DE3910652C2 - Surfactant mixture for use in foaming body cleansers - Google Patents

Surfactant mixture for use in foaming body cleansers

Info

Publication number
DE3910652C2
DE3910652C2 DE19893910652 DE3910652A DE3910652C2 DE 3910652 C2 DE3910652 C2 DE 3910652C2 DE 19893910652 DE19893910652 DE 19893910652 DE 3910652 A DE3910652 A DE 3910652A DE 3910652 C2 DE3910652 C2 DE 3910652C2
Authority
DE
Germany
Prior art keywords
weight
sodium lauryl
surfactant mixture
lauric acid
mixture according
Prior art date
Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
Revoked
Application number
DE19893910652
Other languages
German (de)
Other versions
DE3910652A1 (en
Inventor
Heinrich Baust
Wolfgang Dr Gros
Current Assignee (The listed assignees may be inaccurate. Google has not performed a legal analysis and makes no representation or warranty as to the accuracy of the list.)
Reckitt Benckiser NV
Original Assignee
Joh A Benckiser 67059 Ludwigshafen De GmbH
Joh A Benckiser GmbH
Priority date (The priority date is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the date listed.)
Filing date
Publication date
Application filed by Joh A Benckiser 67059 Ludwigshafen De GmbH, Joh A Benckiser GmbH filed Critical Joh A Benckiser 67059 Ludwigshafen De GmbH
Priority to DE19893910652 priority Critical patent/DE3910652C2/en
Priority to AT35590A priority patent/AT403005B/en
Publication of DE3910652A1 publication Critical patent/DE3910652A1/en
Application granted granted Critical
Publication of DE3910652C2 publication Critical patent/DE3910652C2/en
Anticipated expiration legal-status Critical
Revoked legal-status Critical Current

Links

Classifications

    • A—HUMAN NECESSITIES
    • A61—MEDICAL OR VETERINARY SCIENCE; HYGIENE
    • A61K—PREPARATIONS FOR MEDICAL, DENTAL OR TOILETRY PURPOSES
    • A61K8/00—Cosmetics or similar toiletry preparations
    • A61K8/18—Cosmetics or similar toiletry preparations characterised by the composition
    • A61K8/30—Cosmetics or similar toiletry preparations characterised by the composition containing organic compounds
    • A61K8/46—Cosmetics or similar toiletry preparations characterised by the composition containing organic compounds containing sulfur
    • A61K8/463—Cosmetics or similar toiletry preparations characterised by the composition containing organic compounds containing sulfur containing sulfuric acid derivatives, e.g. sodium lauryl sulfate
    • A—HUMAN NECESSITIES
    • A61—MEDICAL OR VETERINARY SCIENCE; HYGIENE
    • A61K—PREPARATIONS FOR MEDICAL, DENTAL OR TOILETRY PURPOSES
    • A61K8/00—Cosmetics or similar toiletry preparations
    • A61K8/18—Cosmetics or similar toiletry preparations characterised by the composition
    • A61K8/30—Cosmetics or similar toiletry preparations characterised by the composition containing organic compounds
    • A61K8/33—Cosmetics or similar toiletry preparations characterised by the composition containing organic compounds containing oxygen
    • A61K8/39—Derivatives containing from 2 to 10 oxyalkylene groups
    • A—HUMAN NECESSITIES
    • A61—MEDICAL OR VETERINARY SCIENCE; HYGIENE
    • A61K—PREPARATIONS FOR MEDICAL, DENTAL OR TOILETRY PURPOSES
    • A61K8/00—Cosmetics or similar toiletry preparations
    • A61K8/18—Cosmetics or similar toiletry preparations characterised by the composition
    • A61K8/30—Cosmetics or similar toiletry preparations characterised by the composition containing organic compounds
    • A61K8/40—Cosmetics or similar toiletry preparations characterised by the composition containing organic compounds containing nitrogen
    • A61K8/44—Aminocarboxylic acids or derivatives thereof, e.g. aminocarboxylic acids containing sulfur; Salts; Esters or N-acylated derivatives thereof
    • A61K8/442—Aminocarboxylic acids or derivatives thereof, e.g. aminocarboxylic acids containing sulfur; Salts; Esters or N-acylated derivatives thereof substituted by amido group(s)
    • A—HUMAN NECESSITIES
    • A61—MEDICAL OR VETERINARY SCIENCE; HYGIENE
    • A61Q—SPECIFIC USE OF COSMETICS OR SIMILAR TOILETRY PREPARATIONS
    • A61Q19/00—Preparations for care of the skin
    • A61Q19/10—Washing or bathing preparations
    • C—CHEMISTRY; METALLURGY
    • C11—ANIMAL OR VEGETABLE OILS, FATS, FATTY SUBSTANCES OR WAXES; FATTY ACIDS THEREFROM; DETERGENTS; CANDLES
    • C11D—DETERGENT COMPOSITIONS; USE OF SINGLE SUBSTANCES AS DETERGENTS; SOAP OR SOAP-MAKING; RESIN SOAPS; RECOVERY OF GLYCEROL
    • C11D1/00—Detergent compositions based essentially on surface-active compounds; Use of these compounds as a detergent
    • C11D1/88—Ampholytes; Electroneutral compounds
    • C11D1/94—Mixtures with anionic, cationic or non-ionic compounds
    • A—HUMAN NECESSITIES
    • A61—MEDICAL OR VETERINARY SCIENCE; HYGIENE
    • A61K—PREPARATIONS FOR MEDICAL, DENTAL OR TOILETRY PURPOSES
    • A61K2800/00—Properties of cosmetic compositions or active ingredients thereof or formulation aids used therein and process related aspects
    • A61K2800/40—Chemical, physico-chemical or functional or structural properties of particular ingredients
    • A61K2800/59—Mixtures
    • A61K2800/596—Mixtures of surface active compounds
    • C—CHEMISTRY; METALLURGY
    • C11—ANIMAL OR VEGETABLE OILS, FATS, FATTY SUBSTANCES OR WAXES; FATTY ACIDS THEREFROM; DETERGENTS; CANDLES
    • C11D—DETERGENT COMPOSITIONS; USE OF SINGLE SUBSTANCES AS DETERGENTS; SOAP OR SOAP-MAKING; RESIN SOAPS; RECOVERY OF GLYCEROL
    • C11D1/00—Detergent compositions based essentially on surface-active compounds; Use of these compounds as a detergent
    • C11D1/02—Anionic compounds
    • C11D1/04—Carboxylic acids or salts thereof
    • C11D1/06—Ether- or thioether carboxylic acids
    • C—CHEMISTRY; METALLURGY
    • C11—ANIMAL OR VEGETABLE OILS, FATS, FATTY SUBSTANCES OR WAXES; FATTY ACIDS THEREFROM; DETERGENTS; CANDLES
    • C11D—DETERGENT COMPOSITIONS; USE OF SINGLE SUBSTANCES AS DETERGENTS; SOAP OR SOAP-MAKING; RESIN SOAPS; RECOVERY OF GLYCEROL
    • C11D1/00—Detergent compositions based essentially on surface-active compounds; Use of these compounds as a detergent
    • C11D1/02—Anionic compounds
    • C11D1/12—Sulfonic acids or sulfuric acid esters; Salts thereof
    • C11D1/14—Sulfonic acids or sulfuric acid esters; Salts thereof derived from aliphatic hydrocarbons or mono-alcohols
    • C11D1/146—Sulfuric acid esters
    • C—CHEMISTRY; METALLURGY
    • C11—ANIMAL OR VEGETABLE OILS, FATS, FATTY SUBSTANCES OR WAXES; FATTY ACIDS THEREFROM; DETERGENTS; CANDLES
    • C11D—DETERGENT COMPOSITIONS; USE OF SINGLE SUBSTANCES AS DETERGENTS; SOAP OR SOAP-MAKING; RESIN SOAPS; RECOVERY OF GLYCEROL
    • C11D1/00—Detergent compositions based essentially on surface-active compounds; Use of these compounds as a detergent
    • C11D1/66—Non-ionic compounds
    • C11D1/667—Neutral esters, e.g. sorbitan esters
    • C—CHEMISTRY; METALLURGY
    • C11—ANIMAL OR VEGETABLE OILS, FATS, FATTY SUBSTANCES OR WAXES; FATTY ACIDS THEREFROM; DETERGENTS; CANDLES
    • C11D—DETERGENT COMPOSITIONS; USE OF SINGLE SUBSTANCES AS DETERGENTS; SOAP OR SOAP-MAKING; RESIN SOAPS; RECOVERY OF GLYCEROL
    • C11D1/00—Detergent compositions based essentially on surface-active compounds; Use of these compounds as a detergent
    • C11D1/66—Non-ionic compounds
    • C11D1/72—Ethers of polyoxyalkylene glycols
    • C—CHEMISTRY; METALLURGY
    • C11—ANIMAL OR VEGETABLE OILS, FATS, FATTY SUBSTANCES OR WAXES; FATTY ACIDS THEREFROM; DETERGENTS; CANDLES
    • C11D—DETERGENT COMPOSITIONS; USE OF SINGLE SUBSTANCES AS DETERGENTS; SOAP OR SOAP-MAKING; RESIN SOAPS; RECOVERY OF GLYCEROL
    • C11D1/00—Detergent compositions based essentially on surface-active compounds; Use of these compounds as a detergent
    • C11D1/88—Ampholytes; Electroneutral compounds
    • C11D1/90—Betaines

Description

Die vorliegende Erfindung betrifft eine Tensidmischung für den Einsatz in schäumenden Körperreinigungsmitteln, insbesondere für ein Duschgel.The present invention relates to a surfactant mixture for the Use in foaming body cleansing preparations, especially for a shower gel.

Wegen seiner besonders guten Schaumbildung gilt Natriumlauryl­ sulfat als besonders geeignet für den Einsatz in schäumenden Körperreinigungsmitteln wie z. B. in Duschgels. Nun ist aber bekannt, daß Natriumlaurylsulfat zu einer deutlichen Irritation der menschlichen Haut führt.Because of its particularly good foaming, sodium lauryl is used sulfate is particularly suitable for use in foaming Body cleansers such. B. in shower gels. Now it is known that sodium lauryl sulfate to a significant irritation the human skin leads.

Aus der WO 88/05655 A1 ist ein Körperpflegemittel bekannt, welches neben Seife als waschaktive Substanz mindestens ein synthetisches Detergenz enthält. Durch die Mischung werden die nachteiligen Eigenschaften einer isolierten Anwendung zurückgedrängt und eine bessere Hautverträglichkeit erreicht. Als Syndet werden Alkalisalze von Carboxymethylethern von Fettsäureamiden oder Fettsäuren oder Fettalkoholen mit der Seife kombiniert.From WO 88/05655 A1 a personal care product is known, which besides soap as a detergent substance at least one contains synthetic detergent. The mixture will be the adverse properties of an isolated application pushed back and achieved a better skin tolerance. As syndet alkali metal salts of carboxymethyl ethers of Fatty acid amides or fatty acids or fatty alcohols with the Soap combined.

In "Parfümerie und Kosmetik", 59, Nr. 3/78 auf S. 73 ist z. B. hierzu ausgesagt, daß bei Seifen ein Maximum der Irritation bei einer Kettenlänge von C₁₂ bis C₁₄ gefunden wird. Bei Tensiden wird eine zusätzliche Abhängigkeit von der chemischen Konsti­ tution beobachtet, insbesondere negativ wirkt sich hier der Laurylrest aus (S. 75 r. Sp.).In "Perfumery and Cosmetics", 59, no. 3/78 on p. B. stated that soaps have a maximum of irritation a chain length of C₁₂ to C₁₄ is found. For surfactants becomes an additional dependence on the chemical consti observed, especially negatively affects the Lauryl residue (pp. 75 rd Sp.).

Aus diesem Grunde wurde auf den Einsatz dieser Substanzen verzichtet, obwohl sie hinsichtlich der Schaumwirkung unüber­ troffen sind.For this reason, was based on the use of these substances omitted, although they are unsatisfactory in terms of foam effect are affected.

Die vorliegende Erfindung hat sich daher die Aufgabe gestellt, eine Zusammensetzung von Tensiden unter Einschluß von Natrium­ laurylsulfat zu finden, das sich die gute Schaumbildung des Natriumlaurylsulfats zunutze macht, die jedoch hautfreundlich ist und Irritationen sowie allergische Reaktionen vermeidet und nicht auf den Einsatz Dioxin enthaltender Ersatzstoffe wie Fettalkohol­ ethersulfate angewiesen ist. Darüberhinaus soll sie den Nachteil bekannter Natriumlaurylsulfatsysteme nicht aufweisen, die leicht irreversibel auskristallisieren und demgegenüber bis Temperaturen von -10°C stabil sind.The present invention therefore has the task a composition of surfactants including sodium lauryl sulfate, which is the good foaming of the Sodium lauryl sulfate makes use, which is however skin-friendly and avoids irritations and allergic reactions and not on the use of dioxin-containing substitutes such as fatty alcohol ether sulfates is dependent. In addition, it should be the disadvantage  known sodium lauryl sulfate systems which are light crystallize irreversibly and in contrast to temperatures are stable from -10 ° C.

Die Lösung dieser Aufgabe gelingt überraschenderweise durch eine Kombination von Natriumlaurylsulfat mit Natrium-laurylpolyglycol­ ether-carboxylat und Laurinsäure-amidopropyl-betain, wobei im Gegensatz zur Lehre des obengenannten Standes der Technik lediglich Lauryl-verbindungen mit Kettenlängen von 12 Kohlen­ stoffen eingesetzt sind. Die Produkte weisen eine hohe Hautver­ träglichkeit auf, sie irritieren weder die Haut primär noch lösen sie allergische Reaktionen aus.The solution of this problem is surprisingly achieved by a Combination of sodium lauryl sulfate with sodium lauryl polyglycol ether-carboxylate and lauric-amidopropyl-betaine, wherein im Contrary to the teaching of the above-mentioned prior art only lauryl compounds with chain lengths of 12 carbons substances are used. The products have a high Hautver they do not irritate the skin either they cause allergic reactions.

Als besonders schonend und im Hinblick auf den Einsatzzweck wirksam haben sich Mengenverhältnisse von Laurinsäure-amidopropyl-betain zu Laurylsulfat zu Natrium­ laurylpolyglycolether-carboxylat wie 1 : 1,5 : 1,8 bis 1 : 3,2 : 4,3 erwiesen.As a particularly gentle and with regard to the purpose effective proportions of Lauric acid amidopropyl betaine to lauryl sulfate to sodium lauryl polyglycol ether carboxylate such as 1: 1.5: 1.8 to 1: 3,2: 4,3 proved.

Ein weiterer Vorteil der erfindungsgemäßen Mischungen liegt darin, daß sie eiweißfrei formuliert werden können, da auch die hierbei bekannten Aminosäurengemische allergen sein können. Als Rückfettungskomponente wird die Verwendung von Laurinsäure­ monoglycerid zusammen mit der erfindungsgemäßen Tensidmischung vorgeschlagen.Another advantage of the mixtures according to the invention lies in that they can be formulated protein-free, as well as the In this case known amino acid mixtures can be allergenic. The refatting component is the use of lauric acid monoglyceride together with the surfactant mixture according to the invention proposed.

Zur Solubilisierung von üblicherweise in derartigen Hautreini­ gungsmitteln eingesetzten Parfümölen hat sich der Einsatz von Laurylalkoholethoxylat besonders bewährt, da dieses Mittel Öl besonders gut löslich macht, andererseits dieses Ethoxylat ein Mittel ist, das Augenbrennen verhindert. For the solubilization of usually in such Hautreini The use of perfume oils in perfume oils has increased Lauryl alcohol ethoxylate is especially proven as this agent is oil on the other hand makes this ethoxylate a particularly soluble Means is that prevents eye burning.  

Ein Duschgel, wie es bevorzugt mit Hilfe der vorgenannten Substanzen herstellbar ist, enthält neben dem schon genannten Parfümöl Kochsalz als Verdickungsmittel sowie Substanzen zur Konservierung und Wasser.A shower gel, as preferred by the aforementioned Substances can be produced, contains in addition to the already mentioned Perfume oil cooking salt as a thickening agent as well as substances for Preservation and water.

Erfindungsgemäß zusammengesetzte Duschgele weisen vorzugsweise die nachstehenden Mengenverhältnisse auf:Shower gels composed according to the invention preferably have the following proportions:

Natriumlaurylpolyglycolether-carboxylat, 22%-igSodium lauryl polyglycol ether carboxylate, 22% 20-35 Gew.-%20-35% by weight Natriumlaurylsulfat 28%-igSodium lauryl sulfate 28% 14-25 Gew.-%14-25% by weight Laurinsäure-amidopropyl-betain 30%-igLauric acid amidopropyl betaine 30% 8-16 Gew.-%8-16% by weight Laurinsäure-monoglycerid 20%-igLauric acid monoglyceride 20% 1-5 Gew.-%1-5% by weight Laurylalkohol-ethoxylatLauryl alcohol ethoxylate 0,1-0,5 Gew.-%0.1-0.5% by weight Parfümölperfume oil 0,5-2 Gew.-%0.5-2% by weight NaClNaCl 2-10 Gew.-%2-10% by weight Konservierungsmittelpreservative 0,05-0,5 Gew.-%0.05-0.5% by weight Wasserwater add 100add 100 sowie gegebenenfalls Farbstoffeand optionally dyes

Mit Ausnahme des Parfümöls des Kochsalzes und des Konservie­ rungsmittels weisen alle wesentlichen Komponenten C₁₂-Ketten­ längen auf.With the exception of the perfume oil of the cooking salt and the Konservie Means have all the essential components C₁₂ chains length up.

Ausführungsbeispielembodiment Rohstofferaw materials %% Na-Laurylpolyglycolether-carboxylat, 22%-igNa lauryl polyglycol ether carboxylate, 22% 29,8929.89 Na-Laurylsulfat, 28%-igNa lauryl sulfate, 28% 17,8617.86 Laurinsäure-amidopropyl-betain, 30%-igLauric acid amidopropyl betaine, 30% strength 13,0013,00 Laurinsäure-monoglycerid, 20%-igLauric acid monoglyceride, 20% 1,001.00 Laurylalkohol-ethoxylatLauryl alcohol ethoxylate 0,200.20 Parfümölperfume oil 1,101.10 NaClNaCl 4,504.50 Konservierungsmittelpreservative 0,100.10 Farbstoffedyes 0,100.10 Wasser, entkeimtWater, sterilized add 100add 100

Als Konservierungsbeispiel wurde eine Mischung von Dibromdicyano­ butan mit Phenoxyethanol im Verhältnis von 20 : 80 verwendet.As a preservative example, a mixture of Dibromdicyano Butane with phenoxyethanol in the ratio of 20: 80 used.

Das Mittel ist eiweißfrei.The remedy is protein-free.

Unter Verwendung eines üblichen Testpflasters wurde die obige Zusammensetzung auf klinisch gesunde Haut aufgelegt und fixiert. Das Testpflaster wurde nach 24 Stunden entfernt und das Testfeld beurteilt. Weitere Beurteilungen fanden nach 48 und 72 Stunden statt. Es wurden 50 Personen untersucht, wovon 10 Allergiker waren.Using a standard test plaster, the above Composition applied to clinically healthy skin and fixed. The test patch was removed after 24 hours and the test field  assessed. More reviews took place after 48 and 72 hours instead of. 50 people were examined, 10 of them allergic persons were.

Weder nach 24, nach 48, noch nach 72 Stunden fanden sich positive oder zweifelhafte Reaktionen, so daß sich kein Hinweis auf primäre Irritation oder die Auslösung bereits bestehender Allergie gegen das Produkt auffinden ließ.Neither after 24, after 48, nor after 72 hours were positive or dubious reactions, so no indication of primary irritation or triggering of existing ones Allergy to the product was found.

Die Formulierung ist frei von Dioxanspuren, enthält kein Nitrosamin oder zur Bildung von Dioxan oder Nitrosamin geeignete Stoffe und enthält kein Kathon (Isothiazolinon).The formulation is free of dioxane traces, contains no Nitrosamine or suitable for the formation of dioxane or nitrosamine Substances and contains no Kathon (isothiazolinone).

Claims (5)

1. Tensidmischung für den Einsatz in schäumenden Körperreini­ gungsmitteln, gekennzeichnet durch eine Kombination von Natriumlaurylpolyglycolether-carboxylat, Natriumlaurylsulfat und Laurinsäure-amidopropyl-betain.1. A surfactant mixture for use in foaming body cleansing agents, characterized by a combination of sodium lauryl polyglycol ether-carboxylate, sodium lauryl sulfate and lauric amidopropyl betaine. 2. Tensidmischung nach Anspruch 1, gekennzeichnet durch ein Mengenverhältnis von Laurinsäure-amidopropyl-betain zu Natrium-laurylsulfat und zu Natrium-laurylpolyglycolether- carboxylat wie 1 : 1,5 : 1,8 bis 1 : 3,2 : 4,3.2. Surfactant mixture according to claim 1, characterized by a Amount ratio of lauric acid amidopropyl betaine to Sodium lauryl sulfate and to sodium lauryl polyglycol ether carboxylate such as 1: 1.5: 1.8 to 1: 3.2: 4.3. 3. Tensidmischung nach Anspruch 1 oder 2, gekennzeichnet durch einen Gehalt an Laurinsäuremonoglycerid.3. Surfactant mixture according to claim 1 or 2, characterized by a content of lauric acid monoglyceride. 4. Tensidmischung nach einem oder mehreren der Ansprüche 1-3, gekennzeichnet durch einen Gehalt an Laurylalkohol- ethoxylat. 4. surfactant mixture according to one or more of claims 1-3, characterized by a content of lauryl alcohol ethoxylate.   5. Tensidmischung nach einem oder mehreren der Ansprüche 1-4, gekennzeichnet durch folgende Zusammensetzung Natriumlaurylpolyglycolether-carboxylat, 22%ig 20-35 Gew.-% Natriumlaurylsulfat, 28%ig 14-25 Gew.-% Laurinsäure-amidopropyl-betain, 30%ig 8-16 Gew.-% Laurinsäure-monoglycerid, 20%ig 1-5 Gew.-% Laurylalkohol-ethoxylat 0,1-0,5 Gew.-% Parfüm 0,5-2 Gew.-% NaCl 2-0 Gew.-% Konservierungsmittel 0,05-0,5 Gew.-% Wasser add 100
5. Surfactant mixture according to one or more of claims 1-4, characterized by the following composition Sodium lauryl polyglycol ether-carboxylate, 22% 20-35% by weight Sodium lauryl sulfate, 28% 14-25% by weight Lauric acid amidopropyl betaine, 30% 8-16% by weight Lauric acid monoglyceride, 20% 1-5% by weight Lauryl alcohol ethoxylate 0.1-0.5% by weight Perfume 0.5-2% by weight NaCl 2-0% by weight preservative 0.05-0.5% by weight water add 100
DE19893910652 1989-04-01 1989-04-01 Surfactant mixture for use in foaming body cleansers Revoked DE3910652C2 (en)

Priority Applications (2)

Application Number Priority Date Filing Date Title
DE19893910652 DE3910652C2 (en) 1989-04-01 1989-04-01 Surfactant mixture for use in foaming body cleansers
AT35590A AT403005B (en) 1989-04-01 1990-02-15 TENSIDE MIXTURE FOR USE IN FOAMING BODY CLEANSING AGENTS

Applications Claiming Priority (1)

Application Number Priority Date Filing Date Title
DE19893910652 DE3910652C2 (en) 1989-04-01 1989-04-01 Surfactant mixture for use in foaming body cleansers

Publications (2)

Publication Number Publication Date
DE3910652A1 DE3910652A1 (en) 1990-10-04
DE3910652C2 true DE3910652C2 (en) 1997-12-18

Family

ID=6377676

Family Applications (1)

Application Number Title Priority Date Filing Date
DE19893910652 Revoked DE3910652C2 (en) 1989-04-01 1989-04-01 Surfactant mixture for use in foaming body cleansers

Country Status (2)

Country Link
AT (1) AT403005B (en)
DE (1) DE3910652C2 (en)

Families Citing this family (7)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
DE3930725A1 (en) * 1989-09-14 1991-03-21 Benckiser Gmbh Joh A EXTRA-MILDE SHOWER AND HAIR SHAMPOO FORMULATION WITH LOW TENSION CONCENTRATION
GB9006254D0 (en) * 1990-03-20 1990-05-16 Unilever Plc Perfumed products
DE4020500A1 (en) * 1990-06-27 1992-01-02 Benckiser Gmbh Joh A EXTRA MILDE SHOWER AND HAIR CHAMPOO FORMULATION WITH LOW TENSION CONCENTRATION
DE4304066C2 (en) * 1993-02-11 1995-01-26 Beiersdorf Ag Use of high electrolyte concentrations in cosmetic cleaners
JPH06279228A (en) * 1993-03-30 1994-10-04 Kao Corp Foaming composition
JP3400126B2 (en) * 1994-08-24 2003-04-28 花王株式会社 Detergent composition
GB9613899D0 (en) * 1996-07-03 1996-09-04 Procter & Gamble Cleansing compositions

Family Cites Families (5)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
DE2847439A1 (en) * 1978-11-02 1980-05-22 Henkel Kgaa Cosmetic cleanser e.g. shampoo contg. alkali aluminium silicate - prepd. from initial components by co-pptn. during cleanser prodn.
GR77266B (en) * 1981-08-06 1984-09-11 Colgate Palmolive Co
DE3224585A1 (en) * 1982-07-01 1984-01-05 Henkel Kgaa HAIR TREATMENT PREPARATION
DE3703258A1 (en) * 1987-02-04 1988-08-18 Eau De Cologne & Parfuemerie Fabrik 4711 Soap-based personal care products
DE3713684A1 (en) * 1987-04-24 1988-11-10 Wella Ag PRESERVED HAIR AND BODY DETERGENTS AND USE OF A PRESERVATIVE COMBINATION

Also Published As

Publication number Publication date
ATA35590A (en) 1997-03-15
AT403005B (en) 1997-10-27
DE3910652A1 (en) 1990-10-04

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Owner name: BENCKISER N.V., SCHIPHOL, NL

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Free format text: R. ZELLENTIN UND KOLLEGEN, 67061 LUDWIGSHAFEN