CN106362697A - Heavy metal iron adsorption material modified by aminated graphene oxide - Google Patents
Heavy metal iron adsorption material modified by aminated graphene oxide Download PDFInfo
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- CN106362697A CN106362697A CN201610989800.XA CN201610989800A CN106362697A CN 106362697 A CN106362697 A CN 106362697A CN 201610989800 A CN201610989800 A CN 201610989800A CN 106362697 A CN106362697 A CN 106362697A
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- graphene oxide
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- B—PERFORMING OPERATIONS; TRANSPORTING
- B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
- B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
- B01J20/00—Solid sorbent compositions or filter aid compositions; Sorbents for chromatography; Processes for preparing, regenerating or reactivating thereof
- B01J20/22—Solid sorbent compositions or filter aid compositions; Sorbents for chromatography; Processes for preparing, regenerating or reactivating thereof comprising organic material
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- B—PERFORMING OPERATIONS; TRANSPORTING
- B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
- B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
- B01J20/00—Solid sorbent compositions or filter aid compositions; Sorbents for chromatography; Processes for preparing, regenerating or reactivating thereof
- B01J20/02—Solid sorbent compositions or filter aid compositions; Sorbents for chromatography; Processes for preparing, regenerating or reactivating thereof comprising inorganic material
- B01J20/20—Solid sorbent compositions or filter aid compositions; Sorbents for chromatography; Processes for preparing, regenerating or reactivating thereof comprising inorganic material comprising free carbon; comprising carbon obtained by carbonising processes
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- C—CHEMISTRY; METALLURGY
- C02—TREATMENT OF WATER, WASTE WATER, SEWAGE, OR SLUDGE
- C02F—TREATMENT OF WATER, WASTE WATER, SEWAGE, OR SLUDGE
- C02F1/00—Treatment of water, waste water, or sewage
- C02F1/28—Treatment of water, waste water, or sewage by sorption
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- C—CHEMISTRY; METALLURGY
- C02—TREATMENT OF WATER, WASTE WATER, SEWAGE, OR SLUDGE
- C02F—TREATMENT OF WATER, WASTE WATER, SEWAGE, OR SLUDGE
- C02F1/00—Treatment of water, waste water, or sewage
- C02F1/28—Treatment of water, waste water, or sewage by sorption
- C02F1/283—Treatment of water, waste water, or sewage by sorption using coal, charred products, or inorganic mixtures containing them
-
- C—CHEMISTRY; METALLURGY
- C02—TREATMENT OF WATER, WASTE WATER, SEWAGE, OR SLUDGE
- C02F—TREATMENT OF WATER, WASTE WATER, SEWAGE, OR SLUDGE
- C02F2101/00—Nature of the contaminant
- C02F2101/10—Inorganic compounds
- C02F2101/20—Heavy metals or heavy metal compounds
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- Life Sciences & Earth Sciences (AREA)
- Hydrology & Water Resources (AREA)
- Engineering & Computer Science (AREA)
- Environmental & Geological Engineering (AREA)
- Water Supply & Treatment (AREA)
- Analytical Chemistry (AREA)
- Chemical Kinetics & Catalysis (AREA)
- Inorganic Chemistry (AREA)
- Solid-Sorbent Or Filter-Aiding Compositions (AREA)
- Water Treatment By Sorption (AREA)
Abstract
The invention discloses a heavy metal iron adsorption material modified by aminated graphene oxide. The material comprises activated carbon doped with 1-10 wt% of aminated graphene oxide. The aminated graphene oxide enhanced activated carbon material prepared through the method has heavy metal ion adsorption capacity far better than that of activated carbon, and the adsorption of activated carbon for heavy metal ions is enhanced.
Description
Technical field
The present invention relates to environmental technology field, the modified heavy metal ion suction of more particularly, to a kind of amination graphene oxide
Enclosure material.
Background technology
Heavy metal generally refers to more than 60 kind element or density 45 kinds of elements more than 5 more than 4 for the density, but due to
Toxicity in water and soil for the different heavy metals differs greatly, thus environmental science people be generally concerned with vanadium, chromium, cobalt,
The metal ions such as silver, copper, zinc, cadmium, stannum, hydrargyrum, lead.Heavy metal is prevalent in nature with simple substance or compound form mostly
In, too big threat will not be constituted to ecological and the mankind.But in the last few years, because the mankind are to the exhaustive exploitation of metalliferous mineral and smelting
Refining, produce in the industrial processes such as chemical industry, electronics, instrument, machine-building again contain in a large number heavy metal ion (cadmium, chromium, copper, hydrargyrum,
Nickel etc.) waste water, these are all the primary pollution source of water and Soil Environmental Pollution.Heavy metal ion can assemble in human body thus
Lead to the damage of poisoning, cancer and nervous system.
Heavy metal both can be directly entered water body, soil and air, cause environmental pollution it is also possible to water body, soil and
Shift between air, cause the indirect pollution of all kinds of environmental key-elements.Because heavy metal will not nature or biodegradation, therefore a huge sum of money
The place to go belonging to pollution is more difficult.
At present, the minimizing technology of common heavy metal ion mainly has: flocculence, the sedimentation method, membrane separation process, biological treatment
Method, ion exchange and absorption method etc..Absorption method will not produce secondary pollution in terms of administering heavy metal ions in wastewater, reaction
Efficiency high, effect is significant and equipment are simple, and therefore it is most widely used.The core of absorption method is the selection of adsorbent how
Improve the adsorption effect of adsorbent, be the technical barrier that those skilled in the art face.
Content of the invention
It is an object of the invention to proposing a kind of modified heavy metal ion adsorbing material of amination graphene oxide, can
The absorbability making adsorbent is improved.
For reaching this purpose, the present invention employs the following technical solutions:
The modified heavy metal ion adsorbing material of a kind of amination graphene oxide, comprising: doped with 1-10wt% amino
Change the activated carbon of graphene oxide.
Preferably, the doping of described amination graphene oxide is 2-6wt%.Such as 1,1.5,2,2.5,3,3.5,4,
4.5、5.5、6、6.5、7、7.5、8、8.5、9、9.5、10.
The preparation method of the modified heavy metal ion adsorbing material of described amination graphene oxide is as follows:
(1) by the crystalline flake graphite of 2-5 weight portion, the phosphoric acid mixing of the concentrated sulphuric acid of 300-500 weight portion and 30-60 weight portion
Uniformly, it is slowly added to the potassium permanganate of 15-20 weight portion, stir 9-18 hour at 45-55 DEG C;
(2) in mixture, at 0-5 DEG C, add the deionized water of 300-500 weight portion, and the 10- of 20-50 weight portion
The hydrogen peroxide of 30wt% concentration, and stir 5-10 minute;
(3) simultaneously priority deionized water, the hydrochloric acid of 10-30wt% concentration and absolute ethanol washing product are separated, vacuum is done
Dry obtain graphene oxide;
(4) described graphene oxide is scattered in the n of 15-20 weight portion, in n- dimethyl formamide solution, at 0-5 DEG C
The socl of lower addition 40-60 weight portion2, it is warming up to 65-80 DEG C after mix homogeneously, continue stirring 30-40 hour;
(5) by 1,6 hexamethylene diamines are added drop-wise in above-mentioned mixed liquor, stir 2-6 hour at 0-5 DEG C;
(6) add activated carbon, stir 30-180min, filter, obtain solid particle;
(7) by described solid particle under noble gases or nitrogen are protected, it is heated to 450-600 DEG C, is incubated 40-
120min, obtains the enhanced absorbent charcoal material of amination graphene oxide.
The adsorbing material that the present invention obtains substantially increases the adsorption capacity of activated carbon so that the absorption of described adsorbing material
Capacity is more than 149.8mg/g, the significantly larger than 114mg/g of activated carbon.
Specific embodiment
To further illustrate technical scheme below by specific embodiment.
Embodiment 1
Methods described according to the present invention prepares the enhanced active carbon adsorption material of amination graphene oxide, concrete steps
For:
(1) by the crystalline flake graphite of 2 weight portions, the phosphoric acid mix homogeneously of the concentrated sulphuric acid of 300 weight portions and 30 weight portions, slowly
Add the potassium permanganate of 15 weight portions, stir 9 hours at 45 DEG C;
(2) in mixture, at 0 DEG C, add the deionized water of 300 weight portions, and the 10wt% concentration of 20 weight portions
Hydrogen peroxide, and stir 5 minutes;
(3) separate simultaneously priority deionized water, the hydrochloric acid of 10wt% concentration and absolute ethanol washing product, be vacuum dried
To graphene oxide;
(4) described graphene oxide is scattered in the n of 15 weight portions, in n- dimethyl formamide solution, adds at 0 DEG C
The socl of 40 weight portions2, it is warming up to 65 DEG C after mix homogeneously, continue stirring 30 hours;
(5) by 1,6 hexamethylene diamines are added drop-wise in above-mentioned mixed liquor, stir 2 hours at 0 DEG C;
(6) add activated carbon, stir 30min, filter, obtain solid particle;
(7) by described solid particle under noble gases or nitrogen are protected, it is heated to 450 DEG C, is incubated 40min, obtains ammonia
The enhanced absorbent charcoal material of base graphene oxide.
In described absorbent charcoal material, the content of amination graphene oxide is 6%.
Carry out absorption test, the adsorbing material that embodiment 1 prepares with chromium ion, its adsorption capacity is more than 149.8mg/
g.
Comparative example 1
Amination graphene oxide in embodiment 1 is replaced with graphene oxide, remaining composition keeps constant, its absorption
Ability is 96mg/g.
Comparative example 2
Amination graphene oxide in embodiment 1 is replaced with Graphene, remaining composition keeps constant, its absorbability
For 74mg/g.
Comparative example 3
Amination graphene oxide in embodiment 1 is replaced with CNT, remaining composition keeps constant, its energy of adsorption
Power is 92mg/g;
Comparative example 4
All adopt activated carbon, its absorbability is 114mg/g.
From embodiment 1 and comparative example 1-4, the amination graphene oxide that the method for the invention prepares strengthens
The absorbability of absorbent charcoal material heavy metal ion, considerably beyond activated carbon it is achieved that to activated carbon adsorption heavy metal ion
Enhancing.
Claims (3)
1. the modified heavy metal ion adsorbing material of a kind of amination graphene oxide, comprising: doped with 1-10wt% amination
The activated carbon of graphene oxide.
2. the modified heavy metal ion adsorbing material of amination graphene oxide as claimed in claim 1 is it is characterised in that institute
The doping stating amination graphene oxide is 2-6wt%.
3. the preparation method of the modified heavy metal ion adsorbing material of amination graphene oxide as claimed in claim 1 or 2,
It is characterized in that, methods described includes:
(1) by the crystalline flake graphite of 2-5 weight portion, the phosphoric acid mixing of the concentrated sulphuric acid of 300-500 weight portion and 30-60 weight portion is all
Even, it is slowly added to the potassium permanganate of 15-20 weight portion, stir 9-18 hour at 45-55 DEG C;
(2) in mixture, at 0-5 DEG C, add the deionized water of 300-500 weight portion, and the 10- of 20-50 weight portion
The hydrogen peroxide of 30wt% concentration, and stir 5-10 minute;
(3) separate simultaneously priority deionized water, the hydrochloric acid of 10-30wt% concentration and absolute ethanol washing product, be vacuum dried
To graphene oxide;
(4) described graphene oxide is scattered in the n of 15-20 weight portion, in n- dimethyl formamide solution, adds at 0-5 DEG C
Enter the socl of 40-60 weight portion2, it is warming up to 65-80 DEG C after mix homogeneously, continue stirring 30-40 hour;
(5) by 1,6 hexamethylene diamines are added drop-wise in above-mentioned mixed liquor, stir 2-6 hour at 0-5 DEG C;
(6) add activated carbon, stir 30-180min, filter, obtain solid particle;
(7) by described solid particle under noble gases or nitrogen are protected, it is heated to 450-600 DEG C, is incubated 40-120min, obtains
To the enhanced absorbent charcoal material of amination graphene oxide.
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Cited By (7)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
CN108031283A (en) * | 2017-12-23 | 2018-05-15 | 何康德 | A kind of room air eliminating smell agent and preparation method thereof |
CN109316433A (en) * | 2018-12-05 | 2019-02-12 | 邯郸学院 | A kind of facial treatment mask reducing heavy metal pollution |
CN109431851A (en) * | 2018-12-23 | 2019-03-08 | 上海纳米技术及应用国家工程研究中心有限公司 | A kind of facial mask of removal residual heavy metal |
CN110040811A (en) * | 2019-05-22 | 2019-07-23 | 湖南云亭烯新材料科技有限公司 | A kind of graphene filtering adsorpting device |
WO2019192349A1 (en) * | 2018-04-02 | 2019-10-10 | 广东石油化工学院 | Promoter for increasing yield of fluidized catalytic cracking product |
CN112958056A (en) * | 2021-02-03 | 2021-06-15 | 中南大学 | Three-dimensional graphene oxide composite material and preparation method and application thereof |
CN113693278A (en) * | 2021-08-26 | 2021-11-26 | 上海烟草集团有限责任公司 | Composite filter stick for reducing propionic acid in cigarette smoke and cigarette |
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CN103723723A (en) * | 2013-11-22 | 2014-04-16 | 盐城纳新天地新材料科技有限公司 | Preparation method of graphene-modified activated carbon |
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Cited By (10)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
CN108031283A (en) * | 2017-12-23 | 2018-05-15 | 何康德 | A kind of room air eliminating smell agent and preparation method thereof |
WO2019192349A1 (en) * | 2018-04-02 | 2019-10-10 | 广东石油化工学院 | Promoter for increasing yield of fluidized catalytic cracking product |
CN109316433A (en) * | 2018-12-05 | 2019-02-12 | 邯郸学院 | A kind of facial treatment mask reducing heavy metal pollution |
CN109316433B (en) * | 2018-12-05 | 2021-08-27 | 邯郸学院 | Skin care mask capable of reducing heavy metal pollution |
CN109431851A (en) * | 2018-12-23 | 2019-03-08 | 上海纳米技术及应用国家工程研究中心有限公司 | A kind of facial mask of removal residual heavy metal |
CN110040811A (en) * | 2019-05-22 | 2019-07-23 | 湖南云亭烯新材料科技有限公司 | A kind of graphene filtering adsorpting device |
CN110040811B (en) * | 2019-05-22 | 2021-09-07 | 湖南云亭烯新材料科技有限公司 | Graphite alkene filters adsorption equipment |
CN112958056A (en) * | 2021-02-03 | 2021-06-15 | 中南大学 | Three-dimensional graphene oxide composite material and preparation method and application thereof |
CN113693278A (en) * | 2021-08-26 | 2021-11-26 | 上海烟草集团有限责任公司 | Composite filter stick for reducing propionic acid in cigarette smoke and cigarette |
CN113693278B (en) * | 2021-08-26 | 2023-11-07 | 上海烟草集团有限责任公司 | Composite filter stick for reducing propionic acid in cigarette smoke and cigarette |
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Application publication date: 20170201 |