CN1345905A - Nano emlsion adhesion agent and preparation process and use thereof - Google Patents
Nano emlsion adhesion agent and preparation process and use thereof Download PDFInfo
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- CN1345905A CN1345905A CN 00123033 CN00123033A CN1345905A CN 1345905 A CN1345905 A CN 1345905A CN 00123033 CN00123033 CN 00123033 CN 00123033 A CN00123033 A CN 00123033A CN 1345905 A CN1345905 A CN 1345905A
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- bonding agent
- latex nano
- nano bonding
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Abstract
The present invention relates to a kind of nano emulsion adhesive, its preparation method and applicaltion. Emulsifier, butyl acrylate, acrylic acid, hydroxymethyl acrylamide, hydroxyethyl acrylate, glycidic ester acrylate, styrene, acrylonitrile, ammonium persulfate and water are used as raw material and through the processes of emulsification, polymerization, filtration and discharge of material so as to obtain the invented product which can be used for printing and dyeing ecological fabrics.
Description
The invention belongs to technical field of adhesive, in particular a kind of nanometer emulsion coating dye printing tackiness agent and preparation method and its purposes aspect the printing ecological textile.
Make nanoemulsions from the existing a large amount of reports of the seventies, adopt microemulsion polymerization method, emulsifier content is very high in the micro-emulsion polymerization system, and monomer concentration is very low, and monomer concentration is lower than the concentration of emulsifying agent.Through nearly 30 years effort, to the end of this century, on latex nano bonding agent is synthetic, do not obtain substantial progress yet, can't realize suitability for industrialized production.
The preparation method and the purposes aspect the printing ecological textile thereof that the purpose of this invention is to provide the latex nano bonding agent of a kind of monomer concentration height, excellent property.
Tackiness agent of the present invention is made by following component: (consumption is a weight part)
Emulsifying agent E11-30 emulsifying agent E22-30 butyl acrylate 50-900
Vinylformic acid 10-50, n-methylolacrylamide 0-30 Hydroxyethyl acrylate 0-30
Glycidyl acrylate 0-30 vinylbenzene 0-300 vinyl cyanide 0-30 ammonium persulphate 5
Above-mentioned material accounts for 40% of total material, and all the other are water (tap water).
It is as follows that above-mentioned each component is made method of the present invention:
Earlier above-mentioned monomer is carried out pre-emulsification, temperature is 28-32 ℃, and the time is 20 minutes.Then, with the letex polymerization of semicontinuous hunger-type charging process, polymerization temperature 85-90 ℃, polymerization time is 2 hours, and is last, is warming up to 94-96 ℃, is incubated 2 hours, lowers the temperature 40-50 ℃, filters blowing.
Emulsifying agent E1 is anion surfactant, for example sodium lauryl sulphate, Sodium dodecylbenzene sulfonate etc.
Emulsifying agent E2 is nonionogenic tenside, for example peregal, OP-10 etc.
The present invention also provides the purposes of this tackiness agent aspect printing and dyeing, stamp ecological textile.
Embodiment
Take by weighing raw material by following proportioning:
Butyl acrylate 660 vinylformic acid 30 n-methylolacrylamide 10
Hydroxyethyl acrylate 20 glycidyl acrylates 10 vinylbenzene 240 vinyl cyanide 30
Monomer adds up to 1000, and emulsifying agent E1 is monomeric 1%, and emulsifying agent E2 is monomeric 3%, and ammonium persulphate is monomeric 0.5%, and monomer is 40% of total material, and water is 60% of total material.
Synthetic method is as follows:
Carry out polymerization in the polymeric kettle of 1000 liters, inventory is a polymeric kettle volumetrical 70%.Earlier monomer is mixed, carry out pre-emulsification, emulsifying temperature is 30 ℃, and the time is 20 minutes.Then, with semicontinuous hunger-type charging process emulsion polymerization, 85 ℃ of initiated polymerizations, polymerization time are 2 hours, and are last, are warming up to 95 ℃, are incubated 2 hours, lower the temperature 40 ℃, filter blowing.Gained latex nano bonding agent particle diameter is smaller or equal to 100nm, and solid content is 40%.
Purposes embodiment 1
The nanometer emulsion coating dye printing ecological textile
The ecological textile that utilizes latex nano bonding agent and coating dye printing method to make, product is ecological, production process also is ecological, does not have a large amount of water wastings, and is energy-conservation, cost is low, and can carry out dark coating dye printing processing and manufacturing ecological textile.
Nanometer emulsion coating paste formula following (weight part):
Coating (Red G Ciba) 20 latex nano bonding agents (NMD) 50
The anti-residual amount of network blocking agent (PK) 2 water
Its dyeing is as follows:
Dyeing work in-process grey cloth is soaked two by evenness calender two roll in the dyeing mill base for preparing, mangle expression is 60%, and the cloth specimen that will dye is dried in 110 ℃ baking oven, bakes in 170 ℃ baking oven after 3 minutes then and promptly gets the pigment dyeing ecological textile.
Following table is the experimental result of nanometer emulsion coating dyeing ecological textile colour fastness
Colour fastness (level) Oeko-Tex-Stardard100 experimental result
Unlubricated friction 34
Wet 2 2-3 that rub
Water-fast 34
Acid resistance sweat stain 3-4 4
Alkali resistance sweat stain 3-4 4
Purposes embodiment 2
Nanometer emulsion coating stamp ecological textile
Nanometer emulsion coating printing paste prescription following (weight part):
Coating (Red G Ciba) 30 nanometer emulsion coating printing adhesives (NMP) 200
Thickening material (PTF) the 18 anti-residual amounts of network blocking agent (PK) 2 water
Its printing technology is as follows:
By the good mill base of above-mentioned formulated, the stamp pure cotton grey fabric by the circular screen printer stamp, to be dried under 110 ℃ condition, the work in-process after will drying then get product after baking 3 minutes at 170 ℃.
Following table is the experimental result of nanometer emulsion coating stamp ecological textile colour fastness
Colour fastness (level) Oeko-Tex-Stardard100 experimental result
Unlubricated friction 34
Wet 2 2-3 that rub
Water-fast 34
Acid resistance sweat stain 3-4 4
Alkali resistance sweat stain 3-4 4
Above-mentioned dyeing, stamp experimental result all satisfy ecological textile Oeko-Tex-Stardard100 standard, and this is that general coating dye printing institute is inaccessible, is characteristics of the present invention.In addition, other ecological index such as heavy metal content, pesticide residue all can reach in this experiment.
Claims (6)
1, a kind of latex nano bonding agent is characterized in that: it is made by the following weight proportion raw material
Emulsifying agent E11-30 emulsifying agent E22-30 butyl acrylate 50-900
Vinylformic acid 10-50 n-methylolacrylamide 0-30 Hydroxyethyl acrylate 0-30
Glycidyl acrylate 0-30 vinylbenzene 0-300 vinyl cyanide 0-30 ammonium persulphate 5
Above-mentioned material accounts for 40% of total material, and all the other are water (tap water).
2, latex nano bonding agent according to claim 1 is characterized in that: emulsifying agent E1 is anionic or Sodium dodecylbenzene sulfonate.
3, latex nano bonding agent according to claim 1 is characterized in that: emulsifying agent E2 is nonionogenic tenside, for example peregal, OP-10 etc.
4, a kind of preparation method of latex nano bonding agent, the preparation technology of this method is as follows:
Earlier above-mentioned monomer is carried out pre-emulsification, temperature is 28-32 ℃, and the time is 20 minutes.Then, with the letex polymerization of semicontinuous hunger-type charging process, polymerization temperature 85-90 ℃, polymerization time is 2 hours, and is last, is warming up to 94-96 ℃, is incubated 2 hours, lowers the temperature 40-50 ℃, filters blowing.
5, the purposes of the described latex nano bonding agent of claim 1 aspect the printing and dyeing ecological textile.
6, the purposes of the described latex nano bonding agent of claim 1 aspect the stamp ecological textile.
Priority Applications (1)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| CN 00123033 CN1345905A (en) | 2000-09-22 | 2000-09-22 | Nano emlsion adhesion agent and preparation process and use thereof |
Applications Claiming Priority (1)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| CN 00123033 CN1345905A (en) | 2000-09-22 | 2000-09-22 | Nano emlsion adhesion agent and preparation process and use thereof |
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| CN1345905A true CN1345905A (en) | 2002-04-24 |
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| CN 00123033 Pending CN1345905A (en) | 2000-09-22 | 2000-09-22 | Nano emlsion adhesion agent and preparation process and use thereof |
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Cited By (9)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN1304693C (en) * | 2005-01-04 | 2007-03-14 | 浙江大学 | Automobile engine filter paper immersion resin emusion and preparation method thereof |
| CN100376607C (en) * | 2005-12-28 | 2008-03-26 | 中国化工建设总公司常州涂料化工研究院 | Latex type hydroxy acryl acid resin possessing core-shell configuration |
| CN101476246B (en) * | 2008-01-03 | 2011-09-07 | 浙江理工大学 | Burn-out printing flock fabric and preparation thereof |
| CN103981741A (en) * | 2014-05-30 | 2014-08-13 | 辽宁恒星精细化工有限公司 | Gold silver powder printing adhesive for pure cotton fabrics subjected to wet overprinting after reactive printing and preparation method thereof |
| CN104312499A (en) * | 2014-09-29 | 2015-01-28 | 中山市宝泰化工有限公司 | Glue and preparation method thereof |
| CN104313908A (en) * | 2014-10-30 | 2015-01-28 | 南通臻龙粘合剂有限公司 | Production process for imitated active printing adhesive |
| CN104313907A (en) * | 2014-10-30 | 2015-01-28 | 南通臻龙粘合剂有限公司 | Production process for super-soft printing adhesive |
| CN108004696A (en) * | 2017-12-05 | 2018-05-08 | 常州市运达印染有限公司 | A kind of pigment auxiliary agent of no sewage nanometer printing and dyeing and its preparation method and application |
| CN114479722A (en) * | 2022-01-14 | 2022-05-13 | 安徽富印新材料有限公司 | Water-based acrylate pressure-sensitive adhesive |
-
2000
- 2000-09-22 CN CN 00123033 patent/CN1345905A/en active Pending
Cited By (11)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN1304693C (en) * | 2005-01-04 | 2007-03-14 | 浙江大学 | Automobile engine filter paper immersion resin emusion and preparation method thereof |
| CN100376607C (en) * | 2005-12-28 | 2008-03-26 | 中国化工建设总公司常州涂料化工研究院 | Latex type hydroxy acryl acid resin possessing core-shell configuration |
| CN101476246B (en) * | 2008-01-03 | 2011-09-07 | 浙江理工大学 | Burn-out printing flock fabric and preparation thereof |
| CN103981741A (en) * | 2014-05-30 | 2014-08-13 | 辽宁恒星精细化工有限公司 | Gold silver powder printing adhesive for pure cotton fabrics subjected to wet overprinting after reactive printing and preparation method thereof |
| CN103981741B (en) * | 2014-05-30 | 2015-10-28 | 辽宁恒星精细化工有限公司 | For the golden and silver printing adhesive and preparation method thereof of over print wet after pure cotton fabric reactive printing |
| CN104312499A (en) * | 2014-09-29 | 2015-01-28 | 中山市宝泰化工有限公司 | Glue and preparation method thereof |
| CN104313908A (en) * | 2014-10-30 | 2015-01-28 | 南通臻龙粘合剂有限公司 | Production process for imitated active printing adhesive |
| CN104313907A (en) * | 2014-10-30 | 2015-01-28 | 南通臻龙粘合剂有限公司 | Production process for super-soft printing adhesive |
| CN108004696A (en) * | 2017-12-05 | 2018-05-08 | 常州市运达印染有限公司 | A kind of pigment auxiliary agent of no sewage nanometer printing and dyeing and its preparation method and application |
| CN108004696B (en) * | 2017-12-05 | 2019-01-29 | 常州市运达印染有限公司 | A kind of pigment auxiliary agent and its preparation method and application of no sewage nanometer printing and dyeing |
| CN114479722A (en) * | 2022-01-14 | 2022-05-13 | 安徽富印新材料有限公司 | Water-based acrylate pressure-sensitive adhesive |
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