CN107956106A - A kind of antibacterial felt-proofing finishing method of wool cap - Google Patents

A kind of antibacterial felt-proofing finishing method of wool cap Download PDF

Info

Publication number
CN107956106A
CN107956106A CN201711235488.6A CN201711235488A CN107956106A CN 107956106 A CN107956106 A CN 107956106A CN 201711235488 A CN201711235488 A CN 201711235488A CN 107956106 A CN107956106 A CN 107956106A
Authority
CN
China
Prior art keywords
wool cap
mass concentration
antibacterial
wool
cap
Prior art date
Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
Withdrawn
Application number
CN201711235488.6A
Other languages
Chinese (zh)
Inventor
李佳
Current Assignee (The listed assignees may be inaccurate. Google has not performed a legal analysis and makes no representation or warranty as to the accuracy of the list.)
Anhui Zhongfu Wool Cap Co Ltd
Original Assignee
Anhui Zhongfu Wool Cap Co Ltd
Priority date (The priority date is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the date listed.)
Filing date
Publication date
Application filed by Anhui Zhongfu Wool Cap Co Ltd filed Critical Anhui Zhongfu Wool Cap Co Ltd
Priority to CN201711235488.6A priority Critical patent/CN107956106A/en
Publication of CN107956106A publication Critical patent/CN107956106A/en
Withdrawn legal-status Critical Current

Links

Classifications

    • D—TEXTILES; PAPER
    • D06—TREATMENT OF TEXTILES OR THE LIKE; LAUNDERING; FLEXIBLE MATERIALS NOT OTHERWISE PROVIDED FOR
    • D06M—TREATMENT, NOT PROVIDED FOR ELSEWHERE IN CLASS D06, OF FIBRES, THREADS, YARNS, FABRICS, FEATHERS OR FIBROUS GOODS MADE FROM SUCH MATERIALS
    • D06M11/00—Treating fibres, threads, yarns, fabrics or fibrous goods made from such materials, with inorganic substances or complexes thereof; Such treatment combined with mechanical treatment, e.g. mercerising
    • D06M11/32—Treating fibres, threads, yarns, fabrics or fibrous goods made from such materials, with inorganic substances or complexes thereof; Such treatment combined with mechanical treatment, e.g. mercerising with oxygen, ozone, ozonides, oxides, hydroxides or percompounds; Salts derived from anions with an amphoteric element-oxygen bond
    • D06M11/36—Treating fibres, threads, yarns, fabrics or fibrous goods made from such materials, with inorganic substances or complexes thereof; Such treatment combined with mechanical treatment, e.g. mercerising with oxygen, ozone, ozonides, oxides, hydroxides or percompounds; Salts derived from anions with an amphoteric element-oxygen bond with oxides, hydroxides or mixed oxides; with salts derived from anions with an amphoteric element-oxygen bond
    • D06M11/46—Oxides or hydroxides of elements of Groups 4 or 14 of the Periodic System; Titanates; Zirconates; Stannates; Plumbates
    • D—TEXTILES; PAPER
    • D06—TREATMENT OF TEXTILES OR THE LIKE; LAUNDERING; FLEXIBLE MATERIALS NOT OTHERWISE PROVIDED FOR
    • D06M—TREATMENT, NOT PROVIDED FOR ELSEWHERE IN CLASS D06, OF FIBRES, THREADS, YARNS, FABRICS, FEATHERS OR FIBROUS GOODS MADE FROM SUCH MATERIALS
    • D06M11/00—Treating fibres, threads, yarns, fabrics or fibrous goods made from such materials, with inorganic substances or complexes thereof; Such treatment combined with mechanical treatment, e.g. mercerising
    • D06M11/32—Treating fibres, threads, yarns, fabrics or fibrous goods made from such materials, with inorganic substances or complexes thereof; Such treatment combined with mechanical treatment, e.g. mercerising with oxygen, ozone, ozonides, oxides, hydroxides or percompounds; Salts derived from anions with an amphoteric element-oxygen bond
    • D06M11/50—Treating fibres, threads, yarns, fabrics or fibrous goods made from such materials, with inorganic substances or complexes thereof; Such treatment combined with mechanical treatment, e.g. mercerising with oxygen, ozone, ozonides, oxides, hydroxides or percompounds; Salts derived from anions with an amphoteric element-oxygen bond with hydrogen peroxide or peroxides of metals; with persulfuric, permanganic, pernitric, percarbonic acids or their salts
    • D—TEXTILES; PAPER
    • D06—TREATMENT OF TEXTILES OR THE LIKE; LAUNDERING; FLEXIBLE MATERIALS NOT OTHERWISE PROVIDED FOR
    • D06M—TREATMENT, NOT PROVIDED FOR ELSEWHERE IN CLASS D06, OF FIBRES, THREADS, YARNS, FABRICS, FEATHERS OR FIBROUS GOODS MADE FROM SUCH MATERIALS
    • D06M11/00—Treating fibres, threads, yarns, fabrics or fibrous goods made from such materials, with inorganic substances or complexes thereof; Such treatment combined with mechanical treatment, e.g. mercerising
    • D06M11/77—Treating fibres, threads, yarns, fabrics or fibrous goods made from such materials, with inorganic substances or complexes thereof; Such treatment combined with mechanical treatment, e.g. mercerising with silicon or compounds thereof
    • D06M11/79—Treating fibres, threads, yarns, fabrics or fibrous goods made from such materials, with inorganic substances or complexes thereof; Such treatment combined with mechanical treatment, e.g. mercerising with silicon or compounds thereof with silicon dioxide, silicic acids or their salts
    • D—TEXTILES; PAPER
    • D06—TREATMENT OF TEXTILES OR THE LIKE; LAUNDERING; FLEXIBLE MATERIALS NOT OTHERWISE PROVIDED FOR
    • D06M—TREATMENT, NOT PROVIDED FOR ELSEWHERE IN CLASS D06, OF FIBRES, THREADS, YARNS, FABRICS, FEATHERS OR FIBROUS GOODS MADE FROM SUCH MATERIALS
    • D06M11/00—Treating fibres, threads, yarns, fabrics or fibrous goods made from such materials, with inorganic substances or complexes thereof; Such treatment combined with mechanical treatment, e.g. mercerising
    • D06M11/83—Treating fibres, threads, yarns, fabrics or fibrous goods made from such materials, with inorganic substances or complexes thereof; Such treatment combined with mechanical treatment, e.g. mercerising with metals; with metal-generating compounds, e.g. metal carbonyls; Reduction of metal compounds on textiles
    • D—TEXTILES; PAPER
    • D06—TREATMENT OF TEXTILES OR THE LIKE; LAUNDERING; FLEXIBLE MATERIALS NOT OTHERWISE PROVIDED FOR
    • D06M—TREATMENT, NOT PROVIDED FOR ELSEWHERE IN CLASS D06, OF FIBRES, THREADS, YARNS, FABRICS, FEATHERS OR FIBROUS GOODS MADE FROM SUCH MATERIALS
    • D06M13/00—Treating fibres, threads, yarns, fabrics or fibrous goods made from such materials, with non-macromolecular organic compounds; Such treatment combined with mechanical treatment
    • D06M13/10—Treating fibres, threads, yarns, fabrics or fibrous goods made from such materials, with non-macromolecular organic compounds; Such treatment combined with mechanical treatment with compounds containing oxygen
    • D06M13/152—Treating fibres, threads, yarns, fabrics or fibrous goods made from such materials, with non-macromolecular organic compounds; Such treatment combined with mechanical treatment with compounds containing oxygen having a hydroxy group bound to a carbon atom of a six-membered aromatic ring
    • D—TEXTILES; PAPER
    • D06—TREATMENT OF TEXTILES OR THE LIKE; LAUNDERING; FLEXIBLE MATERIALS NOT OTHERWISE PROVIDED FOR
    • D06M—TREATMENT, NOT PROVIDED FOR ELSEWHERE IN CLASS D06, OF FIBRES, THREADS, YARNS, FABRICS, FEATHERS OR FIBROUS GOODS MADE FROM SUCH MATERIALS
    • D06M13/00—Treating fibres, threads, yarns, fabrics or fibrous goods made from such materials, with non-macromolecular organic compounds; Such treatment combined with mechanical treatment
    • D06M13/244—Treating fibres, threads, yarns, fabrics or fibrous goods made from such materials, with non-macromolecular organic compounds; Such treatment combined with mechanical treatment with compounds containing sulfur or phosphorus
    • D06M13/248—Treating fibres, threads, yarns, fabrics or fibrous goods made from such materials, with non-macromolecular organic compounds; Such treatment combined with mechanical treatment with compounds containing sulfur or phosphorus with compounds containing sulfur
    • D06M13/262—Sulfated compounds thiosulfates
    • D—TEXTILES; PAPER
    • D06—TREATMENT OF TEXTILES OR THE LIKE; LAUNDERING; FLEXIBLE MATERIALS NOT OTHERWISE PROVIDED FOR
    • D06M—TREATMENT, NOT PROVIDED FOR ELSEWHERE IN CLASS D06, OF FIBRES, THREADS, YARNS, FABRICS, FEATHERS OR FIBROUS GOODS MADE FROM SUCH MATERIALS
    • D06M13/00—Treating fibres, threads, yarns, fabrics or fibrous goods made from such materials, with non-macromolecular organic compounds; Such treatment combined with mechanical treatment
    • D06M13/50—Treating fibres, threads, yarns, fabrics or fibrous goods made from such materials, with non-macromolecular organic compounds; Such treatment combined with mechanical treatment with organometallic compounds; with organic compounds containing boron, silicon, selenium or tellurium atoms
    • D—TEXTILES; PAPER
    • D06—TREATMENT OF TEXTILES OR THE LIKE; LAUNDERING; FLEXIBLE MATERIALS NOT OTHERWISE PROVIDED FOR
    • D06M—TREATMENT, NOT PROVIDED FOR ELSEWHERE IN CLASS D06, OF FIBRES, THREADS, YARNS, FABRICS, FEATHERS OR FIBROUS GOODS MADE FROM SUCH MATERIALS
    • D06M15/00—Treating fibres, threads, yarns, fabrics, or fibrous goods made from such materials, with macromolecular compounds; Such treatment combined with mechanical treatment
    • D06M15/01—Treating fibres, threads, yarns, fabrics, or fibrous goods made from such materials, with macromolecular compounds; Such treatment combined with mechanical treatment with natural macromolecular compounds or derivatives thereof
    • D06M15/03—Polysaccharides or derivatives thereof
    • D—TEXTILES; PAPER
    • D06—TREATMENT OF TEXTILES OR THE LIKE; LAUNDERING; FLEXIBLE MATERIALS NOT OTHERWISE PROVIDED FOR
    • D06M—TREATMENT, NOT PROVIDED FOR ELSEWHERE IN CLASS D06, OF FIBRES, THREADS, YARNS, FABRICS, FEATHERS OR FIBROUS GOODS MADE FROM SUCH MATERIALS
    • D06M15/00—Treating fibres, threads, yarns, fabrics, or fibrous goods made from such materials, with macromolecular compounds; Such treatment combined with mechanical treatment
    • D06M15/19—Treating fibres, threads, yarns, fabrics, or fibrous goods made from such materials, with macromolecular compounds; Such treatment combined with mechanical treatment with synthetic macromolecular compounds
    • D06M15/37—Macromolecular compounds obtained otherwise than by reactions only involving carbon-to-carbon unsaturated bonds
    • D—TEXTILES; PAPER
    • D06—TREATMENT OF TEXTILES OR THE LIKE; LAUNDERING; FLEXIBLE MATERIALS NOT OTHERWISE PROVIDED FOR
    • D06M—TREATMENT, NOT PROVIDED FOR ELSEWHERE IN CLASS D06, OF FIBRES, THREADS, YARNS, FABRICS, FEATHERS OR FIBROUS GOODS MADE FROM SUCH MATERIALS
    • D06M16/00—Biochemical treatment of fibres, threads, yarns, fabrics, or fibrous goods made from such materials, e.g. enzymatic
    • D—TEXTILES; PAPER
    • D06—TREATMENT OF TEXTILES OR THE LIKE; LAUNDERING; FLEXIBLE MATERIALS NOT OTHERWISE PROVIDED FOR
    • D06M—TREATMENT, NOT PROVIDED FOR ELSEWHERE IN CLASS D06, OF FIBRES, THREADS, YARNS, FABRICS, FEATHERS OR FIBROUS GOODS MADE FROM SUCH MATERIALS
    • D06M16/00—Biochemical treatment of fibres, threads, yarns, fabrics, or fibrous goods made from such materials, e.g. enzymatic
    • D06M16/003—Biochemical treatment of fibres, threads, yarns, fabrics, or fibrous goods made from such materials, e.g. enzymatic with enzymes or microorganisms
    • D—TEXTILES; PAPER
    • D06—TREATMENT OF TEXTILES OR THE LIKE; LAUNDERING; FLEXIBLE MATERIALS NOT OTHERWISE PROVIDED FOR
    • D06M—TREATMENT, NOT PROVIDED FOR ELSEWHERE IN CLASS D06, OF FIBRES, THREADS, YARNS, FABRICS, FEATHERS OR FIBROUS GOODS MADE FROM SUCH MATERIALS
    • D06M2101/00—Chemical constitution of the fibres, threads, yarns, fabrics or fibrous goods made from such materials, to be treated
    • D06M2101/02—Natural fibres, other than mineral fibres
    • D06M2101/10—Animal fibres
    • D06M2101/12—Keratin fibres or silk
    • D—TEXTILES; PAPER
    • D06—TREATMENT OF TEXTILES OR THE LIKE; LAUNDERING; FLEXIBLE MATERIALS NOT OTHERWISE PROVIDED FOR
    • D06M—TREATMENT, NOT PROVIDED FOR ELSEWHERE IN CLASS D06, OF FIBRES, THREADS, YARNS, FABRICS, FEATHERS OR FIBROUS GOODS MADE FROM SUCH MATERIALS
    • D06M2200/00—Functionality of the treatment composition and/or properties imparted to the textile material
    • D06M2200/10—Repellency against liquids
    • D06M2200/12—Hydrophobic properties
    • D—TEXTILES; PAPER
    • D06—TREATMENT OF TEXTILES OR THE LIKE; LAUNDERING; FLEXIBLE MATERIALS NOT OTHERWISE PROVIDED FOR
    • D06M—TREATMENT, NOT PROVIDED FOR ELSEWHERE IN CLASS D06, OF FIBRES, THREADS, YARNS, FABRICS, FEATHERS OR FIBROUS GOODS MADE FROM SUCH MATERIALS
    • D06M2200/00—Functionality of the treatment composition and/or properties imparted to the textile material
    • D06M2200/45—Shrinking resistance, anti-felting properties

Abstract

The invention discloses a kind of antibacterial felt-proofing finishing method of wool cap, including：Wool cap is immersed in penetrating agent JFC aqueous solution, is added after ultrasound, drying in hydrogen peroxide, immersion, washing, dry must pre-process wool cap；Ethanol and acetic acid are mixed, add butyl titanate, adds silver fluoride and tetrabutyl ammonium fluoride, is washed after placing at room temperature to neutrality, is filtered, is dried to obtain material A；Salicylic acid and arginine are added to the water, material A is added, soaks at room temperature, filter, wash, be dried to obtain modified nano-titanium dioxide；Organosilicon quaternary ammonium salt, protease, chitosan, sodium metasilicate, lauryl sodium sulfate, modified nano-titanium dioxide, polycarbamouylsulfonate esters, catechin, sulfonic group beta cyclodextrin and coupling agent are added to the water, it is ultrasonic to obtain finishing agent；Pretreatment wool cap is immersed in finishing agent and is padded, cleans, dry, baking to obtain the wool cap of antibacterial feld proofing.

Description

A kind of antibacterial felt-proofing finishing method of wool cap
Technical field
The present invention relates to wool field of hat, more particularly to a kind of antibacterial felt-proofing finishing method of wool cap.
Background technology
Wool cap is prepared by raw material of wool, has the characteristics that cold-proof comfort, is favored by people.On the one hand, Wool is a kind of protein fibre, absorption bacterium and mould is easy to, on the other hand, due to the scale layer of wool surfaces so that Wool cap is in the solution repeatedly during extruding and kneading, and there are fiber, simultaneously, gap diminishes simultaneously between fiber for winding and felt mutually Tend to be close, it is impossible to which restorable felting phenomenon, influences a mao wearability for wool cap.
The content of the invention
Based on technical problem existing for background technology, the present invention proposes a kind of antibacterial feld proofing side of wool cap Method, its process is simple, and suitable for industrial production, the wool cap of preparation has excellent antibiotic property and felt proofing.
A kind of antibacterial felt-proofing finishing method of wool cap proposed by the present invention, comprises the following steps：
S1, by wool cap immerse penetrating agent JFC aqueous solution in, ultrasound, drying after add hydrogen peroxide in, at 40-55 DEG C Lower immersion 30-50min, washes, is dried to obtain pretreatment wool cap；
S2, mix ethanol and acetic acid, adds butyl titanate and stirs evenly, then adds silver fluoride and tetrabutyl fluorination Ammonium, washs to neutrality after placing 2-3 days at room temperature, filters, is dried to obtain material A；Salicylic acid and arginine are added to the water, stirred Material A is added after mixing uniformly, is soaked 3-5 days at room temperature, is filtered, washs, is dried to obtain modified nano-titanium dioxide；
S3, by organosilicon quaternary ammonium salt, protease, chitosan, sodium metasilicate, lauryl sodium sulfate, modified nano-silica Titanium, polycarbamouylsulfonate esters, catechin, sulfonic acid group-beta-cyclodextrin and coupling agent, which are added to the water, to stir evenly, at 60-70 DEG C Lower ultrasound 30-80min obtains finishing agent；
S4, will pad in the finishing agent that immerses in S3 of pretreatment wool cap in S1, then cleaned, dry, bake Obtain the wool cap of antibacterial feld proofing.
Preferably, in S1, the mass concentration of penetrating agent JFC is 1-1.8g/L in penetrating agent JFC aqueous solution.
Preferably, in S1, the ultrasound 10-20min at 30-45 DEG C.
Preferably, in S2, butyl titanate, ethanol, the volume ratio of acetic acid are 10-20：120-150：1-4.
Preferably, in S2, butyl titanate, silver fluoride, the mass ratio of tetrabutyl ammonium fluoride are 6-15：1-4：1-5.
Preferably, in S2, material A, salicylic acid, arginic weight ratio are 16-24：6-13：6-13.
Preferably, in the finishing agent of S3, the mass concentration of organosilicon quaternary ammonium salt is 30-50g/L, and the quality of protease is dense Spend for 10-35g/L, the mass concentration of chitosan is 25-50g/L, and the mass concentration of sodium metasilicate is 3-10g/L, dodecyl sulphur The mass concentration of sour sodium is 2-5g/L, and the mass concentration of modified nano-titanium dioxide is 30-50g/L, polycarbamouylsulfonate esters Mass concentration be 15-42g/L, the mass concentration of catechin is 10-35g/L, and the mass concentration of sulfonic acid group-beta-cyclodextrin is 30-47g/L, the mass concentration of coupling agent is 2-5g/L.
Preferably, in S3, described pad is rolled for two leachings two, bath raio 1：35-1：65, pick-up 75-80%.
Preferably, in S4, the temperature of drying is 60-80 DEG C.
Preferably, in S4, the temperature baked is 115-130 DEG C, and the time baked is 6-9min.
The antibacterial felt-proofing finishing method of wool cap of the present invention, wool cap is immersed in hydrogen peroxide and soaked by it, is reduced The felting ball density and area felting of wool fiber, assigns wool cap excellent felt proofing；Mixed in ethanol and acetic acid Close in liquid, using butyl titanate, silver fluoride and tetrabutyl ammonium fluoride as raw material, obtained fluorine-containing and silver-colored nano-titanium dioxide material A, after it is mixed with salicylic acid and arginine, salicylic acid and arginine stablize modification with chelating and bridged linkage respectively and arrive material The surface of A has obtained modified nano-titanium dioxide, and as the raw material of finishing agent, dispersiveness is more preferable in system, is being coupled It is crosslinked together with protease with carbamyl sulphonic acid ester under the action of agent, reduce protease and damaged caused by fiber strength Wound, while bacteria cell wall can be destroyed with organosilicon quaternary ammonium salt, chitosan, catechin, the cooperation of sulfonic acid group-beta-cyclodextrin, increase Add the permeability of bacteria cell wall, so that bacterium be killed, play the role of antibacterial, while assign wool cap excellent water repellent Property and felt proofing.
Embodiment
In the following, technical scheme is described in detail by specific embodiment.
Embodiment 1
A kind of antibacterial felt-proofing finishing method of wool cap proposed by the present invention, comprises the following steps：
S1, by wool cap immerse penetrating agent JFC aqueous solution in, ultrasound, drying after add hydrogen peroxide in, soaked at 55 DEG C 30min is steeped, washes, be dried to obtain pretreatment wool cap；
S2, mix ethanol and acetic acid, adds butyl titanate and stirs evenly, then adds silver fluoride and tetrabutyl fluorination Ammonium, washs to neutrality after placing 2 days at room temperature, filters, is dried to obtain material A；Salicylic acid and arginine are added to the water, stirred Material A is added after uniformly, is soaked 5 days at room temperature, is filtered, washs, is dried to obtain modified nano-titanium dioxide；
S3, by organosilicon quaternary ammonium salt, protease, chitosan, sodium metasilicate, lauryl sodium sulfate, modified nano-silica Titanium, polycarbamouylsulfonate esters, catechin, sulfonic acid group-beta-cyclodextrin and coupling agent, which are added to the water, to stir evenly, and surpasses at 60 DEG C Sound 80min obtains finishing agent；
S4, will pad in the finishing agent that immerses in S3 of pretreatment wool cap in S1, then cleaned, dry, bake Obtain the wool cap of antibacterial feld proofing.
Embodiment 2
A kind of antibacterial felt-proofing finishing method of wool cap proposed by the present invention, comprises the following steps：
S1, by wool cap immerse penetrating agent JFC aqueous solution in, ultrasound, drying after add hydrogen peroxide in, soaked at 40 DEG C 50min is steeped, washes, be dried to obtain pretreatment wool cap；
S2, mix ethanol and acetic acid, adds butyl titanate and stirs evenly, then adds silver fluoride and tetrabutyl fluorination Ammonium, washs to neutrality after placing 3 days at room temperature, filters, is dried to obtain material A；Salicylic acid and arginine are added to the water, stirred Material A is added after uniformly, is soaked 3 days at room temperature, is filtered, washs, is dried to obtain modified nano-titanium dioxide；
S3, by organosilicon quaternary ammonium salt, protease, chitosan, sodium metasilicate, lauryl sodium sulfate, modified nano-silica Titanium, polycarbamouylsulfonate esters, catechin, sulfonic acid group-beta-cyclodextrin and coupling agent, which are added to the water, to stir evenly, and surpasses at 70 DEG C Sound 30min obtains finishing agent；
S4, will pad in the finishing agent that immerses in S3 of pretreatment wool cap in S1, then cleaned, dry, bake Obtain the wool cap of antibacterial feld proofing.
Embodiment 3
A kind of antibacterial felt-proofing finishing method of wool cap proposed by the present invention, comprises the following steps：
S1, immerse wool cap in the penetrating agent JFC aqueous solution that mass concentration is 1.8g/L, ultrasonic at 30 DEG C 20min, adds in hydrogen peroxide after drying, soaks 45min at 43 DEG C, washes, is dried to obtain pretreatment wool cap；
S2, mix ethanol and acetic acid, adds butyl titanate and stirs evenly, wherein, butyl titanate, ethanol, the body of acetic acid Product is than being 10：150：1, silver fluoride and tetrabutyl ammonium fluoride are then added, wherein, butyl titanate, silver fluoride, tetrabutyl ammonium fluoride Mass ratio be 15：1：5, washed after placing 2 days at room temperature to neutrality, filter, be dried to obtain material A；By salicylic acid and smart ammonia Acid is added to the water, and is stirring evenly and then adding into material A, wherein, material A, salicylic acid, arginic weight ratio are 24：6：13, room temperature Lower immersion 3 days, filters, washs, is dried to obtain modified nano-titanium dioxide；
S3, by organosilicon quaternary ammonium salt, protease, chitosan, sodium metasilicate, lauryl sodium sulfate, modified nano-silica Titanium, polycarbamouylsulfonate esters, catechin, sulfonic acid group-beta-cyclodextrin and coupling agent, which are added to the water, to stir evenly, and surpasses at 67 DEG C Sound 38min obtains finishing agent；Wherein, in finishing agent, the mass concentration of organosilicon quaternary ammonium salt is 50g/L, the quality of protease Concentration is 10g/L, and the mass concentration of chitosan is 50g/L, and the mass concentration of sodium metasilicate is 3g/L, the matter of lauryl sodium sulfate Amount concentration is 5g/L, and the mass concentration of modified nano-titanium dioxide is 30g/L, and the mass concentration of polycarbamouylsulfonate esters is 42g/L, the mass concentration of catechin is 10g/L, and the mass concentration of sulfonic acid group-beta-cyclodextrin is 47g/L, and the quality of coupling agent is dense Spend for 2g/L；
S4, two roll two leachings in finishing agent that the pretreatment wool cap in S1 is immersed in S3, bath raio 1：35, pick-up For 80%, then clean, dried at 60 DEG C, 6min is baked at 130 DEG C and obtains the wool cap of antibacterial feld proofing.
Embodiment 4
A kind of antibacterial felt-proofing finishing method of wool cap proposed by the present invention, comprises the following steps：
S1, by wool cap immerse mass concentration be 1g/L penetrating agent JFC aqueous solution in, the ultrasound 10min at 45 DEG C, Added after drying in hydrogen peroxide, soak 38min at 52 DEG C, washed, be dried to obtain pretreatment wool cap；
S2, mix ethanol and acetic acid, adds butyl titanate and stirs evenly, wherein, butyl titanate, ethanol, the body of acetic acid Product is than being 20：120：4, silver fluoride and tetrabutyl ammonium fluoride are then added, wherein, butyl titanate, silver fluoride, tetrabutyl ammonium fluoride Mass ratio be 6：4：1, washed after placing 3 days at room temperature to neutrality, filter, be dried to obtain material A；By salicylic acid and arginine It is added to the water, is stirring evenly and then adding into material A, wherein, material A, salicylic acid, arginic weight ratio are 16：13：6, at room temperature Immersion 5 days, filters, washs, is dried to obtain modified nano-titanium dioxide；
S3, by organosilicon quaternary ammonium salt, protease, chitosan, sodium metasilicate, lauryl sodium sulfate, modified nano-silica Titanium, polycarbamouylsulfonate esters, catechin, sulfonic acid group-beta-cyclodextrin and coupling agent, which are added to the water, to stir evenly, and surpasses at 63 DEG C Sound 70min obtains finishing agent；Wherein, in finishing agent, the mass concentration of organosilicon quaternary ammonium salt is 30g/L, the quality of protease Concentration is 35g/L, and the mass concentration of chitosan is 25g/L, and the mass concentration of sodium metasilicate is 10g/L, lauryl sodium sulfate Mass concentration is 2g/L, and the mass concentration of modified nano-titanium dioxide is 50g/L, and the mass concentration of polycarbamouylsulfonate esters is 15g/L, the mass concentration of catechin is 35g/L, and the mass concentration of sulfonic acid group-beta-cyclodextrin is 30g/L, and the quality of coupling agent is dense Spend for 5g/L；
S4, two roll two leachings in finishing agent that the pretreatment wool cap in S1 is immersed in S3, bath raio 1：65, pick-up For 75%, then clean, dried at 80 DEG C, 9min is baked at 115 DEG C and obtains the wool cap of antibacterial feld proofing.
Embodiment 5
A kind of antibacterial felt-proofing finishing method of wool cap proposed by the present invention, comprises the following steps：
S1, immerse wool cap in the penetrating agent JFC aqueous solution that mass concentration is 1.5g/L, ultrasonic at 40 DEG C 15min, adds in hydrogen peroxide after drying, soaks 40min at 50 DEG C, washes, is dried to obtain pretreatment wool cap；
S2, mix ethanol and acetic acid, adds butyl titanate and stirs evenly, wherein, butyl titanate, ethanol, the body of acetic acid Product is than being 15：135：3, silver fluoride and tetrabutyl ammonium fluoride are then added, wherein, butyl titanate, silver fluoride, tetrabutyl ammonium fluoride Mass ratio be 11：3：4, washed after placing 2.5 days at room temperature to neutrality, filter, be dried to obtain material A；By salicylic acid and essence Propylhomoserin is added to the water, and is stirring evenly and then adding into material A, wherein, material A, salicylic acid, arginic weight ratio are 20：11：9, room The lower immersion of temperature 4 days, filters, washs, is dried to obtain modified nano-titanium dioxide；
S3, by organosilicon quaternary ammonium salt, protease, chitosan, sodium metasilicate, lauryl sodium sulfate, modified nano-silica Titanium, polycarbamouylsulfonate esters, catechin, sulfonic acid group-beta-cyclodextrin and coupling agent, which are added to the water, to stir evenly, and surpasses at 65 DEG C Sound 50min obtains finishing agent；Wherein, in finishing agent, the mass concentration of organosilicon quaternary ammonium salt is 40g/L, the quality of protease Concentration is 21g/L, and the mass concentration of chitosan is 38g/L, and the mass concentration of sodium metasilicate is 7g/L, the matter of lauryl sodium sulfate Amount concentration is 3g/L, and the mass concentration of modified nano-titanium dioxide is 40g/L, and the mass concentration of polycarbamouylsulfonate esters is 25g/L, the mass concentration of catechin is 22g/L, and the mass concentration of sulfonic acid group-beta-cyclodextrin is 36g/L, and the quality of coupling agent is dense Spend for 3.5g/L；
S4, two roll two leachings in finishing agent that the pretreatment wool cap in S1 is immersed in S3, bath raio 1：45, pick-up For 78%, then clean, dried at 70 DEG C, 8min is baked at 125 DEG C and obtains the wool cap of antibacterial feld proofing.
The foregoing is only a preferred embodiment of the present invention, but protection scope of the present invention be not limited thereto, Any one skilled in the art the invention discloses technical scope in, technique according to the invention scheme and its Inventive concept is subject to equivalent substitution or change, should be covered by the protection scope of the present invention.

Claims (10)

1. a kind of antibacterial felt-proofing finishing method of wool cap, it is characterised in that comprise the following steps：
S1, by wool cap immerse penetrating agent JFC aqueous solution in, ultrasound, drying after add hydrogen peroxide in, soaked at 40-55 DEG C 30-50min is steeped, washes, be dried to obtain pretreatment wool cap；
S2, mix ethanol and acetic acid, adds butyl titanate and stirs evenly, then adds silver fluoride and tetrabutyl ammonium fluoride, room Temperature lower placement is washed to neutrality after 2-3 days, is filtered, is dried to obtain material A；Salicylic acid and arginine are added to the water, stirring is equal Material A is added after even, is soaked 3-5 days at room temperature, is filtered, washs, is dried to obtain modified nano-titanium dioxide；
S3, by organosilicon quaternary ammonium salt, protease, chitosan, sodium metasilicate, lauryl sodium sulfate, modified nano-titanium dioxide, poly- Carbamyl sulphonic acid ester, catechin, sulfonic acid group-beta-cyclodextrin and coupling agent, which are added to the water, to stir evenly, ultrasonic at 60-70 DEG C 30-80min obtains finishing agent；
S4, will pad in the finishing agent that immerses in S3 of pretreatment wool cap in S1, then cleaned, dry, bake to obtain The wool cap of antibacterial feld proofing.
2. the antibacterial felt-proofing finishing method of wool cap according to claim 1, it is characterised in that in S1, bleeding agent The mass concentration of penetrating agent JFC is 1-1.8g/L in JFC aqueous solutions.
3. the antibacterial felt-proofing finishing method of wool cap according to claim 1 or claim 2, it is characterised in that in S1, Ultrasound 10-20min at 30-45 DEG C.
4. according to the antibacterial felt-proofing finishing method of wool cap any one of claim 1-3, it is characterised in that in S2 In, butyl titanate, ethanol, the volume ratio of acetic acid are 10-20：120-150：1-4.
5. according to the antibacterial felt-proofing finishing method of wool cap any one of claim 1-4, it is characterised in that in S2 In, butyl titanate, silver fluoride, the mass ratio of tetrabutyl ammonium fluoride are 6-15：1-4：1-5.
6. according to the antibacterial felt-proofing finishing method of wool cap any one of claim 1-5, it is characterised in that in S2 In, material A, salicylic acid, arginic weight ratio are 16-24：6-13：6-13.
7. according to the antibacterial felt-proofing finishing method of wool cap any one of claim 1-6, it is characterised in that in S3 Finishing agent in, the mass concentration of organosilicon quaternary ammonium salt is 30-50g/L, and the mass concentration of protease is 10-35g/L, chitosan Mass concentration be 25-50g/L, the mass concentration of sodium metasilicate is 3-10g/L, and the mass concentration of lauryl sodium sulfate is 2- 5g/L, the mass concentration of modified nano-titanium dioxide is 30-50g/L, and the mass concentration of polycarbamouylsulfonate esters is 15-42g/ L, the mass concentration of catechin are 10-35g/L, and the mass concentration of sulfonic acid group-beta-cyclodextrin is 30-47g/L, the quality of coupling agent Concentration is 2-5g/L.
8. according to the antibacterial felt-proofing finishing method of wool cap any one of claim 1-7, it is characterised in that in S3 In, described pad is rolled for two leachings two, bath raio 1：35-1：65, pick-up 75-80%.
9. according to the antibacterial felt-proofing finishing method of wool cap any one of claim 1-8, it is characterised in that in S4 In, the temperature of drying is 60-80 DEG C.
10. according to the antibacterial felt-proofing finishing method of wool cap any one of claim 1-9, it is characterised in that In S4, the temperature baked is 115-130 DEG C, and the time baked is 6-9min.
CN201711235488.6A 2017-11-30 2017-11-30 A kind of antibacterial felt-proofing finishing method of wool cap Withdrawn CN107956106A (en)

Priority Applications (1)

Application Number Priority Date Filing Date Title
CN201711235488.6A CN107956106A (en) 2017-11-30 2017-11-30 A kind of antibacterial felt-proofing finishing method of wool cap

Applications Claiming Priority (1)

Application Number Priority Date Filing Date Title
CN201711235488.6A CN107956106A (en) 2017-11-30 2017-11-30 A kind of antibacterial felt-proofing finishing method of wool cap

Publications (1)

Publication Number Publication Date
CN107956106A true CN107956106A (en) 2018-04-24

Family

ID=61959624

Family Applications (1)

Application Number Title Priority Date Filing Date
CN201711235488.6A Withdrawn CN107956106A (en) 2017-11-30 2017-11-30 A kind of antibacterial felt-proofing finishing method of wool cap

Country Status (1)

Country Link
CN (1) CN107956106A (en)

Cited By (1)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
CN112609456A (en) * 2020-11-28 2021-04-06 无锡市丹怡纺织品有限公司 Preparation method of felt-shrinkage-resistant woolen overcoat

Citations (6)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
CN104611935A (en) * 2015-02-03 2015-05-13 湖州市菱湖重兆金辉丝织厂 Felt proofing method for wool fabrics
CN104631117A (en) * 2015-02-03 2015-05-20 湖州市菱湖重兆金辉丝织厂 Antibiotic finishing method of wool fabric
CN104629615A (en) * 2015-02-26 2015-05-20 河南科技大学 UV varnish for coating surface of wood board product and coating method of UV varnish
CN105544198A (en) * 2016-01-25 2016-05-04 苏州印丝特纺织数码科技有限公司 Antibacterial and anti-felting wool fabric finishing method
CN105568665A (en) * 2015-12-30 2016-05-11 江阴市长泾花园毛纺织有限公司 Production method of dirt repelling and felting resisting wool fabric
CN106758259A (en) * 2017-01-17 2017-05-31 常熟市新光毛条处理有限公司 A kind of wool tops is without chlorine shiinkproof finish technique

Patent Citations (6)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
CN104611935A (en) * 2015-02-03 2015-05-13 湖州市菱湖重兆金辉丝织厂 Felt proofing method for wool fabrics
CN104631117A (en) * 2015-02-03 2015-05-20 湖州市菱湖重兆金辉丝织厂 Antibiotic finishing method of wool fabric
CN104629615A (en) * 2015-02-26 2015-05-20 河南科技大学 UV varnish for coating surface of wood board product and coating method of UV varnish
CN105568665A (en) * 2015-12-30 2016-05-11 江阴市长泾花园毛纺织有限公司 Production method of dirt repelling and felting resisting wool fabric
CN105544198A (en) * 2016-01-25 2016-05-04 苏州印丝特纺织数码科技有限公司 Antibacterial and anti-felting wool fabric finishing method
CN106758259A (en) * 2017-01-17 2017-05-31 常熟市新光毛条处理有限公司 A kind of wool tops is without chlorine shiinkproof finish technique

Cited By (1)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
CN112609456A (en) * 2020-11-28 2021-04-06 无锡市丹怡纺织品有限公司 Preparation method of felt-shrinkage-resistant woolen overcoat

Similar Documents

Publication Publication Date Title
CN102002854A (en) Multifunctional textile finishing agent, preparation method thereof and cotton textile finishing method
CN103882724A (en) Method for processing fabric by utilizing silver-loaded chitosan antibacterial agent
CN107858458A (en) A kind of processing technology of cow leather
CN108977977A (en) Hospital gauze preparation method with bacteriostasis
CN109252356A (en) A kind of fiber gauze production technology of high intensity
CN107956106A (en) A kind of antibacterial felt-proofing finishing method of wool cap
CN110549696B (en) Hyaluronic acid-based skin-friendly cloth and preparation method thereof
KR101742025B1 (en) An antibacterial towel and manufacturing method thereof
CN103485173A (en) Chitosan quaternary ammonium salt antibacterial-finishing process for fabric
CN114181425B (en) Flame-retardant, antibacterial and mildewproof cellulose-based foam material as well as preparation method and application thereof
CN102677468B (en) Method for increasing weight and bulkiness of silk floss
CN108744010A (en) A kind of preparation method of medical modified polypropene adhesive-bonded fabric dressing
CN111020713A (en) Production process of jute palm
CN107177986A (en) A kind of method for carrying out feld proofing to wool fabric using modified protein enzyme
CN105421041A (en) Method for producing washable antibacterial pure cotton cloth
CN107938342A (en) A kind of finishing technique of wool cap
CN103061137B (en) Raw cashmere washing auxiliary and raw cashmere washing method
CN108560268A (en) The fulling process of woollen sweater
DE60122861T2 (en) TREATMENT OF TEXTILES
KR102647897B1 (en) Eco-friendly fabric dyeing method
CN109337769A (en) A kind of natural environmental-protective kitchen cleaning agent and preparation method thereof
CN110835852A (en) High-whiteness grey cloth finishing process
CN110820314A (en) High-stability gray fabric finishing process
CN107217465A (en) Fabric printing pre-treating method
CN117758454A (en) Production process of curtain cloth with fireproof and flame-retardant functions

Legal Events

Date Code Title Description
PB01 Publication
PB01 Publication
SE01 Entry into force of request for substantive examination
SE01 Entry into force of request for substantive examination
WW01 Invention patent application withdrawn after publication

Application publication date: 20180424

WW01 Invention patent application withdrawn after publication