CN108031283A - A kind of room air eliminating smell agent and preparation method thereof - Google Patents

A kind of room air eliminating smell agent and preparation method thereof Download PDF

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Publication number
CN108031283A
CN108031283A CN201711409797.0A CN201711409797A CN108031283A CN 108031283 A CN108031283 A CN 108031283A CN 201711409797 A CN201711409797 A CN 201711409797A CN 108031283 A CN108031283 A CN 108031283A
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CN
China
Prior art keywords
parts
eliminating smell
smell agent
room air
citric acid
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Pending
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CN201711409797.0A
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Chinese (zh)
Inventor
何康德
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Individual
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Individual
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Priority to CN201711409797.0A priority Critical patent/CN108031283A/en
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Classifications

    • BPERFORMING OPERATIONS; TRANSPORTING
    • B01PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01DSEPARATION
    • B01D53/00Separation of gases or vapours; Recovering vapours of volatile solvents from gases; Chemical or biological purification of waste gases, e.g. engine exhaust gases, smoke, fumes, flue gases, aerosols
    • B01D53/34Chemical or biological purification of waste gases
    • B01D53/74General processes for purification of waste gases; Apparatus or devices specially adapted therefor
    • B01D53/86Catalytic processes
    • B01D53/8603Removing sulfur compounds
    • B01D53/8612Hydrogen sulfide
    • AHUMAN NECESSITIES
    • A01AGRICULTURE; FORESTRY; ANIMAL HUSBANDRY; HUNTING; TRAPPING; FISHING
    • A01NPRESERVATION OF BODIES OF HUMANS OR ANIMALS OR PLANTS OR PARTS THEREOF; BIOCIDES, e.g. AS DISINFECTANTS, AS PESTICIDES OR AS HERBICIDES; PEST REPELLANTS OR ATTRACTANTS; PLANT GROWTH REGULATORS
    • A01N59/00Biocides, pest repellants or attractants, or plant growth regulators containing elements or inorganic compounds
    • AHUMAN NECESSITIES
    • A01AGRICULTURE; FORESTRY; ANIMAL HUSBANDRY; HUNTING; TRAPPING; FISHING
    • A01NPRESERVATION OF BODIES OF HUMANS OR ANIMALS OR PLANTS OR PARTS THEREOF; BIOCIDES, e.g. AS DISINFECTANTS, AS PESTICIDES OR AS HERBICIDES; PEST REPELLANTS OR ATTRACTANTS; PLANT GROWTH REGULATORS
    • A01N59/00Biocides, pest repellants or attractants, or plant growth regulators containing elements or inorganic compounds
    • A01N59/16Heavy metals; Compounds thereof
    • BPERFORMING OPERATIONS; TRANSPORTING
    • B01PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01DSEPARATION
    • B01D53/00Separation of gases or vapours; Recovering vapours of volatile solvents from gases; Chemical or biological purification of waste gases, e.g. engine exhaust gases, smoke, fumes, flue gases, aerosols
    • B01D53/34Chemical or biological purification of waste gases
    • B01D53/74General processes for purification of waste gases; Apparatus or devices specially adapted therefor
    • B01D53/86Catalytic processes
    • B01D53/8668Removing organic compounds not provided for in B01D53/8603 - B01D53/8665
    • BPERFORMING OPERATIONS; TRANSPORTING
    • B01PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01DSEPARATION
    • B01D2255/00Catalysts
    • B01D2255/20Metals or compounds thereof
    • B01D2255/207Transition metals
    • B01D2255/20707Titanium
    • BPERFORMING OPERATIONS; TRANSPORTING
    • B01PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01DSEPARATION
    • B01D2255/00Catalysts
    • B01D2255/80Type of catalytic reaction
    • B01D2255/802Photocatalytic
    • BPERFORMING OPERATIONS; TRANSPORTING
    • B01PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01DSEPARATION
    • B01D2257/00Components to be removed
    • B01D2257/90Odorous compounds not provided for in groups B01D2257/00 - B01D2257/708
    • BPERFORMING OPERATIONS; TRANSPORTING
    • B01PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01DSEPARATION
    • B01D2257/00Components to be removed
    • B01D2257/91Bacteria; Microorganisms
    • BPERFORMING OPERATIONS; TRANSPORTING
    • B01PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01DSEPARATION
    • B01D2258/00Sources of waste gases
    • B01D2258/06Polluted air

Abstract

The present patent application discloses a kind of room air eliminating smell agent and preparation method thereof, is made of the material of following parts by weight:0.1 ~ 0.3 part of amino functional graphene oxide, 2 ~ 4 parts of SODIUM PERCARBONATE, 3 ~ 5 parts of citric acid, 6 ~ 8 parts of nano-titanium dioxide, 70 ~ 90 parts of deionized water.The present patent application also discloses the preparation method of room air eliminating smell agent, and a small amount of sprinkling, which can form a film, plays the effect of eliminating smell agent, easy to use without smearing.

Description

A kind of room air eliminating smell agent and preparation method thereof
Technical field
The present invention relates to indoor air purification field, and in particular to a kind of room air eliminating smell agent and preparation method thereof.
Background technology
As the improvement of people's living standards, the finishing degree in room is increasingly severe, and many finishing materials are easily released The pernicious gases such as formaldehyde, aromatic hydrocarbon, alcohol, ester are released into air, the health of harmful to human.Supplied in summer using air-conditioning, winter Between warm period, room compares closing, atmosphere draught-free, the pernicious gas of finishing material release, body metabolism product, flue gas, culinary art Indoors, higher concentration, can aggravate the infringement to health for the aggregations such as oil smoke, sewer peculiar smell.Therefore, it is necessary to interior Air is purified.
At present, the method for the treatment of air indoor has a variety of, such as sprays photocatalyst, eliminating smell agent, formaldehyde lyase. 201510008433.6 disclosing a kind of fitting up deodouring agent, mainly include nano-titanium dioxide and magnesium silicate, further include citric acid And sodium chloride, when in use, need and water is mixed into weak yellow liquid, be then sprayed on the surface of interior decoration thing, this needs is adopted Carried out with professional equipment, by professional to operate, it is inconvenient to use.201410215832.5 disclose a kind of multi-functional air Wax and preparation method thereof is purified, which includes glazing agent, emulsifying agent, eliminating smell agent, nano oxidized metal, solvent, nano-tourmaline Powder, the invention need to be applied to the surfaces such as furniture, leather, floor when in use, form a tunic, smearing is time-consuming and laborious, expired It is difficult to replace after invalid.Thus, currently without easy to use, the eliminating smell agent of long-acting holding.
The content of the invention
The technical problems to be solved by the invention are the defects of overcoming the above prior art, there is provided a kind of room air removes Taste agent and preparation method thereof, being capable of easy to use, long-acting holding.
The technical solution of the present invention is as follows:A kind of room air eliminating smell agent, is made of the material of following parts by weight: 0.1 ~ 0.5 part of amino functional graphene oxide, 2 ~ 6 parts of SODIUM PERCARBONATE, 0.03 ~ 0.05 part of citric acid, nano-titanium dioxide 5 ~ 10 parts, 70 ~ 90 parts of deionized water.
Preferably, the room air eliminating smell agent is made of the material of following parts by weight:Amino functional graphite oxide 0. 1 ~ 0.3 part of alkene, 2 ~ 4 parts of SODIUM PERCARBONATE, 3 ~ 5 parts of citric acid, 6 ~ 8 parts of nano-titanium dioxide, 70 ~ 90 parts of deionized water.
Preferably, the amino functional graphene oxide is grapheme modified for aminopropyl triethoxysilane.Aminopropyl Triethoxysilane is grapheme modified nontoxic, and taste removal effect is more preferable.
A kind of preparation method of room air eliminating smell agent, comprises the following steps:
1) SODIUM PERCARBONATE, nano-titanium dioxide are weighed, is uniformly mixed, powder is made;
2) citric acid is dissolved, the aqueous citric acid solution of 5 ~ 15wt% is made;
3) amino functional graphene oxide is dissolved, aqueous citric acid solution is added dropwise to it, stands 2 ~ 4h, forms mixed solution;
4) powder is added into mixed solution, stirred evenly, stand 3 ~ 5h, to obtain the final product.
Amino acid functionalised graphene oxide adds on a small quantity, and graphene has two-dimension plane structure, can increase eliminating smell agent Specific surface area, there is provided harmful substance is adsorbed in the space of more biggers, and citric acid is added dropwise increases its film-formation result;Amino at the same time Middle N-H keys in functionalization graphene easily form hydrogen bond with the molecule containing S, O, N, such as cause the sulphur of bathroom odor peculiar smell Change hydrogen, methyl mercaptan, ethamine, indoles;SODIUM PERCARBONATE is nontoxic, odorless, it is possible to provide hydroxyl radical free radical, has strong oxidizing property, enhancing is killed Bacterium ability, quickly kill removing to the bacterium that is adsorbed onto in hole.Nano-titanium dioxide, can be in visible light conditions as photochemical catalyst Lower oxygenolysis pernicious gas.Exist at the same time while SODIUM PERCARBONATE, nano-titanium dioxide, since nano-titanium dioxide can be A small amount of hydroxyl radical free radical is generated under visible light conditions, this small amount of hydroxyl radical free radical can be used as SODIUM PERCARBONATE to form hydroxyl free The initiator of base, forms synergistic effect, and the foreign matter absorbed into eliminating smell agent hole can concentrate cohesion to be aoxidized, and foreign matter is dropped by oxidation Solution, peculiar smell disappear, and fundamentally eliminate the indoor foreign matter for causing peculiar smell.
The product simply sprinkling can form a film, available for bedroom, parlor, toilet or kitchen.Discharged during culinary cuisine A large amount of oil smoke, the oil smoke and dust that the adsorbable lower section of eliminating smell agent is not taken away by kitchen ventilator.The peculiar smell pernicious gas of toilet with Vapor is together adsorbed in eliminating smell agent, by hydrogen bond or loose structure, is attached at eliminating smell agent surface or is adsorbed in hole, is gathered Collect the foreign matter on eliminating smell agent, by oxidative degradation.
The beneficial effects of the invention are as follows:
1)Simple sprinkling can form a film, and play the effect of eliminating smell agent, easy to use without smearing;
2)Citric acid increases its film-formation result, reduces toxicity, contributes to the shaping of film and the degraded to foreign matter;
3)A small amount of hydroxyl radical free radical that nano-titanium dioxide can generate under visible light conditions, hydroxyl is formed as SODIUM PERCARBONATE The initiator of free radical, has strong oxidizing property, strengthens sterilizing ability;
4)Each component forms synergistic effect, and the foreign matter absorbed into eliminating smell agent hole can concentrate cohesion to be aoxidized, and foreign matter degraded is different Taste disappears, and fundamentally eliminates the indoor foreign matter for causing peculiar smell.
Embodiment
The present invention is described in further details with specific embodiment below, but the present invention is not only limited in detail below in fact Apply example.
Embodiment provided below is simultaneously not used to the scope that the limitation present invention is covered, described step nor with To limit its execution sequence.Those skilled in the art are the present invention with reference to existing common knowledge conspicuously improved, also fall Enter within the protection domain of application claims.
Embodiment one
A kind of room air eliminating smell agent, is made of the material of following parts by weight:1 part of amino functional graphene oxide, cross carbon Sour 2 parts of sodium, 0.03 part of citric acid, 5 parts of nano-titanium dioxide.
A kind of preparation method of room air eliminating smell agent, comprises the following steps:
1) SODIUM PERCARBONATE, nano-titanium dioxide are weighed, is uniformly mixed, powder is made;
2) citric acid is dissolved, the aqueous citric acid solution of 5wt% is made;
3) amino functional graphene oxide is dissolved, aqueous citric acid solution is added dropwise to it, stands 2h, forms mixed solution;
4) powder is added into mixed solution, stirred evenly, stand 3h, to obtain the final product.
Embodiment two
A kind of room air eliminating smell agent, is made of the material of following parts by weight:5 parts of amino functional graphene oxide, cross carbon Sour 6 parts of sodium, 0.05 part of citric acid, 10 parts of nano-titanium dioxide.
A kind of preparation method of room air eliminating smell agent, comprises the following steps:
1) SODIUM PERCARBONATE, nano-titanium dioxide are weighed, is uniformly mixed, powder is made;
2) citric acid is dissolved, the aqueous citric acid solution of 15wt% is made;
3) amino functional graphene oxide is dissolved, aqueous citric acid solution is added dropwise to it, stands 4h, forms mixed solution;
4) powder is added into mixed solution, stirred evenly, stand 5h, to obtain the final product.
Embodiment three
A kind of room air eliminating smell agent, is made of the material of following parts by weight:1 part of amino functional graphene oxide, cross carbon Sour 2 parts of sodium, 0.03 part of citric acid, 6 parts of nano-titanium dioxide.
A kind of preparation method of room air eliminating smell agent, comprises the following steps:
1) SODIUM PERCARBONATE, nano-titanium dioxide are weighed, is uniformly mixed, powder is made;
2) citric acid is dissolved, the aqueous citric acid solution of 8wt% is made;
3) amino functional graphene oxide is dissolved, aqueous citric acid solution is added dropwise to it, stands 2h, forms mixed solution;
4) powder is added into mixed solution, stirred evenly, stand 3h, to obtain the final product.
Example IV
A kind of room air eliminating smell agent, is made of the material of following parts by weight:3 parts of amino functional graphene oxide, cross carbon Sour 4 parts of sodium, 0.05 part of citric acid, 8 parts of nano-titanium dioxide.
A kind of preparation method of room air eliminating smell agent, comprises the following steps:
1) SODIUM PERCARBONATE, nano-titanium dioxide are weighed, is uniformly mixed, powder is made;
2) citric acid is dissolved, the aqueous citric acid solution of 12wt% is made;
3) amino functional graphene oxide is dissolved, aqueous citric acid solution is added dropwise to it, stands 4h, forms mixed solution;
4) powder is added into mixed solution, stirred evenly, stand 5h, to obtain the final product.
Embodiment five
A kind of room air eliminating smell agent, is made of the material of following parts by weight:2 parts of amino functional graphene oxide, cross carbon Sour 3 parts of sodium, 0.04 part of citric acid, 7 parts of nano-titanium dioxide.
A kind of preparation method of room air eliminating smell agent, comprises the following steps:
1) SODIUM PERCARBONATE, nano-titanium dioxide are weighed, is uniformly mixed, powder is made;
2) citric acid is dissolved, the aqueous citric acid solution of 10wt% is made;
3) amino functional graphene oxide is dissolved, aqueous citric acid solution is added dropwise to it, stands 3h, forms mixed solution;
Powder is added into mixed solution, is stirred evenly, stands 4h, to obtain the final product.

Claims (4)

1. a kind of room air eliminating smell agent, it is characterised in that be made of the material of following parts by weight:Amino functional aoxidizes stone Black alkene 0.1 ~ 0. 5 part, 2 ~ 6 parts of SODIUM PERCARBONATE, 3 ~ 5 parts of citric acid, 5 ~ 10 parts of nano-titanium dioxide, 70 ~ 90 parts of deionized water.
2. room air eliminating smell agent according to claim 1, it is characterised in that the room air eliminating smell agent is by following heavy Measure the material composition of number:0. 1 ~ 0.3 part of amino functional graphene oxide, 2 ~ 4 parts of SODIUM PERCARBONATE, 3 ~ 5 parts of citric acid, receive 6 ~ 8 parts of titanium dioxide of rice, 70 ~ 90 parts of deionized water.
3. room air eliminating smell agent according to claim 1, it is characterised in that the amino functional graphene oxide is Aminopropyl triethoxysilane is grapheme modified.
4. a kind of preparation method of the room air eliminating smell agent based on described in claim 1, it is characterised in that including following step Suddenly:
1) SODIUM PERCARBONATE, nano-titanium dioxide are weighed, is uniformly mixed, powder is made;
2) citric acid is dissolved, the aqueous citric acid solution of 5 ~ 15wt% is made;
3) amino functional graphene oxide is dissolved, aqueous citric acid solution is added dropwise to it, stands 2 ~ 4h, forms mixed solution;
Powder is added into mixed solution, is stirred evenly, stands 3 ~ 5h, to obtain the final product.
CN201711409797.0A 2017-12-23 2017-12-23 A kind of room air eliminating smell agent and preparation method thereof Pending CN108031283A (en)

Priority Applications (1)

Application Number Priority Date Filing Date Title
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Application Number Priority Date Filing Date Title
CN201711409797.0A CN108031283A (en) 2017-12-23 2017-12-23 A kind of room air eliminating smell agent and preparation method thereof

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Cited By (5)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
CN109046008A (en) * 2018-08-03 2018-12-21 上海弥如新材料科技有限公司 A kind of efficient automobile eliminates the unusual smell spray
CN109499339A (en) * 2018-12-27 2019-03-22 广州爱居环保科技有限公司 A kind of room air eliminating smell agent and preparation method thereof
CN110627668A (en) * 2018-06-22 2019-12-31 天津理工大学 Preparation method of carbon-based harmful gas scavenger
CN110801526A (en) * 2019-11-22 2020-02-18 高军利 Preparation method of deodorant
KR102208783B1 (en) * 2020-10-08 2021-01-28 애드문코퍼레이션 주식회사 Spray composition and method for preparing thereof

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Cited By (5)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
CN110627668A (en) * 2018-06-22 2019-12-31 天津理工大学 Preparation method of carbon-based harmful gas scavenger
CN109046008A (en) * 2018-08-03 2018-12-21 上海弥如新材料科技有限公司 A kind of efficient automobile eliminates the unusual smell spray
CN109499339A (en) * 2018-12-27 2019-03-22 广州爱居环保科技有限公司 A kind of room air eliminating smell agent and preparation method thereof
CN110801526A (en) * 2019-11-22 2020-02-18 高军利 Preparation method of deodorant
KR102208783B1 (en) * 2020-10-08 2021-01-28 애드문코퍼레이션 주식회사 Spray composition and method for preparing thereof

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Application publication date: 20180515