CN107938342A - A kind of finishing technique of wool cap - Google Patents
A kind of finishing technique of wool cap Download PDFInfo
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- CN107938342A CN107938342A CN201711236348.0A CN201711236348A CN107938342A CN 107938342 A CN107938342 A CN 107938342A CN 201711236348 A CN201711236348 A CN 201711236348A CN 107938342 A CN107938342 A CN 107938342A
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- CN
- China
- Prior art keywords
- wool cap
- cap
- wool
- added
- finishing technique
- Prior art date
- Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
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- 210000002268 wool Anatomy 0.000 title claims abstract description 88
- 238000000034 method Methods 0.000 title claims abstract description 24
- QTBSBXVTEAMEQO-UHFFFAOYSA-N Acetic acid Chemical compound CC(O)=O QTBSBXVTEAMEQO-UHFFFAOYSA-N 0.000 claims abstract description 42
- XLYOFNOQVPJJNP-UHFFFAOYSA-N water Substances O XLYOFNOQVPJJNP-UHFFFAOYSA-N 0.000 claims abstract description 31
- YGSDEFSMJLZEOE-UHFFFAOYSA-N salicylic acid Chemical compound OC(=O)C1=CC=CC=C1O YGSDEFSMJLZEOE-UHFFFAOYSA-N 0.000 claims abstract description 30
- LFQSCWFLJHTTHZ-UHFFFAOYSA-N Ethanol Chemical compound CCO LFQSCWFLJHTTHZ-UHFFFAOYSA-N 0.000 claims abstract description 28
- 238000011282 treatment Methods 0.000 claims abstract description 27
- XLOMVQKBTHCTTD-UHFFFAOYSA-N Zinc monoxide Chemical compound [Zn]=O XLOMVQKBTHCTTD-UHFFFAOYSA-N 0.000 claims abstract description 26
- SOQBVABWOPYFQZ-UHFFFAOYSA-N oxygen(2-);titanium(4+) Chemical class [O-2].[O-2].[Ti+4] SOQBVABWOPYFQZ-UHFFFAOYSA-N 0.000 claims abstract description 22
- FPGGTKZVZWFYPV-UHFFFAOYSA-M tetrabutylammonium fluoride Chemical compound [F-].CCCC[N+](CCCC)(CCCC)CCCC FPGGTKZVZWFYPV-UHFFFAOYSA-M 0.000 claims abstract description 22
- 239000000463 material Substances 0.000 claims abstract description 20
- FPCJKVGGYOAWIZ-UHFFFAOYSA-N butan-1-ol;titanium Chemical compound [Ti].CCCCO.CCCCO.CCCCO.CCCCO FPCJKVGGYOAWIZ-UHFFFAOYSA-N 0.000 claims abstract description 17
- 239000003795 chemical substances by application Substances 0.000 claims abstract description 17
- 229920001661 Chitosan Polymers 0.000 claims abstract description 15
- FJKROLUGYXJWQN-UHFFFAOYSA-N papa-hydroxy-benzoic acid Natural products OC(=O)C1=CC=C(O)C=C1 FJKROLUGYXJWQN-UHFFFAOYSA-N 0.000 claims abstract description 15
- 229960004889 salicylic acid Drugs 0.000 claims abstract description 15
- 229920000858 Cyclodextrin Polymers 0.000 claims abstract description 14
- 239000001116 FEMA 4028 Substances 0.000 claims abstract description 14
- ZSTLPJLUQNQBDQ-UHFFFAOYSA-N azanylidyne(dihydroxy)-$l^{5}-phosphane Chemical compound OP(O)#N ZSTLPJLUQNQBDQ-UHFFFAOYSA-N 0.000 claims abstract description 14
- 229960004853 betadex Drugs 0.000 claims abstract description 14
- ADRVNXBAWSRFAJ-UHFFFAOYSA-N catechin Natural products OC1Cc2cc(O)cc(O)c2OC1c3ccc(O)c(O)c3 ADRVNXBAWSRFAJ-UHFFFAOYSA-N 0.000 claims abstract description 14
- 235000005487 catechin Nutrition 0.000 claims abstract description 14
- 229950001002 cianidanol Drugs 0.000 claims abstract description 14
- 229940096017 silver fluoride Drugs 0.000 claims abstract description 14
- REYHXKZHIMGNSE-UHFFFAOYSA-M silver monofluoride Chemical compound [F-].[Ag+] REYHXKZHIMGNSE-UHFFFAOYSA-M 0.000 claims abstract description 14
- PFTAWBLQPZVEMU-DZGCQCFKSA-N (+)-catechin Chemical compound C1([C@H]2OC3=CC(O)=CC(O)=C3C[C@@H]2O)=CC=C(O)C(O)=C1 PFTAWBLQPZVEMU-DZGCQCFKSA-N 0.000 claims abstract description 13
- RCEAADKTGXTDOA-UHFFFAOYSA-N OS(O)(=O)=O.CCCCCCCCCCCC[Na] Chemical compound OS(O)(=O)=O.CCCCCCCCCCCC[Na] RCEAADKTGXTDOA-UHFFFAOYSA-N 0.000 claims abstract description 13
- VYPSYNLAJGMNEJ-UHFFFAOYSA-N Silicium dioxide Chemical compound O=[Si]=O VYPSYNLAJGMNEJ-UHFFFAOYSA-N 0.000 claims abstract description 13
- 239000004115 Sodium Silicate Substances 0.000 claims abstract description 13
- 239000007822 coupling agent Substances 0.000 claims abstract description 13
- ZDXPYRJPNDTMRX-UHFFFAOYSA-N glutamine Natural products OC(=O)C(N)CCC(N)=O ZDXPYRJPNDTMRX-UHFFFAOYSA-N 0.000 claims abstract description 13
- 235000019795 sodium metasilicate Nutrition 0.000 claims abstract description 13
- NTHWMYGWWRZVTN-UHFFFAOYSA-N sodium silicate Chemical compound [Na+].[Na+].[O-][Si]([O-])=O NTHWMYGWWRZVTN-UHFFFAOYSA-N 0.000 claims abstract description 13
- 229910052911 sodium silicate Inorganic materials 0.000 claims abstract description 13
- 239000011787 zinc oxide Substances 0.000 claims abstract description 13
- ZDXPYRJPNDTMRX-VKHMYHEASA-N L-glutamine Chemical compound OC(=O)[C@@H](N)CCC(N)=O ZDXPYRJPNDTMRX-VKHMYHEASA-N 0.000 claims abstract description 12
- 239000004475 Arginine Substances 0.000 claims abstract description 9
- ODKSFYDXXFIFQN-BYPYZUCNSA-P L-argininium(2+) Chemical compound NC(=[NH2+])NCCC[C@H]([NH3+])C(O)=O ODKSFYDXXFIFQN-BYPYZUCNSA-P 0.000 claims abstract description 9
- ODKSFYDXXFIFQN-UHFFFAOYSA-N arginine Natural products OC(=O)C(N)CCCNC(N)=N ODKSFYDXXFIFQN-UHFFFAOYSA-N 0.000 claims abstract description 9
- 239000004342 Benzoyl peroxide Substances 0.000 claims abstract description 8
- OMPJBNCRMGITSC-UHFFFAOYSA-N Benzoylperoxide Chemical compound C=1C=CC=CC=1C(=O)OOC(=O)C1=CC=CC=C1 OMPJBNCRMGITSC-UHFFFAOYSA-N 0.000 claims abstract description 8
- 235000019400 benzoyl peroxide Nutrition 0.000 claims abstract description 8
- YVNRUPSDZZZUQJ-UHFFFAOYSA-N [O].NC1=CC=CC=C1 Chemical group [O].NC1=CC=CC=C1 YVNRUPSDZZZUQJ-UHFFFAOYSA-N 0.000 claims abstract description 5
- 238000003756 stirring Methods 0.000 claims description 23
- 239000003995 emulsifying agent Substances 0.000 claims description 22
- 238000002604 ultrasonography Methods 0.000 claims description 15
- BLRPTPMANUNPDV-UHFFFAOYSA-N Silane Chemical compound [SiH4] BLRPTPMANUNPDV-UHFFFAOYSA-N 0.000 claims description 14
- 239000003153 chemical reaction reagent Substances 0.000 claims description 14
- 230000008878 coupling Effects 0.000 claims description 14
- 238000010168 coupling process Methods 0.000 claims description 14
- 238000005859 coupling reaction Methods 0.000 claims description 14
- 229910000077 silane Inorganic materials 0.000 claims description 14
- LSNNMFCWUKXFEE-UHFFFAOYSA-M Bisulfite Chemical group OS([O-])=O LSNNMFCWUKXFEE-UHFFFAOYSA-M 0.000 claims description 13
- 239000007864 aqueous solution Substances 0.000 claims description 13
- 238000001035 drying Methods 0.000 claims description 13
- 239000000203 mixture Substances 0.000 claims description 13
- 238000002386 leaching Methods 0.000 claims description 9
- 238000010792 warming Methods 0.000 claims description 7
- 238000006243 chemical reaction Methods 0.000 claims description 6
- 230000004048 modification Effects 0.000 claims description 6
- 238000012986 modification Methods 0.000 claims description 6
- PAYRUJLWNCNPSJ-UHFFFAOYSA-N Aniline Chemical compound NC1=CC=CC=C1 PAYRUJLWNCNPSJ-UHFFFAOYSA-N 0.000 claims description 3
- 239000002253 acid Substances 0.000 claims description 3
- 230000008859 change Effects 0.000 claims description 3
- 150000002148 esters Chemical class 0.000 claims description 3
- 238000002156 mixing Methods 0.000 claims description 3
- XUIMIQQOPSSXEZ-UHFFFAOYSA-N Silicon Chemical compound [Si] XUIMIQQOPSSXEZ-UHFFFAOYSA-N 0.000 claims 1
- 125000003236 benzoyl group Chemical group [H]C1=C([H])C([H])=C(C([H])=C1[H])C(*)=O 0.000 claims 1
- 150000002978 peroxides Chemical class 0.000 claims 1
- 229910052710 silicon Inorganic materials 0.000 claims 1
- 239000010703 silicon Substances 0.000 claims 1
- 239000006087 Silane Coupling Agent Substances 0.000 abstract 1
- WHGYBXFWUBPSRW-FOUAGVGXSA-N beta-cyclodextrin Chemical compound OC[C@H]([C@H]([C@@H]([C@H]1O)O)O[C@H]2O[C@@H]([C@@H](O[C@H]3O[C@H](CO)[C@H]([C@@H]([C@H]3O)O)O[C@H]3O[C@H](CO)[C@H]([C@@H]([C@H]3O)O)O[C@H]3O[C@H](CO)[C@H]([C@@H]([C@H]3O)O)O[C@H]3O[C@H](CO)[C@H]([C@@H]([C@H]3O)O)O3)[C@H](O)[C@H]2O)CO)O[C@@H]1O[C@H]1[C@H](O)[C@@H](O)[C@@H]3O[C@@H]1CO WHGYBXFWUBPSRW-FOUAGVGXSA-N 0.000 abstract 1
- 235000011175 beta-cyclodextrine Nutrition 0.000 abstract 1
- 238000010438 heat treatment Methods 0.000 abstract 1
- 238000002791 soaking Methods 0.000 abstract 1
- -1 4- amino Phenoxy Chemical group 0.000 description 7
- CHIHQLCVLOXUJW-UHFFFAOYSA-N benzoic anhydride Chemical compound C=1C=CC=CC=1C(=O)OC(=O)C1=CC=CC=C1 CHIHQLCVLOXUJW-UHFFFAOYSA-N 0.000 description 5
- 239000000835 fiber Substances 0.000 description 5
- QGZKDVFQNNGYKY-UHFFFAOYSA-N Ammonia Chemical compound N QGZKDVFQNNGYKY-UHFFFAOYSA-N 0.000 description 4
- 230000003115 biocidal effect Effects 0.000 description 4
- 238000004546 feltproofing Methods 0.000 description 4
- 239000003063 flame retardant Substances 0.000 description 4
- QGZKDVFQNNGYKY-UHFFFAOYSA-O Ammonium Chemical compound [NH4+] QGZKDVFQNNGYKY-UHFFFAOYSA-O 0.000 description 3
- 238000004140 cleaning Methods 0.000 description 3
- 238000003682 fluorination reaction Methods 0.000 description 3
- 238000007654 immersion Methods 0.000 description 3
- 239000002994 raw material Substances 0.000 description 3
- 239000012257 stirred material Substances 0.000 description 3
- IJGRMHOSHXDMSA-UHFFFAOYSA-N Atomic nitrogen Chemical compound N#N IJGRMHOSHXDMSA-UHFFFAOYSA-N 0.000 description 2
- 102000003929 Transaminases Human genes 0.000 description 2
- 108090000340 Transaminases Proteins 0.000 description 2
- 229910021529 ammonia Inorganic materials 0.000 description 2
- 229960003121 arginine Drugs 0.000 description 2
- 238000005516 engineering process Methods 0.000 description 2
- RNFJDJUURJAICM-UHFFFAOYSA-N 2,2,4,4,6,6-hexaphenoxy-1,3,5-triaza-2$l^{5},4$l^{5},6$l^{5}-triphosphacyclohexa-1,3,5-triene Chemical compound N=1P(OC=2C=CC=CC=2)(OC=2C=CC=CC=2)=NP(OC=2C=CC=CC=2)(OC=2C=CC=CC=2)=NP=1(OC=1C=CC=CC=1)OC1=CC=CC=C1 RNFJDJUURJAICM-UHFFFAOYSA-N 0.000 description 1
- 241000894006 Bacteria Species 0.000 description 1
- 230000009471 action Effects 0.000 description 1
- 150000001408 amides Chemical class 0.000 description 1
- 150000001412 amines Chemical class 0.000 description 1
- 230000000844 anti-bacterial effect Effects 0.000 description 1
- PFTAWBLQPZVEMU-UHFFFAOYSA-N catechin Chemical compound OC1CC2=C(O)C=C(O)C=C2OC1C1=CC=C(O)C(O)=C1 PFTAWBLQPZVEMU-UHFFFAOYSA-N 0.000 description 1
- 238000009950 felting Methods 0.000 description 1
- 229910052731 fluorine Inorganic materials 0.000 description 1
- 239000011737 fluorine Substances 0.000 description 1
- 125000001153 fluoro group Chemical group F* 0.000 description 1
- 230000036541 health Effects 0.000 description 1
- 239000012535 impurity Substances 0.000 description 1
- 238000009776 industrial production Methods 0.000 description 1
- 238000004898 kneading Methods 0.000 description 1
- 229910052757 nitrogen Inorganic materials 0.000 description 1
- 238000006116 polymerization reaction Methods 0.000 description 1
- 238000002360 preparation method Methods 0.000 description 1
- 238000002203 pretreatment Methods 0.000 description 1
- 230000008569 process Effects 0.000 description 1
- 102000004169 proteins and genes Human genes 0.000 description 1
- 108090000623 proteins and genes Proteins 0.000 description 1
- 229910052709 silver Inorganic materials 0.000 description 1
- 239000004332 silver Substances 0.000 description 1
- 239000000243 solution Substances 0.000 description 1
- 239000000126 substance Substances 0.000 description 1
- 238000006467 substitution reaction Methods 0.000 description 1
- 238000004804 winding Methods 0.000 description 1
- RNWHGQJWIACOKP-UHFFFAOYSA-N zinc;oxygen(2-) Chemical class [O-2].[Zn+2] RNWHGQJWIACOKP-UHFFFAOYSA-N 0.000 description 1
Classifications
-
- D—TEXTILES; PAPER
- D06—TREATMENT OF TEXTILES OR THE LIKE; LAUNDERING; FLEXIBLE MATERIALS NOT OTHERWISE PROVIDED FOR
- D06M—TREATMENT, NOT PROVIDED FOR ELSEWHERE IN CLASS D06, OF FIBRES, THREADS, YARNS, FABRICS, FEATHERS OR FIBROUS GOODS MADE FROM SUCH MATERIALS
- D06M14/00—Graft polymerisation of monomers containing carbon-to-carbon unsaturated bonds on to fibres, threads, yarns, fabrics, or fibrous goods made from such materials
- D06M14/02—Graft polymerisation of monomers containing carbon-to-carbon unsaturated bonds on to fibres, threads, yarns, fabrics, or fibrous goods made from such materials on to materials of natural origin
- D06M14/06—Graft polymerisation of monomers containing carbon-to-carbon unsaturated bonds on to fibres, threads, yarns, fabrics, or fibrous goods made from such materials on to materials of natural origin of animal origin, e.g. wool or silk
-
- D—TEXTILES; PAPER
- D06—TREATMENT OF TEXTILES OR THE LIKE; LAUNDERING; FLEXIBLE MATERIALS NOT OTHERWISE PROVIDED FOR
- D06M—TREATMENT, NOT PROVIDED FOR ELSEWHERE IN CLASS D06, OF FIBRES, THREADS, YARNS, FABRICS, FEATHERS OR FIBROUS GOODS MADE FROM SUCH MATERIALS
- D06M11/00—Treating fibres, threads, yarns, fabrics or fibrous goods made from such materials, with inorganic substances or complexes thereof; Such treatment combined with mechanical treatment, e.g. mercerising
- D06M11/32—Treating fibres, threads, yarns, fabrics or fibrous goods made from such materials, with inorganic substances or complexes thereof; Such treatment combined with mechanical treatment, e.g. mercerising with oxygen, ozone, ozonides, oxides, hydroxides or percompounds; Salts derived from anions with an amphoteric element-oxygen bond
- D06M11/36—Treating fibres, threads, yarns, fabrics or fibrous goods made from such materials, with inorganic substances or complexes thereof; Such treatment combined with mechanical treatment, e.g. mercerising with oxygen, ozone, ozonides, oxides, hydroxides or percompounds; Salts derived from anions with an amphoteric element-oxygen bond with oxides, hydroxides or mixed oxides; with salts derived from anions with an amphoteric element-oxygen bond
- D06M11/46—Oxides or hydroxides of elements of Groups 4 or 14 of the Periodic Table; Titanates; Zirconates; Stannates; Plumbates
-
- D—TEXTILES; PAPER
- D06—TREATMENT OF TEXTILES OR THE LIKE; LAUNDERING; FLEXIBLE MATERIALS NOT OTHERWISE PROVIDED FOR
- D06M—TREATMENT, NOT PROVIDED FOR ELSEWHERE IN CLASS D06, OF FIBRES, THREADS, YARNS, FABRICS, FEATHERS OR FIBROUS GOODS MADE FROM SUCH MATERIALS
- D06M11/00—Treating fibres, threads, yarns, fabrics or fibrous goods made from such materials, with inorganic substances or complexes thereof; Such treatment combined with mechanical treatment, e.g. mercerising
- D06M11/77—Treating fibres, threads, yarns, fabrics or fibrous goods made from such materials, with inorganic substances or complexes thereof; Such treatment combined with mechanical treatment, e.g. mercerising with silicon or compounds thereof
- D06M11/79—Treating fibres, threads, yarns, fabrics or fibrous goods made from such materials, with inorganic substances or complexes thereof; Such treatment combined with mechanical treatment, e.g. mercerising with silicon or compounds thereof with silicon dioxide, silicic acids or their salts
-
- D—TEXTILES; PAPER
- D06—TREATMENT OF TEXTILES OR THE LIKE; LAUNDERING; FLEXIBLE MATERIALS NOT OTHERWISE PROVIDED FOR
- D06M—TREATMENT, NOT PROVIDED FOR ELSEWHERE IN CLASS D06, OF FIBRES, THREADS, YARNS, FABRICS, FEATHERS OR FIBROUS GOODS MADE FROM SUCH MATERIALS
- D06M13/00—Treating fibres, threads, yarns, fabrics or fibrous goods made from such materials, with non-macromolecular organic compounds; Such treatment combined with mechanical treatment
- D06M13/322—Treating fibres, threads, yarns, fabrics or fibrous goods made from such materials, with non-macromolecular organic compounds; Such treatment combined with mechanical treatment with compounds containing nitrogen
- D06M13/44—Treating fibres, threads, yarns, fabrics or fibrous goods made from such materials, with non-macromolecular organic compounds; Such treatment combined with mechanical treatment with compounds containing nitrogen containing nitrogen and phosphorus
-
- D—TEXTILES; PAPER
- D06—TREATMENT OF TEXTILES OR THE LIKE; LAUNDERING; FLEXIBLE MATERIALS NOT OTHERWISE PROVIDED FOR
- D06M—TREATMENT, NOT PROVIDED FOR ELSEWHERE IN CLASS D06, OF FIBRES, THREADS, YARNS, FABRICS, FEATHERS OR FIBROUS GOODS MADE FROM SUCH MATERIALS
- D06M15/00—Treating fibres, threads, yarns, fabrics, or fibrous goods made from such materials, with macromolecular compounds; Such treatment combined with mechanical treatment
- D06M15/01—Treating fibres, threads, yarns, fabrics, or fibrous goods made from such materials, with macromolecular compounds; Such treatment combined with mechanical treatment with natural macromolecular compounds or derivatives thereof
- D06M15/03—Polysaccharides or derivatives thereof
-
- D—TEXTILES; PAPER
- D06—TREATMENT OF TEXTILES OR THE LIKE; LAUNDERING; FLEXIBLE MATERIALS NOT OTHERWISE PROVIDED FOR
- D06M—TREATMENT, NOT PROVIDED FOR ELSEWHERE IN CLASS D06, OF FIBRES, THREADS, YARNS, FABRICS, FEATHERS OR FIBROUS GOODS MADE FROM SUCH MATERIALS
- D06M16/00—Biochemical treatment of fibres, threads, yarns, fabrics, or fibrous goods made from such materials, e.g. enzymatic
- D06M16/003—Biochemical treatment of fibres, threads, yarns, fabrics, or fibrous goods made from such materials, e.g. enzymatic with enzymes or microorganisms
-
- D—TEXTILES; PAPER
- D06—TREATMENT OF TEXTILES OR THE LIKE; LAUNDERING; FLEXIBLE MATERIALS NOT OTHERWISE PROVIDED FOR
- D06M—TREATMENT, NOT PROVIDED FOR ELSEWHERE IN CLASS D06, OF FIBRES, THREADS, YARNS, FABRICS, FEATHERS OR FIBROUS GOODS MADE FROM SUCH MATERIALS
- D06M2101/00—Chemical constitution of the fibres, threads, yarns, fabrics or fibrous goods made from such materials, to be treated
- D06M2101/02—Natural fibres, other than mineral fibres
- D06M2101/10—Animal fibres
- D06M2101/12—Keratin fibres or silk
-
- D—TEXTILES; PAPER
- D06—TREATMENT OF TEXTILES OR THE LIKE; LAUNDERING; FLEXIBLE MATERIALS NOT OTHERWISE PROVIDED FOR
- D06M—TREATMENT, NOT PROVIDED FOR ELSEWHERE IN CLASS D06, OF FIBRES, THREADS, YARNS, FABRICS, FEATHERS OR FIBROUS GOODS MADE FROM SUCH MATERIALS
- D06M2200/00—Functionality of the treatment composition and/or properties imparted to the textile material
- D06M2200/10—Repellency against liquids
- D06M2200/12—Hydrophobic properties
-
- D—TEXTILES; PAPER
- D06—TREATMENT OF TEXTILES OR THE LIKE; LAUNDERING; FLEXIBLE MATERIALS NOT OTHERWISE PROVIDED FOR
- D06M—TREATMENT, NOT PROVIDED FOR ELSEWHERE IN CLASS D06, OF FIBRES, THREADS, YARNS, FABRICS, FEATHERS OR FIBROUS GOODS MADE FROM SUCH MATERIALS
- D06M2200/00—Functionality of the treatment composition and/or properties imparted to the textile material
- D06M2200/30—Flame or heat resistance, fire retardancy properties
-
- D—TEXTILES; PAPER
- D06—TREATMENT OF TEXTILES OR THE LIKE; LAUNDERING; FLEXIBLE MATERIALS NOT OTHERWISE PROVIDED FOR
- D06M—TREATMENT, NOT PROVIDED FOR ELSEWHERE IN CLASS D06, OF FIBRES, THREADS, YARNS, FABRICS, FEATHERS OR FIBROUS GOODS MADE FROM SUCH MATERIALS
- D06M2200/00—Functionality of the treatment composition and/or properties imparted to the textile material
- D06M2200/45—Shrinking resistance, anti-felting properties
Landscapes
- Engineering & Computer Science (AREA)
- Textile Engineering (AREA)
- Life Sciences & Earth Sciences (AREA)
- Chemical & Material Sciences (AREA)
- Biochemistry (AREA)
- Microbiology (AREA)
- Chemical Kinetics & Catalysis (AREA)
- General Chemical & Material Sciences (AREA)
- Zoology (AREA)
- Cosmetics (AREA)
- Treatments For Attaching Organic Compounds To Fibrous Goods (AREA)
- Chemical Or Physical Treatment Of Fibers (AREA)
Abstract
The invention discloses a kind of finishing technique of wool cap, including：Wool cap is immersed in the water ultrasonic single treatment wool cap；After pi-allyl diethyl phosphate is emulsified, the zinc oxide that silane coupling agent KH 570 is modified is added, adjusts pH, benzoyl peroxide is added after heating and obtains mixed liquor, single treatment wool cap is immersed and soaks to obtain after-treatment wool cap；Ethanol, acetic acid are mixed, add butyl titanate, adds silver fluoride, tetrabutyl ammonium fluoride, room temperature is positioned to material A；Salicylic acid and arginine are added to the water, add material A, soaking at room temperature obtains modified nano-titanium dioxide；P-doped Ludox, glutamine transaminage, chitosan, sodium metasilicate, lauryl sodium sulfate, six (4 amino-benzene oxygen) rings, three phosphonitrile, modified nano-titanium dioxide, catechin, sulfonic group beta cyclodextrin, coupling agent are added to the water ultrasonic finishing agent；After-treatment wool cap is immersed in finishing agent and is padded, cleans, dry, bake.
Description
Technical field
The present invention relates to wool field of hat, more particularly to a kind of finishing technique of wool cap.
Background technology
Wool cap is prepared by raw material of wool, has the characteristics that cold-proof comfort, is favored by people.On the one hand,
Wool is a kind of protein fibre, if not shining for a long time, easily grows bacterium, endangers people's health, on the other hand, due to wool
The scale layer on surface so that wool cap is in the solution repeatedly during extruding and kneading, there are fiber mutually winding and felt simultaneously,
Gap diminishes and tends to be close between fiber, it is impossible to which restorable felting phenomenon, influences a mao wearability for wool cap.Separately
Outside, due to the relatively high nitrogen content in wool fiber chemical constitution, though make wool cap with certain fire resistance, but still cannot
Meet the needs in some high efficiency flame retardance fields.Therefore, generally require to carry out antibacterial, felt proofing and fire-retardant whole to wool cap
Reason, improves its antibiotic property, felt proofing and anti-flammability.
The content of the invention
Based on technical problem existing for background technology, the present invention proposes a kind of finishing technique of wool cap, its process
Simply, there is excellent antibiotic property and felt proofing suitable for industrial production, the wool cap of preparation, while has excellent fire-retardant
Property.
A kind of finishing technique of wool cap proposed by the present invention, comprises the following steps：
Wool cap, be immersed in the water, the ultrasound 30-50min at 40-55 DEG C by S1, and single treatment wool is obtained after dry
Cap；
S2, by pi-allyl diethyl phosphate add emulsifier aqueous solution in, it is emulsified in the rotating speed of 5000-8000r/min
8-12min, adds the zinc oxide that Silane coupling reagent KH-570 is modified, and regulation system is acidity, is warming up to 75-85 DEG C, added
Benzoyl Oxide is uniformly mixing to obtain mixed liquor；Single treatment wool cap in S1 is immersed in mixed liquor, at 90-100 DEG C
Lower reaction 30-50min, after reaction through rinsing, drying to obtain after-treatment wool cap；
S3, mix ethanol and acetic acid, adds butyl titanate and stirs evenly, then adds silver fluoride and tetrabutyl fluorination
Ammonium, washs to neutrality after placing 2-3 days at room temperature, filters, is dried to obtain material A；Salicylic acid and arginine are added to the water, stirred
Material A is added after mixing uniformly, is soaked 3-5 days at room temperature, is filtered, washs, is dried to obtain modified nano-titanium dioxide；
S4, by p-doped Ludox, glutamine transaminage, chitosan, sodium metasilicate, lauryl sodium sulfate, six (4- amino
Phenoxy group) to be added to the water stirring equal for three phosphonitrile of ring, modified nano-titanium dioxide, catechin, sulfonic acid group-beta-cyclodextrin and coupling agent
Even, ultrasound 30-80min obtains finishing agent at 60-70 DEG C；
S5, two roll two leachings in finishing agent that the after-treatment wool cap in S2 is immersed in S4, then cleaned, dry
Do, bake the wool cap arranged.
Preferably, in S2, pi-allyl diethyl phosphate, emulsifying agent, the zinc oxide of Silane coupling reagent KH-570 modification, mistake
The weight ratio of Benzoyl Oxide is 30-50：1-3：5-17：1-2.3.
Preferably, in S2, the mass fraction of emulsifying agent is 3-5% in emulsifier aqueous solution.
Preferably, in S3, butyl titanate, ethanol, the volume ratio of acetic acid are 10-20：120-150：1-4.
Preferably, in S3, butyl titanate, silver fluoride, the mass ratio of tetrabutyl ammonium fluoride are 6-15：1-4：1-5.
Preferably, in S3, material A, salicylic acid, arginic weight ratio are 16-24：6-13：6-13.
Preferably, in S4, p-doped Ludox, glutamine transaminage, chitosan, sodium metasilicate, lauryl sodium sulfate,
Six (4- amino-benzene oxygens) rings three phosphonitrile, modified nano-titanium dioxide, catechin, sulfonic acid group-beta-cyclodextrin, coupling agent, water
Weight ratio is 30-65：20-45：10-38：2-10：1-5：20-50：20-35：6-17：3-15：2-5：1000.
Preferably, in S5, during two leachings two are rolled, bath raio 1：35-1：65, pick-up 85-90%.
Preferably, in S5, the temperature of drying is 60-80 DEG C.
Preferably, in S5, the temperature baked is 145-155 DEG C, and the time baked is 3-5min.
The finishing technique of wool cap of the present invention, it soaks ultrasound in wool cap water, eliminates wool fiber
The impurity on surface；Wool cap is added in pi-allyl p diethylaminobenzoic acid aqueous solution of ester, while adds Silane coupling reagent KH-570
Modified zinc oxide, under the action of benzoyl peroxide, what pi-allyl diethyl phosphate and Silane coupling reagent KH-570 were modified
Zinc oxide on the surface of woollen cap subbundle, makes that wool cap is water-fastness, and durable flame-proof is good, antibiotic property by double-bond polymerization
Can be excellent；In ethanol and acetic acid mixture, with butyl titanate, silver fluoride and tetrabutyl ammonium fluoride raw material, obtained it is fluorine-containing and
The nano-titanium dioxide material A of silver, after it is mixed with salicylic acid and arginine, salicylic acid and arginine are respectively with chelating and bridge
Even stable structure modification is to the surface of material A, and as the raw material of finishing agent, dispersiveness is more preferable in system, with glutamy
Amine transaminase, chitosan, catechin and sulfonic acid group-beta-cyclodextrin coordinate, and improve while woollen cap subbundle strength is kept
Antibiotic property, felt proofing and the water repellency of wool cap；P-doped Ludox, six (4- amino-benzene oxygens) rings, three phosphonitrile, paddy ammonia
In amide transaminase, chitosan addition system, cooperate, S1 pretreatments can be repaired and S2 flame retardant treatments make wool cap
Into strength damage, meanwhile, improve the combustibility and hot property of wool cap, assign wool cap excellent fire-retardant durable
Property.
Embodiment
In the following, technical scheme is described in detail by specific embodiment.
Embodiment 1
A kind of finishing technique of wool cap proposed by the present invention, comprises the following steps：
Wool cap, be immersed in the water, the ultrasound 50min at 40 DEG C by S1, and single treatment wool cap is obtained after dry；
S2, add pi-allyl diethyl phosphate in emulsifier aqueous solution, in the emulsified 8min of the rotating speed of 8000r/min,
The zinc oxide that Silane coupling reagent KH-570 is modified is added, regulation system is acidity, is warming up to 85 DEG C, adds benzoyl peroxide and stirs
Mix and uniformly obtain mixed liquor；Single treatment wool cap in S1 is immersed in mixed liquor, 50min is reacted at 90 DEG C, is reacted
After end after-treatment wool cap is obtained through rinsing, drying；
S3, mix ethanol and acetic acid, adds butyl titanate and stirs evenly, then adds silver fluoride and tetrabutyl fluorination
Ammonium, washs to neutrality after placing 3 days at room temperature, filters, is dried to obtain material A；Salicylic acid and arginine are added to the water, stirred
Material A is added after uniformly, is soaked 3 days at room temperature, is filtered, washs, is dried to obtain modified nano-titanium dioxide；
S4, by p-doped Ludox, glutamine transaminage, chitosan, sodium metasilicate, lauryl sodium sulfate, six (4- amino
Phenoxy group) to be added to the water stirring equal for three phosphonitrile of ring, modified nano-titanium dioxide, catechin, sulfonic acid group-beta-cyclodextrin and coupling agent
Even, ultrasound 30min obtains finishing agent at 70 DEG C；
S5, two roll two leachings in finishing agent that the after-treatment wool cap in S2 is immersed in S4, then cleaned, dry
Do, bake the wool cap arranged.
Embodiment 2
A kind of finishing technique of wool cap proposed by the present invention, comprises the following steps：
Wool cap, be immersed in the water, the ultrasound 30min at 55 DEG C by S1, and single treatment wool cap is obtained after dry；
S2, add pi-allyl diethyl phosphate in emulsifier aqueous solution, in the emulsified 12min of the rotating speed of 5000r/min,
The zinc oxide that Silane coupling reagent KH-570 is modified is added, regulation system is acidity, is warming up to 75 DEG C, adds benzoyl peroxide and stirs
Mix and uniformly obtain mixed liquor；Single treatment wool cap in S1 is immersed in mixed liquor, 30min is reacted at 100 DEG C, is reacted
After end after-treatment wool cap is obtained through rinsing, drying；
S3, mix ethanol and acetic acid, adds butyl titanate and stirs evenly, then adds silver fluoride and tetrabutyl fluorination
Ammonium, washs to neutrality after placing 2 days at room temperature, filters, is dried to obtain material A；Salicylic acid and arginine are added to the water, stirred
Material A is added after uniformly, is soaked 5 days at room temperature, is filtered, washs, is dried to obtain modified nano-titanium dioxide；
S4, by p-doped Ludox, glutamine transaminage, chitosan, sodium metasilicate, lauryl sodium sulfate, six (4- amino
Phenoxy group) to be added to the water stirring equal for three phosphonitrile of ring, modified nano-titanium dioxide, catechin, sulfonic acid group-beta-cyclodextrin and coupling agent
Even, ultrasound 80min obtains finishing agent at 60 DEG C；
S5, two roll two leachings in finishing agent that the after-treatment wool cap in S2 is immersed in S4, then cleaned, dry
Do, bake the wool cap arranged.
Embodiment 3
A kind of finishing technique of wool cap proposed by the present invention, comprises the following steps：
Wool cap, be immersed in the water, the ultrasound 46min at 45 DEG C by S1, and single treatment wool cap is obtained after dry；
S2, add pi-allyl diethyl phosphate in emulsifier aqueous solution, in the emulsified 10min of the rotating speed of 6000r/min,
The zinc oxide that Silane coupling reagent KH-570 is modified is added, regulation system is acidity, is warming up to 77 DEG C, adds benzoyl peroxide and stirs
Mix and uniformly obtain mixed liquor, wherein, pi-allyl diethyl phosphate, emulsifying agent, the zinc oxide of Silane coupling reagent KH-570 modification, mistake
The weight ratio of Benzoyl Oxide is 50：1：17：1, the mass fraction of emulsifying agent is 5% in emulsifier aqueous solution；By one in S1
Secondary processing wool cap is immersed in mixed liquor, 45min is reacted at 92 DEG C, after reaction through rinsing, drying to obtain secondary place
Manage wool cap；
S3, mix ethanol and acetic acid, adds butyl titanate and stirs evenly, wherein, butyl titanate, ethanol, the body of acetic acid
Product is than being 20：120：4, silver fluoride and tetrabutyl ammonium fluoride are then added, wherein, butyl titanate, silver fluoride, tetrabutyl ammonium fluoride
Mass ratio be 6：4：1, washed after placing 3 days at room temperature to neutrality, filter, be dried to obtain material A；By salicylic acid and arginine
It is added to the water, is stirring evenly and then adding into material A, wherein, material A, salicylic acid, arginic weight ratio are 16：13：6, at room temperature
Immersion 5 days, filters, washs, is dried to obtain modified nano-titanium dioxide；
S4, by p-doped Ludox, glutamine transaminage, chitosan, sodium metasilicate, lauryl sodium sulfate, six (4- amino
Phenoxy group) to be added to the water stirring equal for three phosphonitrile of ring, modified nano-titanium dioxide, catechin, sulfonic acid group-beta-cyclodextrin and coupling agent
It is even, wherein, p-doped Ludox, glutamine transaminage, chitosan, sodium metasilicate, lauryl sodium sulfate, six (4- aminobenzene oxygen
Base) three phosphonitrile of ring, modified nano-titanium dioxide, catechin, sulfonic acid group-beta-cyclodextrin, coupling agent, the weight ratio of water be 65：20：
38：2：5：20：35：6：15：2：1000, ultrasound 45min obtains finishing agent at 68 DEG C；
S5, two roll two leachings in finishing agent that the after-treatment wool cap in S2 is immersed in S4, bath raio 1：65, roll remaining
Rate is 85%, and in 80 DEG C of drying after cleaning, the wool cap that 5min is arranged is baked at 145 DEG C.
Embodiment 4
A kind of finishing technique of wool cap proposed by the present invention, comprises the following steps：
Wool cap, be immersed in the water, the ultrasound 38min at 52 DEG C by S1, and single treatment wool cap is obtained after dry；
S2, add pi-allyl diethyl phosphate in emulsifier aqueous solution, in the emulsified 9min of the rotating speed of 7000r/min,
The zinc oxide that Silane coupling reagent KH-570 is modified is added, regulation system is acidity, is warming up to 82 DEG C, adds benzoyl peroxide and stirs
Mix and uniformly obtain mixed liquor, wherein, pi-allyl diethyl phosphate, emulsifying agent, the zinc oxide of Silane coupling reagent KH-570 modification, mistake
The weight ratio of Benzoyl Oxide is 30：3：5：2.3, the mass fraction of emulsifying agent is 3% in emulsifier aqueous solution；By one in S1
Secondary processing wool cap is immersed in mixed liquor, 35min is reacted at 98 DEG C, after reaction through rinsing, drying to obtain secondary place
Manage wool cap；
S3, mix ethanol and acetic acid, adds butyl titanate and stirs evenly, wherein, butyl titanate, ethanol, the body of acetic acid
Product is than being 10：150：1, silver fluoride and tetrabutyl ammonium fluoride are then added, wherein, butyl titanate, silver fluoride, tetrabutyl ammonium fluoride
Mass ratio be 15：1：5, washed after placing 2 days at room temperature to neutrality, filter, be dried to obtain material A；By salicylic acid and smart ammonia
Acid is added to the water, and is stirring evenly and then adding into material A, wherein, material A, salicylic acid, arginic weight ratio are 24：6：13, room temperature
Lower immersion 3 days, filters, washs, is dried to obtain modified nano-titanium dioxide；
S4, by p-doped Ludox, glutamine transaminage, chitosan, sodium metasilicate, lauryl sodium sulfate, six (4- amino
Phenoxy group) to be added to the water stirring equal for three phosphonitrile of ring, modified nano-titanium dioxide, catechin, sulfonic acid group-beta-cyclodextrin and coupling agent
It is even, wherein, p-doped Ludox, glutamine transaminage, chitosan, sodium metasilicate, lauryl sodium sulfate, six (4- aminobenzene oxygen
Base) three phosphonitrile of ring, modified nano-titanium dioxide, catechin, sulfonic acid group-beta-cyclodextrin, coupling agent, the weight ratio of water be 30：45：
10：10：1：50：20：17：3：5：1000, ultrasound 72min obtains finishing agent at 62 DEG C；
S5, two roll two leachings in finishing agent that the after-treatment wool cap in S2 is immersed in S4, bath raio 1：35, roll remaining
Rate is 90%, and in 60 DEG C of drying after cleaning, the wool cap that 3min is arranged is baked at 155 DEG C.
Embodiment 5
A kind of finishing technique of wool cap proposed by the present invention, comprises the following steps：
Wool cap, be immersed in the water, the ultrasound 40min at 50 DEG C by S1, and single treatment wool cap is obtained after dry；
S2, add pi-allyl diethyl phosphate in emulsifier aqueous solution, in the emulsified 10min of the rotating speed of 6000r/min,
The zinc oxide that Silane coupling reagent KH-570 is modified is added, regulation system is acidity, is warming up to 80 DEG C, adds benzoyl peroxide and stirs
Mix and uniformly obtain mixed liquor, wherein, pi-allyl diethyl phosphate, emulsifying agent, the zinc oxide of Silane coupling reagent KH-570 modification, mistake
The weight ratio of Benzoyl Oxide is 40：2：15：2, the mass fraction of emulsifying agent is 4% in emulsifier aqueous solution；By one in S1
Secondary processing wool cap is immersed in mixed liquor, 40min is reacted at 95 DEG C, after reaction through rinsing, drying to obtain secondary place
Manage wool cap；
S3, mix ethanol and acetic acid, adds butyl titanate and stirs evenly, wherein, butyl titanate, ethanol, the body of acetic acid
Product is than being 15：130：3, silver fluoride and tetrabutyl ammonium fluoride are then added, wherein, butyl titanate, silver fluoride, tetrabutyl ammonium fluoride
Mass ratio be 8：2：3, washed after placing 2 days at room temperature to neutrality, filter, be dried to obtain material A；By salicylic acid and arginine
It is added to the water, is stirring evenly and then adding into material A, wherein, material A, salicylic acid, arginic weight ratio are 21：9：10, at room temperature
Immersion 4 days, filters, washs, is dried to obtain modified nano-titanium dioxide；
S4, by p-doped Ludox, glutamine transaminage, chitosan, sodium metasilicate, lauryl sodium sulfate, six (4- amino
Phenoxy group) to be added to the water stirring equal for three phosphonitrile of ring, modified nano-titanium dioxide, catechin, sulfonic acid group-beta-cyclodextrin and coupling agent
It is even, wherein, p-doped Ludox, glutamine transaminage, chitosan, sodium metasilicate, lauryl sodium sulfate, six (4- aminobenzene oxygen
Base) three phosphonitrile of ring, modified nano-titanium dioxide, catechin, sulfonic acid group-beta-cyclodextrin, coupling agent, the weight ratio of water be 52：40：
31：7：3：33：29：15：8：3：1000, ultrasound 50min obtains finishing agent at 65 DEG C；
S5, two roll two leachings in finishing agent that the after-treatment wool cap in S2 is immersed in S4, bath raio 1：45, roll remaining
Rate is 88%, and in 70 DEG C of drying after cleaning, the wool cap that 4min is arranged is baked at 148 DEG C.
The foregoing is only a preferred embodiment of the present invention, but protection scope of the present invention be not limited thereto,
Any one skilled in the art the invention discloses technical scope in, technique according to the invention scheme and its
Inventive concept is subject to equivalent substitution or change, should be covered by the protection scope of the present invention.
Claims (10)
1. a kind of finishing technique of wool cap, it is characterised in that comprise the following steps：
Wool cap, be immersed in the water, the ultrasound 30-50min at 40-55 DEG C by S1, and single treatment wool cap is obtained after dry；
S2, by pi-allyl diethyl phosphate add emulsifier aqueous solution in, in the emulsified 8- of the rotating speed of 5000-8000r/min
12min, adds the zinc oxide that Silane coupling reagent KH-570 is modified, and regulation system is acidity, is warming up to 75-85 DEG C, adds peroxide
Change benzoyl and be uniformly mixing to obtain mixed liquor；Single treatment wool cap in S1 is immersed in mixed liquor, at 90-100 DEG C
30-50min is reacted, after reaction through rinsing, drying to obtain after-treatment wool cap；
S3, mix ethanol and acetic acid, adds butyl titanate and stirs evenly, then adds silver fluoride and tetrabutyl ammonium fluoride, room
Temperature lower placement is washed to neutrality after 2-3 days, is filtered, is dried to obtain material A；Salicylic acid and arginine are added to the water, stirring is equal
Material A is added after even, is soaked 3-5 days at room temperature, is filtered, washs, is dried to obtain modified nano-titanium dioxide；
S4, by p-doped Ludox, glutamine transaminage, chitosan, sodium metasilicate, lauryl sodium sulfate, six (4- aminobenzene oxygen
Base) three phosphonitrile of ring, modified nano-titanium dioxide, catechin, sulfonic acid group-beta-cyclodextrin and coupling agent be added to the water and stir evenly,
Ultrasound 30-80min obtains finishing agent at 60-70 DEG C；
S5, two roll two leachings in finishing agent that the after-treatment wool cap in S2 is immersed in S4, then cleaned, drying, roasting
Dry the wool cap arranged.
2. the finishing technique of wool cap according to claim 1, it is characterised in that in S2, pi-allyl diethyl phosphate,
Emulsifying agent, the zinc oxide of Silane coupling reagent KH-570 modification, the weight ratio of benzoyl peroxide are 30-50：1-3：5-17：1-
2.3。
3. the finishing technique of wool cap according to claim 1 or claim 2, it is characterised in that in S2, in emulsifier aqueous solution
The mass fraction of emulsifying agent is 3-5%.
4. according to the finishing technique of wool cap any one of claim 1-3, it is characterised in that in S3, metatitanic acid fourth
Ester, ethanol, the volume ratio of acetic acid are 10-20：120-150：1-4.
5. according to the finishing technique of wool cap any one of claim 1-4, it is characterised in that in S3, metatitanic acid fourth
Ester, silver fluoride, the mass ratio of tetrabutyl ammonium fluoride are 6-15：1-4：1-5.
6. according to the finishing technique of wool cap any one of claim 1-5, it is characterised in that in S3, material A,
Salicylic acid, arginic weight ratio are 16-24：6-13：6-13.
7. according to the finishing technique of wool cap any one of claim 1-6, it is characterised in that in S4, p-doped silicon
Colloidal sol, glutamine transaminage, chitosan, sodium metasilicate, lauryl sodium sulfate, six (4- amino-benzene oxygens) rings, three phosphonitrile, change
Property nano-titanium dioxide, catechin, sulfonic acid group-beta-cyclodextrin, coupling agent, the weight ratio of water are 30-65：20-45：10-38：2-
10：1-5：20-50：20-35：6-17：3-15：2-5：1000.
8. according to the finishing technique of wool cap any one of claim 1-7, it is characterised in that in S5, in two leachings
During two roll, bath raio 1：35-1：65, pick-up 85-90%.
9. according to the finishing technique of wool cap any one of claim 1-8, it is characterised in that in S5, drying
Temperature is 60-80 DEG C.
10. according to the finishing technique of wool cap any one of claim 1-9, it is characterised in that in S5, bake
Temperature is 145-155 DEG C, and the time baked is 3-5min.
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