CN107986884A - A kind of compound organic foliar fertilizer and preparation method thereof - Google Patents

A kind of compound organic foliar fertilizer and preparation method thereof Download PDF

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Publication number
CN107986884A
CN107986884A CN201711456019.7A CN201711456019A CN107986884A CN 107986884 A CN107986884 A CN 107986884A CN 201711456019 A CN201711456019 A CN 201711456019A CN 107986884 A CN107986884 A CN 107986884A
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China
Prior art keywords
compound organic
foliar fertilizer
marine products
organic foliar
parts
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CN201711456019.7A
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Chinese (zh)
Inventor
宋松
童文彬
陈慧明
薛占奎
徐君
吴学荣
雷春松
罗诚
练健俊
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Wanli Shennong Co Ltd
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Wanli Shennong Co Ltd
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Priority to CN201711456019.7A priority Critical patent/CN107986884A/en
Publication of CN107986884A publication Critical patent/CN107986884A/en
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    • CCHEMISTRY; METALLURGY
    • C05FERTILISERS; MANUFACTURE THEREOF
    • C05GMIXTURES OF FERTILISERS COVERED INDIVIDUALLY BY DIFFERENT SUBCLASSES OF CLASS C05; MIXTURES OF ONE OR MORE FERTILISERS WITH MATERIALS NOT HAVING A SPECIFIC FERTILISING ACTIVITY, e.g. PESTICIDES, SOIL-CONDITIONERS, WETTING AGENTS; FERTILISERS CHARACTERISED BY THEIR FORM
    • C05G5/00Fertilisers characterised by their form
    • C05G5/20Liquid fertilisers
    • CCHEMISTRY; METALLURGY
    • C05FERTILISERS; MANUFACTURE THEREOF
    • C05CNITROGENOUS FERTILISERS
    • C05C3/00Fertilisers containing other salts of ammonia or ammonia itself, e.g. gas liquor
    • CCHEMISTRY; METALLURGY
    • C05FERTILISERS; MANUFACTURE THEREOF
    • C05FORGANIC FERTILISERS NOT COVERED BY SUBCLASSES C05B, C05C, e.g. FERTILISERS FROM WASTE OR REFUSE
    • C05F17/00Preparation of fertilisers characterised by biological or biochemical treatment steps, e.g. composting or fermentation
    • C05F17/20Preparation of fertilisers characterised by biological or biochemical treatment steps, e.g. composting or fermentation using specific microorganisms or substances, e.g. enzymes, for activating or stimulating the treatment
    • YGENERAL TAGGING OF NEW TECHNOLOGICAL DEVELOPMENTS; GENERAL TAGGING OF CROSS-SECTIONAL TECHNOLOGIES SPANNING OVER SEVERAL SECTIONS OF THE IPC; TECHNICAL SUBJECTS COVERED BY FORMER USPC CROSS-REFERENCE ART COLLECTIONS [XRACs] AND DIGESTS
    • Y02TECHNOLOGIES OR APPLICATIONS FOR MITIGATION OR ADAPTATION AGAINST CLIMATE CHANGE
    • Y02WCLIMATE CHANGE MITIGATION TECHNOLOGIES RELATED TO WASTEWATER TREATMENT OR WASTE MANAGEMENT
    • Y02W30/00Technologies for solid waste management
    • Y02W30/40Bio-organic fraction processing; Production of fertilisers from the organic fraction of waste or refuse

Abstract

The present invention relates to a kind of compound organic foliar fertilizer, include the component of following mass fraction:0.1~2 part of compound 60~80 parts of organic liquor, 3~10 parts of calcium nitrate, 3~10 parts of magnesium nitrate, 1~5 part of zinc sulfate, 1~5 part of borax, 1~5 part of ferrous sulfate, 0.1~3 part of manganese sulfate and ammonium molybdate.The invention further relates to a kind of preparation method of compound organic foliar fertilizer.Compound organic foliar fertilizer provided by the invention contains amino acid, alginic acid, humic acid isoreactivity organic principle, contain micro- and a small amount of npk nutrient in calcium, magnesium, zinc, boron, iron, manganese, molybdenum etc., active material absorption micro- in being promoted by modes such as chelatings, improves crop growth conditions.

Description

A kind of compound organic foliar fertilizer and preparation method thereof
Technical field
The present invention relates to technical field of agricultural fertilizers, and in particular to a kind of compound organic foliar fertilizer and preparation method thereof.
Background technology
Foliage dressing with respect to conventional soil fertilising be most flexibly, easily fertilization mode, be to construct modern agriculture " solid is applied The important element of fertilizer " pattern, it has also become an important fertilizer practice in modern agricultural production.Foliage dressing protrude the characteristics of be With strong points, Nutrient Absorption operating is fast, can avoid fixation of the soil to some nutrients, improves plant recovery of nutrient, and apply fertilizer Amount is few, obvious effect of increasing production.
The marine products accessory substances such as Optimization of Low Value Fish, marine products processing fent and low value seaweed are in marine industries because what cannot be got well opens Hair is utilized and largely banked up, and seriously affects local environment.A large amount of protein are rich in Optimization of Low Value Fish and marine products processing leftover bits and pieces, together When also contain various bioactivators, seaweed rich in alginic acid, mannitol, glycine betaine, chitosan, polyphenol isoreactivity material and Various trace elements.These marine products accessory substances can be used efficiently in fertilizer industry.
With the continuous development of biogas engineering, the yield of biogas residue and biogas liquid is huge, it is difficult to handles.Rich in nitrogen, phosphorus, potassium in biogas slurry And the nutrient such as humic acid, while acetic acid, propionic acid, butyric acid, gibberellin, heteroauxin isoreactivity material are also enriched in, work can be improved The disease-resistant, insect-prevention ability of thing.In addition, containing a large amount of microorganisms and a certain amount of enzyme in biogas slurry, contribute to fermentation or the enzyme of material Solution.
The trace element fertilising of many peasant households centering at present is paid little attention to so that the middle trace element in soil is being planted year after year Gradually lack afterwards.In addition, when a great number of elements fertilizer input is excessive, it is easy to crop is influenced because of antagonism to calcium, magnesium, zinc etc. Middle micro- absorption, the thing followed are that some physiological disturbances occur.Foliage dressing is plant absorption nutritional ingredient, especially It is a kind of supplement of middle Trace Elements, can make up the deficiency that root system absorbs nutrient.Therefore, developing one kind can supplement Micro- compound organic foliar fertilizer has great importance in plant.
The content of the invention
To solve the above-mentioned problems in the prior art, the present invention provides a kind of compound organic foliar fertilizer and its system Preparation Method.
The present invention relates to following technical solution:
A kind of compound organic foliar fertilizer, includes the component of following mass fraction:Compound 60~80 parts of organic liquor, calcium nitrate 3~10 parts, 3~10 parts of magnesium nitrate, 1~5 part of zinc sulfate, 1~5 part of borax, 1~5 part of ferrous sulfate, 0.1~3 part of manganese sulfate and 0.1~2 part of ammonium molybdate;
The step of preparation process of the compound organic liquor is as follows:
(1) by 1~5 part of Optimization of Low Value Fish crushed material, 0~3 part of marine products processing fent crushed material, low value seaweed crushed material 1~5 0~1 part of composition fermentation materials of part and biological carbon, access strain, bank up 30~40 days, obtain marine products byproduct fermentation material;
(2) toward the biogas slurry of 3~5 times of quality of addition in gained marine products byproduct fermentation material in step (1), stir evenly, adjust Section pH to 6~7, puts into enzyme, lasting to stir, and when hydrolysis 10~15 is small at 40~60 DEG C, when standing 16~24 is small, takes supernatant liquid Extruding filtering, obtains compound organic liquor,
Preferably, it is equal toward the biogas slurry of 3~5 times of quality of addition in gained marine products byproduct fermentation material in step (1), stirring Even, adjusting pH to 6~7, puts into enzyme, lasting to stir, and when hydrolysis 15 is small at 50 DEG C, when standing 24 is small, takes supernatant liquid to extrude Filter, obtains compound organic liquor.
Filter residue and lower sediment extrusion dehydration, liquid portion are incorporated in compound organic liquor, residue can be used as organic fertilizer or The raw material of compound organic and inorganic fertilizer uses, and realizes maximally utilizing for resource.
The Optimization of Low Value Fish crushed material, marine products processing fent crushed material and low value seaweed crushed material are by corresponding marine products pair Product adds and gained is crushed in pulverizer, and the liquid portion after the crushing of marine products accessory substance collects the refinement for fish oil.
The marine products processing fent includes the one or more in fish head, fish-bone, fish guts, shrimp head, shrimp tail.
The biological carbon is obtained by animal dung high temperature carbonization, can assisted fermentation and removal material raw meat mainly based on pig manure Taste.
The biogas slurry is the fermentation residue liquid that feces of livestock and poultry, feed remnants and animal house wash away rich water.
The strain of access is saccharomycete and lactic acid bacteria in the step (1).
The enzyme of input is cellulase, pectase and protease in the step (2), and the input amount of the enzyme is marine products pair The 0.5%~3% of product fermentations material quality.
A kind of preparation method of compound organic foliar fertilizer, comprises the following steps:Gained it will be compounded with as stated above Machine liquid is added in reaction kettle, heat temperature raising, and after sterilising and enzyme inactivating, it is sub- to add calcium nitrate, magnesium nitrate, zinc sulfate, borax, sulfuric acid Iron, manganese sulfate and ammonium molybdate, maintain temperature at 50~60 DEG C, stirring, fully chelating, and filtering is canned, obtains compound organic foliage Fertilizer.
Marine products byproduct fermentation material can retain sub-fraction in step (1), the thing before putting into fermentation when fermenting next time In material, the input and cost of strain can be reduced so during continuous production.
Compared with prior art, the beneficial effects of the invention are as follows:Compound organic foliar fertilizer provided by the invention contains ammonia Base acid, alginic acid, humic acid isoreactivity organic principle, contain micro- and a small amount of nitrogen in calcium, magnesium, zinc, boron, iron, manganese, molybdenum etc. Phosphorus potassium nutrition, active material absorption micro- in being promoted by modes such as chelatings, improves crop growth conditions.
The marine products accessory substance Combined Treatment such as Optimization of Low Value Fish, marine products processing fent and low value seaweed, is more advantageous to fermenting, first sends out The processing mode that ferment digests again improves the extraction efficiency of active ingredient.
When marine products accessory substance is digested using biogas slurry as medium, microorganism and enzyme in biogas slurry can play in enzymolysis process Booster action, enzymolysis efficiency is improved while rationally biogas slurry is utilized.
Embodiment
In order to which technical characteristic, purpose and the beneficial effect of the present invention is more clearly understood, in conjunction with instantiation To technical scheme carry out it is described further below, techniques not described means of the present invention by usual manner in the art into OK, it should be understood that these embodiments are only illustrative of the invention and is not intended to limit the scope of the invention.
Embodiment 1
A kind of compound organic foliar fertilizer, includes the component of following mass fraction:Compound 80 parts of organic liquor, calcium nitrate 10 Part, 8 parts of magnesium nitrate, 2 parts of zinc sulfate, 1 part of borax, 1 part of ferrous sulfate, 0.1 part of manganese sulfate and 0.1 part of ammonium molybdate.
Preparation method includes the following steps:
(1) by 4 parts of Optimization of Low Value Fish crushed material, 1 part of marine products processing fent crushed material, 4 parts of low value seaweed crushed material and biology 1 part of composition fermentation materials of carbon, access saccharomycete and lactic acid bacteria, bank up 40 days, obtain marine products byproduct fermentation material;
(2) toward the biogas slurry that 4 times of quality are added in marine products byproduct fermentation material obtained by step (1), stir evenly, adjust pH to 6~7, cellulase, pectase and protease are added, the input amount of enzyme is the 1.8% of marine products byproduct fermentation material quality, is continued Stirring, when hydrolysis 15 is small at 40~60 DEG C, when standing 24 is small, takes supernatant liquid extruding filtering, obtains compound organic liquor;
(3) compound organic liquor obtained by step (2) is added in reaction kettle, is heated to 85 DEG C, sterilising and enzyme inactivating, 20 points Zhong Hou, calcium nitrate, magnesium nitrate, zinc sulfate, borax, ferrous sulfate, manganese sulfate and molybdenum are added according to above-mentioned mass fraction proportioning Sour ammonium, maintains temperature at 50~60 DEG C, when stirring 3 is small, fully chelates;
(4) filter, it is canned, obtain compound organic foliar fertilizer.
Embodiment 2
A kind of compound organic foliar fertilizer, includes the component of following mass fraction:Compound 70 parts of organic liquor, 5 parts of calcium nitrate, 2 parts of 5 parts of magnesium nitrate, 3 parts of zinc sulfate, 2 parts of borax, 3 parts of ferrous sulfate, 2 parts of manganese sulfate and ammonium molybdate.
Preparation method includes the following steps:
(1) by 3 parts of Optimization of Low Value Fish crushed material, 1 part of marine products processing fent crushed material, 4 parts of low value seaweed crushed material and biology 0.5 part of composition fermentation materials of carbon, access saccharomycete and lactic acid bacteria, bank up 36 days, obtain marine products byproduct fermentation material;
(2) toward the biogas slurry that 5 times of quality are added in marine products byproduct fermentation material obtained by step (1), stir evenly, adjust pH to 6~7, cellulase, pectase and protease are added, the input amount of enzyme is the 2.3% of marine products byproduct fermentation material quality, is continued Stirring, when hydrolysis 12 is small at 40~60 DEG C, when standing 18 is small, takes supernatant liquid extruding filtering, obtains compound organic liquor;
(3) compound organic liquor obtained by step (2) is added in reaction kettle, is heated to 85 DEG C, sterilising and enzyme inactivating, 20 points Zhong Hou, calcium nitrate, magnesium nitrate, zinc sulfate, borax, ferrous sulfate, manganese sulfate and molybdenum are added according to above-mentioned mass fraction proportioning Sour ammonium, maintains temperature at 50~60 DEG C, when stirring 3 is small, fully chelates;
(4) filter, it is canned, obtain compound organic foliar fertilizer.
Embodiment 3
A kind of compound organic foliar fertilizer, includes the component of following mass fraction:Compound 65 parts of organic liquor, 7 parts of calcium nitrate, 1 part of 7 parts of magnesium nitrate, 1 part of zinc sulfate, 2 parts of borax, 2 parts of ferrous sulfate, 1 part of manganese sulfate and ammonium molybdate.
Preparation method includes the following steps:
(1) by 5 parts of Optimization of Low Value Fish crushed material, 2 parts of marine products processing fent crushed material, 2 parts of low value seaweed crushed material and biology 1 part of composition fermentation materials of carbon, access saccharomycete and lactic acid bacteria, bank up 35 days, obtain marine products byproduct fermentation material;
(2) toward the biogas slurry that 4 times of quality are added in marine products byproduct fermentation material obtained by step (1), stir evenly, adjust pH to 6~7, cellulase, pectase and protease are added, the input amount of enzyme is the 2.3% of marine products byproduct fermentation material quality, is continued Stirring, when hydrolysis 15 is small at 50 DEG C, when standing 24 is small, takes supernatant liquid extruding filtering, obtains compound organic liquor;
(3) compound organic liquor obtained by step (2) is added in reaction kettle, is heated to 85 DEG C, sterilising and enzyme inactivating, 20 points Zhong Hou, calcium nitrate, magnesium nitrate, zinc sulfate, borax, ferrous sulfate, manganese sulfate and molybdenum are added according to above-mentioned mass fraction proportioning Sour ammonium, maintains temperature at 50~60 DEG C, when stirring 3 is small, fully chelates;
(4) filter, it is canned, obtain compound organic foliar fertilizer.
Embodiment 4
A kind of compound organic foliar fertilizer, includes the component of following mass fraction:Compound 80 parts of organic liquor, calcium nitrate 10 Part, 8 parts of magnesium nitrate, 2 parts of zinc sulfate, 1 part of borax, 1 part of ferrous sulfate, 0.1 part of manganese sulfate and 0.1 part of ammonium molybdate.
Preparation method includes the following steps:
(1) by 4 parts of composition fermentation materials of 4 parts of Optimization of Low Value Fish crushed material and low value seaweed crushed material, saccharomycete and lactic acid are accessed Bacterium, banks up 40 days, obtains marine products byproduct fermentation material;
(2) toward the biogas slurry that 4 times of quality are added in marine products byproduct fermentation material obtained by step (1), stir evenly, adjust pH to 6~7, cellulase, pectase and protease are added, the input amount of enzyme is the 1.8% of marine products byproduct fermentation material quality, is continued Stirring, when hydrolysis 15 is small at 40~60 DEG C, when standing 24 is small, takes supernatant liquid extruding filtering, obtains compound organic liquor;
(3) compound organic liquor obtained by step (2) is added in reaction kettle, is heated to 85 DEG C, sterilising and enzyme inactivating, 20 points Zhong Hou, calcium nitrate, magnesium nitrate, zinc sulfate, borax, ferrous sulfate, manganese sulfate and molybdenum are added according to above-mentioned mass fraction proportioning Sour ammonium, maintains temperature at 50~60 DEG C, when stirring 3 is small, fully chelates;
(4) filter, it is canned, obtain compound organic foliar fertilizer.
Application Example
In order to verify the effect of foliar fertilizer of the present invention, to plant strawberry as experiment crop, with being compounded with embodiment 1 Machine foliar fertilizer is as test group, and as a control group, the npk nutrient input amount of two processing is suitable for punching fertilising, and in strawberry Completely the same way to manage is used during plantation.
Test place:Ten thousand inner legendary god of farming research institute of Hangzhou, Zhejiang province city Xihu District and Jinhua, Zhejiang Province city Jindong District Ling Xia Zhen Fan Tian Cun.
In terms of the growing way of field, for test process after foliar fertilizer is sprayed, leaf color is greener thicker, and chlorophyll content will height In control treatment;First batch of fruit of test process shifts to an earlier date 2 days maturations compared with control treatment.
Harvest the strawberry of first three batch of fruit, crop result such as table 1 below:
Table 1
As shown in Table 1:Compared with conventional fertilizer application, after tested fertilizer, yield of strawberry rises, Xihu District of Hangzhou City experiment Point volume increase 10.8%, Jinhua Jindong District experimental point volume increase 10.5%.
Significant difference result such as table 2 below and 3:
Table 2
Xihu District of Hangzhou City experimental point statistical analysis is as follows:
Table 3
The experimental point statistical analysis of Jinhua Jindong District is as follows:
Significance analysis is carried out to difference processing by DPS statistical analysis softwares,
From table 2 and 3:The P=0.008 of Xihu District of Hangzhou City experimental point, the P=of Jinhua Jindong District experimental point 0.002, the P of two testing sites is both less than 0.01, illustrates to reach the pole level of signifiance.
Have in conclusion compound organic foliar fertilizer provided by the invention contains amino acid, alginic acid, humic acid isoreactivity Machine component, containing micro- and a small amount of npk nutrient in calcium, magnesium, zinc, boron, iron, manganese, molybdenum etc., the ammonia in compound organic liquor The materials such as base acid are trace element chelated with, can advantageously promote middle micro- absorption, improve crop growth conditions, carry High crop yield, it is highly practical, it is adapted to promote in this area.
The foregoing is merely preferred embodiments of the present invention, are not intended to limit the invention, all essences in the present invention With within principle, any modification, equivalent replacement, improvement and so on, should all be included in the protection scope of the present invention god.

Claims (9)

  1. A kind of 1. compound organic foliar fertilizer, it is characterised in that:Include the component of following mass fraction:Compound organic liquor 60~80 Part, 3~10 parts of calcium nitrate, 3~10 parts of magnesium nitrate, 1~5 part of zinc sulfate, 1~5 part of borax, 1~5 part of ferrous sulfate, manganese sulfate 0.1~3 part and 0.1~2 part of ammonium molybdate;
    The step of preparation process of the compound organic liquor is as follows:
    (1) by 1~5 part of Optimization of Low Value Fish crushed material, 0~3 part of marine products processing fent crushed material, 1~5 part of low value seaweed crushed material and 0~1 part of composition fermentation materials of biological carbon, access strain, bank up 30~40 days, obtain marine products byproduct fermentation material;
    (2) toward the biogas slurry of 3~5 times of quality of addition in gained marine products byproduct fermentation material in step (1), stir evenly, adjust pH To 6~7, enzyme is put into, persistently stirring, when hydrolysis 10~15 is small at 40~60 DEG C, when standing 16~24 is small, take supernatant liquid to extrude Filtering, obtains compound organic liquor.
  2. A kind of 2. compound organic foliar fertilizer as claimed in claim 1, it is characterised in that:The step (2) is toward step (1) The biogas slurry of 4 times of quality is added in middle gained marine products byproduct fermentation material, is stirred evenly, adjusts pH to 6~7, enzyme is put into, persistently stirs Mix, when hydrolysis 15 is small at 50 DEG C, when standing 24 is small, takes supernatant liquid extruding filtering, obtain compound organic liquor.
  3. A kind of 3. compound organic foliar fertilizer as claimed in claim 1, it is characterised in that:The Optimization of Low Value Fish crushed material, marine products Processing fent crushed material and low value seaweed crushed material are to add corresponding marine products accessory substance to crush gained in pulverizer.
  4. A kind of 4. compound organic foliar fertilizer as claimed in claim 1, it is characterised in that:The marine products processing fent includes One or more in fish head, fish-bone, fish guts, shrimp head, shrimp tail.
  5. A kind of 5. compound organic foliar fertilizer as claimed in claim 1, it is characterised in that:The biological carbon is by animal dung high temperature Charing gained.
  6. A kind of 6. compound organic foliar fertilizer as claimed in claim 1, it is characterised in that:The biogas slurry is feces of livestock and poultry, raises The remaining fermentation residue liquid that rich water is washed away with animal house of material.
  7. A kind of 7. compound organic foliar fertilizer as claimed in claim 1, it is characterised in that:The bacterium of access in the step (1) Kind is saccharomycete and lactic acid bacteria.
  8. A kind of 8. compound organic foliar fertilizer as claimed in claim 1, it is characterised in that:The enzyme of input in the step (2) For cellulase, pectase and protease, the input amount of the enzyme is the 0.5%~3% of marine products byproduct fermentation material quality.
  9. A kind of 9. preparation method of compound organic foliar fertilizer described in based on claim 1-8 any one, it is characterised in that Comprise the following steps:The compound organic liquor of gained it will be added to as stated above in reaction kettle, heat temperature raising, after sterilising and enzyme inactivating, Calcium nitrate, magnesium nitrate, zinc sulfate, borax, ferrous sulfate, manganese sulfate and ammonium molybdate are added, maintains temperature to be stirred at 50~60 DEG C Mix, fully chelating, filtering is canned, obtains compound organic foliar fertilizer.
CN201711456019.7A 2017-12-28 2017-12-28 A kind of compound organic foliar fertilizer and preparation method thereof Pending CN107986884A (en)

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Cited By (4)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
CN108976062A (en) * 2018-10-24 2018-12-11 内蒙古风泽中孚生物科技有限公司 A kind of foliar fertilizer and its production technology
CN109438083A (en) * 2018-12-27 2019-03-08 广西壮族自治区农业科学院农业资源与环境研究所 A kind of selenium-enriched liquid fertilizer
CN109912367A (en) * 2019-04-02 2019-06-21 许帅 A kind of smooth carbon foliar fertilizer and preparation method thereof
CN110218107A (en) * 2019-07-01 2019-09-10 潘凤芝 A kind of nutrient solution and its production technology containing microelement

Citations (1)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
CN105000993A (en) * 2015-07-23 2015-10-28 合肥众月健康科技有限公司 High-permeability liquid fertilizer and preparing method thereof

Patent Citations (1)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
CN105000993A (en) * 2015-07-23 2015-10-28 合肥众月健康科技有限公司 High-permeability liquid fertilizer and preparing method thereof

Cited By (4)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
CN108976062A (en) * 2018-10-24 2018-12-11 内蒙古风泽中孚生物科技有限公司 A kind of foliar fertilizer and its production technology
CN109438083A (en) * 2018-12-27 2019-03-08 广西壮族自治区农业科学院农业资源与环境研究所 A kind of selenium-enriched liquid fertilizer
CN109912367A (en) * 2019-04-02 2019-06-21 许帅 A kind of smooth carbon foliar fertilizer and preparation method thereof
CN110218107A (en) * 2019-07-01 2019-09-10 潘凤芝 A kind of nutrient solution and its production technology containing microelement

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