CN108083886A - A kind of special fertilizer for cultivating of honeysuckle and preparation method thereof - Google Patents

A kind of special fertilizer for cultivating of honeysuckle and preparation method thereof Download PDF

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Publication number
CN108083886A
CN108083886A CN201711198778.8A CN201711198778A CN108083886A CN 108083886 A CN108083886 A CN 108083886A CN 201711198778 A CN201711198778 A CN 201711198778A CN 108083886 A CN108083886 A CN 108083886A
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Prior art keywords
parts
honeysuckle
epoxy resin
cultivating
calcium
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CN201711198778.8A
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Chinese (zh)
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不公告发明人
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Changsha Road Industrial Design Co
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Changsha Road Industrial Design Co
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Priority to CN201711198778.8A priority Critical patent/CN108083886A/en
Publication of CN108083886A publication Critical patent/CN108083886A/en
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    • CCHEMISTRY; METALLURGY
    • C05FERTILISERS; MANUFACTURE THEREOF
    • C05BPHOSPHATIC FERTILISERS
    • C05B7/00Fertilisers based essentially on alkali or ammonium orthophosphates
    • CCHEMISTRY; METALLURGY
    • C05FERTILISERS; MANUFACTURE THEREOF
    • C05GMIXTURES OF FERTILISERS COVERED INDIVIDUALLY BY DIFFERENT SUBCLASSES OF CLASS C05; MIXTURES OF ONE OR MORE FERTILISERS WITH MATERIALS NOT HAVING A SPECIFIC FERTILISING ACTIVITY, e.g. PESTICIDES, SOIL-CONDITIONERS, WETTING AGENTS; FERTILISERS CHARACTERISED BY THEIR FORM
    • C05G3/00Mixtures of one or more fertilisers with additives not having a specially fertilising activity
    • CCHEMISTRY; METALLURGY
    • C05FERTILISERS; MANUFACTURE THEREOF
    • C05GMIXTURES OF FERTILISERS COVERED INDIVIDUALLY BY DIFFERENT SUBCLASSES OF CLASS C05; MIXTURES OF ONE OR MORE FERTILISERS WITH MATERIALS NOT HAVING A SPECIFIC FERTILISING ACTIVITY, e.g. PESTICIDES, SOIL-CONDITIONERS, WETTING AGENTS; FERTILISERS CHARACTERISED BY THEIR FORM
    • C05G3/00Mixtures of one or more fertilisers with additives not having a specially fertilising activity
    • C05G3/80Soil conditioners
    • CCHEMISTRY; METALLURGY
    • C05FERTILISERS; MANUFACTURE THEREOF
    • C05GMIXTURES OF FERTILISERS COVERED INDIVIDUALLY BY DIFFERENT SUBCLASSES OF CLASS C05; MIXTURES OF ONE OR MORE FERTILISERS WITH MATERIALS NOT HAVING A SPECIFIC FERTILISING ACTIVITY, e.g. PESTICIDES, SOIL-CONDITIONERS, WETTING AGENTS; FERTILISERS CHARACTERISED BY THEIR FORM
    • C05G3/00Mixtures of one or more fertilisers with additives not having a specially fertilising activity
    • C05G3/90Mixtures of one or more fertilisers with additives not having a specially fertilising activity for affecting the nitrification of ammonium compounds or urea in the soil

Abstract

The invention discloses a kind of special fertilizer for cultivating of honeysuckle, are made of the raw material below according to parts by weight:5 25 parts of Su Gu meter potassium, 3 17 parts of thiophanate methyl, 1 11 parts of calcium dodecyl benzene sulfonate, 4 18 parts of epoxy resin integument Diammonium phosphate (DAP), 4 16 parts of epoxy resin integument potassium nitrate, 5 25 parts of tripterygium wilfordii, 2 18 parts of adder-wort, 2 14 parts of phosphorus humic acid phosphorus, 3 15 parts of bacillus megaterium, 2 10 parts of polyacrylamide, 5 25 parts of rhizome of cyrtomium, 5 15 parts of modified meerschaum, 17 parts of catalase, 28 parts of nano-calcium carbonate calcium powder, 2 10 parts of ethoxylated trimethylolpropane triacrylate.The present invention has the advantages that rich in nutrition content, promotes gold and silver flower growth and fertilizer loss rate low.

Description

A kind of special fertilizer for cultivating of honeysuckle and preparation method thereof
Technical field
The present invention relates to fertilizer manufacture fields more particularly to a kind of special fertilizer for cultivating of honeysuckle and preparation method thereof.
Background technology
Honeysuckle also known as honeysuckle." honeysuckle " one is come from《Compendium of Materia Medica》, it is rear to turn since honeysuckle flowers are just opened as white For yellow, hence obtain one's name honeysuckle, and honeysuckle is known as clearing heat and detoxicating good medicine from ancient times.The sweet cold air fragrance of its property, clear heat with drugs of sweet flavour and cold nature Without injuring one's stomach, fragrance reaches thoroughly again can eliminating evil.Honeysuckle can dispelling wind-heat, also kind removing summer-heat blood poison, for various febrile diseases, such as body The diseases such as heat, dermexanthesis, hair spot, heat toxin sore carbuncle, abscess of throat, equal significant effect.
At present, people are when planting honeysuckle, in order to which honeysuckle is made to can grow sturdily, it will usually be reached by applying fertilizer To the purpose for promoting gold and silver flower growth, existing fertilizer used on the market is not only with single nutrient component, it is impossible to meet gold and silver Required in the growth course nutrient of flower, while a problem that fertilizer generally existing fertilizer loss rate on the market is big, and The loss of fertilizer not only increases the use cost of people, while the heavy metal ion of fertilizer can be penetrated into soil, cause soil The hardening of matter, long-time service meeting damage to land structure, is unfavorable for the plantation of people.
The content of the invention
The defects of in order to overcome the above-mentioned prior art, the object of the present invention is to provide a kind of honeysuckle special fertilizer for cultivating and Its preparation method.
The present invention takes following technical scheme to realize:A kind of special fertilizer for cultivating of honeysuckle, by below according to weight Measure the raw material composition of number:5-25 parts of Su Gu meter potassium, 3-17 parts of thiophanate methyl, 1-11 parts of calcium dodecyl benzene sulfonate, epoxy 4-18 parts of coated with resin Diammonium phosphate (DAP), 4-16 parts of epoxy resin integument potassium nitrate, 5-25 parts of tripterygium wilfordii, 2-18 parts of adder-wort, rotten plant Sour phosphorus 2-14 parts, 3-15 parts of bacillus megaterium, 2-10 parts of polyacrylamide, 5-25 parts of rhizome of cyrtomium, 5-15 parts of modified meerschaum, mistake 1-7 parts of hydrogen oxide enzyme, 2-8 parts of nano-calcium carbonate calcium powder, 2-10 parts of ethoxylated trimethylolpropane triacrylate.
The modified meerschaum is made of following steps:
(1) sepiolite is put into reducing mechanism and crushes processing, grinding time 50min obtains powder sepiolite;
(2) sepiolite after crushing is added in into water and triethyl group hexyl phosphoric acid, obtains sepiolite suspension, sepiolite is hanged Supernatant liquid is stirred, and 3h is stood after the completion of stirring, upper suspension is taken, processing is dried;
(3) material obtained in step 2 is added in the sulfuric acid solution of 5-10mol/L, the acid treatment time is 12-18h, is obtained Sour modified meerschaum;
(4) the sour modified meerschaum obtained in step 3 addition surfactant is surface-treated to obtain modified Hai Pao Stone.
A kind of special fertilizer for cultivating of above-mentioned honeysuckle, is made of the raw material below according to parts by weight:Su Gu meter potassium 15 Part, 10 parts of thiophanate methyl, 6 parts of calcium dodecyl benzene sulfonate, 11 parts of epoxy resin integument Diammonium phosphate (DAP), epoxy resin integument nitre Sour 12 parts of potassium, 15 parts of tripterygium wilfordii, 10 parts of adder-wort, 8 parts of phosphorus humic acid phosphorus, 9 parts of bacillus megaterium, 6 parts of polyacrylamide, rhizome of cyrtomium 15 Part, 10 parts of modified meerschaum, 4 parts of catalase, 5 parts of nano-calcium carbonate calcium powder, three acrylic acid of ethoxylated trimethylolpropane 5 parts of ester.
A kind of special fertilizer for cultivating of above-mentioned honeysuckle, the surfactant are octadecyl dimethyl benzyl quaternary ammonium chlorine Compound.
A kind of special fertilizer for cultivating for the honeysuckle stated, the calcium dodecyl benzene sulfonate and epoxy resin integument potassium nitrate it Between weight ratio be 1:2.
A kind of special fertilizer for cultivating for the honeysuckle stated, the ethoxylated trimethylolpropane triacrylate and modified sea Weight ratio is 2 between afrodite:1.
A kind of preparation method of the special fertilizer for cultivating of above-mentioned honeysuckle, comprises the steps of:
(1) the weight composition number of each material in claim 2 is weighed, by Su Gu meter potassium, thiophanate methyl, dodecyl Benzene sulfonic acid calcium, epoxy resin integument Diammonium phosphate (DAP), epoxy resin integument potassium nitrate, tripterygium wilfordii, adder-wort, phosphorus humic acid phosphorus, huge bud Spore bacillus, polyacrylamide, rhizome of cyrtomium, three acrylic acid of catalase, nano-calcium carbonate calcium powder and ethoxylated trimethylolpropane Ester is put into reducing mechanism and is stirred, grinding time 180min;
(2) modified meerschaum will be added in the comminuting matter obtained in step 1, is put into reaction kettle and is stirred, Mixing time is 150min, is carried out at the same time heating, and heating time is 60-90 DEG C;
(3) material obtained in step 2 is put into comminutor and carries out granulation processing, carried out after the completion of being granulated at drying Reason, obtains finished product.
In summary the invention has the advantages that:The present invention has rich in nutrition content, promotes gold and silver flower growth And the low advantage of fertilizer loss rate, described this body structure of sepiolite have the characteristics that threadiness, can be formed in a liquid needle-shaped Group forms the suspended substance of divergence form structure, therefore with better adsorption effect, makes sea by modified sepiolite in water The structure of afrodite changes, and increases the specific surface area of sepiolite, therefore has higher porosity compared to sepiolite, so as to More outstanding adsorption capacity is made it have, active ingredient that can effectively in fixing soil makes the nutrient in fertilizer uniform It is absorbed by plants, achievees the purpose that improve utilization rate of fertilizer, while can also be effectively promoted the growth of honeysuckle, be its growth Sufficient nutrient is provided, the secondary fertilising of people is also avoided, reduces financial cost;The calcium dodecyl benzene sulfonate can have The wetting of the increase fertilizer of effect and adhesive ability, layer protective layer is formed in fertilizer surface, prevents fertilizer is excessively scattered from causing Insufficient situation is absorbed, so as to improve assimilation effect of the honeysuckle to nutrient in fertilizer;The epoxy resin integument nitric acid Potassium can not only provide potash fertilizer for the growth of honeysuckle, and the epoxy resin integument potassium nitrate cooperation modified meerschaum can be into one The raising utilization rate of fertilizer of step makes the nutrient of fertilizer be released slowly in soil, makes honeysuckle to fertilizer by the setting of coating Nutrient can more fully absorb;Hydroxyl group in the ethoxylated trimethylolpropane triacrylate can be with Epoxy-functional in epoxy resin integument potassium nitrate reacts, and forms Epoxy Interpenetration Polymer Networks compound, so as in fertilizer Expect that surface forms one layer of finer and close controlled release film layer, not only so that fertilizer has better controlled release properties, while have fertilizer There is better osmotic effect, promote absorption of the honeysuckle to fertilizer.
Specific embodiment
Embodiment 1
The preparation of modified meerschaum
The modified meerschaum is made of following steps:
(1) sepiolite is put into reducing mechanism and crushes processing, grinding time 50min obtains powder sepiolite;
(2) sepiolite after crushing is added in into water and triethyl group hexyl phosphoric acid, obtains sepiolite suspension, sepiolite is hanged Supernatant liquid is stirred, and 3h is stood after the completion of stirring, upper suspension is taken, processing is dried;
(3) material obtained in step 2 is added in the sulfuric acid solution of 5-10mol/L, the acid treatment time is 12-18h, is obtained Sour modified meerschaum;
(4) the sour modified meerschaum obtained in step 3 addition surfactant is surface-treated to obtain modified Hai Pao Stone.
Embodiment 2
Weigh 5 parts of Su Gu meter potassium, 3 parts of thiophanate methyl, 1 part of calcium dodecyl benzene sulfonate, epoxy resin integument di(2-ethylhexyl)phosphate It is 4 parts of ammonium, 2 parts of epoxy resin integument potassium nitrate, 5 parts of tripterygium wilfordii, 2 parts of adder-wort, 2 parts of phosphorus humic acid phosphorus, 3 parts of bacillus megaterium, poly- 2 parts of acrylamide, 5 parts of rhizome of cyrtomium, three propylene of 1 part of catalase, 2 parts of nano-calcium carbonate calcium powder and ethoxylated trimethylolpropane 2 parts of acid esters, is put into reducing mechanism and is stirred, grinding time 180min;It will add in the comminuting matter obtained in step 1 Enter 1 part of modified meerschaum, be put into reaction kettle and be stirred, mixing time 150min is carried out at the same time heating, adds The hot time is 60-90 DEG C;The material obtained in step 2 is put into comminutor and carries out granulation processing, is dried after the completion of being granulated Dry-cure obtains finished product.
Embodiment 3
Weigh 15 parts of Su Gu meter potassium, 10 parts of thiophanate methyl, 6 parts of calcium dodecyl benzene sulfonate, epoxy resin integument phosphoric acid 11 parts of diammonium, 12 parts of epoxy resin integument potassium nitrate, 15 parts of tripterygium wilfordii, 10 parts of adder-wort, 8 parts of phosphorus humic acid phosphorus, bacillus megaterium 9 Part, 6 parts of polyacrylamide, 15 parts of rhizome of cyrtomium, 4 parts of catalase, 5 parts of nano-calcium carbonate calcium powder, ethoxylated trimethylolpropane 6 parts of triacrylate is put into reducing mechanism and is stirred, grinding time 180min;The crushed material that will be obtained in step 1 3 parts of modified meerschaum is added in material, is put into reaction kettle and is stirred, mixing time 150min is carried out at the same time heating Processing, heating time are 60-90 DEG C;The material obtained in step 2 is put into comminutor and carries out granulation processing, after the completion of granulation Drying and processing is carried out, obtains finished product.
Embodiment 4
Weigh 25 parts of Su Gu meter potassium, 17 parts of thiophanate methyl, 11 parts of calcium dodecyl benzene sulfonate, epoxy resin integument phosphoric acid 18 parts of diammonium, 22 parts of epoxy resin integument potassium nitrate, 25 parts of tripterygium wilfordii, 18 parts of adder-wort, 14 parts of phosphorus humic acid phosphorus, bacillus megaterium 15 parts, 10 parts of polyacrylamide, 25 parts of rhizome of cyrtomium, 7 parts of catalase, 8 parts of nano-calcium carbonate calcium powder and ethoxylation trihydroxy methyl 10 parts of propane triacrylate is put into reducing mechanism and is stirred, grinding time 180min;The powder that will be obtained in step 1 5 parts of modified meerschaum is added in broken material, is put into reaction kettle and is stirred, mixing time 150min is carried out at the same time Heat, heating time is 60-90 DEG C;The material obtained in step 2 is put into comminutor and carries out granulation processing, has been granulated Into rear carry out drying and processing, finished product is obtained.
Comparative example 1
Weigh 5 parts of Su Gu meter potassium, 3 parts of thiophanate methyl, 4 parts of epoxy resin integument Diammonium phosphate (DAP), 5 parts of tripterygium wilfordii, adder-wort 2 Part, 2 parts of phosphorus humic acid phosphorus, 3 parts of bacillus megaterium, 2 parts of polyacrylamide, 5 parts of rhizome of cyrtomium, 1 part of catalase and nano-calcium carbonate 2 parts of calcium powder, is put into reducing mechanism and is stirred, grinding time 180min;The comminuting matter obtained in step 1 is put into It is stirred in reaction kettle, mixing time 150min, is carried out at the same time heating, heating time is 60-90 DEG C;It will step The material obtained in rapid 2, which is put into comminutor, carries out granulation processing, carries out drying and processing after the completion of being granulated, obtains finished product.
Comparative example 2
Weigh 15 parts of Su Gu meter potassium, 10 parts of thiophanate methyl, 11 parts of epoxy resin integument Diammonium phosphate (DAP), 15 parts of tripterygium wilfordii, It 10 parts of adder-wort, 8 parts of phosphorus humic acid phosphorus, 9 parts of bacillus megaterium, 6 parts of polyacrylamide, 15 parts of rhizome of cyrtomium, 4 parts of catalase and receives 5 parts of Paris white of rice, is put into reducing mechanism and is stirred, grinding time 180min;The crushed material that will be obtained in step 1 Material, which is put into reaction kettle, to be stirred, and mixing time 150min is carried out at the same time heating, heating time 60-90 ℃;The material obtained in step 2 is put into comminutor and carries out granulation processing, drying and processing is carried out after the completion of being granulated, obtains into Product.
Comparative example 3
Weigh 25 parts of Su Gu meter potassium, 17 parts of thiophanate methyl, 18 parts of epoxy resin integument Diammonium phosphate (DAP), 25 parts of tripterygium wilfordii, 18 parts of adder-wort, 14 parts of phosphorus humic acid phosphorus, 15 parts of bacillus megaterium, 10 parts of polyacrylamide, 25 parts of rhizome of cyrtomium, 7 parts of catalase With 8 parts of nano-calcium carbonate calcium powder, it is put into reducing mechanism and is stirred, grinding time 180min;The powder that will be obtained in step 1 Broken material is put into reaction kettle and is stirred, and mixing time 150min is carried out at the same time heating, and heating time is 60-90℃;The material obtained in step 2 is put into comminutor and carries out granulation processing, drying and processing is carried out after the completion of being granulated, obtains To finished product.
Experimental method
Fertilizer treatment will be carried out in the honeysuckle of same growing environment, and growing way is close, is divided into A groups and B groups, A groups are Experimental group, B groups are control group, and every group of 90 plants of selection honeysuckle is divided into three parts, are applied respectively in embodiment and comparative example Fertilizer observes honeysuckle upgrowth situation after maturation and soil property is tested.
The small honeysuckle upgrowth situation of observation post administration is applied, the result is shown in the following table 1.
It can be seen from Table 1 that the comparison of embodiment 2-4 and comparative example 1-3, not only may be used using fertilizer provided by the invention To improve the per mu yield of honeysuckle, while the utilization rate of fertilizer is improved, avoid the excessive loss of fertilizer, and reduce soil The content of middle heavy metal ion has preferable environmental protection characteristic.
The above is the embodiment of the present invention, therefore all construction, feature and principle institutes according to described in the present patent application scope The equivalent change or modification done, is included in the range of present patent application.

Claims (6)

1. a kind of special fertilizer for cultivating of honeysuckle, which is characterized in that be made of the raw material below according to parts by weight:Su Gu meter potassium 5-25 parts, 3-17 parts of thiophanate methyl, 1-11 parts of calcium dodecyl benzene sulfonate, 4-18 parts of epoxy resin integument Diammonium phosphate (DAP), ring 4-16 parts of oxygen coated with resin potassium nitrate, 5-25 parts of tripterygium wilfordii, 2-18 parts of adder-wort, 2-14 parts of phosphorus humic acid phosphorus, bacillus megaterium 3- 15 parts, 2-10 parts of polyacrylamide, 5-25 parts of rhizome of cyrtomium, 5-15 parts of modified meerschaum, 1-7 parts of catalase, nano-calcium carbonate 2-8 parts of powder, 2-10 parts of ethoxylated trimethylolpropane triacrylate;
The modified meerschaum is made of following steps:
(1) sepiolite is put into reducing mechanism and crushes processing, grinding time 50min obtains powder sepiolite;
(2) sepiolite after crushing is added in into water and triethyl group hexyl phosphoric acid, sepiolite suspension is obtained, to sepiolite suspension It is stirred, 3h is stood after the completion of stirring, upper suspension is taken, processing is dried;
(3) material obtained in step 2 is added in the sulfuric acid solution of 5-10mol/L, the acid treatment time is 12-18h, obtains acid and changes Property sepiolite;
(4) the sour modified meerschaum obtained in step 3 addition surfactant is surface-treated to obtain modified meerschaum.
2. the special fertilizer for cultivating of a kind of honeysuckle according to claim 1, which is characterized in that by below according to parts by weight Raw material composition:15 parts of Su Gu meter potassium, 10 parts of thiophanate methyl, 6 parts of calcium dodecyl benzene sulfonate, epoxy resin integument di(2-ethylhexyl)phosphate 11 parts of ammonium, 12 parts of epoxy resin integument potassium nitrate, 15 parts of tripterygium wilfordii, 10 parts of adder-wort, 8 parts of phosphorus humic acid phosphorus, bacillus megaterium 9 Part, 6 parts of polyacrylamide, 15 parts of rhizome of cyrtomium, 10 parts of modified meerschaum, 4 parts of catalase, 5 parts of nano-calcium carbonate calcium powder, ethyoxyl Change 5 parts of trimethylolpropane trimethacrylate.
3. a kind of special fertilizer for cultivating of honeysuckle according to claim 1, it is characterised in that:The surfactant is ten Eight alkyldimethylbenzylammonium aliquats.
4. a kind of special fertilizer for cultivating of honeysuckle according to claim 1, it is characterised in that:The dodecyl benzene sulfonic acid Weight ratio is 1 between calcium and epoxy resin integument potassium nitrate:2.
5. a kind of special fertilizer for cultivating of honeysuckle according to claim 1, it is characterised in that:The three hydroxyl first of ethoxylation Weight ratio is 2 between base propane triacrylate and modified meerschaum:1.
6. according to a kind of preparation method of the special fertilizer for cultivating of honeysuckle of claim 1-2 any one of them, which is characterized in that It comprises the steps of:
(1) the weight composition number of each material in claim 2 is weighed, by Su Gu meter potassium, thiophanate methyl, detergent alkylate sulphur Sour calcium, epoxy resin integument Diammonium phosphate (DAP), epoxy resin integument potassium nitrate, tripterygium wilfordii, adder-wort, phosphorus humic acid phosphorus, huge gemma bar Bacterium, polyacrylamide, rhizome of cyrtomium, catalase, nano-calcium carbonate calcium powder and ethoxylated trimethylolpropane triacrylate are put Enter reducing mechanism to be stirred, grinding time 180min;
(2) modified meerschaum will be added in the comminuting matter obtained in step 1, is put into reaction kettle and is stirred, stirred Time is 150min, is carried out at the same time heating, and heating time is 60-90 DEG C;
(3) material obtained in step 2 is put into comminutor and carries out granulation processing, carried out drying and processing after the completion of being granulated, obtain To finished product.
CN201711198778.8A 2017-11-26 2017-11-26 A kind of special fertilizer for cultivating of honeysuckle and preparation method thereof Pending CN108083886A (en)

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Application publication date: 20180529