CN108071026A - A kind of dye liquor preparation method for improving textile coating dyeing anti-microbial property - Google Patents
A kind of dye liquor preparation method for improving textile coating dyeing anti-microbial property Download PDFInfo
- Publication number
- CN108071026A CN108071026A CN201711142741.3A CN201711142741A CN108071026A CN 108071026 A CN108071026 A CN 108071026A CN 201711142741 A CN201711142741 A CN 201711142741A CN 108071026 A CN108071026 A CN 108071026A
- Authority
- CN
- China
- Prior art keywords
- dye liquor
- cellulose powder
- powder
- antibacterial
- dyeing
- Prior art date
- Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
- Pending
Links
Classifications
-
- D—TEXTILES; PAPER
- D06—TREATMENT OF TEXTILES OR THE LIKE; LAUNDERING; FLEXIBLE MATERIALS NOT OTHERWISE PROVIDED FOR
- D06P—DYEING OR PRINTING TEXTILES; DYEING LEATHER, FURS OR SOLID MACROMOLECULAR SUBSTANCES IN ANY FORM
- D06P1/00—General processes of dyeing or printing textiles, or general processes of dyeing leather, furs, or solid macromolecular substances in any form, classified according to the dyes, pigments, or auxiliary substances employed
- D06P1/44—General processes of dyeing or printing textiles, or general processes of dyeing leather, furs, or solid macromolecular substances in any form, classified according to the dyes, pigments, or auxiliary substances employed using insoluble pigments or auxiliary substances, e.g. binders
- D06P1/46—General processes of dyeing or printing textiles, or general processes of dyeing leather, furs, or solid macromolecular substances in any form, classified according to the dyes, pigments, or auxiliary substances employed using insoluble pigments or auxiliary substances, e.g. binders using compositions containing natural macromolecular substances or derivatives thereof
-
- D—TEXTILES; PAPER
- D06—TREATMENT OF TEXTILES OR THE LIKE; LAUNDERING; FLEXIBLE MATERIALS NOT OTHERWISE PROVIDED FOR
- D06P—DYEING OR PRINTING TEXTILES; DYEING LEATHER, FURS OR SOLID MACROMOLECULAR SUBSTANCES IN ANY FORM
- D06P1/00—General processes of dyeing or printing textiles, or general processes of dyeing leather, furs, or solid macromolecular substances in any form, classified according to the dyes, pigments, or auxiliary substances employed
- D06P1/02—General processes of dyeing or printing textiles, or general processes of dyeing leather, furs, or solid macromolecular substances in any form, classified according to the dyes, pigments, or auxiliary substances employed using azo dyes
-
- D—TEXTILES; PAPER
- D06—TREATMENT OF TEXTILES OR THE LIKE; LAUNDERING; FLEXIBLE MATERIALS NOT OTHERWISE PROVIDED FOR
- D06P—DYEING OR PRINTING TEXTILES; DYEING LEATHER, FURS OR SOLID MACROMOLECULAR SUBSTANCES IN ANY FORM
- D06P1/00—General processes of dyeing or printing textiles, or general processes of dyeing leather, furs, or solid macromolecular substances in any form, classified according to the dyes, pigments, or auxiliary substances employed
- D06P1/14—General processes of dyeing or printing textiles, or general processes of dyeing leather, furs, or solid macromolecular substances in any form, classified according to the dyes, pigments, or auxiliary substances employed using phthalocyanine dyes without vatting
-
- D—TEXTILES; PAPER
- D06—TREATMENT OF TEXTILES OR THE LIKE; LAUNDERING; FLEXIBLE MATERIALS NOT OTHERWISE PROVIDED FOR
- D06P—DYEING OR PRINTING TEXTILES; DYEING LEATHER, FURS OR SOLID MACROMOLECULAR SUBSTANCES IN ANY FORM
- D06P1/00—General processes of dyeing or printing textiles, or general processes of dyeing leather, furs, or solid macromolecular substances in any form, classified according to the dyes, pigments, or auxiliary substances employed
- D06P1/44—General processes of dyeing or printing textiles, or general processes of dyeing leather, furs, or solid macromolecular substances in any form, classified according to the dyes, pigments, or auxiliary substances employed using insoluble pigments or auxiliary substances, e.g. binders
- D06P1/445—Use of auxiliary substances before, during or after dyeing or printing
-
- D—TEXTILES; PAPER
- D06—TREATMENT OF TEXTILES OR THE LIKE; LAUNDERING; FLEXIBLE MATERIALS NOT OTHERWISE PROVIDED FOR
- D06P—DYEING OR PRINTING TEXTILES; DYEING LEATHER, FURS OR SOLID MACROMOLECULAR SUBSTANCES IN ANY FORM
- D06P1/00—General processes of dyeing or printing textiles, or general processes of dyeing leather, furs, or solid macromolecular substances in any form, classified according to the dyes, pigments, or auxiliary substances employed
- D06P1/44—General processes of dyeing or printing textiles, or general processes of dyeing leather, furs, or solid macromolecular substances in any form, classified according to the dyes, pigments, or auxiliary substances employed using insoluble pigments or auxiliary substances, e.g. binders
- D06P1/64—General processes of dyeing or printing textiles, or general processes of dyeing leather, furs, or solid macromolecular substances in any form, classified according to the dyes, pigments, or auxiliary substances employed using insoluble pigments or auxiliary substances, e.g. binders using compositions containing low-molecular-weight organic compounds without sulfate or sulfonate groups
- D06P1/651—Compounds without nitrogen
- D06P1/65106—Oxygen-containing compounds
- D06P1/65118—Compounds containing hydroxyl groups
Landscapes
- Engineering & Computer Science (AREA)
- Textile Engineering (AREA)
- Coloring (AREA)
- Agricultural Chemicals And Associated Chemicals (AREA)
Abstract
The present invention relates to a kind of dye liquor preparation methods for improving textile coating dyeing anti-microbial property, belong to textile printing and dyeing processing technique field.The present invention uses and antimicrobial treatment is carried out under the environmental condition of ultrasonic wave to cellulose powder, then antibacterial cellulose powder is added to prepare in dye liquor and becomes pigment dyeing dye liquor, when with dyeing and weaving object on this dye liquor, contained antibacterial cellulose powder is transferred on fabric in dye liquor, so as to improve the anti-microbial property of pigment dyeing fabric.Cellulose powder can also be dyed to different colors before antimicrobial treatment and carry out antimicrobial treatment again, and it is coloured antibacterial cellulose powder to be so added in dye liquor, and the fabric dyed with this dye liquor can reach the appearance of colour mixture.The method of the preparation pigment dyeing dye liquor of the present invention, dye liquor process for preparation is simple and practicable, can carry out industrial applications.
Description
Technical field
The present invention relates to a kind of dye liquor preparation methods for improving textile coating dyeing anti-microbial property, belong to textile printing and dyeing processing skill
Art field.
Background technology
With continuous improvement of the people to printing and dyeing enterprise production environmental requirement, pigment dyeing is since its is simple for process, operation
Conveniently, colour combination is easy, and need not generally be washed after pigment dyeing, and dyeing can be completed by simple curing fixation
Process saves substantial amounts of water, and in the case where present water resource is increasingly deficient, pigment dyeing has been increasingly printing and dyeing enterprise institute
Favor.Coating, adhesive and the main components such as other auxiliary agents and water are typically contained in the dye liquor composition of pigment dyeing.Wherein,
Coating provides colouring component in the dye liquor of pigment dyeing, is by the pigment of organic (or inorganic) and corresponding dispersant, wetting
The auxiliary agents such as agent, colloid protective agent, preservative add the ground manufactured slurry of water.During using pigment dyeing, since coating is to fibre
No affinity is tieed up, so from the limitation of fiber self property, so as to avoid as dyeing, for a variety of fibres
When tieing up the blended fabric dyeing formed, it is necessary to each of which kind fiber respectively upper dye and caused by puzzlement, can be used same
Kind coating is by the color and luster that different types of fiber contaminates identical in blended fabric, and the fabric color dyed is uniform and stable.Therefore,
Pigment dyeing technique is suitable for pure spinning and the blended fabric of multiple fiber, particularly with the dyeing of polyester cotton.
With advances in technology with the raising of living standards of the people, the textile with antimicrobial health care function is increasingly subject to
The attention of consumer.Realize that the antibiotic property means of fabric are various, open magazine《Wool spinning science and technology》, the 2nd phase of 2005 publication dates
Antibiotic finish is carried out to woven cashmere products in entitled " exploitations of antibacterial woven cashmere products ", is retaining the original excellent product of cashmere
On the basis of matter, the good anti-microbial property of fleece fabrics is imparted.Open magazine《Textile journal》, the 9th phase of 2011 publication dates
It is had studied in entitled " influence of the silver plated fiber content to antibacterial fabric performance " and silver-plated nylon fibre is passed through into different tissues knot
Institute's attainable antibacterial effect when structure is weaved, when silver plated fiber content is 11.99%, bacteriostasis rate can reach more than 99%.This
A little open source literatures show what the acquisition of antibacterial fabric performance was realized generally by finishing functions are carried out to it.
Chinese patent application publication No. CN 101886328A, November 17 2010 Shen Qing Publication date, innovation and creation
Entitled " antibacterial treatment process of wool worsted fabric ", this application discloses one kind with nano composite antibacterial finishing agent CTA-
736 be auxiliary agent, and antimicrobial treatment is first carried out to wool top, then carries out antimicrobial treatment to fabric, so that fabric has the side of anti-microbial property
Method.This method carries out antimicrobial treatment, the essence or finishing functions of processing method in terms of fiber and two, fabric.It is Chinese special
Sharp application publication number CN 102441173A, May 9 2012 Shen Qing Publication date, innovation and creation it is entitled " water-insoluble
Protein powder is the preparation method of the drug delivery system of pharmaceutical carrier ", this application discloses a kind of by protein powder
As pharmaceutical carrier, for the controlled release of drug, preferably to achieve the purpose that treatment using drug.This is protein powder
Innovation and creation in medicament slow release field, for the natural organic powder of functionalization for pigment dyeing, is dyed with improving
The open source literature of fabric property is then more rare.
The content of the invention
In view of the above problems, it is an object of the invention to improve the anti-microbial property of pigment dyeing fabric, by
When preparing the dye liquor of pigment dyeing, the cellulose powder after antimicrobial treatment is added in into formula for dye liquor, is added using these
Anti-microbial property possessed by the antibacterial cellulose powder added, to improve the antibiotic property of pigment dyeing fabric.
To achieve these goals, technical solution is：
A kind of dye liquor preparation method for improving textile coating dyeing anti-microbial property, the dye liquor preparation method press following step
It is rapid to carry out：
A. the antimicrobial treatment of cellulose powder
The cellulose powder that grain size is 15~30 μm is placed in and is mixed by absolute ethyl alcohol, distilled water and antiseptic CTA-736
It in the treatment fluid formed, is ultrasonically treated in supersonic generator, the treatment fluid containing cellulose powder after supersound process
Through suction filtration, sonicated cellulose powder is obtained, then the sonicated cellulose powder that will be obtained is dried, at heat
Reason, becomes antibacterial cellulose powder, wherein, the bath raio for the treatment of fluid is 1:20~1:50, the volume ratio of absolute ethyl alcohol and distilled water
For 2:8~4:The concentration of 6, antiseptic CTA-736 are 10~20g/L, and ultrasonic power is 1200~1800 watts, is ultrasonically treated temperature
It spends for 25~35 DEG C, sonication treatment time is 10~15min, and drying temperature is 30~40 DEG C, and drying time is 25~30min,
Heat treatment temperature is 90~100 DEG C, and heat treatment time is 10~15min；
B. the preparation of dye liquor
In antibacterial cellulose powder after antibacterial processed, quality is separately added into as 10~20 times of antibacterial cellulose powder
Distilled water, 2~6 times of absolute ethyl alcohol, 2~5 times of adhesive UDT, 0.2~0.5 times of crosslinking agent AF6900,1~4 times
Coating mixes, and is then stirred evenly under the conditions of 600~800r/min mixing speeds and 30~40min mixings time,
Preparing becomes dye liquor.
The cellulose powder is one kind in cotton fiber powder or flaxen fiber powder.
The coating is one kind in azo coating or phthalocyanines coating.
As a result of above technical scheme, a kind of dye liquor preparation side for improving textile coating dyeing anti-microbial property of the present invention
The technical characterstic of method is：
Antimicrobial treatment is carried out under the environmental condition of ultrasonic wave to cellulose powder, what is contained in antiseptic has sterilization work(
The group of energy is connected on cellulose powder, so that cellulose powder has anti-microbial property.By antibacterial cellulose powder
It is added in dye liquor to prepare and becomes pigment dyeing dye liquor, the cellulose powder constituents with antibacterial functions are just contained in dye liquor,
When with dyeing and weaving object on this dye liquor, antibacterial cellulose powder contained therein is transferred on fabric, so as to improve
The anti-microbial property of pigment dyeing fabric.Cellulose powder can also be dyed to different colors before antimicrobial treatment and carry out antibacterial again
Processing, it is coloured antibacterial cellulose powder to be so added in dye liquor, and the fabric dyed with this dye liquor can reach
The appearance of colour mixture.The method of the preparation pigment dyeing dye liquor of the present invention, dye liquor process for preparation is simple and practicable, can carry out industry
Change application.
Specific embodiment
With reference to specific embodiment, to a kind of dye liquor preparation side of improvement textile coating dyeing anti-microbial property of the present invention
Method is described in further detail.
A kind of dye liquor preparation method for improving textile coating dyeing anti-microbial property, the dye liquor preparation method press following step
It is rapid to carry out：
A. the antimicrobial treatment of cellulose powder
The cellulose powder that grain size is 15~30 μm is placed in and is mixed by absolute ethyl alcohol, distilled water and antiseptic CTA-736
It in the treatment fluid formed, is ultrasonically treated in supersonic generator, the treatment fluid containing cellulose powder after supersound process
Through suction filtration, sonicated cellulose powder is obtained, then the sonicated cellulose powder that will be obtained is dried, at heat
Reason, becomes antibacterial cellulose powder, wherein, the bath raio for the treatment of fluid is 1:20~1:50, the volume ratio of absolute ethyl alcohol and distilled water
For 2:8~4:The concentration of 6, antiseptic CTA-736 are 10~20g/L, and ultrasonic power is 1200~1800 watts, is ultrasonically treated temperature
It spends for 25~35 DEG C, sonication treatment time is 10~15min, and drying temperature is 30~40 DEG C, and drying time is 25~30min,
Heat treatment temperature is 90~100 DEG C, and heat treatment time is 10~15min.
Cellulose powder is by cellulosic fibre materials such as cotton fiber or flaxen fibers, is process by physical mechanical effect
Cellulose micro particles of the grain size scale at 15~30 μm, the too small then difficulty of processing of grain size is big, adds production cost；Grain size
It is larger, the crock fastness of pigment dyeing fabric may be reduced.During powder is become by fiber process, merely through object
Reason acts on, and the basic chemical composition of these cellulose powders remains as cellulose, and the maximum variation that they occur is appearance shape
In terms of state and grain size scale, zero dimension powder is become by original one-dimensional linear, cellulose powder particle is compared with fibrinogen specific surface area
Increase greatly, this causes cellulose powder to be significantly increased compared with fibrinogen to the adsorption capacity for contaminating material.Also, cellulose fibre passes through
Cross after fine processing, show more reactive groups that may participate in reaction in powder, the chemical reaction ability of powder compared with
Fibrinogen significantly improves.When carrying out antimicrobial treatment to cellulose powder, under the same treatment conditions of cellulose fibre, it is fine
The antiseptic of the plain powder absorption of dimension can be distributed on the surface area of bigger so that on the powder of same units area, it is difficult to reach
To the treatment effect consistent with fibrinogen.So when carrying out antimicrobial treatment, it can suitably increase the dosage of antiseptic.Antimicrobial treatment
Liquid is mixed by absolute ethyl alcohol, distilled water and antiseptic CTA-736, wherein, the bath raio for the treatment of fluid is 1:20~1:50, nothing
The volume ratio of water-ethanol and distilled water is 2:8~4:The concentration of 6, antiseptic CTA-736 are 10~20g/L.Distilled water can make fibre
The plain powder of dimension occurs swelling and is dispersed in treatment fluid, and dosage should ensure that the abundant swelling of cellulose powder.Absolute ethyl alcohol
Molecular weight is small, surface tension is low, viscosity is small, permeability is strong, can promote the swelling of cellulose powder, and can mitigate powder in water
In aggregation, it is scattered in treatment fluid to be conducive to powder, and powder is made preferably to be reacted with antiseptic.To fill cellulose powder
Sub-dip stain and reaction, the bath raio for the treatment of fluid is 1:20~1:50.The volume ratio of absolute ethyl alcohol and distilled water can not mistake in treatment fluid
Height, so that antiseptic CTA-736 is uniform and stable in treatment fluid.Antiseptic CTA-736 is Nano type complex antimicrobials, is had wide
Compose antibacterial, it is washable efficient the characteristics of, can effectively sterilize, is antibacterial, and peculiar smell can be eliminated.Cellulose powder by antimicrobial treatment with
Afterwards, the group with sterilizing function contained in antiseptic is connected on cellulose powder, so that cellulose powder has
There is antibacterial effect.Cellulose powder is impregnated in the antimicrobial treatment solution of configuration, is ultrasonically treated in ultrasonic environment, is surpassed
Acoustic power is 1200~1800 watts, and it is 25~35 DEG C to be ultrasonically treated temperature, and sonication treatment time is 10~15min.Ultrasonic wave
It is that a kind of frequency is 2 × 104Hz~2 × 109The mechanical wave of Hz, action principle are the dither effects using ultrasonic wave, make fiber
Plain powder generates substantial amounts of gap to accommodate more antiseptics during the treatment, and is in the cellulose powder of swelling
Fluffy state, in addition, the cavitation effect generated using ultrasonic wave, pushes antiseptic to deeper area under HI high impact effect
Domain so that cellulose powder body can fully adsorption antibacterial agent, improve the respond of cellulose powder and antiseptic.Cellulose
When powder is ultrasonically treated in antimicrobial treatment solution, ultrasonic power should mutually be assisted with being ultrasonically treated the parameters such as temperature, time
Adjust consistent, ultrasonic power is high, then treatment temperature and processing time can accordingly decrease.Contain fibre after will be sonicated
The treatment fluid of the plain powder of dimension is filtered, then will filter the obtained cellulose powder for being adsorbed with antiseptic 30~40 DEG C compared with
It is dried under low temperature, it is uniform and stable in favor of subsequent heat treatment effect.Then by the cellulose powder of drying at 90~100 DEG C
At a temperature of be heat-treated 10~15min, become antibacterial cellulose powder.Heat treatment can make to adsorb in fiber after supersound process
Unreacted antiseptic, further reacts under the action of thermal energy on plain powder, to assign the anti-microbial property of cellulose powder.
B. the preparation of dye liquor
In antibacterial cellulose powder after antibacterial processed, quality is separately added into as 10~20 times of antibacterial cellulose powder
Distilled water, 2~6 times of absolute ethyl alcohol, 2~5 times of adhesive UDT, 0.2~0.5 times of crosslinking agent AF6900,1~4 times
Coating mixes, and is then stirred evenly under the conditions of 600~800r/min mixing speeds and 30~40min mixings time,
Preparing becomes dye liquor.
The effect of distilled water is to make antibacterial cellulose powder that swelling occur and disperse.To promote the scattered of cellulose powder,
Need the booster action by means of absolute ethyl alcohol.Absolute ethyl alcohol has strong osmotic performance, can accelerate antibacterial cellulose powder and exist
Swelling in water reduces the aggregation of antibacterial cellulose powder, is conducive to the scattered of powder.Absolute ethyl alcohol can also promote coating contaminating
Rapid osmotic on yarn dyed fabric improves dyeing tinctorial yield and colour vividness, anhydrous when dyed fabric is in follow-up curing fixation
Ethyl alcohol can volatilize away from fabric again, not interfere with the performance of dyed fabric.The addition of absolute ethyl alcohol should be with distilled water, anti-
The raw materials such as fungin powder are adapted, and the excessively high meeting diluted staining solution concentration of absolute ethyl alcohol addition reduces the solid content of dye liquor, difficult
To contaminate to obtain deep heavy colour.Adhesive UDT is the pigment dyeing binding agent of structural acrylic, can be in fiber surface after high temperature bakes
It forms continuous transparent nano thin-film and assigns the fastness of pigment dyeing fabric.Due to the antibacterial cellulose powder added in dye liquor
The grain size of body is more than the grain size of pigment in coating, so needing to improve ratio of the adhesive in dye liquor, so that adhesive is in fibre
It forms a film well in dimension, by the constraint of antibacterial cellulose powder particle on the fabric, so as to improve the friction of pigment dyeing fabric jail
Degree.The low then film forming of binder dosage is poor, and dosage is excessively high, and dyed fabric feel can be made tacky, influence the wearability of product,
It is also possible to cover antibacterial cellulose powder because of thicker film layer, prevents the antibiotic effect of antibacterial cellulose powder from fully sending out
It waves.Crosslinking agent AF6900 is the copolymer of isocyanates and acrylate, is used together with adhesive UDT, after pyroreaction,
The film of network-like crosslinking interpenetrating can be formed in powder and fiber surface, to improve the fastness of pigment dyeing fabric.According to dyeing
Azo coating or phthalocyanines coating may be selected when preparing dye liquor in the requirements such as the color and fastness of fabric, and dosage will be with addition
Antibacterial cellulose powder mutually coordinate.Then under the conditions of 600~800r/min mixing speeds and 30~40min mixings time,
Physical agitation mixing is carried out to the raw material of addition, preparing becomes dyeing dye liquor.Stirring at this time must be full and uniform, it is ensured that stirs
Speed and mixing time are mixed, mixture is made quickly to be moved under larger stirring shearing force, under longer mixing time
Being uniformly mixed becomes dye liquor.Notice that mixing speed at this time can not be too low, otherwise may cause powder due to shearing force is insufficient
It stirs not open, makes dye liquor irregular；In addition, also to prevent in quick stirring, the splashing of dye liquor, meanwhile, mixing time cannot mistake
Short, otherwise antibacterial cellulose powder is difficult to stir evenly in a short time.
Specific embodiment
Embodiment one
As stated above, by the cotton fiber powder that 100g grain sizes are 15 μm, 2L is placed in by absolute ethyl alcohol and distilled water by body
Product is than being 2:In the treatment fluid containing 20g antiseptics CTA-736 that 8 ratio is prepared, ultrasonic power at 1200 watts, 35 DEG C
At a temperature of be ultrasonically treated 15min, the treatment fluid containing cotton fiber powder after supersound process is filtered, is obtained through ultrasound
The cotton fiber powder of processing, then obtained sonicated cotton fiber powder is dried into 30min at a temperature of 30 DEG C, then
Cotton fiber powder after drying is heat-treated 15min at a temperature of 90 DEG C, becomes antibiotic cotton fiber powder.To antibacterial processed
Adhesive UDT, 50g of the distilled water of 1000g, the absolute ethyl alcohol of 600g, 500g are separately added into antibiotic cotton fiber powder afterwards
The 8111 bright red FFG of azo coating of crosslinking agent AF6900,400g mix, then in 600r/min mixing speeds and
It is stirred evenly under the conditions of 40min mixings time, preparing becomes dye liquor.
Embodiment two
As stated above, by the cotton fiber powder that 100g grain sizes are 30 μm, 5L is placed in by absolute ethyl alcohol and distilled water by body
Product is than being 4:In the treatment fluid containing 100g antiseptics CTA-736 that 6 ratio is prepared, ultrasonic power at 1800 watts, 25
10min is ultrasonically treated at a temperature of DEG C, the treatment fluid containing cotton fiber powder after supersound process is filtered, is obtained through super
The cotton fiber powder of sonication, then obtained sonicated cotton fiber powder is dried into 25min at a temperature of 40 DEG C, so
The cotton fiber powder after drying is heat-treated 10min at a temperature of 100 DEG C afterwards, becomes antibiotic cotton fiber powder.To through antibacterial
Be separately added into treated antibiotic cotton fiber powder the distilled water of 2000g, the absolute ethyl alcohol of 200g, 200g adhesive UDT,
Huang FG is mixed in the azo coating 8202 of crosslinking agent AF6900,100g of 20g, then in 800r/min mixing speeds
It is stirred evenly under the conditions of 30min mixings time, preparing becomes dye liquor.
Embodiment three
As stated above, by the cotton fiber powder that 100g grain sizes are 22.5 μm, 3.5L is placed in by absolute ethyl alcohol and distilled water
It is 3 by volume:In the treatment fluid containing 52.5g antiseptics CTA-736 that 7 ratio is prepared, in 1500 watts of ultrasonic wave work(
Rate is ultrasonically treated 12.5min at a temperature of 30 DEG C, and the treatment fluid containing cotton fiber powder after supersound process is filtered,
Sonicated cotton fiber powder is obtained, then obtained sonicated cotton fiber powder is dried at a temperature of 35 DEG C
Then cotton fiber powder after drying is heat-treated 12.5min at a temperature of 95 DEG C, becomes antibiotic cotton fiber powder by 27.5min
Body.The distilled water of 1500g, the absolute ethyl alcohol of 400g, 350g are separately added into antibiotic cotton fiber powder after antibacterial processed
The 6301 pink F3R of azo coating of crosslinking agent AF6900,250g of adhesive UDT, 35g mix, Ran Hou
It is stirred evenly under the conditions of 700r/min mixing speeds and 35min mixings time, preparing becomes dye liquor.
Example IV
As stated above, by the flaxen fiber powder that 100g grain sizes are 15 μm, 2L is placed in by absolute ethyl alcohol and distilled water by body
Product is than being 2:In the treatment fluid containing 20g antiseptics CTA-736 that 8 ratio is prepared, ultrasonic power at 1200 watts, 35 DEG C
At a temperature of be ultrasonically treated 15min, the treatment fluid containing flaxen fiber powder after supersound process is filtered, is obtained through ultrasound
The flaxen fiber powder of processing, then obtained sonicated flaxen fiber powder is dried into 30min at a temperature of 30 DEG C, then
Flaxen fiber powder after drying is heat-treated 15min at a temperature of 90 DEG C, becomes antibacterial flaxen fiber powder.To antibacterial processed
Adhesive UDT, 50g of the distilled water of 1000g, the absolute ethyl alcohol of 600g, 500g are separately added into antibacterial flaxen fiber powder afterwards
The 8601 green FB of phthalocyanines coating of crosslinking agent AF6900,400g mix, then in 600r/min mixing speeds and
It is stirred evenly under the conditions of 40min mixings time, preparing becomes dye liquor.
Embodiment five
As stated above, by the flaxen fiber powder that 100g grain sizes are 30 μm, 5L is placed in by absolute ethyl alcohol and distilled water by body
Product is than being 4:In the treatment fluid containing 100g antiseptics CTA-736 that 6 ratio is prepared, ultrasonic power at 1800 watts, 25
10min is ultrasonically treated at a temperature of DEG C, the treatment fluid containing flaxen fiber powder after supersound process is filtered, is obtained through super
The flaxen fiber powder of sonication, then obtained sonicated flaxen fiber powder is dried into 25min at a temperature of 40 DEG C, so
The flaxen fiber powder after drying is heat-treated 10min at a temperature of 100 DEG C afterwards, becomes antibacterial flaxen fiber powder.To through antibacterial
Be separately added into treated antibacterial flaxen fiber powder the distilled water of 2000g, the absolute ethyl alcohol of 200g, 200g adhesive UDT,
The 8301 indigo plant FFG of phthalocyanines coating of crosslinking agent AF6900,100g of 20g are mixed, then in 800r/min mixing speeds
It is stirred evenly under the conditions of 30min mixings time, preparing becomes dye liquor.
Embodiment six
As stated above, by the flaxen fiber powder that 100g grain sizes are 22.5 μm, 3.5L is placed in by absolute ethyl alcohol and distilled water
It is 3 by volume:In the treatment fluid containing 52.5g antiseptics CTA-736 that 7 ratio is prepared, in 1500 watts of ultrasonic wave work(
Rate is ultrasonically treated 12.5min at a temperature of 30 DEG C, and the treatment fluid containing flaxen fiber powder after supersound process is filtered,
Sonicated flaxen fiber powder is obtained, then obtained sonicated flaxen fiber powder is dried at a temperature of 35 DEG C
Then flaxen fiber powder after drying is heat-treated 12.5min by 27.5min at a temperature of 95 DEG C, become antibacterial flaxen fiber powder
Body.The distilled water of 1500g, the absolute ethyl alcohol of 400g, 350g are separately added into antibacterial flaxen fiber powder after antibacterial processed
The 6406 bright blue FGB of phthalocyanines coating of crosslinking agent AF6900,250g of adhesive UDT, 35g mix, Ran Hou
It is stirred evenly under the conditions of 700r/min mixing speeds and 35min mixings time, preparing becomes dye liquor.
Claims (3)
1. a kind of dye liquor preparation method for improving textile coating dyeing anti-microbial property, it is characterised in that：The dye liquor preparation side
Method carries out according to the following steps：
A. the antimicrobial treatment of cellulose powder
The cellulose powder that grain size is 15~30 μm is placed in and is mixed by absolute ethyl alcohol, distilled water and antiseptic CTA-736
Treatment fluid in, be ultrasonically treated in supersonic generator, the treatment fluid containing cellulose powder after supersound process through take out
Filter obtains sonicated cellulose powder, then obtained sonicated cellulose powder is dried, heat treatment, into
For antibacterial cellulose powder, wherein, the bath raio for the treatment of fluid is 1:20~1:50, the volume ratio of absolute ethyl alcohol and distilled water is 2:8
~4:The concentration of 6, antiseptic CTA-736 are 10~20g/L, and ultrasonic power is 1200~1800 watts, are ultrasonically treated temperature and are
25~35 DEG C, sonication treatment time be 10~15min, drying temperature be 30~40 DEG C, drying time be 25~30min, heat at
It is 90~100 DEG C to manage temperature, and heat treatment time is 10~15min；
B. the preparation of dye liquor
In antibacterial cellulose powder after antibacterial processed, the steaming that quality is 10~20 times of antibacterial cellulose powder is separately added into
Distilled water, 2~6 times of absolute ethyl alcohol, 2~5 times of adhesive UDT, 0.2~0.5 times of crosslinking agent AF6900,1~4 times of coating
It mixes, is then stirred evenly under the conditions of 600~800r/min mixing speeds and 30~40min mixings time, prepared
As dye liquor.
2. a kind of dye liquor preparation method for improving textile coating dyeing anti-microbial property as described in claim 1, it is characterised in that：
The cellulose powder is one kind in cotton fiber powder or flaxen fiber powder.
3. a kind of dye liquor preparation method for improving textile coating dyeing anti-microbial property as described in claim 1, it is characterised in that：
The coating is one kind in azo coating or phthalocyanines coating.
Priority Applications (1)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| CN201711142741.3A CN108071026A (en) | 2017-11-17 | 2017-11-17 | A kind of dye liquor preparation method for improving textile coating dyeing anti-microbial property |
Applications Claiming Priority (1)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| CN201711142741.3A CN108071026A (en) | 2017-11-17 | 2017-11-17 | A kind of dye liquor preparation method for improving textile coating dyeing anti-microbial property |
Publications (1)
| Publication Number | Publication Date |
|---|---|
| CN108071026A true CN108071026A (en) | 2018-05-25 |
Family
ID=62157471
Family Applications (1)
| Application Number | Title | Priority Date | Filing Date |
|---|---|---|---|
| CN201711142741.3A Pending CN108071026A (en) | 2017-11-17 | 2017-11-17 | A kind of dye liquor preparation method for improving textile coating dyeing anti-microbial property |
Country Status (1)
| Country | Link |
|---|---|
| CN (1) | CN108071026A (en) |
Citations (1)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN102212964A (en) * | 2010-04-09 | 2011-10-12 | 英联企业有限公司 | Preparation for application to cellulosic textile materials and textiles containing said preparation |
-
2017
- 2017-11-17 CN CN201711142741.3A patent/CN108071026A/en active Pending
Patent Citations (1)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN102212964A (en) * | 2010-04-09 | 2011-10-12 | 英联企业有限公司 | Preparation for application to cellulosic textile materials and textiles containing said preparation |
Similar Documents
| Publication | Publication Date | Title |
|---|---|---|
| CN108754867A (en) | A kind of antibacterial nonwoven cloth and preparation method thereof | |
| Babar et al. | Exhaust reactive dyeing of lyocell fabric with ultrasonic energy | |
| Diaa et al. | Printing wool fabrics with natural dyes curcuma and alkanet (a critique) | |
| EP3353343A1 (en) | Textile fabrics with denim-like features | |
| CN106381730B (en) | A kind of original bamboo fabric based on grape pigment dyeing and preparation method thereof | |
| CN107354529A (en) | A kind of preparation method of acrylic fiber, acrylic fiber and fabric | |
| Reda et al. | An observation on the wet processes of natural fabrics | |
| CN207738903U (en) | A kind of acrylic fiber and fabric | |
| CN101302661A (en) | Preparation method of colored antibacterial viscose fiber | |
| CN108071026A (en) | A kind of dye liquor preparation method for improving textile coating dyeing anti-microbial property | |
| CN113846453A (en) | Yarn dyeing and finishing device and method | |
| Hassabo et al. | Acrylic fabric printing with different techniques | |
| CN109594333A (en) | A kind of mosquito-proof antibacterial fabric fabric and preparation method thereof | |
| CN107916564A (en) | Embroidery thread for three-dimensional embroidery and preparation method thereof | |
| KR20060040626A (en) | The he manufacturing method of flocked fabrics with elasticity using scrapped leather | |
| KR20060016282A (en) | Multi layer non-woven fabric and manufacturing method using nano-silverparticles and microcapsules | |
| JP7179270B2 (en) | Fiber with alginate coating and method for producing same | |
| CN108060593A (en) | A kind of dye liquor preparation method for improving textile coating dyeing antistatic property | |
| CN110367610A (en) | A kind of antibacterial deodourizing socks and its manufacturing method | |
| CN108071025A (en) | A kind of color paste formulation method for improving textile coating stamp anti-microbial property | |
| CN100334294C (en) | Preparation process for silk protein colorant and its application | |
| CN108060592A (en) | A kind of dye liquor preparation method for improving textile coating dyeing uv resistance energy | |
| CN107916583A (en) | A kind of color paste formulation method for improving textile coating stamp fire resistance | |
| CN107841892A (en) | A kind of color paste formulation method for improving textile coating ultraviolet-proof printed performance | |
| CN107858842A (en) | A kind of dye liquor preparation method for improving textile coating dyeing water repellency |
Legal Events
| Date | Code | Title | Description |
|---|---|---|---|
| PB01 | Publication | ||
| PB01 | Publication | ||
| SE01 | Entry into force of request for substantive examination | ||
| SE01 | Entry into force of request for substantive examination | ||
| RJ01 | Rejection of invention patent application after publication | ||
| RJ01 | Rejection of invention patent application after publication |
Application publication date: 20180525 |