperse dye, acid dye and reactive dye.
Disclosure of Invention
The invention provides natural dye ink-jet transfer printing ink and an application method thereof. The method comprises the steps of adopting an ink-jet printing mode to spray-print patterns on a transfer printing film coated with an ink absorption coating, transferring the patterns to a textile through wet-state pressure applying transfer printing, and then steaming and fixing the colors to obtain the natural dye transfer printing textile with excellent fastness.
The natural dye ink-jet transfer printing ink provided by the invention comprises the following components in parts by mass: 5-15% of natural dye, 15-30% of humectant, 0.5-1.0% of stabilizer, 0.1-0.5% of surfactant, 0.1-0.5% of chelating agent and the balance of deionized water.
The natural dye is one of gardenia yellow, turmeric, monascus yellow, monascus red, cochineal red, tomato red, lac red, sodium copper chlorophyllin and gardenia blue.
The humectant consists of a high-boiling point solvent and a low-boiling point solvent, wherein the low-boiling point solvent is ethanol, and the high-boiling point solvent is one of ethylene glycol, glycerol and diethylene glycol; the mass ratio of the low-boiling point solvent to the high-boiling point solvent is 1:1-1: 3.
The stabilizer is one of alpha-tocopherol, gallic acid, caffeic acid and phenyl salicylate.
The surfactant is one or more of alkyl glycoside, fatty alcohol-polyoxyethylene ether, coconut oil fatty acid diethanolamide, rapid penetrant T, sodium dodecyl sulfate and sodium dodecyl sulfate.
The chelating agent is disodium ethylene diamine tetraacetate or tetrasodium ethylene diamine tetraacetate.
The preparation method of the natural dye ink-jet transfer printing ink comprises the following steps: adding the natural dye, the humectant, the stabilizer, the surfactant and the chelating agent into deionized water, fully stirring at the rotation speed of 300rad/min of 100-.
The physical and chemical indexes of the natural dye ink-jet transfer printing ink are as follows: the viscosity is 3-4mpa · s, the surface tension is 25-40mN/m, and the conductivity is 4-7 ms/cm.
The invention also provides an application method of the natural dye ink-jet transfer printing ink, which comprises the following steps:
(1) preparing a transfer film: uniformly coating the prepared coating agent on a PET film or a BOPP film, and airing for later use;
wherein the coating agent comprises the following components in parts by mass:
(2) transfer printing and steaming: loading the prepared ink into an ink box, and printing a pattern on a transfer film by using an EPSON R330 color ink-jet printer, wherein the resolution is set to be 300 dpi; adopting a spraying device to spray and uniformly wet a single surface of a bleached fabric, controlling the liquid carrying rate of the fabric to be 40-50%, and balancing for 3-5min for later use after wetting; closely attaching the printing surface of the transfer printing film to the wetting surface of the fabric, rolling and transferring by a flat panel pyrograph, after the transfer printing is finished, uncovering the film from the surface of the fabric, and steaming the transfer printing fabric for 15-45min at the temperature of 102-105 ℃.
(3) And (3) treatment: and (3) washing the steamed fabric in the step (2) once by warm water and cold water at 50 ℃, immersing the fabric into a polylysine aqueous solution with the mass concentration of 2-5g/L, fixing the color at 60-90 ℃ for 30-60min, washing the fabric twice by the warm water and the cold water at 50 ℃ after the treatment is finished, and drying the fabric at 60-80 ℃.
Wherein the attapulgite in the step (1) is PalyGel 325 provided by Anhui Mingmei mineral chemical Co.
The fabric in the step (2) is one of pure cotton fabric, linen fabric, silk fabric and viscose fabric, and the rolling transfer pressure is 3-5kg/cm2The transfer time is 30-60 s.
The molecular weight of the polylysine in the step (3) is 3600-4300.
The ink-jet transfer printing technology provided by the invention well solves the problem that the fluff on the fabric is easy to damage a nozzle in direct injection printing; natural dye is used as a coloring component, and the light resistance of the ink and the printed fabric thereof is improved by adding a stabilizer; the urea is added into the coating agent to realize low quantitative supply, and meanwhile, the inorganic thickening agent is added to reduce the affinity of the coating agent and the film and also facilitate paste removal after transfer printing; the single side of the fabric is wetted by adopting a spraying mode, so that the problem that the printed pattern is not clear in outline due to too high humidity is solved; the polylysine is adopted to perform color fixation treatment on the printed fabric, so that the problems of serious color change and dark color caused by metal ion mordant treatment are solved.
The invention has the beneficial effects that:
(1) the natural dye printing is realized by adopting an ink-jet transfer printing mode, and the problems that pretreatment conditions are difficult to control and fiber fluff is easy to damage a spray head when the ink-jet printing faces different fabrics are solved.
(2) The characteristics that polylysine is rich in cations and has strong electrostatic acting force with natural dye with anions are utilized to carry out color fixing treatment on printed fabrics, so that the influence of metal ion mordant on the color light of the natural dye is avoided; and the polylysine has better water solubility and smaller molecular weight, and is easy to permeate into the fabric.
Drawings
FIG. 1 is a schematic view of a single-sided wet-laid printed pattern profile;
FIG. 2 is a schematic view of a double-sided wet-laid print pattern profile;
in this, a fine line microscope magnified 40-fold photograph in which all the print line widths are 3 pixels wide was printed.
Detailed Description
The present invention will be described in further detail with reference to specific examples. It will be understood that these examples are intended to illustrate the invention and are not intended to limit the scope of the invention in any way.
Example 1
The ink for ink-jet transfer printing comprises the following components in parts by mass: turmeric 5%, ethanol 7.5%, ethylene glycol 7.5%, alpha-tocopherol 0.5%, alkyl glycoside 0.1%, disodium edetate 0.1%, and deionized water 79.3%.
Adding the natural dye, the humectant, the stabilizer, the surfactant and the chelating agent into deionized water, fully stirring at the rotating speed of 100rad/min for 60min, standing for 1h, adjusting the pH to 7 by triethanolamine, filtering once by a microfiltration membrane with the pore diameter of 0.45 mu m, filtering once by a microfiltration membrane with the pore diameter of 0.22 mu m, and filling the filtered ink into an ink box for printing or sealing and storing.
The ink for ink-jet transfer printing has the viscosity of 3mpa & s, the surface tension of 26.89mN/m and the conductivity of 4.46ms/cm, and is not abnormal after being placed for 6 months.
The ink-jet transfer printing method comprises the following steps:
(1) preparing a transfer film: uniformly coating the prepared coating agent on a PET film, and airing for later use; wherein the coating agent comprises the following components in parts by mass:
(2) transfer printing, steaming and post-treatment: loading the prepared ink into an ink box, and printing a pattern on a transfer film by using an EPSON R330 color ink-jet printer, wherein the resolution is set to be 300 dpi; adopting a spraying device to spray and uniformly wet a single surface of a bleached pure cotton fabric, controlling the liquid carrying rate of the fabric at 40%, and balancing for 3min for later use after wetting; closely attaching the transfer printing film printing surface and the fabric wetting surface, and pressing and transferring with a flat-plate pyrograph machine under the transfer printing pressure of 3kg/cm2The transfer printing time is 60s, after the transfer printing is finished, the film is uncovered from the surface of the fabric, the transfer printing fabric is steamed for 45min at 102 ℃, after being washed once by warm water and cold water at 50 ℃, the fabric is immersed into polylysine aqueous solution with the mass concentration of 2g/L and the molecular weight of 3600-4300, the color is fixed for 60min at 60 ℃, after the treatment is finished, the fabric is washed twice by the warm water and the cold water at 50 ℃ respectively, and then the fabric is dried at 60 ℃.
Comparative example 1-1
The ink for ink-jet transfer printing comprises the following components in parts by mass: turmeric 5%, ethanol 7.5%, ethylene glycol 7.5%, alkyl glycoside 0.1%, disodium edetate 0.1%, and deionized water 79.8%.
Adding the natural dye, the humectant, the surfactant and the chelating agent into deionized water, fully stirring at the rotating speed of 100rad/min for 60min, standing for 1h, adjusting the pH to 7 by triethanolamine, filtering once by a microfiltration membrane with the pore diameter of 0.45 mu m, filtering once by a microfiltration membrane with the pore diameter of 0.22 mu m, and filling the filtered ink into an ink box for printing or sealing and storing.
The viscosity of the ink for ink-jet transfer printing is 3mpa & s, the surface tension is 27.15mN/m, the conductivity is 4.58ms/cm, and the ink is placed for 1 month, suspended matters appear, and the color of the ink becomes light.
The ink-jet transfer printing method comprises the following steps:
(1) preparing a transfer film: uniformly coating the prepared coating agent on a PET film, and airing for later use; wherein the coating agent comprises the following components in parts by mass:
(2) transfer printing, steaming and post-treatment: loading the prepared ink into an ink box, and printing a pattern on a transfer film by using an EPSON R330 color ink-jet printer, wherein the resolution is set to be 300 dpi; adopting a spraying device to spray and uniformly wet a single surface of a bleached pure cotton fabric, controlling the liquid carrying rate of the fabric at 40%, and balancing for 3min for later use after wetting; closely attaching the transfer printing film printing surface and the fabric wetting surface, and pressing and transferring with a flat-plate pyrograph machine under the transfer printing pressure of 3kg/cm2The transfer printing time is 60s, after the transfer printing is finished, the film is uncovered from the surface of the fabric, the transfer printing fabric is steamed for 45min at 102 ℃, after being washed once by warm water and cold water at 50 ℃, the fabric is immersed into polylysine aqueous solution with the mass concentration of 2g/L and the molecular weight of 3600-4300, the color is fixed for 60min at 60 ℃, after the treatment is finished, the fabric is washed twice by the warm water and the cold water at 50 ℃ respectively, and then the fabric is dried at 60 ℃.
Comparative examples 1 to 2
The ink for ink-jet transfer printing comprises the following components in parts by mass: turmeric 5%, ethanol 7.5%, ethylene glycol 7.5%, alpha-tocopherol 0.5%, alkyl glycoside 0.1%, disodium edetate 0.1%, and deionized water 79.3%.
Adding the natural dye, the humectant, the stabilizer, the surfactant and the chelating agent into deionized water, fully stirring at the rotating speed of 100rad/min for 60min, standing for 1h, adjusting the pH to 7 by triethanolamine, filtering once by a microfiltration membrane with the pore diameter of 0.45 mu m, filtering once by a microfiltration membrane with the pore diameter of 0.22 mu m, and filling the filtered ink into an ink box for printing or sealing and storing.
The ink for ink-jet transfer printing has the viscosity of 3mpa & s, the surface tension of 26.72mN/m and the conductivity of 5.01ms/cm, and is placed for 6 months without abnormality.
The ink-jet transfer printing method comprises the following steps:
(1) preparing a transfer film: uniformly coating the prepared coating agent on a PET film, and airing for later use; wherein the coating agent comprises the following components in parts by mass:
(2) transfer printing, steaming and post-treatment: loading the prepared ink into an ink box, and printing a pattern on a transfer film by using an EPSON R330 color ink-jet printer, wherein the resolution is set to be 300 dpi; adopting a spraying device to spray and uniformly wet a single surface of a bleached pure cotton fabric, controlling the liquid carrying rate of the fabric at 40%, and balancing for 3min for later use after wetting; closely attaching the transfer printing film printing surface and the fabric wetting surface, and pressing and transferring with a flat-plate pyrograph machine under the transfer printing pressure of 3kg/cm2The transfer printing time is 60s, after the transfer printing is finished, the film is uncovered from the surface of the fabric, the transfer printing fabric is steamed for 45min at 102 ℃, washed once by warm water and cold water at 50 ℃, and dried at 60 ℃.
Comparative examples 1 to 3
The ink for ink-jet transfer printing comprises the following components in parts by mass: turmeric 5%, ethanol 7.5%, ethylene glycol 7.5%, alpha-tocopherol 0.5%, alkyl glycoside 0.1%, disodium edetate 0.1%, and deionized water 79.3%.
Adding the natural dye, the humectant, the stabilizer, the surfactant and the chelating agent into deionized water, fully stirring at the rotating speed of 100rad/min for 60min, standing for 1h, adjusting the pH to 7 by triethanolamine, filtering once by a microfiltration membrane with the pore diameter of 0.45 mu m, filtering once by a microfiltration membrane with the pore diameter of 0.22 mu m, and filling the filtered ink into an ink box for printing or sealing and storing.
The ink for ink-jet transfer printing has the viscosity of 3mpa & s, the surface tension of 26.52mN/m and the conductivity of 4.96ms/cm, and is placed for 6 months without abnormality.
The ink-jet transfer printing method comprises the following steps:
(1) preparing a transfer film: uniformly coating the prepared coating agent on a PET film, and airing for later use; wherein the coating agent comprises the following components in parts by mass:
(2) transfer printing, steaming and post-treatment: loading the prepared ink into an ink box, and printing a pattern on a transfer film by using an EPSON R330 color ink-jet printer, wherein the resolution is set to be 300 dpi;
(3) soaking a bleached pure cotton fabric into a chitosan finishing liquid, wherein the formula of the chitosan finishing liquid is as follows: the concentration of chitosan is 0.25 g/L; the concentration of the epoxy chloropropane is 0.01 mol/L; the solvent is citric acid solution with mass fraction of 5%, and chitosan molecular weight is 1.1 × 105The degree of deacetylation is 75%; soaking and rolling for two times, wherein the rolling residual rate is 70%, then soaking and rolling a NaOH solution with the mass fraction of 5%, soaking and rolling for two times, the rolling residual rate is 80%, drying at 80 ℃, baking for 3min at 140 ℃, then washing for 3 times by using distilled water, and drying for later use;
(4) carrying out single-side spraying and uniform moistening on the pure cotton fabric pretreated in the step (3) by using a spraying device, controlling the liquid carrying rate of the fabric to be 40%, and balancing for 3min for later use after the moistening is finished; closely attaching the transfer printing film printing surface and the fabric wetting surface, and pressing and transferring with a flat-plate pyrograph machine under the transfer printing pressure of 3kg/cm2The transfer printing time is 60s, after the transfer printing is finished, the film is uncovered from the surface of the fabric, the transfer printing fabric is steamed for 45min at 102 ℃, the fabric is washed twice by warm water and cold water at 50 ℃, and the fabric is dried at 60 ℃.
Comparative examples 1 to 4
The ink for ink-jet transfer printing comprises the following components in parts by mass: turmeric 5%, ethanol 7.5%, ethylene glycol 7.5%, alpha-tocopherol 0.5%, alkyl glycoside 0.1%, disodium edetate 0.1%, and deionized water 79.3%.
Adding the natural dye, the humectant, the stabilizer, the surfactant and the chelating agent into deionized water, fully stirring at the rotating speed of 100rad/min for 60min, standing for 1h, adjusting the pH to 7 by triethanolamine, filtering once by a microfiltration membrane with the pore diameter of 0.45 mu m, filtering once by a microfiltration membrane with the pore diameter of 0.22 mu m, and filling the filtered ink into an ink box for printing or sealing and storing.
The ink for ink-jet transfer printing has the viscosity of 3mpa & s, the surface tension of 27.32mN/m and the conductivity of 4.88ms/cm, and is placed for 6 months without abnormality.
The ink-jet transfer printing method comprises the following steps:
(1) preparing a transfer film: uniformly coating the prepared coating agent on a PET film, and airing for later use; wherein the coating agent comprises the following components in parts by mass:
(2) transfer printing, steaming and post-treatment: loading the prepared ink into an ink box, and printing a pattern on a transfer film by using an EPSON R330 color ink-jet printer, wherein the resolution is set to be 300 dpi; adopting a spraying device to spray and uniformly wet a single surface of a bleached pure cotton fabric, controlling the liquid carrying rate of the fabric at 40%, and balancing for 3min for later use after wetting; closely attaching the transfer printing film printing surface and the fabric wetting surface, and pressing and transferring with a flat-plate pyrograph machine under the transfer printing pressure of 3kg/cm2The transfer printing time is 60s, after the transfer printing is finished, the film is uncovered from the surface of the fabric, the transfer printing fabric is steamed for 45min at 102 ℃, washed once by warm water and cold water at 50 ℃, and then immersed into the fabric with the size of 0.3 multiplied by 10-3Fixing color in mol/L chlorinated high-iron aqueous solution at 40 deg.C for 10min, washing with warm water and cold water at 50 deg.C twice, and oven drying at 60 deg.C.
Example 2
The ink for ink-jet transfer printing comprises the following components in parts by mass: 15% of lac red, 10% of ethanol, 20% of glycerol, 1.0% of gallic acid, 0.5% of fatty alcohol-polyoxyethylene ether, 0.5% of tetrasodium ethylenediamine tetraacetate and 53% of deionized water.
Adding the natural dye, the humectant, the stabilizer, the surfactant and the chelating agent into deionized water, fully stirring at the rotating speed of 300rad/min for 30min, standing for 2h, adjusting the pH to 7.5 by triethanolamine, filtering once by a microfiltration membrane with the pore diameter of 0.45 mu m, filtering once by a microfiltration membrane with the pore diameter of 0.22 mu m, and filling the filtered ink into an ink box for printing or sealing and storing.
The ink for ink-jet transfer printing has the viscosity of 4mpa & s, the surface tension of 36.66mN/m and the conductivity of 6.91ms/cm, and is placed for 6 months without abnormality.
The ink-jet transfer printing method comprises the following steps:
(1) preparing a transfer film: uniformly coating the prepared coating agent on a BOPP film, and airing for later use; wherein the coating agent comprises the following components in parts by mass:
(2) transfer printing, steaming and post-treatment: loading the prepared ink into an ink box, and printing a pattern on a transfer film by using an EPSON R330 color ink-jet printer, wherein the resolution is set to be 300 dpi; adopting a spraying device to spray and uniformly wet the single side of the bleached linen fabric, controlling the liquid carrying rate of the fabric at 50%, and balancing for 5min for later use after wetting; closely attaching the transfer printing film printing surface and the fabric wetting surface, and pressing and transferring with a flat-plate pyrograph machine under the transfer printing pressure of 5kg/cm2And the transfer printing time is 30s, after the transfer printing is finished, the film is uncovered from the surface of the fabric, the transfer printing fabric is steamed for 15min at 105 ℃, after being washed once by warm water and cold water at 50 ℃, the fabric is immersed into polylysine aqueous solution with the mass concentration of 5g/L and the molecular weight of 3600-4300, the fixation treatment is carried out for 30min at 90 ℃, after the treatment is finished, the fabric is washed twice by the warm water and the cold water at 50 ℃ respectively, and then the fabric is dried at 80 ℃.
Comparative example 2-1
The ink for ink-jet transfer printing comprises the following components in parts by mass: 15% of lac red, 10% of ethanol, 20% of glycerol, 1.0% of gallic acid, 0.5% of fatty alcohol-polyoxyethylene ether, 0.5% of tetrasodium ethylenediamine tetraacetate and 53% of deionized water.
Adding the natural dye, the humectant, the stabilizer, the surfactant and the chelating agent into deionized water, fully stirring at the rotating speed of 300rad/min for 30min, standing for 2h, adjusting the pH to 7.5 by triethanolamine, filtering once by a microfiltration membrane with the pore diameter of 0.45 mu m, filtering once by a microfiltration membrane with the pore diameter of 0.22 mu m, and filling the filtered ink into an ink box for printing or sealing and storing.
The ink for ink-jet transfer printing has the viscosity of 4mpa & s, the surface tension of 36.66mN/m and the conductivity of 6.91ms/cm, and is placed for 6 months without abnormality.
The ink-jet transfer printing method comprises the following steps:
(1) preparing a transfer film: uniformly coating the prepared coating agent on a BOPP film, and airing for later use; wherein the coating agent comprises the following components in parts by mass:
(2) transfer printing, steaming and post-treatment: loading the prepared ink into an ink box, and printing a pattern on a transfer film by using an EPSON R330 color ink-jet printer, wherein the resolution is set to be 300 dpi; adopting a spraying device to spray and uniformly wet the single side of the bleached linen fabric, controlling the liquid carrying rate of the fabric at 50%, and balancing for 5min for later use after wetting; closely attaching the transfer printing film printing surface and the fabric wetting surface, and pressing and transferring with a flat-plate pyrograph machine under the transfer printing pressure of 5kg/cm2And the transfer printing time is 30s, after the transfer printing is finished, the film is uncovered from the surface of the fabric, the transfer printing fabric is steamed for 15min at 105 ℃, after being washed once by warm water and cold water at 50 ℃, the fabric is immersed into polylysine aqueous solution with the mass concentration of 1g/L and the molecular weight of 3600-4300, the fixation treatment is carried out for 30min at 90 ℃, after the treatment is finished, the fabric is washed twice by the warm water and the cold water at 50 ℃ respectively, and then the fabric is dried at 80 ℃.
Comparative examples 2 to 2
The ink for ink-jet transfer printing comprises the following components in parts by mass: 15% of lac red, 10% of ethanol, 20% of glycerol, 1.0% of gallic acid, 0.5% of fatty alcohol-polyoxyethylene ether, 0.5% of tetrasodium ethylenediamine tetraacetate and 53% of deionized water.
Adding the natural dye, the humectant, the stabilizer, the surfactant and the chelating agent into deionized water, fully stirring at the rotating speed of 300rad/min for 30min, standing for 2h, adjusting the pH to 7.5 by triethanolamine, filtering once by a microfiltration membrane with the pore diameter of 0.45 mu m, filtering once by a microfiltration membrane with the pore diameter of 0.22 mu m, and filling the filtered ink into an ink box for printing or sealing and storing.
The ink for ink-jet transfer printing has the viscosity of 4mpa & s, the surface tension of 36.66mN/m and the conductivity of 6.91ms/cm, and is placed for 6 months without abnormality.
The ink-jet transfer printing method comprises the following steps:
(1) preparing a transfer film: uniformly coating the prepared coating agent on a BOPP film, and airing for later use; wherein the coating agent comprises the following components in parts by mass:
(2) transfer printing, steaming and post-treatment: loading the prepared ink into an ink box, and printing a pattern on a transfer film by using an EPSON R330 color ink-jet printer, wherein the resolution is set to be 300 dpi; adopting a spraying device to spray and uniformly wet the single side of the bleached linen fabric, controlling the liquid carrying rate of the fabric at 50%, and balancing for 5min for later use after wetting; closely attaching the transfer printing film printing surface and the fabric wetting surface, and pressing and transferring with a flat-plate pyrograph machine under the transfer printing pressure of 5kg/cm2And the transfer printing time is 30s, after the transfer printing is finished, the film is uncovered from the surface of the fabric, the transfer printing fabric is steamed for 15min at 105 ℃, after being washed once by warm water and cold water at 50 ℃, the fabric is immersed into polylysine aqueous solution with the mass concentration of 6g/L and the molecular weight of 3600-4300, the fixation treatment is carried out for 30min at 90 ℃, after the treatment is finished, the fabric is washed twice by the warm water and the cold water at 50 ℃ respectively, and then the fabric is dried at 80 ℃.
Comparative examples 2 to 3
The ink for ink-jet transfer printing comprises the following components in parts by mass: 15% of lac red, 10% of ethanol, 20% of glycerol, 1.0% of gallic acid, 0.5% of fatty alcohol-polyoxyethylene ether, 0.5% of tetrasodium ethylenediamine tetraacetate and 53% of deionized water.
Adding the natural dye, the humectant, the stabilizer, the surfactant and the chelating agent into deionized water, fully stirring at the rotating speed of 300rad/min for 30min, standing for 2h, adjusting the pH to 7.5 by triethanolamine, filtering once by a microfiltration membrane with the pore diameter of 0.45 mu m, filtering once by a microfiltration membrane with the pore diameter of 0.22 mu m, and filling the filtered ink into an ink box for printing or sealing and storing.
The ink for ink-jet transfer printing has the viscosity of 4mpa & s, the surface tension of 36.66mN/m and the conductivity of 6.91ms/cm, and is placed for 6 months without abnormality.
The ink-jet transfer printing method comprises the following steps:
(1) preparing a transfer film: uniformly coating the prepared coating agent on a BOPP film, and airing for later use; wherein the coating agent comprises the following components in parts by mass:
(2) transfer printing, steaming and post-treatment: loading the prepared ink into an ink box, and printing a pattern on a transfer film by using an EPSON R330 color ink-jet printer, wherein the resolution is set to be 300 dpi; adopting a spraying device to spray and uniformly wet the single side of the bleached linen fabric, controlling the liquid carrying rate of the fabric at 50%, and balancing for 5min for later use after wetting; closely attaching the transfer printing film printing surface and the fabric wetting surface, and pressing and transferring with a flat-plate pyrograph machine under the transfer printing pressure of 5kg/cm2The transfer printing time is 30s, after the transfer printing is finished, the film is uncovered from the surface of the fabric, the transfer printing fabric is steamed for 15min at 105 ℃, after being washed once by warm water and cold water at 50 ℃, the fabric is immersed into polylysine aqueous solution with the mass concentration of 5g/L and the molecular weight of 30000-70000, the fixation treatment is carried out for 30min at 90 ℃, after the treatment is finished, the fabric is washed twice by the warm water and the cold water at 50 ℃ respectively, and then the fabric is dried at 80 ℃.
Example 3
The ink for ink-jet transfer printing comprises the following components in parts by mass: 10% of sodium copper chlorophyllin, 5% of ethanol, 15% of diethylene glycol, 0.8% of caffeic acid, 0.25% of rapid penetrating agent T, 0.3% of disodium ethylene diamine tetraacetate and the balance of deionized water.
Adding the natural dye, the humectant, the stabilizer, the surfactant and the chelating agent into deionized water, fully stirring at the rotating speed of 200rad/min for 45min, standing for 1.5h, adjusting the pH to 7.2 by triethanolamine, filtering once by a microfiltration membrane with the pore diameter of 0.45 mu m, filtering once by a microfiltration membrane with the pore diameter of 0.22 mu m, and filling the filtered ink into an ink box for printing or sealing and storing.
The ink for ink-jet transfer printing has the viscosity of 4mpa & s, the surface tension of 29.68mN/m and the conductivity of 5.65ms/cm, and is not abnormal after being placed for 6 months.
The ink-jet transfer printing method comprises the following steps:
(1) preparing a transfer film: uniformly coating the prepared coating agent on a PET film, and airing for later use; wherein the coating agent comprises the following components in parts by mass:
(2) transfer printing, steaming and post-treatment: loading the prepared ink into an ink box, and printing a pattern on a transfer film by using an EPSON R330 color ink-jet printer, wherein the resolution is set to be 300 dpi; adopting a spraying device to spray and uniformly wet a single surface of a bleached silk fabric, controlling the liquid carrying rate of the fabric at 45%, and balancing for 4min for later use after wetting; closely attaching the transfer printing film printing surface and the fabric wetting surface, and pressing and transferring with a flat-plate pyrograph machine under the transfer printing pressure of 4kg/cm2The transfer printing time is 45s, after the transfer printing is finished, the film is uncovered from the surface of the fabric, the transfer printing fabric is steamed for 30min at 103 ℃, after being washed once by warm water and cold water at 50 ℃, the fabric is immersed into polylysine aqueous solution with the mass concentration of 3g/L and the molecular weight of 3600-4300, the fixation treatment is carried out for 45min at 75 ℃, after the treatment is finished, the fabric is washed twice by the warm water and the cold water at 50 ℃ respectively, and then the fabric is dried at 70 ℃.
Example 4
The ink for ink-jet transfer printing comprises the following components in parts by mass: 8% of tomato red, 10% of ethanol, 15% of glycerol, 0.6% of phenyl salicylate, 0.4% of sodium dodecyl sulfate, 0.4% of tetrasodium ethylenediamine tetraacetate and the balance of deionized water.
Adding the natural dye, the humectant, the stabilizer, the surfactant and the chelating agent into deionized water, fully stirring at the rotating speed of 250rad/min for 40min, standing for 1.2h, adjusting the pH to 7.3 by triethanolamine, filtering once by a microfiltration membrane with the pore diameter of 0.45 mu m, filtering once by a microfiltration membrane with the pore diameter of 0.22 mu m, and filling the filtered ink into an ink box for printing or sealing and storing.
The ink for ink-jet transfer printing has the viscosity of 3mpa & s, the surface tension of 28.27mN/m and the conductivity of 6.05ms/cm, and is placed for 6 months without abnormality.
The application method of the ink-jet transfer printing ink comprises the following steps:
(1) preparing a transfer film: uniformly coating the prepared coating agent on a BOPP film, and airing for later use; wherein the coating agent comprises the following components in parts by mass:
(2) transfer printing, steaming and post-treatment: loading the prepared ink into an ink box, and printing a pattern on a transfer film by using an EPSON R330 color ink-jet printer, wherein the resolution is set to be 300 dpi; adopting a spraying device to carry out single-side spraying and uniform moistening on bleached pure cotton fabric, linen fabric, silk fabric and viscose fabric, controlling the liquid carrying rate of the fabric at 42%, and balancing for 3.5min for later use after the moistening is finished; closely attaching the transfer printing film printing surface and the fabric wetting surface, and pressing and transferring with a flat-plate pyrograph machine under the transfer printing pressure of 3.5kg/cm2The transfer printing time is 40s, after the transfer printing is finished, the film is uncovered from the surface of the fabric, the transfer printing fabric is steamed for 35min at 104 ℃, washed once by warm water and cold water at 50 ℃, immersed in polylysine aqueous solution with mass concentration of 4g/L and molecular weight of 3600-4300, subjected to color fixation treatment for 50min at 65 ℃, and after the treatment is finished, the film is removed by using a solventWashing with warm water and cold water at 50 deg.C twice, and oven drying at 75 deg.C.
Example 5
Color parameter testing: the K/S value of the dyed fabric is measured in a datacolor test color matching instrument under the following test conditions: d65 illuminant at a 10 ° viewing angle, each sample was folded twice and averaged for 4 measurements.
And (3) testing color fastness: the friction color fastness is determined according to GB/T3920-2008 'color fastness to rubbing test of textiles'.
The soaping color fastness is measured according to the C (3) method of GB/T3921-2008 'soaping color fastness resistance test for textiles'.
The color fastness to sunlight refers to the color fastness to artificial light in a textile color fastness test of GB/T8427-2008: xenon arc.
The test results were as follows:
TABLE 1 printed fabrics K/S value and color fastness
As can be seen from Table 1, the printed fabrics obtained in examples 1-4 are dark in color and excellent in various color fastnesses, and the printed fabrics obtained in comparative example 1-1, in which no stabilizer is added to the ink-jet transfer ink, are poor in light fastness; comparative examples 1-2 had poor color fastness of the fabric obtained without fixation treatment with polylysine. Comparative examples 1-3 were fixed with chitosan, which was mainly cross-linked on the fabric surface due to its relatively large molecular weight, and therefore, the resulting printed fabrics had poor crockfastness and the chitosan-fixed fabrics had a hard hand. Comparative examples 1 to 4 Using Fe3+Mordant dyeing of Fe3+The ions form a complex with natural dye to improve the color fastness of printed fabrics, the affinity of the complex with cellulose fibers is very weak, and the color fastness of the fabrics is improved mainly through physical actions such as winding and drawing among fibers, so that the improvement range is largerSmall and Fe3+The ions are easy to hydrolyze in the mordant dyeing process to form Fe (OH) on the cloth surface3Precipitation, which also does not contribute to the improvement of the color fastness of the fabric. And Fe3+The ions are yellow, and the color of the fabric is easy to change after mordant dyeing (the K/S value of the fabric before mordant dyeing is 5.66, and L is*Is 63.82, C*46.72, h is 75.65; the K/S value of the fabric after mordant dyeing is 7.82, L*Is 69.79, C*59.43, h 86.12).
In comparative example 2-1, polylysine was used at a low concentration, the plant dye that had been dyed on the fabric was not completely bound to polylysine, and the resulting printed fabric had a low K/S value and poor color fastness. Although the concentration of polylysine in comparative example 2-2 was higher than that of example 2, the K/S value and various color fastnesses were not significantly higher than in example 2, probably because the vegetable dyes on the fabric were all bound to polylysine, and too high a polylysine concentration was not beneficial for improving the performance of the printed fabric. In comparative examples 2-3, polylysine solution with a large molecular weight is selected for fixation, and because the polylysine solution has a large molecular weight and a positive charge, the polylysine solution is not easy to permeate into the fiber to be combined with the plant dye in the fixation process, so that the obtained printed fabric has a low K/S value and poor color fastness.
Claims (9)
1. The natural dye ink-jet transfer printing method is characterized by comprising the following specific steps:
(1) preparing a transfer film: uniformly coating the prepared coating agent on a PET film or a BOPP film, and airing for later use;
(2) transferring and steaming, namely filling natural dye ink-jet transfer printing ink into an ink box, and printing a pattern on the transfer printing film obtained in the step (1) by using an EPSON R330 color ink-jet printer; adopting a spraying device to spray and uniformly wet the single side of the bleached fabric, and balancing for 3-5min for later use after wetting; closely attaching the printing surface of the transfer printing film to the wetting surface of the fabric, rolling and transferring by a flat-plate pyrograph machine, uncovering the film from the surface of the fabric after the transfer printing is finished, and steaming;
(3) and (3) treatment: and (3) washing the steamed fabric in the step (2) once by warm water and cold water respectively, immersing the fabric into a polylysine aqueous solution, fixing the color, washing twice by the warm water and the cold water respectively after finishing the treatment, and drying.
2. The natural dye inkjet transfer printing method according to claim 1, wherein the coating agent in the step (1) has a composition of, in parts by mass:
3. the natural dye inkjet transfer printing process according to claim 1, wherein: the natural dye ink-jet transfer printing ink in the step (2) comprises the following components in parts by mass: 5-15% of natural dye, 15-30% of humectant, 0.5-1.0% of stabilizer, 0.1-0.5% of surfactant, 0.1-0.5% of chelating agent and the balance of deionized water.
4. The natural dye inkjet transfer printing method according to claim 3, wherein the natural dye is one of gardenia yellow, turmeric, monascus yellow, monascus red, cochineal red, tomato red, shellac red, sodium copper chlorophyllin, gardenia blue; the humectant consists of a high-boiling point solvent and a low-boiling point solvent, wherein the low-boiling point solvent is ethanol, and the high-boiling point solvent is one of ethylene glycol, glycerol and diethylene glycol; the mass ratio of the low-boiling point solvent to the high-boiling point solvent is 1:1-1: 3.
5. The natural dye inkjet transfer printing method of claim 3, wherein the stabilizer is one of alpha-tocopherol, gallic acid, caffeic acid and phenyl salicylate, the surfactant is one or more of alkyl glycoside, fatty alcohol polyoxyethylene ether, coconut oil fatty acid diethanolamide, rapid penetration agent T, sodium dodecyl sulfate and sodium dodecyl sulfate, and the chelating agent is disodium ethylenediamine tetraacetic acid or tetrasodium ethylenediamine tetraacetic acid.
6. The natural dye inkjet transfer printing method according to claim 3, wherein the natural dye inkjet transfer printing ink is prepared by: adding natural dye, humectant, stabilizer, surfactant and chelating agent into deionized water, stirring at 100-300rad/min for 30-60min, standing for 1-2h, adjusting pH to 7-7.5 with triethanolamine, filtering with microporous membrane with pore diameter of 0.45 μm, filtering with microporous membrane with pore diameter of 0.22 μm, and printing or sealing the filtered ink in an ink box.
7. The natural dye inkjet transfer printing method according to claim 1, wherein the color inkjet printer resolution in step (2) is set to 300 dpi; the fabric is one of pure cotton fabric, linen fabric, silk fabric and viscose fabric, and the liquid carrying rate of the fabric is controlled to be 40-50% in the moistening process.
8. The natural dye inkjet transfer printing method according to claim 1, wherein the nip transfer pressure in the step (2) is 3 to 5kg/cm2The transfer printing time is 30-60 s; the transfer fabric was steamed for 15-45min at 102-105 ℃.
9. The natural dye inkjet transfer printing process according to claim 1, wherein: the polylysine in the step (3) has the molecular weight of 3600-4300, the polylysine aqueous solution has the mass concentration of 2-5g/L, the fixation treatment is carried out for 30-60min at the temperature of 60-90 ℃, and the drying temperature is 60-80 ℃.
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Cited By (3)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN114016308A (en) * | 2021-11-26 | 2022-02-08 | 武汉纺织大学 | Digital transfer printing method using plant dye ink |
| CN115679720A (en) * | 2022-11-24 | 2023-02-03 | 浙江迎丰科技股份有限公司 | Cold transfer printing method for acid dye |
| CN115928461A (en) * | 2022-12-27 | 2023-04-07 | 郑州鸿盛数码科技股份有限公司 | Digital direct-injection printing process for cellulose fiber fabric by using plant dye ink |
Citations (6)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN202357579U (en) * | 2011-10-31 | 2012-08-01 | 刘静 | Double-face dewing device used in wet-method transfer printing of fabrics |
| CN104098954A (en) * | 2014-07-18 | 2014-10-15 | 浙江亿得化工有限公司 | Novel activated printing ink and preparation method thereof as well as direct printing technology |
| US20150116418A1 (en) * | 2013-02-21 | 2015-04-30 | Kiwa Chemical Industry Co., Ltd. | Sublimating dye ink for ink jets and dyeing method |
| CN106087477A (en) * | 2016-06-20 | 2016-11-09 | 常州大学 | A kind of textile inkjet printing reactive dye ink and preparation method thereof |
| CN107780264A (en) * | 2017-10-25 | 2018-03-09 | 常州大学 | A kind of cellulose base fiber fabric ink-jet method for transfer printing |
| WO2018135419A1 (en) * | 2017-01-23 | 2018-07-26 | 日本化薬株式会社 | Ink composition for inkjet textile printing and textile printing method for fibers with use of same |
-
2021
- 2021-04-21 CN CN202110427724.4A patent/CN113062129B/en active Active
Patent Citations (6)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN202357579U (en) * | 2011-10-31 | 2012-08-01 | 刘静 | Double-face dewing device used in wet-method transfer printing of fabrics |
| US20150116418A1 (en) * | 2013-02-21 | 2015-04-30 | Kiwa Chemical Industry Co., Ltd. | Sublimating dye ink for ink jets and dyeing method |
| CN104098954A (en) * | 2014-07-18 | 2014-10-15 | 浙江亿得化工有限公司 | Novel activated printing ink and preparation method thereof as well as direct printing technology |
| CN106087477A (en) * | 2016-06-20 | 2016-11-09 | 常州大学 | A kind of textile inkjet printing reactive dye ink and preparation method thereof |
| WO2018135419A1 (en) * | 2017-01-23 | 2018-07-26 | 日本化薬株式会社 | Ink composition for inkjet textile printing and textile printing method for fibers with use of same |
| CN107780264A (en) * | 2017-10-25 | 2018-03-09 | 常州大学 | A kind of cellulose base fiber fabric ink-jet method for transfer printing |
Cited By (4)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN114016308A (en) * | 2021-11-26 | 2022-02-08 | 武汉纺织大学 | Digital transfer printing method using plant dye ink |
| CN114016308B (en) * | 2021-11-26 | 2023-12-01 | 武汉纺织大学 | Digital transfer printing method using vegetable dye ink |
| CN115679720A (en) * | 2022-11-24 | 2023-02-03 | 浙江迎丰科技股份有限公司 | Cold transfer printing method for acid dye |
| CN115928461A (en) * | 2022-12-27 | 2023-04-07 | 郑州鸿盛数码科技股份有限公司 | Digital direct-injection printing process for cellulose fiber fabric by using plant dye ink |
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Application publication date: 20210702 Assignee: Liyang glory Plastic Co.,Ltd. Assignor: CHANGZHOU University Contract record no.: X2023980052012 Denomination of invention: A natural dye inkjet transfer printing ink and its application method Granted publication date: 20221216 License type: Common License Record date: 20231213 |