TW300252B - - Google Patents

Description

Printed by the Employee Consumer Cooperative of the Central Bureau of Standards of the Ministry of Economic Affairs A7 ΒΊ_ V. Description of the invention () [Technical Field] The present invention is based on a detergent composition which has excellent cleaning power and foaming property, and has low irritability. In particular, B8 can be stably combined with the ionic conditioner of Clams in the detergent composition, and it has a special moisturizing effect on hair washing and conditioning. [Background Art] In the past, anionic surfactants were often used as main bases in detergents, especially hair detergents, because of their excellent cleaning power and foaming power. However, because the anionic surfactant is too irritating, it is often used together with a low-irritant active agent when it is actually used in hair detergents. Therefore, the lower irritant hair detergents have been warmly expected. . In addition, in recent years, a considerable number of cleaning products with adjustment effects »have been proposed for review. There are also quite a lot of substances with adjustment effect which are cationic substances. When the Kuma ionic substance is added to the detergent with M anionic interface activity as the main base, the cationic substance and the anionic surfactant will form a confusion. Therefore, it is very difficult to match and the adjustment effect cannot be fully expressed. Therefore, the non-ionic interface activity _ as the main group _ which is less irritating than the anionic interface active surface, and the ionicity adjustment thinner is easier to match is proposed to review the possibility. For example, the non-ionic interfacial agent alkyl sugar (Alkyl Saccharide), that is, a non-ionic surfactant containing an alkyl sugar bar and »ionic polymer low-resistance cleaning _ composition ( Japanese Patent Publication No. 6-23085), containing alkyl sugar stripe nonionic surfactants, M fatty acid vinegar and anionic surfactants or amphoterics. This paper scale is applicable to China National Standard Rate (CNS) M specifications (210X297 mm) 1 ------------ ^ ------ 1Τ ------ ^ (Please read the precautions on the back before I. Λ. This page) 1. 4 A7 B7_ 5. Description of the invention () Detergent composition for surface-active rinse-off (Japanese Patent Publication No. 6-23086¾) etc. However, due to the price of non-ionic surfactants in the alkyl sugar series, they tried to use relatively low prices Non-ionic surfactants of the polyoxyethylene-alkyl-K (Poly-oxy-ethylene-alkyl-ether) type are used in conjunction with the cleaning scrub. However, since this polyoxyethylene alkyl ether type non-ionic surfactant mostly lacks foaming properties, it can hardly be used as a hair detergent. At most, it is in the amide amine type amphoteric surfactant or When the alkanolamide type non-ionic agent is used as the main active agent, the auxiliary component of the M poly gas ethylene < Poly-oxy-ethylene > type active agent is added to the shampoo. (Japanese Patent Laid-Open No. 55-25436) [Invention of the Invention] Therefore, the object of the present invention is to provide excellent cleansing and foaming properties, low sluggishness, and even stability in conjunction with cationic adjustment for cleaning of epilepsy Iff composition. Printed by the Beigong Consumer Cooperative of the Central Bureau of Standards of the Ministry of Economic Affairs under such circumstances, due to the research efforts of the inventors, it was found that the use of specific polyoxyethylene-alkyl-alky ether) type non-ionic active agent, and sugar beet IMbetaine) type surfactant and specific non-ionic surfactant M specific ratio combination, you can get a commercial cleaning power "high foaming and low irritation detergent The invention was completed. Yidi, the detergent composition of the present invention contains the following components (A), (Β) and (C >: (A > -general formula (1); this paper scale is applicable to the Chinese national standard rate (CNS > A4 Specifications (210X297 gong) 5 A7 B7 printed by the Consumer Labor Cooperative of the Central Standards Bureau of the Ministry of Economic Affairs 5. Description of the invention () R1〇- (CH2CH2〇) nH (1) (In the formula, R1 represents the iodine number 11 ~ 15 straight Bond or branched chain alkyl or alkenyl group, η represents a number from 11 to 30) Polyoxyethylene alkyl ether type nonionic interface activity represented by formula (1) _ weight * percentage ~ 50¾ (B > Beet «(betaine) type thin interface activity, weight percentage U) 1 ~ 10¾ (Ο- general formula (2> ~ (5>; CH3

I, N R2-N > 0 (2)

I CH, (In the formula, Re represents a straight or branched alkyl or alkenyl group of 8 to 18) R3-C〇R4) s-Gt (3) (In the formula, R3 represents an iodine number of 6 ~ The alkyl or alkenyl group of straight chain or branched silver carp of 18, R4 represents an alkylene with an iodine number of 2 to 4, G represents a residue derived from a migrating sugar with an iodine number of 5 or 6, and s is from 0 to 10. Integer, t is a number from 1 to 10) 〇H2C-0-R5

I HC-0-R6 (4)

I H2C-〇-R7 (In the formula, any one of R ·, R «, RT has only one β, M can be 0 = CR · W represents an alkyl or alkenyl group with a straight bond or branched bond of iodine number 6 ~ 18 ), The remaining paper size is applicable to China National Standard (CNS) A4 specification (210X297mm) ------------- installed ------ ordered ------ line- -(Please read the precautions on the back and then V? This page) ~ 6 V. Description of the invention (A7 B7's second symbol represents a hydrogen atom.

(ch2ch2〇) uh IR9-C0N- (CH2CH20) vH (5) Ministry of Economic Affairs Central Bureau of Bureau of Industry and Fisheries Consumer Cooperation Du Yinchuang (where R * represents a straight bond of 8 to 16 or branched alkanes) Group or alkenyl group, U and V each represent an integer from 0 to 10, and U and V have at least one health is 1 to ±) Non-ionic interface represented by the formula (3 >, < 4 >, (5 > Activity_ Emission of 1 or 2 kinds of M on the weight percentage C01 ~ 10: and the weight of the aforementioned component (Α > / [previous component (Β > + previous component < 〇) It is 1/1 ~ 10 / Between 1. The cleansing M composition of the present invention is particularly suitable for use as a cleaning agent for hair and body and bones, in which a cleaning agent for hair and an ion-limiting modifier are combined as the most effective cleaning agent [Detailed description of the invention] Under Μ, the "cleaning in the present invention" I components of the composition. The component (Α) polyoxyvinyl alkyl «type nonionic interface used in the present invention Activity _ has been expressed in the general formula (I > as mentioned above * in the formula, where it represents an alkyl or alkenyl group of straight or branched chains 11 to 15 such as undecyl, dodecyl, deca Alkyl, tetradecyl, pentadecyl, undecenyl, dodecenyl, tridecenyl, tetradecenyl, pentadecenyl, etc. In the composition, the sulfo number of this R1 must be 11 ~ 15 rooms, and the ring gas ethane < eth-ylene-oxide> pay and the number of ears η must be between 11 ~ 30, if it is outside this range, you can not get full cleaning power and foaming Among them, in particular, please read the note on the back of the book. The paper size is based on the Chinese National Standard (CNS) A4 (210X297 mm). 7 Printed by the Ministry of Economic Affairs, Central Standard Falconry Bureau, Beigong Consumer Cooperative. Description of the invention () The linear or branched alkyl or alkenyl group with an iodine number of R1 of 12 ~ 14, and a non-ionic interface activity of polyethoxyethylene alkyl ether type with η between 15 ~ 25 The agent is more ideal for obtaining more foaming properties. "The non-ionic interface of the polyoxyethylene alkyl ether type of the aforementioned component (A) is the main group M of the cleaning_composition of the present invention, It accounts for 5 ~ 50X of the weight of the whole composition (Under M, unless otherwise specified, [%] means [reset%]). Ideally between 10Χ ~ 50¾¾, 10Χ ~ 30Χ To be more ideal, it is most ideal when it is mixed with 10X ~ 20Z. The full cleaning performance and foaming property cannot be obtained. The viscosity of the cleaning agent becomes higher when it exceeds 502, and it is difficult to mix with other ingredients. Used in the present invention Ingredients (B > Betaine) surfactants include carbo-betaine, sulfo-betaine, imidazole-betaine, etc., among which The carbo-betaine type amphoteric surfactant represented by the general formula < 8 >,

CHS

I R-ia-N- (CH2) r-C00M (8)

I ch3 (where Rie represents a linear or branched alkyl or alkenyl group with an iodine number of 8 to 20 * or R19C0NH (CH «> z (Ri3 represents a straight or branched iodine number of 8 to 20 The alkyl or alkenyl group of the bond, z represents an integer of 1 to 5), M ^ hydrogen atom, M metal, or tri-ethanol-a ^ ine, and y is an integer of 1 to 5) or the general formula (9 > The sulfo-betaine type gender interface interface shown in this paper is applicable to the Chinese National Standard (CNS) A4 specification (210X297 mm)-· -------- installation -------- order ---- --Line (please read the notes on the back again. · »This page) (Ministry of Economic Affairs, Central Bureau of Industry and Commerce Employee Consumer Cooperative Printed A7 B7_ V. Description of invention () _ is ideal. Ch3

I R20-N- (CH2) y-S〇3M (9)

I CH3 (In the formula, 11 represents a linear or branched alkyl or alkenyl group with a number of 8 to 20, and M and y have the same meaning as described above). Also, the carbo-betaine amphoteric surfactant represented in the general formula < 8 > is quite ideal, among which * especially the general formula (8 > Rielil RlsCQNH (CHa) 3_ fatty acid-a »ide-propyl-betaine It is the most ideal. The betaine type interface activity of the aforementioned component (B) occupies 1 ~ 10Z in the whole composition, when it is 1 ~ 5ϋ; it is quite ideal, especially when 1 ~ 3Z is combined, it is the most ideal. The complete detergency and foamability cannot be obtained, and the stab resistance will be increased if it exceeds 10%. The component (c) nonionic interface activity used in the present invention is derived from the general formula (2 > Alkyl-di-methyl-amine-oxide, alkyl-saccharide of general formula (3), fatty acid monoglyceride of general formula (4), and general formula (5 > It is composed of alkanolanide (alkanolanide) at least 1% or 2%. These nonionic surfactants are explained below. In the alkyl dimethyl amine oxide represented by the general formula (2) above , Where R · is an alkyl group with an iodine number of 10 ~ 16, especially M decyl, lauryl (dodecyl) and myristyl ( Tetradecyl) is better. This paper scale is applicable to the national standard (CNS) Α4 specification (210Χ297mm) I installed 1 II-ordered IIIIII line (please read the precautions on the back and then this page) AA B7 Printed by the Employee Consumer Cooperative of the Central Falcon Bureau of the Ministry of Economic Affairs 5. Description of the invention () Among the aforementioned general formula (3) alkyl sugars, the number of alkyl groups of R3 in the chemical formula is ideally between 10 and 14, especially decyl (Decyl), dodecyl, and tridecyl * are most ideal. R * is ideal for ethylene and propylene. G is more than single or double ternary used as raw materials. The structure determined by the type of sugar * waiting is "the ideal of sugar, galacto, and fruit. S is ideal between 0 ~ 2, t is ideal between 1 ~ 2. The general formula (3 > The alkyl sugars represented in; especially when S = 0, G is the residue formed by the dextrose. The alkyl polyglycoside (alkyl-polyglucoside) is ideal. In the aforementioned general formula (4) fatty acids In monoglyceride (fatty acid-iono-glyceride), its chemical formula Re is the most ideal when the nitrate number is 8 ~ 12. 4) The combination of ester can form K on any sulfonate of glycerol. In the alkanolamine of general formula (5) above, the chemical formula Rs is a straight or branched alkyl group with an iodine number of 10 to 14. Or an alkenyl group is ideal ", especially a straight bond alkyl group having an iodine number of 11 to 13 is most ideal. U and V are each an integer from 0 to 3, which is ideal 0. In some nonionic surfactants, the alkyl dimethylamine oxide in the aforementioned general formula (2) and, in the aforementioned general formula (4>) The fatty monoglyceride of fatty acid is ideal because it can improve the foamability more. In the general formula (4), the fatty acid monoglyceride in the above formula is Mdecanoic acid-mono-glyceride (decanoic acid monoglyceride), Laurie acid-iono-glyceride (lauric acid monoglyceride) is ideal. The non-ionic interfacial agent of the aforementioned component < c > can be 1 type or 2 ---------------- -Order ------ Line --- (Please read the precautions on the back before h. ≪ »> This I) A paper size is applicable to the Chinese National Standard (CNS) A4 specification (210X297mm) 10 -1 Π _ A7 B7 V. Description of the invention (When used in combination of two types, especially when two or more types are used in combination, it is quite ideal because it can improve the foamability. Non-ionic surfactant of the aforementioned component (c >) It generally accounts for 1 ~ 10J of the total composition: but it is more ideal when it is 1 ~ 5¾. When it is less than U, it is impossible to obtain complete cleansing and foaming properties * It may be exceeded when it meets 10X The cleaning performance of the composition of the present invention, the compounding amount of the aforementioned component (A >, relative to the aforementioned component (B > and (C > compounding *, the weight ratio of the sum of The aforementioned component (A) / (the aforementioned component (B > + front fan component, its value must be between 1/1 ~ 10/1, when it is outside of this range, it cannot simultaneously perform the cleaning performance, foamability, And low irritation. And when the weight ratio is between 3/2 ~ 3/1, it is very ideal because it can improve the foamability. Also, the detergent composition * of the present invention can also be easily compared with The ionicity adjustment of Μ is combined to obtain a complete adjustment effect. The cationic adjustment agents such as ionic surfactants and ion-limiting polymers, etc. In these cationic adjustments, the general formula (6 >; And < 7) The cationic surfactant is the most ideal for height adjustment. (Please read the notes on the back before i " this page). Installation · Printed I 1 0 -Ν-R12 R13 · Χ- (6) (In the formula, R " represents a straight «or branched bond between iodine number 8 ~ 22 Alkyl or alkenyl, R11 represents an argon atom, methyl, ethyl, or straight-chain or branched alkyl or alkenyl with 8 to 22 atoms, and R13 each represents a hydrogen atom, methyl or ethyl , X · means β cable atom or eaves anion group.) This paper scale adopts the Chinese National Standard (CNS) A4 specification (210X 297 mm) 11 Central Standard of the Ministry of Economic Affairs Printed for employee consumer cooperatives 300202 _ ^ _ V. Invention Description () R15 R14- L-(CH2) w- N- (CH2) x- CHCH2- N + -R17 · X- (7)

IIIYZ R16 (In the formula, R1 * represents a linear or branched alkyl or alkenyl group with a sulphur number between 7 and 35, 1116 and 11〃 represent the same or different nick numbers between 1 and 4. Alkyl or hydroxyalkyl or hydrogen atom, L represents -CONJ- (butyl is a hydrogen atom or an alkyl or hydrocarbon alkyl group having an iodine number of 1 to 3), -0-, or -COO-, and Y represents a hydrogen atom , Alkyl, straight-chain or branched alkyl, alkenyl, or hydroxyalkyl with an iodine number of 1 to 36 or the chemical group shown below. Z represents a hydrogen atom or a hydrocarbon group, and W represents R15 丨 +-( CH2) x-chch2-n-r17 · χ-II 'Z R18 2 or 3, X is an integer of 0 or 1 ~ 5, X- is the same as above. However, when X = 1, Z is a hydrogen atom or a hydroxyl group , X = 〇, 2, 3, 4, 5, Z is a hydrogen atom) In the general formula (6) »ionic surfactant, its chemical formula is a linear alkyl group with an iodine number of 14 ~ 22, R "is ideal when methyl or ethyl, R11 * and 11 * 3 are the same or different methyl or ethyl, X- is MCI ·, Br_, (: 1130509- or (^} 111050! 1 -Ideal. In the aforementioned general formula (7> cationic surfactant, its chemical formula V is the sulfonic number 7 ~ 21, Especially when it is 11 ~ 17, and Rie, Rie or tnj are each methyl or ethyl, M is -CONH-, Y is a body atom or hydroxyl group, z * hydrogen atom or the size of this paper is applicable to the Chinese National Standard (CNS) A4 Specifications (210X297 gong mai) (please read the notes on the back before 4, this page) -installation. Order 12 5. Description of the invention () A7 B7 Negative labor consumption cooperation of the Central Bureau of Standards of the Ministry of Economic Affairs Duprinting the hydroxyl cationic interface activity w, because it can have a higher foaming property during washing, it is quite ideal. Some》 Ionicity adjustment _ is generally ideal when it is 0.1 ~ 10Z of the whole composition, and more preferably when it is 1 ~ 10Z, especially in 3 ~ 8Z is the most ideal because of its excellent adjustment effect. In addition, the detergent composition of the present invention can be used together, and the interface activity of the shaded furnace used in general cleaning is used in conjunction with each other (without prejudice to the cost Within the scope of the effects of the invention). The interfacial activity of the anion-like nucleus has alkyl sulfonate, alkyl ester sulfonate, alkyl sulfonate, sulfosuccinate, α-androstate Fatty acid acid 9, α-olefin-sulfonate < cx -olefin-sulfonic acid), saturated or unsaturated fatty acid salt Phosphate monoester type interface active brewing and amido amino acids, etc. Furthermore, the cleaning M composition of the present invention can be combined with polysilicon gas (Silicone) inducing the mule to fall within the range that does not affect the effect of the present invention. This can give a good slippery feel and smilax pine feel. This kind of polysilicone induces the general washing of the genus _ common with cosmetics without restrictions. For example, dimethyl polysilane, methyl phenyl polysilicone Oxyalkane, polyester modified polysiloxane, epoxy modified polysiloxane, alkoxy modified polysiloxane, and amine modified polysiloxane, etc. In addition, the cleaning composition of the present invention, in addition to the aforementioned components, can also be blended with the following components, such as general cosmetics, B-products, and food, if necessary, without impairing the effects of the present invention. , Such as scalp removal, anti-inflammatory ϋ, thinning effect, antiseptic moisturizing, such as propylene glycol (dipropylene glycol), glycerin, diethylethylene glycol monoethyl _ (di-ethylene-glycol- ^ ono-ethyl-ether), mountain (please read the precautions on the back first and then register again-this page)

.tT line This paper scale is applicable to the national standard (CNS) A4 specification (210X297 mm) 13 A7 B7 Printed by the employee consumer cooperative of the Central Standards Bureau of the Ministry of Economic Affairs 5. Description of invention () Pear alcohol, pan-fermentation, etc. The coloring is thin with dyes, pigments, etc .; polypermethrin induces sensitization, such as pearlization, hydroxy-propyl-polyglucosamine, etc .; various blended spices; in addition, it is described in ENCYCLDPEDIA OP SHAMPOO INGREDIENTS (MICELLE 1985) The components and the like can be appropriately blended as long as they do not impair the effects of the present invention. The detergent composition of the present invention can be prepared according to a general method, and can also be hidden in paste, gel, liquid and other dosage forms. [Examples] Hereinafter, examples will be given to explain the present invention in more detail, but the present invention is not limited to the scope of some examples. [Examples 1 to 6 and Comparative Examples 1 to 14] According to the composition shown in Table 1 to Table 3, the shampoo was split by the general method, and the cleansability, foamability, and the following methods were evaluated. Piru irritability. The results are shown in Table 1 ~ Table 3. [Evaluation method] Detergency: M washing soap U is applied to the hair of healthy Japanese women, and then 20 volunteers are washed in 1 minute. After treatment, M is evaluated according to the following criteria. Ο: Very good (The volunteers on 905ίKK estimated that the cleaning power was good.) Ο: Good (805: ~ less than 905; volunteers evaluated that the cleaning power was good) △: Somewhat bad (705; ~ less than 80Χ volunteer The person evaluated that the washing power was good > X: Not good (less than 70: Volunteers rated ϊ evaluated the washing power as good.) Foaming property: dilute the shampoo 20 times the aqueous solution 800 · 1 (liquid 200 paper The standard is applicable to China National Standard Rate (CNS) Α4 specification (210X297mm) I --------- installed ------ ordered ------ line --- (please read the back side first Note one more time, > ν page) (14 A7 B7 V. Description of the invention () Inject into the country barrel, put a stirring feather in the aqueous solution to make it turn around in a shovel for 5 minutes, let stand for 30 seconds, then The foaming property was evaluated according to the criteria under K. In addition, the number of revolutions of the stirring feather was 1000 rpB, which was reversed every 5 seconds. Ο: The foaming property was very good 〇: The foaming property was good △: There was foaming, but the feeling Too little fee X: There is almost no blistering. Irritation of the skin: 20 volunteers, dipping their hands in shampoo for 5 minutes and then drying, and repeating this action 10 times, then evaluate according to the following criteria. O : Volunteers at 90XM feel low stimuli. 80: Volunteers less than 902 feel low irritability A: 70 ~ Volunteers less than feel low irritability X: Volunteers less than 702 feel low剌 性。 (Please read the precautions on the back and then ’'y book). Packing and Threading The paper printed by the Ministry of Economic Affairs, Central Bureau of Standards, and Employee Consumer Cooperatives. The paper size is applicable to the China National Mouth (CNS) A4 specification (2 丨 0X297mm) 15 1C-V. Description of the invention (A7 B7 Composition of the printed form of the Employee Consumer Cooperative of the Central Sample Bureau of the Ministry of Economic Affairs 0:> Example 1 2 3 4 5 6 Polyoxyethylene 15 15 15 15 15 15 base ϋ (Ci., E0 = 20) polyoxyvinyl alkyl K (Ce, E0 = 20) polygaseous vinyl alkyl ether (Ci „, E0 = 40) polygaseous vinyl nonyl benzene Ester (E0 = 20) sodium lauryl acetoacetate (E0 = 3) lauryl phenylaminopropyl lauryl hydroxysulfonic acid 2 2 2 2 2 2 beet silver carp lauryl dimethylamine 3 3 2 Oxide decanoic acid monoacylglycerol decyl glucoside «lauryl alcohol diethylase 3 3 3 1 amide water balance Balance balance balance balance washing power Ο Ο Ο Ο Ο Ο foaming power 〇〇〇 〇〇〇 skin irritation 〇〇〇〇〇〇: general formula (3>, R3 = C1 (JHai, s = 0, G = glucose residue, t = l The number of brackets in parentheses represents the sulfon number of the alkyl group. This paper scale is applicable to China National Standards (CNS) A4 specification (210X297mm). Please read the notes on the back of the A line _ 1 夂 一 16 V. Description of invention () Composition ω Polygas vinyl alkyl ether (Cia , E0 = 20) Polyoxyethylene alkyl ether (Ce, E0 = 20) Polyoxyethylene alkyl ether (Ci ,. E0 = 40) Polyoxyethylene nonanyl phenyl ester (E0 = 20) Laurel Enzymatic ester sodium sulfate (E0 = 3) Lauryl amine ammonium propyl betaine lauryl alcohol hydroxy hindered acid lauryl dimethyl amine oxide decanoic acid army glycerin decyl glucoside lauryl alcohol diethyl yeast Amine water A7 B7 Table 2 Central Bureau of Samples, Ministry of Economic Affairs, Employee Consumer Cooperatives, Printed Power Stimulation Pimples I. Washing and Peeling Comparative Example 1 2 3 4 5 6 7 15 15 15 15 15 15 15 2 2 2 2 2 2 3 3 3 3 Balance Balance Balance Balance Balance Balance Balance Δ Δ 〇Ο 〇Ο 〇X Δ △ Ο X Δ △ 〇〇Δ X 〇〇〇: general formula (3> Middle, RLCuH *, s = 0, G = «Grape residue, t = l The number of brackets in parentheses indicates the number of alkyl sulfon. This paper scale is applicable to China National Standard (CNS) Α4 regulation Grid (210Χ297mm) ---------------- ir ------ ^-r (please read the precautions on the back and then this page) ^ 17 5 2. Description of invention () A7 B7 Printed form 3 of the Employees ’Consumer Cooperative of the Central Standards Bureau of the Ministry of Economic Affairs 3 Composition 0 :) Comparative Example 8 9 10 11 12 13 14 Polyoxyvinyl alkane 15 15 15 15 5 30 Ether (C ", E0 = 20) Polyoxyethylene alkyl ether (Ce. E0 = 20) Polyoxyethylene alkyl ether (Cia, E0 = 40) Polyoxyethylene nonanol phenyl ester (E0 = 20) Lauryl alcohol ester Acid sodium salt (E0 = 3) Lauryl amide propyl 2 5 1 Sugar beet inspection Lauryl hydroxy sulfonic acid Beet old lauryl dimethyl amine oxide capric acid monoglyceryl decyl glucoside Lauryl diethanol 3 3 3 3 3 5 1 amine water balance balance balance balance balance balance balance cleaning power 〇〇〇〇XX XX foaming power △ △ Δ Δ △ Δ X skin irritation 〇〇〇〇Δ △△ △: general formula (3) In the formula, R3 = C1 (> Hai, s = 0, G = «glucose residue, t = l. The sulfon number in parentheses represents the number of alkyl groups. This paper scale is applicable to China National Standard (CNS) A4 specification (210X297mm) ---, --------- ¾ .------ 1T ------ A (please read first (Notes on the back of this page) ~ 18 V. Description of the invention () A7 B7 [Examples 7 to 11 and Comparative Examples 15 to 24] The composition shown in the root table 4 to table 6 is manufactured by the Kato method g fine, as in Example 1, the cleansing property, foaming property and skin irritation were evaluated. In addition, the softness of the hair and the stability of washing after drying were evaluated according to the following methods. The results are shown in Table 4 ~ Table 6. [Evaluation method] The softness of the hair after drying: Take shampoo U and apply it to 20g (15c ·>) of healthy Japanese female hair. After 1 minute of sickle to make it foam, wash with water * and dry with a towel After that, the volunteers performed the hair dryer drying operation. After drying, the softness of the hair was evaluated based on the following criteria. Ο: Very soft and Zen 0: Soft △: Slightly lacking softness X: Rough and hard. Wash The stability of the agent: after the shampoo is manufactured, it will be shaken vigorously, and let it stand at 20 1C for one week and then visually evaluate the state of the liquid. Please read the back item before f ·-· this τ page Printed by the Ministry of Economic Affairs of the Central Bureau of Industry and Fisheries Cooperative Printing Co., Ltd .: Uniform liquid △: Almost uniform liquid, but there are some precipitates X: There are quite a lot of precipitates. This paper scale uses the Chinese country Standard (CNS> Α4 specification (210X297 mm) 19-19 A7 B7 V. Description of invention () Table 4 Composition (%) Example 7 8 9 10 11 Multi-gas vinyl alkane 15 15 15 15 15 Ether (Cia , E0 = 20) sodium lauryl ester sulfonate sodium salt (E0 = 3) laurylamide propyl 2 2 2 2 2 Beetroot lauryl dimethylamine vaporized capric acid monoacylglycerol decyl glucoside lauryl diethanolamide cetyl trimethylammonium nitride 4 grade ammonium salt type compound-2 3 2 3 2 3 2 3 2 3 Water balance balance balance balance balance cleansing power OOOOOO foaming power OOOOOO skin irritation OOOOOO softness of hair after drying OOOOOOOO Stability Ⅱ 〇〇〇〇II J --- 1 ---- installed-(please read the precautions on the back and then this page), booking / printed by the Ministry of Economic Affairs, Central Standard Falcon Bureau employee consumption cooperative ^ ' ch3 C uH ”N n / X ^ / X CHv C i

δ ^ 〇H

The number of brackets in OH brackets indicates the number of sulfides of alkyl groups. The paper size is based on the Chinese National Standard (CNS) A4 specification (210X297mm). 20 _ ο η-A7 B7 V. Description of invention () Employees of the Central Standard Falconry Bureau Consumer Cooperative Printed Table 5 Composition m fch Comparative Example 15 16 17 18 19 Polyoxyvinyl alkane 15 15 15 15 15 Ether (Cia, E0 = 20) Lauryl alcohol ester sodium sulfonate (E0 = 3) Lauric acid Acetaminopropyl beet test lauryl dimethyl amine oxide capric acid monoacyl glycerol decyl glucoside lauryl diethanol amine cetacean trimethyl ammonium nitride 4 grade ammonium salt type compound 3 2 3 2 3 2 3 2 3 Water balance, balance, balance, balance, cleaning power, foaming power, X, △, △, △, △, skin resistance 0, △, 〇〇〇, softness of hair after drying, △ △, △ 〇〇 The stability of detergent

C 1 3H 27

V Η 1 'ch3 Ν \ / \ j .N // \ ^ NN-CH3-Ci J OH 1 ^ CH3

0H The number in parentheses indicates the number of alkyl groups. Please read the notes on the back of the page. Item and then the binding line on this page. The paper size is applicable to the Chinese National Standard (CNS) A4 specification (210X297 mm) 21 A7 B7 V. Invention Description () Table 6

Composition ω tb Comparative Example 20 21 22 23 24 Multi-gas vinyl alkane 15 5 30 group_ (Cl ,, E0 = 20) Lauryl ester sulfonic acid 15 sodium salt (E0 = 3) Aminopropyl laurel laurate Lauryl dimethylamine 2 5 1 2 Oxide decanoic acid monoglycerin glyceryl decyl inulin glycoside lauryl diethyl yeast 2 2 5 1 2 Glutamine cetyl alcohol trimethylammonium nitride 4 grade ammonium salt Type compound water 3 Balance 3 Balance 3 Balance 3 Balance 3 Balance washing power 〇XX 〇〇 Foaming force Δ Δ Δ X 〇Piru stimulus 〇Δ Δ Δ △ Hair softness after drying 〇〇〇〇X Wash Stability of detergent 〇Δ Δ 〇 X

Y ^ N-CE3'C £ ~ OH I CH3 The number of brackets in parentheses indicates the number of alkyl groups. 22 This paper scale applies the Chinese National Standard (CNS) A4 specification (210 X 297 mm) 3002ΰ2 Α7 Β7 5. Description of the invention () C Example 12 (shampoo)] According to the composition shown below, it is prepared by the K common method Dee shampoo. The shampoo thus obtained has excellent cleansing properties and lathering properties. * It has little stab resistance. (Composition) • (96) Polyoxyethylene (15) lauryl ester 10.0 lauryl hydroxy sulfonate betaine-1.0 emulsyl glucoside 〃 2.0 monodecanoic acid capric acid 3.0 cationized arsenic beta >; 0.3 Hydroxyethylferricin 3> 0.1 Silicone latex 1.0 pH adjuster appropriate amount of pigment appropriate amount of fragrance appropriate amount of water balance I,. 4— I n IIIIII order — IIII line (please read the precautions on the back and then expand this page) (Printed by the Ministry of Economic Affairs Central Bureau of Customs and Industry Beigong Consumer Cooperatives total 100.0 u:-General formula (3> Medium, R3 = C " Hai, S = 0, G = Glucose residue, t = 1.2: JR400 (manufactured by UCC } 3 >: HEC-SE850 (Xinyue Chemical Industry Co., Ltd.): SM-8702C (Dongxiang • Dow Corning Corporation) This paper scale applies the Chinese National Standard (CNS) A4 specification (210X297 mm) 23 V. Description of invention ( A7 B7 [Inspection Example 13 (Washing Airunsi Double-Effect Detergent)] According to the following composition, the shampoo-running bismuth double-effect detergent is split by an ordinary method. The resulting detergent, its wash It has excellent net performance and foaming property, has low stab resistance and has high silk effect. ) (%) Polyoxyethylene (20> lauryl ester, lauryl dimethylamine gasification, lauric acid, amidopropyl, sweet decanoate, capric acid, monoacylglycerol, trimethylstearic acid, ammonium helium, silicon latex β > Distearic Acid Vinyl Glycerin pH Adjuster Pigment Perfume Water 10 0 Appropriate amount, proper placement and appropriate balance (please read the precautions on the back page and then this page) Total 100 Printed by the Employees' Consumer Cooperative of the Central Standard Falcon Bureau, Ministry of Economic Affairs: BY22-029 (Dongsang • Dow Corning Corporation) This paper scale is applicable to China National Standard (CNS) Α4 specification (210X297mm) 24 V. Description of invention () A 7 B7 C funding example 14 (shower milk)] The body wash is manufactured according to the following general composition method. The body wash obtained therefrom has excellent cleansing performance, foaming performance, and low irritation. (Composition) (%) Polyvinyl vinyl (20 > Lauryl Alkyl Ester 16.0 Lauryl Alcohol Diethyl Glyceramide 3.0 Amyl «5 Glycosides β > 2.0 Lauryl Molybdopropyl Beet_ 2.0 Decanoic Acid Monoglycerin Glycerin 2.0 Distearic Acid Vinyl Glycerin 1.0 pH Adjuster Amount Colors are suitable, spices are suitable for water balance. 11 ^ I ^ 141 nj (please read the precautions on the back page and this page first) Total 100.0 Printed by the Ministry of Economic Affairs, China National Bureau of Customs and Appraisal of Beigong Consumer Cooperatives: General formula (3), R3 = C " Hai, S = 0 、 G = Sample vine residues, t = 1.2 This paper scale is applicable to the Chinese National Standard (CNS) A4 specification (210x297 mm) 25 Α? Β7 V. Description of invention () [Availability in industry] The detergent composition of the invention is excellent in both cleaning power and lathering property, and has low stab resistance. Therefore, it is suitable for use as a detergent for hair and a detergent for body and skull. Also, it can be easily and stably combined with the cationic adjustment, especially when used as a hair detergent (shampoo and moisturizing double-effect detergent), the hair dye is very soft in the wash and irrigation, and it is also dry after drying. It is soft and natural and very easy to comb. Within the spirit and scope of the present invention, the practitioner should be able to understand that there may be many variations or changes in the present invention. Therefore, the above-mentioned embodiment is not only a partial example of the present invention, and all variants or modifications of various forms should be included in the invention described in the appended request garden. -------------- installed ------ ordered ------ line-J (please read the notes on the back first and then "quote this page" 1. Ministry of Economic Affairs The standards of the paper printed by the Bureau of Standards and Staff's Consumer Cooperative apply the Chinese National Standard (CNS) Α4 specification (210X297mm) 26-ΟΛ

Claims (1)

Printed by the Beigong Consumer Cooperative of the Central Escalation Bureau of the Ministry of Economic Affairs 6. Scope of patent application 1. A detergent composition containing the following components (A), (B) and (C): (A) — General formula (1 ): RM-aHiCHzOh-H CD (where R1 represents a linear or branched alkyl or alkenyl group with a number of 11 to 15 and η represents a number between 11 and 30) Alkyl ether (Poly-oxy-ethlene-alky buether) type non-ionic interface activity is thin 5 ~ 50% (weight ratio); (B) sweet sifty (betaine) type interface activity 1 ~ 1〇 by weight ratio) ; (C) from the general formula (2) ~ (5): CH3 I R2-N> 0 (2) I ch3 (where, Ra represents the alkyl or alkenes of straight silver carp or branched silver carp 8-8 Radical) R3-C〇R4), -G, (3) (wherein R3 represents a straight bond or branched chain alkyl or alkenyl group with sulfonic number 6 ~ 18, R * represents alkylene with a number 2 ~ 4) G · G represents a sulfonic acid residue of 5 or 6 sulfones, s is an integer from 0 to 10, t is an integer from 1 to 10> h2c-o-r5 HC-0-R6 (4) I HiiC-0- R7 The size of this paper is applicable to the national standard of CNS A4 specification (210X297mm) I ~ I ^ ~ n II Pack i I booked-IIIII Brigade ( Read the precautions on the back ^ \ this page) (27 A8 B8 C8 D8 printed by the Zhengong Consumer Cooperative of the Central Standards Bureau of the Ministry of Economic Affairs. Six, the scope of patent application (where Re, Re, R7 can only be 0 = CR * (Re is a straight-chain or branched alkyl or alkenyl group with a 6 to 18 number), and the remaining 2 is a radium atom.) (CH2CH20) uH… I (5) R9-CON-CCH2〇 H2〇) vH (where R9 represents a straight bond or branched chain alkyl group or alkenyl group of 8 to 16 sulfone numbers, U and V each represent an integer of 0 to 10, at least one of u and V has a commission of 1 or more ) One or two or more of the nonionic surfactants indicated (weight ratio 1 to 103!), And the weight of the aforementioned component (A) / [the aforementioned component (B) + the aforementioned component (C)] The ratio is between 1/1 ~ 10/1. 2. The detergent composition as stated in item 1 of Shenzhao Patent Fanpu, where the general formula (1) above is a straight chain with a number of 12 ~ 14 Or branched alkyl or alkenyl group, η is a value of 15 ~ 25. 3. As mentioned in the application of the patent Jieguo, the Jieer composition, wherein the aforementioned component (B) is a carbonyl beet ( carbo-betaine) type intersex active interface 4. For the cleaning composition described in item 1 of the patent application, the aforementioned component (C) is a non-ionic surface active agent represented by the aforementioned general formula (2) or (4). 5. For example, the detergent composition contained in item 1 of the scope of the patent application, where the first ——. Hl ·.! ---- installed ------ ordered ------ travel (please first Read the precautions on the back 1, page of this page) This paper uses the Chinese National Standard (CNS) A4 specifications (210X297 mm) 28 κ Naling «30i) 2b2 A8 B8 C8 D8 Patent application The weight ratio of said component (A) / [the aforementioned component (B) + the aforementioned component (C)] is 3/2 ~ 3/1. 6. For example, the detergent composition contained in item 1 of the patent application Fan Nai contains cationic catfish. 7. The cleaning thin composition as described in item 6 of the patent application park contains the aforementioned cationic adjustment thin (the weight ratio is between 0.1 ~ 10X. 8. As stated in the application range of item 6 or 7 Cleansing bribe composition, wherein the aforementioned cation adjustment film is the cation interface activity shown in the following general formula (6) or (7) _; R10- N-R13 · χ- (6) --T --- L-- ---. Install-- (please read the notes on the back &v; write this page first) I (In the formula, R111 represents a straight or branched alkyl or alkenyl group with a nitrate number of 8 ~ 22, R1 * Means «atom, methyl, ethyl, or straight or branched alkyl or alkenyl group with 8 to 22 sulfone numbers, Ria and R〃 each mean gas atom, methyl or ethyl, X · means Halogen atom or organic anion group.) Printed by the Ministry of Tourism and Economics, Central Rongju Bureau of Consumer Labor Cooperatives R14- L-(CH2) w- N- (CH2) x- CHCH2- N-R17 · X " Ϋ Z R16 ( 7) (In the formula, R14 represents an alkyl or alkenyl group with a linear or branched chain sulfonic acid number between 7 and 35. Rie, Rie & RlT are the same or different sulfonic acid numbers. Standard (CNS> A4 specification (210X297mm 29 Patent application range A8 B8 C8 D8 Alkyl, alkynyl alkyl or hydrogen atom between 1 ~ 4, L represents -CONJ- (Butyl is hydrogen atom or alkyl or alkyl group with 1 ~ 3 number ), -0-, or -C00-, Y is a hydrogen atom, an alkyl group, an alkyl group, an alkenyl group, a hydroxyalkyl group having a straight number of 1 to 36 or a branched bond, or is represented by the following formula -(CH2) x-CHCH2 IZ -N + -R17 χ-Z is a hydrogen atom or an oxo group, W is a value of 2 or 3, X is an integer of 0 or 1 ~ 5, X- is the same as above. , X = 1 * Z represents a hydrogen atom or a hydroxyl group, X = 0, 2, 3, 4, 5 and Z is a hydrogen atom) As the detergent composition contained in item 8 of the patent application * The ionicity adjusting agent is the ion-limiting interfacial activity shown in the above general formula (7>. I, .1 I binding " cheng-Λ (please read the precautions on the back-. 'K this page) Economy Ministry of Central Standards Bureau Beigong Consumer Cooperatives China-made 30 paper standards using the Chinese National Standards (CNS) A4 wash (210X297 mm)