CN108071025A - A kind of color paste formulation method for improving textile coating stamp anti-microbial property - Google Patents
A kind of color paste formulation method for improving textile coating stamp anti-microbial property Download PDFInfo
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- CN108071025A CN108071025A CN201711142727.3A CN201711142727A CN108071025A CN 108071025 A CN108071025 A CN 108071025A CN 201711142727 A CN201711142727 A CN 201711142727A CN 108071025 A CN108071025 A CN 108071025A
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- D—TEXTILES; PAPER
- D06—TREATMENT OF TEXTILES OR THE LIKE; LAUNDERING; FLEXIBLE MATERIALS NOT OTHERWISE PROVIDED FOR
- D06P—DYEING OR PRINTING TEXTILES; DYEING LEATHER, FURS OR SOLID MACROMOLECULAR SUBSTANCES IN ANY FORM
- D06P1/00—General processes of dyeing or printing textiles, or general processes of dyeing leather, furs, or solid macromolecular substances in any form, classified according to the dyes, pigments, or auxiliary substances employed
- D06P1/44—General processes of dyeing or printing textiles, or general processes of dyeing leather, furs, or solid macromolecular substances in any form, classified according to the dyes, pigments, or auxiliary substances employed using insoluble pigments or auxiliary substances, e.g. binders
- D06P1/46—General processes of dyeing or printing textiles, or general processes of dyeing leather, furs, or solid macromolecular substances in any form, classified according to the dyes, pigments, or auxiliary substances employed using insoluble pigments or auxiliary substances, e.g. binders using compositions containing natural macromolecular substances or derivatives thereof
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- D—TEXTILES; PAPER
- D06—TREATMENT OF TEXTILES OR THE LIKE; LAUNDERING; FLEXIBLE MATERIALS NOT OTHERWISE PROVIDED FOR
- D06P—DYEING OR PRINTING TEXTILES; DYEING LEATHER, FURS OR SOLID MACROMOLECULAR SUBSTANCES IN ANY FORM
- D06P1/00—General processes of dyeing or printing textiles, or general processes of dyeing leather, furs, or solid macromolecular substances in any form, classified according to the dyes, pigments, or auxiliary substances employed
- D06P1/02—General processes of dyeing or printing textiles, or general processes of dyeing leather, furs, or solid macromolecular substances in any form, classified according to the dyes, pigments, or auxiliary substances employed using azo dyes
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- D—TEXTILES; PAPER
- D06—TREATMENT OF TEXTILES OR THE LIKE; LAUNDERING; FLEXIBLE MATERIALS NOT OTHERWISE PROVIDED FOR
- D06P—DYEING OR PRINTING TEXTILES; DYEING LEATHER, FURS OR SOLID MACROMOLECULAR SUBSTANCES IN ANY FORM
- D06P1/00—General processes of dyeing or printing textiles, or general processes of dyeing leather, furs, or solid macromolecular substances in any form, classified according to the dyes, pigments, or auxiliary substances employed
- D06P1/14—General processes of dyeing or printing textiles, or general processes of dyeing leather, furs, or solid macromolecular substances in any form, classified according to the dyes, pigments, or auxiliary substances employed using phthalocyanine dyes without vatting
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- D—TEXTILES; PAPER
- D06—TREATMENT OF TEXTILES OR THE LIKE; LAUNDERING; FLEXIBLE MATERIALS NOT OTHERWISE PROVIDED FOR
- D06P—DYEING OR PRINTING TEXTILES; DYEING LEATHER, FURS OR SOLID MACROMOLECULAR SUBSTANCES IN ANY FORM
- D06P1/00—General processes of dyeing or printing textiles, or general processes of dyeing leather, furs, or solid macromolecular substances in any form, classified according to the dyes, pigments, or auxiliary substances employed
- D06P1/44—General processes of dyeing or printing textiles, or general processes of dyeing leather, furs, or solid macromolecular substances in any form, classified according to the dyes, pigments, or auxiliary substances employed using insoluble pigments or auxiliary substances, e.g. binders
- D06P1/445—Use of auxiliary substances before, during or after dyeing or printing
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- D—TEXTILES; PAPER
- D06—TREATMENT OF TEXTILES OR THE LIKE; LAUNDERING; FLEXIBLE MATERIALS NOT OTHERWISE PROVIDED FOR
- D06P—DYEING OR PRINTING TEXTILES; DYEING LEATHER, FURS OR SOLID MACROMOLECULAR SUBSTANCES IN ANY FORM
- D06P1/00—General processes of dyeing or printing textiles, or general processes of dyeing leather, furs, or solid macromolecular substances in any form, classified according to the dyes, pigments, or auxiliary substances employed
- D06P1/44—General processes of dyeing or printing textiles, or general processes of dyeing leather, furs, or solid macromolecular substances in any form, classified according to the dyes, pigments, or auxiliary substances employed using insoluble pigments or auxiliary substances, e.g. binders
- D06P1/46—General processes of dyeing or printing textiles, or general processes of dyeing leather, furs, or solid macromolecular substances in any form, classified according to the dyes, pigments, or auxiliary substances employed using insoluble pigments or auxiliary substances, e.g. binders using compositions containing natural macromolecular substances or derivatives thereof
- D06P1/48—Derivatives of carbohydrates
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- D—TEXTILES; PAPER
- D06—TREATMENT OF TEXTILES OR THE LIKE; LAUNDERING; FLEXIBLE MATERIALS NOT OTHERWISE PROVIDED FOR
- D06P—DYEING OR PRINTING TEXTILES; DYEING LEATHER, FURS OR SOLID MACROMOLECULAR SUBSTANCES IN ANY FORM
- D06P1/00—General processes of dyeing or printing textiles, or general processes of dyeing leather, furs, or solid macromolecular substances in any form, classified according to the dyes, pigments, or auxiliary substances employed
- D06P1/44—General processes of dyeing or printing textiles, or general processes of dyeing leather, furs, or solid macromolecular substances in any form, classified according to the dyes, pigments, or auxiliary substances employed using insoluble pigments or auxiliary substances, e.g. binders
- D06P1/64—General processes of dyeing or printing textiles, or general processes of dyeing leather, furs, or solid macromolecular substances in any form, classified according to the dyes, pigments, or auxiliary substances employed using insoluble pigments or auxiliary substances, e.g. binders using compositions containing low-molecular-weight organic compounds without sulfate or sulfonate groups
- D06P1/651—Compounds without nitrogen
- D06P1/65106—Oxygen-containing compounds
- D06P1/65118—Compounds containing hydroxyl groups
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Abstract
The present invention relates to a kind of color paste formulation methods for improving textile coating stamp anti-microbial property, belong to textile printing and dyeing processing technique field.The present invention, which uses that antiseptic protein powder is added in paste formula system to prepare, becomes print paste, and this protein powder constituents with antibacterial functions are just contained in such print paste.When printing fabric using the print paste prepared, wherein the antiseptic protein powder contained is transferred on fabric, using antibacterial functions possessed by antiseptic protein powder, so as to improve the antibiotic property of pigment printing fabric.When coloured antiseptic protein powder is used to prepare print paste, the fabric printed with this mill base can show the visual effect of colour mixture.The method of the preparation paint-printing colour size of the present invention, mill base process for preparation simple possible have operability, can realize industrialization.
Description
Technical field
The present invention relates to a kind of color paste formulation methods for improving textile coating stamp anti-microbial property, belong to textile printing and dyeing processing skill
Art field.
Background technology
Pigment printing is will be on the fibrous material of clagging to printing by means of the effect of adhesive in print paste
A kind of printing method.Since its is simple for process, production procedure is short, and water need not be generally carried out especially after pigment printing
It washes, so as to save substantial amounts of water, and reduces the discharge of pollution, be a kind of production and processing mode of clean environment firendly, so
It is deep to be welcome by printing and dyeing enterprise.Coating, adhesive, thickener and other auxiliary agents are typically contained in the mill base composition of pigment printing
With the main components such as water.Wherein, coating provides colouring component in the mill base of pigment printing, is by the pigment of organic (or inorganic)
Add the ground manufactured slurry of water with auxiliary agents such as corresponding dispersant, wetting agent, colloid protective agent, preservatives.Using painting
When expecting stamp, due to the organic solvent not soluble in water and conventional of the granules of pigments in coating so that coating is not direct to fiber
Property, as long as ensureing that the adhesive in print paste there are enough adhesivenesses, stamp can be almost carried out to all fibrous materials, it can
It avoids the problem that bringing using different dyes Graft versus host disease during dye printing, the stamp for multiple fiber blending product provides very
Good solution route, pigment printing technique are particularly suitable for the stamp of polyester cotton.
With advances in technology with the raising of living standards of the people, the textile with antimicrobial health care function is increasingly subject to
The attention of consumer.Realize that the antibiotic property means of fabric are various, open magazine《Textile journal》, the 9th phase of 2011 publication dates
It is had studied in entitled " influence of the silver plated fiber content to antibacterial fabric performance " and silver-plated nylon fibre is passed through into different tissues knot
Institute's attainable antibacterial effect when structure is weaved, when silver plated fiber content is 11.99%, bacteriostasis rate can reach more than 99%.It is public
Open magazine《Printing and dyeing》, the 8th phase of 2004 publication dates entitled " anti-microbial properties of chitosan finishing cotton fabrics " middle use is not
Chitosan oxidative breakdown product with molecular weight arranges cotton fabrics, and cotton fabrics can be made to obtain certain antibacterial effect
Fruit.Open magazine《Hunan Institute Of Engineering's journal》, the 2nd phase of 2016 publication dates it is entitled " antibiotic finish of cotton fabric and its
Cotton fabric is subjected to antibiotic finish with antibacterial finishing agent in performance test ", finds the anti-microbial property of cotton fabric as antiseptic is dense
The raising of degree and enhance.These open source literatures show that the acquisition of antibacterial fabric performance is whole generally by function is carried out to fabric
Manage what is realized.
101886328 A of Chinese patent application publication No. CN, November 17 2010 Shen Qing Publication date, innovation and creation
Entitled " antibacterial treatment process of wool worsted fabric ", this application discloses one kind with nano composite antibacterial finishing agent CTA-
736 be auxiliary agent, and antimicrobial treatment is first carried out to wool top, then carries out antimicrobial treatment to fabric, so that fabric has the side of anti-microbial property
Method.This method carries out antimicrobial treatment, the essence or finishing functions of processing method in terms of fiber and two, fabric.It is Chinese special
Sharp 102677221 A of application publication number CN, 2012 Shen Qing Publication dates September 19 days, a kind of entitled " fibre of innovation and creation
Tie up the preparation method of cellulose protein fiber ", protein powder is added in rayon spinning stoste this application discloses a kind of
Spinning is carried out, to prepare the method for regenerated fiber cellulose protein composite fibre.This be to protein powder in spinning field
Using for adding the protein powder of functionalization in paint-printing colour size, to improve the disclosure of printing fabric functional
Document is then rarely reported.
The content of the invention
In view of the above problems, it is an object of the invention to improve the anti-microbial property of pigment printing fabric, by
When preparing paint-printing colour size, the protein powder after antimicrobial treatment is added in into paste formula, utilizes these additions
Antiseptic protein powder possessed by antiseptic, to improve the anti-microbial property of pigment printing fabric.
To achieve these goals, technical solution is：
A kind of color paste formulation method for improving textile coating stamp anti-microbial property, the color paste formulation method press following step
It is rapid to carry out：
A. the antimicrobial treatment of protein powder
The protein powder that grain size is 10~20 μm is placed in and is mixed by absolute ethyl alcohol, distilled water and antiseptic CTA-736
It in the treatment fluid formed, is ultrasonically treated in supersonic generator, the treatment fluid containing protein powder after supersound process
Through suction filtration, sonicated protein powder is obtained, then the sonicated protein powder that will be obtained is dried, at heat
Reason, becomes antiseptic protein powder, wherein, the bath raio for the treatment of fluid is 1:20~1:50, the volume ratio of absolute ethyl alcohol and distilled water
For 2:8~4:The concentration of 6, antiseptic CTA-736 are 5~15g/L, and ultrasonic power is 1200~1800 watts, is ultrasonically treated temperature
It spends for 30~40 DEG C, sonication treatment time is 15~20min, and drying temperature is 30~40 DEG C, and drying time is 25~30min,
Heat treatment temperature is 100~110 DEG C, and heat treatment time is 10~15min；
B. the preparation of mill base
Under the conditions of 200~300r/min mixing speeds and 6~10min mixings time, the antibacterial after antibacterial processed
In protein powder, be separately added into quality be the distilled water of 6~10 times of antiseptic protein powder, 2~3 times of absolute ethyl alcohol, 4~
6 times of adhesive UDT premixs are combined, then in 400~600r/min mixing speeds and 80~100min mixing time items
It is stirred evenly under part, preparing becomes antiseptic protein powder slurry, then adds 10 by the mass percent of antiseptic protein powder slurry
~20% coating and 1~2.6% sodium alginate, in 600~800r/min mixing speeds and 100~120min mixings time
Under the conditions of stir evenly, prepare become mill base.
The protein powder is one kind in silk powder or wool powder or down-powder.
The coating is one kind in azo coating or phthalocyanines coating.
As a result of above technical scheme, a kind of mill base preparation side for improving textile coating stamp anti-microbial property of the present invention
The technical characterstic of method is：
After antimicrobial treatment, the group with sterilizing function contained in antiseptic is connected to protein powder
On protein powder, so that protein powder has anti-microbial property.Antiseptic protein powder is added to paste formula system
Middle prepare becomes print paste, and this protein powder constituents with antibacterial functions are just contained in such print paste.When
When printing fabric using print paste, wherein the antiseptic protein powder contained is transferred on fabric, antibacterial protein is utilized
Antibacterial functions possessed by matter powder, so as to improve the antibiotic property of pigment printing fabric, to meet people to antibiotic fabric
Demand.These antiseptic protein powders added in paste formula, can also be dyed to different face before antimicrobial treatment
Color carries out antimicrobial treatment again, and it is coloured antiseptic protein powder to be so added in print paste, is printed with this mill base
The fabric of system can show the visual effect of colour mixture.The method of the preparation paint-printing colour size of the present invention, the letter of mill base process for preparation
It is single feasible, there is operability, can realize industrialization.
Specific embodiment
With reference to specific embodiment, to a kind of mill base preparation side of raising textile coating stamp anti-microbial property of the present invention
Method is described in further detail.
A kind of color paste formulation method for improving textile coating stamp anti-microbial property, the color paste formulation method press following step
It is rapid to carry out：
A. the antimicrobial treatment of protein powder
The protein powder that grain size is 10~20 μm is placed in and is mixed by absolute ethyl alcohol, distilled water and antiseptic CTA-736
It in the treatment fluid formed, is ultrasonically treated in supersonic generator, the treatment fluid containing protein powder after supersound process
Through suction filtration, sonicated protein powder is obtained, then the sonicated protein powder that will be obtained is dried, at heat
Reason, becomes antiseptic protein powder, wherein, the bath raio for the treatment of fluid is 1:20~1:50, the volume ratio of absolute ethyl alcohol and distilled water
For 2:8~4:The concentration of 6, antiseptic CTA-736 are 5~15g/L, and ultrasonic power is 1200~1800 watts, is ultrasonically treated temperature
It spends for 30~40 DEG C, sonication treatment time is 15~20min, and drying temperature is 30~40 DEG C, and drying time is 25~30min,
Heat treatment temperature is 100~110 DEG C, and heat treatment time is 10~15min.
Protein powder is by one kind in the protein fibres such as silk fiber or wool fiber or down fiber, by machine
Protein micro particles of the grain size scale that tool cutting and grinding forms at 10~20 μm, the too small then difficulty of processing of grain size is big, increases
Production cost；Grain size is larger, may result in the reduction of post-coatings PRINTED FABRIC crock fastness.By fiber process into
During powder particle, being acted on merely through physical mechanical, the basic chemical composition of these protein powders remains as protein,
The maximum of generation, which changes, to be to process front and rear appearance physical aspect and the difference of scale, and material appearance is by original one-dimensional linear
Become zero dimension powder, protein powder particle has great increase compared with fibrinogen specific surface area, this cause protein powder compared with
Fibrinogen significantly increases the adsorption capacity for contaminating material.Also, protein fibre is in after fine is processed into powder
Reveal more active groups, the chemical reaction ability of powder is significantly improved compared with fibrinogen.When to protein powder progress antibacterial
During processing, under the treatment conditions identical with protein fibre, the antiseptic of protein powder absorption can be distributed in the table of bigger
On area so that on the powder of same units area, it is difficult to reach the handling result consistent with fiber.So carrying out antibacterial
During processing, the dosage of antiseptic also will be improved accordingly, to meet actual demand.Antimicrobial treatment solution is by absolute ethyl alcohol, distilled water
It is mixed with antiseptic CTA-736, wherein, the bath raio for the treatment of fluid is 1:20~1:50, the volume of absolute ethyl alcohol and distilled water
Than for 2:8~4:The concentration of 6, antiseptic CTA-736 are 5~15g/L.Distilled water can make protein powder that swelling occur and disperse
In treatment fluid, dosage should ensure that the abundant swelling of protein powder.Absolute ethyl alcohol molecular weight is small, surface tension is low, viscosity
It is small, permeability is strong, can accelerate the swelling of protein powder, and can reduce the aggregation of powder in water, be conducive to point of powder
It dissipates, powder is made preferably to be reacted with antiseptic.Antiseptic CTA-736 is Nano type complex antimicrobials, has broad-spectrum antiseptic, washable
The characteristics of efficient, can effectively sterilize, is antibacterial, and can eliminate peculiar smell.Protein powder is after antimicrobial treatment, in antiseptic
The group with sterilizing function contained is connected on protein powder, so that protein powder has antibacterial effect.
Since the adsorption capacity of protein powder confrontation microbial inoculum is stronger, so to ensure treatment effect, the concentration of antiseptic CTA-736 is true
It is set to 5~15g/L.The volume ratio of absolute ethyl alcohol and distilled water is unsuitable excessively high, so that antiseptic CTA-736 stablizes in treatment fluid
In the presence of.It is sufficiently impregnated and reacts for guarantee protein powder, the bath raio for the treatment of fluid is arranged to 1:20~1:50.By protein powder
Be impregnated in the treatment fluid containing absolute ethyl alcohol, distilled water and antiseptic CTA-736 of preparation, under the conditions of ultrasonic environment into
Row is ultrasonically treated, and ultrasonic power is 1200~1800 watts, and it is 30~40 DEG C to be ultrasonically treated temperature, sonication treatment time for 15~
20min.Ultrasonic wave is that a kind of frequency is 2 × 104Hz~2 × 109The mechanical wave of Hz, action principle are shaking using ultrasonic wave
Dynamic effect, makes protein powder generate substantial amounts of gap during the treatment to accommodate more antiseptics, and makes swelling
Protein powder is in loose state, in addition, the cavitation effect generated using ultrasonic wave, by antiseptic under HI high impact effect
Push deeper region to, so as to accelerate the reaction rate of protein powder and antiseptic and improve reaction efficiency.Protein powder
When being handled in antimicrobial treatment solution, the adjusting of ultrasonic power should be with being ultrasonically treated the parameters such as temperature, sonication treatment time
Mutually coordinated consistent, ultrasonic power is high, then treatment temperature and processing time can accordingly decrease.After supersound process
Protein powder adsorbed substantial amounts of antiseptic, some antiseptic has occurred instead under the energy booster action of ultrasonic wave
It should.The treatment fluid containing protein powder after will be sonicated filters, then is adsorbed with antiseptic by what suction filtration obtained
Protein powder dried under 30~40 DEG C of lower temperature, it is uniform and stable in favor of subsequent heat treatment effect.Heat treatment
Temperature is 100~110 DEG C, and heat treatment time is 10~15min.Heat treatment be thermal energy effect under, make by supersound process with
After adsorb the unreacted antiseptic on protein powder and further react, to assign the anti-microbial property of protein powder.
B. the preparation of mill base
Under the conditions of 200~300r/min mixing speeds and 6~10min mixings time, the antibacterial after antibacterial processed
In protein powder, be separately added into quality be the distilled water of 6~10 times of antiseptic protein powder, 2~3 times of absolute ethyl alcohol, 4~
6 times of adhesive UDT premixs are combined, then in 400~600r/min mixing speeds and 80~100min mixing time items
It is stirred evenly under part, preparing becomes antiseptic protein powder slurry, then adds 10 by the mass percent of antiseptic protein powder slurry
~20% coating and 1~2.6% sodium alginate, in 600~800r/min mixing speeds and 100~120min mixings time
Under the conditions of stir evenly, prepare become mill base.
When preparing print paste, it is 200~300r/min that it is relatively low, which to start the mixing speed sized mixing, this is primarily to anti-
Only in charging raw material splashing, one side stirring at low speed in 6~10min feeds on one side, in order to avoid antiseptic protein powder is adding
It lumps during material, influences to disperse.In antiseptic protein powder after antibacterial processed, quality is separately added into as antibacterial protein
The distilled water that 6~10 times of matter powder, 2~3 times of absolute ethyl alcohol, 4~6 times of adhesive UDT premixs are combined.Due to stirring
The speed low time is short, these raw materials are simply simply pre-mixed, and there are no sufficiently uniformly disperse.The effect of distilled water
It is to make antiseptic protein powder that sufficiently swelling occur and disperse.To promote the scattered, it is necessary to by means of anhydrous of protein powder
The booster action of ethyl alcohol.Absolute ethyl alcohol molecular weight is low, and permeability is strong, can accelerate the swelling of antiseptic protein powder in water, have
Beneficial to the rapid dispersion of powder.Ethyl alcohol can also accelerate the infiltration of the print paste being printed on fabric in the fibre, improve stamp
Tinctorial yield and colour vividness, when PRINTED FABRIC is in follow-up curing fixation, ethyl alcohol can volatilize away from fabric again, Bu Huiying
Ring the performance of PRINTED FABRIC.Absolute ethyl alcohol dosage should be suitable, and ratio is excessively high, can reduce antiseptic protein powder in print paste
In relative amount, and need increase thickener dosage, the feel of PRINTED FABRIC is impacted.Adhesive UDT is propylene
Acids pigment printing binding agent, the film forming on fiber are transparent continuous.The additional proportion of adhesive, binder dosage should be controlled
Too low, then film forming is deteriorated, it is difficult to which fettering antiseptic protein powder well on the fabric, reduces the friction jail of PRINTED FABRIC
Degree；If binder dosage is excessively high, cover layer is thickening, and antiseptic protein powder is covered by thicker macromolecule membrane layer
In, antiseptic protein powder is difficult to play its antibacterial functions.Then the slurries after premixing are stirred into speed in 400~600r/min
It is stirred evenly under the conditions of degree and 80~100min mixings time, preparing becomes antiseptic protein powder slurry.Stirring speed is improved at this time
Degree, makes slurries quickly move under larger stirring shearing force, and being uniformly mixed raw material after prolonged stirring becomes
Antiseptic protein powder slurry.Mixing speed is unsuitable too low, and shearing force otherwise may be made insufficient, antiseptic protein powder is caused to stir
It mixes not open, in addition also to prevent the splashing of the powder slurry in quick stirring, meanwhile, mixing time cannot be too short, otherwise antibacterial egg
White matter powder slurry is difficult to stir evenly in a short time.It is again antiseptic protein powder slurry mass percent 10~20% by quality
Coating and 1~2.6% sodium alginate be added in the antiseptic protein powder slurry of preparation.The coating type of selection has azo
The problems such as one kind in class coating or phthalocyanines coating, dosage will consider to print color, the fastness of fabric.Match somebody with somebody in print paste
The sodium alginate added in side is printing thickening agent, and sodium alginate is a kind of natural macromolecule amylose, and there is good thickening to imitate
Fruit can improve the viscosity of mill base, prevent mill base imbibition, assign mill base rheological characteristic and bin stability, can make printing pattern face
Color is bright-coloured, sharpness of border, color it is uniform.According to the formula composition and material rate of print paste, the sodium alginate quality of addition
It is advisable with 1~2.6% mass percent to antiseptic protein powder slurry.Sodium alginate dosage is too low, then color paste viscosity is small, oozes
Change seriously, printing obscure boundary is clear；When dosage is excessively high, print paste viscosity increases, and mill base scrapes difficulty, and stamp can be knitted
The feel of object has an impact.To antiseptic protein powder slurry, coating and sodium alginate in 600~800r/min mixing speeds and
It is stirred evenly under the conditions of 100~120min mixings time, preparing becomes print paste.It must assure that mixing speed and mixing time
So as to stir evenly, otherwise the sodium alginate macromolecular in print paste may unfold not exclusively, and thickening effect is deteriorated, and mistake
Fast mixing speed can also make print paste splash.
Specific embodiment
Embodiment one
As stated above, by the silk powder that 100g grain sizes are 10 μm, 2L is placed in by absolute ethyl alcohol and distilled water by volume
Than for 2:In the treatment fluid containing 10g antiseptics CTA-736 that 8 ratio is prepared, ultrasonic power at 1200 watts, 40 DEG C
At a temperature of be ultrasonically treated 20min, the treatment fluid containing silk powder after supersound process is filtered, is obtained sonicated
Silk powder, then obtained sonicated silk powder is dried into 30min at a temperature of 30 DEG C, then will be after drying
Silk powder be heat-treated 15min at a temperature of 100 DEG C, become anti bacteria natural silk powder.In 200r/min mixing speeds and
Under the conditions of 10min mixings time, the distilled water of 600g, 300g are separately added into the anti bacteria natural silk powder after antibacterial processed
Absolute ethyl alcohol, the adhesive UDT premixs of 600g are combined, then in 400r/min mixing speeds and 100min mixing time items
It is stirred evenly under part, preparing becomes anti bacteria natural silk powder slurry, then the azo coating of 160g is added in into anti bacteria natural silk powder slurry
The sodium alginate of 8111 bright red FFG and 16g stirs evenly under the conditions of 600r/min mixing speeds and 120min mixings time,
Preparing becomes mill base.
Embodiment two
As stated above, by the wool powder that 100g grain sizes are 20 μm, 5L is placed in by absolute ethyl alcohol and distilled water by volume
Than for 4:In the treatment fluid containing 75g antiseptics CTA-736 that 6 ratio is prepared, ultrasonic power at 1800 watts, 30 DEG C
At a temperature of be ultrasonically treated 15min, the treatment fluid containing wool powder after supersound process is filtered, is obtained sonicated
Wool powder, then obtained sonicated wool powder is dried into 25min at a temperature of 40 DEG C, then will be after drying
Wool powder be heat-treated 10min at a temperature of 110 DEG C, become antibacterial wool powder.In 300r/min mixing speeds and
Under the conditions of 6min mixings time, the distilled water of 1000g, 200g are separately added into the antibacterial wool powder after antibacterial processed
Absolute ethyl alcohol, the adhesive UDT premixs of 400g are combined, then in 600r/min mixing speeds and 80min mixing time items
It is stirred evenly under part, preparing becomes antibacterial wool powder slurry, then the azo coating of 340g is added in into antibacterial wool powder slurry
The sodium alginate of Huang FG and 44.2g, stirs evenly under the conditions of 800r/min mixing speeds and 100min mixings time in 8202,
Preparing becomes mill base.
Embodiment three
As stated above, by the down-powder that 100g grain sizes are 15 μm, 3.5L is placed in by absolute ethyl alcohol and distilled water by body
Product is than being 3:In the treatment fluid containing 35g antiseptics CTA-736 that 7 ratio is prepared, ultrasonic power at 1500 watts, 35 DEG C
At a temperature of be ultrasonically treated 17.5min, the treatment fluid containing down-powder after supersound process is filtered, is obtained through ultrasound
The down-powder of processing, then obtained sonicated down-powder is dried into 27.5min at a temperature of 35 DEG C, then will
Down-powder after drying is heat-treated 12.5min at a temperature of 105 DEG C, becomes antibacterial down feather powder.It is stirred in 250r/min
Under the conditions of speed and 8min mixings time, be separately added into the antibacterial down feather powder after antibacterial processed 800g distilled water,
The absolute ethyl alcohol of 250g, the adhesive UDT premixs of 500g are combined, and are then stirred in 500r/min mixing speeds and 90min
It is stirred evenly under time conditions, preparing becomes antibacterial down feather powder slurry, then the idol of 247.5g is added in into antibacterial down feather powder slurry
The sodium alginate of 6301 pink F3R and 29.7g of nitrogen class coating, under the conditions of 700r/min mixing speeds and 110min mixings time
It stirs evenly, preparing becomes mill base.
Example IV
As stated above, by the silk powder that 100g grain sizes are 10 μm, 2L is placed in by absolute ethyl alcohol and distilled water by volume
Than for 2:In the treatment fluid containing 10g antiseptics CTA-736 that 8 ratio is prepared, ultrasonic power at 1200 watts, 40 DEG C
At a temperature of be ultrasonically treated 20min, the treatment fluid containing silk powder after supersound process is filtered, is obtained sonicated
Silk powder, then obtained sonicated silk powder is dried into 30min at a temperature of 30 DEG C, then will be after drying
Silk powder be heat-treated 15min at a temperature of 100 DEG C, become anti bacteria natural silk powder.In 200r/min mixing speeds and
Under the conditions of 10min mixings time, the distilled water of 600g, 300g are separately added into the anti bacteria natural silk powder after antibacterial processed
Absolute ethyl alcohol, the adhesive UDT premixs of 600g are combined, then in 400r/min mixing speeds and 100min mixing time items
It is stirred evenly under part, preparing becomes anti bacteria natural silk powder slurry, then the phthalocyanines coating of 160g is added in into anti bacteria natural silk powder slurry
The sodium alginate of 8601 green FB and 16g stirs evenly under the conditions of 600r/min mixing speeds and 120min mixings time, prepares
As mill base.
Embodiment five
As stated above, by the wool powder that 100g grain sizes are 20 μm, 5L is placed in by absolute ethyl alcohol and distilled water by volume
Than for 4:In the treatment fluid containing 75g antiseptics CTA-736 that 6 ratio is prepared, ultrasonic power at 1800 watts, 30 DEG C
At a temperature of be ultrasonically treated 15min, the treatment fluid containing wool powder after supersound process is filtered, is obtained sonicated
Wool powder, then obtained sonicated wool powder is dried into 25min at a temperature of 40 DEG C, then will be after drying
Wool powder be heat-treated 10min at a temperature of 110 DEG C, become antibacterial wool powder.In 300r/min mixing speeds and
Under the conditions of 6min mixings time, the distilled water of 1000g, 200g are separately added into the antibacterial wool powder after antibacterial processed
Absolute ethyl alcohol, the adhesive UDT premixs of 400g are combined, then in 600r/min mixing speeds and 80min mixing time items
It is stirred evenly under part, preparing becomes antibacterial wool powder slurry, then the phthalocyanines coating of 340g is added in into antibacterial wool powder slurry
The sodium alginate of 8301 indigo plant FFG and 44.2g, stirs evenly under the conditions of 800r/min mixing speeds and 100min mixings time,
Preparing becomes mill base.
Embodiment six
As stated above, by the down-powder that 100g grain sizes are 15 μm, 3.5L is placed in by absolute ethyl alcohol and distilled water by body
Product is than being 3:In the treatment fluid containing 35g antiseptics CTA-736 that 7 ratio is prepared, ultrasonic power at 1500 watts, 35 DEG C
At a temperature of be ultrasonically treated 17.5min, the treatment fluid containing down-powder after supersound process is filtered, is obtained through ultrasound
The down-powder of processing, then obtained sonicated down-powder is dried into 27.5min at a temperature of 35 DEG C, then will
Down-powder after drying is heat-treated 12.5min at a temperature of 105 DEG C, becomes antibacterial down feather powder.It is stirred in 250r/min
Under the conditions of speed and 8min mixings time, be separately added into the antibacterial down feather powder after antibacterial processed 800g distilled water,
The absolute ethyl alcohol of 250g, the adhesive UDT premixs of 500g are combined, and are then stirred in 500r/min mixing speeds and 90min
It is stirred evenly under time conditions, preparing becomes antibacterial down feather powder slurry, then the phthalein of 247.5g is added in into antibacterial down feather powder slurry
The sodium alginate of 6406 bright blue FGB and 29.7g of cyanines class coating, under the conditions of 700r/min mixing speeds and 110min mixings time
It stirs evenly, preparing becomes mill base.
Claims (3)
1. a kind of color paste formulation method for improving textile coating stamp anti-microbial property, it is characterised in that：The mill base preparation side
Method carries out according to the following steps：
A. the antimicrobial treatment of protein powder
The protein powder that grain size is 10~20 μm is placed in and is mixed by absolute ethyl alcohol, distilled water and antiseptic CTA-736
Treatment fluid in, be ultrasonically treated in supersonic generator, the treatment fluid containing protein powder after supersound process through take out
Filter obtains sonicated protein powder, then obtained sonicated protein powder is dried, heat treatment, into
For antiseptic protein powder, wherein, the bath raio for the treatment of fluid is 1:20~1:50, the volume ratio of absolute ethyl alcohol and distilled water is 2:8
~4:The concentration of 6, antiseptic CTA-736 are 5~15g/L, and ultrasonic power is 1200~1800 watts, and it is 30 to be ultrasonically treated temperature
~40 DEG C, sonication treatment time is 15~20min, and drying temperature is 30~40 DEG C, and drying time is 25~30min, is heat-treated
Temperature is 100~110 DEG C, and heat treatment time is 10~15min；
B. the preparation of mill base
Under the conditions of 200~300r/min mixing speeds and 6~10min mixings time, the antibacterial protein after antibacterial processed
In matter powder, distilled water, 2~3 times of absolute ethyl alcohol, 4~6 times that quality is 6~10 times of antiseptic protein powder are separately added into
Adhesive UDT premix be combined, then under the conditions of 400~600r/min mixing speeds and 80~100min mixings time
Stir evenly, prepare become antiseptic protein powder slurry, then by antiseptic protein powder slurry mass percent addition 10~
20% coating and 1~2.6% sodium alginate, in 600~800r/min mixing speeds and 100~120min mixing time items
It is stirred evenly under part, preparing becomes mill base.
2. a kind of color paste formulation method for improving textile coating stamp anti-microbial property as described in claim 1, it is characterised in that：
The protein powder is one kind in silk powder or wool powder or down-powder.
3. a kind of color paste formulation method for improving textile coating stamp anti-microbial property as described in claim 1, it is characterised in that：
The coating is one kind in azo coating or phthalocyanines coating.
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