CN107841890A - A kind of color paste formulation method for improving textile coating stamp water repellency - Google Patents
A kind of color paste formulation method for improving textile coating stamp water repellency Download PDFInfo
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- CN107841890A CN107841890A CN201711142711.2A CN201711142711A CN107841890A CN 107841890 A CN107841890 A CN 107841890A CN 201711142711 A CN201711142711 A CN 201711142711A CN 107841890 A CN107841890 A CN 107841890A
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- water repellent
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- D—TEXTILES; PAPER
- D06—TREATMENT OF TEXTILES OR THE LIKE; LAUNDERING; FLEXIBLE MATERIALS NOT OTHERWISE PROVIDED FOR
- D06P—DYEING OR PRINTING TEXTILES; DYEING LEATHER, FURS OR SOLID MACROMOLECULAR SUBSTANCES IN ANY FORM
- D06P1/00—General processes of dyeing or printing textiles, or general processes of dyeing leather, furs, or solid macromolecular substances in any form, classified according to the dyes, pigments, or auxiliary substances employed
- D06P1/44—General processes of dyeing or printing textiles, or general processes of dyeing leather, furs, or solid macromolecular substances in any form, classified according to the dyes, pigments, or auxiliary substances employed using insoluble pigments or auxiliary substances, e.g. binders
- D06P1/46—General processes of dyeing or printing textiles, or general processes of dyeing leather, furs, or solid macromolecular substances in any form, classified according to the dyes, pigments, or auxiliary substances employed using insoluble pigments or auxiliary substances, e.g. binders using compositions containing natural macromolecular substances or derivatives thereof
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- D—TEXTILES; PAPER
- D06—TREATMENT OF TEXTILES OR THE LIKE; LAUNDERING; FLEXIBLE MATERIALS NOT OTHERWISE PROVIDED FOR
- D06P—DYEING OR PRINTING TEXTILES; DYEING LEATHER, FURS OR SOLID MACROMOLECULAR SUBSTANCES IN ANY FORM
- D06P1/00—General processes of dyeing or printing textiles, or general processes of dyeing leather, furs, or solid macromolecular substances in any form, classified according to the dyes, pigments, or auxiliary substances employed
- D06P1/02—General processes of dyeing or printing textiles, or general processes of dyeing leather, furs, or solid macromolecular substances in any form, classified according to the dyes, pigments, or auxiliary substances employed using azo dyes
-
- D—TEXTILES; PAPER
- D06—TREATMENT OF TEXTILES OR THE LIKE; LAUNDERING; FLEXIBLE MATERIALS NOT OTHERWISE PROVIDED FOR
- D06P—DYEING OR PRINTING TEXTILES; DYEING LEATHER, FURS OR SOLID MACROMOLECULAR SUBSTANCES IN ANY FORM
- D06P1/00—General processes of dyeing or printing textiles, or general processes of dyeing leather, furs, or solid macromolecular substances in any form, classified according to the dyes, pigments, or auxiliary substances employed
- D06P1/14—General processes of dyeing or printing textiles, or general processes of dyeing leather, furs, or solid macromolecular substances in any form, classified according to the dyes, pigments, or auxiliary substances employed using phthalocyanine dyes without vatting
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- D—TEXTILES; PAPER
- D06—TREATMENT OF TEXTILES OR THE LIKE; LAUNDERING; FLEXIBLE MATERIALS NOT OTHERWISE PROVIDED FOR
- D06P—DYEING OR PRINTING TEXTILES; DYEING LEATHER, FURS OR SOLID MACROMOLECULAR SUBSTANCES IN ANY FORM
- D06P1/00—General processes of dyeing or printing textiles, or general processes of dyeing leather, furs, or solid macromolecular substances in any form, classified according to the dyes, pigments, or auxiliary substances employed
- D06P1/44—General processes of dyeing or printing textiles, or general processes of dyeing leather, furs, or solid macromolecular substances in any form, classified according to the dyes, pigments, or auxiliary substances employed using insoluble pigments or auxiliary substances, e.g. binders
- D06P1/445—Use of auxiliary substances before, during or after dyeing or printing
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- D—TEXTILES; PAPER
- D06—TREATMENT OF TEXTILES OR THE LIKE; LAUNDERING; FLEXIBLE MATERIALS NOT OTHERWISE PROVIDED FOR
- D06P—DYEING OR PRINTING TEXTILES; DYEING LEATHER, FURS OR SOLID MACROMOLECULAR SUBSTANCES IN ANY FORM
- D06P1/00—General processes of dyeing or printing textiles, or general processes of dyeing leather, furs, or solid macromolecular substances in any form, classified according to the dyes, pigments, or auxiliary substances employed
- D06P1/44—General processes of dyeing or printing textiles, or general processes of dyeing leather, furs, or solid macromolecular substances in any form, classified according to the dyes, pigments, or auxiliary substances employed using insoluble pigments or auxiliary substances, e.g. binders
- D06P1/46—General processes of dyeing or printing textiles, or general processes of dyeing leather, furs, or solid macromolecular substances in any form, classified according to the dyes, pigments, or auxiliary substances employed using insoluble pigments or auxiliary substances, e.g. binders using compositions containing natural macromolecular substances or derivatives thereof
- D06P1/48—Derivatives of carbohydrates
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- Engineering & Computer Science (AREA)
- Textile Engineering (AREA)
- Health & Medical Sciences (AREA)
- Life Sciences & Earth Sciences (AREA)
- Molecular Biology (AREA)
- Treatments For Attaching Organic Compounds To Fibrous Goods (AREA)
Abstract
The present invention relates to a kind of color paste formulation method for improving textile coating stamp water repellency, belong to textile printing and dyeing processing technique field.The present invention is used the protein powder after water repellent processing, it is added to prepare in paste formula and turns into print paste, this protein powder constituents with waterproofing function are so just contained in print paste, when print paste be used to print fabric, the water repellent protein powder wherein contained is transferred on fabric, using waterproofing function possessed by water repellent protein powder, so as to improve the water repellency of pigment printing fabric.When these protein powders pass through dyeing process in water repellent before processing, fabric that the print paste prepared with these coloured water repellent protein powders is printed, the appearance of colour mixture can be reached.The method of the preparation paint-printing colour size of the present invention, mill base process for preparation is simple and easy, workable, has industrial applications prospect.
Description
Technical field
The present invention relates to a kind of color paste formulation method for improving textile coating stamp water repellency, category textile printing and dyeing processing skill
Art field.
Background technology
Pigment printing is by means of the effect of adhesive in print paste and by the fibrous material of clagging to printing
A kind of printing method.Because its technique is simple, production procedure is short, it is especially latter in pigment printing as need not enter water-filling
Wash, so as to save substantial amounts of water, and reduce the discharge of pollution, be a kind of production and processing mode of clean environment firendly, so
It is deep to be welcome by printing and dyeing enterprise.Coating, adhesive, thickener and other auxiliary agents are typically contained in the mill base composition of pigment printing
With the main component such as water.Wherein, coating provides colouring component in the mill base of pigment printing, is by the pigment of organic (or inorganic)
Add the ground manufactured slurry of water with auxiliary agents such as corresponding dispersant, wetting agent, colloid protective agent, preservatives.Using painting
When expecting stamp, due to the organic solvent not soluble in water and conventional of the granules of pigments in coating so that coating is not direct to fiber
Property, as long as ensureing that the adhesive in print paste there are enough adhesivenesses, stamp can be almost carried out to all fibrous materials, can
The problem of avoiding bringing using different dyes Graft versus host disease during dye printing, the stamp for multiple fiber blending product provides very
Good solution route, pigment printing technique are particularly suitable for use in the stamp of polyester cotton.
The water repellency of fabric refers to that the surface tension of fiber is relatively low, and water droplet can not soak the surface of fiber, and fabric is still
Its gas permeability can so be kept.Fabric with water repellency can meet a variety of demands, such as high-grade Western-style clothes, underlinen fabric, Yi Jiqi
It has the occasion of water repellent requirement.Because textile fabric is hydrophilic high polymer material mostly, pigment printing fabric has certain
Hydrophily, be intended to realize its water repellent effect generally by water repellent finish to complete.Open magazine《Shanghai Textile science and technology》, it is public
Open in the 9th phase of 2015 dates entitled " preparation of super-hydrophobic sensitization discoloration dacron and its performance study " to by coating
The dacron of stamp carries out Organic fluoride arrangement, dacron is obtained super-hydrophobic surface property.Open magazine《Printing and dyeing》,
Lead in the 3rd phase of nineteen ninety-five publication date entitled " application of the AG480 finishing agents in pigment printing product water and oil repellent finish "
Finishing agent AG480 is crossed to arrange pigment printing product to obtain water and oil repellant performance.These water repellent effects are not all had
There is the angle from print paste to realize.
Some patents of invention disclose the application field of protein powder, Chinese patent application publication No. CN 102441173
A, May 9 2012 Shen Qing Publication date, innovation and creation it is entitled " sedimentable protein matter powder be pharmaceutical carrier medicine
The preparation method of thing delivery systme ", this application case disclose it is a kind of using protein powder as pharmaceutical carrier, for medicine can
Controlled release is put, to better profit from the purpose that medicine reaches treatment.The A of Chinese patent application publication No. CN 102677221, application are public
2012 cloth dates September 19 days, entitled " a kind of preparation method of cellular protein fiber " of innovation and creation, this application case
Disclose a kind of protein powder is added in rayon spinning stoste and carry out spinning, it is compound to prepare regenerated fiber cellulose protein
The method of fiber.The A of Chinese patent application publication No. CN 103556465, Shen Qing Publication date 2014 year 2 month 5, innovation and creation
Entitled " a kind of method of polymer filaments surface recombination natural protein fibre powder ", this application case discloses a kind of exist
The method that synthetic fibers surface recombination protein powder body prepares bicomponent filament yarn, the long filament of formation are functional.For utilizing function
The protein powder of change is added in paint-printing colour size, and it is less then to disclose report with the document of improvement printing fabric property.
The content of the invention
For above-mentioned problem, it is an object of the invention to improve the water repellency of pigment printing fabric, by
When preparing paint-printing colour size, protein powder of the addition after water repellent processing into paste formula, these additions are utilized
Water repellent protein powder possessed by waterproofing function, to improve the water repellency of pigment printing fabric.
To achieve these goals, its technical solution is：
A kind of color paste formulation method for improving textile coating stamp water repellency, described color paste formulation method press following step
It is rapid to carry out：
A. the water repellent processing of protein powder
By particle diameter be 10~20 μm of protein powder be placed in mixed by absolute ethyl alcohol, distilled water and water repellent FK-518 and
Into through vinegar acid for adjusting pH value be 5~6 treatment fluid in, be ultrasonically treated in supersonic generator, contained after supersound process
There is the treatment fluid of protein powder through filtering, obtain sonicated protein powder, then it is sonicated by what is obtained
Protein powder is dried, and heat treatment, turns into water repellent protein powder, wherein, the bath raio for the treatment of fluid is 1:20~1:50, anhydrous second
The volume ratio of alcohol and distilled water is 2:8~4:6, water repellent FK-518 concentration are 10~50g/L, ultrasonic power is 1200~
1800 watts, it is 50~60 DEG C to be ultrasonically treated temperature, and sonication treatment time is 35~40min, and drying temperature is 30~40 DEG C, drying
Time is 25~30min, and heat treatment temperature is 100~110 DEG C, and heat treatment time is 15~20min；
B. the preparation of mill base
Under the conditions of 200~300r/min mixing speeds and 6~10min mixings time, to the water repellent after water repellent is handled
In protein powder, be separately added into quality be the distilled water of 6~10 times of water repellent protein powder, 2~3 times of absolute ethyl alcohol, 3~
5 times of adhesive UDT premixs are combined, then in 400~600r/min mixing speeds and 80~100min mixing time bars
Being stirred under part, preparation turns into water repellent protein powder somaplasm, then 5 are added by the mass percent of water repellent protein powder somaplasm~
15% coating and 1~2.5% sodium alginate, in 600~800r/min mixing speeds and 100~120min mixing time bars
Stirred under part, preparation turns into mill base.
Described protein powder is one kind in silk powder or wool powder or down-powder.
Described coating is one kind in azo coating or phthalocyanines coating.
As a result of above technical scheme, a kind of mill base preparation side for improving textile coating stamp water repellency of the present invention
The technical characterstic of method is：
Protein powder can significantly reduce the surface energy of protein powder, change its surface after water repellent processing
Property, protein powder is increased the angle of wetting of water, be not easy to be spontaneously wet out by water, so that protein powder produces water repellent effect.
Water repellent protein powder is added to prepare in paste formula system and turns into print paste, this is just contained in such print paste
Protein powder constituents of the kind with waterproofing function.When print paste be used to print fabric, wherein the water repellent albumen contained
Matter powder is transferred on fabric, using waterproofing function possessed by water repellent protein powder, so as to improve coating
The water repellency of PRINTED FABRIC, to meet the requirement of the water repellent of the fabrics such as high-grade Western-style clothes, shirt.Added in paste formula these
Water repellent protein powder, different colors can also be dyed in water repellent before processing and carry out water repellent processing again, be so added to print
In pattern slurry is coloured water repellent protein powder, and the outward appearance that the fabric printed with this mill base can show colour mixture is imitated
Fruit.The method of the preparation paint-printing colour size of the present invention, mill base process for preparation is simple and easy, workable, has industrialization
Application prospect.
Embodiment
With reference to specific embodiment, to a kind of mill base preparation side of raising textile coating stamp water repellency of the present invention
Method is described in further detail.
A kind of color paste formulation method for improving textile coating stamp water repellency, described color paste formulation method press following step
It is rapid to carry out：
A. the water repellent processing of protein powder
By particle diameter be 10~20 μm of protein powder be placed in mixed by absolute ethyl alcohol, distilled water and water repellent FK-518 and
Into through vinegar acid for adjusting pH value be 5~6 treatment fluid in, be ultrasonically treated in supersonic generator, contained after supersound process
There is the treatment fluid of protein powder through filtering, obtain sonicated protein powder, then it is sonicated by what is obtained
Protein powder is dried, and heat treatment, turns into water repellent protein powder, wherein, the bath raio for the treatment of fluid is 1:20~1:50, anhydrous second
The volume ratio of alcohol and distilled water is 2:8~4:6, water repellent FK-518 concentration are 10~50g/L, ultrasonic power is 1200~
1800 watts, it is 50~60 DEG C to be ultrasonically treated temperature, and sonication treatment time is 35~40min, and drying temperature is 30~40 DEG C, drying
Time is 25~30min, and heat treatment temperature is 100~110 DEG C, and heat treatment time is 15~20min.
Protein powder is by one kind in the protein fibre such as silk fiber or wool fiber or down fiber, by machine
Protein micro particles of the particle diameter yardstick that tool cutting and grinding forms at 10~20 μm, the too small then difficulty of processing of particle diameter is big, increase
Production cost；Particle diameter is larger, may result in the reduction of the crock fastness of post-coatings PRINTED FABRIC.By fiber to powder
In the process of body particle, acted on merely through physical mechanical, the basic chemical composition of these protein powders remains as albumen
Matter, the maximum change of generation are to process front and rear outward appearance physical aspect and the difference of yardstick, and material appearance is by original one-dimensional
Linearly become zero dimension powder, the more corresponding fibrillation specific surface area of protein powder particle has great increase, and this causes egg
White matter powder significantly increases compared with fibrillation to the suction-operated for contaminating material.Also, protein fibre by fine processing after,
There is the group that can more participate in reaction to reveal in powder, the chemical reaction ability of powder significantly improves compared with fibrillation.
When carrying out water repellent processing to protein powder, under the treatment conditions same with corresponding protein fibre, protein powder
The water repellent of absorption can be distributed on bigger surface area so that on the powder of same units area, it is difficult to reach with it is corresponding
The consistent treatment effect of fiber.So when carrying out water repellent processing, the dosage of water repellent will be also correspondingly improved, and could so be reached
To preferable treatment effect.Water repellent treatment fluid is mixed by absolute ethyl alcohol, distilled water and water repellent FK-518, is adjusted through acetic acid
It is 5~6 to save pH value, wherein, the bath raio for the treatment of fluid is 1:20~1:50, the volume ratio of absolute ethyl alcohol and distilled water is 2:8~4:
6, water repellent FK-518 concentration are 10~50g/L.The effect of distilled water is to make protein powder that sufficiently swelling occur and divide
It is dispersed in treatment fluid, its dosage should ensure that the abundant swelling of protein powder.Absolute ethyl alcohol molecular weight is small, surface tension is low,
Viscosity is small, permeability is strong, can promote the swelling of protein powder, and can mitigate aggregation of the powder in water, is advantageous to powder
It is scattered in treatment fluid, powder is preferably reacted with water repellent.Water repellent FK-518 is that fluorine-containing macromolecule is birdsed of the same feather flock together zoarium,
After handling on protein powder, the surface energy of protein powder can be significantly reduced, soaks the water of protein powder surface
Angle increases, and is not easy to be spontaneously wet out by water, so as to change the surface property of protein powder, protein powder is had water repellent effect.By
It is stronger to the adsorption capacity of water repellent in protein powder, so to ensure treatment effect, water repellent FK-518 concentration determines
For 10~50g/L.Water repellent FK-518 is polymer, is insoluble in organic solvent ethanol, so absolute ethyl alcohol and distilled water
Volume ratio it is unsuitable too high, water repellent FK-518 otherwise may be made to be difficult to be stabilized in treatment fluid.To ensure protein
Powder is sufficiently impregnated and reacted, and the bath raio that the bath raio for the treatment of fluid should not be too low but too high can also reduce protein powder to water repellent
The exhaustion rate of agent, so the bath raio for the treatment of fluid is set as 1:20~1:50.PH value is solutions of weak acidity, can be made on protein powder
Part amino protonate, to promote protein powder and water repellent preferably to react.Protein powder is impregnated
In the treatment fluid containing absolute ethyl alcohol, distilled water and water repellent FK-518 of preparation, surpassed under the conditions of ultrasonic environment
Sonication, ultrasonic power be 1200~1800 watts, be ultrasonically treated temperature be 50~60 DEG C, sonication treatment time be 35~
40min.Ultrasonic wave is that a kind of frequency is 2 × 104Hz~2 × 109Hz mechanical wave, its action principle are shaking using ultrasonic wave
Dynamic effect, makes protein powder produce substantial amounts of space during processing to accommodate more water repellents, and make swelling
Protein powder is in loose state, in addition, using cavitation effect caused by ultrasonic wave, by water repellent under HI high impact effect
Push deeper region to, so that protein powder more adsorbs water repellent more quickly, increase protein powder and water repellent
Reaction chance.Protein powder after being ultrasonically treated has adsorbed substantial amounts of water repellent, and some water repellent is super
Reacted under the energy booster action of sound wave on protein powder.Protein powder is handled in water repellent treatment fluid
When, the regulation of ultrasonic power should be with mutually coordinated consistent, the ultrasonic power that is ultrasonically treated the parameters such as temperature, sonication treatment time
Height, then treatment temperature and processing time can correspondingly reduce.The treatment fluid containing protein powder after will be sonicated
Filtered, then will filter the obtained protein powder for having adsorbed water repellent dry 25 under 30~40 DEG C of lower temperature~
30min, it is uniform and stable in favor of subsequent heat treatment effect.Then by the protein powder after drying in 100~110 DEG C of temperature
15~20min of lower heat treatment, turns into water repellent protein powder.The purpose of heat treatment is in the presence of heat energy, is made by ultrasound
Absorption unreacted water repellent on protein powder further reacts after processing, is formed and had in protein powder surface
There is the film of low-surface-energy, to assign the water repellency of protein powder.
B. the preparation of mill base
Under the conditions of 200~300r/min mixing speeds and 6~10min mixings time, to the water repellent after water repellent is handled
In protein powder, be separately added into quality be the distilled water of 6~10 times of water repellent protein powder, 2~3 times of absolute ethyl alcohol, 3~
5 times of adhesive UDT premixs are combined, then in 400~600r/min mixing speeds and 80~100min mixing time bars
Being stirred under part, preparation turns into water repellent protein powder somaplasm, then 5 are added by the mass percent of water repellent protein powder somaplasm~
15% coating and 1~2.5% sodium alginate, in 600~800r/min mixing speeds and 100~120min mixing time bars
Stirred under part, preparation turns into mill base.
When preparing print paste, the relatively low mixing speed for starting to size mixing is 200~300r/min, and this is primarily to anti-
Only in charging raw material splashing, one side stirring at low speed in 6~10min feeds on one side, in order to avoid water repellent protein powder is adding
Form particle during material, influence to disperse.It is water repellent that quality is separately added into the water repellent protein powder after water repellent is handled
The distilled water that 6~10 times of protein powder, 2~3 times of absolute ethyl alcohol, 3~5 times of adhesive UDT premixs are combined.Due to
The mixing speed low time is short, and these raw materials are simply simply pre-mixed, and are not disperseed sufficiently uniformly also.Distilled water
Effect is to make water repellent protein powder that sufficiently swelling occur and be dispersed therein, because protein powder have passed through at water repellent
Reason, its surface energy is relatively low, and the effect for relying solely on distilled water is difficult to fully be swelled in a short time, it is necessary to by means of the auxiliary of ethanol
Help effect.Ethanol is the organic molecule thing for having strong permeance property, can accelerate swelling of the water repellent protein powder in water,
The aggregation extent of water repellent protein powder is reduced, is advantageous to the scattered of powder.Ethanol can also promote the stamp being printed on fabric
The rapid osmotic of mill base in the fibre, can improve stamp tinctorial yield and colour vividness, when PRINTED FABRIC bakes admittedly follow-up
During color, ethanol and can is volatilized away from fabric, does not interfere with the performance of PRINTED FABRIC.Absolute ethyl alcohol dosage should be suitable, ratio
It is too high, dilute mill base can be rushed, reduces relative amount of the water repellent protein powder in print paste, and needs to increase thickener
Dosage, the feel of PRINTED FABRIC can be impacted.Adhesive UDT is acrylic coating printing adhesive, on fiber
Good film-forming property.The additional proportion of adhesive should be controlled, binder dosage is too low, then film forming is poor, it is difficult to by water repellent protein
Powder is strapped on fabric well, reduces the crock fastness of PRINTED FABRIC；If binder dosage is too high, cover layer becomes
Thickness, water repellent protein powder are covered by thicker macromolecule membrane layer, the water repellent protein powder being so printed on fabric
Body is difficult to its waterproofing function.Then by the slurries after premixing in 400~600r/min mixing speeds and 80~100min
Stirred under the conditions of mixing time, preparation turns into water repellent protein powder somaplasm.Mixing speed is now improved, in larger stirring
Slurries is quickly moved under shearing force, make raw material is well mixed to turn into water repellent protein powder after prolonged stirring
Slurry.Mixing speed is unsuitable too low, and shearing force otherwise may be made insufficient, cause water repellent protein powder to stir not open, in addition
Prevent in quick stirring, powder slurry splashing blow tank, meanwhile, mixing time can not be too short, otherwise water repellent protein powder
Slurry is difficult to stir in a short time.Coating and 1 by quality for water repellent protein powder somaplasm mass percent 5~15% again
~2.5% sodium alginate is added in the water repellent protein powder somaplasm of preparation.It is available when preparing paint-printing colour size
Coating type has one kind in azo coating or phthalocyanines coating, and its dosage will consider that printing color, fastness of fabric etc. asks
Topic.The sodium alginate added in print paste formula is printing thickening agent, and sodium alginate is a kind of natural macromolecule amylose, tool
There is good thickening effect, the viscosity of mill base can be improved, prevent mill base imbibition, assign mill base rheological characteristic and bin stability,
Can make bright-colored printing pattern, sharpness of border, color it is uniform.According to the formula of print paste composition and material rate, add
Sodium alginate quality be advisable with 1~2.5% mass percent to water repellent protein powder somaplasm, sodium alginate dosage is too low,
Then color paste viscosity is small, and imbibition is serious, and printing obscure boundary is clear；When dosage is too high, print paste viscosity is too big, and mill base scrapes tired
Difficulty, and the feel of PRINTED FABRIC can be had an impact.To water repellent protein powder somaplasm, coating and sodium alginate in 600~800r/
Stirred under the conditions of min mixing speeds and 100~120min mixings time, preparation turns into print paste.It must assure that stirring
So as to stir, otherwise the sodium alginate macromolecular in print paste may unfold not exclusively, increase for speed and mixing time
Thick effect is deteriorated, and too fast mixing speed, can also print paste is splashed.
Specific embodiment
Embodiment one
As stated above, by the silk powder that 100g particle diameters are 10 μm, 2L is placed in by absolute ethyl alcohol and distilled water by volume
Than for 2:What 8 ratio was prepared contains 20g water repellent FK-518, and in the treatment fluid for being 5 through vinegar acid for adjusting pH value, at 1200 watts
Ultrasonic power, be ultrasonically treated 40min at a temperature of 60 DEG C, the treatment fluid containing silk powder after supersound process is carried out
Filter, obtain sonicated silk powder, then obtained sonicated silk powder is dried at a temperature of 30 DEG C
Dry 30min, is then heat-treated 20min at a temperature of 100 DEG C by the silk powder after drying, turns into water repellent silk powder.
Under the conditions of 200r/min mixing speeds and 10min mixings time, it is separately added into the water repellent silk powder after water repellent is handled
600g distilled water, 300g absolute ethyl alcohol, 500g adhesive UDT premixs are combined, and then stir speed in 400r/min
Being stirred under the conditions of degree and 100min mixings time, preparation turns into water repellent silk powder slurry, then into water repellent silk powder slurry
The 75g bright red FFG and 15g of azo coating 8111 sodium alginate is added, is stirred in 600r/min mixing speeds and 120min
Stirred under time conditions, preparation turns into mill base.
Embodiment two
As stated above, by the wool powder that 100g particle diameters are 20 μm, 5L is placed in by absolute ethyl alcohol and distilled water by volume
Than for 4:What 6 ratio was prepared contains 250g water repellent FK-518, and in the treatment fluid for being 6 through vinegar acid for adjusting pH value, 1800
Watt ultrasonic power, be ultrasonically treated 35min at a temperature of 50 DEG C, the treatment fluid containing wool powder after supersound process is entered
Row filters, and obtains sonicated wool powder, then by obtained sonicated wool powder at a temperature of 40 DEG C
25min is dried, the wool powder after drying is then heat-treated 15min at a temperature of 110 DEG C, turns into water repellent wool powder.
Under the conditions of 300r/min mixing speeds and 6min mixings time, it is separately added into the water repellent wool powder after water repellent is handled
1000g distilled water, 200g absolute ethyl alcohol, 300g adhesive UDT premixs are combined, and then stir speed in 600r/min
Stirred under the conditions of degree and 80min mixings time, preparation turns into water repellent wool powder somaplasm, then adds into water repellent wool powder somaplasm
Enter the sodium alginate of yellow FG and 40g in 240g azo coating 8202, when 800r/min mixing speeds and 100min stir
Between under the conditions of stir, preparation turn into mill base.
Embodiment three
As stated above, by the down-powder that 100g particle diameters are 15 μm, 3.5L is placed in by absolute ethyl alcohol and distilled water by body
Product is than being 3:What 7 ratio was prepared contains 105g water repellent FK-518, and in the treatment fluid for being 5.5 through vinegar acid for adjusting pH value,
1500 watts of ultrasonic power, 37.5min is ultrasonically treated at a temperature of 55 DEG C, by the place containing down-powder after supersound process
Reason liquid is filtered, and obtains sonicated down-powder, then by obtained sonicated down-powder at 35 DEG C
At a temperature of dry 27.5min, the down-powder after drying is then heat-treated 17.5min at a temperature of 105 DEG C, turns into water repellent
Down-powder.Under the conditions of 250r/min mixing speeds and 8min mixings time, to the water repellent down-powder after water repellent is handled
In be separately added into 800g distilled water, 250g absolute ethyl alcohol, 400g adhesive UDT premix be combined, then in 500r/
Stirred under the conditions of min mixing speeds and 90min mixings time, preparing, which turns into water repellent down-powder, starches, then to water repellent eider down
The 155g pink F3R and 27.125g of azo coating 6301 sodium alginate is added in powder slurry, in 700r/min mixing speeds
Stirred with the conditions of 110min mixings time, preparation turns into mill base.
Example IV
As stated above, by the silk powder that 100g particle diameters are 10 μm, 2L is placed in by absolute ethyl alcohol and distilled water by volume
Than for 2:What 8 ratio was prepared contains 20g water repellent FK-518, and in the treatment fluid for being 5 through vinegar acid for adjusting pH value, at 1200 watts
Ultrasonic power, be ultrasonically treated 40min at a temperature of 60 DEG C, the treatment fluid containing silk powder after supersound process is carried out
Filter, obtain sonicated silk powder, then obtained sonicated silk powder is dried at a temperature of 30 DEG C
Dry 30min, is then heat-treated 20min at a temperature of 100 DEG C by the silk powder after drying, turns into water repellent silk powder.
Under the conditions of 200r/min mixing speeds and 10min mixings time, it is separately added into the water repellent silk powder after water repellent is handled
600g distilled water, 300g absolute ethyl alcohol, 500g adhesive UDT premixs are combined, and then stir speed in 400r/min
Being stirred under the conditions of degree and 100min mixings time, preparation turns into water repellent silk powder slurry, then into water repellent silk powder slurry
The 75g green FB and 15g of phthalocyanines coating 8601 sodium alginate is added, in 600r/min mixing speeds and 120min mixings time
Under the conditions of stir, preparation turn into mill base.
Embodiment five
As stated above, by the wool powder that 100g particle diameters are 20 μm, 5L is placed in by absolute ethyl alcohol and distilled water by volume
Than for 4:What 6 ratio was prepared contains 250g water repellent FK-518, and in the treatment fluid for being 6 through vinegar acid for adjusting pH value, 1800
Watt ultrasonic power, be ultrasonically treated 35min at a temperature of 50 DEG C, the treatment fluid containing wool powder after supersound process is entered
Row filters, and obtains sonicated wool powder, then by obtained sonicated wool powder at a temperature of 40 DEG C
25min is dried, the wool powder after drying is then heat-treated 15min at a temperature of 110 DEG C, turns into water repellent wool powder.
Under the conditions of 300r/min mixing speeds and 6min mixings time, it is separately added into the water repellent wool powder after water repellent is handled
1000g distilled water, 200g absolute ethyl alcohol, 300g adhesive UDT premixs are combined, and then stir speed in 600r/min
Stirred under the conditions of degree and 80min mixings time, preparation turns into water repellent wool powder somaplasm, then adds into water repellent wool powder somaplasm
Enter the 240g blue FFG and 40g of phthalocyanines coating 8301 sodium alginate, in 800r/min mixing speeds and 100min mixings time
Under the conditions of stir, preparation turn into mill base.
Embodiment six
As stated above, by the down-powder that 100g particle diameters are 15 μm, 3.5L is placed in by absolute ethyl alcohol and distilled water by body
Product is than being 3:What 7 ratio was prepared contains 105g water repellent FK-518, and in the treatment fluid for being 5.5 through vinegar acid for adjusting pH value,
1500 watts of ultrasonic power, 37.5min is ultrasonically treated at a temperature of 55 DEG C, by the place containing down-powder after supersound process
Reason liquid is filtered, and obtains sonicated down-powder, then by obtained sonicated down-powder at 35 DEG C
At a temperature of dry 27.5min, the down-powder after drying is then heat-treated 17.5min at a temperature of 105 DEG C, turns into water repellent
Down-powder.Under the conditions of 250r/min mixing speeds and 8min mixings time, to the water repellent down-powder after water repellent is handled
In be separately added into 800g distilled water, 250g absolute ethyl alcohol, 400g adhesive UDT premix be combined, then in 500r/
Stirred under the conditions of min mixing speeds and 90min mixings time, preparing, which turns into water repellent down-powder, starches, then to water repellent eider down
The 155g bright blue FGB and 27.125g of phthalocyanines coating 6406 sodium alginate is added in powder slurry, in 700r/min mixing speeds
Stirred with the conditions of 110min mixings time, preparation turns into mill base.
Claims (3)
- A kind of 1. color paste formulation method for improving textile coating stamp water repellency, it is characterised in that：Described mill base preparation side Method is carried out according to the following steps：A. the water repellent processing of protein powderThe protein powder that particle diameter is 10~20 μm is placed in what is mixed by absolute ethyl alcohol, distilled water and water repellent FK-518 In the treatment fluid for being 5~6 through vinegar acid for adjusting pH value, it is ultrasonically treated in supersonic generator, egg is contained after supersound process The treatment fluid of white matter powder obtains sonicated protein powder, then the sonicated albumen that will be obtained through filtering Matter powder is dried, and heat treatment, turns into water repellent protein powder, wherein, the bath raio for the treatment of fluid is 1:20~1:50, absolute ethyl alcohol with The volume ratio of distilled water is 2:8~4:6, water repellent FK-518 concentration are 10~50g/L, and ultrasonic power is 1200~1800 Watt, it is 50~60 DEG C to be ultrasonically treated temperature, and sonication treatment time is 35~40min, and drying temperature is 30~40 DEG C, drying time For 25~30min, heat treatment temperature is 100~110 DEG C, and heat treatment time is 15~20min；B. the preparation of mill baseUnder the conditions of 200~300r/min mixing speeds and 6~10min mixings time, to the water repellent albumen after water repellent is handled In matter powder, distilled water, 2~3 times of absolute ethyl alcohol, 3~5 times that quality is 6~10 times of water repellent protein powder are separately added into Adhesive UDT premix be combined, then under the conditions of 400~600r/min mixing speeds and 80~100min mixings time Stir, preparation turns into water repellent protein powder somaplasm, then adds 5~15% by the mass percent of water repellent protein powder somaplasm Coating and 1~2.5% sodium alginate, under the conditions of 600~800r/min mixing speeds and 100~120min mixings time Stir, preparation turns into mill base.
- A kind of 2. color paste formulation method for improving textile coating stamp water repellency as claimed in claim 1, it is characterised in that： Described protein powder is one kind in silk powder or wool powder or down-powder.
- A kind of 3. color paste formulation method for improving textile coating stamp water repellency as claimed in claim 1, it is characterised in that： Described coating is one kind in azo coating or phthalocyanines coating.
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Citations (8)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN101270196A (en) * | 2007-12-29 | 2008-09-24 | 武汉科技学院 | Process for preparing hygroscopic vapor transmission polyurethane membrane |
| CN101407961A (en) * | 2008-10-31 | 2009-04-15 | 汤毅 | Moisture absorption quick-drying fabric and producing method thereof |
| CN101781855A (en) * | 2010-01-08 | 2010-07-21 | 浙江理工大学 | Dyeing method of protein material |
| CN102212964A (en) * | 2010-04-09 | 2011-10-12 | 英联企业有限公司 | Preparation for application to cellulosic textile materials and textiles containing said preparation |
| CN103225215A (en) * | 2013-04-28 | 2013-07-31 | 百利合化工（中山）有限公司 | Environmental protection fire retardation type textile printing coating material and preparation method thereof |
| CN104131465A (en) * | 2014-08-14 | 2014-11-05 | 浙江辰鸿纺织品科技有限公司 | Coating and mordanting process for semi-shading window decoration |
| CN104153197A (en) * | 2014-08-14 | 2014-11-19 | 浙江辰鸿纺织品科技有限公司 | Mordanting process for half shading window decoration |
| CN105696377A (en) * | 2016-03-13 | 2016-06-22 | 耿云花 | Efficient and rapid steaming printing technology adopting reactive dyes |
-
2017
- 2017-11-17 CN CN201711142711.2A patent/CN107841890A/en active Pending
Patent Citations (8)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN101270196A (en) * | 2007-12-29 | 2008-09-24 | 武汉科技学院 | Process for preparing hygroscopic vapor transmission polyurethane membrane |
| CN101407961A (en) * | 2008-10-31 | 2009-04-15 | 汤毅 | Moisture absorption quick-drying fabric and producing method thereof |
| CN101781855A (en) * | 2010-01-08 | 2010-07-21 | 浙江理工大学 | Dyeing method of protein material |
| CN102212964A (en) * | 2010-04-09 | 2011-10-12 | 英联企业有限公司 | Preparation for application to cellulosic textile materials and textiles containing said preparation |
| CN103225215A (en) * | 2013-04-28 | 2013-07-31 | 百利合化工（中山）有限公司 | Environmental protection fire retardation type textile printing coating material and preparation method thereof |
| CN104131465A (en) * | 2014-08-14 | 2014-11-05 | 浙江辰鸿纺织品科技有限公司 | Coating and mordanting process for semi-shading window decoration |
| CN104153197A (en) * | 2014-08-14 | 2014-11-19 | 浙江辰鸿纺织品科技有限公司 | Mordanting process for half shading window decoration |
| CN105696377A (en) * | 2016-03-13 | 2016-06-22 | 耿云花 | Efficient and rapid steaming printing technology adopting reactive dyes |
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