CN108049213B - A kind of colouring method of polyamide fibre - Google Patents

A kind of colouring method of polyamide fibre Download PDF

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Publication number
CN108049213B
CN108049213B CN201810056530.6A CN201810056530A CN108049213B CN 108049213 B CN108049213 B CN 108049213B CN 201810056530 A CN201810056530 A CN 201810056530A CN 108049213 B CN108049213 B CN 108049213B
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China
Prior art keywords
fabric
drain
acid
carries out
high molecular
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Expired - Fee Related
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CN201810056530.6A
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Chinese (zh)
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CN108049213A (en
Inventor
麦沛明
叶福成
马俊岭
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Fujian Longyan Xique Textile Co ltd
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Xinxing Textile (shenzhen) Co Ltd
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    • DTEXTILES; PAPER
    • D06TREATMENT OF TEXTILES OR THE LIKE; LAUNDERING; FLEXIBLE MATERIALS NOT OTHERWISE PROVIDED FOR
    • D06PDYEING OR PRINTING TEXTILES; DYEING LEATHER, FURS OR SOLID MACROMOLECULAR SUBSTANCES IN ANY FORM
    • D06P3/00Special processes of dyeing or printing textiles, or dyeing leather, furs, or solid macromolecular substances in any form, classified according to the material treated
    • D06P3/02Material containing basic nitrogen
    • D06P3/04Material containing basic nitrogen containing amide groups
    • D06P3/06Material containing basic nitrogen containing amide groups using acid dyes
    • DTEXTILES; PAPER
    • D06TREATMENT OF TEXTILES OR THE LIKE; LAUNDERING; FLEXIBLE MATERIALS NOT OTHERWISE PROVIDED FOR
    • D06PDYEING OR PRINTING TEXTILES; DYEING LEATHER, FURS OR SOLID MACROMOLECULAR SUBSTANCES IN ANY FORM
    • D06P1/00General processes of dyeing or printing textiles, or general processes of dyeing leather, furs, or solid macromolecular substances in any form, classified according to the dyes, pigments, or auxiliary substances employed
    • D06P1/39General processes of dyeing or printing textiles, or general processes of dyeing leather, furs, or solid macromolecular substances in any form, classified according to the dyes, pigments, or auxiliary substances employed using acid dyes
    • DTEXTILES; PAPER
    • D06TREATMENT OF TEXTILES OR THE LIKE; LAUNDERING; FLEXIBLE MATERIALS NOT OTHERWISE PROVIDED FOR
    • D06PDYEING OR PRINTING TEXTILES; DYEING LEATHER, FURS OR SOLID MACROMOLECULAR SUBSTANCES IN ANY FORM
    • D06P5/00Other features in dyeing or printing textiles, or dyeing leather, furs, or solid macromolecular substances in any form
    • D06P5/02After-treatment
    • D06P5/04After-treatment with organic compounds
    • DTEXTILES; PAPER
    • D06TREATMENT OF TEXTILES OR THE LIKE; LAUNDERING; FLEXIBLE MATERIALS NOT OTHERWISE PROVIDED FOR
    • D06PDYEING OR PRINTING TEXTILES; DYEING LEATHER, FURS OR SOLID MACROMOLECULAR SUBSTANCES IN ANY FORM
    • D06P5/00Other features in dyeing or printing textiles, or dyeing leather, furs, or solid macromolecular substances in any form
    • D06P5/02After-treatment
    • D06P5/04After-treatment with organic compounds
    • D06P5/08After-treatment with organic compounds macromolecular

Abstract

The invention belongs to textile dyeing technical fields, more particularly to a kind of colouring method of polyamide fibre, method of the invention carries out last cleaning by using high molecular polymer, so as to realize the dyeing of polyamide fibre, the colouring method process stabilizing, process is easy to control, and the fabric after dyeing is without flaws such as dyeing defect, color spots, bleed-resistant color fastness, Washing and colorfastness to rubbing are higher, and quality is preferable.

Description

A kind of colouring method of polyamide fibre
Technical field
The invention belongs to textile dyeing technical fields, and in particular to a kind of colouring method of polyamide fibre.
Background technique
Fiber is divided into chemical fibre and natural fiber, and wherein chemical fibre is with natural polymer or artificial synthesized High-molecular compound be raw material, by what is prepared made from the processes such as spinning solution, spinning and post-processing with textile performance Fiber.Have many advantages, such as it is fast light, wear-resisting, easy to wash it is easily dry, do not go rotten, be not damaged by insects.Be widely used in manufacture clothing fabric, filter cloth, Conveyer belt, rotary hose, rope, fishing net, electric insulated, medical suture, tyre cord and parachute etc..
Polyamide fibre (is commonly called as nylon), and scientific name is Fypro, belongs to one of chemical fibre, is worldwide A kind of synthetic fibers.Compared with terylene, acrylic fibers, polyamide fibre has the advantages that solid wear-resisting, density is small, and fabric is light, thus is disappeared Expense person's is widely recognized as.But due to fiber self structure problem, equalization, colour rendering, the depth of continuous synthetic fibre are poor, dyeing jail Spend it is low, therefore, in order to improve the color fastness of nylon fabric, generally use to dyed fabric carry out zwitterion dual fixation, Increase the method for washing dynamics simultaneously.This method not only makes dyeing and finishing manufacturing procedure become tediously long, considerably increases production cost, and And the fabric feeling after cationic fixation is hardened, and is not easy to return something for repairs, and the medicament of different ions can also pollute dyeing installation increasing Oil (gas) filling device cleaning frequency.
For example, Chinese patent application 201610504349.8 discloses a kind of dyeing for improving polyamide fibre color fastness, packet Washing-fixation-shaping process after pre-treatment-dyeing-dye is included, the laking procedure carries out in rinsing machine: (1) first segment 45 DEG C of -65 DEG C of clear water of sink reinforce washing;It is anti-to sequentially add glacial acetic acid, fixation spot for (2) second -90 DEG C of warm water of 80 DEG C of water-saving groove Only agent and color fixing agent carry out fixation;(3) 45 DEG C of -65 DEG C of clear water washings of third water-saving groove.The laking procedure of the dyeing is in water It is carried out in washing machine, avoids the process of water inlet and draining repeatedly, saved energy consumption to a certain extent, for improving the color of polyamide fibre Fastness is still to be realized by addition color fixing agent, and have additional water-washing step, avoids to form fixation spot, but the color of polyamide fibre is firm Degree is not significantly increased.
Chinese patent application 201610540247.1 discloses a kind of terylene/the CDP fabrics/chinlon/spandex fabric Colouring method has follow steps: (1) fabric being immersed in the first dye liquor containing refining emulsifier and disperse dyes, acid adding PH is adjusted, then in 120 DEG C~135 DEG C of at a temperature of processing 20min~60min, then is cooled to 60 DEG C or less drains;(2) will By step (1), treated that fabric successively carries out that hot water wash, reduction cleaning and acid neutralize;(3) it will be handled by step (2) Fabric afterwards is immersed in the second dye liquor containing the dye of positive ion and is handled;It (4) will be by step (3) treated fabric leaching It is handled in the third dye liquor containing acid dyes;(5) will by step (4) treated, fabric carries out room temperature washing, Acid fixation is carried out after drain again.The colouring method of the fabric is more conventional, mainly by disperse dyes, the dye of positive ion and The cooperation of acid dyes and dye liquor pH value and temperature, to realize dyeing, the chemical substance during this method is more, and all needs It is separately configured, higher to the measuring requirement of chemical component, realization is complex, and does not effectively improve color fastness.
Summary of the invention
In order to solve the above technical problems, applicant provides a kind of new nylon dyeing method by research, this method is steady It is fixed it is easy to control, dyeing effect is preferable, this method will can not do the bleeding color fastness of double nylon dyeing fabrics handled admittedly from 2 grades 4-5 grades are promoted to, and shortens dyeing process process, items brought by cationic fixation is avoided to adversely affect, saving is produced into This.
What the present invention was achieved through the following technical solutions:
A kind of nylon fabric colouring method, has follow steps:
(1) fabric is immersed in the first dye liquor containing acidity dye leveller ER and acid dyes Lanaset Blue PA, on the rocks Vinegar acid for adjusting pH be 4.0~5.0, then 98 DEG C~110 DEG C at a temperature of handle 20min~40min, then be cooled to 60 DEG C with Lower drain;
It (2) will the drain after step (1) treated fabric carries out 40 DEG C~60 DEG C of the 10min~20min that soaps;
(3) will by step (2) treated, fabric first carries out room temperature water washes, after drain, with acid at 60 DEG C~80 DEG C Property color fixing agent fixation 15min~30min;
(4) it will be immersed in 35 DEG C~45 DEG C of the hot water containing high molecular polymer CCX by the fabric of step (3) processing 15min~25min is washed, after drain, room temperature washing.
First dye liquor described in step (1) is every liter containing 1.0g~2.0g acidity dye leveller and 0.05g~3.0g acid The aqueous solution of property dyestuff;And the total weight of acid dyes is the 0.05%~3.0% of fabric weight.
It is soaped described in step (2) using every liter of aqueous solution containing 0.5~2.0g acrylic copolymer;It is described Acrylic copolymer be 2- acrylic acid and 2,5- furasndione sodium polymer.
Acidic color fixing agent described in step (3) is every liter of aqueous solution containing 0.5g~1.5g acidic color fixing agent.It is described Acidic color fixing agent be aromatic sulfonate in any one.
The total weight of step (4) described high molecular polymer is the 2%~4% of fabric weight.
High molecular polymer described in step (4) refers to the mixture of polymeric fatty alcohol ether derivant.
Compared with the prior art, the present invention has the following advantages and good effect: method of the invention is by using macromolecule Polymer carries out last cleaning, and so as to realize the dyeing of polyamide fibre, the colouring method process stabilizing, process is easy to control, dye For fabric after color without flaws such as dyeing defect, color spots, bleed-resistant color fastness, Washing and colorfastness to rubbing are higher, quality compared with It is good.
Specific embodiment
Acidity dye leveller of the present invention is purchased from the acid dye leveller HT- of Jiangsu De Wang chemical engineering industry Co., Ltd production 33N, main component are alkyl alcohol ethoxylates;The acid dyes is produced purchased from Jiangsu De Wang chemical engineering industry Co., Ltd SunacidOrangeGSN;The acidic color fixing agent is purchased from the HT-GL acidity fixation of Hetai Chemical Co., Ltd., Suzhou's production Agent, main component are syntannin acid derivative.
Test example:
Test method: content of formaldehyde test: GB/T2912.1-2912.2-1998, when content of formaldehyde < 20ppm thinks not examine Out;Acid resistance test: GB/T5555-2003;Soaping fastness test: GB/T3921-1997;Water test: GB/T5713- 1997;Bleed-resistant color fastness test: big ball method;Crock fastness test: GB/T3920-1997;Perspiration fastness test: AATCC- 15-1995;Chromatism test: it is tested with ColorEye7000A.
Experimental result indicates as follows:
1 the performance test results of table
After the present invention is used for nylon fabric as can be seen from the above table, the free formaldehyde content that cloth cover is discharged all is not detected, It may be considered environmental-friendly green chemical products.Product of the present invention colour fixation includes soaping fastness, water, resistance to infiltration Color color fastness, crock fastness and color difference etc. are better than comparative example, and have excellent acid-resistant stability.
Prepare embodiment
Embodiment 1
1. by 500kg silk floss synthetic fibre fabric be immersed in every liter containing 1.0gHT-33N and 0.05g SunacidOrange GSN it is (described The total weight of acid dyes be fabric weight 0.05%) the first dye liquor in, add 1M salt acid for adjusting pH be 4.0, then 98 40min is handled at a temperature of DEG C, then is cooled to 60 DEG C or less drains;
2. by the drain after step 1. treated fabric carries out 40 DEG C of the 20min that soaps;
3. will by step, 2. treated that fabric first carries out room temperature water washes, after drain, then carry out 60 DEG C of acid fixation 30min;
4. the fabric 3. handled by step is immersed in 35 DEG C of the hot water containing high molecular polymer and washes 25min, After drain, room temperature washing.
Embodiment 2
1. by 500kg silk floss synthetic fibre fabric be immersed in every liter containing 2.0gHT-33N and 3.0g Sunacid OrangeGSN it is (described The total weight of acid dyes be fabric weight 0.5%) the first dye liquor in, add 2M hydrochloric acid agent adjust pH be 4.5, then 98 30min is handled at a temperature of DEG C, then is cooled to 60 DEG C or less drains;
2. by the drain after step 1. treated fabric carries out 40 DEG C of the 15min that soaps;
3. will by step, 2. treated that fabric first carries out room temperature water washes, after drain, then carry out 65 DEG C of acid fixation 15min;
It is washed 4. immersing the fabric 3. handled by step in 35 DEG C of the hot water containing special high molecular polymer 25min, after drain, room temperature washing.
Embodiment 3
1. 500kg silk floss synthetic fibre fabric, which is immersed in every liter, contains 1.8g HT-33N and 2.05g SunacidOrange GSN (institute State acid dyes total weight be fabric weight 1.5%) the first dye liquor in, add 1.5M hydrochloric acid agent adjust pH be 4.8, then 100 DEG C at a temperature of handle 30min, then be cooled to 60 DEG C or less drains;
2. by the drain after step 1. treated fabric carries out 50 DEG C of the 18min that soaps;
3. will by step, 2. treated that fabric first carries out room temperature water washes, after drain, then carry out 75 DEG C of acid fixation 20min;
It is washed 4. immersing the fabric 3. handled by step in 42 DEG C of the hot water containing special high molecular polymer 18min, after drain, room temperature washing.
Embodiment 4
1. 500kg silk floss synthetic fibre fabric, which is immersed in every liter, contains 1.5g HT-33N and 1.05g SunacidOrange GSN (institute State acid dyes total weight be fabric weight 2.85%) the first dye liquor in, add 0.8M hydrochloric acid agent adjust pH be 4.3, so Afterwards 106 DEG C at a temperature of handle 37min, then be cooled to 60 DEG C or less drains;
2. by the drain after step 1. treated fabric carries out 48 DEG C of the 16min that soaps;
3. will by step, 2. treated that fabric first carries out room temperature water washes, after drain, then carry out 70 DEG C of acid fixation 20min;
It is washed 4. immersing the fabric 3. handled by step in 45 DEG C of the hot water containing special high molecular polymer 25min, after drain, room temperature washing.
Embodiment 5
1. by 500kg silk floss synthetic fibre fabric be immersed in every liter containing 1.6g HT-33N and 2.8g SunacidOrange GSN it is (described The total weight of acid dyes be fabric weight 3.0%) the first dye liquor in, add 1M hydrochloric acid agent adjust pH be 5.0, then exist 20min is handled at a temperature of 110 DEG C, then is cooled to 60 DEG C or less drains;
2. by the drain after step 1. treated fabric carries out 60 DEG C of the 10min that soaps;
3. will by step, 2. treated that fabric first carries out room temperature water washes, after drain, then carry out 60 DEG C of acid fixation 30min;
It is washed 4. immersing the fabric 3. handled by step in 45 DEG C of the hot water containing special high molecular polymer 15min, after drain, room temperature washing.
Comparative example
1. by 500kg silk floss synthetic fibre fabric be immersed in every liter containing 1.0gHT-33N and 0.05g SunacidOrange GSN it is (described The total weight of acid dyes be fabric weight 0.05%) the first dye liquor in, add 1M salt acid for adjusting pH be 4.0, then 98 40min is handled at a temperature of DEG C, then is cooled to 60 DEG C or less drains;
2. by the drain after step 1. treated fabric carries out 40 DEG C of the 20min that soaps;
3. will by step, 2. treated that fabric first carries out room temperature water washes, after drain, then carry out 60 DEG C of acid fixation 30min;
4. the fabric 3. handled by step is immersed in 35 DEG C of hot water and washes 25min, after drain, room temperature washing.
Above by the description of specific embodiment, the invention will be further described, but it is to limit of the invention that this, which is not, System, those skilled in the art's basic thought according to the present invention can make various modifications or improvements, but without departing from this The basic thought of invention, is all within the scope of the present invention.

Claims (1)

1. a kind of nylon fabric colouring method, it is characterised in that this method are as follows:
(1) 500kg nylon fabric is immersed in every liter of containing 1.5g HT-33N and 1.05g Sunacid Orange GSN In one dye liquor, add 0.8M hydrochloric acid agent adjust pH be 4.3, then 106 DEG C at a temperature of handle 37min, then be cooled to 60 DEG C with Lower drain;
It (2) will the drain after step (1) treated fabric carries out 48 DEG C of the 16min that soaps;It is described soap using Every liter of aqueous solution containing 0.5~2.0g acrylic copolymer, wherein acrylic copolymer is 2- acrylic acid and 2,5- furans two The polymer of ketone sodium;
(3) will by step (2) treated, fabric first carries out room temperature water washes, after drain, then carry out 70 DEG C of acid fixation 20min;The acidic color fixing agent is every liter of aqueous solution containing 0.5g~1.5g acidic color fixing agent;The acidic color fixing agent For any one in aromatic sulfonate;
(4) it will immerse in 45 DEG C of the hot water containing special high molecular polymer and wash by the fabric of step (3) processing 25min, after drain, room temperature washing;The total weight of high molecular polymer is the 2%~4% of fabric weight;The polyphosphazene polymer Close the mixture that object refers to polymeric fatty alcohol ether derivant: high molecular polymer CCX.
CN201810056530.6A 2018-01-21 2018-01-21 A kind of colouring method of polyamide fibre Expired - Fee Related CN108049213B (en)

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CN108914654A (en) * 2018-07-25 2018-11-30 安徽新生纺织有限公司 It is a kind of suitable for polyamide fibre, the colouring method of aramid fiber blended textile
CN109610205A (en) * 2018-11-28 2019-04-12 广州市番禺区协运来化工用品有限公司 A kind of acidic color fixing agent and preparation method thereof
CN109695164A (en) * 2018-12-07 2019-04-30 浙江名毅新能源股份有限公司 A kind of high fastness acid dyeing technique
CN111778739A (en) * 2020-01-02 2020-10-16 军事科学院系统工程研究院军需工程技术研究所 Acid low-temperature dip dyeing method for chinlon 56 fiber and fabric
CN113463411B (en) * 2020-03-31 2023-02-03 鲁泰纺织股份有限公司 On-line dyeing process for nylon fancy yarn
CN114214849A (en) * 2021-11-01 2022-03-22 江苏阳光股份有限公司 Preparation method of functional environment-friendly worsted fabric and worsted fabric
CN114855476A (en) * 2022-06-06 2022-08-05 华纺股份有限公司 Method for dyeing nylon-cotton blended fabric

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JPS5696976A (en) * 1979-12-28 1981-08-05 Toray Industries White resist and discharge style method
CN103422237A (en) * 2012-05-25 2013-12-04 常州老三集团有限公司 Fabric and dyeing and finishing process thereof
CN106638047A (en) * 2016-12-28 2017-05-10 朱爱民 Dyeing technology of chinlon
CN106757891A (en) * 2017-01-22 2017-05-31 晋江沙禾布业有限公司 The continuous dyeing system and its continuous dyeing method of a kind of nylon fabric

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Effective date of registration: 20220801

Address after: 364002 No. 233, Longyan Avenue, Xinlu village, Yanshi Town, Xinluo District, Longyan City, Fujian Province

Patentee after: FUJIAN LONGYAN XIQUE TEXTILE Co.,Ltd.

Address before: 518106 Gongming Office of Guangming New District, Shenzhen, Guangdong, sixth to nineteenth buildings in Xintian Pu new industrial district.

Patentee before: SUN HING TEXTILE (SHENZHEN) CO.,LTD.

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Granted publication date: 20190827