CN108002946A - A kind of humic acid Water soluble fertilizer and preparation method thereof - Google Patents
A kind of humic acid Water soluble fertilizer and preparation method thereof Download PDFInfo
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- CN108002946A CN108002946A CN201711179471.3A CN201711179471A CN108002946A CN 108002946 A CN108002946 A CN 108002946A CN 201711179471 A CN201711179471 A CN 201711179471A CN 108002946 A CN108002946 A CN 108002946A
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- humic acid
- water soluble
- soluble fertilizer
- acid water
- fertilizer
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- C—CHEMISTRY; METALLURGY
- C05—FERTILISERS; MANUFACTURE THEREOF
- C05B—PHOSPHATIC FERTILISERS
- C05B7/00—Fertilisers based essentially on alkali or ammonium orthophosphates
-
- C—CHEMISTRY; METALLURGY
- C05—FERTILISERS; MANUFACTURE THEREOF
- C05G—MIXTURES OF FERTILISERS COVERED INDIVIDUALLY BY DIFFERENT SUBCLASSES OF CLASS C05; MIXTURES OF ONE OR MORE FERTILISERS WITH MATERIALS NOT HAVING A SPECIFIC FERTILISING ACTIVITY, e.g. PESTICIDES, SOIL-CONDITIONERS, WETTING AGENTS; FERTILISERS CHARACTERISED BY THEIR FORM
- C05G3/00—Mixtures of one or more fertilisers with additives not having a specially fertilising activity
-
- C—CHEMISTRY; METALLURGY
- C05—FERTILISERS; MANUFACTURE THEREOF
- C05G—MIXTURES OF FERTILISERS COVERED INDIVIDUALLY BY DIFFERENT SUBCLASSES OF CLASS C05; MIXTURES OF ONE OR MORE FERTILISERS WITH MATERIALS NOT HAVING A SPECIFIC FERTILISING ACTIVITY, e.g. PESTICIDES, SOIL-CONDITIONERS, WETTING AGENTS; FERTILISERS CHARACTERISED BY THEIR FORM
- C05G3/00—Mixtures of one or more fertilisers with additives not having a specially fertilising activity
- C05G3/60—Biocides or preservatives, e.g. disinfectants, pesticides or herbicides; Pest repellants or attractants
-
- C—CHEMISTRY; METALLURGY
- C05—FERTILISERS; MANUFACTURE THEREOF
- C05G—MIXTURES OF FERTILISERS COVERED INDIVIDUALLY BY DIFFERENT SUBCLASSES OF CLASS C05; MIXTURES OF ONE OR MORE FERTILISERS WITH MATERIALS NOT HAVING A SPECIFIC FERTILISING ACTIVITY, e.g. PESTICIDES, SOIL-CONDITIONERS, WETTING AGENTS; FERTILISERS CHARACTERISED BY THEIR FORM
- C05G3/00—Mixtures of one or more fertilisers with additives not having a specially fertilising activity
- C05G3/80—Soil conditioners
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- Life Sciences & Earth Sciences (AREA)
- Pest Control & Pesticides (AREA)
- Chemical & Material Sciences (AREA)
- Organic Chemistry (AREA)
- Plant Pathology (AREA)
- Soil Sciences (AREA)
- Fertilizers (AREA)
Abstract
The present invention relates to a kind of humic acid Water soluble fertilizer and preparation method thereof, component is:Urea, monoammonium phosphate, Diammonium phosphate (DAP), sulphur ammonium, dipotassium hydrogen phosphate, potassium carbonate, potassium nitrate, potassium fulvate, magnesium sulfate, humic acid, rhamnolipid, marine mussel mucoprotein, chitosan, indolebutyric acid, polyvinyl alcohol, sodium carboxymethylcellulose, sodium alkyl benzene sulfonate.Available for various vegetables, tomato is particularly suitable for.Soil can be improved, balanced Releasing nutrient, formula is reasonable, is more advantageous to effective release of fertilizer efficiency, is easy to vegetables and fully absorbs, be a kind of free of contamination environment-friendly fertilizer of noresidue.
Description
Technical field
The invention belongs to agricultural fertilizer technical field, is related to a kind of humic acid Water soluble fertilizer and preparation method thereof.
Background technology
Water soluble fertilizer is called liquid fertilizer, it is a kind of water-soluble fertilizer for top dressing, mainly the vigorous season in plant growth
Section carries out top dressing, and the actual quick-acting chemical fertilizer exactly solid are soluble in water and applied fertilizer in a manner of water band fertilizer.Water soluble fertilizer is led to
Common water-soluble chemical fertilizer, mainly nitrogenous fertilizer and potash fertilizer, the water solubility of the two is strong, is combined by rich water, allows the nutrient of solubility to ooze
Enter in soil, then absorbed for crop root.Water soluble fertilizer currently on the market mainly has three kinds of inorganic type, organic type and bion.
But existing Water soluble fertilizer effect is single, same formula is used for Different Crop, it is impossible to meet the growth demand of specified plant.It is existing
When Water soluble fertilizer is directly applied to pear tree, there are effective composition proportion is not reasonable, effective rate of utilization is low, is lost in fast, and wastage is big,
Meanwhile its nutritional ingredient is few, the nutrient needed for Growth of Pear Trees development can not be supplied comprehensively.
The content of the invention
The present invention is directed to deficiency of the prior art, there is provided a kind of humic acid Water soluble fertilizer and preparation method thereof.Suitable for vegetable
Colza is planted, and can improve soil, adjusts the pH value of soil, balanced Releasing nutrient, promotes Nutrient Absorption, effective disease-prevention and insecticide, increases
Strong resistance, increases yield.
Technical solution of the present invention is as follows:
A kind of humic acid Water soluble fertilizer, parts by weight composition are:
Urea 40~55, humic acid 35~45, monoammonium phosphate 30~40, Diammonium phosphate (DAP) 30~40, sulphur ammonium 20~25, phosphoric acid hydrogen two
Potassium 20~25, potassium carbonate 20~25, potassium nitrate 20~25, potassium fulvate 20~25, magnesium sulfate 25~30, rhamnolipid 5~8,
Marine mussel mucin 1 5~20, chitosan 5~8, indolebutyric acid 3~5, polyvinyl alcohol 5~8, sodium carboxymethylcellulose 5~8,
Sodium alkyl benzene sulfonate 3~5.
The sodium carboxymethylcellulose average degree of polymerization is preferably 1800~2200.
The polyvinyl alcohol average degree of polymerization is preferably 1500~1900.
The humic acid Water soluble fertilizer particle diameter is preferably 8~10mm.
A kind of preparation method of humic acid Water soluble fertilizer, step include:
1)By chitosan, rhamnolipid, marine mussel mucoprotein and polyvinyl alcohol, 10~20min is stirred, forms gelatinous
Lotion, 15~25 DEG C stand incubate 5~7h, then add urea, monoammonium phosphate, Diammonium phosphate (DAP), sulphur ammonium, dipotassium hydrogen phosphate,
Potassium carbonate, potassium nitrate, potassium fulvate, magnesium sulfate, stirring add water to solid and all dissolve, and form uniform solution;
2)Step 1)Solution centrifugation, remove layer 20~30 min of bulky grain cryomilling to granularity be 80~100nm after, add
In supernatant liquor after to centrifugation, it is uniformly mixed;
3)To step 2)Addition humic acid, sodium carboxymethylcellulose, sodium alkyl benzene sulfonate, indolebutyric acid in solution, 75~80 DEG C
2~3h is stirred, is granulated, is dry, obtaining humic acid Water soluble fertilizer.
Step 1)In, mixing speed is 300~600 revs/min.
Above-mentioned humic acid Water soluble fertilizer:Available for various vegetables, tomato is particularly suitable for.
Compared with prior art, its advantage is technical solution of the present invention:Soil can be improved, balanced Releasing nutrient, matches somebody with somebody
Fang Heli, compared with common fertilizer, the resistance enhancing of plant, yield significantly improves.The Water soluble fertilizer being prepared, active ingredient are born
It is loaded on gel carrier, ensures that Water soluble fertilizer is rapidly-soluble at the same time, the long-acting release of active ingredient, fertilizer materials are few, fertilizer efficiency time
It is long;Fertilizer granularity is big, and the fertilizer density on unit area is small, is slowly spread after water-soluble, and with the addition of several slow dissolubility nutrition members
Element, is more advantageous to effective release of fertilizer efficiency, is easy to vegetables and fully absorbs, be a kind of free of contamination environment-friendly fertilizer of noresidue.
Embodiment
Illustrate technical solution of the present invention and beneficial effect below by specific embodiment.
Embodiment 1
A kind of humic acid Water soluble fertilizer, parts by weight composition are:Urea 48, humic acid 39, monoammonium phosphate 36, Diammonium phosphate (DAP) 35, sulphur ammonium
22nd, dipotassium hydrogen phosphate 22, potassium carbonate 23, potassium nitrate 23, potassium fulvate 24, magnesium sulfate 28, rhamnolipid 6, marine mussel glue egg
White 17, chitosan 6, indolebutyric acid 4, polyvinyl alcohol 6, sodium carboxymethylcellulose 7, sodium alkyl benzene sulfonate 4.
Preparation method, step include:
1)By chitosan, rhamnolipid, marine mussel mucoprotein and polyvinyl alcohol(Average degree of polymerization is 1500~1900)Mixing,
Stirring(300~600 revs/min)15min, forms lotion, is stood at 20 DEG C and incubates 5-7h, then adds urea, monoammonium phosphate, phosphorus
Sour diammonium, sulphur ammonium, dipotassium hydrogen phosphate, potassium carbonate, potassium nitrate, potassium fulvate, magnesium sulfate, stirring add water to solid and all dissolve,
Form uniform solution;
Step 1)In, mixing speed is 300-600 revs/min.
2)Step 1)Solution centrifugation, remove layer bulky grain cryomilling 25min to granularity be 80~100nm after, add
In supernatant liquor after to centrifugation, it is uniformly mixed;
3)To step 2)Humic acid, sodium carboxymethylcellulose are added in solution(Average degree of polymerization is 1800~2200), alkylbenzene
Sodium sulfonate, indolebutyric acid, 75-80 DEG C of stirring 3h, are granulated, are dry, obtain the humic acid Water soluble fertilizer that particle diameter is 8-10mm.
Embodiment 2
A kind of humic acid Water soluble fertilizer, parts by weight composition are:Urea 40~55, humic acid 35~45, monoammonium phosphate 30~40, phosphoric acid
Diammonium 30~40, sulphur ammonium 20~25, dipotassium hydrogen phosphate 20~25, potassium carbonate 20~25, potassium nitrate 20~25, potassium fulvate 20~
25th, magnesium sulfate 25~30, rhamnolipid 5~8, marine mussel mucin 1 5~20, chitosan 5~8, indolebutyric acid 3~5, poly-
Vinyl alcohol 5~8, sodium carboxymethylcellulose 5~8, sodium alkyl benzene sulfonate 3~5.
Preparation method is the same as embodiment 1.
Embodiment 3
A kind of humic acid Water soluble fertilizer, parts by weight composition are:Urea 55, humic acid 45, monoammonium phosphate 40, Diammonium phosphate (DAP) 40, sulphur ammonium
25th, dipotassium hydrogen phosphate 25, potassium carbonate 25, potassium nitrate 25, potassium fulvate 25, magnesium sulfate 30, rhamnolipid 8, marine mussel glue egg
White 20, chitosan 8, indolebutyric acid 5, polyvinyl alcohol 8, sodium carboxymethylcellulose 8, sodium alkyl benzene sulfonate 5.
Preparation method is the same as embodiment 1
Application example one:
Test vegetable variety:Tomato
Experiment packet and fertilizer application mode:Medium fertility field, is randomly divided into 5 cells, corresponds to experimental group 1~3 and right respectively
According to group 1.
Experimental group 1~3 applies Water soluble fertilizer made from embodiment 1~3 and the conventional foundation fertilizer suitable for local soil respectively.
Control group 1 uses existing Water soluble fertilizer(Like the prosperous series of agriculture)The conventional foundation fertilizer suitable for local soil is administered simultaneously.
Method of application:5-7 days after tomato seedling transplant survival, per acre using 3~5kg;Florescence, per acre using 5~8kg;
Fruiting period, is applied using 6~8kg, Jia Shuichong per acre.
Interpretation of result:
The indices of experimental group and control group, the conventional foundation fertilizer that local soil is suitable for only applying contrast, and the results are shown in Table 1.
1 experimental group of table and control group Fertilizer application Contrast on effect
。
Claims (6)
1. a kind of humic acid Water soluble fertilizer, it is characterised in that parts by weight, which form, is:Urea 40~55, humic acid 35~45, phosphoric acid one
Ammonium 30~40, Diammonium phosphate (DAP) 30~40, sulphur ammonium 20~25, dipotassium hydrogen phosphate 20~25, potassium carbonate 20~25, potassium nitrate 20~
25th, potassium fulvate 20~25, magnesium sulfate 25~30, rhamnolipid 5~8, marine mussel mucin 1 5~20, chitosan 5~8,
Indolebutyric acid 3~5, polyvinyl alcohol 5~8, sodium carboxymethylcellulose 5~8, sodium alkyl benzene sulfonate 3~5.
2. humic acid Water soluble fertilizer according to claim 1, it is characterised in that:Sodium carboxymethylcellulose average degree of polymerization is
1800~2200.
3. humic acid Water soluble fertilizer according to claim 1, it is characterised in that:Polyvinyl alcohol average degree of polymerization for 1500~
1900。
4. humic acid Water soluble fertilizer according to claim 1, it is characterised in that:Humic acid Water soluble fertilizer particle diameter is 8~10mm.
5. the preparation method of any one of a kind of claim 1-4 humic acid Water soluble fertilizers, it is characterised in that step includes:
1)By chitosan, rhamnolipid, marine mussel mucoprotein and polyvinyl alcohol, 10~20min is stirred, forms gelatinous
Lotion, 15~25 DEG C stand incubate 5~7h, then add urea, monoammonium phosphate, Diammonium phosphate (DAP), sulphur ammonium, dipotassium hydrogen phosphate,
Potassium carbonate, potassium nitrate, potassium fulvate, magnesium sulfate, stirring add water to solid and all dissolve, and form uniform solution;
2)Step 1)Solution centrifugation, remove layer 20~30 min of bulky grain cryomilling to granularity be 80~100 nm after, add
Enter in the supernatant liquor to after centrifugation, be uniformly mixed;
3)To step 2)Addition humic acid, sodium carboxymethylcellulose, sodium alkyl benzene sulfonate, indolebutyric acid in solution, 75~80 DEG C
2~3h is stirred, is granulated, is dry, obtaining humic acid Water soluble fertilizer.
6. preparation method according to claim 5, it is characterised in that:Step 1)In, mixing speed for 300~600 turns/
Point.
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Cited By (4)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
CN109220449A (en) * | 2018-08-31 | 2019-01-18 | 贺州市飞龙种养专业合作社 | The implantation methods of slow seedling are taken root based on quickening plum |
CN111440023A (en) * | 2020-03-17 | 2020-07-24 | 浙江丰瑜生态科技股份有限公司 | Slow-release water-soluble fertilizer containing humic acid |
CN111499449A (en) * | 2020-03-25 | 2020-08-07 | 浙江丰瑜生态科技股份有限公司 | Slow-release water-soluble fertilizer suitable for planting in sandy soil and application thereof |
CN112430160A (en) * | 2020-11-26 | 2021-03-02 | 江西省三汇科技有限公司 | Mineral source potassium fulvate water-soluble fertilizer and preparation method thereof |
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CN103011988A (en) * | 2013-01-15 | 2013-04-03 | 青岛鲸灵海洋科技有限公司 | Organic liquid fertilizer containing chitosan |
CN103070167A (en) * | 2010-03-30 | 2013-05-01 | 湖州紫金生物科技有限公司 | Application of rhamnolipid as additive |
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Cited By (5)
Publication number | Priority date | Publication date | Assignee | Title |
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CN109220449A (en) * | 2018-08-31 | 2019-01-18 | 贺州市飞龙种养专业合作社 | The implantation methods of slow seedling are taken root based on quickening plum |
CN111440023A (en) * | 2020-03-17 | 2020-07-24 | 浙江丰瑜生态科技股份有限公司 | Slow-release water-soluble fertilizer containing humic acid |
CN111499449A (en) * | 2020-03-25 | 2020-08-07 | 浙江丰瑜生态科技股份有限公司 | Slow-release water-soluble fertilizer suitable for planting in sandy soil and application thereof |
CN111499449B (en) * | 2020-03-25 | 2021-11-16 | 浙江丰瑜生态科技股份有限公司 | Slow-release water-soluble fertilizer suitable for planting in sandy soil and application thereof |
CN112430160A (en) * | 2020-11-26 | 2021-03-02 | 江西省三汇科技有限公司 | Mineral source potassium fulvate water-soluble fertilizer and preparation method thereof |
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