CN108078812A - A kind of novel washing shield Two-in-one shampoo and preparation method thereof - Google Patents

Abstract

The present invention provides a kind of novel washings to protect Two-in-one shampoo, is prepared by the raw material of following parts by weight：58 parts of INCROQUAT TMC-80,37 parts of cetostearyl alcohol, 0.5 1.5 parts of myristic acid nutmeg alcohol ester, 0.1 0.3 parts of polyquaternium, 0.5 1.5 parts of dimethyl silicone polymer, ethylene group are double（Two polyoxyethylene groups of dodecyl）35 parts of ammonium bromide, 0.5 2 parts of Coconut Fatty Acid Monoethanolamide, 0.5 1 parts of D panthenols, 23 parts of glycerine, 0.5 1.5 parts of cocoyl glucosides, 12 parts of dodecanamide propyl amine oxide, 0.1 0.15 parts of EDTA disodiums, 0.1 0.15 parts of climbazole, 0.2 0.5 parts of 12 parts of 0.5 1.5 parts of 0.1 0.5 parts of 0.3 0.6 parts of compound, citric acid, essence, protein hydrolysate, guar gum hydroxypropyltrimonium chloride, 60 78 parts of the deionized water of methylisothiazolinone and methylchloroisothiazandnone.Shampoo foam stability cardability, antistatic property, moisture retention, the compliance that the present invention prepares are preferable, effectively hair can be nursed while hair is cleaned, and it is two-in-one to wash shield for really realization.

Description

A kind of novel washing shield Two-in-one shampoo and preparation method thereof

Technical field

The present invention relates to household chemicals technical fields, and in particular to a kind of novel washing shield Two-in-one shampoo and its preparation Method.

Background technology

Shampoo has very long developing history, and people are with cleaning products such as soap, washing powder before the thirties in last century To clean hair；The eighties, the appearance of hair conditioner change people and have one's hair wash and be accustomed to, no longer only focus on the cleaning of hair, but take It is used with hair conditioner, focuses on the submissive of hair, but needed using hair conditioner after hair washing, and hair conditioner is not easy to rinse, and needs more Secondary flushing, loses time and resource；The nineties, Procter ＆ Gamble release " it is two-in-one to wash shield " Rejoice product, are washed instead of traditional Shampoo and hair conditioner, will have one's hair wash and one step of hair care is completed, and it is convenient, not complicated to have the characteristics that.

But due to " washing " and " shield " be anions and canons Action of Surfactant respectively as a result, both frequently result in because Inhibitory action precipitates, and the effect of hair-washing hair-care is not achieved, and the Using experiences of consumer are also satisfied not to the utmost so that two-in-one Shampoo is slightly aobvious inferior in market competition.Then the conditioning-type shampoo using cation opsonizing agent and silicone oil as hair care ingredient should It transports and gives birth to, but still need supplement of the hair conditioner as hair care, it is two-in-one that shield is washed in real realization.

The content of the invention

It is an object of the invention to overcome the shortcomings of the shampoo of the prior art really realize wash shield it is two-in-one, carry For a kind of novel washing shield Two-in-one shampoo and preparation method thereof.

To achieve these goals, the technical solution adopted by the present invention is as follows：

A kind of novel washing protects Two-in-one shampoo, is prepared by the raw material of following parts by weight：Behenyl chlorine Change 5-8 parts of ammonium, 3-7 parts of cetostearyl alcohol, 0.5-1.5 parts of myristic acid nutmeg alcohol ester, 0.1-0.3 parts of polyquaternium, poly- two 0.5-1.5 parts of methylsiloxane, ethylene group are double（Two polyoxyethylene groups of dodecyl）3-5 parts of ammonium bromide, coconut oil monoethanol acyl 0.5-2 parts of amine, 0.5-1 parts of D-pantothenyl aleohol, 2-3 parts of glycerine, 0.5-1.5 parts of cocoyl glucosides, dodecanamide propyl amine oxide 1-2 Part, 0.1-0.15 parts of EDTA- disodiums, 0.1-0.15 parts of climbazole, methylisothiazolinone and methylchloroisothiazandnone are answered Close 0.3-0.6 parts of object, 0.1-0.5 parts of citric acid, 0.5-1.5 parts of essence, 1-2 parts of protein hydrolysate, guar gum oxypropyl trimethyl chlorine Change 0.2-0.5 parts of ammonium, 60-78 parts of deionized water.

Above-mentioned novel washing shield Two-in-one shampoo, wherein, it is prepared by the raw material of following parts by weight：Docosyl 6.5 parts of trimethyl ammonium chloride, 5 parts of cetostearyl alcohol, 1 part of myristic acid nutmeg alcohol ester, 0.2 part of polyquaternium, poly dimethyl 1 part of siloxanes, ethylene group are double（Two polyoxyethylene groups of dodecyl）4 parts of ammonium bromide, 1.25 parts of Coconut Fatty Acid Monoethanolamide, D- are general It is 0.75 part of alcohol, 2.5 parts of glycerine, 1 part of cocoyl glucosides, 1.5 parts of dodecanamide propyl amine oxide, 0.125 part of EDTA- disodiums, sweet 0.3 part of 0.45 part of compound, citric acid, the essence 1 of precious 0.125 part of element, methylisothiazolinone and methylchloroisothiazandnone Part, 1.5 parts of protein hydrolysate, 0.35 part of guar gum hydroxypropyltrimonium chloride, 69 parts of deionized water.

Above-mentioned novel washing shield Two-in-one shampoo, wherein, the methylisothiazolinone and methylchloroisothiazandnone Compound in the weight ratio of methylisothiazolinone and methylchloroisothiazandnone be 1：3.

The preparation method of above-mentioned novel washing shield Two-in-one shampoo, comprises the following steps：

（1）The appropriate deionization of guar gum hydroxypropyltrimonium chloride addition for weighing above-mentioned parts by weight disperses, and is heated with stirring to Guar gum hydroxypropyltrimonium chloride dispersion liquid is made in bright shape；

（2）Weigh the INCROQUAT TMC-80 of above-mentioned weight, cetostearyl alcohol, myristic acid nutmeg alcohol ester, poly- Quaternary ammonium salt adds in remaining deionized water, and constant temperature is stirred to being completely dissolved at 65-75 DEG C, and mixed liquor is made；

（3）The ethylene group of above-mentioned parts by weight is double（Two polyoxyethylene groups of dodecyl）Ammonium bromide, step（1）In Guar obtained Glue hydroxypropyltrimonium chloride dispersion liquid adds in step（2）In in mixed liquor obtained, constant temperature is stirred to complete at 65-75 DEG C Dissolving；

（4）50-52 DEG C is cooled to, adds in dimethyl silicone polymer, glycerine, cocoyl glucosides, the lauramide of above-mentioned parts by weight Propyl amine oxide, constant temperature are stirred to being completely dissolved；

（5）40-45 DEG C is cooled to, adds in the D-pantothenyl aleohol of above-mentioned parts by weight, constant temperature stirs evenly；

（6）It is cooled to 35-40 DEG C, with suitable citric acid tune pH to 6.5, then adds in clout, stir evenly and discharge to obtain the final product.

The preparation method of above-mentioned novel washing shield Two-in-one shampoo, wherein, in step（1）In, the guar gum propyl three The weight ratio of ammonio methacrylate and deionized water is 1:（10-12）.

Shampoo is common personal hair cleaning supplies, primarily serves the cleaning decontamination to hair, sterilization degerming, protects The effect of method, nourishing hair, main component mainly have detergent, softening agent, chelating agent, preservative, relieving itching and removing dandruff agent, pH tune Save agent, thickener.In inventive formulation, ethylene group is double（Two polyoxyethylene groups of dodecyl）Ammonium bromide, coconut oil monoethanol Amide, dodecanamide propyl amine oxide are detergent, are mainly used for the cleaning to hair；INCROQUAT TMC-80, Myristic acid nutmeg alcohol ester, dimethyl silicone polymer, cetostearyl alcohol, polyquaternium be conditioner, mainly for hair into The soft nursing of row；Climbazole is anti-dandruff and itching-relieving agent, mainly removes dandruff, antipruritic；Guar gum hydroxypropyltrimonium chloride is increasing Thick dose, mainly play a part of thickening to shampoo, glycerine, cocoyl glucosides, protein hydrolysate, D-pantothenyl aleohol are moisturizer, are to wash The main nutrient composition of shampoo provides nutritional ingredient for hair；EDTA- disodiums are chelating agent, and citric acid is pH adjusting agent, first The compound of base isothiazolinone and methylchloroisothiazandnone is preservative；In inventive formulation, by the way that ethylene group is double （Two polyoxyethylene groups of dodecyl）The two kinds of cationic surfactant conducts of ammonium bromide and INCROQUAT TMC-80 " washing " and the main base of " shield ", being both avoided that due to cationic and anionic surfactant inhibitory action causes to precipitate, and is not achieved and washes Hair hair care the drawbacks of, while be equipped with again dimethyl silicone polymer make the shampoo prepared really realize wash shield it is two-in-one, and Nonionic surfactant cocoyl glucosides is added, can effectively be compounded with cationic surfactant, promotes hair washing The effect of hair care, addition guar gum hydroxypropyltrimonium chloride is there are mainly two types of effect, first, the quiet of hair can be reduced effectively Electricity, second is that as thickener, conventional shampoo is usually to make thickener with salt, and ethylene group is double in the present invention（Dodecyl two Polyoxyethylene groups）Ammonium bromide belongs to high polymer, need to be by the use of high polymer as thickener.

Raw material used in the present invention is that purchase obtains, wherein, ethylene group is double（Two polyoxyethylene groups of dodecyl）Bromine Change ammonium and belong to Gemini quaternary ammonium salts, choose in the pure Chemical Co., Ltd. of henna academic libraries；D-pantothenyl aleohol, cetostearyl alcohol, glycerine, cocounut oil Base glucosides, polyquaternium, climbazole, guar gum hydroxypropyltrimonium chloride, protein hydrolysate, Coconut Fatty Acid Monoethanolamide, Pork and beans Cool acid nutmeg alcohol ester, dodecanamide propyl amine oxide, essence belong to technical grade, choose in the limited public affairs of the excellent element chemistry science and technology in Qingdao Department；EDTA- disodiums, citric acid belong to analysis it is pure, choose in Tianjin Kermel Chemical Reagent Co., Ltd.；Polydimethylsiloxanes Alkane technical grade is chosen in Jiangxi blue star spark organosilicon Co., Ltd.

By that will have the cationic surfactant ethylene group of cleaning capacity double in the present invention（Two polyoxy second of dodecyl Alkenyl）Ammonium bromide and the cation surface activating INCROQUAT TMC-80 with hair care effect are compounded, and are passed through Investigate the research of compatibility and properties, have developed it is a kind of have both hair washing, the new Two-in-one shampoo of hair care effect, it is full The foot needs of modern fast rhythm of life.

Description of the drawings

Fig. 1 is the surface tension curve of different primary surfactants；

Fig. 2 is foam test result；

Fig. 3 is the wet hair carding property figure of different shampoos（a）Performance map is managed with hair drying comb（b）.

Specific embodiment

Embodiment 1

A kind of novel washing protects Two-in-one shampoo, is prepared by the raw material of following parts by weight：Behenyl chlorine Change 5-8 parts of ammonium, 3-7 parts of cetostearyl alcohol, 0.5-1.5 parts of myristic acid nutmeg alcohol ester, 0.1-0.3 parts of polyquaternium, poly- two 0.5-1.5 parts of methylsiloxane, ethylene group are double（Two polyoxyethylene groups of dodecyl）3-5 parts of ammonium bromide, coconut oil monoethanol acyl 0.5-2 parts of amine, 0.5-1 parts of D-pantothenyl aleohol, 2-3 parts of glycerine, 0.5-1.5 parts of cocoyl glucosides, dodecanamide propyl amine oxide 1-2 Part, 0.1-0.15 parts of EDTA- disodiums, 0.1-0.15 parts of climbazole, methylisothiazolinone and methylchloroisothiazandnone are answered Close 0.3-0.6 parts of object, 0.1-0.5 parts of citric acid, 0.5-1.5 parts of essence, 1-2 parts of protein hydrolysate, guar gum oxypropyl trimethyl chlorine Change 0.2-0.5 parts of ammonium, 60-78 parts of deionized water.

Wherein, methylisothiazolinone and first in the methylisothiazolinone and the compound of methylchloroisothiazandnone The weight ratio of base chloroisothiazole quinoline ketone is 1：3.

The preparation method of above-mentioned novel washing shield Two-in-one shampoo, is as follows：

（1）The appropriate deionization of guar gum hydroxypropyltrimonium chloride addition for weighing above-mentioned parts by weight disperses, and is heated with stirring to Bright shape, obtained guar gum hydroxypropyltrimonium chloride dispersion liquid, the guar gum hydroxypropyltrimonium chloride and deionized water Weight ratio is 1:（10-12）.

（2）Weigh the INCROQUAT TMC-80, cetostearyl alcohol, myristic acid myristyl alcohol of above-mentioned weight Ester, polyquaternium add in remaining deionized water, and constant temperature is stirred to being completely dissolved at 65-75 DEG C, and mixed liquor is made；

（3）The ethylene group of above-mentioned parts by weight is double（Two polyoxyethylene groups of dodecyl）Ammonium bromide, step（1）In Guar obtained Glue hydroxypropyltrimonium chloride dispersion liquid adds in step（2）In in mixed liquor obtained, constant temperature is stirred to complete at 65-75 DEG C Dissolving；

（4）50-52 DEG C is cooled to, adds in dimethyl silicone polymer, glycerine, cocoyl glucosides, the lauramide of above-mentioned parts by weight Propyl amine oxide, constant temperature are stirred to being completely dissolved；

（5）40-45 DEG C is cooled to, adds in the D-pantothenyl aleohol of above-mentioned parts by weight, constant temperature stirs evenly；

（6）It is cooled to 35-40 DEG C, with suitable citric acid tune pH to 6.5, then adds in clout, stir evenly and discharge to obtain the final product.

The shampoo prepared using said ratio and preparation method, foam stability cardability, antistatic property, moisturizing Property, compliance it is preferable, effectively hair can be nursed while hair is cleaned, need not still further using hair care It is two-in-one to wash shield for element, really realization.

Embodiment 2

A kind of novel washing protects Two-in-one shampoo, is prepared by the raw material of following parts by weight：Behenyl chlorine Change 6.5 parts of ammonium, 5 parts of cetostearyl alcohol, 1 part of myristic acid nutmeg alcohol ester, 0.2 part of polyquaternium, dimethyl silicone polymer 1 Part, ethylene group are double（Two polyoxyethylene groups of dodecyl）4 parts of ammonium bromide, 1.25 parts of Coconut Fatty Acid Monoethanolamide, D-pantothenyl aleohol 0.75 Part, 2.5 parts of glycerine, 1 part of cocoyl glucosides, 1.5 parts of dodecanamide propyl amine oxide, 0.125 part of EDTA- disodiums, climbazole 0.125 part, 1 part of 0.3 part of 0.45 part of compound, citric acid, essence, the water of methylisothiazolinone and methylchloroisothiazandnone Solve 1.5 parts of albumen, 0.35 part of guar gum hydroxypropyltrimonium chloride, 69 parts of deionized water.

Wherein, methylisothiazolinone and first in the methylisothiazolinone and the compound of methylchloroisothiazandnone The weight ratio of base chloroisothiazole quinoline ketone is 1：3.

The preparation method of above-mentioned novel washing shield Two-in-one shampoo, is as follows：

（1）The appropriate deionization of guar gum hydroxypropyltrimonium chloride addition for weighing above-mentioned parts by weight disperses, and is heated with stirring to Bright shape, obtained guar gum hydroxypropyltrimonium chloride dispersion liquid, the guar gum hydroxypropyltrimonium chloride and deionized water Weight ratio is 1:11.

（2）Weigh the INCROQUAT TMC-80, cetostearyl alcohol, myristic acid myristyl alcohol of above-mentioned weight Ester, polyquaternium add in remaining deionized water, and constant temperature is stirred to being completely dissolved at 70 DEG C, and mixed liquor is made；

（3）The ethylene group of above-mentioned parts by weight is double（Two polyoxyethylene groups of dodecyl）Ammonium bromide, step（1）In Guar obtained Glue hydroxypropyltrimonium chloride dispersion liquid adds in step（2）In in mixed liquor obtained, constant temperature is stirred to completely molten at 70 DEG C Solution；

（4）51 DEG C are cooled to, adds in dimethyl silicone polymer, glycerine, cocoyl glucosides, the dodecanamide propyl of above-mentioned parts by weight Amine oxide, constant temperature are stirred to being completely dissolved；

（5）43 DEG C are cooled to, adds in the D-pantothenyl aleohol of above-mentioned parts by weight, constant temperature stirs evenly；

（6）It is cooled to 38 DEG C, with suitable citric acid tune pH to 6.5, then adds in clout, stir evenly and discharge to obtain the final product.

The shampoo prepared using said ratio and preparation method, foam stability cardability, antistatic property, moisturizing Property, compliance it is preferable, effectively hair can be nursed while hair is cleaned, need not still further using hair care It is two-in-one to wash shield for element, really realization.

A kind of formula for novel washing shield Two-in-one shampoo that 3-42 of the embodiment of the present invention is provided is shown in Table 1-4.

Table 1

Table 2

Table 3

Table 4

The present invention is obtained by following optimum experimental：

1st, primary surfactant critical micelle concentration compares

（1）Stoste is prepared：1g samples to be tested are accurately weighed respectively to be dissolved in suitable quantity of water, are shaken up and are settled to 100mL, wherein to be measured Sample is double for ethylene group（Two polyoxyethylene groups of dodecyl）Ammonium bromide（E1705）, lauryl sodium sulfate（K12）, lauryl Ammonium sulfate（K12A）；

（2）Prepare liquid is prepared：The above-mentioned stoste difference of 25mL, 20mL, 15mL, 10mL, 5mL, 2.5mL, 1mL, 0.5mL is pipetted respectively It is settled in 50mL volumetric flasks, labeled as prepare liquid 1^#、2^#、3^#、4^#、5^#、6^#、7^#、8^#Number prepare liquid；Pipette respectively 5mL, The 6 of 2.5mL, 1mL^#Number prepare liquid is settled to 50mL, labeled as 9^#、10^#、11^#Number prepare liquid；The 9 of 5mL, 2.5mL are pipetted respectively^# Number prepare liquid is settled to 50mL, labeled as 12^#With 13^#Number prepare liquid；

（3）The surface tension of each prepare liquid is measured, surveys 5 times, is averaged.

2nd, foam performance is tested

By the measure of GB/T13173-2008 detergent foaming powers.

3rd, Hair setting performance test

（1）Topknot pre-processes

Prepare several hair topknots of the same race（Length 50cm, weight about 20g）, rinsed, rubbed twice with 40 DEG C of tap water, dried； Weigh 5g lauryl sodium sulfate（K12）1000mL beakers are dissolved in, are heated to 75 DEG C；Then topknot is soaked in beaker, is put Put 45 DEG C of climatic chambers two hours；Take out topknot, gently rubbing a moment, rinsed well with tap water, then with hair-dryer away from From being blown to half-dried, last naturally dry at topknot 20cm；

（2）Topknot cardability is tested

5g hair washing water samples to be measured are weighed, are applied on topknot, are rubbed two minutes, until generating abundant foam, stand five minutes, so It is rinsed well afterwards with tap water；Excessive moisture is wiped with towel, until topknot does not drip, is combed with comb suitable, is surveyed with pulling force Try instrument hygrometric hair comb rationality；

Then hair is blown at topknot 20cm with hair-dryer half-dried, is combed with comb suitable, naturally dry uses universal tensile The cardability of the dry hair of tester test.

4th, physicochemical property is tested

Shampoo physicochemical property test is carried out according to GB/T29679-2013.

5th, crowd tests investigation

10 subjects experience respectively the shampoo made using the proportioning and method of the embodiment of the present invention 2 and commercially available brand A, Commercially available brand B shampoos provide scoring to its flexibility, antistatic property, moisture retention, cleaning effect, anti-dandruff and itching-relieving effect：5 points- It is fabulous, 4 points-good, 3 points-general, 2 points-poor, 1 point-very poor.

As a result with analysis

1st, different primary surfactant surface tension

Under room temperature, the surface tension of E1705, K12, K12A of different quality concentration, the result is shown in Figure 1 are tested, it can be seen that With the increase of concentration, the surface tension of three all continuously decreases.K12 surface tension when concentration is 1g/L is minimum 24.7mN/m, when concentration is less than 1g/L, with the increase of concentration, surface tension is more and more lower, and it is more aobvious to reduce trend It writes；When concentration is more than 1g/L, with the increase of concentration, surface tension has slow increase tendency.E1705 and K12A are dense There is apparent turning point when spending 0.5g/L, which is 26.3mN/m, and E1705 surface tension is 27.2mN/M. When concentration is 0.0025g/L, the surface tension of K12 and K12A are respectively 71.0mN/m and 71.4mN/m, approach and steam at room temperature The surface tension of distilled water, and the surface tension of E1705 is 64.7mN/m.Further demonstrate that the surface-active of E1705 is preferable.

2nd, the foam performance of shampoo

According to the shampoo that the raw material proportioning in the present embodiment 2 and preparation method make, investigate its foam performance, and with it is commercially available Brand A, commercially available brand B are compared, and the comparing result of foam performance is shown in Fig. 2, it can be seen that using 2 Central Plains of the embodiment of the present invention The commercially available brand A of foam height ratio for the shampoo that material is matched with method makes, the foam height of commercially available brand B shampoos are low, The foam stability that foam height difference when comparing three kinds of shampoo 5min and 10min can be seen that shampoo of the present invention is preferable, It is found in experimentation, prepares the foam of shampoo than brand hair washing water bubble exquisiteness, stability is good, easily rinses.

3rd, carding property is tested

Cardability shows as the frictional force between hair and comb, is tested respectively using raw material proportioning in the embodiment of the present invention 2 The shampoo prepared with method, commercially available brand A shampoos, the cardability of commercially available brand B shampoos, concrete outcome are shown in Fig. 3, Middle Fig. 3 a are wet hair comb rationality, and Fig. 3 b are dry carding.It can be seen from the figure that dry hair is smaller than the frictional force of wet hair More, wherein the wet hair of commercially available brand A shampoos and hair drying comb rationality are all very poor, commercially available brand B shampoos take second place, and the present invention is implemented The cardability for the shampoo that example 2 makes is relatively preferable, illustrates that shampoo provided by the invention has preferable hair care and profit hair Performance.

4th, physical and chemical index is evaluated

The shampoo made using raw material proportioning and method in the embodiment of the present invention 2 is managed according to GB/T29679-2013 Change index test, test result is as shown in table 5.Test result shows that the shampoo that the present invention makes is up to standard, and reaches excellent Grade product level.

5th, crowd tests research and appraisal

Shampoo, the commercially available brand A hair washings that research and appraisal method makes the embodiment of the present invention 2 are tested according to above-mentioned crowd Water, the flexibility of commercially available brand B shampoos, antistatic property, moisture retention, cleaning effect, anti-dandruff and itching-relieving effect score, specifically It the results are shown in Table 6.As can be seen from Table 6, the shampoo that the embodiment of the present invention 2 makes is compared with commercially available brand B shampoos, clearly Clean effect is slightly below commercially available brand B shampoos, antistatic property and moisture retention better than commercially available brand B shampoos, remaining item does not have There is apparent difference；Compared with brand A, items evaluation is above brand A.

Claims (5)

1. a kind of novel washing protects Two-in-one shampoo, which is characterized in that is prepared by the raw material of following parts by weight：Docosane 5-8 parts of base trimethyl ammonium chloride, 3-7 parts of cetostearyl alcohol, 0.5-1.5 parts of myristic acid nutmeg alcohol ester, polyquaternium 0.1- 0.3 part, 0.5-1.5 parts of dimethyl silicone polymer, ethylene group it is double（Two polyoxyethylene groups of dodecyl）3-5 parts of ammonium bromide, cocounut oil Sour single ethanol amide 0.5-2 parts, 0.5-1 parts of D-pantothenyl aleohol, 2-3 parts of glycerine, 0.5-1.5 parts of cocoyl glucosides, dodecanamide propyl 1-2 parts of amine oxide, 0.1-0.15 parts of EDTA- disodiums, 0.1-0.15 parts of climbazole, methylisothiazolinone and methyl chloroisothiazole 1-2 parts of 0.5-1.5 parts of 0.1-0.5 parts of 0.3-0.6 parts of compound, citric acid, essence, protein hydrolysate, the guar gum propyl of quinoline ketone 0.2-0.5 parts of trimethyl ammonium chloride, 60-78 parts of deionized water.

2. novel washing according to claim 1 protects Two-in-one shampoo, which is characterized in that by the raw material system of following parts by weight It is standby to form：6.5 parts of INCROQUAT TMC-80,5 parts of cetostearyl alcohol, 1 part of myristic acid nutmeg alcohol ester, polyquaternary amine 0.2 part of salt, 1 part of dimethyl silicone polymer, ethylene group are double（Two polyoxyethylene groups of dodecyl）4 parts of ammonium bromide, coconut oil list second 1.25 parts of alkylolamides, 0.75 part of D-pantothenyl aleohol, 2.5 parts of glycerine, 1 part of cocoyl glucosides, 1.5 parts of dodecanamide propyl amine oxide, 0.125 part of EDTA- disodiums, 0.125 part of climbazole, the compound 0.45 of methylisothiazolinone and methylchloroisothiazandnone Part, 0.3 part of citric acid, 1 part of essence, 1.5 parts of protein hydrolysate, 0.35 part of guar gum hydroxypropyltrimonium chloride, deionized water 69 Part.

3. Two-in-one shampoo is protected according to any novel washings of claim 1-2, which is characterized in that the methyl-isothiazol The weight ratio of methylisothiazolinone and methylchloroisothiazandnone is 1 in quinoline ketone and the compound of methylchloroisothiazandnone： 3。

4. according to the preparation method of any novel washing shield Two-in-one shampoos of claim 1-2, which is characterized in that including Following steps：

（1）The appropriate deionization of guar gum hydroxypropyltrimonium chloride addition for weighing above-mentioned parts by weight disperses, and is heated with stirring to Guar gum hydroxypropyltrimonium chloride dispersion liquid is made in bright shape；

（2）Weigh the INCROQUAT TMC-80 of above-mentioned weight, cetostearyl alcohol, myristic acid nutmeg alcohol ester, poly- Quaternary ammonium salt adds in remaining deionized water, and constant temperature is stirred to being completely dissolved at 65-75 DEG C, and mixed liquor is made；

（3）The ethylene group of above-mentioned parts by weight is double（Two polyoxyethylene groups of dodecyl）Ammonium bromide, step（1）In Guar obtained Glue hydroxypropyltrimonium chloride dispersion liquid adds in step（2）In in mixed liquor obtained, constant temperature is stirred to complete at 65-75 DEG C Dissolving；

（4）50-52 DEG C is cooled to, adds in dimethyl silicone polymer, glycerine, cocoyl glucosides, the lauramide of above-mentioned parts by weight Propyl amine oxide, constant temperature are stirred to being completely dissolved；

（5）40-45 DEG C is cooled to, adds in the D-pantothenyl aleohol of above-mentioned parts by weight, constant temperature stirs evenly；

（6）It is cooled to 35-40 DEG C, with suitable citric acid tune pH to 6.5, then adds in clout, stir evenly and discharge to obtain the final product.

5. the preparation method of novel washing shield Two-in-one shampoo according to claim 4, which is characterized in that in step（1）In, The weight ratio of the guar gum hydroxypropyltrimonium chloride and deionized water is 1:（10-12）.