CN108004696B - A kind of pigment auxiliary agent and its preparation method and application of no sewage nanometer printing and dyeing - Google Patents
A kind of pigment auxiliary agent and its preparation method and application of no sewage nanometer printing and dyeing Download PDFInfo
- Publication number
- CN108004696B CN108004696B CN201711271244.3A CN201711271244A CN108004696B CN 108004696 B CN108004696 B CN 108004696B CN 201711271244 A CN201711271244 A CN 201711271244A CN 108004696 B CN108004696 B CN 108004696B
- Authority
- CN
- China
- Prior art keywords
- dyeing
- parts
- sewage
- printing
- fabric
- Prior art date
- Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
- Active
Links
Classifications
-
- D—TEXTILES; PAPER
- D06—TREATMENT OF TEXTILES OR THE LIKE; LAUNDERING; FLEXIBLE MATERIALS NOT OTHERWISE PROVIDED FOR
- D06B—TREATING TEXTILE MATERIALS USING LIQUIDS, GASES OR VAPOURS
- D06B3/00—Passing of textile materials through liquids, gases or vapours to effect treatment, e.g. washing, dyeing, bleaching, sizing, impregnating
- D06B3/10—Passing of textile materials through liquids, gases or vapours to effect treatment, e.g. washing, dyeing, bleaching, sizing, impregnating of fabrics
- D06B3/18—Passing of textile materials through liquids, gases or vapours to effect treatment, e.g. washing, dyeing, bleaching, sizing, impregnating of fabrics combined with squeezing, e.g. in padding machines
-
- D—TEXTILES; PAPER
- D06—TREATMENT OF TEXTILES OR THE LIKE; LAUNDERING; FLEXIBLE MATERIALS NOT OTHERWISE PROVIDED FOR
- D06P—DYEING OR PRINTING TEXTILES; DYEING LEATHER, FURS OR SOLID MACROMOLECULAR SUBSTANCES IN ANY FORM
- D06P1/00—General processes of dyeing or printing textiles, or general processes of dyeing leather, furs, or solid macromolecular substances in any form, classified according to the dyes, pigments, or auxiliary substances employed
- D06P1/44—General processes of dyeing or printing textiles, or general processes of dyeing leather, furs, or solid macromolecular substances in any form, classified according to the dyes, pigments, or auxiliary substances employed using insoluble pigments or auxiliary substances, e.g. binders
- D06P1/445—Use of auxiliary substances before, during or after dyeing or printing
-
- D—TEXTILES; PAPER
- D06—TREATMENT OF TEXTILES OR THE LIKE; LAUNDERING; FLEXIBLE MATERIALS NOT OTHERWISE PROVIDED FOR
- D06P—DYEING OR PRINTING TEXTILES; DYEING LEATHER, FURS OR SOLID MACROMOLECULAR SUBSTANCES IN ANY FORM
- D06P1/00—General processes of dyeing or printing textiles, or general processes of dyeing leather, furs, or solid macromolecular substances in any form, classified according to the dyes, pigments, or auxiliary substances employed
- D06P1/44—General processes of dyeing or printing textiles, or general processes of dyeing leather, furs, or solid macromolecular substances in any form, classified according to the dyes, pigments, or auxiliary substances employed using insoluble pigments or auxiliary substances, e.g. binders
- D06P1/60—General processes of dyeing or printing textiles, or general processes of dyeing leather, furs, or solid macromolecular substances in any form, classified according to the dyes, pigments, or auxiliary substances employed using insoluble pigments or auxiliary substances, e.g. binders using compositions containing polyethers
- D06P1/613—Polyethers without nitrogen
- D06P1/6131—Addition products of hydroxyl groups-containing compounds with oxiranes
- D06P1/6133—Addition products of hydroxyl groups-containing compounds with oxiranes from araliphatic or aliphatic alcohols
-
- D—TEXTILES; PAPER
- D06—TREATMENT OF TEXTILES OR THE LIKE; LAUNDERING; FLEXIBLE MATERIALS NOT OTHERWISE PROVIDED FOR
- D06P—DYEING OR PRINTING TEXTILES; DYEING LEATHER, FURS OR SOLID MACROMOLECULAR SUBSTANCES IN ANY FORM
- D06P1/00—General processes of dyeing or printing textiles, or general processes of dyeing leather, furs, or solid macromolecular substances in any form, classified according to the dyes, pigments, or auxiliary substances employed
- D06P1/44—General processes of dyeing or printing textiles, or general processes of dyeing leather, furs, or solid macromolecular substances in any form, classified according to the dyes, pigments, or auxiliary substances employed using insoluble pigments or auxiliary substances, e.g. binders
- D06P1/62—General processes of dyeing or printing textiles, or general processes of dyeing leather, furs, or solid macromolecular substances in any form, classified according to the dyes, pigments, or auxiliary substances employed using insoluble pigments or auxiliary substances, e.g. binders using compositions containing low-molecular-weight organic compounds with sulfate, sulfonate, sulfenic or sulfinic groups
- D06P1/621—Compounds without nitrogen
- D06P1/622—Sulfonic acids or their salts
- D06P1/623—Aliphatic, aralophatic or cycloaliphatic
-
- D—TEXTILES; PAPER
- D06—TREATMENT OF TEXTILES OR THE LIKE; LAUNDERING; FLEXIBLE MATERIALS NOT OTHERWISE PROVIDED FOR
- D06P—DYEING OR PRINTING TEXTILES; DYEING LEATHER, FURS OR SOLID MACROMOLECULAR SUBSTANCES IN ANY FORM
- D06P1/00—General processes of dyeing or printing textiles, or general processes of dyeing leather, furs, or solid macromolecular substances in any form, classified according to the dyes, pigments, or auxiliary substances employed
- D06P1/44—General processes of dyeing or printing textiles, or general processes of dyeing leather, furs, or solid macromolecular substances in any form, classified according to the dyes, pigments, or auxiliary substances employed using insoluble pigments or auxiliary substances, e.g. binders
- D06P1/62—General processes of dyeing or printing textiles, or general processes of dyeing leather, furs, or solid macromolecular substances in any form, classified according to the dyes, pigments, or auxiliary substances employed using insoluble pigments or auxiliary substances, e.g. binders using compositions containing low-molecular-weight organic compounds with sulfate, sulfonate, sulfenic or sulfinic groups
- D06P1/621—Compounds without nitrogen
- D06P1/627—Sulfates
-
- D—TEXTILES; PAPER
- D06—TREATMENT OF TEXTILES OR THE LIKE; LAUNDERING; FLEXIBLE MATERIALS NOT OTHERWISE PROVIDED FOR
- D06P—DYEING OR PRINTING TEXTILES; DYEING LEATHER, FURS OR SOLID MACROMOLECULAR SUBSTANCES IN ANY FORM
- D06P1/00—General processes of dyeing or printing textiles, or general processes of dyeing leather, furs, or solid macromolecular substances in any form, classified according to the dyes, pigments, or auxiliary substances employed
- D06P1/44—General processes of dyeing or printing textiles, or general processes of dyeing leather, furs, or solid macromolecular substances in any form, classified according to the dyes, pigments, or auxiliary substances employed using insoluble pigments or auxiliary substances, e.g. binders
- D06P1/64—General processes of dyeing or printing textiles, or general processes of dyeing leather, furs, or solid macromolecular substances in any form, classified according to the dyes, pigments, or auxiliary substances employed using insoluble pigments or auxiliary substances, e.g. binders using compositions containing low-molecular-weight organic compounds without sulfate or sulfonate groups
- D06P1/651—Compounds without nitrogen
- D06P1/65106—Oxygen-containing compounds
- D06P1/65118—Compounds containing hydroxyl groups
Landscapes
- Engineering & Computer Science (AREA)
- Textile Engineering (AREA)
- Coloring (AREA)
Abstract
The invention discloses a kind of no sewage nanometer dyeing and printing process, include the following steps: that (1) imports mill base in evenness calender；(2) fabric is imported；(3) color development；(4) additive is imported；(5) be formed, mill base imported in evenness calender, fabric is immersed in mill base, 100 ~ 120 DEG C at a temperature of carry out color development, mill base can rapidly adhere to, permeate on fabric, and the cloth cover after printing and dyeing is with excellent color firmness；Fabric is carried out shaping using forming machine, importing additive helps to improve the toughness and erecting degree of fabric；After mill base infiltration completes printing and dyeing on fabric, any sewage is not remained in evenness calender, avoids the generation of waste water after printing and dyeing.
Description
Technical field
The present invention relates to printing technology, in particular to a kind of pigment auxiliary agent of no sewage nanometer printing and dyeing and preparation method thereof and
Using.
Background technique
The printing technology in China has very long history, the pattern drawn by dyeing and printing process, remarkably true to life, very
It is true to nature, embody horizontal highly developed of China weaving, superb printing technology behind, agglomerated Chinese people wisdom and
Hard sweat.And in recent years, it is biggish for polluting as energy-saving and emission-reduction are increasingly becoming a trend of China's industrial development
Dyeing receives enormous impact.The especially beginning of this year, the advance to perfect order of various regions government " showing sword " action, one band of the Yangtze River Delta
Printing and dyeing enterprise in there is 90% or more to need to renovate promotion, each printing and dyeing enterprise is faced with huge test and challenge.
When printing and dyeing enterprise is using traditional dyeing and printing process printing and dyeing 1t cloth, need to expend 100t water, while generating 100t waste water
And about 5t steam, 300 degree of electricity and 400 yuan of artificial, higher costs.Application publication number is CN101200860A's in existing patent
Chinese invention patent discloses a kind of dyeing method of fabric, and its step are as follows: (1) static or movement will be placed in printed fabrics
Station or conveyer belt on, the station or conveyer belt are made or which is provided with venthole by gas permeable material；(2) will
Negative pressure of vacuum generation system is placed in below station or transport platform, and dyestuff is atomized, and starts negative pressure of vacuum generation system, in negative pressure
Under the action of, the dyestuff of atomization from the top of fabric by pattern cards and the absorption of station or conveyer belt on the fabric to get.
This dyeing method replaces the method for tradition washing, is coloured using the atomization method of negative pressure of vacuum on cloth surface, is effectively subtracted
The generation of a large amount of waste water is lacked, but the color firmness for using negative pressure of vacuum coloring to will lead to cloth cover is poor.
Summary of the invention
The object of the present invention is to provide a kind of no sewage nanometer dyeing and printing process, are both avoided that the generation of waste water after printing and dyeing, also
Cloth cover color firmness after can guarantee printing and dyeing is excellent.
Above-mentioned technical purpose of the invention has the technical scheme that
A kind of no sewage nanometer dyeing and printing process, includes the following steps:
(1) mill base is imported in the evenness calender that two leachings two are rolled；
(2) it is then introduced into fabric；
(3) pass through forming machine color development in 100~120 DEG C of temperature environment；
(4) additive is imported in evenness calender；
(5) it is formed again by 180 degrees Celsius of forming machine, completes printing and dyeing.
By using above-mentioned technical proposal, mill base is viscous liquid, mill base is imported in evenness calender, fabric is immersed in
In mill base, 100~120 DEG C at a temperature of carry out color development, mill base can rapidly adhere to, permeate on fabric, after printing and dyeing
Cloth cover has excellent color firmness；Fabric is carried out shaping using forming machine, importing additive helps to improve fabric
Toughness and erecting degree；After mill base infiltration completes printing and dyeing on fabric, any sewage is not remained in evenness calender, avoids printing and dyeing
The generation of waste water afterwards.
The present invention is further arranged to: the mill base in step (1) is by 20~80 parts of pigment auxiliary agents and 10~30 parts of pigment
Grinding is formed, and wherein the average grain diameter of pigment is 100~300nm.
By using above-mentioned technical proposal, mill base is to be formed by pigment auxiliary agent with pigment grind, the pigment particle size of selection compared with
It carefully, is nanoscale, nanoscale mill base strong adsorption force, the permeability for grinding formation are high, help to enhance the color jail on cloth cover
Soundness.
The present invention is further arranged to: the mill base in step (1) is dried into powdered store at 80~100 DEG C.
By using above-mentioned technical proposal, since mill base is liquid viscous liquid, have the defects that transport is inconvenient, it will
Mill base is dried at 80~100 DEG C, is dried into solid powdery, solves the problems, such as that transport is inconvenient.
Another object of the present invention is to disclose a kind of pigment auxiliary agent of no sewage nanometer printing and dyeing, every 100 parts such as above-mentioned
Pigment auxiliary agent include following parts by weight component: 1~5 part of α-sodium olefin sulfonate, 1.35~4 parts of isomeric alcohol polyethenoxy ether,
Laureth mixes 1~6 part of solvent, 1~3 part of chelating agent, 1~3 part of AEO-3,1~1.5 part of nonionic penetrant, OP-10 1
~2 parts, remaining be water.
By using above-mentioned technical proposal, it is prepared for a kind of pigment auxiliary agent, there is excellent adsorptivity, permeability, wetting
Property and soil release performance, can quickly, thoroughly by pigment composition absorption, permeate on fabric to be printed and dyed, guarantee fabric surface tool
There is good color firmness；
α-sodium olefin sulfonate has excellent surface-active, and the surface tension of water is significantly reduced within the scope of a certain concentration；
Correspondingly, having excellent dissolubility, wetability, foaming characteristic and resistance to hard water, dispersion of calcium soap；With good
Good detergency, especially also shows that the characteristics of detergency does not reduce in hard water；In addition, also having good biodegrade
Performance；
Isomeric alcohol polyethenoxy ether is colourless or weak yellow liquid, soluble easily in water, has excellent emulsification, washing decontamination
Power, hard water resistance performance, chemical stability and Environmental compatibility are good in wider pH value range, can be used as dispersing agent, wetting agent,
Bleeding agent, detergent；
It is usually white or weak yellow liquid that laureth, which mixes solvent, and smell without exception is soluble easily in water, is had excellent
Decontamination, emulsification, foam performance, biological degradability etc., for washing, emulsifying, soak, assisting-dyeing, diffusion the effects of；It is especially active
Object content is high, is not influenced by the water hardness, has excellent hard water resistance property；
After chelating agent is added, the dispersion performance of each component in pigment auxiliary agent is improved, prevents metal ion from chemically reacting
Middle formation sediment, while the fabric in fabric can also be protected not to be damaged；
AEO-3 is one kind of fatty alcohol polyoxyethylene ether, is white oil object under room temperature, is soluble in oil and organic solvent,
It can be dispersed in water, there is excellent emulsifiability；Belong to lipophilic emulsifier, Cucumber can be enhanced in organic solvent
Solubility can be used as the emulsifier of production w/o type lotion, can be used as the effective component of the finish of synthetic fiber industry,
Other industry can be used as solubilizer, water defoaming agent uses；
Nonionic penetrant is a kind of extremely strong fluent material of penetration, has good adhesive force, and fast drying, resistance to
Mill property is strong, while also having good chemical resistance and water resistance；
OP-10 is a kind of emulsifier, and intramolecular contains hydrophilic and two kinds of groups of oleophylic, the interface formation circle of Yi Shui and oil
One side is well dispersed in another party by surface layer or adsorption layer, and two kinds of immiscible liquid is made to form stable emulsion, tool
Have excellent level dyeing, emulsification, wetting, diffusion, antistatic property, can be used as synthetic fiber oiling agent, bleaching and dyeing in diffusant, level dyeing
Agent, oil field foaming agent, wetting agent, retardant, detergent and emulsifier use.
The present invention is further arranged to: the α-sodium olefin sulfonate is replaced using sldium lauryl sulfate.
By using above-mentioned technical proposal, sldium lauryl sulfate can replace α-sodium olefin sulfonate to use, laruyl alcohol sulfuric acid
Sodium is white or faint yellow powdery, is dissolved in water, insensitive to alkali and hard water, has good emulsification, infiltration, decontamination and dispersibility
Energy；And foaming power is stronger, reduces the usage amount of foaming agent；It can be used as emulsifier, extinguishing chemical, foaming agent and textile auxiliary.
The present invention is further arranged to: the isomeric alcohol polyethenoxy ether selects different tridecanol polyoxyethylene ether, different ten alcohol
At least one of polyoxyethylene ether.
By using above-mentioned technical proposal, isomeric alcohol polyethenoxy ether is preferably different tridecanol and different ten alcohol, different tridecanol
Polyoxyethylene ether is easily dispersed, and is dissolved in water, is had excellent wetability, permeability and emulsibility, is used as in textile industry de-
Rouge agent, detergent, emulsifier and refining agent component；There are special emulsifying effectiveness, and energy to amido silicon oil and dimethicone
Effect after improving use, less than general silicone oil emulsification agent dosage, lotion is more stable, and has extremely strong penetration, permeable
To the inside of weaving product, to improve the soft comfortable of textile product；Different ten alcohol polyoxyethylene ether be efficient dispersing agent,
Wetting agent and emulsifier are free of benzene ring structure, are the substitutes that alkyl phenol polyoxyethylene ether is excellent in textile auxiliary and detergent.
The present invention is further arranged to: the laureth mixes solvent and selects -5 carboxylic acid of laureth, laruyl alcohol poly-
At least one of -9 sulfuric ester ammonium of ether.
By using above-mentioned technical proposal, -5 carboxylic acid of laureth is a kind of artificial synthesized compound,
Be by natural acid and it is ethylene-oxide-modified form, in the present invention be used as detergent and emulsifier, also have
Excellent film forming, wetability and antistatic property；- 9 sulfuric ester ammonium of laureth is the surfactant of excellent combination property,
Have the function of cleaning, blistering；Particularly, -5 carboxylic acid of laureth and -9 sulfuric ester ammonium of laureth are blended,
Solvent is mixed collectively as laureth, the two generates synergistic effect, significantly improves isomeric alcohol polyethenoxy ether in system
Dissolution degree.
The present invention is further arranged to: further including 1~3 part of+PO+EO of 8 carbon isomery alcohol.
By using above-mentioned technical proposal, 8 carbon isomery alcohol+PO+EO are the fatty alcohols that branch is had in molecular structure, are compared
In the derivative of straight-chain fatty alcohol, in performance have specificity, have outstanding performance be have good wetting, emulsification, decontamination,
Detergency, solubilising, blistering, antistatic, dispersion and the performances such as antirust, lubrication, and be easy to and other additive compatibilities, nontoxic and stimulation
Property is small, biological degradability is preferable and the characteristics such as lower dynamic surface tension.
The present invention is further arranged to: the nonionic penetrant selects at least one of JFC-E, JFC-2.
By using above-mentioned technical proposal, the penetration of JFC-E and JFC-2 type bleeding agent is stronger, for surface roughness
Biggish textile printing and dyeing product still can more securely be attached to the surface of printing and dyeing product, be widely used in printing and dyeing assistant field.
Another object of the present invention is to disclose a kind of preparation method of no sewage nanometer printing and dyeing pigment auxiliary agent, including such as
Lower step:
(1) it ingredient: is calculated according to 100 parts by weight pigment auxiliary agents, including 1~5 part of α-sodium olefin sulfonate, isomery alcohol polyoxy second
1.35~4 parts of alkene ether, laureth mix 1~6 part of solvent, 8 1~3 part of carbon isomery alcohol+PO+EO, 1~3 part of chelating agent, AEO-
3 1~3 parts, 1~1.5 part of nonionic penetrant, 1~2 part of OP-10, remaining be water；
(2) water, α-sodium olefin sulfonate and isomeric alcohol polyethenoxy ether is sequentially added into reaction vessel to be sufficiently stirred；
(3) laureth is then added and mixes solvent, be sufficiently stirred；
(4) 8 carbon isomery alcohol+PO+EO, AEO-3, nonionic penetrant and OP-10 is continuously added to be mixed thoroughly.
By using above-mentioned technical proposal, a kind of preparation method of pigment auxiliary agent is disclosed, raw material sources are extensive, by stirring
It the operation such as mixes, mix, chemically reacting, being prepared for that strong adsorption force, permeability be good and the pigment auxiliary agent of energy-saving and environmental protection.
In conclusion the invention has the following advantages:
1, the invention discloses a kind of no sewage nanometer dyeing and printing process, can rapidly be adhered to color using homemade mill base
On dyeing fabric, the fabric color firmness after printing and dyeing is high, and after printing and dyeing, sewage will not be generated in evenness calender, compared to
Using the printing technology of traditional dye vat, when print and dye 1t cloth when need to expend 100t water, also mean that and generate 100t waste water, effectively
Solves the problems, such as the processing of large amount of sewage；
2, pigment auxiliary agent strong adsorption force of the invention, permeability are high, can rapidly adsorb pigment, permeate on fabric,
It ensure that fabric surface has good color firmness；
3, pigment particle size of the invention is nanoscale, and granularity is higher, is easier to be attached on fabric, further improves base
Color firmness on cloth；
4, compared to the dyeing and printing process of traditional dye vat, printing steps are greatly reduced, save process, printing and dyeing can save every time
It saves 4 hours, improves printing and dyeing efficiency；
5, in addition to generating 100t waste water, about 5t steam, 300 degree can also be expended when printing and dyeing 1t cloth in traditional dyeing and finishing technology
Electricity and 400 yuan it is artificial, and dyeing and printing process of the invention does not use steam, does not need dye vat electricity consumption, does not need the people of cylinder dye yet
Work cost.
Specific embodiment
Invention is further described in detail with reference to embodiments.
Raw material sources: α-sodium olefin sulfonate, sldium lauryl sulfate are bought from the green great environmental protection company of Beijing water section；
- 5 carboxylic acid of laureth, -9 sulfuric ester ammonium of laureth are bought from the modest and amiable company in Nantong；Different tridecanol polyoxy
Vinethene, different ten alcohol polyoxyethylene ether are bought from Nantong sanda company.
Equipment source: evenness calender is bought from Shandong Wan Kai Machinery Co., Ltd.；Nano-level grinder purchase is imperial from Changzhou
Prosperous chemical machinery Co., Ltd；Forming machine is bought from Jiangyin Hua Tong Machinery Co., Ltd..
Embodiment one:
A kind of preparation method of no sewage nanometer printing and dyeing pigment auxiliary agent, includes the following steps:
(1) it ingredient: is calculated according to 100 parts by weight pigment auxiliary agents, including 1 part of α-sodium olefin sulfonate, different tridecanol polyoxy second
1.35 parts of alkene ether, 1 part of -5 carboxylic acid of laureth, 81 part of carbon isomery alcohol+PO+EO, 1 part of chelating agent, 1 part of AEO-3, JFC-E
1 part, 1 part of OP-10, remaining be water；
(2) water, α-sodium olefin sulfonate and different tridecanol polyoxyethylene ether are sequentially added into reaction vessel, chelating agent carries out
It is sufficiently stirred；
(3) -5 carboxylic acid of laureth is then added, is sufficiently stirred；
(4) 8 carbon isomery alcohol+PO+EO are continuously added, AEO-3, JFC-E and OP-10 are mixed thoroughly.
Embodiment two:
A kind of preparation method of no sewage nanometer printing and dyeing pigment auxiliary agent, includes the following steps:
(1) it ingredient: is calculated according to 100 parts by weight pigment auxiliary agents, including 3 parts of α-sodium olefin sulfonate, different ten alcohol polyoxyethylene
2.3 parts of ether, 2.8 parts of -9 sulfuric ester ammonium of laureth, 8 1.5 parts of carbon isomery alcohol+PO+EO, 1.5 parts of chelating agent, AEO-3 1
Part, 1 part of JFC-2,1 part of OP-10, remaining be water；
(2) water, α-sodium olefin sulfonate and different ten alcohol polyoxyethylene ether, chelating agent is sequentially added into reaction vessel to be filled
Divide stirring；
(3) -9 sulfuric ester ammonium of laureth is then added, is sufficiently stirred；
(4) 8 carbon isomery alcohol+PO+EO are continuously added, AEO-3, JFC-2 and OP-10 are mixed thoroughly.
Embodiment three:
A kind of preparation method of no sewage nanometer printing and dyeing pigment auxiliary agent, includes the following steps:
(1) it ingredient: is calculated according to 100 parts by weight pigment auxiliary agents, including 3 parts of α-sodium olefin sulfonate, different tridecanol polyoxy second
3 parts of alkene ether, 1 part of -5 carboxylic acid of laureth, 2 parts of -9 sulfuric ester ammonium of laureth, 82 parts of carbon isomery alcohol+PO+EO, chelating
2 parts of agent, 2 parts of AEO-3,1.5 parts of JFC-E, 2 parts of OP-10, remaining be water；
(2) water, α-sodium olefin sulfonate and different tridecanol polyoxyethylene ether are sequentially added into reaction vessel, chelating agent carries out
It is sufficiently stirred；
(3) -5 carboxylic acid of laureth is then added, is sufficiently stirred；
(4) 8 carbon isomery alcohol+PO+EO are continuously added, AEO-3, JFC-E and OP-10 are mixed thoroughly.
Example IV:
A kind of preparation method of no sewage nanometer printing and dyeing pigment auxiliary agent, includes the following steps:
(1) it ingredient: is calculated according to 100 parts by weight pigment auxiliary agents, including 3 parts of sldium lauryl sulfate, different tridecanol polyoxy second
3 parts of alkene ether, 1 part of -5 carboxylic acid of laureth, 2 parts of -9 sulfuric ester ammonium of laureth, 82 parts of carbon isomery alcohol+PO+EO, chelating
2 parts of agent, 2 parts of AEO-3,1.5 parts of JFC-E, 2 parts of OP-10, remaining be water；
(2) water, α-sodium olefin sulfonate and different tridecanol polyoxyethylene ether are sequentially added into reaction vessel, chelating agent carries out
It is sufficiently stirred；
(3) -5 carboxylic acid of laureth is then added, is sufficiently stirred；
(4) 8 carbon isomery alcohol+PO+EO are continuously added, AEO-3, JFC-E and OP-10 are mixed thoroughly.
Embodiment five:
A kind of preparation method of no sewage nanometer printing and dyeing pigment auxiliary agent, includes the following steps:
(1) it ingredient: is calculated according to 100 parts by weight pigment auxiliary agents, including 5 parts of α-sodium olefin sulfonate, different tridecanol polyoxy second
3 parts of alkene ether, 5 parts of -5 carboxylic acid of laureth, 83 parts of carbon isomery alcohol+PO+EO, 3 parts of chelating agent, 2.5 parts of AEO-3, JFC-E
1.5 parts, 1~2 part of OP-10, remaining be water；
(2) water, α-sodium olefin sulfonate and different tridecanol polyoxyethylene ether are sequentially added into reaction vessel, chelating agent carries out
It is sufficiently stirred；
(3) -5 carboxylic acid of laureth is then added, is sufficiently stirred；
(4) 8 carbon isomery alcohol+PO+EO are continuously added, AEO-3, JFC-E and OP-10 are mixed thoroughly.
Embodiment six:
A kind of preparation method of no sewage nanometer printing and dyeing pigment auxiliary agent, includes the following steps:
(1) it ingredient: is calculated according to 100 parts by weight pigment auxiliary agents, including 5 parts of α-sodium olefin sulfonate, different tridecanol polyoxy second
3 parts of alkene ether, 5 parts of -5 carboxylic acid of laureth, 3 parts of chelating agent, 2.5 parts of AEO-3, JFC-E1.5 parts, 1~2 part of OP-10, its
Yu Weishui；
(2) water, α-sodium olefin sulfonate and different tridecanol polyoxyethylene ether are sequentially added into reaction vessel, chelating agent carries out
It is sufficiently stirred；
(3) -5 carboxylic acid of laureth is then added, is sufficiently stirred；
(4) AEO-3, JFC-E and OP-10 is continuously added to be mixed thoroughly.
Embodiment seven:
A kind of no sewage nanometer dyeing and printing process, includes the following steps:
(1) mill base is imported in the evenness calender that two leachings two are rolled, wherein mill base is the pigment prepared by 80 parts of embodiments one
Auxiliary agent is formed with 20 parts of pigment grinds；
(2) it is then introduced into fabric；
(3) it is dyed in 100~120 DEG C of temperature environment by forming machine；
(4) softener, erecting agent are imported in evenness calender；
(5) it is formed again by 180 degrees Celsius of forming machine, completes printing and dyeing.
Embodiment eight: it is in place of the difference of embodiment seven, pigment auxiliary agent used is prepared by embodiment two.
Embodiment nine: it is in place of the difference of embodiment seven, pigment auxiliary agent used is prepared by embodiment three.
Embodiment ten: it is in place of the difference of embodiment seven, pigment auxiliary agent used is prepared by example IV.
Embodiment 11: it is in place of the difference of embodiment seven, pigment auxiliary agent used is prepared by embodiment five.
Embodiment 12: it is in place of the difference of embodiment seven, pigment auxiliary agent used is prepared by embodiment six.
Comparative example: using traditional dye vat printing and dyeing method dyeing fabric.
Detection means:
1, it colour fastness to rubbing: is carried out according to colour fastness to rubbing of the GB/T3920-2008 standard to the fabric after printing and dyeing
Test；
2, it color fastness to water: is tested according to color fastness to water of the GB/T5713-2013 standard to the fabric after printing and dyeing；
3, it is upper and lower permeance property: to observe the fabric after permeating completely to the upper surface of chemical fibre class fabric sprinkling mill base
The color situation on surface；
4, environmental-protecting performance: according to the content of formaldehyde in GB/T2912.1-2009 standard test textile.
The testing result of colour fastness to rubbing is as follows:
By upper table it is found that using the fabric after dyeing and printing process printing and dyeing of the invention, either resistance to unlubricated friction detection or resistance to
The wet detection that rubs, meets GB/T3920-2008 standard, with excellent wear resistance, and what conventionally employed dye vat mode was printed and dyed
The resistance to unlubricated friction of fabric and the wet ability rubbed are poor.
The testing result of color fastness to water is as follows:
| Sample | Type | Unit | Standard value | Measured value | Evaluation |
| Embodiment seven | Staining | Grade | >=3~4 | 4 | Meet |
| Embodiment eight | Staining | Grade | >=3~4 | 4 | Meet |
| Embodiment nine | Staining | Grade | >=3~4 | 4 | Meet |
| Embodiment ten | Staining | Grade | >=3~4 | 4 | Meet |
| Embodiment 11 | Staining | Grade | >=3~4 | 4 | Meet |
| Embodiment 12 | Staining | Grade | >=3~4 | 4 | Meet |
| Comparative example | Staining | Grade | >=3~4 | 3 | Meet |
By upper table it is found that fabric after dyeing and printing process printing and dyeing of the invention, reaches 4 grade standards；In aqueous solution
When encountering other colors, it is not easy to staining occur；Using traditional dye vat mode dyeing fabric, measured value reaches 3 grades, resistance to water colour jail
Degree complies with standard, but effect is undesirable.
The testing result of permeance property is as shown in the table:
By upper table it is found that mill base is sprayed on the upper surface of fabric, mill base is permeated under the effect of gravity, to seep completely
After thoroughly, the lower surface of fabric is printed and dyed completely, it has been observed that the upper and lower surfaces of fabric and no color differnece；And the fabric of comparative example,
After carrying out Liquid penetrant testing, it is found that the upper and lower surfaces color difference of fabric is obvious, it is seen then that the permeability of mill base is poor.
The testing result of environmental-protecting performance is as follows:
By upper table it is found that not detecting content of formaldehyde in the fabric after printing and dyeing, there is excellent environmental-protecting performance；And
Using the printing and dyeing method of traditional dye vat, the content of formaldehyde of 26.8mg/kg is detected, influence the health of user.
This specific embodiment is only explanation of the invention, is not limitation of the present invention, those skilled in the art
Member can according to need the modification that not creative contribution is made to the present embodiment after reading this specification, but as long as at this
All by the protection of Patent Law in the scope of the claims of invention.
Claims (6)
1. a kind of no sewage nanometer dyeing and printing process, which comprises the steps of:
(1) in the evenness calender for rolling mill base importing two into two；
(2) it is then introduced into fabric；
(3) pass through forming machine color development in 100 ~ 120 DEG C of temperature environment；
(4) additive is imported in evenness calender；
(5) it is formed again by forming machine 180 degree, completes printing and dyeing；
The mill base is formed by 20 ~ 80 parts of pigment auxiliary agents and 10 ~ 30 parts of pigment grinds, and wherein the average grain diameter of pigment is
100~300nm；
Mill base in the step (1) is dried into powdered stored at 80 ~ 100 DEG C；
The pigment auxiliary agent includes the component of following parts by weight: total amount is 100 parts, 1 ~ 5 part of sldium lauryl sulfate, isomery alcohol
1.35 ~ 4 parts of polyoxyethylene ether, laureth mix 1 ~ 6 part of solvent, 1 ~ 3 part of chelating agent, 1 ~ 3 part of AEO-3, nonionic
1 ~ 1.5 part of bleeding agent, 1 ~ 2 part of OP-10, remaining be water.
2. a kind of no sewage nanometer dyeing and printing process according to claim 1, it is characterised in that: the isomery alcohol polyoxyethylene
Ether selects at least one of different tridecanol polyoxyethylene ether, different ten alcohol polyoxyethylene ether.
3. a kind of no sewage nanometer dyeing and printing process according to claim 1, it is characterised in that: the laureth is mixed molten
At least one of -5 carboxylic acid of laureth, -9 sulfuric ester ammonium of laureth are selected in agent.
4. a kind of no sewage nanometer dyeing and printing process according to claim 1, it is characterised in that: further include 8 carbon isomery alcohol+PO
1 ~ 3 part of+EO.
5. a kind of no sewage nanometer dyeing and printing process according to claim 1, it is characterised in that: the nonionic penetrant choosing
With at least one of JFC-E, JFC-2.
6. a kind of no sewage nanometer dyeing and printing process according to claim 1-5, which is characterized in that pigment auxiliary agent system
Preparation Method includes the following steps:
(1) it ingredient: is calculated according to 100 parts by weight pigment auxiliary agents, including 1 ~ 5 part of sldium lauryl sulfate, isomeric alcohol polyethenoxy ether
1.35 ~ 4 parts, laureth mix 1 ~ 6 part of solvent, 81 ~ 3 part of carbon isomery alcohol+PO+EO, 1 ~ 3 part of chelating agent, AEO-3 1 ~ 3
Part, 1 ~ 1.5 part of nonionic penetrant, 1 ~ 2 part of OP-10, remaining be water；
(2) water, sldium lauryl sulfate and isomeric alcohol polyethenoxy ether is sequentially added into reaction vessel to be sufficiently stirred；
(3) laureth is then added and mixes solvent, be sufficiently stirred；
(4) 8 carbon isomery alcohol+PO+EO, AEO-3, nonionic penetrant and OP-10 is continuously added to be mixed thoroughly.
Priority Applications (1)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| CN201711271244.3A CN108004696B (en) | 2017-12-05 | 2017-12-05 | A kind of pigment auxiliary agent and its preparation method and application of no sewage nanometer printing and dyeing |
Applications Claiming Priority (1)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| CN201711271244.3A CN108004696B (en) | 2017-12-05 | 2017-12-05 | A kind of pigment auxiliary agent and its preparation method and application of no sewage nanometer printing and dyeing |
Publications (2)
| Publication Number | Publication Date |
|---|---|
| CN108004696A CN108004696A (en) | 2018-05-08 |
| CN108004696B true CN108004696B (en) | 2019-01-29 |
Family
ID=62057069
Family Applications (1)
| Application Number | Title | Priority Date | Filing Date |
|---|---|---|---|
| CN201711271244.3A Active CN108004696B (en) | 2017-12-05 | 2017-12-05 | A kind of pigment auxiliary agent and its preparation method and application of no sewage nanometer printing and dyeing |
Country Status (1)
| Country | Link |
|---|---|
| CN (1) | CN108004696B (en) |
Families Citing this family (4)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN109638286B (en) * | 2018-11-29 | 2021-03-30 | 瑞红锂电池材料(苏州)有限公司 | Carboxymethyl cellulose-based binder and application thereof in lithium battery |
| CN109914055B (en) * | 2019-03-27 | 2021-10-26 | 福建格利尔印染有限公司 | High-end environment-friendly PU leather base cloth anhydrous dyeing process and production line thereof |
| CN110284285A (en) * | 2019-07-04 | 2019-09-27 | 常州安达环保科技有限公司 | A kind of non-aqueous dyeing method of dacron |
| CN110565409A (en) * | 2019-10-24 | 2019-12-13 | 常州安达环保科技有限公司 | dye assistant for sewage-free nano printing and dyeing and preparation method thereof |
Citations (4)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN1345905A (en) * | 2000-09-22 | 2002-04-24 | 吉林省纺织工业设计研究院 | Nano emlsion adhesion agent and preparation process and use thereof |
| CN105220524A (en) * | 2015-11-12 | 2016-01-06 | 宋婷婷 | A kind of prescription of its dyeing liquor for foam dyeing and technique for applying |
| CN106758329A (en) * | 2016-12-30 | 2017-05-31 | 江苏中诚印染股份有限公司 | A kind of high-performance forest land camouflage facing material printing technology |
| CN106906677A (en) * | 2017-03-27 | 2017-06-30 | 上海兴康化工有限公司 | A kind of non-wastewater discharge of woven fabric material connects dyeing technique |
-
2017
- 2017-12-05 CN CN201711271244.3A patent/CN108004696B/en active Active
Patent Citations (4)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN1345905A (en) * | 2000-09-22 | 2002-04-24 | 吉林省纺织工业设计研究院 | Nano emlsion adhesion agent and preparation process and use thereof |
| CN105220524A (en) * | 2015-11-12 | 2016-01-06 | 宋婷婷 | A kind of prescription of its dyeing liquor for foam dyeing and technique for applying |
| CN106758329A (en) * | 2016-12-30 | 2017-05-31 | 江苏中诚印染股份有限公司 | A kind of high-performance forest land camouflage facing material printing technology |
| CN106906677A (en) * | 2017-03-27 | 2017-06-30 | 上海兴康化工有限公司 | A kind of non-wastewater discharge of woven fabric material connects dyeing technique |
Non-Patent Citations (2)
| Title |
|---|
| 染整前处理绿色助剂及新型前处理工艺;刘旭峰;《日用化学品科学》;20070831;第30卷(第8期);第21-24页 |
| 纳米生态染料的研究;关士林等;《印染助剂》;20040229;第21卷(第1期);第15-17页 |
Also Published As
| Publication number | Publication date |
|---|---|
| CN108004696A (en) | 2018-05-08 |
Similar Documents
| Publication | Publication Date | Title |
|---|---|---|
| CN108004696B (en) | A kind of pigment auxiliary agent and its preparation method and application of no sewage nanometer printing and dyeing | |
| CN101629130B (en) | Fabric one-bath deoiling agent | |
| KR20190078644A (en) | A water-soluble unit capacity article comprising a water-soluble fibrous structure and particles | |
| CN101435162A (en) | Formula of foam dyeing system and foam dyeing method of base cloth for multifunctional water stabbed superfine fiber leather | |
| CN101906717B (en) | Product turning liquid into printing and production method thereof | |
| CN106087407B (en) | High-efficiency oil removal agent for textile | |
| CN105002022A (en) | Low-temperature deoiling scouring agent and preparation method thereof | |
| CN109652988A (en) | A kind of complex enzyme formulation and its application for improving jeans water washing effect | |
| CN109234086A (en) | A kind of concentrated type detergent composition | |
| JP7350047B2 (en) | Liquid detergent composition for clothing | |
| CN110629567A (en) | High-performance active printing paste | |
| CN107630370A (en) | Collect multi-functional dyeing with bath degreaser | |
| CN107858843B (en) | A kind of textile color fixing agent of chitosan-containing quaternary ammonium salt and preparation method thereof | |
| CN107446725B (en) | Oil-in-water microemulsion degreaser and preparation method and application thereof | |
| HUE030121T2 (en) | Fabric treatment composition with a fabric substantive dye | |
| CN101457032B (en) | Dark blue reactive dye composition for cotton and dyeing use thereof | |
| CN101525852A (en) | Colored fabric and clothes | |
| CN110218714A (en) | A kind of compounding cellulase and its application for the polishing of denim stone mill | |
| Sivaramakrishnan | The use of surfactants in the finishing of technical textiles | |
| Tímár-Balázsy | Wet cleaning of historical textiles: surfactants and other wash bath additives | |
| CN107164982B (en) | Green food-grade detergent for textile printing and dyeing | |
| CN105064069A (en) | Disperse dye color fasteness elevator and preparation method thereof | |
| CN113186725B (en) | Environment-friendly mercerizing penetrating agent for cotton fabrics and preparation method thereof | |
| CA2311176A1 (en) | Use of partly oxidized polyethylene as an ironing aid in liquid water-containing fabric softeners | |
| CN104532560A (en) | Refining agent for continuous dyeing |
Legal Events
| Date | Code | Title | Description |
|---|---|---|---|
| PB01 | Publication | ||
| PB01 | Publication | ||
| SE01 | Entry into force of request for substantive examination | ||
| SE01 | Entry into force of request for substantive examination | ||
| GR01 | Patent grant | ||
| GR01 | Patent grant | ||
| TR01 | Transfer of patent right | ||
| TR01 | Transfer of patent right |
Effective date of registration: 20190225 Address after: 213100 Baijia Formation, Donghua Village, Hutang Town, Wujin District, Changzhou City, Jiangsu Province Patentee after: Changzhou Anda Environmental Protection Technology Co., Ltd. Address before: 213100 Donghua Village Industrial Concentration Zone, Hutang Town, Wujin District, Changzhou City, Jiangsu Province Patentee before: Changzhou Yun Da printing and dyeing Co., Ltd. |