CN107747221A - A kind of color paste formulation method for improving textile coating stamp antistatic property - Google Patents
A kind of color paste formulation method for improving textile coating stamp antistatic property Download PDFInfo
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- CN107747221A CN107747221A CN201711142729.2A CN201711142729A CN107747221A CN 107747221 A CN107747221 A CN 107747221A CN 201711142729 A CN201711142729 A CN 201711142729A CN 107747221 A CN107747221 A CN 107747221A
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- D—TEXTILES; PAPER
- D06—TREATMENT OF TEXTILES OR THE LIKE; LAUNDERING; FLEXIBLE MATERIALS NOT OTHERWISE PROVIDED FOR
- D06P—DYEING OR PRINTING TEXTILES; DYEING LEATHER, FURS OR SOLID MACROMOLECULAR SUBSTANCES IN ANY FORM
- D06P1/00—General processes of dyeing or printing textiles, or general processes of dyeing leather, furs, or solid macromolecular substances in any form, classified according to the dyes, pigments, or auxiliary substances employed
- D06P1/44—General processes of dyeing or printing textiles, or general processes of dyeing leather, furs, or solid macromolecular substances in any form, classified according to the dyes, pigments, or auxiliary substances employed using insoluble pigments or auxiliary substances, e.g. binders
- D06P1/46—General processes of dyeing or printing textiles, or general processes of dyeing leather, furs, or solid macromolecular substances in any form, classified according to the dyes, pigments, or auxiliary substances employed using insoluble pigments or auxiliary substances, e.g. binders using compositions containing natural macromolecular substances or derivatives thereof
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- D—TEXTILES; PAPER
- D06—TREATMENT OF TEXTILES OR THE LIKE; LAUNDERING; FLEXIBLE MATERIALS NOT OTHERWISE PROVIDED FOR
- D06M—TREATMENT, NOT PROVIDED FOR ELSEWHERE IN CLASS D06, OF FIBRES, THREADS, YARNS, FABRICS, FEATHERS OR FIBROUS GOODS MADE FROM SUCH MATERIALS
- D06M15/00—Treating fibres, threads, yarns, fabrics, or fibrous goods made from such materials, with macromolecular compounds; Such treatment combined with mechanical treatment
- D06M15/01—Treating fibres, threads, yarns, fabrics, or fibrous goods made from such materials, with macromolecular compounds; Such treatment combined with mechanical treatment with natural macromolecular compounds or derivatives thereof
- D06M15/15—Proteins or derivatives thereof
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- Engineering & Computer Science (AREA)
- Textile Engineering (AREA)
- Treatments For Attaching Organic Compounds To Fibrous Goods (AREA)
Abstract
The present invention relates to a kind of color paste formulation method for improving textile coating stamp antistatic property, belong to textile printing and dyeing processing technique field.The present invention is used the protein powder after antistatic treatment, it is added to prepare in paste formula and turns into print paste, the protein powder constituents with anti-static function are contained so in print paste, after mill base is printed on fabric, antistatic protein powder is transferred on fabric, so as to the antistatic behaviour having using protein powder, to improve the antistatic property of pigment printing fabric.Carry out antistatic treatment again after protein powder is dyed to different colors before antistatic treatment, it is coloured antistatic protein powder to be so added in paste formula, and the fabric printed by this mill base can obtain the visual effect of colour mixture.The method that the present invention prepares paint-printing colour size, mill base process for preparation simple possible, has operability, it is easy to accomplish industrialized production.
Description
Technical field
The present invention relates to a kind of color paste formulation method for improving textile coating stamp antistatic property, category textile printing and dyeing processing
Technical field.
Background technology
Pigment printing is by means of the effect of adhesive in print paste and by the fibrous material of clagging to printing
A kind of printing method.Because its technique is simple, production procedure is short, it is especially latter in pigment printing as need not enter water-filling
Wash, so as to save substantial amounts of water, and reduce the discharge of pollution, be a kind of production and processing mode of clean environment firendly, so
It is deep to be welcome by printing and dyeing enterprise.Coating, adhesive, thickener and other auxiliary agents are typically contained in the mill base composition of pigment printing
With the main component such as water.Wherein, coating provides colouring component in the mill base of pigment printing, is by the pigment of organic (or inorganic)
Add the ground manufactured slurry of water with auxiliary agents such as corresponding dispersant, wetting agent, colloid protective agent, preservatives.Using painting
When expecting stamp, due to the organic solvent not soluble in water and conventional of the granules of pigments in coating so that coating is not direct to fiber
Property, as long as ensureing that the adhesive in print paste there are enough adhesivenesses, stamp can be almost carried out to all fibrous materials, can
Avoid using problem caused by different dyes Graft versus host disease during dye printing, the stamp for multiple fiber blending product provides
Good solution, pigment printing technique are particularly suitable for use in the stamp of polyester cotton.
Wool, chemical fibre and some blend fabric, because of its unique style and excellent performance, and by the green grass or young crops of consumer
Look at.But the fabric containing these materials in wearing process because friction etc. effect be also easy to produce electrostatic, so as to adsorb dust, inhale body,
Make one uncomfortable when wearing, this phenomenon occurs especially in the season of northern cold cool-drying.Therefore, antistatic textile is developed
Have great importance.Open magazine《Wool spinning science and technology》, entitled " the woolen antistatic finish of o. 11th of 2012 publication dates
Select three kinds of different antistatic additive to use different technique in technique ", antistatic finish carried out to wool fabric, the results showed that
Preferable treatment effect can be obtained by soaking three roll process using chitosan three.Open magazine《Zhejiang Prov Engineering Academy journal》, it is open
The good antistatic additive of washability is developed in the 3rd phase of 2000 dates entitled " the antistatic research of polyester ", and can be used for
The antistatic finish of polyester, chemical ＆ blended fabric and blend fabric.Open magazine《Printing and dyeing》, the 5th phase title of 2015 publication dates
It is anti-quiet to be carried out in " antistatic finish of wool and its blend fabric " using five kinds of antistatic additive to wool and its blend fabric
Electricity arranges, and different fabrics and finishing technique obtain different antistatic effects.The antistatic property of these fabrics all passes through
Antistatic finish is carried out to it to obtain.
Some patents of invention disclose the application field of protein powder, Chinese patent application publication No. CN 102677222
A, 2012 Shen Qing Publication dates September 19 days, a kind of entitled " preparation of high-strength cellulose protein fiber of innovation and creation
Method ", this application case disclose a kind of method that high-strength cellulose protein fiber is prepared using organic powder, technique letter
It is single, good product performance, it is easy to accomplish industrialized production.The A of Chinese patent application publication No. CN 102441173, data of publication of application
2012 phase May 9, innovation and creation it is entitled " sedimentable protein matter powder for pharmaceutical carrier drug delivery system
Preparation method ", this application case discloses one kind using protein powder as pharmaceutical carrier, for the controlled release of medicine, with more
Good land productivity medicine reaches the purpose for the treatment of.The A of Chinese patent application publication No. CN 1594682,2005 3 Shen Qing Publication date
The moon 16, a kind of entitled " chemical fibre and its producer being modified with natural protein fiber superfine powder of innovation and creation
Method ", this application case disclose a kind of by fine protein powder and the method for raw materials of chemical fibres composite spinning, formation
Fiber there is imitative hair, Silk and other effects, the physics and chemical property of fiber can be improved.For the protein using functionalization
Powder is added in paint-printing colour size, to improve the document of printing fabric property then rarely seen open report.
The content of the invention
For above-mentioned problem, it is an object of the invention to improve the antistatic property of pigment printing fabric, pass through
The protein powder added into paste formula after antistatic treatment, turn into paint-printing colour size to prepare, utilize print
Antistatic behaviour possessed by the antistatic protein powder added in pattern slurry, to improve the antistatic behaviour of pigment printing fabric
Energy.
To achieve these goals, its technical solution is：
A kind of color paste formulation method for improving textile coating stamp antistatic property, described color paste formulation method is by following
Step is carried out：
A. the antistatic treatment of protein powder
The protein powder that particle diameter is 10~20 μm is placed in and mixed by absolute ethyl alcohol, distilled water and antistatic additive FK-312
In the treatment fluid formed, it is ultrasonically treated in supersonic generator, the treatment fluid containing protein powder after supersound process
Through filtering, sonicated protein powder is obtained, then obtained sonicated protein powder is dried, at heat
Reason, turns into antistatic protein powder, wherein, the bath raio for the treatment of fluid is 1:20~1:50, the volume of absolute ethyl alcohol and distilled water
Than for 1:9~3:7, antistatic additive FK-312 concentration are 20~100g/L, and ultrasonic power is 1200~1800 watts, at ultrasound
It is 45~55 DEG C to manage temperature, and sonication treatment time be 25~30min, and drying temperature is 30~40 DEG C, drying time for 25~
30min, heat treatment temperature are 100~120 DEG C, and heat treatment time is 15~20min；
B. the preparation of mill base
Under the conditions of 200~300r/min mixing speeds and 6~10min mixings time, to resisting after antistatic treatment
In electrostatic protein matter powder, be separately added into quality be the distilled water of antistatic 6.5~10.5 times of protein powder, 2~3.5 times
Absolute ethyl alcohol, 3~5.5 times of adhesive UDT premixs are combined, then 400~600r/min mixing speeds and 80~
Being stirred under the conditions of 100min mixings time, preparation turns into antistatic protein powder somaplasm, then by antistatic protein powder
The coating and 1~2.6% sodium alginate of the mass percent addition 8~18% of slurry, in 600~800r/min mixing speeds and
Stirred under the conditions of 100~120min mixings time, preparation turns into mill base.
Described protein powder is one kind in silk powder or wool powder or down-powder.
Described coating is one kind in azo coating or phthalocyanines coating.
As a result of above technical scheme, a kind of mill base for improving textile coating stamp antistatic property of the present invention is prepared
The technical characterstic of method is：
For protein powder after antistatic treatment, antistatic additive can form one layer of cation in protein powder surface
Conductive film, this layer film can conduct caused electrostatic charge rapidly, and minimizing electrostatic lotus gathers protein powder surface, from
And make protein powder that there is anlistatig feature.Antistatic protein powder is added to prepare in paste formula and turns into print
Pattern is starched, and this protein powder constituents with anti-static function is just contained in such print paste, when mill base is printed
After on to fabric, the protein powder with anti-static function is transferred on fabric, so as to utilize protein powder
The antistatic behaviour that body has, to improve the antistatic property of pigment printing fabric.When protein powder before antistatic treatment quilt
Antistatic treatment is carried out again after dying different colors, and it is coloured antistatic protein to be so added in paste formula
Powder, the fabric printed by this mill base can obtain the visual effect of colour mixture.The present invention prepares the method for paint-printing colour size, color
Process for preparation simple possible is starched, there is operability, it is easy to accomplish industrialized production.
Embodiment
With reference to specific embodiment, a kind of mill base of raising textile coating stamp antistatic property of the present invention is prepared
Method is described in further detail.
A kind of color paste formulation method for improving textile coating stamp antistatic property, described color paste formulation method is by following
Step is carried out：
A. the antistatic treatment of protein powder
The protein powder that particle diameter is 10~20 μm is placed in and mixed by absolute ethyl alcohol, distilled water and antistatic additive FK-312
In the treatment fluid formed, it is ultrasonically treated in supersonic generator, the treatment fluid containing protein powder after supersound process
Through filtering, sonicated protein powder is obtained, then obtained sonicated protein powder is dried, at heat
Reason, turns into antistatic protein powder, wherein, the bath raio for the treatment of fluid is 1:20~1:50, the volume of absolute ethyl alcohol and distilled water
Than for 1:9~3:7, antistatic additive FK-312 concentration are 20~100g/L, and ultrasonic power is 1200~1800 watts, at ultrasound
It is 45~55 DEG C to manage temperature, and sonication treatment time be 25~30min, and drying temperature is 30~40 DEG C, drying time for 25~
30min, heat treatment temperature are 100~120 DEG C, and heat treatment time is 15~20min.
Protein powder is by one kind in the protein fibre such as silk fiber or wool fiber or down fiber, by machine
Protein micro particles of the particle diameter yardstick that tool cutting and grinding forms at 10~20 μm, the too small then difficulty of processing of particle diameter is big, increase
Production cost；Particle diameter is larger, may result in the reduction of the crock fastness of post-coatings PRINTED FABRIC.By fiber to powder
In the process of body particle, acted on merely through physical mechanical, the basic structural unit of these protein powders remains as albumen
Matter, the maximum change occurred compared with the fiber of before processing are to process front and rear outward appearance physical aspect and the difference of yardstick, material
Material outward appearance becomes zero dimension powder by original one-dimensional linear, and protein powder has than the specific surface area of fibrillation greatly to be carried
Height, this causes protein powder to significantly increase the adsorption capacity for contaminating material compared with fibrillation.Also, protein fibre is by super
After refinement processing, there is the group that can more participate in reaction to display in powder, the chemical reaction ability of powder is more former
Fiber significantly improves.When carrying out antistatic treatment to protein powder, under the treatment conditions same with fibrillation, protein
The antistatic additive of powder absorption can be distributed on bigger surface area so that the powder on same units area, it is difficult to reach
The treatment effect consistent with fibrillation.So when carrying out antistatic treatment, the dosage of antistatic additive also will be modulated suitably, to protect
Demonstrate,prove preferable treatment effect.Antistatic treatment liquid is mixed by absolute ethyl alcohol, distilled water, antistatic additive FK-312, wherein,
The bath raio for the treatment of fluid is 1:20~1:50, the volume ratio of absolute ethyl alcohol and distilled water is 1:9~3:7, antistatic additive FK-312's
Concentration is 20~100g/L.Distilled water can make antistatic protein powder fully be swelled and be dispersed in treatment fluid, its dosage
It must assure that the abundant swelling of powder.Absolute ethyl alcohol molecular weight is small, surface tension is low, viscosity is small, permeability is strong, can promote egg
The swelling of white matter powder, and aggregation of the powder in water can be mitigated, be advantageous to powder and disperse in treatment fluid, powder is more held
Easily reacted with antistatic additive.To be sufficiently impregnated protein powder and reacting, the bath raio for the treatment of fluid is set as 1:20~1:
50.Chemical concentration in treatment fluid is higher, and the volume ratio of absolute ethyl alcohol and distilled water is unsuitable excessive, in order to avoid influence antistatic
Agent it is dispersed.Protein powder can form one layer of cationic electroconductive after antistatic additive FK-312 processing on its surface
Film, this layer film can conduct caused electrostatic charge rapidly, minimizing electrostatic lotus protein powder surface accumulation, so as to reach
To anlistatig effect.By protein powder be impregnated in preparation containing absolute ethyl alcohol, distilled water and antistatic additive FK-312
In treatment fluid, it is ultrasonically treated in ultrasonic environment, ultrasonic power is 1200~1800 watts, and it is 45 to be ultrasonically treated temperature
~55 DEG C, sonication treatment time is 25~30min.Ultrasonic wave is that a kind of frequency is 2 × 104Hz~2 × 109Hz mechanical wave, its
Action principle is the dither effect using ultrasonic wave, protein powder is produced substantial amounts of space in processing procedure, to accommodate
More antistatic additive, and the protein powder of swelling is in loose state.In addition, imitated using cavitation caused by ultrasonic wave
Should, antistatic additive is deep into broader region under HI high impact effect, it is anti-so as to promote protein powder fully to adsorb
Electrostatic agent, improve the respond of protein powder and antistatic additive.Protein powder after being ultrasonically treated adsorbs
Substantial amounts of antistatic additive, some antistatic additive under the energy booster action of ultrasonic wave, on protein powder there occurs
Reaction.When protein powder is ultrasonically treated in antistatic treatment liquid, ultrasonic power should be with being ultrasonically treated temperature, time
Mutually coordinate etc. parameter, when ultrasonic power improves, then can correspondingly reduce treatment temperature and processing time.At will be through ultrasound
The treatment fluid containing protein powder after reason is filtered, then will filter the obtained absorption protein of a large amount of antistatic additive
Powder is dried under 30~40 DEG C of lower temperature, uniform and stable in favor of subsequent heat treatment effect.Then by after drying
Protein powder is heat-treated 15~20min at a temperature of 100~120 DEG C, turns into antistatic protein powder.Heat treatment can make to surpass
The unreacted antistatic additive on protein powder is adsorbed after sonication, is further reacted in the presence of heat energy,
Protein powder surface forms cationic electroconductive film, to assign the antistatic property of protein powder.
B. the preparation of mill base
Under the conditions of 200~300r/min mixing speeds and 6~10min mixings time, to resisting after antistatic treatment
In electrostatic protein matter powder, be separately added into quality be the distilled water of antistatic 6.5~10.5 times of protein powder, 2~3.5 times
Absolute ethyl alcohol, 3~5.5 times of adhesive UDT premixs are combined, then 400~600r/min mixing speeds and 80~
Being stirred under the conditions of 100min mixings time, preparation turns into antistatic protein powder somaplasm, then by antistatic protein powder
The coating and 1~2.6% sodium alginate of the mass percent addition 8~18% of slurry, in 600~800r/min mixing speeds and
Stirred under the conditions of 100~120min mixings time, preparation turns into mill base.
When preparing print paste, the relatively low mixing speed for starting to size mixing is 200~300r/min, and this is primarily to anti-
Only charging when raw material splashing, one side stirring at low speed in 6~10min on one side feed, to prevent antistatic protein powder
Lumpd during charging, influence to disperse.Because the mixing speed low time is short, these raw materials are simply simply pre-mixed one
Rise, do not disperse sufficiently uniformly also.Into the antistatic protein powder after antistatic treatment, it is anti-to be separately added into quality
Distilled water, 2~3.5 times of absolute ethyl alcohol, 3~5.5 times of the adhesive UDT premixs of 6.5~10.5 times of electrostatic protein matter powder
It is combined.The effect of distilled water is to make antistatic protein powder that sufficiently swelling occur and disperse.Due to antistatic albumen
Matter powder is easy to assemble in water, promotes the swelling of protein powder so to add absolute ethyl alcohol and disperses.Absolute ethyl alcohol is also
The print paste rapid osmotic that can make to be printed on fabric enters fibrous inside, to improve stamp tinctorial yield and colour vividness.
When PRINTED FABRIC is in follow-up curing fixation, ethanol can volatilize away from fabric, will not to the final mass of Printing
Have an impact.Absolute ethyl alcohol dosage should be moderate, and dosage is too high, can reduce phase of the antistatic protein powder in print paste
To content, and need to increase the dosage of thickener, the feel of PRINTED FABRIC is impacted.Adhesive UDT applies for acrylic compounds
Expect printing adhesive, the good film-forming property on fiber, protein powder and pigment particles can be adhered on the fabric of printing, carried
The fastness of high Printing.The ratio of adhesive should be moderate in print paste, and dosage is too low, then film forming is deteriorated, antistatic egg
White matter powder is difficult to be strapped on fabric completely, can reduce the crock fastness of PRINTED FABRIC；If binder dosage is too high, cover
Epiphragma layer is thickening, and antistatic protein powder is covered by thicker macromolecule membrane layer, so that is printed on fabric
Antistatic protein powder, it is difficult to effectively play its anti-static function.Then by the slurries after premixing 400~
Stirred under the conditions of 600r/min mixing speeds and 80~100min mixings time, preparation turns into antistatic protein powder
Slurry.Mixing speed is now improved, slurries is quickly moved under larger stirring shearing force, is made under prolonged stirring
Raw material is well mixed.Mixing speed now is unsuitable too low, and shearing force otherwise can be caused insufficient, make antistatic protein powder point
It is scattered irregular, in addition, also to prevent in quick stirring, powder slurry splashing blow tank；Meanwhile mixing time can not be too short, otherwise
Antistatic protein powder somaplasm is difficult that stirring in a short time is opened.The mass percent of antistatic protein powder somaplasm is pressed again, to
The coating and 1~2.6% sodium alginate of addition 8~18% in antistatic protein powder somaplasm.Preparing paint-printing colour size
When, available coating type has one kind in azo coating or phthalocyanines coating, and its addition should be according to printing fabric
Color, fastness etc. are required and adjusted.The sodium alginate added in print paste formula is printing thickening agent, and sodium alginate is one
Kind natural macromolecule amylose, has good thickening effect, can improve the viscosity of mill base, prevents mill base imbibition, assigns mill base
Rheological characteristic and bin stability, can make bright-colored printing pattern, sharpness of border, color it is uniform.According to the formula of print paste
Composition and material rate, the sodium alginate quality of addition using resist 1~2.6% mass percent of electrostatic protein matter powder slurry as
Preferably, sodium alginate dosage is too low, then color paste viscosity is small, and imbibition is serious, and printing obscure boundary is clear；When dosage is too high, stamp color
Slurry viscosity is too big, and mill base scrapes difficulty, and the feel of PRINTED FABRIC can be had an impact.By antistatic protein powder somaplasm, apply
Material and sodium alginate stir under the conditions of 600~800r/min mixing speeds and 100~120min mixings time, are configured to
For print paste.Mixing speed and mixing time be must assure that so as to stir, otherwise the printing effect of print paste is deteriorated,
And too fast mixing speed, it print paste is splashed and is polluted.
Specific embodiment
Embodiment one
As stated above, by the silk powder that 100g particle diameters are 10 μm, 2L is placed in by absolute ethyl alcohol and distilled water by volume
Than for 1:In the treatment fluid containing 40g antistatic additive FK-312 that 9 ratio is prepared, ultrasonic power at 1200 watts, 55 DEG C
At a temperature of be ultrasonically treated 30min, the treatment fluid containing silk powder after supersound process is filtered, obtain through ultrasound at
The silk powder of reason, then obtained sonicated silk powder is dried into 30min at a temperature of 30 DEG C, then will drying
Silk powder afterwards is heat-treated 20min at a temperature of 100 DEG C, turns into antistatic silk powder.In 200r/min mixing speeds
Under the conditions of 10min mixings time, be separately added into the antistatic silk powder after antistatic treatment 650g distilled water,
350g absolute ethyl alcohol, 550g adhesive UDT premixs are combined, and are then stirred in 400r/min mixing speeds and 100min
Stirred under time conditions, preparation turns into antistatic silk powder slurry, then adds 132g's into antistatic silk powder slurry
The bright red FFG and 16.5g of azo coating 8111 sodium alginate, in 600r/min mixing speeds and 120min mixing time conditions
Under stir, preparation turn into mill base.
Embodiment two
As stated above, by the wool powder that 100g particle diameters are 20 μm, 5L is placed in by absolute ethyl alcohol and distilled water by volume
Than for 3:In the treatment fluid containing 500g antistatic additive FK-312 that 7 ratio is prepared, ultrasonic power at 1800 watts, 45 DEG C
At a temperature of be ultrasonically treated 25min, the treatment fluid containing wool powder after supersound process is filtered, obtain through ultrasound at
The wool powder of reason, then obtained sonicated wool powder is dried into 25min at a temperature of 40 DEG C, then will drying
Wool powder afterwards is heat-treated 15min at a temperature of 120 DEG C, turns into antistatic wool powder.In 300r/min mixing speeds
Under the conditions of 6min mixings time, be separately added into the antistatic wool powder after antistatic treatment 1050g distilled water,
200g absolute ethyl alcohol, 300g adhesive UDT premixs are combined, and are then stirred in 600r/min mixing speeds and 80min
Stirred under time conditions, preparation turns into antistatic wool powder somaplasm, then adds 297g's into antistatic wool powder somaplasm
Yellow FG and 42.9g sodium alginate in azo coating 8202, in 800r/min mixing speeds and 100min mixing time conditions
Under stir, preparation turn into mill base.
Embodiment three
As stated above, by the down-powder that 100g particle diameters are 15 μm, 3.5L is placed in by absolute ethyl alcohol and distilled water by body
Product is than being 2:In the treatment fluid containing 210g antistatic additive FK-312 that 8 ratio is prepared, ultrasonic power at 1500 watts, 50
27.5min is ultrasonically treated at a temperature of DEG C, the treatment fluid containing down-powder after supersound process is filtered, is obtained through super
The down-powder of sonication, then obtained sonicated down-powder is dried into 27.5min at a temperature of 35 DEG C, then
Down-powder after drying is heat-treated 17.5min at a temperature of 110 DEG C, turns into antistatic down-powder.In 250r/min
Under the conditions of mixing speed and 8min mixings time, it is separately added into 850g's into the antistatic down-powder after antistatic treatment
Distilled water, 275g absolute ethyl alcohol, 425g adhesive UDT premixs are combined, then in 500r/min mixing speeds and
Stirred under the conditions of 90min mixings time, preparing, which turns into antistatic down-powder, starches, then adds in being starched to antistatic down-powder
Enter the 214.5g pink F3R and 29.7g of azo coating 6301 sodium alginate, stirred in 700r/min mixing speeds and 110min
Mix and stirred under time conditions, preparation turns into mill base.
Example IV
As stated above, by the silk powder that 100g particle diameters are 10 μm, 2L is placed in by absolute ethyl alcohol and distilled water by volume
Than for 1:In the treatment fluid containing 40g antistatic additive FK-312 that 9 ratio is prepared, ultrasonic power at 1200 watts, 55 DEG C
At a temperature of be ultrasonically treated 30min, the treatment fluid containing silk powder after supersound process is filtered, obtain through ultrasound at
The silk powder of reason, then obtained sonicated silk powder is dried into 30min at a temperature of 30 DEG C, then will drying
Silk powder afterwards is heat-treated 20min at a temperature of 100 DEG C, turns into antistatic silk powder.In 200r/min mixing speeds
Under the conditions of 10min mixings time, be separately added into the antistatic silk powder after antistatic treatment 650g distilled water,
350g absolute ethyl alcohol, 550g adhesive UDT premixs are combined, and are then stirred in 400r/min mixing speeds and 100min
Stirred under time conditions, preparation turns into antistatic silk powder slurry, then adds 132g's into antistatic silk powder slurry
The green FB and 16.5g of phthalocyanines coating 8601 sodium alginate, under the conditions of 600r/min mixing speeds and 120min mixings time
Stir, preparation turns into mill base.
Embodiment five
As stated above, by the wool powder that 100g particle diameters are 20 μm, 5L is placed in by absolute ethyl alcohol and distilled water by volume
Than for 3:In the treatment fluid containing 500g antistatic additive FK-312 that 7 ratio is prepared, ultrasonic power at 1800 watts, 45 DEG C
At a temperature of be ultrasonically treated 25min, the treatment fluid containing wool powder after supersound process is filtered, obtain through ultrasound at
The wool powder of reason, then obtained sonicated wool powder is dried into 25min at a temperature of 40 DEG C, then will drying
Wool powder afterwards is heat-treated 15min at a temperature of 120 DEG C, turns into antistatic wool powder.In 300r/min mixing speeds
Under the conditions of 6min mixings time, be separately added into the antistatic wool powder after antistatic treatment 1050g distilled water,
200g absolute ethyl alcohol, 300g adhesive UDT premixs are combined, and are then stirred in 600r/min mixing speeds and 80min
Stirred under time conditions, preparation turns into antistatic wool powder somaplasm, then adds 297g's into antistatic wool powder somaplasm
The blue FFG and 42.9g of phthalocyanines coating 8301 sodium alginate, under the conditions of 800r/min mixing speeds and 100min mixings time
Stir, preparation turns into mill base.
Embodiment six
As stated above, by the down-powder that 100g particle diameters are 15 μm, 3.5L is placed in by absolute ethyl alcohol and distilled water by body
Product is than being 2:In the treatment fluid containing 210g antistatic additive FK-312 that 8 ratio is prepared, ultrasonic power at 1500 watts, 50
27.5min is ultrasonically treated at a temperature of DEG C, the treatment fluid containing down-powder after supersound process is filtered, is obtained through super
The down-powder of sonication, then obtained sonicated down-powder is dried into 27.5min at a temperature of 35 DEG C, then
Down-powder after drying is heat-treated 17.5min at a temperature of 110 DEG C, turns into antistatic down-powder.In 250r/min
Under the conditions of mixing speed and 8min mixings time, it is separately added into 850g's into the antistatic down-powder after antistatic treatment
Distilled water, 275g absolute ethyl alcohol, 425g adhesive UDT premixs are combined, then in 500r/min mixing speeds and
Stirred under the conditions of 90min mixings time, preparing, which turns into antistatic down-powder, starches, then adds in being starched to antistatic down-powder
Enter the 214.5g bright blue FGB and 29.7g of phthalocyanines coating 6406 sodium alginate, stirred in 700r/min mixing speeds and 110min
Mix and stirred under time conditions, preparation turns into mill base.
Claims (3)
- A kind of 1. color paste formulation method for improving textile coating stamp antistatic property, it is characterised in that：Described mill base is prepared Method is carried out according to the following steps：A. the antistatic treatment of protein powderThe protein powder that particle diameter is 10~20 μm is placed in and mixed by absolute ethyl alcohol, distilled water and antistatic additive FK-312 Treatment fluid in, be ultrasonically treated in supersonic generator, the treatment fluid containing protein powder after supersound process is through taking out Filter, sonicated protein powder is obtained, then obtained sonicated protein powder is dried, heat treatment, into For antistatic protein powder, wherein, the bath raio for the treatment of fluid is 1:20~1:50, the volume ratio of absolute ethyl alcohol and distilled water is 1: 9~3:7, antistatic additive FK-312 concentration are 20~100g/L, and ultrasonic power is 1200~1800 watts, is ultrasonically treated temperature For 45~55 DEG C, sonication treatment time is 25~30min, and drying temperature is 30~40 DEG C, and drying time is 25~30min, heat Treatment temperature is 100~120 DEG C, and heat treatment time is 15~20min；B. the preparation of mill baseUnder the conditions of 200~300r/min mixing speeds and 6~10min mixings time, to antistatic after antistatic treatment In protein powder, it is the distilled water of antistatic 6.5~10.5 times of protein powder, 2~3.5 times anhydrous to be separately added into quality Ethanol, 3~5.5 times of adhesive UDT premixs are combined, then in 400~600r/min mixing speeds and 80~100min Stirred under the conditions of mixing time, preparation turns into antistatic protein powder somaplasm, then the matter by antistatic protein powder somaplasm Measure the coating and 1~2.6% sodium alginate of percentage addition 8~18%, 600~800r/min mixing speeds and 100~ Stirred under the conditions of 120min mixings time, preparation turns into mill base.
- 2. a kind of color paste formulation method for improving textile coating stamp antistatic property as claimed in claim 1, its feature exist In：Described protein powder is one kind in silk powder or wool powder or down-powder.
- 3. a kind of color paste formulation method for improving textile coating stamp antistatic property as claimed in claim 1, its feature exist In：Described coating is one kind in azo coating or phthalocyanines coating.
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